WO2002028484A1 - Neutral fire extinguishant and preparation thereof - Google Patents

Neutral fire extinguishant and preparation thereof Download PDF

Info

Publication number
WO2002028484A1
WO2002028484A1 PCT/KR2001/001655 KR0101655W WO0228484A1 WO 2002028484 A1 WO2002028484 A1 WO 2002028484A1 KR 0101655 W KR0101655 W KR 0101655W WO 0228484 A1 WO0228484 A1 WO 0228484A1
Authority
WO
WIPO (PCT)
Prior art keywords
fire
extinguishant
fire extinguishant
solution
specific gravity
Prior art date
Application number
PCT/KR2001/001655
Other languages
French (fr)
Inventor
Seop Gon Chough
Original Assignee
Perfect Korea Co., Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Perfect Korea Co., Ltd filed Critical Perfect Korea Co., Ltd
Priority to AU2001296040A priority Critical patent/AU2001296040A1/en
Publication of WO2002028484A1 publication Critical patent/WO2002028484A1/en

Links

Classifications

    • AHUMAN NECESSITIES
    • A62LIFE-SAVING; FIRE-FIGHTING
    • A62DCHEMICAL MEANS FOR EXTINGUISHING FIRES OR FOR COMBATING OR PROTECTING AGAINST HARMFUL CHEMICAL AGENTS; CHEMICAL MATERIALS FOR USE IN BREATHING APPARATUS
    • A62D1/00Fire-extinguishing compositions; Use of chemical substances in extinguishing fires
    • A62D1/0028Liquid extinguishing substances
    • A62D1/0035Aqueous solutions
    • AHUMAN NECESSITIES
    • A62LIFE-SAVING; FIRE-FIGHTING
    • A62DCHEMICAL MEANS FOR EXTINGUISHING FIRES OR FOR COMBATING OR PROTECTING AGAINST HARMFUL CHEMICAL AGENTS; CHEMICAL MATERIALS FOR USE IN BREATHING APPARATUS
    • A62D1/00Fire-extinguishing compositions; Use of chemical substances in extinguishing fires
    • AHUMAN NECESSITIES
    • A62LIFE-SAVING; FIRE-FIGHTING
    • A62DCHEMICAL MEANS FOR EXTINGUISHING FIRES OR FOR COMBATING OR PROTECTING AGAINST HARMFUL CHEMICAL AGENTS; CHEMICAL MATERIALS FOR USE IN BREATHING APPARATUS
    • A62D1/00Fire-extinguishing compositions; Use of chemical substances in extinguishing fires
    • A62D1/0028Liquid extinguishing substances
    • A62D1/005Dispersions; Emulsions

Definitions

  • the present invention relates, in general, to a fire extinguishant applicable to forest fire as well as ordinary fire and, more particularly, to a neutral fire extinguishant incorrosive of metal containers. Also, the present invention is concerned with a method for preparing a fire-extinguishant that is not corrosive to metal containers.
  • fire extinguishants significantly corrode metal containers with the passage of time. Accordingly, conventional fire extinguishants suffer from the disadvantage of being difficult to store in containers made of metal such as copper, iron or aluminum, which are used in fire engines and helicopters, for a long time of period.
  • the present invention pertains to a fire extinguishant which is neutral in pH so that no oxidative corrosion occurs in metal containers containing it.
  • the fire extinguishant of the present invention is applicable to fire engines or fire- fighting planes which are usually provided with metal tanks for storing fire extinguishants.
  • the fire extinguishant comprises 60 kg of ammonium sulfate ((NH 4 ) 2 SO 4 ), 8 kg of urea (CO(NH 2 ) 2 ), 3 kg of potassium sulfate (K 2 SO 4 ), 2 kg of potassium carbonate (K 2 CO 3 ), 1.5 kg of sodium phosphate (Na 3 PO 4 ), 500 g of an anion surfactant, and 500 g of alum per 100 liters of water.
  • the fire extinguishant of the present invention has a specific gravity of 3.2 and is not frozen at as low as -20 °C. Further, the fire extinguishant of the present invention shows excellent adhesion and penetration properties for wood.
  • the fire extinguishant of the present invention is particularly useful for the extinguishment of forest fire or fire on structures made of wood. Additionally, application of the fire extinguishant to such wooden or other inflammable structures brings about fire prevention effects. Furthermore, upon firing, a fire line can be constructed by applying the fire extinguishant of the present invention. Also, the present invention pertains to the preparation of such a fire extinguishant. To 100 liters of water is added 60 kg of ammonium sulfate ((NH ) 2 SO ) with stirring, to give a solution with a specific gravity of 2.3. Next, 8 kg of urea (CO(NH 2 )2) is dissolved in the solution with stirring to give a solution with a specific gravity of 2.7, followed by the addition of 3 kg of potassium sulfate
  • a neutral fire extinguishant was prepared as follows.
  • fire extinguishants are composed mainly of acidic and/or alkaline compounds, they are apt to corrode metal, suffering from the disadvantage of reducing the lifespan of fire-fighting facilities, particularly metal containers, which are usually mounted onto fire engines and fire-fighting planes.
  • the fire extinguishant of the present invention is neutral in acidity and thus does not corrode its metal containers.
  • the fire extinguishant of the present invention have a specific gravity of 3.2 so that it is not frozen at as low as -20 °C. Further, the fire extinguishant of the present invention shows excellent adhesion and penetration properties for wood.
  • the fire extinguishant of the present invention is effectively used for the extinguishment of forest fire or fire on structures made of wood. Moreover, application of the fire extinguishant to such wooden or other inflammable structures brings about fire prevention effects. Upon firing, a fire line can be constructed by applying the fire extinguishant of the present invention.
  • the present invention has been described in an illustrative manner, and it is to be understood that the terminology used is intended to be in the nature of description rather than of limitation. Many modifications and variations of the present invention are possible in light of the above teachings. Therefore, it is to be understood that within the scope of the appended claims, the invention may be practiced otherwise than as specifically described.

Abstract

Disclosed are a fire extinguishant incorrosive to metal containers and a preparation method thereof. The fire extinguishant is prepared by dissolving 60 kg of ammonium sulfate ((NH4)2SO4) in 100 liters of water, followed by the addition of 8 kg of urea (CO(NH2)2), 3 kg of potassium sulfate (K2SO4), 2 kg of potassium carbonate (K2CO3), 1.5 kg of sodium phosphate (Na3PO4), 500 g of an anion surfactant, and 500 g of alum. In addition to being incorrosive to metal, the fire extinguishant have a specific gravity of 3.2 so that it is not frozen at as low as -20 °C. Further the fire extinguishant shows excellent adhesion and penetration properties for wood, so that it is effectively used for the extinghishment of forest fire or fire on structures made of wood. Additionally, application of the fire extinguishant to such wooden or other inflammable structures brings about fire prevention effects. Upon firing, a fire line can be constructed by applying the fire extinguishant.

Description

NEUTRAL FIRE EXTINGfflSHANT AND PREPARATION THEREOF
BACKGROUND OF THE INVENTION
The present invention relates, in general, to a fire extinguishant applicable to forest fire as well as ordinary fire and, more particularly, to a neutral fire extinguishant incorrosive of metal containers. Also, the present invention is concerned with a method for preparing a fire-extinguishant that is not corrosive to metal containers.
Composed typically of acidic and/or alkaline, fire extinguishants significantly corrode metal containers with the passage of time. Accordingly, conventional fire extinguishants suffer from the disadvantage of being difficult to store in containers made of metal such as copper, iron or aluminum, which are used in fire engines and helicopters, for a long time of period.
Therefore, it is an object of the present invention to solve the problems encountered in prior arts and to provide a novel neutral fire extinguishant which does not corrode metal containers.
It is another object of the present invention to provide a method for preparing such a neutral fire extinguishant.
DESCRIPTION OF THE INVENTION
The present invention pertains to a fire extinguishant which is neutral in pH so that no oxidative corrosion occurs in metal containers containing it. Thus, the fire extinguishant of the present invention is applicable to fire engines or fire- fighting planes which are usually provided with metal tanks for storing fire extinguishants.
In accordance with the present invention, the fire extinguishant comprises 60 kg of ammonium sulfate ((NH4)2SO4), 8 kg of urea (CO(NH2)2), 3 kg of potassium sulfate (K2SO4), 2 kg of potassium carbonate (K2CO3), 1.5 kg of sodium phosphate (Na3PO4), 500 g of an anion surfactant, and 500 g of alum per 100 liters of water. The fire extinguishant of the present invention has a specific gravity of 3.2 and is not frozen at as low as -20 °C. Further, the fire extinguishant of the present invention shows excellent adhesion and penetration properties for wood.
With these advantages, the fire extinguishant of the present invention is particularly useful for the extinguishment of forest fire or fire on structures made of wood. Additionally, application of the fire extinguishant to such wooden or other inflammable structures brings about fire prevention effects. Furthermore, upon firing, a fire line can be constructed by applying the fire extinguishant of the present invention. Also, the present invention pertains to the preparation of such a fire extinguishant. To 100 liters of water is added 60 kg of ammonium sulfate ((NH )2SO ) with stirring, to give a solution with a specific gravity of 2.3. Next, 8 kg of urea (CO(NH2)2) is dissolved in the solution with stirring to give a solution with a specific gravity of 2.7, followed by the addition of 3 kg of potassium sulfate
(K2SO4) to increase the gravity to 2.9. Subsequently, 2 kg of potassium carbonate (K2CO3) is mixed with the solution by stirring to produce a solution with a specific gravity of 3.1. Afterwards, addition of 1.5 kg of sodium phosphate (Na3PO4) gives a solution with a specific gravity of 3.15. Also, 500 g of an anion surfactant is added to produce a solution having a specific gravity of 3.2. Finally, the resulting solution is added with 500 g of alum and subjected to precipitation to obtain the fire extinguishant of the present invention.
EXAMPLE 1
A neutral fire extinguishant was prepared as follows.
First Process
60 kg of ammonium sulfate ((NELι)2SO4) was dissolved in 100 liters of water with stirring to produce a solution with a specific gravity of 2.3.
Second Process
8 kg of urea (CO(NH2)2) was added to the solution of the first process with stirring to produce a solution with a specific gravity of 2.7.
Third Process
3 kg of potassium sulfate (K2SO4) was added to the solution of the second process with stirring to produce a solution with a specific gravity of 2.9.
Fourth Process 2 kg of potassium carbonate (K CO3) was added to the solution of the third process with stirring to produce a solution with a specific gravity of 3.1.
Fifth Process
1.5 kg of sodium phosphate (Na3PO ) was added to the solution of the fourth process with stirring to produce a solution with a specific gravity of 3.15.
Sixth Process 500 g of an anion surfactant was added to the solution of the fifth process with stirring to produce a solution with a specific gravity of 3.2, followed by the addition of 500 g of alum and precipitation.
INDUSTRIAL APPLICABILITY
As described above, because conventional fire extinguishants are composed mainly of acidic and/or alkaline compounds, they are apt to corrode metal, suffering from the disadvantage of reducing the lifespan of fire-fighting facilities, particularly metal containers, which are usually mounted onto fire engines and fire-fighting planes. However, the fire extinguishant of the present invention is neutral in acidity and thus does not corrode its metal containers. In addition, the fire extinguishant of the present invention have a specific gravity of 3.2 so that it is not frozen at as low as -20 °C. Further, the fire extinguishant of the present invention shows excellent adhesion and penetration properties for wood. With these advantages, the fire extinguishant of the present invention is effectively used for the extinguishment of forest fire or fire on structures made of wood. Moreover, application of the fire extinguishant to such wooden or other inflammable structures brings about fire prevention effects. Upon firing, a fire line can be constructed by applying the fire extinguishant of the present invention. The present invention has been described in an illustrative manner, and it is to be understood that the terminology used is intended to be in the nature of description rather than of limitation. Many modifications and variations of the present invention are possible in light of the above teachings. Therefore, it is to be understood that within the scope of the appended claims, the invention may be practiced otherwise than as specifically described.

Claims

1. A fire extinguishant, comprising 60 kg of ammonium sulfate ((NH 2SO4), 8 kg of urea (CO(NH2)2), 3 kg of potassium sulfate (K2SO4), 2 kg of potassium carbonate (K2CO3), 1.5 kg of sodium phosphate (Na3PO4), 500 g of an anion surfactant, and 500 g of alum per 100 liters of water.
2. A method for preparing a fire extinguishant, comprising: adding 60 kg of ammonium sulfate ((NH4)2SO4) in 100 liters of water with stirring to produce a solution with a specific gravity of 2.3; further adding 8 kg of urea (CO(NH2)2) with stirring to produce a solution a specific gravity of 2,7. further adding 3 kg of potassium sulfate (K2SO4) with stirring to produce a solution with a specific gravity of 2.9; further adding 2 kg of potassium carbonate (K2CO3) with stirring to produce a solution with a specific gravity of 3.1; further adding 1.5 kg of sodium phosphate (Na3PO4) with stirring to produce a solution with a specific gravity of 3.15; and further adding 500 g of an anion surfactant with stirring to produce a solution with a specific gravity of 3.2, further adding 500 g of alum, and subjecting the resulting solution to precipitation.
PCT/KR2001/001655 2000-10-05 2001-10-04 Neutral fire extinguishant and preparation thereof WO2002028484A1 (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
AU2001296040A AU2001296040A1 (en) 2000-10-05 2001-10-04 Neutral fire extinguishant and preparation thereof

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
KR1020000058531A KR20020024513A (en) 2000-10-05 2000-10-05 manufacturing method for fire-extinguish
KR2000/58531 2000-10-05

Publications (1)

Publication Number Publication Date
WO2002028484A1 true WO2002028484A1 (en) 2002-04-11

Family

ID=19691972

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/KR2001/001655 WO2002028484A1 (en) 2000-10-05 2001-10-04 Neutral fire extinguishant and preparation thereof

Country Status (3)

Country Link
KR (1) KR20020024513A (en)
AU (1) AU2001296040A1 (en)
WO (1) WO2002028484A1 (en)

Cited By (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB2497820A (en) * 2012-02-23 2013-06-26 Wcm Products Ltd Fire extinguishing composition and delivery apparatus
NL2018405B1 (en) * 2017-02-22 2018-09-17 Ecoxtinguish B V l00% Biodegradable fire extinguishing agent
US11633636B2 (en) 2017-12-02 2023-04-25 Mighty Fire Breaker Llc Wireless neighborhood wildfire defense system network supporting proactive protection of life and property in a neighborhood through GPS-tracking and mapping of environmentally-clean anti-fire (AF) chemical liquid spray applied to the property before wild fires reach the neighborhood
US11826592B2 (en) 2018-01-09 2023-11-28 Mighty Fire Breaker Llc Process of forming strategic chemical-type wildfire breaks on ground surfaces to proactively prevent fire ignition and flame spread, and reduce the production of smoke in the presence of a wild fire
US11865394B2 (en) 2017-12-03 2024-01-09 Mighty Fire Breaker Llc Environmentally-clean biodegradable water-based concentrates for producing fire inhibiting and fire extinguishing liquids for fighting class A and class B fires
US11865390B2 (en) 2017-12-03 2024-01-09 Mighty Fire Breaker Llc Environmentally-clean water-based fire inhibiting biochemical compositions, and methods of and apparatus for applying the same to protect property against wildfire
US11911643B2 (en) 2021-02-04 2024-02-27 Mighty Fire Breaker Llc Environmentally-clean fire inhibiting and extinguishing compositions and products for sorbing flammable liquids while inhibiting ignition and extinguishing fire

Families Citing this family (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR100426347B1 (en) * 2002-01-02 2004-04-06 이왕수 An Environmental Affinity Type Fire Extinguishing Chemicals
KR100540598B1 (en) * 2003-12-03 2006-01-12 (주)코프론케미칼 Manufacturing method of neutral reinforcing composition for extinguishing fire
KR100822720B1 (en) * 2006-06-13 2008-04-17 대한민국 Forest fire extinguishant and manufacturing method
BR112021012212A2 (en) * 2020-01-24 2021-09-08 Jose Roberto Do Carmo FIRE RETARDANT AND BLOCKING COMPOSITION FOR USE IN FOREST FIRE, AND RESULTING PREPARATION PROCESS
CN113350732A (en) * 2021-06-11 2021-09-07 邦威(山西)消防科技发展有限公司 Micro-molecular environment-friendly anti-freezing fire extinguishing agent and preparation method thereof

Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4560485A (en) * 1983-04-21 1985-12-24 Magyar Szenhidrogenipari Kutato-Fejleszto Intezet Fire-fighting powders
US4950410A (en) * 1988-12-30 1990-08-21 United American, Inc. Fire extinguishing compositions and methods
US4971728A (en) * 1987-01-30 1990-11-20 Monsanto Company Method for the preparation of aqueous fire retarding concentrates
US5091097A (en) * 1991-06-05 1992-02-25 Old Firehand Corporation Fire extinguishing and inhibiting material
KR19980033477U (en) * 1996-12-07 1998-09-05 박병재 Magnetic Adsorption Dual Oil Filter
US5820776A (en) * 1997-05-16 1998-10-13 Ansul, Incorporated Combination of a novel fire extinguishing composition employing a eutectic salt mixture and water and a method of using same to extinguish fires

Patent Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4560485A (en) * 1983-04-21 1985-12-24 Magyar Szenhidrogenipari Kutato-Fejleszto Intezet Fire-fighting powders
US4971728A (en) * 1987-01-30 1990-11-20 Monsanto Company Method for the preparation of aqueous fire retarding concentrates
US4950410A (en) * 1988-12-30 1990-08-21 United American, Inc. Fire extinguishing compositions and methods
US5091097A (en) * 1991-06-05 1992-02-25 Old Firehand Corporation Fire extinguishing and inhibiting material
KR19980033477U (en) * 1996-12-07 1998-09-05 박병재 Magnetic Adsorption Dual Oil Filter
US5820776A (en) * 1997-05-16 1998-10-13 Ansul, Incorporated Combination of a novel fire extinguishing composition employing a eutectic salt mixture and water and a method of using same to extinguish fires

Cited By (18)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB2497820A (en) * 2012-02-23 2013-06-26 Wcm Products Ltd Fire extinguishing composition and delivery apparatus
GB2497820B (en) * 2012-02-23 2013-11-27 Wcm Products Ltd Fire-extiguishing compositions and apparatus
NL2018405B1 (en) * 2017-02-22 2018-09-17 Ecoxtinguish B V l00% Biodegradable fire extinguishing agent
US11697040B2 (en) 2017-12-02 2023-07-11 Mighty Fire Breaker Llc Wild fire defense system network using a command center, spraying systems and mobile computing systems configured to proactively defend homes and neighborhoods against threat of wild fire by spraying environmentally-safe anti-fire chemical liquid on property surfaces before presence of wild fire
US11697039B2 (en) 2017-12-02 2023-07-11 Mighty Fire Breaker Llc Wireless communication network, GPS-tracked back-pack spraying systems and command center configured for proactively spraying environmentally-safe anti-fire chemical liquid on property surfaces to inhibit fire ignition and flame spread in the presence of wild fire
US11642555B2 (en) 2017-12-02 2023-05-09 Mighty Fire Breaker Llc Wireless wildfire defense system network for proactively defending homes and neighborhoods against wild fires by spraying environmentally-clean anti-fire chemical liquid on property and buildings and forming GPS-tracked and mapped chemical fire breaks about the property
US11654313B2 (en) 2017-12-02 2023-05-23 Mighty Fire Breaker Llc Wireless communication network, GPS-tracked ground-based spraying tanker vehicles and command center configured for proactively spraying environmentally-safe anti-fire chemical liquid on property surfaces to inhibit fire ignition and flame spread in the presence of wild fire
US11654314B2 (en) 2017-12-02 2023-05-23 Mighty Fire Breaker Llc Method of managing the proactive spraying of environment ally-clean anti-fire chemical liquid on GPS-specified property surfaces so as to inhibit fire ignition and flame spread in the presence of wild fire
US11633636B2 (en) 2017-12-02 2023-04-25 Mighty Fire Breaker Llc Wireless neighborhood wildfire defense system network supporting proactive protection of life and property in a neighborhood through GPS-tracking and mapping of environmentally-clean anti-fire (AF) chemical liquid spray applied to the property before wild fires reach the neighborhood
US11697041B2 (en) 2017-12-02 2023-07-11 Mighty Fire Breaker Llc Method of proactively defending combustible property against fire ignition and flame spread in the presence of wild fire
US11638844B2 (en) 2017-12-02 2023-05-02 Mighty Fire Breaker Llc Method of proactively protecting property from wild fire by spraying environmentally-clean anti-fire chemical liquid on property surfaces prior to wild fire arrival using remote sensing and GPS-tracking and mapping enabled spraying
US11707639B2 (en) 2017-12-02 2023-07-25 Mighty Fire Breaker Llc Wireless communication network, GPS-tracked mobile spraying systems, and a command system configured for proactively spraying environmentally-safe anti-fire chemical liquid on combustible property surfaces to protect property against fire ignition and flame spread in the presence of wild fire
US11730987B2 (en) 2017-12-02 2023-08-22 Mighty Fire Breaker Llc GPS tracking and mapping wildfire defense system network for proactively defending homes and neighborhoods against threat of wild fire by spraying environmentally-safe anti-fire chemical liquid on property surfaces to inhibit fire ignition and flame spread in the presence of wild fire
US11794044B2 (en) 2017-12-02 2023-10-24 Mighty Fire Breaker Llc Method of proactively forming and maintaining GPS-tracked and mapped environmentally-clean chemical firebreaks and fire protection zones that inhibit fire ignition and flame spread in the presence of wild fire
US11865394B2 (en) 2017-12-03 2024-01-09 Mighty Fire Breaker Llc Environmentally-clean biodegradable water-based concentrates for producing fire inhibiting and fire extinguishing liquids for fighting class A and class B fires
US11865390B2 (en) 2017-12-03 2024-01-09 Mighty Fire Breaker Llc Environmentally-clean water-based fire inhibiting biochemical compositions, and methods of and apparatus for applying the same to protect property against wildfire
US11826592B2 (en) 2018-01-09 2023-11-28 Mighty Fire Breaker Llc Process of forming strategic chemical-type wildfire breaks on ground surfaces to proactively prevent fire ignition and flame spread, and reduce the production of smoke in the presence of a wild fire
US11911643B2 (en) 2021-02-04 2024-02-27 Mighty Fire Breaker Llc Environmentally-clean fire inhibiting and extinguishing compositions and products for sorbing flammable liquids while inhibiting ignition and extinguishing fire

Also Published As

Publication number Publication date
AU2001296040A1 (en) 2002-04-15
KR20020024513A (en) 2002-03-30

Similar Documents

Publication Publication Date Title
EP2059308B1 (en) Flame retardant composition
WO2002028484A1 (en) Neutral fire extinguishant and preparation thereof
US4168983A (en) Phosphate coating composition
EP2173836B1 (en) Flame retardant composition
US20030212177A1 (en) Use of biopolymer thickened fire retardant compositions to suppress fires
KR950004234B1 (en) Corrosion resistant aluminum coating composition
US3309324A (en) Corrosion inhibited ammonium sulfate solutions and compositions useful for manufacturing them
US4176071A (en) Corrosion inhibitor mixture for ammonium sulfate fire-retardant compositions and method for inhibiting corrosivity of such compositions
US3293189A (en) Corrosion-inhibited phosphate solutions and compositions useful for manufacturing them
AU2003203283B2 (en) Fire retardant compositions containing metal ferrites for reduced corrosivity
NO117957B (en)
US3223649A (en) Corrosion-inhibited phosphate solutions and compositions useful for manufacturing them
US3338829A (en) Corrosion-inhibited ammonium orthophosphate solutions and compositions useful for manufacturing them
US4151098A (en) Acidizing subterranean well formations containing deposits of metal compounds
US8202449B2 (en) Corrosion-inhibited ammonium polyphosphate fire retardant compositions
CA2234038C (en) Stabilized, corrosion-inhibited fire retardant compositions and methods
GB1591039A (en) Processes and compositions for coating metal surfaces
US3364149A (en) Corrosion-inhibited phosphate solutions and compositions useful for manufacturing them
US2855286A (en) Process and composition for reducing corrosion of metals
GB2137231A (en) Phosphate coating processes
AU708141B2 (en) Zinc phosphatizing using low concentrations of copper and manganese
US4126469A (en) Solution and procedure for depositing a protective precoating on surfaces of zinc-coated ferrous metal parts against corrosion in presence of water
US3088819A (en) Process and composition for reducing corrosion of aluminum metals
CA2570414A1 (en) Formulation and method for chlorinating recreational water
JPS605056A (en) Rust preventing gypsum composition

Legal Events

Date Code Title Description
AK Designated states

Kind code of ref document: A1

Designated state(s): AE AG AL AM AT AU AZ BA BB BG BR BY BZ CA CH CN CO CR CU CZ DE DK DM DZ EC EE ES FI GB GD GE GH GM HR HU ID IL IN IS JP KE KG KP KR KZ LC LK LR LS LT LU LV MA MD MG MK MN MW MX MZ NO NZ PL PT RO RU SD SE SG SI SK SL TJ TM TR TT TZ UA UG US UZ VN YU ZA ZW

AL Designated countries for regional patents

Kind code of ref document: A1

Designated state(s): GH GM KE LS MW MZ SD SL SZ TZ UG ZW AM AZ BY KG KZ MD RU TJ TM AT BE CH CY DE DK ES FI FR GB GR IE IT LU MC NL PT SE TR BF BJ CF CG CI CM GA GN GQ GW ML MR NE SN TD TG

DFPE Request for preliminary examination filed prior to expiration of 19th month from priority date (pct application filed before 20040101)
121 Ep: the epo has been informed by wipo that ep was designated in this application
REG Reference to national code

Ref country code: DE

Ref legal event code: 8642

122 Ep: pct application non-entry in european phase
NENP Non-entry into the national phase

Ref country code: JP