WO2002059165A3 - Polymerization of olefinic compounds - Google Patents

Polymerization of olefinic compounds Download PDF

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Publication number
WO2002059165A3
WO2002059165A3 PCT/US2002/003088 US0203088W WO02059165A3 WO 2002059165 A3 WO2002059165 A3 WO 2002059165A3 US 0203088 W US0203088 W US 0203088W WO 02059165 A3 WO02059165 A3 WO 02059165A3
Authority
WO
WIPO (PCT)
Prior art keywords
polymerization
group
olefinic compounds
ligands
catalyze
Prior art date
Application number
PCT/US2002/003088
Other languages
French (fr)
Other versions
WO2002059165A2 (en
Inventor
Maurice S Brookhart
Keith Kunitsky
Jon M Malinoski
Lin Wang
Yin Wang
Weijun Liu
Lynda Kaye Johnson
Kristina A Kreutzer
Steven Dale Ittel
Original Assignee
Du Pont
Maurice S Brookhart
Keith Kunitsky
Jon M Malinoski
Lin Wang
Yin Wang
Weijun Liu
Lynda Kaye Johnson
Kristina A Kreutzer
Steven Dale Ittel
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority claimed from US09/871,099 external-priority patent/US6897275B2/en
Application filed by Du Pont, Maurice S Brookhart, Keith Kunitsky, Jon M Malinoski, Lin Wang, Yin Wang, Weijun Liu, Lynda Kaye Johnson, Kristina A Kreutzer, Steven Dale Ittel filed Critical Du Pont
Priority to EP02709300A priority Critical patent/EP1355956A2/en
Priority to JP2002559466A priority patent/JP2004517933A/en
Publication of WO2002059165A2 publication Critical patent/WO2002059165A2/en
Publication of WO2002059165A3 publication Critical patent/WO2002059165A3/en

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Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F15/00—Compounds containing elements of Groups 8, 9, 10 or 18 of the Periodic Table
    • C07F15/0006—Compounds containing elements of Groups 8, 9, 10 or 18 of the Periodic Table compounds of the platinum group
    • C07F15/006—Palladium compounds
    • C07F15/0066—Palladium compounds without a metal-carbon linkage
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F15/00—Compounds containing elements of Groups 8, 9, 10 or 18 of the Periodic Table
    • C07F15/04—Nickel compounds
    • C07F15/045—Nickel compounds without a metal-carbon linkage
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F110/00—Homopolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F110/02—Ethene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F110/00—Homopolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F110/14—Monomers containing five or more carbon atoms
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F210/02—Ethene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/65908—Component covered by group C08F4/64 containing a transition metal-carbon bond in combination with an ionising compound other than alumoxane, e.g. (C6F5)4B-X+
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/65912—Component covered by group C08F4/64 containing a transition metal-carbon bond in combination with an organoaluminium compound

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Indole Compounds (AREA)

Abstract

Certain complexes containing ligands having a phosphino group, amino group or an imino group, and a second functional group such as amide, ester or ketone, when complexed to transition metals, catalyze the (co)polymerization of olefinic compounds such as ethylene, α-olefins and/or acrylates. A newly recognized class of ligands for making copolymer containing polar monomers using late transition metal complexes is described.
PCT/US2002/003088 2001-01-26 2002-01-25 Polymerization of olefinic compounds WO2002059165A2 (en)

Priority Applications (2)

Application Number Priority Date Filing Date Title
EP02709300A EP1355956A2 (en) 2001-01-26 2002-01-25 Polymerization of olefinic compounds
JP2002559466A JP2004517933A (en) 2001-01-26 2002-01-25 Polymerization of olefinic compounds

Applications Claiming Priority (6)

Application Number Priority Date Filing Date Title
US60/264,537 2001-01-25
US26453701P 2001-01-26 2001-01-26
US29479401P 2001-05-31 2001-05-31
US09/871,099 2001-05-31
US60/294,794 2001-05-31
US09/871,099 US6897275B2 (en) 2000-05-31 2001-05-31 Catalysts for olefin polymerization

Publications (2)

Publication Number Publication Date
WO2002059165A2 WO2002059165A2 (en) 2002-08-01
WO2002059165A3 true WO2002059165A3 (en) 2003-05-22

Family

ID=27401711

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/US2002/003088 WO2002059165A2 (en) 2001-01-26 2002-01-25 Polymerization of olefinic compounds

Country Status (3)

Country Link
EP (1) EP1355956A2 (en)
JP (1) JP2004517933A (en)
WO (1) WO2002059165A2 (en)

Families Citing this family (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US20030130452A1 (en) * 2001-10-12 2003-07-10 Johnson Lynda Kaye Copolymers of ethylene with various norbornene derivatives
US7635739B2 (en) * 2005-08-31 2009-12-22 Rohm And Haas Company Substantially linear polymers and methods of making and using same
IT201700006307A1 (en) 2017-01-20 2018-07-20 Versalis Spa BONE-AZOTATE COMPLEX OF IRON, CATALYTIC SYSTEM INCLUDING THE BONE-AZOTATE COMPLEX OF IRON AND PROCEDURE FOR (CO) POLYMERIZATION OF CONJUGATED DIENES
JP6858376B2 (en) * 2017-12-22 2021-04-14 国立大学法人 東京大学 Method for Producing Catalyst for Olefin Polymerization and Polar Group-Containing Olefin Polymer
CN110483587B (en) * 2019-08-27 2021-07-09 中国科学技术大学 Large steric hindrance ketimine nickel catalyst and ligand compound, preparation method and application thereof
CN110483586B (en) * 2019-08-27 2021-07-09 中国科学技术大学 Large steric hindrance ketimine nickel catalyst and ligand compound, preparation method and application thereof

Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO1997002298A1 (en) * 1995-06-30 1997-01-23 E.I. Du Pont De Nemours And Company Olefin polymerization process

Patent Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO1997002298A1 (en) * 1995-06-30 1997-01-23 E.I. Du Pont De Nemours And Company Olefin polymerization process

Also Published As

Publication number Publication date
JP2004517933A (en) 2004-06-17
EP1355956A2 (en) 2003-10-29
WO2002059165A2 (en) 2002-08-01

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