WO2003010136A1 - Organometallic complexes, catalysts containing the same, and process for preparation of carboxylic esters - Google Patents
Organometallic complexes, catalysts containing the same, and process for preparation of carboxylic esters Download PDFInfo
- Publication number
- WO2003010136A1 WO2003010136A1 PCT/JP2002/007051 JP0207051W WO03010136A1 WO 2003010136 A1 WO2003010136 A1 WO 2003010136A1 JP 0207051 W JP0207051 W JP 0207051W WO 03010136 A1 WO03010136 A1 WO 03010136A1
- Authority
- WO
- WIPO (PCT)
- Prior art keywords
- same
- carboxylic esters
- organometallic complexes
- alkyl
- preparation
- Prior art date
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Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F5/00—Compounds containing elements of Groups 3 or 13 of the Periodic System
- C07F5/06—Aluminium compounds
- C07F5/069—Aluminium compounds without C-aluminium linkages
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
- B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
- B01J31/22—Organic complexes
- B01J31/2204—Organic complexes the ligands containing oxygen or sulfur as complexing atoms
- B01J31/2208—Oxygen, e.g. acetylacetonates
- B01J31/2226—Anionic ligands, i.e. the overall ligand carries at least one formal negative charge
- B01J31/2243—At least one oxygen and one nitrogen atom present as complexing atoms in an at least bidentate or bridging ligand
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
- B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
- B01J31/22—Organic complexes
- B01J31/2204—Organic complexes the ligands containing oxygen or sulfur as complexing atoms
- B01J31/2208—Oxygen, e.g. acetylacetonates
- B01J31/2226—Anionic ligands, i.e. the overall ligand carries at least one formal negative charge
- B01J31/2252—Sulfonate ligands
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
- B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
- B01J31/22—Organic complexes
- B01J31/2204—Organic complexes the ligands containing oxygen or sulfur as complexing atoms
- B01J31/2208—Oxygen, e.g. acetylacetonates
- B01J31/2226—Anionic ligands, i.e. the overall ligand carries at least one formal negative charge
- B01J31/2252—Sulfonate ligands
- B01J31/2256—Sulfonate ligands being perfluorinated, i.e. comprising at least one perfluorinated moiety as substructure in case of polyfunctional ligands
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
- B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
- B01J31/22—Organic complexes
- B01J31/2204—Organic complexes the ligands containing oxygen or sulfur as complexing atoms
- B01J31/226—Sulfur, e.g. thiocarbamates
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C311/00—Amides of sulfonic acids, i.e. compounds having singly-bound oxygen atoms of sulfo groups replaced by nitrogen atoms, not being part of nitro or nitroso groups
- C07C311/01—Sulfonamides having sulfur atoms of sulfonamide groups bound to acyclic carbon atoms
- C07C311/02—Sulfonamides having sulfur atoms of sulfonamide groups bound to acyclic carbon atoms of an acyclic saturated carbon skeleton
- C07C311/09—Sulfonamides having sulfur atoms of sulfonamide groups bound to acyclic carbon atoms of an acyclic saturated carbon skeleton the carbon skeleton being further substituted by at least two halogen atoms
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C67/00—Preparation of carboxylic acid esters
- C07C67/44—Preparation of carboxylic acid esters by oxidation-reduction of aldehydes, e.g. Tishchenko reaction
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F7/00—Compounds containing elements of Groups 4 or 14 of the Periodic System
- C07F7/003—Compounds containing elements of Groups 4 or 14 of the Periodic System without C-Metal linkages
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
- B01J2531/02—Compositional aspects of complexes used, e.g. polynuclearity
- B01J2531/0261—Complexes comprising ligands with non-tetrahedral chirality
- B01J2531/0266—Axially chiral or atropisomeric ligands, e.g. bulky biaryls such as donor-substituted binaphthalenes, e.g. "BINAP" or "BINOL"
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
- B01J2531/20—Complexes comprising metals of Group II (IIA or IIB) as the central metal
- B01J2531/26—Zinc
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
- B01J2531/30—Complexes comprising metals of Group III (IIIA or IIIB) as the central metal
- B01J2531/31—Aluminium
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
- B01J2531/30—Complexes comprising metals of Group III (IIIA or IIIB) as the central metal
- B01J2531/32—Gallium
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
- B01J2531/30—Complexes comprising metals of Group III (IIIA or IIIB) as the central metal
- B01J2531/33—Indium
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
- B01J2531/40—Complexes comprising metals of Group IV (IVA or IVB) as the central metal
- B01J2531/42—Tin
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
- B01J2531/40—Complexes comprising metals of Group IV (IVA or IVB) as the central metal
- B01J2531/48—Zirconium
Abstract
Applications Claiming Priority (4)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP2001223862 | 2001-07-25 | ||
JP2001-223862 | 2001-07-25 | ||
JP2001292276A JP2003104953A (en) | 2001-07-25 | 2001-09-25 | Organometallic complex compound and method for producing carboxylic acid ester using the compound |
JP2001-292276 | 2001-09-25 |
Publications (1)
Publication Number | Publication Date |
---|---|
WO2003010136A1 true WO2003010136A1 (en) | 2003-02-06 |
Family
ID=26619210
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
PCT/JP2002/007051 WO2003010136A1 (en) | 2001-07-25 | 2002-07-11 | Organometallic complexes, catalysts containing the same, and process for preparation of carboxylic esters |
Country Status (3)
Country | Link |
---|---|
JP (1) | JP2003104953A (en) |
CN (1) | CN1464875A (en) |
WO (1) | WO2003010136A1 (en) |
Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO2004047990A1 (en) * | 2002-11-27 | 2004-06-10 | Showa Denko K. K. | Catalyst for the preparation of carboxylic esters and process for the preparation of carboxylic esters with the same |
CN109331875A (en) * | 2018-11-14 | 2019-02-15 | 山西大学 | A kind of double-core magnesium metallic catalyst and its preparation method and application |
Families Citing this family (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN116874411B (en) * | 2023-07-13 | 2024-04-16 | 西安欧得光电材料有限公司 | Synthesis method of 1-bromocarbazole |
Citations (7)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3920444A (en) * | 1970-12-21 | 1975-11-18 | Minnesota Mining & Mfg | Method comprising the use of N-substituted perfluoroalkyanesulfonamides as herbicidal and plant growth modifying agents, and composition |
JPS55108430A (en) * | 1979-02-13 | 1980-08-20 | Japan Synthetic Rubber Co Ltd | Rubber composition |
JPH05230133A (en) * | 1992-02-19 | 1993-09-07 | Mitsui Toatsu Chem Inc | Olefin polymerization catalyst and production of polyolefin using the same |
JPH05295023A (en) * | 1992-04-24 | 1993-11-09 | Mitsui Toatsu Chem Inc | Solid catalyst for polymerizing olefin and production of polyolefin using the same |
DE4238233A1 (en) * | 1992-11-12 | 1994-05-19 | Fahlberg List Pharma Gmbh | Inhibiting 5- or 15-lipoxygenase or cyclo:oxygenase - using N-sulphonyl-aminophenol derivs., e.g. for treating asthma, inflammation or allergy |
US5591848A (en) * | 1994-10-07 | 1997-01-07 | The Penn State Research Foundation | Spiroconjugated charge-transfer dyes for optical applications |
WO1998012190A2 (en) * | 1996-09-11 | 1998-03-26 | Krenitsky Pharmaceutical, Inc. | Phenoxathiin derivatives as inhibitors of monoamine oxidase |
-
2001
- 2001-09-25 JP JP2001292276A patent/JP2003104953A/en active Pending
-
2002
- 2002-07-11 CN CN02802433A patent/CN1464875A/en active Pending
- 2002-07-11 WO PCT/JP2002/007051 patent/WO2003010136A1/en active Application Filing
Patent Citations (7)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3920444A (en) * | 1970-12-21 | 1975-11-18 | Minnesota Mining & Mfg | Method comprising the use of N-substituted perfluoroalkyanesulfonamides as herbicidal and plant growth modifying agents, and composition |
JPS55108430A (en) * | 1979-02-13 | 1980-08-20 | Japan Synthetic Rubber Co Ltd | Rubber composition |
JPH05230133A (en) * | 1992-02-19 | 1993-09-07 | Mitsui Toatsu Chem Inc | Olefin polymerization catalyst and production of polyolefin using the same |
JPH05295023A (en) * | 1992-04-24 | 1993-11-09 | Mitsui Toatsu Chem Inc | Solid catalyst for polymerizing olefin and production of polyolefin using the same |
DE4238233A1 (en) * | 1992-11-12 | 1994-05-19 | Fahlberg List Pharma Gmbh | Inhibiting 5- or 15-lipoxygenase or cyclo:oxygenase - using N-sulphonyl-aminophenol derivs., e.g. for treating asthma, inflammation or allergy |
US5591848A (en) * | 1994-10-07 | 1997-01-07 | The Penn State Research Foundation | Spiroconjugated charge-transfer dyes for optical applications |
WO1998012190A2 (en) * | 1996-09-11 | 1998-03-26 | Krenitsky Pharmaceutical, Inc. | Phenoxathiin derivatives as inhibitors of monoamine oxidase |
Non-Patent Citations (5)
Title |
---|
ANCHISI CARLO ET AL.: "Studies on the synthesis of heterocyclic compounds", J. HETEROCYCL. CHEM., vol. 13, no. 5, 1976, pages 1033 - 1036, XP002957699 * |
ANDRAE K. ET AL.: "1,2-Phenyleneoxothio 3d-element compounds", Z. ANORG. ALLG. CHEM., vol. 498, 1983, pages 199 - 204, XP002957698 * |
HANSON G. ET AL.: "Convenient routes of 4,4''-functionalized o-terphenyls and 2,2''-functionalized biphenyls", J. ORG.CHEM., vol. 46, no. 26, 1981, pages 5441 - 5443, XP002959801 * |
STEGMANN HARTMUT B. ET AL.: "Transformation of 2,2-diphenyl-2-fluor-2,3-dihydro-1,3,2-benzoxazaphospholen", PHOSPHORUS SULFUR, vol. 8, no. 1, 1980, pages 59 - 66, XP002959802 * |
TSUTOMU ISHIKAWA ET AL.: "Anomalous substituent effects in the bischler-napieralski reaction of 2-aryl aromatic formamides", JOURNAL OF ORGANIC CHEMISTRY, vol. 65, no. 26, 2000, pages 9143 - 9151, XP002957700 * |
Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO2004047990A1 (en) * | 2002-11-27 | 2004-06-10 | Showa Denko K. K. | Catalyst for the preparation of carboxylic esters and process for the preparation of carboxylic esters with the same |
CN109331875A (en) * | 2018-11-14 | 2019-02-15 | 山西大学 | A kind of double-core magnesium metallic catalyst and its preparation method and application |
Also Published As
Publication number | Publication date |
---|---|
CN1464875A (en) | 2003-12-31 |
JP2003104953A (en) | 2003-04-09 |
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