WO2002014640A1 - Double glazing - Google Patents

Double glazing Download PDF

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Publication number
WO2002014640A1
WO2002014640A1 PCT/GB2001/003579 GB0103579W WO0214640A1 WO 2002014640 A1 WO2002014640 A1 WO 2002014640A1 GB 0103579 W GB0103579 W GB 0103579W WO 0214640 A1 WO0214640 A1 WO 0214640A1
Authority
WO
WIPO (PCT)
Prior art keywords
glass
frit
double glazing
sheets
glazing unit
Prior art date
Application number
PCT/GB2001/003579
Other languages
French (fr)
Inventor
Anthony John Cooper
Ingemar V. Rodriguez
Original Assignee
Anthony John Cooper
Rodriguez Ingemar V
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Anthony John Cooper, Rodriguez Ingemar V filed Critical Anthony John Cooper
Priority to AU2001282271A priority Critical patent/AU2001282271A1/en
Publication of WO2002014640A1 publication Critical patent/WO2002014640A1/en

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Classifications

    • EFIXED CONSTRUCTIONS
    • E06DOORS, WINDOWS, SHUTTERS, OR ROLLER BLINDS IN GENERAL; LADDERS
    • E06BFIXED OR MOVABLE CLOSURES FOR OPENINGS IN BUILDINGS, VEHICLES, FENCES OR LIKE ENCLOSURES IN GENERAL, e.g. DOORS, WINDOWS, BLINDS, GATES
    • E06B3/00Window sashes, door leaves, or like elements for closing wall or like openings; Layout of fixed or moving closures, e.g. windows in wall or like openings; Features of rigidly-mounted outer frames relating to the mounting of wing frames
    • E06B3/66Units comprising two or more parallel glass or like panes permanently secured together
    • E06B3/663Elements for spacing panes
    • E06B3/66309Section members positioned at the edges of the glazing unit
    • E06B3/66333Section members positioned at the edges of the glazing unit of unusual substances, e.g. wood or other fibrous materials, glass or other transparent materials
    • EFIXED CONSTRUCTIONS
    • E06DOORS, WINDOWS, SHUTTERS, OR ROLLER BLINDS IN GENERAL; LADDERS
    • E06BFIXED OR MOVABLE CLOSURES FOR OPENINGS IN BUILDINGS, VEHICLES, FENCES OR LIKE ENCLOSURES IN GENERAL, e.g. DOORS, WINDOWS, BLINDS, GATES
    • E06B3/00Window sashes, door leaves, or like elements for closing wall or like openings; Layout of fixed or moving closures, e.g. windows in wall or like openings; Features of rigidly-mounted outer frames relating to the mounting of wing frames
    • E06B3/66Units comprising two or more parallel glass or like panes permanently secured together
    • E06B3/673Assembling the units
    • E06B3/67326Assembling spacer elements with the panes
    • EFIXED CONSTRUCTIONS
    • E06DOORS, WINDOWS, SHUTTERS, OR ROLLER BLINDS IN GENERAL; LADDERS
    • E06BFIXED OR MOVABLE CLOSURES FOR OPENINGS IN BUILDINGS, VEHICLES, FENCES OR LIKE ENCLOSURES IN GENERAL, e.g. DOORS, WINDOWS, BLINDS, GATES
    • E06B3/00Window sashes, door leaves, or like elements for closing wall or like openings; Layout of fixed or moving closures, e.g. windows in wall or like openings; Features of rigidly-mounted outer frames relating to the mounting of wing frames
    • E06B3/66Units comprising two or more parallel glass or like panes permanently secured together
    • E06B3/673Assembling the units
    • E06B3/67339Working the edges of already assembled units
    • E06B3/6736Heat treatment

Definitions

  • the present invention relates to double glazing.
  • a double glazed window two sheets of glass are arranged parallel to each other with a narrow gap therebetween.
  • a peripheral seal is provided for trapping gas between the panes, to prevent flow of gas degrading the heat transfer, i.e insulation, properties of the assembly, referred to as a doubling glazing unit.
  • a problem with present double glazing units is that the seal can leak, allowing the ingress of moisture. This can then condense on the inside of the glass, interfering with the transparency of the unit.
  • the object of the present invention is to provide an improved double glazing unit with an improved seal.
  • a double glazing unit of the invention comprises two parallel sheets of glass peripherally sealed to each other, the seal being of fused glass frit.
  • Glass frit is comminuted glass and a binder.
  • the binder is carried in a solvent, whereby the frit can be tape cast in continuous lengths either for subsequent positioning or in situ or screen printed.
  • the binder is driven off.
  • the frit can be heated to higher temperature for fusing it to a substrate on which it is carried.
  • our preferred method of fusing the frit is by laser irradiation. However, we anticipate that it will prove possible to fuse the frit by heating the entire unit in an oven to the frit fusing temperature.
  • the frit is of coloured glass, whereby it absorbs heat on irradiation.
  • the frit is chosen to have substantially the same coefficient of thermal expansion - CTE - as that of the glass to be sealed.
  • the softening point of the glass of the frit is preferably markedly less than that of the glass to be sealed, for example 250°C as against 500°C.
  • the degree of preheat of the glass is preferably maintained below the temper firing temperature, whereby the surface compressive stresses induced to strength the glass on tempering are not relieved, at least in the bulk of the glass.
  • the temper firing temperature is of the order of 500 to 600°C for a glass with a softening temperature of 750°C.
  • a method of producing a double glazing unit comprising two parallel sheets of glass peripherally sealed to each other, consisting in the steps of:
  • the sheets are preheated to close to the frit fusing temperature, whereby the energy supplied by the laser is only that required to raise the temperature of the frit locally to its fusing temperature from the preheat temperature.
  • the degree of preheat of the glass is maintained below the temper firing temperature of the glass, whereby the surface compressive stresses induced to strength the glass on tempering are not relieved, at least in the bulk of the glass.
  • the sealed unit is cooled in a controlled manner.
  • the laser irradiation will be carried out in a dry, inert atmosphere whereby such an atmosphere is enclosed within the double glazing unit.
  • the frit can be preliminarily tape cast and positioned on the glass in continuous lengths. Alternatively, it can be positioned by tape casting direct onto the first sheet of glass. Again, the frit can be positioned by screen printing onto the first sheet of glass.
  • the frit is preliminarily heated to drive off its binder, prior to positioning of the other sheet of glass on it.
  • a double glazing sealing machine comprising: a frit application station for applying frit peripherally to a glass sheet to form one side of a double glazing unit; an assembly station for assembling the double glazing unit from the two glass sheets on top of each other with the frit between them; a preheating station for preheating the assembled pairs of sheets; a laser irradiation station for fusing the frit to seal the sheets to each other; and a cooling station for cooling the sealed units to room temperature.
  • Figure 1 is a perspective view of a double glazing unit of the invention
  • Figure 2 is a scrap cross-sectional view of an edge portion of the unit of Figure 1;
  • Figure 3 is a similar scrap view of the frit in the edge portion being irradiated;
  • Figure 4 is an exploded view of the double glazing unit of Figure 1;
  • Figure 5 is a diagrammatic view of a line for producing the double glazing units of Figure 1;
  • Figure 6(i.) is a diagrammatic view of an assembly station and a preheating station of a sealing machine for producing Figure 1 units;
  • Figure 6(ii.) is a diagrammatic view of laser irradiation station and a cooling station of the sealing machine.
  • Figure 7 is a plane view of an alternative frit arrangement.
  • the double glazing unit of Figures 1 and 2 has a pair of glass sheets 1,2, with a frit seal 3 therebetween, the frit seal being fused to both sheets and extending around the periphery of the unit.
  • the frit seal is fused by irradiation with light 4 from a laser.
  • the frit is of brown glass, whereby it readily absorbs heat on laser irradiation.
  • the precise colour adapting the frit to absorb maximum light energy is dependent on the wave length of the laser light.
  • the laser used for fusing these frits was an Optopower CW diode Laser with fibre delivery and having a power of 60 watts at 830 nm wavelength. Whilst we have satisfactorily fused these frits with this laser, we expect other frits and lasers to be suitable.
  • the frit seal is formed of a rectangle 11 of tape cast frit material.
  • Tape casting is a process well known in the electronics component industry, whereby a slurry of frit material is continuously cast onto a substrate.
  • the binder is mobile due to the presence of the solvent, whereby the comminuted glass can be positioned on the substrate which normally moves continuously away from an orifice whence the frit material is extruded. It passes beneath a so called “doctor blade", which is accurately spaced from the substrate, whereby the frit is formed to an controlled, even thickness.
  • the frit has coherence for handling. In particular it can be cut into lengths for use.
  • frit can also be cast on a disposable laminate from which it can be peeled for use. In this configuration, it can be stamped to shape for use. Prior to fusing, as by laser irradiation, the frit is referred to as "green". Tape casting of frit and its handling in green form is believed to be within the capabilities of the skilled reader of this specification and will not be described further.
  • the stamped rectangles 11 of green, tape cast frit is placed on the lower sheets of glass 2 carried by a conveyor 21 moving in the direction F.
  • the conveyor has a number of frames 22 with upstanding fingers 23 for locating upper and lower sheets.
  • Upper sheets 1 are lowered onto the frit and lower sheets 2 at an assembly station A, by means of suckers 24.
  • the sheets and the frit are radiantly heated by ohmic heaters 25 to close to the frit fusing temperature.
  • one of the upper sheets are still held slightly clear of the frit by the suckers 24, to allow volatile material from the frit binder to be dissipated and for inert gas G to be introduced between the sheets.
  • the sheets are not heated bodily above the temper firing temperature of the glass, to avoid loss of the strengthening of the glass.
  • a laser 26 is traversed around the frit, to fuse it together and to the two glass sheets, thereby sealing the unit.
  • the laser locally raises the frit temperature above its melting point, but the average temperature of the unit remains below it.
  • the sealed unit is passed on to a cooling station C, where a fan 27 blows cool air 28 onto the unit at a controlled rate so that the unit is evenly cooled to avoid build up of thermal stresses in the unit and raising of the temperature of the body of the glass above its temper firing temperature.
  • the frit can be screen printed to either or both sheets, the latter being preferable to enhance the separation of the sheets by the fused frit.
  • More than one laser may be used at once to enhance the speed of fusing.
  • the second laser may operate from below. This is particularly appropriate where three sheets are being united with two frit seals, the one on top of the middle sheet being irradiated from above and the one below from below.

Landscapes

  • Engineering & Computer Science (AREA)
  • Civil Engineering (AREA)
  • Structural Engineering (AREA)
  • Joining Of Glass To Other Materials (AREA)

Abstract

A double glazing unit has a pair of glass sheets (1, 2), with a frit seal (3) therebetween, the frit seal being fused to both sheets and extending around the periphery of the unit. The frit seal is fused by irradiation with light 4 from a laser. Typically, the frit is of brown glass, whereby it readily absorbs heat on laser irradiation.

Description

DOUBLE GLAZING
The present invention relates to double glazing.
This application claims priority from the following US provisional patent applications:
Application No. 60/224949, dated 11th August 2000 and Application No. 60/238269, dated 5th October 2000.
In a double glazed window, two sheets of glass are arranged parallel to each other with a narrow gap therebetween. A peripheral seal is provided for trapping gas between the panes, to prevent flow of gas degrading the heat transfer, i.e insulation, properties of the assembly, referred to as a doubling glazing unit.
A problem with present double glazing units is that the seal can leak, allowing the ingress of moisture. This can then condense on the inside of the glass, interfering with the transparency of the unit.
The object of the present invention is to provide an improved double glazing unit with an improved seal.
A double glazing unit of the invention comprises two parallel sheets of glass peripherally sealed to each other, the seal being of fused glass frit.
Glass frit is comminuted glass and a binder. The binder is carried in a solvent, whereby the frit can be tape cast in continuous lengths either for subsequent positioning or in situ or screen printed. On heating, the binder is driven off. The frit can be heated to higher temperature for fusing it to a substrate on which it is carried.
Our preferred method of fusing the frit is by laser irradiation. However, we anticipate that it will prove possible to fuse the frit by heating the entire unit in an oven to the frit fusing temperature. In accordance with a preferred feature, the frit is of coloured glass, whereby it absorbs heat on irradiation.
It should be noted that certain double glazing units have three sheets of glass, in effect forming triple glazing units. The invention is equally as applicable to production of triple glazing units as double glazing units.
In accordance with another preferred feature of the invention, the frit is chosen to have substantially the same coefficient of thermal expansion - CTE - as that of the glass to be sealed. On the other hand, the softening point of the glass of the frit is preferably markedly less than that of the glass to be sealed, for example 250°C as against 500°C.
Further, the degree of preheat of the glass is preferably maintained below the temper firing temperature, whereby the surface compressive stresses induced to strength the glass on tempering are not relieved, at least in the bulk of the glass. Typically, the temper firing temperature is of the order of 500 to 600°C for a glass with a softening temperature of 750°C.
In accordance with another aspect of the invention, there is provided: a method of producing a double glazing unit comprising two parallel sheets of glass peripherally sealed to each other, consisting in the steps of:
• applying the frit to one of the sheets of glass,
• positioning the other sheet of glass over the first sheet on the frit and • locally heating the frit to fusing temperature by traversing it with laser irradiation, whereby the two sheets of glass become peripherally sealed together.
Preferably, the sheets are preheated to close to the frit fusing temperature, whereby the energy supplied by the laser is only that required to raise the temperature of the frit locally to its fusing temperature from the preheat temperature. Again, preferably the degree of preheat of the glass is maintained below the temper firing temperature of the glass, whereby the surface compressive stresses induced to strength the glass on tempering are not relieved, at least in the bulk of the glass.
Subsequent to irradiation, the sealed unit is cooled in a controlled manner.
Normally, the laser irradiation will be carried out in a dry, inert atmosphere whereby such an atmosphere is enclosed within the double glazing unit.
The frit can be preliminarily tape cast and positioned on the glass in continuous lengths. Alternatively, it can be positioned by tape casting direct onto the first sheet of glass. Again, the frit can be positioned by screen printing onto the first sheet of glass.
Normally, the frit is preliminarily heated to drive off its binder, prior to positioning of the other sheet of glass on it.
According to a third aspect of the invention, there is provided a double glazing sealing machine comprising: a frit application station for applying frit peripherally to a glass sheet to form one side of a double glazing unit; an assembly station for assembling the double glazing unit from the two glass sheets on top of each other with the frit between them; a preheating station for preheating the assembled pairs of sheets; a laser irradiation station for fusing the frit to seal the sheets to each other; and a cooling station for cooling the sealed units to room temperature.
To help understanding of the present invention, a specific embodiment thereof will now be described by way of example and with reference to the accompanying drawings, in which:
Figure 1 is a perspective view of a double glazing unit of the invention;
Figure 2 is a scrap cross-sectional view of an edge portion of the unit of Figure 1; Figure 3 is a similar scrap view of the frit in the edge portion being irradiated;
Figure 4 is an exploded view of the double glazing unit of Figure 1;
Figure 5 is a diagrammatic view of a line for producing the double glazing units of Figure 1;
Figure 6(i.) is a diagrammatic view of an assembly station and a preheating station of a sealing machine for producing Figure 1 units;
Figure 6(ii.) is a diagrammatic view of laser irradiation station and a cooling station of the sealing machine; and
Figure 7 is a plane view of an alternative frit arrangement.
The double glazing unit of Figures 1 and 2 has a pair of glass sheets 1,2, with a frit seal 3 therebetween, the frit seal being fused to both sheets and extending around the periphery of the unit.
As shown in Figure 3, the frit seal is fused by irradiation with light 4 from a laser. Typically, the frit is of brown glass, whereby it readily absorbs heat on laser irradiation. The precise colour adapting the frit to absorb maximum light energy is dependent on the wave length of the laser light.
Two frits which have been used satisfactorily are Nos 75-10052-25 and 75-
10052-26 from Emca-Remex/Ferro. These are dark brown and dark green in colour. The laser used for fusing these frits was an Optopower CW diode Laser with fibre delivery and having a power of 60 watts at 830 nm wavelength. Whilst we have satisfactorily fused these frits with this laser, we expect other frits and lasers to be suitable.
Referring to Figure 4, the frit seal is formed of a rectangle 11 of tape cast frit material. Tape casting is a process well known in the electronics component industry, whereby a slurry of frit material is continuously cast onto a substrate. During casting, the binder is mobile due to the presence of the solvent, whereby the comminuted glass can be positioned on the substrate which normally moves continuously away from an orifice whence the frit material is extruded. It passes beneath a so called "doctor blade", which is accurately spaced from the substrate, whereby the frit is formed to an controlled, even thickness. When the solvent has evaporated, the frit has coherence for handling. In particular it can be cut into lengths for use. It can also be cast on a disposable laminate from which it can be peeled for use. In this configuration, it can be stamped to shape for use. Prior to fusing, as by laser irradiation, the frit is referred to as "green". Tape casting of frit and its handling in green form is believed to be within the capabilities of the skilled reader of this specification and will not be described further.
As shown in Figure 5, 6(i.) & 6(ii.), the stamped rectangles 11 of green, tape cast frit is placed on the lower sheets of glass 2 carried by a conveyor 21 moving in the direction F. The conveyor has a number of frames 22 with upstanding fingers 23 for locating upper and lower sheets. Upper sheets 1 are lowered onto the frit and lower sheets 2 at an assembly station A, by means of suckers 24.
At the next, preheat station P, the sheets and the frit are radiantly heated by ohmic heaters 25 to close to the frit fusing temperature. At this stage, one of the upper sheets are still held slightly clear of the frit by the suckers 24, to allow volatile material from the frit binder to be dissipated and for inert gas G to be introduced between the sheets. The sheets are not heated bodily above the temper firing temperature of the glass, to avoid loss of the strengthening of the glass.
At the laser station L, shown in Figure 6(ii.), a laser 26 is traversed around the frit, to fuse it together and to the two glass sheets, thereby sealing the unit. The laser locally raises the frit temperature above its melting point, but the average temperature of the unit remains below it.
The sealed unit is passed on to a cooling station C, where a fan 27 blows cool air 28 onto the unit at a controlled rate so that the unit is evenly cooled to avoid build up of thermal stresses in the unit and raising of the temperature of the body of the glass above its temper firing temperature.
The invention is not intended to be restricted to the details of the above described embodiment. In place of use of a stamped rectangle of green tape, as shown in Figure 7, individual lengths 111,112,113,114 of tape cast frit can be assembled onto the lower sheet 102 prior to addition of the upper sheet. Particular attention should be paid to abutment of individual lengths at the corners, so that on fusing, the corners as well as the sides are gas tight.
Again, the frit can be screen printed to either or both sheets, the latter being preferable to enhance the separation of the sheets by the fused frit.
More than one laser may be used at once to enhance the speed of fusing. The second laser may operate from below. This is particularly appropriate where three sheets are being united with two frit seals, the one on top of the middle sheet being irradiated from above and the one below from below.

Claims

CLAIMS:
1. A double glazing unit comprising two parallel sheets of glass peripherally sealed to each other, the seal being of fused glass frit.
2. A double glazing unit as claimed in claim 1, wherein the frit is of coloured glass, whereby it absorbs heat on irradiation for sealing.
3. A double glazing unit as claimed in claim 1 or claim 2, wherein the unit comprises three or more parallel sheets of glass peripherally sealed to each other by fused glass frit.
4. A double glazing unit as claimed in claim 1, claim 2 or claim 3, wherein the frit has substantially the same coefficient of thermal expansion as that of the glass to be sealed.
5. A double glazing unit as claimed in any preceding claim, wherein the glass of the frit has a softening point less than that of the glass to be sealed.
6. A method of producing a double glazing unit comprising two parallel sheets of glass peripherally sealed to each other, consisting in the steps of:
• applying the frit to one of the sheets of glass,
• positioning the other sheet of glass over the first sheet on the frit and
• locally heating the frit to fusing temperature by traversing it with laser irradiation, whereby the two sheets of glass become peripherally sealed together.
7. A method as claimed in claim 6, wherein the sheets are preheated to close to the frit fusing temperature, whereby the energy supplied by the laser is only that required to raise the temperature of the frit locally to its fusing temperature from the preheat temperature.
8. A method as claimed in claim 6 or claim 7, wherein the degree of preheat of the glass is maintained below the temper firing temperature of the glass, whereby the surface compressive stresses induced to strengthen the glass on tempering are not relieved, at least in the bulk of the glass.
9. A method as claimed in claim 6, claim 7 or claim 8, wherein the sealed unit is cooled in a controlled manner.
10. A method as claimed in any one of claims 6 to 9, wherein the laser irradiation is carried out in a dry, inert atmosphere, whereby such an atmosphere is enclosed within the double glazing unit.
11. A method as claimed in any one of claims 6 to 10, wherein the frit is preliminarily tape cast and positioned on the glass in continuous lengths.
12. A method as claimed in any one of claims 6 to 10, wherein the frit is positioned by tape casting direct onto the first sheet of glass.
13. A method as claimed in any one of claims 6 to 10, wherein the frit is positioned by screen printing onto the first sheet of glass.
14. A method as claimed in any one of claims 10 to 13, wherein the frit is preliminarily heated to drive off its binder, prior to positioning of the other sheet of glass on it.
15. A double glazing sealing machine comprising:
• a frit application station for applying frit peripherally to a glass sheet to form one side of a double glazing unit;
• an assembly station for assembling the double glazing unit from the two glass sheets on top of each other with the frit between them; • a preheating station for preheating the assembled pairs of sheets;
• a laser irradiation station for fusing the frit to seal the sheets to each other; and
• a cooling station for cooling the sealed units to room temperature.
PCT/GB2001/003579 2000-08-11 2001-08-09 Double glazing WO2002014640A1 (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
AU2001282271A AU2001282271A1 (en) 2000-08-11 2001-08-09 Double glazing

Applications Claiming Priority (4)

Application Number Priority Date Filing Date Title
US22494900P 2000-08-11 2000-08-11
US60/224,949 2000-08-11
US23826900P 2000-10-05 2000-10-05
US60/238,269 2000-10-05

Publications (1)

Publication Number Publication Date
WO2002014640A1 true WO2002014640A1 (en) 2002-02-21

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Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/GB2001/003579 WO2002014640A1 (en) 2000-08-11 2001-08-09 Double glazing

Country Status (3)

Country Link
US (1) US20020043046A1 (en)
AU (1) AU2001282271A1 (en)
WO (1) WO2002014640A1 (en)

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WO2009078912A1 (en) * 2007-12-14 2009-06-25 Guardian Industries Corp. Localized heating of edge seals for a vacuum insulating glass unit, and/or unitized oven for accomplishing the same
US8227055B2 (en) 2009-05-01 2012-07-24 Guardian Industries Corp. Vacuum insulating glass unit including infrared meltable glass frit, and/or method of making the same
US8506738B2 (en) 2007-12-17 2013-08-13 Guardian Industries Corp. Localized heating via an infrared heat source array of edge seals for a vacuum insulating glass unit, and/or unitized oven with infrared heat source array for accomplishing the same
US8733128B2 (en) 2011-02-22 2014-05-27 Guardian Industries Corp. Materials and/or method of making vacuum insulating glass units including the same
US8802203B2 (en) 2011-02-22 2014-08-12 Guardian Industries Corp. Vanadium-based frit materials, and/or methods of making the same
US9290408B2 (en) 2011-02-22 2016-03-22 Guardian Industries Corp. Vanadium-based frit materials, and/or methods of making the same
US9309146B2 (en) 2011-02-22 2016-04-12 Guardian Industries Corp. Vanadium-based frit materials, binders, and/or solvents and methods of making the same
US9359247B2 (en) 2011-02-22 2016-06-07 Guardian Industries Corp. Coefficient of thermal expansion filler for vanadium-based frit materials and/or methods of making and/or using the same
US9458052B2 (en) 2011-02-22 2016-10-04 Guardian Industries Corp. Coefficient of thermal expansion filler for vanadium-based frit materials and/or methods of making and/or using the same
US9593527B2 (en) 2014-02-04 2017-03-14 Guardian Industries Corp. Vacuum insulating glass (VIG) unit with lead-free dual-frit edge seals and/or methods of making the same
US9822580B2 (en) 2011-02-22 2017-11-21 Guardian Glass, LLC Localized heating techniques incorporating tunable infrared element(s) for vacuum insulating glass units, and/or apparatuses for same
US9988302B2 (en) 2014-02-04 2018-06-05 Guardian Glass, LLC Frits for use in vacuum insulating glass (VIG) units, and/or associated methods

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US20040188124A1 (en) * 2002-03-22 2004-09-30 Stark David H. Hermetic window assemblies and frames
US20060191215A1 (en) * 2002-03-22 2006-08-31 Stark David H Insulated glazing units and methods
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WO2010019484A2 (en) 2008-08-09 2010-02-18 Eversealed Windows, Inc. Asymmetrical flexible edge seal for vacuum insulating glass
US8329267B2 (en) 2009-01-15 2012-12-11 Eversealed Windows, Inc. Flexible edge seal for vacuum insulating glazing units
US8512830B2 (en) 2009-01-15 2013-08-20 Eversealed Windows, Inc. Filament-strung stand-off elements for maintaining pane separation in vacuum insulating glazing units
WO2011153381A2 (en) 2010-06-02 2011-12-08 Eversealed Windows, Inc. Multi-pane glass unit having seal with adhesive and hermetic coating layer
US9328512B2 (en) 2011-05-05 2016-05-03 Eversealed Windows, Inc. Method and apparatus for an insulating glazing unit and compliant seal for an insulating glazing unit
US9441416B2 (en) * 2012-09-27 2016-09-13 Guardian Industries Corp. Low temperature hermetic sealing via laser
JP2016513065A (en) * 2013-02-21 2016-05-12 コーニング インコーポレイテッド Method for forming tempered sintered glass structure
CN103682177B (en) * 2013-12-16 2015-03-25 深圳市华星光电技术有限公司 Manufacturing method of flexible OLED panel
US20160181574A1 (en) * 2014-01-03 2016-06-23 Shenzhen China Star Optoelectronics Technology Co., Ltd. Method for manufacturing flexible oled (organic light emitting diode) panel

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CN101896680A (en) * 2007-12-14 2010-11-24 格尔德殿工业公司 Localized heating of edge seals for a vacuum insulating glass unit, and/or unitized oven for accomplishing the same
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