WO2002030203A1 - Composition for generating chlorine dioxide - Google Patents
Composition for generating chlorine dioxide Download PDFInfo
- Publication number
- WO2002030203A1 WO2002030203A1 PCT/US2001/030644 US0130644W WO0230203A1 WO 2002030203 A1 WO2002030203 A1 WO 2002030203A1 US 0130644 W US0130644 W US 0130644W WO 0230203 A1 WO0230203 A1 WO 0230203A1
- Authority
- WO
- WIPO (PCT)
- Prior art keywords
- chlorine dioxide
- water
- chlorite
- sodium
- product
- Prior art date
Links
- OSVXSBDYLRYLIG-UHFFFAOYSA-N dioxidochlorine(.) Chemical compound O=Cl=O OSVXSBDYLRYLIG-UHFFFAOYSA-N 0.000 title claims abstract description 155
- 239000004155 Chlorine dioxide Substances 0.000 title claims abstract description 77
- 235000019398 chlorine dioxide Nutrition 0.000 title claims abstract description 77
- 239000000203 mixture Substances 0.000 title claims abstract description 73
- UKLNMMHNWFDKNT-UHFFFAOYSA-M sodium chlorite Chemical compound [Na+].[O-]Cl=O UKLNMMHNWFDKNT-UHFFFAOYSA-M 0.000 claims abstract description 43
- 229910000342 sodium bisulfate Inorganic materials 0.000 claims abstract description 40
- WBHQBSYUUJJSRZ-UHFFFAOYSA-M sodium bisulfate Chemical compound [Na+].OS([O-])(=O)=O WBHQBSYUUJJSRZ-UHFFFAOYSA-M 0.000 claims abstract description 39
- LWXVCCOAQYNXNX-UHFFFAOYSA-N lithium hypochlorite Chemical compound [Li+].Cl[O-] LWXVCCOAQYNXNX-UHFFFAOYSA-N 0.000 claims abstract description 32
- 229960002218 sodium chlorite Drugs 0.000 claims abstract description 32
- 238000009472 formulation Methods 0.000 claims abstract description 23
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 50
- QBWCMBCROVPCKQ-UHFFFAOYSA-N chlorous acid Chemical compound OCl=O QBWCMBCROVPCKQ-UHFFFAOYSA-N 0.000 claims description 38
- 229910001919 chlorite Inorganic materials 0.000 claims description 36
- 229910052619 chlorite group Inorganic materials 0.000 claims description 36
- 238000000034 method Methods 0.000 claims description 17
- 239000012190 activator Substances 0.000 claims description 15
- WQYVRQLZKVEZGA-UHFFFAOYSA-N hypochlorite Chemical compound Cl[O-] WQYVRQLZKVEZGA-UHFFFAOYSA-N 0.000 claims description 9
- 239000002253 acid Substances 0.000 claims description 8
- 230000000249 desinfective effect Effects 0.000 claims description 8
- 235000012055 fruits and vegetables Nutrition 0.000 claims description 6
- 239000004615 ingredient Substances 0.000 claims description 5
- 231100001261 hazardous Toxicity 0.000 claims description 3
- 239000002351 wastewater Substances 0.000 claims description 3
- 238000004332 deodorization Methods 0.000 claims 1
- 239000000645 desinfectant Substances 0.000 abstract description 5
- 239000007864 aqueous solution Substances 0.000 abstract description 4
- 239000007788 liquid Substances 0.000 abstract description 3
- 238000004519 manufacturing process Methods 0.000 abstract description 3
- 238000000275 quality assurance Methods 0.000 abstract 1
- 239000000243 solution Substances 0.000 description 39
- 238000006243 chemical reaction Methods 0.000 description 13
- 239000000047 product Substances 0.000 description 13
- 239000007787 solid Substances 0.000 description 12
- 235000020188 drinking water Nutrition 0.000 description 9
- 239000003651 drinking water Substances 0.000 description 9
- 238000002156 mixing Methods 0.000 description 8
- 239000007800 oxidant agent Substances 0.000 description 7
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 description 6
- FAPWRFPIFSIZLT-UHFFFAOYSA-M Sodium chloride Chemical compound [Na+].[Cl-] FAPWRFPIFSIZLT-UHFFFAOYSA-M 0.000 description 6
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 6
- 239000000460 chlorine Substances 0.000 description 6
- 229910052801 chlorine Inorganic materials 0.000 description 6
- 239000004480 active ingredient Substances 0.000 description 5
- QWPPOHNGKGFGJK-UHFFFAOYSA-N hypochlorous acid Chemical compound ClO QWPPOHNGKGFGJK-UHFFFAOYSA-N 0.000 description 5
- 238000002360 preparation method Methods 0.000 description 5
- 238000004659 sterilization and disinfection Methods 0.000 description 5
- XTEGARKTQYYJKE-UHFFFAOYSA-M Chlorate Chemical compound [O-]Cl(=O)=O XTEGARKTQYYJKE-UHFFFAOYSA-M 0.000 description 4
- CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 description 4
- OSGAYBCDTDRGGQ-UHFFFAOYSA-L calcium sulfate Chemical compound [Ca+2].[O-]S([O-])(=O)=O OSGAYBCDTDRGGQ-UHFFFAOYSA-L 0.000 description 4
- QBWCMBCROVPCKQ-UHFFFAOYSA-M chlorite Chemical compound [O-]Cl=O QBWCMBCROVPCKQ-UHFFFAOYSA-M 0.000 description 4
- 230000002860 competitive effect Effects 0.000 description 4
- 239000002243 precursor Substances 0.000 description 4
- MHAJPDPJQMAIIY-UHFFFAOYSA-N Hydrogen peroxide Chemical compound OO MHAJPDPJQMAIIY-UHFFFAOYSA-N 0.000 description 3
- WMFOQBRAJBCJND-UHFFFAOYSA-M Lithium hydroxide Chemical compound [Li+].[OH-] WMFOQBRAJBCJND-UHFFFAOYSA-M 0.000 description 3
- PMZURENOXWZQFD-UHFFFAOYSA-L Sodium Sulfate Chemical compound [Na+].[Na+].[O-]S([O-])(=O)=O PMZURENOXWZQFD-UHFFFAOYSA-L 0.000 description 3
- -1 hypochlorite anion Chemical class 0.000 description 3
- 238000004806 packaging method and process Methods 0.000 description 3
- 239000011780 sodium chloride Substances 0.000 description 3
- 229910052938 sodium sulfate Inorganic materials 0.000 description 3
- BZSXEZOLBIJVQK-UHFFFAOYSA-N 2-methylsulfonylbenzoic acid Chemical compound CS(=O)(=O)C1=CC=CC=C1C(O)=O BZSXEZOLBIJVQK-UHFFFAOYSA-N 0.000 description 2
- ZKQDCIXGCQPQNV-UHFFFAOYSA-N Calcium hypochlorite Chemical compound [Ca+2].Cl[O-].Cl[O-] ZKQDCIXGCQPQNV-UHFFFAOYSA-N 0.000 description 2
- 230000002378 acidificating effect Effects 0.000 description 2
- 238000003556 assay Methods 0.000 description 2
- 238000001816 cooling Methods 0.000 description 2
- 238000010790 dilution Methods 0.000 description 2
- 239000012895 dilution Substances 0.000 description 2
- 239000007789 gas Substances 0.000 description 2
- QAOWNCQODCNURD-UHFFFAOYSA-M hydrogensulfate Chemical compound OS([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-M 0.000 description 2
- 239000003701 inert diluent Substances 0.000 description 2
- 229940060367 inert ingredients Drugs 0.000 description 2
- 238000009434 installation Methods 0.000 description 2
- KWGKDLIKAYFUFQ-UHFFFAOYSA-M lithium chloride Chemical compound [Li+].[Cl-] KWGKDLIKAYFUFQ-UHFFFAOYSA-M 0.000 description 2
- 231100000252 nontoxic Toxicity 0.000 description 2
- 230000003000 nontoxic effect Effects 0.000 description 2
- 230000001590 oxidative effect Effects 0.000 description 2
- 239000000376 reactant Substances 0.000 description 2
- 150000003839 salts Chemical class 0.000 description 2
- 229910000029 sodium carbonate Inorganic materials 0.000 description 2
- 235000011152 sodium sulphate Nutrition 0.000 description 2
- 238000003860 storage Methods 0.000 description 2
- 238000012360 testing method Methods 0.000 description 2
- 108700024827 HOC1 Proteins 0.000 description 1
- 239000007832 Na2SO4 Substances 0.000 description 1
- 229920001131 Pulp (paper) Polymers 0.000 description 1
- 101100178273 Saccharomyces cerevisiae (strain ATCC 204508 / S288c) HOC1 gene Proteins 0.000 description 1
- 239000005708 Sodium hypochlorite Substances 0.000 description 1
- 239000003619 algicide Substances 0.000 description 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 1
- 230000003115 biocidal effect Effects 0.000 description 1
- 239000007844 bleaching agent Substances 0.000 description 1
- 230000003139 buffering effect Effects 0.000 description 1
- 239000006227 byproduct Substances 0.000 description 1
- 230000008859 change Effects 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 229940077239 chlorous acid Drugs 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 238000000354 decomposition reaction Methods 0.000 description 1
- 239000002781 deodorant agent Substances 0.000 description 1
- 238000010586 diagram Methods 0.000 description 1
- CEJLBZWIKQJOAT-UHFFFAOYSA-N dichloroisocyanuric acid Chemical compound ClN1C(=O)NC(=O)N(Cl)C1=O CEJLBZWIKQJOAT-UHFFFAOYSA-N 0.000 description 1
- 238000004090 dissolution Methods 0.000 description 1
- 230000009977 dual effect Effects 0.000 description 1
- 235000013399 edible fruits Nutrition 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 239000002360 explosive Substances 0.000 description 1
- 239000000446 fuel Substances 0.000 description 1
- 230000007062 hydrolysis Effects 0.000 description 1
- 238000006460 hydrolysis reaction Methods 0.000 description 1
- 239000012535 impurity Substances 0.000 description 1
- 238000010348 incorporation Methods 0.000 description 1
- 238000002347 injection Methods 0.000 description 1
- 239000007924 injection Substances 0.000 description 1
- 229910052500 inorganic mineral Inorganic materials 0.000 description 1
- ZFSLODLOARCGLH-UHFFFAOYSA-N isocyanuric acid Chemical compound OC1=NC(O)=NC(O)=N1 ZFSLODLOARCGLH-UHFFFAOYSA-N 0.000 description 1
- XGZVUEUWXADBQD-UHFFFAOYSA-L lithium carbonate Chemical compound [Li+].[Li+].[O-]C([O-])=O XGZVUEUWXADBQD-UHFFFAOYSA-L 0.000 description 1
- 229910052808 lithium carbonate Inorganic materials 0.000 description 1
- XQHAGELNRSUUGU-UHFFFAOYSA-M lithium chlorate Chemical compound [Li+].[O-]Cl(=O)=O XQHAGELNRSUUGU-UHFFFAOYSA-M 0.000 description 1
- 238000005259 measurement Methods 0.000 description 1
- 239000002906 medical waste Substances 0.000 description 1
- 239000011707 mineral Substances 0.000 description 1
- 150000007522 mineralic acids Chemical class 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 239000003129 oil well Substances 0.000 description 1
- 150000007524 organic acids Chemical class 0.000 description 1
- 235000005985 organic acids Nutrition 0.000 description 1
- 239000011368 organic material Substances 0.000 description 1
- 230000003647 oxidation Effects 0.000 description 1
- 238000007254 oxidation reaction Methods 0.000 description 1
- 239000001301 oxygen Substances 0.000 description 1
- 229910052760 oxygen Inorganic materials 0.000 description 1
- OTYBMLCTZGSZBG-UHFFFAOYSA-L potassium sulfate Chemical compound [K+].[K+].[O-]S([O-])(=O)=O OTYBMLCTZGSZBG-UHFFFAOYSA-L 0.000 description 1
- 229910052939 potassium sulfate Inorganic materials 0.000 description 1
- 235000011151 potassium sulphates Nutrition 0.000 description 1
- 244000144977 poultry Species 0.000 description 1
- 235000013594 poultry meat Nutrition 0.000 description 1
- 239000002244 precipitate Substances 0.000 description 1
- 238000012545 processing Methods 0.000 description 1
- 230000035945 sensitivity Effects 0.000 description 1
- 230000035939 shock Effects 0.000 description 1
- 238000004513 sizing Methods 0.000 description 1
- SUKJFIGYRHOWBL-UHFFFAOYSA-N sodium hypochlorite Chemical compound [Na+].Cl[O-] SUKJFIGYRHOWBL-UHFFFAOYSA-N 0.000 description 1
- GOLXNESZZPUPJE-UHFFFAOYSA-N spiromesifen Chemical compound CC1=CC(C)=CC(C)=C1C(C(O1)=O)=C(OC(=O)CC(C)(C)C)C11CCCC1 GOLXNESZZPUPJE-UHFFFAOYSA-N 0.000 description 1
- 230000000638 stimulation Effects 0.000 description 1
- 239000000725 suspension Substances 0.000 description 1
- 230000002459 sustained effect Effects 0.000 description 1
- 231100000331 toxic Toxicity 0.000 description 1
- 230000002588 toxic effect Effects 0.000 description 1
- 235000013311 vegetables Nutrition 0.000 description 1
- 238000004065 wastewater treatment Methods 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B11/00—Oxides or oxyacids of halogens; Salts thereof
- C01B11/02—Oxides of chlorine
- C01B11/022—Chlorine dioxide (ClO2)
- C01B11/023—Preparation from chlorites or chlorates
- C01B11/024—Preparation from chlorites or chlorates from chlorites
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N59/00—Biocides, pest repellants or attractants, or plant growth regulators containing elements or inorganic compounds
-
- A—HUMAN NECESSITIES
- A23—FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
- A23B—PRESERVING, e.g. BY CANNING, MEAT, FISH, EGGS, FRUIT, VEGETABLES, EDIBLE SEEDS; CHEMICAL RIPENING OF FRUIT OR VEGETABLES; THE PRESERVED, RIPENED, OR CANNED PRODUCTS
- A23B7/00—Preservation or chemical ripening of fruit or vegetables
- A23B7/14—Preserving or ripening with chemicals not covered by groups A23B7/08 or A23B7/10
- A23B7/153—Preserving or ripening with chemicals not covered by groups A23B7/08 or A23B7/10 in the form of liquids or solids
- A23B7/157—Inorganic compounds
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K33/00—Medicinal preparations containing inorganic active ingredients
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K33/00—Medicinal preparations containing inorganic active ingredients
- A61K33/14—Alkali metal chlorides; Alkaline earth metal chlorides
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K33/00—Medicinal preparations containing inorganic active ingredients
- A61K33/40—Peroxides
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F1/00—Treatment of water, waste water, or sewage
- C02F1/72—Treatment of water, waste water, or sewage by oxidation
- C02F1/76—Treatment of water, waste water, or sewage by oxidation with halogens or compounds of halogens
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F2303/00—Specific treatment goals
- C02F2303/04—Disinfection
Abstract
Description
Claims
Priority Applications (4)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CA002423198A CA2423198A1 (en) | 2000-10-12 | 2001-10-01 | Composition for generating chlorine dioxide |
MXPA03002917A MXPA03002917A (en) | 2000-10-12 | 2001-10-01 | Composition for generating chlorine dioxide. |
EP01977308A EP1328156A4 (en) | 2000-10-12 | 2001-10-01 | Composition for generating chlorine dioxide |
AU2001296438A AU2001296438A1 (en) | 2000-10-12 | 2001-10-01 | Composition for generating chlorine dioxide |
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US09/689,236 | 2000-10-12 | ||
US09/689,236 US6602442B1 (en) | 1999-02-25 | 2000-10-12 | Composition for generating chlorine dioxide |
Publications (1)
Publication Number | Publication Date |
---|---|
WO2002030203A1 true WO2002030203A1 (en) | 2002-04-18 |
Family
ID=24767607
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
PCT/US2001/030644 WO2002030203A1 (en) | 2000-10-12 | 2001-10-01 | Composition for generating chlorine dioxide |
Country Status (7)
Country | Link |
---|---|
US (1) | US6602442B1 (en) |
EP (1) | EP1328156A4 (en) |
CN (1) | CN1288981C (en) |
AU (1) | AU2001296438A1 (en) |
CA (1) | CA2423198A1 (en) |
MX (1) | MXPA03002917A (en) |
WO (1) | WO2002030203A1 (en) |
Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO2007024340A2 (en) * | 2005-08-22 | 2007-03-01 | Ecolab Inc. | Oxidation method and compositions therefor |
CN103300063A (en) * | 2013-07-04 | 2013-09-18 | 龚佳郎 | Solid chlorine dioxide release agent |
Families Citing this family (16)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US7695692B2 (en) * | 2003-08-06 | 2010-04-13 | Sanderson William D | Apparatus and method for producing chlorine dioxide |
US7488457B2 (en) * | 2003-10-10 | 2009-02-10 | Halox Technologies, Inc. | Systems and methods for generating chlorine dioxide |
US7476307B2 (en) * | 2003-10-10 | 2009-01-13 | Halox Technologies, Inc. | Systems and methods for generating chlorine dioxide |
US20050249658A1 (en) * | 2004-04-23 | 2005-11-10 | Safe Solid Solutions, Inc. | Solid chlorine dioxide releasing compositions having increased temperature stability and method for delivery of solid chlorine dioxide releasing compositions |
US9446952B2 (en) * | 2005-03-24 | 2016-09-20 | Nalco Company | Batch methods for producing chlorine dioxide solutions |
US20090232903A1 (en) * | 2005-12-16 | 2009-09-17 | Sanderson William D | Biocide compositions |
WO2007078838A2 (en) * | 2005-12-16 | 2007-07-12 | Sanderson William D | Solid biocide composition and sealed biocide article |
US20090028965A1 (en) * | 2007-07-26 | 2009-01-29 | Clinimax Limited | Multi-part disinfectant |
US7666384B2 (en) * | 2008-01-17 | 2010-02-23 | Sanderson William D | Stable chlorine dioxide tablet |
US20130136685A1 (en) | 2011-11-25 | 2013-05-30 | Juan Carlos Baselli | Portable Chlorie Dioxide Generator |
US11279617B2 (en) | 2011-11-25 | 2022-03-22 | Juan Carlos Baselli | Portable chlorine dioxide generator |
US11000041B2 (en) | 2015-08-06 | 2021-05-11 | Int'l Capital Investment Llc | Disinfectant for drinkable water, food contact, industry, spas, swimming pools and air sterilization |
US10512270B2 (en) | 2016-04-01 | 2019-12-24 | Eagle Us 2 Llc | Acid tablet composition and methods of preparing and using the same |
JP7291958B2 (en) * | 2018-04-03 | 2023-06-16 | 三慶株式会社 | Manufacturing method for obtaining novel chlorine oxide composition from degraded hypochlorite |
JP2021080140A (en) * | 2019-11-21 | 2021-05-27 | ネオシーエル カンパニー リミテッド | Chlorine dioxide aqueous solution composition retaining concentration for long terms at ordinary temperature and method for producing the same |
US11572296B1 (en) * | 2020-04-02 | 2023-02-07 | Bio-Cide International, Inc. | Method for extending time of activity of chlorite-based biocides |
Citations (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US4104190A (en) * | 1976-03-23 | 1978-08-01 | Minnesota Mining And Manufacturing Company | Generation of chlorine dioxide for disinfection and sterilization |
US4689169A (en) * | 1983-11-10 | 1987-08-25 | Rio Linda Chemical Company, Inc. | Dry compositions for the production of chlorine dioxide |
US5399288A (en) * | 1992-07-23 | 1995-03-21 | Abic Limited | Solid composition releasing chlorine dioxide |
GB2304706A (en) * | 1995-09-01 | 1997-03-26 | Feedwater Treatment Services L | Generating chlorine dioxide |
Family Cites Families (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE2728170C2 (en) * | 1977-06-23 | 1982-12-09 | Lehmann, Wilfried, 3203 Sarstedt | Process for the preparation of an aqueous solution of chlorine dioxide |
US4234446A (en) * | 1979-10-09 | 1980-11-18 | Kenneth T. Place | Method and apparatus for producing chlorine dioxide |
US4547381A (en) | 1983-11-10 | 1985-10-15 | Rio Linda Chemical Co., Inc. | Dry compositions for the production of chlorine dioxide |
US6197215B1 (en) * | 1999-02-25 | 2001-03-06 | Vulcan Chemicals | Composition for generating chlorine dioxide |
-
2000
- 2000-10-12 US US09/689,236 patent/US6602442B1/en not_active Expired - Fee Related
-
2001
- 2001-10-01 AU AU2001296438A patent/AU2001296438A1/en not_active Abandoned
- 2001-10-01 EP EP01977308A patent/EP1328156A4/en not_active Withdrawn
- 2001-10-01 WO PCT/US2001/030644 patent/WO2002030203A1/en not_active Application Discontinuation
- 2001-10-01 CN CN01816632.6A patent/CN1288981C/en not_active Expired - Fee Related
- 2001-10-01 MX MXPA03002917A patent/MXPA03002917A/en active IP Right Grant
- 2001-10-01 CA CA002423198A patent/CA2423198A1/en not_active Abandoned
Patent Citations (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US4104190A (en) * | 1976-03-23 | 1978-08-01 | Minnesota Mining And Manufacturing Company | Generation of chlorine dioxide for disinfection and sterilization |
US4689169A (en) * | 1983-11-10 | 1987-08-25 | Rio Linda Chemical Company, Inc. | Dry compositions for the production of chlorine dioxide |
US5399288A (en) * | 1992-07-23 | 1995-03-21 | Abic Limited | Solid composition releasing chlorine dioxide |
GB2304706A (en) * | 1995-09-01 | 1997-03-26 | Feedwater Treatment Services L | Generating chlorine dioxide |
Cited By (7)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO2007024340A2 (en) * | 2005-08-22 | 2007-03-01 | Ecolab Inc. | Oxidation method and compositions therefor |
WO2007024340A3 (en) * | 2005-08-22 | 2007-05-31 | Ecolab Inc | Oxidation method and compositions therefor |
CN101247724A (en) * | 2005-08-22 | 2008-08-20 | 埃科莱布有限公司 | Oxidation method and compositions therefor |
US8318231B2 (en) | 2005-08-22 | 2012-11-27 | Ecolab Usa Inc. | Oxidation method and compositions therefor |
CN101247724B (en) * | 2005-08-22 | 2012-12-05 | 埃科莱布有限公司 | Oxidation method and compositions therefor |
EP2543252A1 (en) * | 2005-08-22 | 2013-01-09 | Ecolab Inc. | Oxidation method and compositions therefor |
CN103300063A (en) * | 2013-07-04 | 2013-09-18 | 龚佳郎 | Solid chlorine dioxide release agent |
Also Published As
Publication number | Publication date |
---|---|
CN1288981C (en) | 2006-12-13 |
MXPA03002917A (en) | 2004-12-03 |
US6602442B1 (en) | 2003-08-05 |
CN1482860A (en) | 2004-03-17 |
EP1328156A1 (en) | 2003-07-23 |
CA2423198A1 (en) | 2002-04-18 |
AU2001296438A1 (en) | 2002-04-22 |
EP1328156A4 (en) | 2004-01-14 |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
US6602442B1 (en) | Composition for generating chlorine dioxide | |
EP0847371B1 (en) | Preparation and use of biocidal solutions | |
CN110150315B (en) | Solid high-purity chlorine dioxide releasing agent | |
US4908215A (en) | Hypochlorite compositions containing thiosulfate and use thereof | |
EP1154690B1 (en) | Composition for generating chlorine dioxide | |
JPH0477723B2 (en) | ||
AU2004238859A1 (en) | Preparation of and dispensing chlorine dioxide | |
JPH10182106A (en) | Generation of chlorine dioxide gas and production therefor | |
JPS63246304A (en) | Composition for generating chlorine dioxide gas | |
EP0482811A1 (en) | Chlorous acid solutions | |
JPH10182105A (en) | Kit for preparing chlorine dioxide solution | |
CN111547683A (en) | Reagent, device and method for purification | |
US20240156099A1 (en) | Composition for generation of chlorine dioxide for use as sanitizer | |
JPH11157805A (en) | Production kit for aqueous chlorine dioxide, aqueous chlorine dioxide precursor composition and production of aqueous chlorine dioxide | |
AU2003204430B2 (en) | Preparation and use of biocidal solutions | |
BR102022017218A2 (en) | COMPOSITION FOR GENERATING CHLORINE DIOXIDE FOR USE AS A SANITIZER | |
JP2000263047A (en) | Solid agent for preparing water to be electrolyzed |
Legal Events
Date | Code | Title | Description |
---|---|---|---|
AK | Designated states |
Kind code of ref document: A1 Designated state(s): AE AG AL AM AT AU AZ BA BB BG BR BY BZ CA CH CN CO CR CU CZ DE DK DM DZ EE ES FI GB GD GE GH GM HR HU ID IL IN IS JP KE KG KP KR KZ LC LK LR LS LT LU LV MA MD MG MK MN MW MX MZ NO NZ PL PT RO RU SD SE SG SI SK SL TJ TM TR TT TZ UA UG UZ VN YU ZA ZW |
|
AL | Designated countries for regional patents |
Kind code of ref document: A1 Designated state(s): GH GM KE LS MW MZ SD SL SZ TZ UG ZW AM AZ BY KG KZ MD RU TJ TM AT BE CH CY DE DK ES FI FR GB GR IE IT LU MC NL PT SE TR BF BJ CF CG CI CM GA GN GQ GW ML MR NE SN TD TG |
|
121 | Ep: the epo has been informed by wipo that ep was designated in this application | ||
WWE | Wipo information: entry into national phase |
Ref document number: 2001977308 Country of ref document: EP |
|
WWE | Wipo information: entry into national phase |
Ref document number: 2423198 Country of ref document: CA |
|
WWE | Wipo information: entry into national phase |
Ref document number: 018166326 Country of ref document: CN |
|
WWE | Wipo information: entry into national phase |
Ref document number: PA/a/2003/002917 Country of ref document: MX |
|
WWP | Wipo information: published in national office |
Ref document number: 2001977308 Country of ref document: EP |
|
REG | Reference to national code |
Ref country code: DE Ref legal event code: 8642 |
|
NENP | Non-entry into the national phase |
Ref country code: JP |
|
WWW | Wipo information: withdrawn in national office |
Ref document number: 2001977308 Country of ref document: EP |