WO2002100992A1 - Methyl ester-based chewing gum remover - Google Patents
Methyl ester-based chewing gum remover Download PDFInfo
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- WO2002100992A1 WO2002100992A1 PCT/US2002/018309 US0218309W WO02100992A1 WO 2002100992 A1 WO2002100992 A1 WO 2002100992A1 US 0218309 W US0218309 W US 0218309W WO 02100992 A1 WO02100992 A1 WO 02100992A1
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- oil
- Prior art date
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- 229940112822 chewing gum Drugs 0.000 title claims abstract description 20
- 235000015218 chewing gum Nutrition 0.000 title claims abstract description 20
- 150000004702 methyl esters Chemical class 0.000 title claims description 6
- 239000000203 mixture Substances 0.000 claims abstract description 97
- 239000004094 surface-active agent Substances 0.000 claims abstract description 17
- 150000003505 terpenes Chemical class 0.000 claims abstract description 10
- 235000007586 terpenes Nutrition 0.000 claims abstract description 10
- 229920006395 saturated elastomer Polymers 0.000 claims abstract description 9
- 150000001732 carboxylic acid derivatives Chemical class 0.000 claims abstract 3
- 238000000034 method Methods 0.000 claims description 21
- 150000001412 amines Chemical class 0.000 claims description 15
- 238000004140 cleaning Methods 0.000 claims description 10
- 125000004432 carbon atom Chemical group C* 0.000 claims description 6
- QCTZUSWOKFCWNB-QXMHVHEDSA-N (z)-n,n-dimethyloctadec-9-en-1-amine oxide Chemical group CCCCCCCC\C=C/CCCCCCCC[N+](C)(C)[O-] QCTZUSWOKFCWNB-QXMHVHEDSA-N 0.000 claims description 4
- 125000005907 alkyl ester group Chemical group 0.000 claims description 4
- 239000004359 castor oil Substances 0.000 claims description 4
- 235000019438 castor oil Nutrition 0.000 claims description 4
- ZEMPKEQAKRGZGQ-XOQCFJPHSA-N glycerol triricinoleate Natural products CCCCCC[C@@H](O)CC=CCCCCCCCC(=O)OC[C@@H](COC(=O)CCCCCCCC=CC[C@@H](O)CCCCCC)OC(=O)CCCCCCCC=CC[C@H](O)CCCCCC ZEMPKEQAKRGZGQ-XOQCFJPHSA-N 0.000 claims description 4
- XMGQYMWWDOXHJM-UHFFFAOYSA-N limonene Chemical compound CC(=C)C1CCC(C)=CC1 XMGQYMWWDOXHJM-UHFFFAOYSA-N 0.000 claims description 4
- 125000004178 (C1-C4) alkyl group Chemical group 0.000 abstract description 5
- -1 alkyl radical Chemical group 0.000 description 11
- 150000001735 carboxylic acids Chemical class 0.000 description 5
- 235000014113 dietary fatty acids Nutrition 0.000 description 4
- 229930195729 fatty acid Natural products 0.000 description 4
- 239000000194 fatty acid Substances 0.000 description 4
- 239000002904 solvent Substances 0.000 description 4
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 3
- 125000000217 alkyl group Chemical group 0.000 description 3
- 238000009472 formulation Methods 0.000 description 3
- 150000003871 sulfonates Chemical class 0.000 description 3
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 3
- 235000013162 Cocos nucifera Nutrition 0.000 description 2
- 244000060011 Cocos nucifera Species 0.000 description 2
- 230000032050 esterification Effects 0.000 description 2
- 238000005886 esterification reaction Methods 0.000 description 2
- 150000004665 fatty acids Chemical class 0.000 description 2
- DUIOKRXOKLLURE-UHFFFAOYSA-N 2-octylphenol Chemical compound CCCCCCCCC1=CC=CC=C1O DUIOKRXOKLLURE-UHFFFAOYSA-N 0.000 description 1
- BJEBSDPKCMJMEJ-UHFFFAOYSA-N 3-(dodecanoylamino)propyl-oxidoazanium Chemical compound CCCCCCCCCCCC(=O)NCCC[NH2+][O-] BJEBSDPKCMJMEJ-UHFFFAOYSA-N 0.000 description 1
- 239000004215 Carbon black (E152) Substances 0.000 description 1
- 239000005639 Lauric acid Substances 0.000 description 1
- ULUAUXLGCMPNKK-UHFFFAOYSA-N Sulfobutanedioic acid Chemical class OC(=O)CC(C(O)=O)S(O)(=O)=O ULUAUXLGCMPNKK-UHFFFAOYSA-N 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- RGCKGOZRHPZPFP-UHFFFAOYSA-N alizarin Chemical compound C1=CC=C2C(=O)C3=C(O)C(O)=CC=C3C(=O)C2=C1 RGCKGOZRHPZPFP-UHFFFAOYSA-N 0.000 description 1
- 150000004996 alkyl benzenes Chemical class 0.000 description 1
- 150000008051 alkyl sulfates Chemical class 0.000 description 1
- 239000003945 anionic surfactant Substances 0.000 description 1
- BUOSLGZEBFSUDD-BGPZCGNYSA-N bis[(1s,3s,4r,5r)-4-methoxycarbonyl-8-methyl-8-azabicyclo[3.2.1]octan-3-yl] 2,4-diphenylcyclobutane-1,3-dicarboxylate Chemical compound O([C@H]1C[C@@H]2CC[C@@H](N2C)[C@H]1C(=O)OC)C(=O)C1C(C=2C=CC=CC=2)C(C(=O)O[C@@H]2[C@@H]([C@H]3CC[C@H](N3C)C2)C(=O)OC)C1C1=CC=CC=C1 BUOSLGZEBFSUDD-BGPZCGNYSA-N 0.000 description 1
- 238000006243 chemical reaction Methods 0.000 description 1
- 229940031728 cocamidopropylamine oxide Drugs 0.000 description 1
- 229940117583 cocamine Drugs 0.000 description 1
- SYELZBGXAIXKHU-UHFFFAOYSA-N dodecyldimethylamine N-oxide Chemical compound CCCCCCCCCCCC[N+](C)(C)[O-] SYELZBGXAIXKHU-UHFFFAOYSA-N 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- 150000002148 esters Chemical class 0.000 description 1
- RTZKZFJDLAIYFH-UHFFFAOYSA-N ether Substances CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 1
- 150000002191 fatty alcohols Chemical class 0.000 description 1
- 229930195733 hydrocarbon Natural products 0.000 description 1
- 150000002430 hydrocarbons Chemical class 0.000 description 1
- 239000004615 ingredient Substances 0.000 description 1
- WCYWZMWISLQXQU-UHFFFAOYSA-N methyl Chemical class [CH3] WCYWZMWISLQXQU-UHFFFAOYSA-N 0.000 description 1
- POULHZVOKOAJMA-UHFFFAOYSA-N methyl undecanoic acid Natural products CCCCCCCCCCCC(O)=O POULHZVOKOAJMA-UHFFFAOYSA-N 0.000 description 1
- 230000007935 neutral effect Effects 0.000 description 1
- 125000001400 nonyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 239000003921 oil Substances 0.000 description 1
- 235000019198 oils Nutrition 0.000 description 1
- 239000012188 paraffin wax Substances 0.000 description 1
- 150000003254 radicals Chemical class 0.000 description 1
- 150000003839 salts Chemical class 0.000 description 1
- 150000003467 sulfuric acid derivatives Chemical class 0.000 description 1
- 239000003760 tallow Substances 0.000 description 1
- 150000003512 tertiary amines Chemical class 0.000 description 1
- 230000001988 toxicity Effects 0.000 description 1
- 231100000419 toxicity Toxicity 0.000 description 1
- 150000004670 unsaturated fatty acids Chemical class 0.000 description 1
- 235000021122 unsaturated fatty acids Nutrition 0.000 description 1
- 235000015112 vegetable and seed oil Nutrition 0.000 description 1
- 239000008158 vegetable oil Substances 0.000 description 1
- 239000004711 α-olefin Substances 0.000 description 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B08—CLEANING
- B08B—CLEANING IN GENERAL; PREVENTION OF FOULING IN GENERAL
- B08B3/00—Cleaning by methods involving the use or presence of liquid or steam
- B08B3/04—Cleaning involving contact with liquid
- B08B3/08—Cleaning involving contact with liquid the liquid having chemical or dissolving effect
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D9/00—Chemical paint or ink removers
- C09D9/005—Chemical paint or ink removers containing organic solvents
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/66—Non-ionic compounds
- C11D1/83—Mixtures of non-ionic with anionic compounds
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D7/00—Compositions of detergents based essentially on non-surface-active compounds
- C11D7/50—Solvents
- C11D7/5004—Organic solvents
- C11D7/5022—Organic solvents containing oxygen
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B08—CLEANING
- B08B—CLEANING IN GENERAL; PREVENTION OF FOULING IN GENERAL
- B08B2220/00—Type of materials or objects being removed
- B08B2220/02—Chewing gum
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/02—Anionic compounds
- C11D1/12—Sulfonic acids or sulfuric acid esters; Salts thereof
- C11D1/14—Sulfonic acids or sulfuric acid esters; Salts thereof derived from aliphatic hydrocarbons or mono-alcohols
- C11D1/146—Sulfuric acid esters
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/66—Non-ionic compounds
- C11D1/75—Amino oxides
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D7/00—Compositions of detergents based essentially on non-surface-active compounds
- C11D7/22—Organic compounds
- C11D7/24—Hydrocarbons
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D7/00—Compositions of detergents based essentially on non-surface-active compounds
- C11D7/22—Organic compounds
- C11D7/26—Organic compounds containing oxygen
- C11D7/266—Esters or carbonates
Definitions
- the present invention generally relates to a cleaning composition. More particularly, the invention relates to a novel cleaning formulation and process for removing chewing gum from hard surfaces.
- the cleaning composition is readily biodegradable, low in toxicity and volatility, neutral in pH, and is primarily derived from natural resources.
- the present invention is directed to a cleaning composition for removing chewing gum from hard surfaces, the composition containing:
- the present invention is also directed to a process for removing chewing gum from a hard surface involving contacting the chewing gum with the above- identified cleaning composition
- the present invention is directed to a cleaning composition which is highly effective at removing chewing gum from a hard surface.
- the cleaning composition is entirely naturally derived, biodegradable, and has a very low eco- tox profile.
- the cleaning composition is based on a combination of a C 1 - 4 alkyl ester of a C ⁇ -2 2 saturated or unsaturated carboxylic acid, acting as a primary solvent, a terpene component and, optionally, an oil-soluble surfactant.
- the primary solvent used employed by the present invention is a C 1 - 4 alkyl ester of a C 6 -2 2 saturated or unsaturated carboxylic acid.
- the use of an alkyl ester as a solvent in cleaning compositions is significantly more desirable than conventional solvents, such as hydrocarbon derivatives, for environmental reasons.
- a particularly preferred C 1 - 4 alkyl ester of a C ⁇ - 22 saturated or unsaturated carboxylic acid for use in the present invention is a methyl ester corresponding to formula I:
- RiCOOCHa (I) wherein R 1 is an alkyl radical having from about 6 to about 14 carbon atoms. It is derived by the esterification of a fatty acid with methanol. Preferred methyl esters are those derived from the esterification of unsaturated fatty acids having from about 8 to about 10 carbon atoms. Suitable fatty acids from which the fatty acid esters may be derived include, but are not limited to, coconut and other vegetable oils, tallow, etc.
- the C1- 4 alkyl ester of a C 6 - 22 saturated or unsaturated carboxylic acid will typically be present in the chewing gum remover composition in preferred amounts ranging from about 10 to about 90% by weight; from about 35 to about 80% by weight; from about 65 to about 75% by weight, based on the weight of the composition.
- terpene Any saturated or unsaturated terpene may be used in formulating the composition of the present invention, as well as terpene derivatives commonly referred to as terpenoids.
- Particularly preferred terpenes for use in the present invention are the monocyclic terpenes such as, for example, dipentene.
- the terpene component will typically be present in the chewing gum remover composition in preferred amounts ranging from about 10 to about 90% by weight; from about 15 to about 60% by weight; from about 20 to about 30% by weight, based on the weight of the composition.
- Suitable oil-soluble surfactants which may be employed in the present invention include, but are not limited to, oil-soluble salts of alkyl benzene sulfonates, alkyl sulfates, alkyl polyethoxy ether sulfates, paraffin sulfonates, alpha-olefin sulfonates and sulfosuccinates, alpha-sulfocarboxylates and their esters, alkyl glyceryl ether sulfonates, fatty acid monoglyceride sulfates and sulfonates, and alkyl phenol polyethoxyether sulfates.
- oil-soluble surfactants include non-ionic fatty alcohol alkoxylates and nonyl or octyl phenol alkoxylates with HLB values ranging from about 6 - 12.
- a particularly preferred oil-soluble surfactant for use in the present invention is sulfated castor oil, commonly known as Turkey Red Oil.
- the oil-soluble surfactant will typically be present in the chewing gum remover composition in preferred amounts ranging from about 0.1 to about 10% by weight; from about 1 to about 7% by weight; from about 3 to about 5% by weight, based on the weight of the composition.
- Suitable amine oxides which may be employed in the present invention include those which correspond to formula II:
- R 1 is an alkyl or alkenyl radical having from about 7 to about 18 carbon atoms
- R 2 and R 3 are individually alkyl or hydroxyalkyl radicals having from about 1 to about 4 carbon atoms.
- amine oxides which may be used in the present invention include, but are not limited to lauryl amine oxide, cocamine oxide, cocamidopropyl amine oxide, lauryl amido propyl amine oxide.
- a particularly preferred amine oxide is oleyl dimethyl amine oxide, commercially available under the tradename STANDAMOX® 01.
- tertiary amine oxides wherein the radical RCO represents a coconut acid or lauric acid radical, may also be used.
- RCO represents a coconut acid or lauric acid radical
- an amine oxide it will typically be present in the composition in preferred amounts ranging from about 0.1 to about 10% by weight; from about 0.3 to about 5% by weight; from about 0.5 to about 1% by weight, based on the weight of the composition.
- a process for removing chewing gum from a hard surface involving contacting the chewing gum with the above-disclosed composition.
- the present invention will be better understood by the examples which follow, all of which are intended for illustrative purposes only, and are not meant to unduly limit the scope of the invention in any way. Unless otherwise indicated, percentages are on a weight-by-weight basis.
- the above formulation can be applied onto chewing gum on sidewalks and after about 5 to 10 minutes of dwell time, the gum will be sufficiently loosened to enable it to be rinsed away with a stream of water from a pressure washer or garden hose.
Landscapes
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Organic Chemistry (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Wood Science & Technology (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- General Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Emergency Medicine (AREA)
- Materials Engineering (AREA)
- Detergent Compositions (AREA)
- Confectionery (AREA)
Abstract
A chewing gum remover composition containing: (a) a C1-4 alkyl ester of a C6-22 saturated or unsaturated carboxylic acid; (b) a terpene; and (c) optionally, an oil-soluble surfactant, and wherein (a) and (b) are present in the composition in a ratio by weight of from about 10:1 to about 1:10.
Description
METHYL ESTER-BASED CHEWING GUM REMOVER
BACKGROUND OF THE INVENTION:
The present invention generally relates to a cleaning composition. More particularly, the invention relates to a novel cleaning formulation and process for removing chewing gum from hard surfaces. The cleaning composition is readily biodegradable, low in toxicity and volatility, neutral in pH, and is primarily derived from natural resources.
BRIEF SUMMARY OF THE INVENTION:
The present invention is directed to a cleaning composition for removing chewing gum from hard surfaces, the composition containing:
(a) a C-ι-4 alkyl ester of a Cβ-22 saturated or unsaturated carboxylic acid; (b) a terpene; and
(c) optionally, an oil-soluble surfactant to facilitate water rinseability, wherein (a) and (b) are present in the composition at a ratio by weight of from about 10:1 to about 1 :10.
The present invention is also directed to a process for removing chewing gum from a hard surface involving contacting the chewing gum with the above- identified cleaning composition
BRIEF DESCRIPTION OF THE SEVERAL VIEWS OF THE DRAWING: Not applicable.
DETAILED DESCRIPTION OF THE INVENTION:
Other than in the operating examples, or where otherwise indicated, all numbers expressing quantities of ingredients or reaction conditions used herein are to be understood as being modified in all instances by the term "about".
The present invention is directed to a cleaning composition which is highly effective at removing chewing gum from a hard surface. The cleaning composition is entirely naturally derived, biodegradable, and has a very low eco- tox profile. The cleaning composition is based on a combination of a C1-4 alkyl
ester of a Cβ-22 saturated or unsaturated carboxylic acid, acting as a primary solvent, a terpene component and, optionally, an oil-soluble surfactant.
The primary solvent used employed by the present invention is a C1-4 alkyl ester of a C6-22 saturated or unsaturated carboxylic acid. The use of an alkyl ester as a solvent in cleaning compositions is significantly more desirable than conventional solvents, such as hydrocarbon derivatives, for environmental reasons.
A particularly preferred C1-4 alkyl ester of a Cβ-22 saturated or unsaturated carboxylic acid for use in the present invention is a methyl ester corresponding to formula I:
RiCOOCHa (I) wherein R1 is an alkyl radical having from about 6 to about 14 carbon atoms. It is derived by the esterification of a fatty acid with methanol. Preferred methyl esters are those derived from the esterification of unsaturated fatty acids having from about 8 to about 10 carbon atoms. Suitable fatty acids from which the fatty acid esters may be derived include, but are not limited to, coconut and other vegetable oils, tallow, etc.
The C1-4 alkyl ester of a C6-22 saturated or unsaturated carboxylic acid will typically be present in the chewing gum remover composition in preferred amounts ranging from about 10 to about 90% by weight; from about 35 to about 80% by weight; from about 65 to about 75% by weight, based on the weight of the composition.
Any saturated or unsaturated terpene may be used in formulating the composition of the present invention, as well as terpene derivatives commonly referred to as terpenoids. Particularly preferred terpenes for use in the present invention are the monocyclic terpenes such as, for example, dipentene.
The terpene component will typically be present in the chewing gum remover composition in preferred amounts ranging from about 10 to about 90% by weight; from about 15 to about 60% by weight; from about 20 to about 30% by weight, based on the weight of the composition.
Suitable oil-soluble surfactants which may be employed in the present invention include, but are not limited to, oil-soluble salts of alkyl benzene sulfonates, alkyl sulfates, alkyl polyethoxy ether sulfates, paraffin sulfonates,
alpha-olefin sulfonates and sulfosuccinates, alpha-sulfocarboxylates and their esters, alkyl glyceryl ether sulfonates, fatty acid monoglyceride sulfates and sulfonates, and alkyl phenol polyethoxyether sulfates.
Other suitable oil-soluble surfactants include non-ionic fatty alcohol alkoxylates and nonyl or octyl phenol alkoxylates with HLB values ranging from about 6 - 12.
A particularly preferred oil-soluble surfactant for use in the present invention is sulfated castor oil, commonly known as Turkey Red Oil.
The oil-soluble surfactant will typically be present in the chewing gum remover composition in preferred amounts ranging from about 0.1 to about 10% by weight; from about 1 to about 7% by weight; from about 3 to about 5% by weight, based on the weight of the composition.
It has also been found to be particularly advantageous to employ an amine oxide, in combination with an oil-soluble anionic surfactant, in order to further enhance the end-user's ability to rinse away the undesirable chewing gum from a hard surface using a stream of water.
Suitable amine oxides which may be employed in the present invention include those which correspond to formula II:
R1-N→O (II) R3
wherein R1 is an alkyl or alkenyl radical having from about 7 to about 18 carbon atoms, and R2 and R3 are individually alkyl or hydroxyalkyl radicals having from about 1 to about 4 carbon atoms. Examples of amine oxides which may be used in the present invention include, but are not limited to lauryl amine oxide, cocamine oxide, cocamidopropyl amine oxide, lauryl amido propyl amine oxide. A particularly preferred amine oxide is oleyl dimethyl amine oxide, commercially available under the tradename STANDAMOX® 01.
It should also be noted that tertiary amine oxides, wherein the radical RCO represents a coconut acid or lauric acid radical, may also be used.
In the event that an amine oxide is employed, it will typically be present in the composition in preferred amounts ranging from about 0.1 to about 10% by weight; from about 0.3 to about 5% by weight; from about 0.5 to about 1% by weight, based on the weight of the composition.
According to another embodiment of the present invention, there is provided a process for removing chewing gum from a hard surface involving contacting the chewing gum with the above-disclosed composition. The present invention will be better understood by the examples which follow, all of which are intended for illustrative purposes only, and are not meant to unduly limit the scope of the invention in any way. Unless otherwise indicated, percentages are on a weight-by-weight basis.
EXAMPLES A chewing gum remover composition was prepared in accordance with the present invention. Its formulation is found in Table 1 , below.
Table 1
The above formulation can be applied onto chewing gum on sidewalks and after about 5 to 10 minutes of dwell time, the gum will be sufficiently loosened to enable it to be rinsed away with a stream of water from a pressure washer or garden hose.
Claims
1. A chewing gum remover composition comprising:
(a) a C alkyl ester of a C6-22 saturated or unsaturated carboxylic acid;
(b) a terpene; and
(c) optionally, an oil-soluble surfactant, and wherein (a) and (b) are present in the composition in a ratio by weight of from about 10:1 to about 1 :10.
2 The composition of claim 1 wherein (a) is a methyl ester corresponding to formula I:
RiCOOCHa (I) wherein R1 is an alkyl radical having from about 6 to about 14 carbon atoms.
3. The composition of claim 1 wherein (a) is present in the composition in an amount of from about 10 to about 90% by weight, based on the weight of the composition.
4. The composition of claim 1 wherein (a) is present in the composition in an amount of from about 35 to about 80% by weight, based on the weight of the composition.
5. The composition of claim 1 wherein (a) is present in the composition in an amount of from about 65 to about 75% by weight, based on the weight of the composition.
6. The composition of claim 1 wherein (b) is a dipentente.
7. The composition of claim 1 wherein (b) is present in the composition in an amount of from about 10 to about 90% by weight, based on the weight of the composition.
8. The composition of claim 1 wherein (b) is present in the composition in an amount of from about 15 to about 60% by weight, based on the weight of the composition.
9. The composition of claim 1 wherein (b) is present in the composition in an amount of from about 20 to about 30% by weight, based on the weight of the composition.
10. The composition of claim 1 wherein the oil-soluble surfactant is a sulfated castor oil.
11. The composition of claim 1 wherein the oil-soluble surfactant is present in the composition in an amount of from about 0.1 to 10% by weight, based on the weight of the composition.
12. The composition of claim 1 wherein the oil-soluble surfactant is present in the composition in an amount of from about 1 to 7% by weight, based on the weight of the composition.
13. The composition of claim 1 wherein the oil-soluble surfactant is present in the composition in an amount of from about 3 to 5% by weight, based on the weight of the composition.
14. The composition of claim 1 further comprising an amine oxide.
15. The composition of claim 14 wherein the amine oxide is oleyl dimethyl amine oxide.
16. The composition of claim 14 wherein the amine oxide is present in the composition in an amount of from about 0.1 to about 10% by weight, based on the weight of the composition.
17. The composition of claim 14 wherein the amine oxide is present in the composition in an amount of from about 0.3 to about 5% by weight, based on the weight of the composition.
18. The composition of claim 14 wherein the amine oxide is present in the composition in an amount of from about 0.5 to about 1% by weight, based on the weight of the composition.
19. A chewing gum remover composition comprising:
(a) from about 65 to about 75% by weight of a CQ-U methyl ester;
(b) from about 20 to about 30% by weight of a dipentene;
(c) from about 3 to about 5% by weight of sulfated castor oil; and
(d) from about 0.5 to about 1% by weight of oleyl dimethyl amine oxide, all weights being based on the weight of the composition.
20. A process for removing chewing gum from a hard surface comprising contacting the chewing gum with a cleaning composition containing:
(a) a Ci-4 alkyl ester of a Cβ-22 saturated or unsaturated carboxylic acid;
(b) a terpene; and
(c) optionally, an oil-soluble surfactant, and wherein (a) and (b) are present in the composition in a ratio by weight of from about 10:1 to about 1 :10.
21. The process of claim 20 wherein (a) is a methyl ester corresponding to formula I:
RiCOOCHa (I) wherein R-i is an alkyl radical having from about 6 to about 14 carbon atoms.
22. The process of claim 20 wherein (a) is present in the composition in an amount of from about 10 to about 90% by weight, based on the weight of the composition.
23. The process of claim 20 wherein (a) is present in the composition in an amount of from about 35 to about 80% by weight, based on the weight of the composition.
24. The process of claim 20 wherein (a) is present in the composition in an amount of from about 65 to about 75% by weight, based on the weight of the composition.
25. The process of claim 20 wherein (b) is a dipentente.
26. The process of claim 20 wherein (b) is present in the composition in an amount of from about 10 to about 90% by weight, based on the weight of the composition.
27. The process of claim 20 wherein (b) is present in the composition in an amount of from about 15 to about 60% by weight, based on the weight of the composition.
28. The process of claim 20 wherein (b) is present in the composition in an amount of from about 20 to about 30% by weight, based on the weight of the composition.
29. The process of claim 20 wherein the oil-soluble surfactant is a sulfated castor oil.
30. The process of claim 20 wherein the oil-soluble surfactant is present in the composition in an amount of from about 0.1 to 10% by weight, based on the weight of the composition.
31. The process of claim 20 wherein the oil-soluble surfactant is present in the composition in an amount of from about 1 to 7% by weight, based on the weight of the composition.
32. The process of claim 20 wherein the oil-soluble surfactant is present in the composition in an amount of from about 3 to 5% by weight, based on the weight of the composition.
33. The process of claim 20 further comprising an amine oxide.
34. The process of claim 33 wherein the amine oxide is oleyl dimethyl amine oxide.
35. The process of claim 33 wherein the amine oxide is present in the composition in an amount of from about 0.1 to about 10% by weight, based on the weight of the composition.
36. The process of claim 33 wherein the amine oxide is present in the composition in an amount of from about 0.3 to about 5% by weight, based on the weight of the composition.
37. The process of claim 33 wherein the amine oxide is present in the composition in an amount of from about 0.5 to about 1% by weight, based on the weight of the composition.
Applications Claiming Priority (4)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US29781901P | 2001-06-13 | 2001-06-13 | |
| US60/297,819 | 2001-06-13 | ||
| US10/162,352 US6613158B2 (en) | 2001-06-13 | 2002-06-04 | Methyl ester-based chewing gum remover |
| US10/162,352 | 2002-06-04 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| WO2002100992A1 true WO2002100992A1 (en) | 2002-12-19 |
Family
ID=26858682
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| PCT/US2002/018309 WO2002100992A1 (en) | 2001-06-13 | 2002-06-11 | Methyl ester-based chewing gum remover |
Country Status (2)
| Country | Link |
|---|---|
| US (1) | US6613158B2 (en) |
| WO (1) | WO2002100992A1 (en) |
Families Citing this family (12)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US7192912B2 (en) * | 2004-03-18 | 2007-03-20 | Johnsondiversey, Inc. | No VOC solvent blend |
| US20070042078A1 (en) * | 2005-08-22 | 2007-02-22 | Cadbury Adams Usa Llc | Biodegradable chewing gum |
| US8282971B2 (en) * | 2005-08-22 | 2012-10-09 | Kraft Foods Global Brands Llc | Degradable chewing gum |
| US8263143B2 (en) | 2005-08-22 | 2012-09-11 | Kraft Foods Global Brands Llc | Degradable chewing gum |
| US8268371B2 (en) * | 2005-08-22 | 2012-09-18 | Kraft Foods Global Brands Llc | Degradable chewing gum |
| US20070042079A1 (en) * | 2005-08-22 | 2007-02-22 | Cadbury Adams Usa Llc | Environmentally-friendly chewing gum having reduced stickiness |
| US8287928B2 (en) | 2005-08-22 | 2012-10-16 | Kraft Foods Global Brands Llc | Degradable chewing gum |
| FR2939805B1 (en) * | 2008-12-15 | 2011-01-14 | Scr 3L | BIODEGRADABLE ELIMINATING PRODUCT OF CHEWING GUMES, ADHESIVES AND ELASTOMERS |
| US8617317B1 (en) | 2012-07-31 | 2013-12-31 | Ecolab Usa Inc. | All-purpose cleaners with natural, non-volatile solvent |
| DE102014006905A1 (en) * | 2014-05-09 | 2015-11-12 | Mathias Gressenbuch | Cleaning method for removing polymer-containing contaminants |
| US20160257911A1 (en) * | 2015-03-06 | 2016-09-08 | Flotek Chemistry, Llc | Compositions and methods for cleaning a surface and other applications |
| EP3487975A1 (en) | 2016-07-19 | 2019-05-29 | Ecolab USA Inc. | Methods and cleaning solutions for removing chewing gum and other sticky food substances |
Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4306989A (en) * | 1979-10-09 | 1981-12-22 | Lift-Off, Inc. | Composition for releasing adhesives from a surface |
| US4533487A (en) * | 1983-08-15 | 1985-08-06 | Pitre-Jones | Process for producing blended d-Limonene and uses of the blended product |
| US5080821A (en) * | 1988-12-23 | 1992-01-14 | Philippe Lutringer | Hydrocarbon solvent composition |
| WO1996000622A1 (en) * | 1994-06-29 | 1996-01-11 | Zeno Manufacturing Company | Method of removing chewing gum from surfaces |
| GB2336596A (en) * | 1998-04-22 | 1999-10-27 | Geoffrey Wheeler | Chewing gum remover |
Family Cites Families (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5720825A (en) * | 1996-01-29 | 1998-02-24 | Chemtek, Incorporated | Method of cleaning tar and asphalt off of paving or other equipment using combinations of esters and terpenes |
-
2002
- 2002-06-04 US US10/162,352 patent/US6613158B2/en not_active Expired - Lifetime
- 2002-06-11 WO PCT/US2002/018309 patent/WO2002100992A1/en not_active Application Discontinuation
Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4306989A (en) * | 1979-10-09 | 1981-12-22 | Lift-Off, Inc. | Composition for releasing adhesives from a surface |
| US4533487A (en) * | 1983-08-15 | 1985-08-06 | Pitre-Jones | Process for producing blended d-Limonene and uses of the blended product |
| US5080821A (en) * | 1988-12-23 | 1992-01-14 | Philippe Lutringer | Hydrocarbon solvent composition |
| WO1996000622A1 (en) * | 1994-06-29 | 1996-01-11 | Zeno Manufacturing Company | Method of removing chewing gum from surfaces |
| GB2336596A (en) * | 1998-04-22 | 1999-10-27 | Geoffrey Wheeler | Chewing gum remover |
Also Published As
| Publication number | Publication date |
|---|---|
| US20030008789A1 (en) | 2003-01-09 |
| US6613158B2 (en) | 2003-09-02 |
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