WO2002089151A1 - Polymeric foam gaskets and seals - Google Patents
Polymeric foam gaskets and seals Download PDFInfo
- Publication number
- WO2002089151A1 WO2002089151A1 PCT/CA2002/000603 CA0200603W WO02089151A1 WO 2002089151 A1 WO2002089151 A1 WO 2002089151A1 CA 0200603 W CA0200603 W CA 0200603W WO 02089151 A1 WO02089151 A1 WO 02089151A1
- Authority
- WO
- WIPO (PCT)
- Prior art keywords
- foam
- compression
- phr
- polyurethane
- conductive filler
- Prior art date
Links
Classifications
-
- H—ELECTRICITY
- H05—ELECTRIC TECHNIQUES NOT OTHERWISE PROVIDED FOR
- H05K—PRINTED CIRCUITS; CASINGS OR CONSTRUCTIONAL DETAILS OF ELECTRIC APPARATUS; MANUFACTURE OF ASSEMBLAGES OF ELECTRICAL COMPONENTS
- H05K9/00—Screening of apparatus or components against electric or magnetic fields
- H05K9/0007—Casings
- H05K9/0015—Gaskets or seals
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
- C08G18/40—High-molecular-weight compounds
- C08G18/48—Polyethers
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- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F16—ENGINEERING ELEMENTS AND UNITS; GENERAL MEASURES FOR PRODUCING AND MAINTAINING EFFECTIVE FUNCTIONING OF MACHINES OR INSTALLATIONS; THERMAL INSULATION IN GENERAL
- F16J—PISTONS; CYLINDERS; SEALINGS
- F16J15/00—Sealings
- F16J15/02—Sealings between relatively-stationary surfaces
- F16J15/021—Sealings between relatively-stationary surfaces with elastic packing
- F16J15/022—Sealings between relatively-stationary surfaces with elastic packing characterised by structure or material
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F16—ENGINEERING ELEMENTS AND UNITS; GENERAL MEASURES FOR PRODUCING AND MAINTAINING EFFECTIVE FUNCTIONING OF MACHINES OR INSTALLATIONS; THERMAL INSULATION IN GENERAL
- F16J—PISTONS; CYLINDERS; SEALINGS
- F16J15/00—Sealings
- F16J15/02—Sealings between relatively-stationary surfaces
- F16J15/06—Sealings between relatively-stationary surfaces with solid packing compressed between sealing surfaces
- F16J15/064—Sealings between relatively-stationary surfaces with solid packing compressed between sealing surfaces the packing combining the sealing function with other functions
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01B—CABLES; CONDUCTORS; INSULATORS; SELECTION OF MATERIALS FOR THEIR CONDUCTIVE, INSULATING OR DIELECTRIC PROPERTIES
- H01B1/00—Conductors or conductive bodies characterised by the conductive materials; Selection of materials as conductors
- H01B1/20—Conductive material dispersed in non-conductive organic material
- H01B1/22—Conductive material dispersed in non-conductive organic material the conductive material comprising metals or alloys
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G2110/00—Foam properties
- C08G2110/0041—Foam properties having specified density
- C08G2110/005—< 50kg/m3
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G2110/00—Foam properties
- C08G2110/0075—Foam properties prepared with an isocyanate index of 60 or lower
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G2190/00—Compositions for sealing or packing joints
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10S277/00—Seal for a joint or juncture
- Y10S277/92—Seal including electromagnetic shielding feature
Definitions
- This invention relates to electrically conductive, flexible, low-density , 0 polyurethane foams useful for conductive gaskets and seals.
- a number of products have been developed to address the need for 5 conductive gaskets.
- One method uses a two-layer approach.
- the outer layer contains a conductive metal.
- the inner core or layer is intended to provide the desirable properties that an effective gasket should have.
- Such 0 a product is described in co-pending U.S. patent application 09/421,559, which is hereby incorporated by reference in its entirety.
- Another product is a high frequency EMI/RFI shielding gasket made by wrapping a strip of knit mesh material or wire mesh around the exterior of a resilient core.
- Such a mesh-covered core is described in US Patent 4,652,695.
- the core can be made from any highly compressible material but is usually a flexible, non-conductive polyurethane or polyethylene foam.
- the wrap usually contains large quantities of nickel or silver. This makes the wrap very expensive.
- these gaskets cannot be formed-in-place but must be prefabricated. Installation of these gaskets is very labor intensive causing the installation costs and therefore the final gasket costs to be high.
- conductive gaskets Another method of manufacturing conductive gaskets is to encapsulate conductive fillers inside a plastic matrix.
- Flexible elastomers such as silicone and neoprene, are commonly used. US Patent 4,011,360 is an example of many such patents in this area. Flexible elastomers are particularly desirable for gasket materials because of their good performance characteristics and ease of manufacture. Such elastomers have low water absorption and good resistance to cutting.
- the cost of these gaskets is high, particularly when a conductive metal such as silver is used.
- U.S. Patent 4,378,322 describes impregnating a prefabricated foam with conductive materials.
- U.S. Patent 4,931,479 describes producing a high density, high hardness, conductive polyurethane foam for gap filling applications.
- neither of these approaches is suitable for (foam- in-place) gasketing applications.
- the invention is directed to electrically conductive flexible polyurethane foams that are suitable for use as gaskets and seals.
- the gaskets and seals can be used between two conductive surfaces to provide EMI/RFI shielding.
- the gaskets and seals can be foamed-in-place, prefabricated, or molded, at both room temperature and elevated temperatures.
- the foams are soft, flexible, and have low compression deflection. Moreover, the foams have good compression recovery, are cut resistant, and have low water absorption.
- the invention is directed to an electrically conductive flexible polyurethane foam comprising a polyurethane and at least one conductive filler dispersed therein in an amount effective to provide EMI/RFI shielding, wherein the polyurethane comprises an isocyanate component to active hydrogen component in a ratio of at most about 0.20:1, and the foam has compression deflection value at 50% compression of at most about 25 psi.
- the invention is further directed to an electrically conductive flexible polyurethane foam comprising a polyurethane and at least one conductive filler dispersed therein in an amount effective to provide EMI/RFI 10,00 shielding, wherein the polyurethane comprises an isocyanate component to active hydrogen component in a ratio of at most about 0.20:1, and the foam density is at most about 0.95 g/cm 3 .
- the invention is further directed to an electrically conductive flexible polyurethane foam comprising a polyurethane and at least one conductive filler dispersed therein in an amount effective to provide EMI/RFI shielding, wherein the polyurethane comprises an isocyanate component to
- the foam has a noise shielding effectiveness of the foam at a frequency of about 20 to about 1000 MHz of at least about 10 dB.
- the invention is further directed to a gasket or seal comprising an electrically conductive flexible polyurethane foam comprising a polyurethane and at least one conductive filler dispersed therein in an
- the polyurethane comprises an isocyanate component to active hydrogen component in a ratio of at most about 0.20:1, wherein the foam has a density of at most
- the foam has a noise shielding effectiveness at about 20 to about 1000 MHz of at least about 10 dB and a compression deflection value at 50% compression of less than about 25 psi, and wherein the conductive filler concentration is about 140 phr to about 900 phr.
- the invention is directed to flexible, conductive polyurethane foam gaskets 5 and seals that are suitable for EMI RFI shielding.
- the foams are easy to apply, whether prefabricated or foamed in place, and cured at room temperature and/or at elevated temperatures.
- the foams are soft, flexible, and have low compression deflection values. They are resilient, have a low compression set, have low water absorption, and have good cut resistance. They also retain their conductivity after many compression-relaxation cycles.
- polyurethane foams The chemistry of polyurethane foams is well known by those skilled in the art.
- excellent non-conductive flexible foam gaskets have been made from polyurethane resins. They are primarily thermosetting systems.
- the foams are mechanically or chemically blown or a combination of both. They are prefabricated or formed-in-place.
- Flexible foams offer several advantages over non-foamed elastomers in gasket and seal applications.
- Foam gaskets are much softer and more flexible than elastomeric gaskets while maintaining excellent physical properties. Softer materials make better gaskets and seals because they form a better seal against the mating surface.
- Non-conductive elastomers have been produced as soft as around Shore A 20, but elastomers below this hardness have very poor physical properties and are not suitable for most applications.
- Much softer non-conductive flexible polyurethane foams are possible having hardnesses lower than Shore OO 0. Even at these low hardness values they have many desirable physical properties.
- foams may be produced having much lower compression deflection values and better compression recovery than elastomers.
- Foam gaskets having excellent water impermeability are also possible.
- Foams having very low density may be produced, improving compression recovery and decreasing the hardness and compression deflection substantially.
- a low-density foam gasket has less weight per volume than a non-foamed gasket resulting in lower cost to produce. For example, decreasing the density of the foam by 50% may decrease the gasket cost by 50%. It is preferable to lower the density as much as possible without sacrificing other desirable properties.
- Conductive foams can be produced that have the same advantages as non- conductive foams.
- low-density conductive foams can be made at very high loading of conductive fillers. Up to 90% by weight of the total formulation may be conductive fillers.
- the conductive foams may have foam densities as low as 0.1 g cm and may have hardnesses as low as Shore OO 10, e.g. Shore OO 10 to Shore A 5. Low density, conductive foams do not require a higher percentage of conductive fillers in the composition than high-density conductive foams and elastomers.
- An electrically conductive flexible polyurethane foam of the invention is prepared from a composition comprising about 10 wt % to about 70 wt % polyurethane polymer (binder) based on total weight of the composition, preferably about 15 wt% to about 40 wt% polyurethane polymer.
- the amount of polyurethane used depends on the desired final properties of the composition. Those skilled in the art of polyurethane foam formulation know how to combine the ingredients to maximize properties such as compression set, compression deflection, density, tensile strength, elongation, cut resistance and water resistance to obtain the desired properties.
- the mixing ratio of isocyanate component to active hydrogen component is at most about 0.2:1, preferably at most about 0.15:1, more preferably at most about 0.1 :1.
- the combined viscosity of the isocyanate, the hydrogen donor, and any other liquids present should be less than 100,000 cps, preferably less than 50,000 cps.
- Lower viscosity polymers produce lower density foams thus the liquid components preferably have low viscosity.
- Low density foams are difficult to produce with high viscosity polymers. Heat can be applied to reduce viscosity and to decrease foam density. Viscosity reduction additives can also be used to decrease viscosity.
- conductive, low density, two-component polyurethane foams it is preferable to use monomeric or polymeric di-isocyanates instead of using an isocyanate-terminated polyol. Isocyanate-terminated polyols have higher viscosities than monomeric or polymeric isocyanates they are made from.
- the composition further comprises at least one conductive filler in an amount of about 30 wt% to about 90 wt%, preferably about 40 wt% to about 80 wt%, based on the total weight of the total weight of the composition. At least one conductive filler is dispersed throughout the polymer in an amount effective to achieve EMI/RFI shielding.
- the conductive filler has a concentration of about 140 to about 900 parts per 100 parts of resin (polyol and isocyanate combined) ("phr"), preferably about 140 to about 700 phr, more preferably about 140 phr to about 400 phr.
- Conductive fillers may be selected from noble metals, base metals, noble metal coated non-noble metals, noble metal coated glass, noble metal coated plastics, noble metal coated ceramics & carbon blacks. Suitable conductive fillers include, but are not limited to, silver, nickel, aluminum, copper, steel & coatings of these on metallic & non-metallic substrates.
- the conductive filler may be of any suitable form or shape such as particles, spheres, powders, flakes, etc. If conductive particles are used, the size of the particles is typically between about 1 micron and about 80 microns, preferably between about 10 microns and about 30 microns, most preferably about 20 microns.
- conductive fillers other than particles. Conductive foams tend to lose their conductivity on repeated flexing or compression- relaxation cycles. Thus, in accordance with a preferred embodiment, conductive fillers with high aspect ratios are used which allow flexing of the foam without loss of conductivity. Examples of such high aspect ratio fillers are flakes, fibers, filaments, needles, slivers and flexible, hollow microspheres. High aspect ratio fillers provide better particle-to-particle contact at lower load levels. This provides better conductivity at lower loading levels than is required when using fillers with low aspect ratios.
- high aspect ratio fillers permits a higher resin (binder) concentration. Therefore, higher physical properties such as tensile strength, elongation, and compression recovery are obtainable with these fillers.
- the diameter of high aspect ratio fillers should be between about 0.1 micron and about 100 microns, preferably between about 15 and about 30 microns.
- the aspect ratio (L/D) is preferably between about 10/1 and about 3000/1, more preferably between about 20/1 and about 100/1.
- Lower density conductive fillers produce lower density foams.
- Higher density fillers prevent the foam from rising, increasing the density of the foam.
- gaskets are usually small and less than about 3 ⁇ " in diameter and about Vz" high, and the reaction does not generate much heat. Therefore low-density fillers make it easier for the foam to rise higher, making the density of the foam lower.
- the introduction of external heat can also be used to decrease the foam density.
- Softer fillers are preferable over harder fillers. Softer fillers produce softer foams with lower compression deflection values. Softer fillers cause less stress on the polyurethane matrix bonding it into the foam. Softer fillers help the foam withstand repeated compression-relaxation cycles that the gasket will be exposed to. Besides cost, it is advantageous to use softer, nonconductive fillers and coat them with a thin layer of a metallic, conductive, filler. The resulting foams have better adhesion to the substrate and better flexibility. Moreover, fillers that are soft and non-abrasive do not abrade the contact parts of the dispensing equipment as much as harder fillers.
- the fillers are soft and have a Mohs hardness of about 5 or less. Mohs is a standard test used to determine the hardness of solid particles. On this scale, diamonds (being the hardest particle) have a hardness of 15.
- Talc is the softest and is given a hardness of 1. All other particles are in between 1 and 15.
- the conductive foams of the invention have densities of at most about 3
- Such foams provide an expansion rate of about 3 to about 30 times the volume of the 25 initial components.
- the low density, conductive polyurethane foams of the invention produce gaskets that provide at least adequate electromagnetic shielding.
- the foams 0 are conductive, have a volume resistivity of about 0.0017 ohm.cm to about
- ⁇ resulting reduction in noise level i.e. a noise shielding effectiveness, of at least about 10 db, preferably at least about 30 db, more preferably at least about 50 db, in the frequency range of about 20 to about 1000 MHz, may be achieved.
- the low density, conductive polyurethane foams of the invention produce gaskets that have compression deflection values, measured according to ASTM D3574C, of at most about 25 psi when measured at 50%
- compression set generally from about 1 psi to about 25 psi, preferably at most about 15 psi, more preferably at most about 5 psi.
- compression set measured as per ASTM D 1056, range from about 0% to about 30%, preferably from about 0% to about 10%. 5
- Hardness measured according to ASTM D2240, is preferably, in the range of from about Shore OO 0 to about Shore A 30.
- the Shore A hardness measures the hardness of the thin skin on top of the foam. Compression deflection measures the force needed to compress the entire foam specimen a certain percentage of its
- compression deflection measures the strength of the polyurethane elastomer that makes up the walls of the foam and how much force is required to collapse the cell walls.
- Compression deflection and Shore A hardness are not dependent on each other. For example, two 0 foams with the same Shore A hardness can have very different compression deflection values.
- Water resistance can be measured by, for example, weighing a gasket, submersing the gasket under water for a 30 period of time at a specific temperature, removing the gasket and reweighing. The water absorption is then measured as a percent weight of the gasket. If the initial gasket weight was 100 grams and the water absorbed by the gasket was 1 gram, then the water absorption would be
- the mating surface to the gasket in an electrical enclosure is usually a thin strip of metal or plastic.
- gaskets and seals should have high cut
- Cut resistance can be measured by, for example, compressing the center of the gasket 50% length wise with a strip of metal or plastic.
- the diameter of the metal strip may only be 10% of the diameter of the
- Conductive polyurethane foams are highly filled systems. They only contain a small amount of polymer to hold the fillers in place and provide the necessary physical and chemical properties. It is important that the foams retain these properties under actual usage conditions.
- the foam cannot develop hair-line cracks after repeated compression cycles. If hair-line cracks do develop, the gasket will lose its electrical conductivity and its ability to provide adequate shielding.
- One means of determining the retention of conductivity is to measure electrical conductivity after repeated "compression set" cycles. Depending on the intended application of the gasket, these tests can be performed at ambient or elevated temperatures. The number of cycles will also vary.
- a conductive polyurethane foam was prepared from the following components (measured in percent by weight):
- Chem-Cast 901 Polyol is a polyether polyol with a viscosity of 100 cps.
- Isocyanate 608 is a polymeric diphenylmethane diisocyanate with a viscosity of 50 cps.
- the foam contained 200 parts of conductive fillers per 100 parts of polyurethane resin or 66.7% of the total formulation.
- the resultant viscosity was 40,000 cps.
- the polyol and isocyanate components were placed into a meter-mix-dispenser with the dispensing nozzle attached to a robot arm.
- the foam gasket was dispensed on a flat surface in the shape of a gasket l ⁇ " wide and l ⁇ " high.
- the foam had a density of 0.5 g/cm 3 .
- Compression deflection force at 50 % compression was 2.9 psi.
- Hardness was Shore OO 40.
- Compression set was 20 % at 50 %" compression.
- Water absorption was less than 1%.
- the attenuation of the electromagnetic radiation of differing frequencies was measured. The noise reduction was between 60 dB and 80 dB between frequencies of 1 & 900 MHz. Volume resistivity was 0.03 ohms.cm. Surface resistivity was 0.5 ohms.cm 2 .
- a conductive polyurethane foam was prepared from the following components (measured in percent by weight):
- the resulting foam was conductive with a surface resistivity of 0.2 ohms/cm 2 .
- a conductive polyurethane foam was prepared from the following components (measured in percent by weight):
- the resulting foam was not conductive.
- a conductive polyurethane foam was prepared from the following components (measured in percent by weight):
- Isocyanate 2005 is an isocyanate prepolymer with a viscosity of 2000 cps (40 times thicker than Isocyanate 608).
- the density of the conductive foam was 1.1 g/cm 3 .
- the foam density was more than two times higher with the higher viscosity Isocyanate 2005 than the lower viscosity Isocyanate 608.
- A, B, C, and D are all conductive polyurethane foams of the same formulation. Hardness and compression deflection decrease as the foam density decreases.
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- Engineering & Computer Science (AREA)
- General Engineering & Computer Science (AREA)
- Chemical & Material Sciences (AREA)
- Mechanical Engineering (AREA)
- Organic Chemistry (AREA)
- Dispersion Chemistry (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Health & Medical Sciences (AREA)
- Microelectronics & Electronic Packaging (AREA)
- Physics & Mathematics (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Spectroscopy & Molecular Physics (AREA)
- Shielding Devices Or Components To Electric Or Magnetic Fields (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Manufacture Of Porous Articles, And Recovery And Treatment Of Waste Products (AREA)
- Sealing Material Composition (AREA)
- Conductive Materials (AREA)
- Polyurethanes Or Polyureas (AREA)
Abstract
Description
Claims
Priority Applications (4)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
EP02719592A EP1382045B1 (en) | 2001-04-26 | 2002-04-25 | Polymeric foam gaskets and seals |
CA2444527A CA2444527C (en) | 2001-04-26 | 2002-04-25 | Polymeric foam gaskets and seals |
JP2002586360A JP4293793B2 (en) | 2001-04-26 | 2002-04-25 | Polymer foam gaskets and seals |
DE60215324T DE60215324T2 (en) | 2001-04-26 | 2002-04-25 | DAMAGED POLYMER SEAL AND SEALING |
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US09/842,261 | 2001-04-26 | ||
US09/842,261 US6646199B2 (en) | 1999-10-20 | 2001-04-26 | Polymeric foam gaskets and seals |
Publications (1)
Publication Number | Publication Date |
---|---|
WO2002089151A1 true WO2002089151A1 (en) | 2002-11-07 |
Family
ID=25286887
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
PCT/CA2002/000603 WO2002089151A1 (en) | 2001-04-26 | 2002-04-25 | Polymeric foam gaskets and seals |
Country Status (7)
Country | Link |
---|---|
US (1) | US6646199B2 (en) |
EP (1) | EP1382045B1 (en) |
JP (1) | JP4293793B2 (en) |
AT (1) | ATE342570T1 (en) |
CA (1) | CA2444527C (en) |
DE (1) | DE60215324T2 (en) |
WO (1) | WO2002089151A1 (en) |
Cited By (4)
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EP1548337A1 (en) * | 2003-12-24 | 2005-06-29 | Airbus UK Limited | Method of sealing a joint |
US7708281B2 (en) | 2003-12-23 | 2010-05-04 | Airbus Uk Limited | Method of sealing a joint |
US7900412B2 (en) | 2003-12-23 | 2011-03-08 | Airbus Uk Limited | Sealing material |
CN109880344A (en) * | 2019-01-30 | 2019-06-14 | 中北大学 | A kind of preparation method of the high shielding aqueous polyurethane electromagnetic shielding composite foam of low reflection |
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US7039361B1 (en) * | 2002-02-01 | 2006-05-02 | Ciena Corporation | System and method for reducing electromagnetic interference |
US6964809B2 (en) * | 2002-02-15 | 2005-11-15 | Pedro M. Buarque de Macedo | Large high density foam glass tile |
US7060348B2 (en) * | 2002-03-08 | 2006-06-13 | Laird Technologies, Inc. | Flame retardant, electrically conductive shielding materials and methods of making the same |
US7311965B2 (en) * | 2003-07-22 | 2007-12-25 | Pedro M. Buarque de Macedo | Strong, high density foam glass tile having a small pore size |
US8453400B2 (en) * | 2003-07-22 | 2013-06-04 | Pedro M. Buarque de Macedo | Prestressed, strong foam glass tiles |
US8545974B2 (en) * | 2005-02-09 | 2013-10-01 | Laird Technologies, Inc. | Flame retardant EMI shields |
US20100258344A1 (en) * | 2005-02-09 | 2010-10-14 | Laird Technologies, Inc. | Flame retardant emi shields |
US7695560B1 (en) | 2005-12-01 | 2010-04-13 | Buarque De Macedo Pedro M | Strong, lower density composite concrete building material with foam glass aggregate |
US20080073622A1 (en) * | 2006-09-22 | 2008-03-27 | Inolex Investment Corporation | Conductive polyurethane foam and methods for making same |
US20080107883A1 (en) * | 2006-11-08 | 2008-05-08 | L&L Products, Inc. | Coated sealer and method of use |
US20080157915A1 (en) * | 2007-01-03 | 2008-07-03 | Ethan Lin | Flame retardant, electrically-conductive pressure sensitive adhesive materials and methods of making the same |
GB0720705D0 (en) * | 2007-10-23 | 2007-12-05 | Airbus Uk Ltd | Fastener joint with sealing gasket |
JP5701508B2 (en) * | 2009-03-04 | 2015-04-15 | 日東電工株式会社 | Conductive resin foam |
JP6006350B2 (en) * | 2009-03-04 | 2016-10-12 | 日東電工株式会社 | Conductive resin foam |
KR101048083B1 (en) * | 2010-10-14 | 2011-07-11 | 주식회사 이노칩테크놀로지 | Emi shielding gasket |
CN202721947U (en) * | 2011-11-03 | 2013-02-06 | 卢子鬯 | Halogen-free flame-retardant electromagnetic interference protection gasket for electronic instrument |
WO2014139126A1 (en) | 2013-03-14 | 2014-09-18 | Laird Technologies, Inc. | Flame-retardant electrically-conductive adhesive material and method of making the same |
CN104837327A (en) * | 2015-05-21 | 2015-08-12 | 小米科技有限责任公司 | Circuit protection structure and electronic device |
US11512229B2 (en) | 2018-12-27 | 2022-11-29 | Saint-Gobain Performance Plastics Corporation | Polyurethane foam and methods of forming the same |
IL296366A (en) * | 2020-03-18 | 2022-11-01 | Boehringer Ingelheim Microparts Gmbh | Method for assembling dispensing devices, and dispensing device |
CN113637359B (en) * | 2020-05-11 | 2023-10-17 | 臻鼎科技股份有限公司 | Conductive ink and conductive element with tensile properties |
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-
2002
- 2002-04-25 DE DE60215324T patent/DE60215324T2/en not_active Expired - Lifetime
- 2002-04-25 CA CA2444527A patent/CA2444527C/en not_active Expired - Lifetime
- 2002-04-25 AT AT02719592T patent/ATE342570T1/en not_active IP Right Cessation
- 2002-04-25 EP EP02719592A patent/EP1382045B1/en not_active Expired - Lifetime
- 2002-04-25 WO PCT/CA2002/000603 patent/WO2002089151A1/en active IP Right Grant
- 2002-04-25 JP JP2002586360A patent/JP4293793B2/en not_active Expired - Fee Related
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Cited By (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US7708281B2 (en) | 2003-12-23 | 2010-05-04 | Airbus Uk Limited | Method of sealing a joint |
US7900412B2 (en) | 2003-12-23 | 2011-03-08 | Airbus Uk Limited | Sealing material |
EP1548337A1 (en) * | 2003-12-24 | 2005-06-29 | Airbus UK Limited | Method of sealing a joint |
CN109880344A (en) * | 2019-01-30 | 2019-06-14 | 中北大学 | A kind of preparation method of the high shielding aqueous polyurethane electromagnetic shielding composite foam of low reflection |
CN109880344B (en) * | 2019-01-30 | 2021-02-23 | 中北大学 | Preparation method of low-reflection high-shielding waterborne polyurethane electromagnetic shielding composite foam |
Also Published As
Publication number | Publication date |
---|---|
DE60215324D1 (en) | 2006-11-23 |
EP1382045A1 (en) | 2004-01-21 |
CA2444527A1 (en) | 2002-11-07 |
CA2444527C (en) | 2010-10-12 |
JP2004527087A (en) | 2004-09-02 |
JP4293793B2 (en) | 2009-07-08 |
EP1382045B1 (en) | 2006-10-11 |
US6646199B2 (en) | 2003-11-11 |
DE60215324T2 (en) | 2007-05-16 |
ATE342570T1 (en) | 2006-11-15 |
US20020010223A1 (en) | 2002-01-24 |
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