WO2002055637A1 - Combustible solide et son procede de production - Google Patents
Combustible solide et son procede de production Download PDFInfo
- Publication number
- WO2002055637A1 WO2002055637A1 PCT/SE2002/000035 SE0200035W WO02055637A1 WO 2002055637 A1 WO2002055637 A1 WO 2002055637A1 SE 0200035 W SE0200035 W SE 0200035W WO 02055637 A1 WO02055637 A1 WO 02055637A1
- Authority
- WO
- WIPO (PCT)
- Prior art keywords
- offal
- component parts
- mixture
- mixing device
- fuel
- Prior art date
Links
- 238000004519 manufacturing process Methods 0.000 title claims abstract description 10
- 238000000034 method Methods 0.000 title claims abstract description 10
- 239000004449 solid propellant Substances 0.000 title claims description 4
- 239000000446 fuel Substances 0.000 claims abstract description 22
- 239000000463 material Substances 0.000 claims abstract description 22
- 239000000835 fiber Substances 0.000 claims abstract description 15
- 238000002156 mixing Methods 0.000 claims abstract description 15
- 239000003784 tall oil Substances 0.000 claims abstract description 15
- 239000000645 desinfectant Substances 0.000 claims abstract description 8
- 239000007788 liquid Substances 0.000 claims abstract description 5
- 239000007787 solid Substances 0.000 claims abstract description 5
- 239000000203 mixture Substances 0.000 claims description 13
- 239000002023 wood Substances 0.000 claims description 9
- -1 bark Substances 0.000 claims description 4
- 239000010893 paper waste Substances 0.000 claims description 4
- 239000003415 peat Substances 0.000 claims description 4
- 230000014759 maintenance of location Effects 0.000 abstract description 2
- 230000032258 transport Effects 0.000 description 8
- 239000002699 waste material Substances 0.000 description 7
- 230000006378 damage Effects 0.000 description 6
- 230000001580 bacterial effect Effects 0.000 description 4
- 239000002920 hazardous waste Substances 0.000 description 4
- 241001465754 Metazoa Species 0.000 description 3
- 230000008901 benefit Effects 0.000 description 2
- 210000000988 bone and bone Anatomy 0.000 description 2
- 239000006227 byproduct Substances 0.000 description 2
- 238000002485 combustion reaction Methods 0.000 description 2
- 230000001419 dependent effect Effects 0.000 description 2
- 239000008187 granular material Substances 0.000 description 2
- 238000003754 machining Methods 0.000 description 2
- 235000013372 meat Nutrition 0.000 description 2
- 239000002994 raw material Substances 0.000 description 2
- 239000011347 resin Substances 0.000 description 2
- 229920005989 resin Polymers 0.000 description 2
- 210000003625 skull Anatomy 0.000 description 2
- 210000001519 tissue Anatomy 0.000 description 2
- WRIDQFICGBMAFQ-UHFFFAOYSA-N (E)-8-Octadecenoic acid Natural products CCCCCCCCCC=CCCCCCCC(O)=O WRIDQFICGBMAFQ-UHFFFAOYSA-N 0.000 description 1
- LQJBNNIYVWPHFW-UHFFFAOYSA-N 20:1omega9c fatty acid Natural products CCCCCCCCCCC=CCCCCCCCC(O)=O LQJBNNIYVWPHFW-UHFFFAOYSA-N 0.000 description 1
- QSBYPNXLFMSGKH-UHFFFAOYSA-N 9-Heptadecensaeure Natural products CCCCCCCC=CCCCCCCCC(O)=O QSBYPNXLFMSGKH-UHFFFAOYSA-N 0.000 description 1
- 208000035473 Communicable disease Diseases 0.000 description 1
- OYHQOLUKZRVURQ-HZJYTTRNSA-N Linoleic acid Chemical compound CCCCC\C=C/C\C=C/CCCCCCCC(O)=O OYHQOLUKZRVURQ-HZJYTTRNSA-N 0.000 description 1
- ZQPPMHVWECSIRJ-UHFFFAOYSA-N Oleic acid Natural products CCCCCCCCC=CCCCCCCCC(O)=O ZQPPMHVWECSIRJ-UHFFFAOYSA-N 0.000 description 1
- 239000005642 Oleic acid Substances 0.000 description 1
- 206010039203 Road traffic accident Diseases 0.000 description 1
- QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 150000007513 acids Chemical class 0.000 description 1
- 239000010828 animal waste Substances 0.000 description 1
- 230000000844 anti-bacterial effect Effects 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 239000008280 blood Substances 0.000 description 1
- 210000004369 blood Anatomy 0.000 description 1
- 238000005520 cutting process Methods 0.000 description 1
- 230000000249 desinfective effect Effects 0.000 description 1
- 235000014113 dietary fatty acids Nutrition 0.000 description 1
- 201000010099 disease Diseases 0.000 description 1
- 208000037265 diseases, disorders, signs and symptoms Diseases 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 238000002474 experimental method Methods 0.000 description 1
- 235000019197 fats Nutrition 0.000 description 1
- 229930195729 fatty acid Natural products 0.000 description 1
- 239000000194 fatty acid Substances 0.000 description 1
- 150000004665 fatty acids Chemical class 0.000 description 1
- 230000002349 favourable effect Effects 0.000 description 1
- 239000002657 fibrous material Substances 0.000 description 1
- 235000021588 free fatty acids Nutrition 0.000 description 1
- 238000000227 grinding Methods 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- 238000000265 homogenisation Methods 0.000 description 1
- 239000010781 infectious medical waste Substances 0.000 description 1
- 230000002401 inhibitory effect Effects 0.000 description 1
- QXJSBBXBKPUZAA-UHFFFAOYSA-N isooleic acid Natural products CCCCCCCC=CCCCCCCCCC(O)=O QXJSBBXBKPUZAA-UHFFFAOYSA-N 0.000 description 1
- 235000020778 linoleic acid Nutrition 0.000 description 1
- OYHQOLUKZRVURQ-IXWMQOLASA-N linoleic acid Natural products CCCCC\C=C/C\C=C\CCCCCCCC(O)=O OYHQOLUKZRVURQ-IXWMQOLASA-N 0.000 description 1
- YELGFTGWJGBAQU-UHFFFAOYSA-N mephedrone Chemical compound CNC(C)C(=O)C1=CC=C(C)C=C1 YELGFTGWJGBAQU-UHFFFAOYSA-N 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- ZQPPMHVWECSIRJ-KTKRTIGZSA-N oleic acid Chemical compound CCCCCCCC\C=C/CCCCCCCC(O)=O ZQPPMHVWECSIRJ-KTKRTIGZSA-N 0.000 description 1
- 239000008188 pellet Substances 0.000 description 1
- 238000003892 spreading Methods 0.000 description 1
- 230000007480 spreading Effects 0.000 description 1
- 239000007858 starting material Substances 0.000 description 1
- 230000001954 sterilising effect Effects 0.000 description 1
- 238000004659 sterilization and disinfection Methods 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 229910021653 sulphate ion Inorganic materials 0.000 description 1
- 210000001835 viscera Anatomy 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
- C10L5/00—Solid fuels
- C10L5/40—Solid fuels essentially based on materials of non-mineral origin
- C10L5/42—Solid fuels essentially based on materials of non-mineral origin on animal substances or products obtained therefrom, e.g. manure
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E50/00—Technologies for the production of fuel of non-fossil origin
- Y02E50/10—Biofuels, e.g. bio-diesel
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E50/00—Technologies for the production of fuel of non-fossil origin
- Y02E50/30—Fuel from waste, e.g. synthetic alcohol or diesel
Definitions
- Destruction plants of this type are few, and may be located at very large distances from the individual slaughterhouses; which implies that the transports of the hazardous waste may become long.
- offal has a certain intrinsic value, inasmuch as the same has a energy content, the same is thus a marked drawback for slaughterhouses and cutting-up plants, in particular from an economic point of view.
- the slaughterhouses are in this manner hit by particular fees to the selected destruction plants, which take care of the waste.
- a problem associated with offals is also that the bacterial growth in the same takes place quickly; something which implies that the transport to the destruction plant must be effected without delay. In other words, the waste cannot be stored for a long time.
- the transports of the waste which is often effected on the highways, mean that traffic accidents may occur and give rise to infectious waste being liberated in the nature, with ensuing effects on the environment.
- the present invention aims at managing the above-mentioned inconveniences connected with the handling of offal. More precisely, the invention is based on the idea of converting the offal to a useful fuel already in, or in connection with, the slaughterhouses or cutting-up plants. Therefore, a primary object of the invention is to produce a fuel in close connection to the cutting-up of animals, which is easy to handle and transport and which may be stored for a considerable time without giving rise to spread of contagion or smell.
- An additional object is to provide a fuel which may be packed in a rational way in the immediate connection with the manufacturing process and which, after transport to a combustion plant, may be fed into the combustion plant in a simple way. It is also an object to provide a fuel, which has a good heating value.
- At least the primary object is attained by the fuel defined in the characterizing clause of claim 1.
- Preferred embodiments of the fuel according to the invention are furthermore defined in the dependent claims 2-4 .
- the invention also relates to a method for the production of the same.
- the features of said method are seen in the independent claim 5.
- Pre- ferred embodiments of the production method are furthermore defined in the dependent claims 6-8.
- numeral 1 designates a store for offals and 2 designates a cutting up device or disintegrator in which the waste from the store 1 may be cut up into smaller component parts.
- the store 1 may either have a large volume for storing considerable quantities of waste, or have the character of an intermediate store of a limited volume. In both cases, it should be possible to feed out the waste batchwise to the dis- integrator 2, which in turn may consist of a conventional, commercially available mill for grinding purposes.
- Numeral 3 designates a second store for receipt of a fibre material, which in practice may consist of wood shavings, wood chips, peat, bark, waste paper or a mixture hereof.
- the store 3 is intended for such fibre material which is externally acquired and which already at the arrival to the shown plant exists in a finely divided form.
- a third store is shown, in which also larger parts of fibrous material may be received, such as stumps of tree, tree branches, demolition wood, paper packages etc. From the store 4, said material may be emptied into a second disintegrator 5, e.g. a mill, in which the material may be divided into component parts of a suitable size.
- a tank for liquid disinfectant is shown.
- the disintegrators 2, 5, the store 3 and the tank 6 are in a suitable way connected with a central mixing device 7, in which the different fuel-forming components may be received batchwise.
- the mixing device may advantageously consist of a tiltable tumbler of a commercially available type.
- a conveyor 8 is schematically shown, on which a number of transport containers 9 for receiving and storing the ready-produced fuel are shown. The production of the fuel according to the invention is carried out in the following way.
- the animal waste or offal which is used as one of two main raw material components may comprise miscellaneous carcass parts, e.g. skulls, bone pieces, spinal marrow parts, viscera, pieces of fat, blood, etc.
- carcass parts e.g. skulls, bone pieces, spinal marrow parts, viscera, pieces of fat, blood, etc.
- said carcass parts are milled or disintegrated to smaller component parts of a suitable size. More precisely, the disintegration should be driven so far that the component parts of the waste get a maximum size of 50 mm (bone and skull parts do in principle get the form of granules or solid bodies, while tissue parts get the form of rags of a limited length) .
- the same When the disintegrated offal is fed out from the disintegrator, the same usually has a comparatively high moist or liquid content, the consistence of at least the tissue parts resembling the consistence of ordinary minced meat.
- the requisite fibre material which basically is of a biological origin, is fetched from at least one of the two stores 3, 4.
- said material may advantageously be chosen from the group: wood shavings, wood chips, peat, bark, or waste paper.
- the material may also con- sist of a mixture of said starting materials. If the material is of a suitable granule size already in connection with delivery to the plant according to the invention, the same may be stored in the store 3. However, if the material comprises too large components, the same may be stored in the store 4 and then be disintegrated in the disintegrator 5.
- a disinfectant in the form of tall oil is fetched.
- tall oil constitutes a by-product from the production of sulphate pulp and is obtained from the resin substances of the trees.
- the crude tall oil constitutes an mixture of principally 20-50 % resin acids and 35-55 % free fatty acids, such as oleic acid, linoleic acid and higher fatty acids.
- Characteristic of tall oil, in addition to constituting a comparatively inexpensive by-product, is that the same has a disinfecting effect inhibiting the bacterial growth.
- the disintegrated offal is fed batchwise into the mixing device 7 together with a suitable batch of tall oil from the tank 6 as well as a suitable batch of fibre material from either solely the store 3, solely the disintegrator 5, or from both of the same.
- a suitable batch of tall oil from the tank 6 as well as a suitable batch of fibre material from either solely the store 3, solely the disintegrator 5, or from both of the same.
- 50 parts by weight of offal, 49 parts by weight of fibre material and 1 part by weight of tall oil are charged into the mixing device 7.
- the mixing member 7' of the device is brought in motion in order to mix and homogenize the different components.
- the retention time of the material in the mixing device should amount to at least 5 minutes and preferably 10-20 minutes in order to guarantee an optimum homogenization of the material.
- the same should be comparatively dry (the moisture content should not exceed 20 %) .
- the wet offal is mixed with the comparatively dry fibre material components, the last-mentioned ones absorb and binds liquid, the tumbling of the components in the mixing device resulting in the formation of pellet-like or briquet-like bodies of a solid character.
- said individual bodies are well separable and may be handled as other debris goods.
- the formed fuel bodies may in regards of transport and storing be handled in the same way as pellets or briquets.
- the fuel bodies may be emptied into a sealable container 9 which is brought out of the plant, e.g. via a conveyor 8.
- the packed fuel may be stored and transported with a relatively high degree of freedom by the disinfectant tall oil effectively counteracting bacterial growth.
- the fuel may be stored for weeks without having to be burnt.
- Essential advantages of the invention is on one hand that offal which is difficult to handle is converted into a fuel of solid shape, and on the other hand that the fuel is disinfected, whereby the same may be stored for a considerable time without an aggravating bacterial growth. Therefore, the produced fuel may be handled, stored and transported in a rational and economically favourable way.
- Another substantial advantage is that the produced fuel may be burnt in conventional destruction plants, e.g. thermal power stations (i.e. not necessarily in particular destruction plants) , possibly together with other fuels. Because of the comparatively high thermal value of not solely the fibre material components, but also the proper offal, considerable amounts of energy may be extracted and utilized.
- the proportions between the components used in the initial mixture may deviate from the above-mentioned example. Principally, it should be emphasized that the share of wet offal may be increased, the dryer the fibre material component is. However, the content of offal in the material mixture should be within the range of 40-70 % by weight, suitably 45-55 % by weight. The share of disinfectant in the form of tall oil should be within the range of 0,5-2 % by weight. Experiments made have, however, shown that approx. 1 % by weight of tall oil is optimum in the balancing between raw material cost and bactericidal effect. Furthermore, it should be pointed out that also other components than those that are defined in the subsequent claim may be added to the initial mixture.
Landscapes
- Chemical & Material Sciences (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Organic Chemistry (AREA)
- Solid Fuels And Fuel-Associated Substances (AREA)
Abstract
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
SE0100107A SE521077C2 (sv) | 2001-01-15 | 2001-01-15 | Fast bränsle samt förfarande för framställning därav |
SE0100107-2 | 2001-01-15 |
Publications (1)
Publication Number | Publication Date |
---|---|
WO2002055637A1 true WO2002055637A1 (fr) | 2002-07-18 |
Family
ID=20282625
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
PCT/SE2002/000035 WO2002055637A1 (fr) | 2001-01-15 | 2002-01-11 | Combustible solide et son procede de production |
Country Status (2)
Country | Link |
---|---|
SE (1) | SE521077C2 (fr) |
WO (1) | WO2002055637A1 (fr) |
Cited By (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
FR2819822A1 (fr) * | 2001-01-22 | 2002-07-26 | Camille Vaysset | Fabrication de buches et briques compressees |
US10662387B2 (en) | 2017-06-13 | 2020-05-26 | Arr-Maz Products, L.P. | Additive used in the production of wood pellets |
US10858606B2 (en) | 2017-06-13 | 2020-12-08 | Arr-Maz Products, L.P. | Structured composite wood pellets for dust/fines mitigation and method of producing them |
Citations (8)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE2234438A1 (de) * | 1972-07-13 | 1974-01-24 | Bauer Karl | Verfahren und vorrichtung zum aufbereiten von faekalien der massen-viehhaltung, insbesondere gefluegelfarmen, und von schlachtabfaellen zu hochwertigen duengemitteln |
US4548615A (en) * | 1983-06-30 | 1985-10-22 | Institut Francais Du Petrole | Process for manufacturing solid fuels from heavy hydrocarbon oils and vegetable materials |
WO1987002377A1 (fr) * | 1985-10-16 | 1987-04-23 | Sailor, Lo^/Kken Skibsproviantering Aps | Combustible compose d'un melange de fibres cellulosiques et de boues contenant des graisses et/ou des huiles ou de dechets |
US5389114A (en) * | 1990-10-19 | 1995-02-14 | Forder; David E. | Method of treating and using waste products |
EP0725128A2 (fr) * | 1995-01-23 | 1996-08-07 | Bycosin Aktiebolag | Additif pour biocombustible solide |
GB2313901A (en) * | 1996-06-06 | 1997-12-10 | Ronald Sherwen | Mobile incinerator for animal carcasses |
DE19628521A1 (de) * | 1996-07-04 | 1998-01-15 | Kraftwerks Und Anlagenbau Ag | Verfahren und Anlage zur anaeroben Verwertung von Tierkörperteilen und von von Tieren stammenden Erzeugnissen |
WO1999047282A1 (fr) * | 1998-03-18 | 1999-09-23 | Erick Schmidt | Procede de bioraffinage de dechets organiques pour la production de produits nutritionnels steriles et denatures |
-
2001
- 2001-01-15 SE SE0100107A patent/SE521077C2/sv not_active IP Right Cessation
-
2002
- 2002-01-11 WO PCT/SE2002/000035 patent/WO2002055637A1/fr not_active Application Discontinuation
Patent Citations (8)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE2234438A1 (de) * | 1972-07-13 | 1974-01-24 | Bauer Karl | Verfahren und vorrichtung zum aufbereiten von faekalien der massen-viehhaltung, insbesondere gefluegelfarmen, und von schlachtabfaellen zu hochwertigen duengemitteln |
US4548615A (en) * | 1983-06-30 | 1985-10-22 | Institut Francais Du Petrole | Process for manufacturing solid fuels from heavy hydrocarbon oils and vegetable materials |
WO1987002377A1 (fr) * | 1985-10-16 | 1987-04-23 | Sailor, Lo^/Kken Skibsproviantering Aps | Combustible compose d'un melange de fibres cellulosiques et de boues contenant des graisses et/ou des huiles ou de dechets |
US5389114A (en) * | 1990-10-19 | 1995-02-14 | Forder; David E. | Method of treating and using waste products |
EP0725128A2 (fr) * | 1995-01-23 | 1996-08-07 | Bycosin Aktiebolag | Additif pour biocombustible solide |
GB2313901A (en) * | 1996-06-06 | 1997-12-10 | Ronald Sherwen | Mobile incinerator for animal carcasses |
DE19628521A1 (de) * | 1996-07-04 | 1998-01-15 | Kraftwerks Und Anlagenbau Ag | Verfahren und Anlage zur anaeroben Verwertung von Tierkörperteilen und von von Tieren stammenden Erzeugnissen |
WO1999047282A1 (fr) * | 1998-03-18 | 1999-09-23 | Erick Schmidt | Procede de bioraffinage de dechets organiques pour la production de produits nutritionnels steriles et denatures |
Cited By (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
FR2819822A1 (fr) * | 2001-01-22 | 2002-07-26 | Camille Vaysset | Fabrication de buches et briques compressees |
US10662387B2 (en) | 2017-06-13 | 2020-05-26 | Arr-Maz Products, L.P. | Additive used in the production of wood pellets |
US10858606B2 (en) | 2017-06-13 | 2020-12-08 | Arr-Maz Products, L.P. | Structured composite wood pellets for dust/fines mitigation and method of producing them |
Also Published As
Publication number | Publication date |
---|---|
SE521077C2 (sv) | 2003-09-30 |
SE0100107D0 (sv) | 2001-01-15 |
SE0100107L (sv) | 2002-07-16 |
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