WO2002018047A3 - Gold containing carbonylation catalyst and use thereof - Google Patents

Gold containing carbonylation catalyst and use thereof Download PDF

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Publication number
WO2002018047A3
WO2002018047A3 PCT/ZA2001/000131 ZA0100131W WO0218047A3 WO 2002018047 A3 WO2002018047 A3 WO 2002018047A3 ZA 0100131 W ZA0100131 W ZA 0100131W WO 0218047 A3 WO0218047 A3 WO 0218047A3
Authority
WO
WIPO (PCT)
Prior art keywords
catalyst
carbonylation catalyst
gold
gold containing
carbonylation
Prior art date
Application number
PCT/ZA2001/000131
Other languages
French (fr)
Other versions
WO2002018047A2 (en
Inventor
Bongani Simon Nkosi
Yvette Michelle Terblans
Original Assignee
Sasol Tech Pty Ltd
Bongani Simon Nkosi
Yvette Michelle Terblans
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Sasol Tech Pty Ltd, Bongani Simon Nkosi, Yvette Michelle Terblans filed Critical Sasol Tech Pty Ltd
Priority to AU2001293318A priority Critical patent/AU2001293318A1/en
Publication of WO2002018047A2 publication Critical patent/WO2002018047A2/en
Publication of WO2002018047A3 publication Critical patent/WO2002018047A3/en

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Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F9/00—Compounds containing elements of Groups 5 or 15 of the Periodic Table
    • C07F9/02—Phosphorus compounds
    • C07F9/28—Phosphorus compounds with one or more P—C bonds
    • C07F9/50—Organo-phosphines
    • C07F9/5045—Complexes or chelates of phosphines with metallic compounds or metals
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/24—Phosphines, i.e. phosphorus bonded to only carbon atoms, or to both carbon and hydrogen atoms, including e.g. sp2-hybridised phosphorus compounds such as phosphabenzene, phosphole or anionic phospholide ligands
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/24—Phosphines, i.e. phosphorus bonded to only carbon atoms, or to both carbon and hydrogen atoms, including e.g. sp2-hybridised phosphorus compounds such as phosphabenzene, phosphole or anionic phospholide ligands
    • B01J31/2404—Cyclic ligands, including e.g. non-condensed polycyclic ligands, the phosphine-P atom being a ring member or a substituent on the ring
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/24—Phosphines, i.e. phosphorus bonded to only carbon atoms, or to both carbon and hydrogen atoms, including e.g. sp2-hybridised phosphorus compounds such as phosphabenzene, phosphole or anionic phospholide ligands
    • B01J31/2404—Cyclic ligands, including e.g. non-condensed polycyclic ligands, the phosphine-P atom being a ring member or a substituent on the ring
    • B01J31/2409—Cyclic ligands, including e.g. non-condensed polycyclic ligands, the phosphine-P atom being a ring member or a substituent on the ring with more than one complexing phosphine-P atom
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
    • C07C45/49—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reaction with carbon monoxide
    • C07C45/50—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reaction with carbon monoxide by oxo-reactions
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F1/00—Compounds containing elements of Groups 1 or 11 of the Periodic Table
    • C07F1/005—Compounds containing elements of Groups 1 or 11 of the Periodic Table without C-Metal linkages
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2231/00—Catalytic reactions performed with catalysts classified in B01J31/00
    • B01J2231/30—Addition reactions at carbon centres, i.e. to either C-C or C-X multiple bonds
    • B01J2231/32—Addition reactions to C=C or C-C triple bonds
    • B01J2231/321—Hydroformylation, metalformylation, carbonylation or hydroaminomethylation
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2231/00—Catalytic reactions performed with catalysts classified in B01J31/00
    • B01J2231/50—Redistribution or isomerisation reactions of C-C, C=C or C-C triple bonds
    • B01J2231/52—Isomerisation reactions
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/10—Complexes comprising metals of Group I (IA or IB) as the central metal
    • B01J2531/18—Gold

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Inorganic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Health & Medical Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Biochemistry (AREA)
  • General Health & Medical Sciences (AREA)
  • Molecular Biology (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Catalysts (AREA)

Abstract

The invention provides a carbonylation catalyst for carbonylating olefins, said catalyst containing an organometallic complex containing gold metal. The catalyst may be in an unsupported homogeneous form. The organometallic gold complex containing gold metal may be a monometallic gold complex. The carbonylation catalyst may be a hydroformylation catalyst for hydroformylating olefins to aldehydes. The invention also provides a carbonylation process using said catalyst.
PCT/ZA2001/000131 2000-09-01 2001-08-31 Gold containing carbonylation catalyst and use thereof WO2002018047A2 (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
AU2001293318A AU2001293318A1 (en) 2000-09-01 2001-08-31 Carbonylation catalyst

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
ZA2000/4589 2000-09-01
ZA200004589 2000-09-01

Publications (2)

Publication Number Publication Date
WO2002018047A2 WO2002018047A2 (en) 2002-03-07
WO2002018047A3 true WO2002018047A3 (en) 2002-06-13

Family

ID=25588890

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/ZA2001/000131 WO2002018047A2 (en) 2000-09-01 2001-08-31 Gold containing carbonylation catalyst and use thereof

Country Status (2)

Country Link
AU (1) AU2001293318A1 (en)
WO (1) WO2002018047A2 (en)

Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0668287A2 (en) * 1988-12-02 1995-08-23 Hoechst Aktiengesellschaft Sulfonated phenyl phosphine-containing complexes
WO1997021648A1 (en) * 1995-12-13 1997-06-19 Basf Aktiengesellschaft Process for catalytic addition of nucleophiles to alkines or allenes

Patent Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0668287A2 (en) * 1988-12-02 1995-08-23 Hoechst Aktiengesellschaft Sulfonated phenyl phosphine-containing complexes
WO1997021648A1 (en) * 1995-12-13 1997-06-19 Basf Aktiengesellschaft Process for catalytic addition of nucleophiles to alkines or allenes

Non-Patent Citations (2)

* Cited by examiner, † Cited by third party
Title
CHENG-GUO JIA ET AL.: "Preparation and catalytic properties of polymer-supported Fe-Co-Cu and Fe-Co-Au pentametallic clusters", REACTIVE POLYMERS, vol. 18, no. 3, 1992, ELSEVIER SCIENCE PUBLISHERS, AMSTERDAM, NL, pages 203 - 211, XP002194470, ISSN: 0923-1137 *
G.N. ILINICH ET AL.: "Reactive properties of phosphine complexes of some transition metals in ethylene carbonylation", REACTION KINETICS AND CATALYSIS LETTERS., vol. 31, no. 1, 1986, ELSEVIER, AMSTERDAM., NL, pages 61 - 64, XP008001903, ISSN: 0133-1736 *

Also Published As

Publication number Publication date
AU2001293318A1 (en) 2002-03-13
WO2002018047A2 (en) 2002-03-07

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