WO2002051607A1 - Formed goods using waste rubber and method for manufacturing the same - Google Patents
Formed goods using waste rubber and method for manufacturing the same Download PDFInfo
- Publication number
- WO2002051607A1 WO2002051607A1 PCT/KR2001/001290 KR0101290W WO02051607A1 WO 2002051607 A1 WO2002051607 A1 WO 2002051607A1 KR 0101290 W KR0101290 W KR 0101290W WO 02051607 A1 WO02051607 A1 WO 02051607A1
- Authority
- WO
- WIPO (PCT)
- Prior art keywords
- parts
- weight
- goods
- waste rubber
- waste
- Prior art date
Links
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29B—PREPARATION OR PRETREATMENT OF THE MATERIAL TO BE SHAPED; MAKING GRANULES OR PREFORMS; RECOVERY OF PLASTICS OR OTHER CONSTITUENTS OF WASTE MATERIAL CONTAINING PLASTICS
- B29B17/00—Recovery of plastics or other constituents of waste material containing plastics
- B29B17/0026—Recovery of plastics or other constituents of waste material containing plastics by agglomeration or compacting
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29B—PREPARATION OR PRETREATMENT OF THE MATERIAL TO BE SHAPED; MAKING GRANULES OR PREFORMS; RECOVERY OF PLASTICS OR OTHER CONSTITUENTS OF WASTE MATERIAL CONTAINING PLASTICS
- B29B17/00—Recovery of plastics or other constituents of waste material containing plastics
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/01—Hydrocarbons
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29K—INDEXING SCHEME ASSOCIATED WITH SUBCLASSES B29B, B29C OR B29D, RELATING TO MOULDING MATERIALS OR TO MATERIALS FOR MOULDS, REINFORCEMENTS, FILLERS OR PREFORMED PARTS, e.g. INSERTS
- B29K2021/00—Use of unspecified rubbers as moulding material
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29L—INDEXING SCHEME ASSOCIATED WITH SUBCLASS B29C, RELATING TO PARTICULAR ARTICLES
- B29L2030/00—Pneumatic or solid tyres or parts thereof
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02W—CLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO WASTEWATER TREATMENT OR WASTE MANAGEMENT
- Y02W30/00—Technologies for solid waste management
- Y02W30/50—Reuse, recycling or recovery technologies
- Y02W30/62—Plastics recycling; Rubber recycling
Definitions
- the present invention relates to goods recycled from waste rubber and a method for manufacturing the same, and more particularly to technology for manufacturing rubber products formed by using powdered scrap rubber from the rubber industry.
- Waste tires which are now generated in large quantities, have been used as a source from which a variety of goods can be molded.
- adhesives have been used in manufacturing waste tires into goods.
- they are insufficiently competitive in terms of production cost because the > adhesives added to vulcanized waste tire powder are expensive.
- Much effort has been made to avoid the problems.
- Korean Pat. Laid-Open Publication No.97-027524 which discloses the manufacture of rubber blocks from waste tires by use of latex
- Korean Pat. Appl'n No. 98-63410 which introduces the use of DEG in molding waste tires with the aim of improving commercial values of the goods .
- the present inventors have conducted extensive studies into the treatment and uses of scrap rubber produced by the rubber industry, reaching the conclusion that a combination of additives, including process oil, a vulcanizing accelerant, and a vulcanizing agent, can bring about an improvement in physical properties of the goods molded from waste tires.
- a method for manufacturing rubber goods from waste rubber powder comprising the steps of: admixing 10 ⁇ 20 ml of a process oil, 2 ⁇ 3 parts by weight of a vulcanizing accelerant, 5 ⁇ 10 parts by weight of a vulcanizing agent, 0 ⁇ 15 parts by weight of a pine resin with 100 parts by weight of a waste rubber powder; uniformly homogenizing the admixture; melting the admixture at 150 to 170°C in a mold; and molding the melt into goods.
- a composition of recycled goods comprising 100 parts by weight of waste rubber powder, 10 to 20 ml of a process oil, 2 to 3 parts by weight of a vulcanizing accelerant, 5 to 10 parts by weight of a vulcanizing agent, and 0 to 15 parts by weight of a pine resin.
- Fig. 1 is a histogram illustrating physical properties of waste tire-recycled goods according to kinds of additives.
- Figs. 2 and 3 are histograms illustrating physical properties of waste rubber-recycled goods according to kinds of waste rubbers and process oils.
- Figs. 4 and 5 are curves illustrating the change of physical properties of waste rubber-recycled goods with amounts of pine resin added to the goods .
- the present invention pertains to recycling of waste rubber, which is generated in a large quantity in the rubber industry.
- Useful in the present invention are rubber powders which comprises 0.1% or less of iron content, 0.1% or less of fiber powder content, 10% or less of ash content, 1.0% or less of moisture content, meeting the criteria of KSM 6710 rubber powder of the waste tire, Korean Industry Standard.
- compositions of the waste tire powder used in the invention are as described in the following Table 1:
- the present invention is characterized in that a combination of additives, including process oil, a vulcanizing accelerant, a vulcanizing agent, and optionally pine resin depending on necessary physical properties, is used, instead of adhesives, in molding goods from waste rubber powder.
- the vulcanizing agent is preferably used in the amount of 5 to 10 parts by weight based on 100 parts by weight of the waste rubber powder.
- the amount of vulcanizing agent may affect physical properties of the formed goods. For example, adding less than 5 parts by weight may give rise to no or poor vulcanization, whereas adding more than 10 parts by weight may give rise to excessive vulcanization.
- TMTD Tetramethyl Thiuram Disulfide
- the vulcanizing accelerant is used in the amount of 2 to 3 parts by weight based on 100 parts by weight of the waste rubber powder.
- the vulcanizing accelerant is used in the amount less than 2 parts by weight, the vulcanizing time may be lengthened.
- more than 3 parts by weight of the vulcanizing accelerant may cause an increase in the risk of scotching.
- the process oil its use also characterizes the present invention.
- Fig. 1 there are compared physical properties of goods which are recycled from waste tires by use of urethane adhesive, SBR latex, DEG and process oil.
- the recycled goods by use of process oil are poorer in elongation, but better in tensile strength, compared to those using the other additives.
- process oil has an economic advantage over the other additives.
- the process oil can be selected from naphthanic and aromatic oils, depending on kinds of recycled rubber, as shown in Figs. 2 and 3.
- the amount of the process oil may be 5 to 20 parts by weight based on 100 parts by weight of the used waste rubber powder. When the amount is not within this range, the resulting rubber goods have poor physical properties since mixing and forming cannot be easily accomplished.
- pine resin may be used to improve the physical properties of the recycled goods, such as tensile strength, elongation at break, hardness, and tear strength.
- these physical properties are plotted versus contents of pine resin.
- the amount of the pine resin is determined depending on necessary physical properties and preferably falls within the range of 0 to 10 parts by weight based on 100 parts by weight of the waste rubber powder. Greater than 10 parts by weight of the pine resin makes the recycled goods poor in physical properties .
- EXAMPLE 2 10 ⁇ 20 ml of a process oil, 2 ⁇ 3 parts by weight of a vulcanizing accelerant, 5 ⁇ 10 parts by weight of a vulcanizing agent, and 5 ⁇ 15 parts by weight of a pine resin were admixed with 100 parts by weight of a waste rubber powder, followed by uniformly homogenizing the admixture. After being melted at 150 to 170 °C in a mold, the mixture was molded to goods with the aid of an ordinary process and apparatus .
- the goods of the present invention were found to have a tensile strength of 44 kgf/cm 2 , an elongation at break of about 110%, and a hardness of 84 of hardness. Low as they are in elongation at break, the recycled goods of the present invention are better in terms of tensile strength than those using DEG.
- recycled goods of the present invention were measured to be generally superior in physical properties compared to those using latex (tensile strength 32kgf/cm 2 , elongation at break 180%, hardness 80) .
- the rubber goods of the present invention have economic advantages, even though being poor in physical properties in comparison with the conventional goods (tensile strength 70 kgf/cm 2 , elongation at break 200%, and hardness 76) .
- materials for conventional rubber goods are limited to waste tires
- the present invention is applicable to waste rubber as well as waste tires.
- the improved physical properties make the recycled goods have applications in a broad spectrum of fields.
- the present invention saves production expenses by 7/20-9/20 of expenses of conventional adhesive case.
Abstract
Disclosed are rubber goods recycled from waste rubber powder and a method for manufacturing the same. Instead of expensive adhesive, a homogenized admixture comprising 15&≈25 parts by weight of a process oil, 2≈3 parts by weight of a vulcanizing accelerant, 5≈10 parts by weight of the vulcanizing agent, and 0&≈15 parts by weight of a pine resin is used based on 100 parts by weight of the waste rubber powder. Being economically favorable, the molded goods can promote the recycling of waste rubber.
Description
FORMED GOODS USING WASTE RUBBER AND METHOD FOR MANUFACTURING
THE SAME
BACKGROUND OF THE INVENTION
1. Field of the invention
The present invention relates to goods recycled from waste rubber and a method for manufacturing the same, and more particularly to technology for manufacturing rubber products formed by using powdered scrap rubber from the rubber industry.
2. Description of the Prior Art
Waste tires, which are now generated in large quantities, have been used as a source from which a variety of goods can be molded. Conventionally, adhesives have been used in manufacturing waste tires into goods. However, they are insufficiently competitive in terms of production cost because the > adhesives added to vulcanized waste tire powder are expensive. Much effort has been made to avoid the problems. For example, reference may be made to the patents which have been made by the applicant of the present invention, Korean Pat. Laid-Open Publication No.97-027524, which discloses the manufacture of rubber blocks from waste tires by use of latex, and Korean Pat. Appl'n No. 98-63410,
which introduces the use of DEG in molding waste tires with the aim of improving commercial values of the goods .
However, physical properties of the molded goods made by use of latex or DEG are poorer than those of the molded goods using the adhesive, as shown in Fig.l. Therefore, there remains a need for improving physical properties of the goods molded from waste tires with maintenance of a low production cost.
SUMMARY OF THE INVENTION
The present inventors have conducted extensive studies into the treatment and uses of scrap rubber produced by the rubber industry, reaching the conclusion that a combination of additives, including process oil, a vulcanizing accelerant, and a vulcanizing agent, can bring about an improvement in physical properties of the goods molded from waste tires.
Therefore, it is an object of the present invention to provide goods molded from waste tires, which can be produced at a low production cost with high physical properties.
It is another object of the present invention to provide a method for manufacturing such goods recycled from waste tires . In accordance with an aspect of the present invention,
there is provided a method for manufacturing rubber goods from waste rubber powder, comprising the steps of: admixing 10~20 ml of a process oil, 2~3 parts by weight of a vulcanizing accelerant, 5~10 parts by weight of a vulcanizing agent, 0~15 parts by weight of a pine resin with 100 parts by weight of a waste rubber powder; uniformly homogenizing the admixture; melting the admixture at 150 to 170°C in a mold; and molding the melt into goods.
In accordance with another aspect of the present invention, there is provided a composition of recycled goods, comprising 100 parts by weight of waste rubber powder, 10 to 20 ml of a process oil, 2 to 3 parts by weight of a vulcanizing accelerant, 5 to 10 parts by weight of a vulcanizing agent, and 0 to 15 parts by weight of a pine resin.
BRIEF DESCRIPTION OF THE DRAWINGS
The above and other objects, features and other advantages of the present invention will be more clearly understood from the following detailed description taken in conjunction with the accompanying drawings, in which:
Fig. 1 is a histogram illustrating physical properties of waste tire-recycled goods according to kinds of additives. Figs. 2 and 3 are histograms illustrating physical
properties of waste rubber-recycled goods according to kinds of waste rubbers and process oils.
Figs. 4 and 5 are curves illustrating the change of physical properties of waste rubber-recycled goods with amounts of pine resin added to the goods .
DETAILED DESCRIPTION OF THE INVENTION
The present invention pertains to recycling of waste rubber, which is generated in a large quantity in the rubber industry. Useful in the present invention are rubber powders which comprises 0.1% or less of iron content, 0.1% or less of fiber powder content, 10% or less of ash content, 1.0% or less of moisture content, meeting the criteria of KSM 6710 rubber powder of the waste tire, Korean Industry Standard.
Compositions of the waste tire powder used in the invention are as described in the following Table 1:
TABLE 1
The advantages of the invention will be apparent with reference to the accompanying drawings
The present invention is characterized in that a combination of additives, including process oil, a vulcanizing accelerant, a vulcanizing agent, and optionally pine resin depending on necessary physical properties, is used, instead of adhesives, in molding goods from waste rubber powder. Exemplified by sulfur in the present invention, the vulcanizing agent is preferably used in the amount of 5 to 10 parts by weight based on 100 parts by weight of the waste rubber powder. The amount of vulcanizing agent may affect physical properties of the formed goods. For example, adding less than 5 parts by weight may give rise to no or poor vulcanization, whereas adding more than 10 parts by weight may give rise to excessive vulcanization.
In the invention, it is preferred that TMTD (Tetramethyl Thiuram Disulfide) as the vulcanizing accelerant is used in the amount of 2 to 3 parts by weight based on 100 parts by weight of the waste rubber powder.
For example, when the vulcanizing accelerant is used in the amount less than 2 parts by weight, the vulcanizing time may be lengthened. On the other hand, more than 3 parts by weight of the vulcanizing accelerant may cause an increase in the risk of scotching.
As for the process oil, its use also characterizes the present invention. With reference to Fig. 1, there are compared physical properties of goods which are recycled from waste tires by use of urethane adhesive, SBR latex, DEG and process oil. As shown in the histogram, the recycled goods by use of process oil are poorer in elongation, but better in tensile strength, compared to those using the other additives. Furthermore, process oil has an economic advantage over the other additives. The process oil can be selected from naphthanic and aromatic oils, depending on kinds of recycled rubber, as shown in Figs. 2 and 3. Preferably, the amount of the process oil may be 5 to 20 parts by weight based on 100 parts by weight of the used waste rubber powder. When the amount is not within this range, the resulting rubber goods have poor physical properties since mixing and forming cannot be easily accomplished.
Optionally, pine resin may be used to improve the physical properties of the recycled goods, such as tensile strength, elongation at break, hardness, and tear strength.
With reference to Figs. 4 and 5, these physical properties are plotted versus contents of pine resin. As apparent from the curves, the amount of the pine resin is determined depending on necessary physical properties and preferably falls within the range of 0 to 10 parts by weight based on 100 parts by weight of the waste rubber powder. Greater than 10 parts by weight of the pine resin makes the recycled goods poor in physical properties .
A better understanding of the present invention may be obtained in light of the following examples which are set forth to illustrate, but are not to be construed to limit the present invention.
EXAMPLE 1
10~20 ml of a process oil, 2~3 parts by weight of a vulcanizing accelerant, and 5-10 parts by weight of a vulcanizing agent were admixed with 100 parts by weight of a waste rubber powder, followed by uniformly homogenizing the admixture. After being melted at 150 to 170 °C in a mold, the mixture was molded to goods with the aid of an ordinary process and apparatus.
EXAMPLE 2
10~20 ml of a process oil, 2~3 parts by weight of a vulcanizing accelerant, 5~10 parts by weight of a vulcanizing agent, and 5~15 parts by weight of a pine resin were admixed with 100 parts by weight of a waste rubber powder, followed by uniformly homogenizing the admixture. After being melted at 150 to 170 °C in a mold, the mixture was molded to goods with the aid of an ordinary process and apparatus .
A measurement was made of physical properties of goods (dumbbell type 3) manufactured from waste tire powder (particle size 900 μ ) by the molding process. The goods of the present invention were found to have a tensile strength of 44 kgf/cm2, an elongation at break of about 110%, and a hardness of 84 of hardness. Low as they are in elongation at break, the recycled goods of the present invention are better in terms of tensile strength than those using DEG. In addition, recycled goods of the present invention were measured to be generally superior in physical properties compared to those using latex (tensile strength 32kgf/cm2, elongation at break 180%, hardness 80) . Over the recycled rubber goods using urethane adhesive, the rubber goods of the present invention have economic advantages, even though being poor in physical properties in comparison with the conventional goods (tensile strength 70 kgf/cm2, elongation
at break 200%, and hardness 76) . Whereas materials for conventional rubber goods are limited to waste tires, the present invention is applicable to waste rubber as well as waste tires. Moreover, the improved physical properties make the recycled goods have applications in a broad spectrum of fields. Furthermore, the present invention saves production expenses by 7/20-9/20 of expenses of conventional adhesive case.
The present invention has been described in an illustrative manner, and it is to be understood that the terminology used is intended to be in the nature of description rather than of limitation. Many modifications and variations of the present invention are possible in light of the above teachings. Therefore, it is to be understood that within the scope of the appended claims, the invention may be practiced otherwise than as specifically described.
Claims
1. A method for manufacturing rubber goods from waste rubber powder, comprising the steps of: admixing 10-20 ml of a process oil, 2-3 parts by weight of a vulcanizing accelerant, 5-10 parts by weight of a vulcanizing agent, 0~15 parts by weight of a pine resin with 100 parts by weight of a waste rubber powder; uniformly homogenizing the admixture; melting the admixture at 150 to 170°C in a mold; and molding the melt into goods .
2. A composition of recycled goods, comprising 100 parts by weight of waste rubber powder, 10 to 20 ml of a process oil, 2 to 3 parts by weight of a vulcanizing accelerant, 5 to 10 parts by weight of a vulcanizing agent, and 0 to 15 parts by weight of a pine resin.
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
KR1020000083058A KR20010016611A (en) | 2000-12-27 | 2000-12-27 | The method for manufacturing of rubber using forming goods |
KR2000/83058 | 2000-12-27 |
Publications (1)
Publication Number | Publication Date |
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WO2002051607A1 true WO2002051607A1 (en) | 2002-07-04 |
Family
ID=19703690
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
PCT/KR2001/001290 WO2002051607A1 (en) | 2000-12-27 | 2001-07-31 | Formed goods using waste rubber and method for manufacturing the same |
Country Status (2)
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KR (1) | KR20010016611A (en) |
WO (1) | WO2002051607A1 (en) |
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
KR20010016611A (en) * | 2000-12-27 | 2001-03-05 | 김진국 | The method for manufacturing of rubber using forming goods |
Families Citing this family (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
KR100903652B1 (en) * | 2007-10-18 | 2009-06-18 | 김종문 | Modified asphalt composition used in treated fine waste tire powder with the propylene wax |
Citations (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US4244841A (en) * | 1980-03-24 | 1981-01-13 | Frankland Enterprises, Inc. | Method for recycling rubber and recycled rubber product |
KR940006738A (en) * | 1992-09-05 | 1994-04-25 | 유박인 | Manufacturing method of sidewalk block using waste tires or waste rubber |
EP0657263A1 (en) * | 1993-12-06 | 1995-06-14 | Natrub (Barbados) Limited | Process for regeneration of rubber |
KR970027524A (en) * | 1995-11-30 | 1997-06-24 | 김진국 | Waste Tire Recycling Rubber Press Block |
KR19980083974A (en) * | 1997-05-20 | 1998-12-05 | 이용학 | Manufacturing method of barast mat using waste tire powder |
KR20000046694A (en) * | 1998-12-31 | 2000-07-25 | 김진국 | Rubber molded-article using waste tire powder |
Family Cites Families (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPS5598235A (en) * | 1979-01-22 | 1980-07-26 | Ikeda Hisashi | Preparing reclaimed rubber using waste tire and product thereof |
JPS5599938A (en) * | 1979-01-27 | 1980-07-30 | Kurashiki Kako Kk | Preparation of molding rubber composition comprising vulcanized scrap rubber |
US4504604A (en) * | 1983-11-25 | 1985-03-12 | The Goodyear Tire & Rubber Company | Energy absorbing rubber composition |
JPH05329842A (en) * | 1992-06-02 | 1993-12-14 | Marenori Oonishi | Rubber product using waste tire as raw material |
JP3304189B2 (en) * | 1994-03-18 | 2002-07-22 | マツダ株式会社 | Molding rubber composition containing vulcanized scrap rubber and method for producing the same |
KR20010016611A (en) * | 2000-12-27 | 2001-03-05 | 김진국 | The method for manufacturing of rubber using forming goods |
-
2000
- 2000-12-27 KR KR1020000083058A patent/KR20010016611A/en not_active Application Discontinuation
-
2001
- 2001-07-31 WO PCT/KR2001/001290 patent/WO2002051607A1/en active Application Filing
Patent Citations (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US4244841A (en) * | 1980-03-24 | 1981-01-13 | Frankland Enterprises, Inc. | Method for recycling rubber and recycled rubber product |
KR940006738A (en) * | 1992-09-05 | 1994-04-25 | 유박인 | Manufacturing method of sidewalk block using waste tires or waste rubber |
EP0657263A1 (en) * | 1993-12-06 | 1995-06-14 | Natrub (Barbados) Limited | Process for regeneration of rubber |
KR970027524A (en) * | 1995-11-30 | 1997-06-24 | 김진국 | Waste Tire Recycling Rubber Press Block |
KR19980083974A (en) * | 1997-05-20 | 1998-12-05 | 이용학 | Manufacturing method of barast mat using waste tire powder |
KR20000046694A (en) * | 1998-12-31 | 2000-07-25 | 김진국 | Rubber molded-article using waste tire powder |
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
KR20010016611A (en) * | 2000-12-27 | 2001-03-05 | 김진국 | The method for manufacturing of rubber using forming goods |
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