WO2002064638A3 - Method for the emulsion polymerization of olefins - Google Patents

Method for the emulsion polymerization of olefins Download PDF

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Publication number
WO2002064638A3
WO2002064638A3 PCT/EP2002/001467 EP0201467W WO02064638A3 WO 2002064638 A3 WO2002064638 A3 WO 2002064638A3 EP 0201467 W EP0201467 W EP 0201467W WO 02064638 A3 WO02064638 A3 WO 02064638A3
Authority
WO
WIPO (PCT)
Prior art keywords
olefins
applications
periodic table
elements
group
Prior art date
Application number
PCT/EP2002/001467
Other languages
German (de)
French (fr)
Other versions
WO2002064638A2 (en
Inventor
Marc Oliver Kristen
Mubarik Mahmood Chowdhry
Original Assignee
Basf Ag
Marc Oliver Kristen
Mubarik Mahmood Chowdhry
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Basf Ag, Marc Oliver Kristen, Mubarik Mahmood Chowdhry filed Critical Basf Ag
Priority to AU2002238549A priority Critical patent/AU2002238549A1/en
Publication of WO2002064638A2 publication Critical patent/WO2002064638A2/en
Publication of WO2002064638A3 publication Critical patent/WO2002064638A3/en

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Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F110/00—Homopolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F110/02—Ethene

Landscapes

  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
  • Polymerisation Methods In General (AREA)

Abstract

The invention relates to a method for the emulsion polymerization of one or more olefins by reacting a ligand according to the general formulae (Ia) to (Ic) or a mixture of at least two of the ligands (Ia) to (Ic), wherein M1 is a metal of the first group of the periodic table of elements or hydrogen, with a metal compound of the general formula (M(L2)2 or M(L2)2(L1)z, wherein M is a transition metal of the 7?th to 10th¿ group of the periodic table of elements and preferably nickel, and immediately using the reaction product for the polymerization or copolymerization of olefins in water or in a solvent mixture that contains at least 50 % by volume of water, optionally in the presence of an activator and an emulsifier. The aqueous dispersions of polyolefins such as polyethylene and ethylene copolymerizates obtained according to the inventive method are suitable for applications in the paper industry such as paper coating or surface sizing, paint coatings, raw materials for adhesives, molded foams such as mattresses, textile or leather applications, carpet backings or pharmaceutical applications.
PCT/EP2002/001467 2001-02-14 2002-02-13 Method for the emulsion polymerization of olefins WO2002064638A2 (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
AU2002238549A AU2002238549A1 (en) 2001-02-14 2002-02-13 Method for the emulsion polymerization of olefins

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
DE2001107452 DE10107452A1 (en) 2001-02-14 2001-02-14 Process for the emulsion polymerization of olefins
DE10107452.2 2001-02-14

Publications (2)

Publication Number Publication Date
WO2002064638A2 WO2002064638A2 (en) 2002-08-22
WO2002064638A3 true WO2002064638A3 (en) 2003-03-20

Family

ID=7674382

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/EP2002/001467 WO2002064638A2 (en) 2001-02-14 2002-02-13 Method for the emulsion polymerization of olefins

Country Status (3)

Country Link
AU (1) AU2002238549A1 (en)
DE (1) DE10107452A1 (en)
WO (1) WO2002064638A2 (en)

Families Citing this family (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN105837736B (en) * 2016-06-19 2017-07-18 徐州鸿丰高分子材料有限公司 A kind of preparation method of cold-resistant leather finishing agent
EP3565442A4 (en) 2017-01-04 2020-08-12 Shaw Industries Group, Inc. Carpets having an improved delamination strength and fluid barrier properties and methods of making same

Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0046331A2 (en) * 1980-08-18 1982-02-24 Gulf Research & Development Company Nickel ylides
WO1996023010A2 (en) * 1995-01-24 1996-08-01 E.I. Du Pont De Nemours And Company α-OLEFINS AND OLEFIN POLYMERS AND PROCESSES THEREFOR
WO1997048740A1 (en) * 1996-06-20 1997-12-24 Minnesota Mining And Manufacturing Company Polyolefin microspheres
FR2784110A1 (en) * 1998-10-06 2000-04-07 Atochem Elf Sa PROCESS FOR THE POLYMERIZATION OF OLEFINS IN THE PRESENCE OF WATER
WO2001044325A1 (en) * 1999-12-17 2001-06-21 Basf Aktiengesellschaft Method for the emulsion polymerisation of olefins

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0046331A2 (en) * 1980-08-18 1982-02-24 Gulf Research & Development Company Nickel ylides
WO1996023010A2 (en) * 1995-01-24 1996-08-01 E.I. Du Pont De Nemours And Company α-OLEFINS AND OLEFIN POLYMERS AND PROCESSES THEREFOR
WO1997048740A1 (en) * 1996-06-20 1997-12-24 Minnesota Mining And Manufacturing Company Polyolefin microspheres
FR2784110A1 (en) * 1998-10-06 2000-04-07 Atochem Elf Sa PROCESS FOR THE POLYMERIZATION OF OLEFINS IN THE PRESENCE OF WATER
WO2001044325A1 (en) * 1999-12-17 2001-06-21 Basf Aktiengesellschaft Method for the emulsion polymerisation of olefins

Non-Patent Citations (7)

* Cited by examiner, † Cited by third party
Title
BAUERS, FLORIAN M. ET AL: "Aqueous homo- and copolymerization of ethylene by neutral nickel (II) complexes", MACROMOLECULES (2001), 34(5), 1165-1171, XP001086590 *
HELD, ANKE ET AL: "Aqueous ethylene polymerization: stability of cationic Pd(II) complexes and polymer properties", POLYMER PREPRINTS (AMERICAN CHEMICAL SOCIETY, DIVISION OF POLYMER CHEMISTRY) (2001), 42(1), 466-467, XP008005809 *
HELD, ANKE ET AL: "Coordination polymerization in water affording amorphous polyethylenes", CHEMISTRY--A EUROPEAN JOURNAL (2000), 6(24), 4623-4629, XP001086589 *
MECKING, STEFAN ET AL: "Water as a reaction medium for nickel (II)-catalyzed ethylene polymerization", POLYMER PREPRINTS (AMERICAN CHEMICAL SOCIETY, DIVISION OF POLYMER CHEMISTRY) (2000), 41(1), 209-210, XP008005808 *
SOULA, R. ET AL: "Catalytic Polymerization of Ethylene in Emulsion", MACROMOLECULES (2001), 34(7), 2022-2026, XP001089869 *
TOMOV, ATANAS ET AL: "Emulsion polymerization of ethylene in water medium catalyzed by organotransition metal complexes", MACROMOLECULAR SYMPOSIA (2000), 150(POLYMERS IN DISPERSED MEDIA), 53-58, XP000928036 *
WANG L ET AL: "coordination polymerization of ethylene by single-component rhodium catalysts in protic solvents", JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, AMERICAN CHEMICAL SOCIETY, WASHINGTON, DC, US, vol. 115, 1993, pages 6999 - 7000, XP002168384, ISSN: 0002-7863 *

Also Published As

Publication number Publication date
DE10107452A1 (en) 2002-08-22
WO2002064638A2 (en) 2002-08-22
AU2002238549A1 (en) 2002-08-28

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