WO2002059201A8 - Binary mixtures of biodegradable aliphatic polyesters and products obtained from these - Google Patents

Binary mixtures of biodegradable aliphatic polyesters and products obtained from these

Info

Publication number
WO2002059201A8
WO2002059201A8 PCT/EP2002/000761 EP0200761W WO02059201A8 WO 2002059201 A8 WO2002059201 A8 WO 2002059201A8 EP 0200761 W EP0200761 W EP 0200761W WO 02059201 A8 WO02059201 A8 WO 02059201A8
Authority
WO
WIPO (PCT)
Prior art keywords
aliphatic polyesters
polyesters
fusion
products obtained
biodegradable aliphatic
Prior art date
Application number
PCT/EP2002/000761
Other languages
French (fr)
Other versions
WO2002059201A1 (en
Inventor
Catia Bastioli
Tredici Gianfranco Del
Italo Guanella
Giovanni Floridi
Roberto Ponti
Original Assignee
Novamont Spa
Catia Bastioli
Tredici Gianfranco Del
Italo Guanella
Giovanni Floridi
Roberto Ponti
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Novamont Spa, Catia Bastioli, Tredici Gianfranco Del, Italo Guanella, Giovanni Floridi, Roberto Ponti filed Critical Novamont Spa
Publication of WO2002059201A1 publication Critical patent/WO2002059201A1/en
Publication of WO2002059201A8 publication Critical patent/WO2002059201A8/en

Links

Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B27/00—Layered products comprising a layer of synthetic resin
    • B32B27/36—Layered products comprising a layer of synthetic resin comprising polyesters
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B27/00—Layered products comprising a layer of synthetic resin
    • B32B27/06—Layered products comprising a layer of synthetic resin as the main or only constituent of a layer, which is next to another layer of the same or of a different material
    • B32B27/065—Layered products comprising a layer of synthetic resin as the main or only constituent of a layer, which is next to another layer of the same or of a different material of foam
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B27/00—Layered products comprising a layer of synthetic resin
    • B32B27/18—Layered products comprising a layer of synthetic resin characterised by the use of special additives
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B37/00—Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding
    • B32B37/14—Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding characterised by the properties of the layers
    • B32B37/15—Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding characterised by the properties of the layers with at least one layer being manufactured and immediately laminated before reaching its stable state, e.g. in which a layer is extruded and laminated while in semi-molten state
    • B32B37/153—Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding characterised by the properties of the layers with at least one layer being manufactured and immediately laminated before reaching its stable state, e.g. in which a layer is extruded and laminated while in semi-molten state at least one layer is extruded and immediately laminated while in semi-molten state
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B5/00—Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts
    • B32B5/18—Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts characterised by features of a layer of foamed material
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B65—CONVEYING; PACKING; STORING; HANDLING THIN OR FILAMENTARY MATERIAL
    • B65D—CONTAINERS FOR STORAGE OR TRANSPORT OF ARTICLES OR MATERIALS, e.g. BAGS, BARRELS, BOTTLES, BOXES, CANS, CARTONS, CRATES, DRUMS, JARS, TANKS, HOPPERS, FORWARDING CONTAINERS; ACCESSORIES, CLOSURES, OR FITTINGS THEREFOR; PACKAGING ELEMENTS; PACKAGES
    • B65D65/00—Wrappers or flexible covers; Packaging materials of special type or form
    • B65D65/38—Packaging materials of special type or form
    • B65D65/46—Applications of disintegrable, dissolvable or edible materials
    • B65D65/466—Bio- or photodegradable packaging materials
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J5/00—Manufacture of articles or shaped materials containing macromolecular substances
    • C08J5/18—Manufacture of films or sheets
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L67/00—Compositions of polyesters obtained by reactions forming a carboxylic ester link in the main chain; Compositions of derivatives of such polymers
    • C08L67/02—Polyesters derived from dicarboxylic acids and dihydroxy compounds
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L67/00—Compositions of polyesters obtained by reactions forming a carboxylic ester link in the main chain; Compositions of derivatives of such polymers
    • C08L67/04—Polyesters derived from hydroxycarboxylic acids, e.g. lactones
    • D—TEXTILES; PAPER
    • D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
    • D01F—CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
    • D01F6/00—Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof
    • D01F6/88—Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof from mixtures of polycondensation products as major constituent with other polymers or low-molecular-weight compounds
    • D01F6/92—Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof from mixtures of polycondensation products as major constituent with other polymers or low-molecular-weight compounds of polyesters
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2270/00—Resin or rubber layer containing a blend of at least two different polymers
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2307/00—Properties of the layers or laminate
    • B32B2307/70—Other properties
    • B32B2307/716—Degradable
    • B32B2307/7163—Biodegradable
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2307/00—Properties of the layers or laminate
    • B32B2307/70—Other properties
    • B32B2307/726—Permeability to liquids, absorption
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2367/00—Polyesters, e.g. PET, i.e. polyethylene terephthalate
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2405/00—Adhesive articles, e.g. adhesive tapes
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2437/00—Clothing
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2439/00—Containers; Receptacles
    • B32B2439/40—Closed containers
    • B32B2439/46—Bags
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2439/00—Containers; Receptacles
    • B32B2439/70—Food packaging
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2451/00—Decorative or ornamental articles
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2367/00—Characterised by the use of polyesters obtained by reactions forming a carboxylic ester link in the main chain; Derivatives of such polymers
    • C08J2367/04—Polyesters derived from hydroxy carboxylic acids, e.g. lactones
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02W—CLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO WASTEWATER TREATMENT OR WASTE MANAGEMENT
    • Y02W90/00—Enabling technologies or technologies with a potential or indirect contribution to greenhouse gas [GHG] emissions mitigation
    • Y02W90/10—Bio-packaging, e.g. packing containers made from renewable resources or bio-plastics

Landscapes

  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Manufacturing & Machinery (AREA)
  • Biodiversity & Conservation Biology (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Materials Engineering (AREA)
  • Mechanical Engineering (AREA)
  • General Chemical & Material Sciences (AREA)
  • Textile Engineering (AREA)
  • Compositions Of Macromolecular Compounds (AREA)
  • Biological Depolymerization Polymers (AREA)
  • Manufacture Of Macromolecular Shaped Articles (AREA)

Abstract

A biodegradable mixture obtained by melt mixing polyesters comprising: (A) an aliphatic polyesters of the kind polyhydroxyacid or diaic/diol and their copolymer; (B) a polymer of lactic acid comprising L or D polylactic acid, L, D-polylactic, meso polylactic acid and lactic acid copolymers with hydroxyacids or lactones thereof containing at least 75% of L-lactic or D-lactic acid in which the concentration by weight of A with respect to (A+B) is in the range 30-60% and in which the sum of the fusion entalpies ΔHA and ΔHB of the two polyesters in the mixture is greater than the normalized sum of the fusion entalpies Δ1 and ΔH2 of the aliphatic polyesters prior to melt mixing, the fusion entalpy converted to the polylactic acid-family polymer when the temperature of the film is raised being greater than 35 J/g.
PCT/EP2002/000761 2001-01-25 2002-01-25 Binary mixtures of biodegradable aliphatic polyesters and products obtained from these WO2002059201A1 (en)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
IT2001TO000061A ITTO20010061A1 (en) 2001-01-25 2001-01-25 BINARY MIXTURES OF BIODEGRADABLE ALIPHATIC POLYESTERS AND PRODUCTS OBTAINED FROM THESE.
ITTO2001A000061 2001-01-25

Publications (2)

Publication Number Publication Date
WO2002059201A1 WO2002059201A1 (en) 2002-08-01
WO2002059201A8 true WO2002059201A8 (en) 2002-11-14

Family

ID=11458439

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/EP2002/000761 WO2002059201A1 (en) 2001-01-25 2002-01-25 Binary mixtures of biodegradable aliphatic polyesters and products obtained from these

Country Status (2)

Country Link
IT (1) ITTO20010061A1 (en)
WO (1) WO2002059201A1 (en)

Families Citing this family (23)

* Cited by examiner, † Cited by third party
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EP1603987B1 (en) * 2003-02-21 2011-08-03 Metabolix, Inc. Pha blends
JP3889376B2 (en) * 2003-05-16 2007-03-07 松下電器産業株式会社 Battery package and manufacturing method thereof
US6984426B2 (en) * 2003-06-02 2006-01-10 Cortec Corporation Biodegradable bag
US7492326B1 (en) 2003-06-02 2009-02-17 Cortec Corporation Biodegradable radio frequency identification cards
US7393590B2 (en) * 2004-02-27 2008-07-01 Cereplast, Inc. Biodegradable poly(lactic acid) polymer composition and films, coatings and products comprising Biodegradable poly(lactic acid) polymer compositions
AU2011203494B2 (en) * 2004-07-09 2012-07-26 E. I. Du Pont De Nemours And Company Sulfonated copolyetherester compositions from hydroxyalkanoic acids and shaped articles produced therefrom
US7193029B2 (en) * 2004-07-09 2007-03-20 E. I. Du Pont De Nemours And Company Sulfonated copolyetherester compositions from hydroxyalkanoic acids and shaped articles produced therefrom
US7144972B2 (en) * 2004-07-09 2006-12-05 E. I. Du Pont De Nemours And Company Copolyetherester compositions containing hydroxyalkanoic acids and shaped articles produced therefrom
US9592325B2 (en) 2006-02-07 2017-03-14 Tepha, Inc. Polymeric, degradable drug-eluting stents and coatings
ES2395112T3 (en) * 2006-02-07 2013-02-08 Tepha, Inc. Cured polylactic acid polymers and copolymers
US8979921B2 (en) 2006-02-07 2015-03-17 Tepha, Inc. Polymeric, degradable drug-eluting stents and coatings
US7927532B2 (en) * 2006-02-28 2011-04-19 Cereplast, Inc. Biodegradable nano-polymer compositions and biodegradable articles made thereof
ITMI20061845A1 (en) * 2006-09-27 2008-03-28 Novamont Spa STYLE BIODEGRADABLE POLYPHASIC COMPOSITIONS BASED ON STARCH
EP2300645A4 (en) * 2008-07-16 2011-10-05 Wright & Mcgill Co Biodegradable polyester copolymers
CN101445651B (en) * 2008-12-26 2011-06-15 扬州大学 Bicontinuous biomacromolecule ternary nanometer composite material and preparation method thereof
CN104910599B (en) 2010-05-17 2018-02-09 梅塔玻利克斯公司 Plasticizing polylactic acid containing PHA
EP2491788B1 (en) 2011-02-25 2015-12-23 Kraft Foods R & D, Inc. Food product with a moulded body
CN104379671A (en) 2012-06-05 2015-02-25 梅塔玻利克斯公司 Biobased rubber modified biodegradable polymer blends
CN104755538B (en) 2012-08-17 2018-08-31 Cj 第一制糖株式会社 Bio-rubber modifying agent for blend polymer
CN105531308B (en) 2013-05-30 2021-08-10 Cj 第一制糖株式会社 Recycle blends
WO2015149029A1 (en) 2014-03-27 2015-10-01 Metabolix, Inc. Highly filled polymer systems
CN117844202A (en) 2015-11-17 2024-04-09 Cj第一制糖株式会社 Polymer blends with controlled biodegradation rates
CN107237001B (en) * 2017-06-09 2019-12-27 中国水产科学研究院东海水产研究所 Fishing starch modified polylactic acid monofilament and preparation method thereof

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CA2057668A1 (en) * 1991-12-13 1993-06-14 Speros P. Nemphos Degradable foam
JP3148367B2 (en) * 1992-07-07 2001-03-19 三井化学株式会社 Recovered paper storage container
CA2124847C (en) * 1992-10-02 2005-05-10 Patrick R. Gruber Melt-stable lactide polymer films and processes for manufacture thereof
US5866634A (en) * 1995-09-25 1999-02-02 Shin-Etsu Chemical Co., Ltd Biodegradable polymer compositions and shrink films
JP3339297B2 (en) * 1996-04-02 2002-10-28 三菱化学株式会社 Aliphatic polyester composition
JPH1024518A (en) * 1996-07-10 1998-01-27 Mitsubishi Plastics Ind Ltd Polylactic biodegradable gas barrier film

Also Published As

Publication number Publication date
WO2002059201A1 (en) 2002-08-01
ITTO20010061A0 (en) 2001-01-25
ITTO20010061A1 (en) 2002-07-25

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