WO2002059236A3 - Stabilizer blends for alcohol in hydrocarbon fuel - Google Patents

Stabilizer blends for alcohol in hydrocarbon fuel Download PDF

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Publication number
WO2002059236A3
WO2002059236A3 PCT/US2001/049267 US0149267W WO02059236A3 WO 2002059236 A3 WO2002059236 A3 WO 2002059236A3 US 0149267 W US0149267 W US 0149267W WO 02059236 A3 WO02059236 A3 WO 02059236A3
Authority
WO
WIPO (PCT)
Prior art keywords
alcohol
wide
hydrocarbon fuel
minor
minor amount
Prior art date
Application number
PCT/US2001/049267
Other languages
French (fr)
Other versions
WO2002059236A2 (en
Inventor
Paul R Hart
Ellen M Meyer
Nancy R Calvert
Original Assignee
Betzdearborn Inc
Paul R Hart
Ellen M Meyer
Nancy R Calvert
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Betzdearborn Inc, Paul R Hart, Ellen M Meyer, Nancy R Calvert filed Critical Betzdearborn Inc
Priority to AU2002246715A priority Critical patent/AU2002246715B2/en
Priority to US10/451,939 priority patent/US20040093789A1/en
Publication of WO2002059236A2 publication Critical patent/WO2002059236A2/en
Publication of WO2002059236A3 publication Critical patent/WO2002059236A3/en

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    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09KMATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
    • C09K23/00Use of substances as emulsifying, wetting, dispersing, or foam-producing agents
    • C09K23/017Mixtures of compounds
    • C09K23/018Mixtures of two or more different organic oxygen-containing compounds
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09KMATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
    • C09K23/00Use of substances as emulsifying, wetting, dispersing, or foam-producing agents
    • C09K23/017Mixtures of compounds
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10LFUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L1/00Liquid carbonaceous fuels
    • C10L1/10Liquid carbonaceous fuels containing additives
    • C10L1/14Organic compounds
    • C10L1/143Organic compounds mixtures of organic macromolecular compounds with organic non-macromolecular compounds
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10LFUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L1/00Liquid carbonaceous fuels
    • C10L1/32Liquid carbonaceous fuels consisting of coal-oil suspensions or aqueous emulsions or oil emulsions
    • C10L1/328Oil emulsions containing water or any other hydrophilic phase
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10LFUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L1/00Liquid carbonaceous fuels
    • C10L1/10Liquid carbonaceous fuels containing additives
    • C10L1/14Organic compounds
    • C10L1/16Hydrocarbons
    • C10L1/1616Hydrocarbons fractions, e.g. lubricants, solvents, naphta, bitumen, tars, terpentine
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10LFUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L1/00Liquid carbonaceous fuels
    • C10L1/10Liquid carbonaceous fuels containing additives
    • C10L1/14Organic compounds
    • C10L1/18Organic compounds containing oxygen
    • C10L1/192Macromolecular compounds
    • C10L1/198Macromolecular compounds obtained otherwise than by reactions involving only carbon-to-carbon unsaturated bonds homo- or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon to carbon double bond, and at least one being terminated by an acyloxy radical of a saturated carboxylic acid, of carbonic acid
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10LFUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L1/00Liquid carbonaceous fuels
    • C10L1/10Liquid carbonaceous fuels containing additives
    • C10L1/14Organic compounds
    • C10L1/18Organic compounds containing oxygen
    • C10L1/192Macromolecular compounds
    • C10L1/198Macromolecular compounds obtained otherwise than by reactions involving only carbon-to-carbon unsaturated bonds homo- or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon to carbon double bond, and at least one being terminated by an acyloxy radical of a saturated carboxylic acid, of carbonic acid
    • C10L1/1985Macromolecular compounds obtained otherwise than by reactions involving only carbon-to-carbon unsaturated bonds homo- or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon to carbon double bond, and at least one being terminated by an acyloxy radical of a saturated carboxylic acid, of carbonic acid polyethers, e.g. di- polygylcols and derivatives; ethers - esters
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10LFUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L1/00Liquid carbonaceous fuels
    • C10L1/10Liquid carbonaceous fuels containing additives
    • C10L1/14Organic compounds
    • C10L1/22Organic compounds containing nitrogen
    • C10L1/23Organic compounds containing nitrogen containing at least one nitrogen-to-oxygen bond, e.g. nitro-compounds, nitrates, nitrites
    • C10L1/231Organic compounds containing nitrogen containing at least one nitrogen-to-oxygen bond, e.g. nitro-compounds, nitrates, nitrites nitro compounds; nitrates; nitrites
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10LFUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L1/00Liquid carbonaceous fuels
    • C10L1/10Liquid carbonaceous fuels containing additives
    • C10L1/14Organic compounds
    • C10L1/22Organic compounds containing nitrogen
    • C10L1/234Macromolecular compounds
    • C10L1/238Macromolecular compounds obtained otherwise than by reactions involving only carbon-to-carbon unsaturated bonds
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10LFUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L1/00Liquid carbonaceous fuels
    • C10L1/10Liquid carbonaceous fuels containing additives
    • C10L1/14Organic compounds
    • C10L1/22Organic compounds containing nitrogen
    • C10L1/234Macromolecular compounds
    • C10L1/238Macromolecular compounds obtained otherwise than by reactions involving only carbon-to-carbon unsaturated bonds
    • C10L1/2383Polyamines or polyimines, or derivatives thereof (poly)amines and imines; derivatives thereof (substituted by a macromolecular group containing 30C)
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10NINDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2050/00Form in which the lubricant is applied to the material being lubricated
    • C10N2050/015Dispersions of solid lubricants
    • C10N2050/02Dispersions of solid lubricants dissolved or suspended in a carrier which subsequently evaporates to leave a lubricant coating

Landscapes

  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Materials Engineering (AREA)
  • Liquid Carbonaceous Fuels (AREA)

Abstract

The present invention relates to compositions to stabilize hydrocarbon fuel, over a range of alcohol and water concentrations, against phase separation, containing a blend of two or more wide or one or more wide and one or more tall gaint hydrophobe nonionic surfactants. It also relates to fuel compositions stable toward such phase separation, which include (a) a major portion of a hydrocarbon fuel; (b) a minor amount of a low-alkyl (C1-C3) alcohol; (c) a minor portion of water; and (d) a minor portion of a stabilizer comprising a blend of wide or wide and tall giant hydrphobe nonionic surfactants. Optionally, the fuel compositions also include (e) a minor amount of a combustion aid, such as a cetane improver and (f) a minor amount of a solvent, such as a water solubilizing higher (C4 to C16) alcohol.
PCT/US2001/049267 2000-12-29 2001-12-18 Stabilizer blends for alcohol in hydrocarbon fuel WO2002059236A2 (en)

Priority Applications (2)

Application Number Priority Date Filing Date Title
AU2002246715A AU2002246715B2 (en) 2000-12-29 2001-12-18 Stabilizer blends for alcohol in hydrocarbon fuel
US10/451,939 US20040093789A1 (en) 2000-12-29 2001-12-18 Stabilizer blends for alcohol in hydrocarbon fuel

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US25918900P 2000-12-29 2000-12-29
US60/259,189 2000-12-29

Publications (2)

Publication Number Publication Date
WO2002059236A2 WO2002059236A2 (en) 2002-08-01
WO2002059236A3 true WO2002059236A3 (en) 2003-07-03

Family

ID=22983900

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/US2001/049267 WO2002059236A2 (en) 2000-12-29 2001-12-18 Stabilizer blends for alcohol in hydrocarbon fuel

Country Status (3)

Country Link
US (1) US20040093789A1 (en)
AU (1) AU2002246715B2 (en)
WO (1) WO2002059236A2 (en)

Families Citing this family (17)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US7410514B2 (en) * 2002-12-05 2008-08-12 Greg Binions Liquid fuel composition having aliphatic organic non-hydrocarbon compounds, an aromatic hydrocarbon having an aromatic content of less than 15% by volume, an oxygenate, and water
US20040111957A1 (en) 2002-12-13 2004-06-17 Filippini Brian B. Water blended fuel composition
US7257945B2 (en) 2003-02-10 2007-08-21 U T Battelle, Llc Stripping ethanol from ethanol-blended fuels for use in NOx SCR
US7494959B2 (en) 2005-08-10 2009-02-24 Advanced Lubrication Technology Inc. Multi-phase lubricant compositions containing emulsified boric acid
US7419515B2 (en) * 2005-08-10 2008-09-02 Advanced Lubrication Technology, Inc. Multi-phase distillate fuel compositions and concentrates containing emulsified boric acid
EP2010631A4 (en) * 2006-04-27 2010-03-17 New Generation Biofuels Inc Biofuel composition and method of producing a biofuel
ITRM20060377A1 (en) * 2006-07-19 2008-01-20 Angelis Nazzareno De INTEGRATED PROCEDURE FOR THE PRODUCTION OF BIOFUELS AND BIOFUELS FROM DIFFERENT TYPES OF RAW MATERIALS AND RELATED PRODUCTS
US20100325944A1 (en) * 2007-05-30 2010-12-30 Baker Hughes Incorporated Additives for Cetane Improvement in Middle Distillate Fuels
US20140041286A1 (en) * 2007-09-24 2014-02-13 Sylvatex, Inc. Method of formulating a fuel composition for use in internal-combustion engines
US20090260280A1 (en) * 2008-04-17 2009-10-22 Klausmeier William H Method of formulating a fuel composition for use in internal-combustion engines
US20090260279A1 (en) * 2008-04-17 2009-10-22 Klausmeier William H Biodiesel and diesel compositions
US20090260278A1 (en) * 2008-04-17 2009-10-22 Klausmeier William H Fuel compositions
AP2013007214A0 (en) 2011-03-29 2013-10-31 Fuelina Inc Hybrid fuel and method of making the same
MX2017007234A (en) 2014-12-03 2018-04-10 Univ Drexel Direct incorporation of natural gas into hydrocarbon liquid fuels.
KR101954918B1 (en) 2017-04-10 2019-03-06 김덕섭 Manufacturing method of fuel additive and fuel using the same
WO2019145944A1 (en) * 2018-01-23 2019-08-01 Sally Ronen Fire initiator
EP3887488B1 (en) * 2018-11-30 2023-01-04 TotalEnergies OneTech Quaternary fatty amidoamine compound for use as an additive for fuel

Citations (8)

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US4504275A (en) * 1983-03-24 1985-03-12 Imperial Chemical Industries Plc Emulsifying agents
US4504276A (en) * 1983-03-24 1985-03-12 Imperial Chemical Industries Plc Emulsifying agents
US4509950A (en) * 1983-03-24 1985-04-09 Imperial Chemical Industries Plc Emulsifying agents
US5360458A (en) * 1989-03-02 1994-11-01 The Lubrizol Corporation Oil-water emulsions
US5437693A (en) * 1993-03-17 1995-08-01 Kao Corporation Heavy oil emulsion fuel composition
US5851245A (en) * 1996-05-23 1998-12-22 Kao Corporation Method for producing superheavy oil emulsion fuel and fuel produced thereby
US5992354A (en) * 1993-07-02 1999-11-30 Massachusetts Institute Of Technology Combustion of nanopartitioned fuel
US6383237B1 (en) * 1999-07-07 2002-05-07 Deborah A. Langer Process and apparatus for making aqueous hydrocarbon fuel compositions, and aqueous hydrocarbon fuel compositions

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US3346494A (en) * 1964-04-29 1967-10-10 Exxon Research Engineering Co Microemulsions in liquid hydrocarbons
US3876391A (en) * 1969-02-28 1975-04-08 Texaco Inc Process of preparing novel micro emulsions
DE2653026A1 (en) * 1975-06-30 1978-05-24 Edward C Wenzel LIQUID MIXTURE THAT CAN BE USED AS FUEL FOR COMBUSTION ENGINES
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US4504275A (en) * 1983-03-24 1985-03-12 Imperial Chemical Industries Plc Emulsifying agents
US4504276A (en) * 1983-03-24 1985-03-12 Imperial Chemical Industries Plc Emulsifying agents
US4509950A (en) * 1983-03-24 1985-04-09 Imperial Chemical Industries Plc Emulsifying agents
US5360458A (en) * 1989-03-02 1994-11-01 The Lubrizol Corporation Oil-water emulsions
US5437693A (en) * 1993-03-17 1995-08-01 Kao Corporation Heavy oil emulsion fuel composition
US5992354A (en) * 1993-07-02 1999-11-30 Massachusetts Institute Of Technology Combustion of nanopartitioned fuel
US5851245A (en) * 1996-05-23 1998-12-22 Kao Corporation Method for producing superheavy oil emulsion fuel and fuel produced thereby
US6383237B1 (en) * 1999-07-07 2002-05-07 Deborah A. Langer Process and apparatus for making aqueous hydrocarbon fuel compositions, and aqueous hydrocarbon fuel compositions

Also Published As

Publication number Publication date
WO2002059236A2 (en) 2002-08-01
US20040093789A1 (en) 2004-05-20
AU2002246715B2 (en) 2007-10-18

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