WO2003042155A3 - Procede de preparation de dialkylethylamines a partir de dialkylamines et d'ethylene - Google Patents

Procede de preparation de dialkylethylamines a partir de dialkylamines et d'ethylene Download PDF

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Publication number
WO2003042155A3
WO2003042155A3 PCT/EP2002/012581 EP0212581W WO03042155A3 WO 2003042155 A3 WO2003042155 A3 WO 2003042155A3 EP 0212581 W EP0212581 W EP 0212581W WO 03042155 A3 WO03042155 A3 WO 03042155A3
Authority
WO
WIPO (PCT)
Prior art keywords
amines
dialkyl
ethyl
ethylene
producing
Prior art date
Application number
PCT/EP2002/012581
Other languages
German (de)
English (en)
Other versions
WO2003042155A2 (fr
Inventor
Frank Funke
Ulrich Steinbrenner
Ralf Boehling
Original Assignee
Basf Ag
Frank Funke
Ulrich Steinbrenner
Ralf Boehling
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Basf Ag, Frank Funke, Ulrich Steinbrenner, Ralf Boehling filed Critical Basf Ag
Priority to AU2002358006A priority Critical patent/AU2002358006A1/en
Publication of WO2003042155A2 publication Critical patent/WO2003042155A2/fr
Publication of WO2003042155A3 publication Critical patent/WO2003042155A3/fr

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Classifications

    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C209/00Preparation of compounds containing amino groups bound to a carbon skeleton
    • C07C209/60Preparation of compounds containing amino groups bound to a carbon skeleton by condensation or addition reactions, e.g. Mannich reaction, addition of ammonia or amines to alkenes or to alkynes or addition of compounds containing an active hydrogen atom to Schiff's bases, quinone imines, or aziranes

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)

Abstract

La présente invention concerne un procédé de préparation de dialkyléthylamines R2NEt à partir de dialkylamines R2NH et d'éthylène en la présence de dialkylamide de sodium NaNR2 en tant que catalyseur, avec R = méthyle ou éthyle, la concentration en NaNR2 étant ≤ 1,0 % molaire, de préférence ≤ 0,8 % molaire, de préférence ≤ 0,25 % molaire les pourcentages se rapportant à R2NH - lorsque R = éthyle.
PCT/EP2002/012581 2001-11-12 2002-11-11 Procede de preparation de dialkylethylamines a partir de dialkylamines et d'ethylene WO2003042155A2 (fr)

Priority Applications (1)

Application Number Priority Date Filing Date Title
AU2002358006A AU2002358006A1 (en) 2001-11-12 2002-11-11 Method for producing dialkyl ethyl amines from dialkyl amines and ethylene

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
DE2001155525 DE10155525A1 (de) 2001-11-12 2001-11-12 Verfahren zur Herstellung von Dialkylethylaminen aus Dialkylaminen und Ethylen
DE10155525.3 2001-11-12

Publications (2)

Publication Number Publication Date
WO2003042155A2 WO2003042155A2 (fr) 2003-05-22
WO2003042155A3 true WO2003042155A3 (fr) 2003-10-09

Family

ID=7705479

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/EP2002/012581 WO2003042155A2 (fr) 2001-11-12 2002-11-11 Procede de preparation de dialkylethylamines a partir de dialkylamines et d'ethylene

Country Status (3)

Country Link
AU (1) AU2002358006A1 (fr)
DE (1) DE10155525A1 (fr)
WO (1) WO2003042155A2 (fr)

Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2501556A (en) * 1949-12-16 1950-03-21 Du Pont Alkali metals and their hydrides as catalysts in amine condensation
US2750417A (en) * 1953-04-14 1956-06-12 Ethyl Corp Amine alkylation
US2984687A (en) * 1956-04-27 1961-05-16 Standard Oil Co Catalytic process for n-alkylation of amines
WO2002000597A2 (fr) * 2000-06-28 2002-01-03 Basf Aktiengesellschaft Procede de production d'alkylamines

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2501556A (en) * 1949-12-16 1950-03-21 Du Pont Alkali metals and their hydrides as catalysts in amine condensation
US2750417A (en) * 1953-04-14 1956-06-12 Ethyl Corp Amine alkylation
US2984687A (en) * 1956-04-27 1961-05-16 Standard Oil Co Catalytic process for n-alkylation of amines
WO2002000597A2 (fr) * 2000-06-28 2002-01-03 Basf Aktiengesellschaft Procede de production d'alkylamines

Non-Patent Citations (2)

* Cited by examiner, † Cited by third party
Title
PEZ, GUIDO P. ET AL., PURE & APPL. CHEM., vol. 57, no. 12, 1985, pages 1917 - 1926, XP001091218 *
STEINBORN, DIRK ET AL., Z. CHEM., vol. 29, no. 9, 1989, pages 333 - 334, XP001091225 *

Also Published As

Publication number Publication date
AU2002358006A1 (en) 2003-05-26
WO2003042155A2 (fr) 2003-05-22
DE10155525A1 (de) 2003-05-22

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