WO2001083075A1 - A method and a system for separating a mixture - Google Patents

A method and a system for separating a mixture Download PDF

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Publication number
WO2001083075A1
WO2001083075A1 PCT/IB2001/000673 IB0100673W WO0183075A1 WO 2001083075 A1 WO2001083075 A1 WO 2001083075A1 IB 0100673 W IB0100673 W IB 0100673W WO 0183075 A1 WO0183075 A1 WO 0183075A1
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WO
WIPO (PCT)
Prior art keywords
emulsion
gas
sand
separator tank
separated
Prior art date
Application number
PCT/IB2001/000673
Other languages
French (fr)
Inventor
Pål J. NILSEN
Erik A. Wolff
Original Assignee
Abb Research Ltd.
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Abb Research Ltd. filed Critical Abb Research Ltd.
Priority to US10/258,957 priority Critical patent/US6872239B2/en
Priority to EP01923883A priority patent/EP1284800B1/en
Priority to BRPI0110496A priority patent/BRPI0110496B1/en
Priority to DE60141012T priority patent/DE60141012D1/en
Priority to AT01923883T priority patent/ATE454197T1/en
Publication of WO2001083075A1 publication Critical patent/WO2001083075A1/en

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Classifications

    • EFIXED CONSTRUCTIONS
    • E21EARTH OR ROCK DRILLING; MINING
    • E21BEARTH OR ROCK DRILLING; OBTAINING OIL, GAS, WATER, SOLUBLE OR MELTABLE MATERIALS OR A SLURRY OF MINERALS FROM WELLS
    • E21B43/00Methods or apparatus for obtaining oil, gas, water, soluble or meltable materials or a slurry of minerals from wells
    • E21B43/34Arrangements for separating materials produced by the well
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D17/00Separation of liquids, not provided for elsewhere, e.g. by thermal diffusion
    • B01D17/02Separation of non-miscible liquids
    • B01D17/0208Separation of non-miscible liquids by sedimentation
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D17/00Separation of liquids, not provided for elsewhere, e.g. by thermal diffusion
    • B01D17/02Separation of non-miscible liquids
    • B01D17/0208Separation of non-miscible liquids by sedimentation
    • B01D17/0211Separation of non-miscible liquids by sedimentation with baffles
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D17/00Separation of liquids, not provided for elsewhere, e.g. by thermal diffusion
    • B01D17/02Separation of non-miscible liquids
    • B01D17/0217Separation of non-miscible liquids by centrifugal force
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D17/00Separation of liquids, not provided for elsewhere, e.g. by thermal diffusion
    • B01D17/02Separation of non-miscible liquids
    • B01D17/04Breaking emulsions
    • B01D17/045Breaking emulsions with coalescers
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D19/00Degasification of liquids
    • B01D19/0042Degasification of liquids modifying the liquid flow
    • B01D19/0052Degasification of liquids modifying the liquid flow in rotating vessels, vessels containing movable parts or in which centrifugal movement is caused
    • B01D19/0057Degasification of liquids modifying the liquid flow in rotating vessels, vessels containing movable parts or in which centrifugal movement is caused the centrifugal movement being caused by a vortex, e.g. using a cyclone, or by a tangential inlet
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D19/00Degasification of liquids
    • B01D19/0068General arrangements, e.g. flowsheets

Definitions

  • the present invention relates to a method of separating a mixture, in which the mixture comprising an oil-water emulsion together with gas is conducted to a separator tank for separating the oil from the water.
  • the invention also relates to a system for separating a mixture that comprises an oil-water emulsion together with gas, comprising a separator tank for separating oil from water in the emulsion, and means for separating gas from the emulsion.
  • the invention is applicable to all sorts of oil extraction plants, including land-based ones, but is particularly applicable to offshore applications, and to applications in which oil is extracted from a plurality of wells simultaneously and where mixtures of oil, water and gas from the individual wells are gathered in a common line which comprises one or more separator tanks for separating oil- water emulsions by means of gravitational settling.
  • gravity separators are widely used for the purpose of separating oil from water or vice versa, and also for separating gas from emulsions containing extracted water and oil.
  • Such gravity separators have been used both on land-based crude oil and gas process plants as well as on offshore production platforms, in spite of their significant associated installation costs due to their large space and weight requirements.
  • Gravity separators with different solutions to the separator inlet construction are proposed by prior art.
  • One solution is to incorporate a set of gas/liquid multiple hydrocyclones for separating a gas from an oil-water emulsion inside a conventional horizontal or vertical gravity separator.
  • This design takes advantage of both the centrifugal force of the hydrocyclone and gravity as in a conventional separator.
  • Most of the basic separation of gas from the liquid will be done by the hydrocyclone and main focus has been on reducing foaming of the inlet flow.
  • the oil-water emulsion might, however, become negatively affected in the way indicated above, i.e. become more complex and hard to separate by means of gravitational settling in the separator tank.
  • US 4,617,031 discloses an apparatus for separating multiphase mixtures of gas and oil from liquids, such as petroleum production fluids.
  • the apparatus includes a centrifugal gas/liquid separator arranged inside a gravity separator.
  • the device functions by initially separating the gas from the oil by centrifugation in the conical separator, then by allowing the remaining liquid to further separate by gravity in the retention area of the gravity separator.
  • Special de- misters and a sandtrap are also arranged inside the separator for handling gas and sand that has been separated from the oil-water emulsion.
  • WO 99/25454 discloses a conventional gravity separator comprising a separation vessel incorporating an inlet assembly through which a production flow from an oil well is introduced into the vessel.
  • the production flow contains a mixture of gas, oil and water, which can separate under gravity in the vessel into vertically discrete gas, oil and water layers.
  • the inlet as- sembly includes a gas/liquid cyclone separator for separating the production flow into gas and liquid phases. It is known that the use of such a cyclone inlet assembly improves the efficiency of a gravity separator by pre-separating a proportion of the gas phase and by minimising foaming of the inlet flow which otherwise can occur.
  • centrifugal gas/liquid cyclone separator as described above requires a considerable space inside the gravity separator, thereby contributing to a large and heavy gravity separator arrangement.
  • the oil-water emulsion might also be negatively affected by the treatment it is subjected to in the centrifugal separator, such that its complexity is increased and it becomes difficult to separate by means of gravitational settling in the gravity separator.
  • Another disadvantage is that the gas separated by the centrifugal gas/liquid cyclone may take up a relatively large volume in the gravity separator leading to a correspondingly decreased oil/water separation volume, which will either result in a large and heavy gravity separator arrangement or a relatively smaller production rate of oil. From this point of view the gravity separator arrangement also seems to be less flexible.
  • the invention shall also present a method and a system by means of which different components extracted from one or more wells are efficiently separated into their phases in such a way that an overall control of the separation system is facilitated with optimum flexibility.
  • the object of the invention is achieved by means of the initially defined method, which is characterised in that at least a substantial part of the gas is separated from the mixture or, more precisely, from the oil-water emulsion before the emulsion is introduced into the sepa- rator tank.
  • the emulsion may then easily be further treated before being introduced into the separator for the purpose of making it easier to separate by means of gravitational separation.
  • the gas, which has been separated from the oil- water emulsion is conducted separately to the separator tank and is subjected to a defoaming operation before being introduced into the separator and/or to a compressor, preferably via a scrubber.
  • the defoaming operation preferably includes subjecting the gas to ultrasound for the purpose of breaking foam into its individual components, that is gas and liquid respectively.
  • the emulsion from which the gas has been separated is preferably subjected to a coalescing operation before being introduced into the separator tank.
  • a coalescing operation By means of such an operation the droplet size of the dispersed phase in the emulsion is increased. Thereby, subsequent gravitational separation of the emulsion in the separator tank is promoted.
  • the emulsion from which the gas has been separated is introduced into the separator tank via a liquid/liquid cyclone for further separating the phases of the emulsion.
  • a cyclone is preferably arranged at the inlet, inside the separator.
  • the separator is preferably a gravity separator.
  • solid particles such as sand are present together with the gas and the liquid in the emulsion.
  • at least a substantial part of the extracted sand is separated from the emulsion before the latter is introduced into the separator tank.
  • the need of a large sandtrap at the bottom of the separator tank is reduced.
  • the number of sprinklers and sand outlets in the sandtrap can be heavily reduced, and the sandtrap does not need to be emptied as often as would otherwise be necessary.
  • the objective of the invention is also achieved by means of the initially defined system, which is characterised in that the means for separating the gas from the oil-water emulsion is arranged separately upstream of the separator tank. Upstream is referred to as upstream with reference to the flow direction of the emulsion, which flows from the well or wells to the separator tank in one or more dedicated pipes or conduits.
  • the inventive system comprises a conduit for separately conducting the separated gas from the gas separation means to the separator tank. Thereby it will be possible to pre-treat the gas before it is introduced into the separator tank.
  • the system comprises a defoamer for removing foam from the gas before it is introduced into the separator tank.
  • the defoamer is arranged to break the foam into gas and liquid.
  • the separate gas line also makes it possible to precisely control the amount of gas conducted to the separator tank. This allows for a re- Jerusalem gas volume in the separator tank with an increased oil/water separation volume.
  • the system comprises means for separating sand from the extracted oil-water emulsion.
  • the sand separating means are arranged upstream of the separator tank in the emulsion flow line in order to remove sand from the emulsion or liquid before the latter is introduced into the separator tank.
  • the means for separating sand from the oil-water emulsion comprises a first cyclone in which there is a first pressure fall as a slurry comprising residual emulsion and the sand is separated from the major part of the emulsion, and at least one second cyclone for separating the sand from the emulsion under a second pressure fall, the second pressure fall being substantially larger than the first pressure fall.
  • the system comprises a conduit for conducting the residual emulsion separated from the sand in the second cyclone to the separator tank.
  • the system comprises a liquid-liquid cyclone for the pre-treatment or pre-separation of the emulsion before the latter is subjected to separation by means of gravitational settling in the separator tank.
  • this cyclone is arranged at the inlet, inside the separator tank.
  • Fig. 1 is a schematic view of a first embodiment of the inventive system
  • Fig. 2 is a schematic view of a further development of the inventive system according to Fig. 1.
  • Fig. 1 shows the inventive system according to a first embodiment.
  • the system is connected to a plurality of wells 1-4 from which oil is extracted. Together with the oil, water and gas, sand is also expected to get extracted from the wells 1-4.
  • the ratio between these components is likely to change with time. Individual ratio differences between the wells are also likely to exist.
  • the oil-water-gas mixtures with their content of sand are gathered in a common line or conducting means 5.
  • the system comprises valve arrangements 6 for regulating the individual contributions from the wells 1-4.
  • the resulting mixture is then conducted via the conducting means 5 to a gas/liquid cyclone 7 which separates the gas and the oil/water in separate streams flowing in separate conduits, preferably tubes or pipes, 8, 9.
  • the cyclone 7 preferably has the same features as the cyclone disclosed in the applicants Norwegian patent application no. NO 19993985. Thereby optimum emulsion control in the cyclone can be obtained. This is important in order to make it possible to assess the changing emulsion properties that will be experienced during the life time of the field.
  • the cyclone 7 is designed for the purpose of removing sand from the oil- water emulsion.
  • a sand outlet from the cyclone 7 is schematically shown and denoted 10 in fig. 1.
  • the system also comprises at least one gravity separator 11 designed and arranged for the purpose of separating oil from water in the oil-water emulsion delivered to it via the oil-water emulsion tube or pipe 9.
  • gas still remaining in the oil- water emul- sion is also removed from the emulsion as it is allowed to ascend to an upper part of the separator tank 11 while, simultaneously, the water is separated from the oil through gravitational settling in a lower region of the separator 11.
  • the separator 11 comprises a gas outlet 12, a water outlet 13 and an oil outlet 14.
  • the system comprises a coalescer 15 by means of which the emulsion is pretreated.
  • This pre-treatment preferably includes subjecting the emulsion to microwave radiation by means of a microwave device for the purpose of accomplishing a separate heating of only the water, but not the oil, in the emulsion, and thereby obtaining a kind of pre-separation of the components of the emulsion before the latter reaches the gravity separator 11.
  • the coalescer 15 preferably also comprises a coalescing medium which gets in contact with the emulsion and which has such a polarity that it attracts one of the emulsion components substantially more than it attracts the other component.
  • the emulsion comprises water droplets in a continous oil phase
  • a polar polymer such as PA or PMMA is a preferred coalescing medium.
  • the main feature of the inline coalescer is the ability to increase the droplet size of the dispersed phase in the emulsion or liquid stream.
  • the coalescer may include an electrostatic device or an ultrasound generator.
  • the system also comprises a liquid/liquid cylone 16 arranged for the purpose of pre- separating oil from water in the oil-water emulsion before the latter is subjected to the gravity separation process in the separator 11.
  • the cyclone 16 is arranged inside the gravity separator tank 11.
  • the coalescer 15 is arranged upstream of the cyclone 16 as seen in the emulsion flow direction.
  • complex emulsions are treated such that they become easier to separate through gravity separation in the separator 11.
  • the cyclone 16 is primarily adapted to the separation of one liquid from another, and not for the separation of a gas from a liquid. Thereby, a low cyclone flow speed can be used, which is an advantage when seeking to avoid complex emulsions.
  • the system comprises a defoamer 17 for removing foam from the gas.
  • the gas is conducted via the tube or pipe 8 all the way into the upper part of the separator tank 11.
  • foam is removed from the gas by means of the defoamer 17 before it is introduced into the separator tank 11, special defoamer arrangements inside the separator 11 can be avoided, which is an advantage.
  • the defoamer 17 is arranged to break the foam into its main components, in this case gas, oil and water.
  • the defoamer 17 preferably comprises an ultrasound generator or a mechanical shear device, for the purpose of subjecting the gas/foam to ultrasound or mechanical shear that breaks or splits the foam, thereby contributing to lesser need of any chemical agents for accomplishing a defoaming effect.
  • the system may include means (not shown) for routing the gas directly to a scrubber upstream of a gas compressor with just a pressure balance connection to the separator tank.
  • Such means preferably comprises a separate pump and valve arrangement.
  • the alternative gas tube/pipe is indicated by reference number 18 in fig. 1.
  • Fig. 2 shows a second embodiment of the inventive system, which is a further development of the embodiment shown in fig. 1.
  • the system comprises two further liquid-sand cyclones 19, 20 arranged downstream the cyclone 7 in the flow direction of a sand-liquid slurry sepa- rated from the cyclone 7 via the sand outlet 10 mentioned above.
  • the gas-liquid-sand cyclone 7 defines a first cyclone in which there is a first pressure fall as the slurry comprising residual emulsion and sand is separated from the major part of the emulsion which is conducted via the tube or pipe 9 from the first cyclone 7.
  • the sand-liquid cyclones 19, 20 define second cyclones in which the residual emulsion is separated from the sand. In at least one of the second cyclones 19, 20 the pressure fall is substantially larger than in the first cyclone 7.
  • a slurry consisting of residual emulsion and sand, but with less emulsion than the slurry that is introduced into it, is extracted via the tube or pipe 21 from a first one 19 to a second one 20 of the sand-liquid cyclones.
  • Via another pipe or tube 22 residual emulsion separated from the slurry in the cyclone 19 is conducted to the main emulsion line 9 by means of a pump 23 and further conducted to the coalescer 15 and the gravity separator 11.
  • the slurry delivered via the pipe/tube 21 is further separated, and the obtained emulsion or liquid is separated and conducted via a pipe/tube 24 to the main emulsion line 9 and further on to the gravity separator 11.
  • Via a sand outlet 25 sand is removed from the last one 20 of the second cyclones 19, 20.
  • the pressure fall in the first cyclone 7 can be kept at a fairly low level, which is advantageous from an economical as well as practical and technical point of view.
  • the emulsion reaching the gravity separator 11 will have a very low sand content, and therefore there will be less need of a repeated removal of sand from the bottom of the gravity separator 11.
  • Such a subsea system preferably comprises a pipeline for the direct transportation of oil obtained from the gravity separator or separators 11 to land-based plants.
  • the invention also includes such subsea systems and applications.
  • the invention is also applicable to land-based sites, and it may be implemented on any top side arrangement on land as well as offshore.
  • the number of second cyclones 19, 20 is optional and subject to process optimisation in each single case.

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  • Physics & Mathematics (AREA)
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Abstract

A method and a system for separating a mixture that comprises an oil-water emulsion together with gas. The system comprises a separator tank (11) for separating oil from water in the emulsion, and means for separating gas from the emulsion. The means (7) for separating the gas from the emulsion is arranged separately upstream of the separator tank (11).

Description

A method and a system for separating a mixture
Field of the invention
The present invention relates to a method of separating a mixture, in which the mixture comprising an oil-water emulsion together with gas is conducted to a separator tank for separating the oil from the water. The invention also relates to a system for separating a mixture that comprises an oil-water emulsion together with gas, comprising a separator tank for separating oil from water in the emulsion, and means for separating gas from the emulsion.
The invention is applicable to all sorts of oil extraction plants, including land-based ones, but is particularly applicable to offshore applications, and to applications in which oil is extracted from a plurality of wells simultaneously and where mixtures of oil, water and gas from the individual wells are gathered in a common line which comprises one or more separator tanks for separating oil- water emulsions by means of gravitational settling.
Background of the invention
Devices that separate gases, liquids and solids work on a variety of principles. In oil extrac- tion applications gravity separators are widely used for the purpose of separating oil from water or vice versa, and also for separating gas from emulsions containing extracted water and oil. Such gravity separators have been used both on land-based crude oil and gas process plants as well as on offshore production platforms, in spite of their significant associated installation costs due to their large space and weight requirements.
Most separation systems handle well streams from several wells. The wells are choked to a common pressure into a manifold and the streams of oil, water, gas and solids extracted from the wells are conducted via a common pipe or line to the separator. To reduce the momentum of the incoming gas/liquid well stream in the separator, inlet devices have normally been mounted inside the separator. Traditionally, the inlet devices have been simple splash plates or sets of vanes, even though, more recently, new inlet cyclones have been introduced to make benefit from high g-forces to eliminate foaming in the separator. However, such inlet cyclones may create a very difficult emulsion of oil and water that often can be impossible to separate in the gravity separator. They also add to the weight, space requirement and complexity of the separator.
Recently, some oil companies experience new challenges for their separation process. The fact that some of the wells are oil continuos and some are water continuos may cause complex emulsion patterns. Water droplets can trap oil droplets that, in their turn, may trap small water droplets. The various wells must be choked differently, and as a result thereof there will be large variations in droplet sizes. This adds to the complexity of the incoming gas-oil-water mixture. The water cut for each well will change during the production, typically from 0% water to 90% water. Accordingly the inlet separation system needs to be flexible in handling the various types of mixtures. However, there are difficulties in obtaining inlet separation systems that are flexible and that do not add a considerable weight and volume to the separator arrangement.
Prior art
Gravity separators with different solutions to the separator inlet construction are proposed by prior art. One solution is to incorporate a set of gas/liquid multiple hydrocyclones for separating a gas from an oil-water emulsion inside a conventional horizontal or vertical gravity separator. This design takes advantage of both the centrifugal force of the hydrocyclone and gravity as in a conventional separator. Most of the basic separation of gas from the liquid will be done by the hydrocyclone and main focus has been on reducing foaming of the inlet flow. The oil-water emulsion might, however, become negatively affected in the way indicated above, i.e. become more complex and hard to separate by means of gravitational settling in the separator tank.
US 4,617,031 discloses an apparatus for separating multiphase mixtures of gas and oil from liquids, such as petroleum production fluids. The apparatus includes a centrifugal gas/liquid separator arranged inside a gravity separator. The device functions by initially separating the gas from the oil by centrifugation in the conical separator, then by allowing the remaining liquid to further separate by gravity in the retention area of the gravity separator. Special de- misters and a sandtrap are also arranged inside the separator for handling gas and sand that has been separated from the oil-water emulsion. WO 99/25454 discloses a conventional gravity separator comprising a separation vessel incorporating an inlet assembly through which a production flow from an oil well is introduced into the vessel. The production flow contains a mixture of gas, oil and water, which can separate under gravity in the vessel into vertically discrete gas, oil and water layers. The inlet as- sembly includes a gas/liquid cyclone separator for separating the production flow into gas and liquid phases. It is known that the use of such a cyclone inlet assembly improves the efficiency of a gravity separator by pre-separating a proportion of the gas phase and by minimising foaming of the inlet flow which otherwise can occur.
However, a centrifugal gas/liquid cyclone separator as described above requires a considerable space inside the gravity separator, thereby contributing to a large and heavy gravity separator arrangement. The oil-water emulsion might also be negatively affected by the treatment it is subjected to in the centrifugal separator, such that its complexity is increased and it becomes difficult to separate by means of gravitational settling in the gravity separator. Another disadvantage is that the gas separated by the centrifugal gas/liquid cyclone may take up a relatively large volume in the gravity separator leading to a correspondingly decreased oil/water separation volume, which will either result in a large and heavy gravity separator arrangement or a relatively smaller production rate of oil. From this point of view the gravity separator arrangement also seems to be less flexible.
Object of the invention
It is an object of the invention to provide a method and a system which promotes the design of a small, light and efficient gravity separator for the separation of oil from water in an oil- water emulsion. The invention shall also present a method and a system by means of which different components extracted from one or more wells are efficiently separated into their phases in such a way that an overall control of the separation system is facilitated with optimum flexibility.
Summary of the invention
The object of the invention is achieved by means of the initially defined method, which is characterised in that at least a substantial part of the gas is separated from the mixture or, more precisely, from the oil-water emulsion before the emulsion is introduced into the sepa- rator tank. The emulsion may then easily be further treated before being introduced into the separator for the purpose of making it easier to separate by means of gravitational separation.
According to a preferred embodiment, the gas, which has been separated from the oil- water emulsion, is conducted separately to the separator tank and is subjected to a defoaming operation before being introduced into the separator and/or to a compressor, preferably via a scrubber. Thereby, no or only small defoamers are needed inside the separator. The defoaming operation preferably includes subjecting the gas to ultrasound for the purpose of breaking foam into its individual components, that is gas and liquid respectively.
The emulsion from which the gas has been separated is preferably subjected to a coalescing operation before being introduced into the separator tank. By means of such an operation the droplet size of the dispersed phase in the emulsion is increased. Thereby, subsequent gravitational separation of the emulsion in the separator tank is promoted.
Preferably, the emulsion from which the gas has been separated is introduced into the separator tank via a liquid/liquid cyclone for further separating the phases of the emulsion. Such a cyclone is preferably arranged at the inlet, inside the separator. Thereby the emulsion, which might have become rather complex due to it being extracted from different wells and sub- jected to the treatment in a foregoing gas/liquid separator, is pre-treated to become more easily separated by means of gravitational separation in the separator. The separator is preferably a gravity separator.
Normally, solid particles such as sand are present together with the gas and the liquid in the emulsion. Preferably at least a substantial part of the extracted sand is separated from the emulsion before the latter is introduced into the separator tank. Thereby, the need of a large sandtrap at the bottom of the separator tank is reduced. The number of sprinklers and sand outlets in the sandtrap can be heavily reduced, and the sandtrap does not need to be emptied as often as would otherwise be necessary.
The objective of the invention is also achieved by means of the initially defined system, which is characterised in that the means for separating the gas from the oil-water emulsion is arranged separately upstream of the separator tank. Upstream is referred to as upstream with reference to the flow direction of the emulsion, which flows from the well or wells to the separator tank in one or more dedicated pipes or conduits.
The inventive system comprises a conduit for separately conducting the separated gas from the gas separation means to the separator tank. Thereby it will be possible to pre-treat the gas before it is introduced into the separator tank. Preferably, the system comprises a defoamer for removing foam from the gas before it is introduced into the separator tank. The defoamer is arranged to break the foam into gas and liquid. The separate gas line also makes it possible to precisely control the amount of gas conducted to the separator tank. This allows for a re- duced gas volume in the separator tank with an increased oil/water separation volume.
According to a preferred embodiment of the invention the system comprises means for separating sand from the extracted oil-water emulsion. The sand separating means are arranged upstream of the separator tank in the emulsion flow line in order to remove sand from the emulsion or liquid before the latter is introduced into the separator tank. Thereby, the need of a large sandtrap at the bottom of the separator tank is reduced. Even though some sort of a sandtrap still might be needed, it does not need to be as powerful as before. The number of sprinklers and sand outlets in the sandtrap can be heavily reduced, and the sandtrap does not need to be emptied as often as would otherwise be necessary. This, in its turn, promotes the positioning of the separator tank submerged into the water instead of on top of an offshore platform.
The means for separating sand from the oil-water emulsion comprises a first cyclone in which there is a first pressure fall as a slurry comprising residual emulsion and the sand is separated from the major part of the emulsion, and at least one second cyclone for separating the sand from the emulsion under a second pressure fall, the second pressure fall being substantially larger than the first pressure fall. Thereby, energy consumption is reduced and the residual emulsion is efficiently taken care of. Preferably, the system comprises a conduit for conducting the residual emulsion separated from the sand in the second cyclone to the separator tank. Possibly, it comprises a pump means for pumping the residual emulsion from the second cyclone to the separator or to the main conduit via which the emulsion extracted from the first cyclone is conducted to the separator. The residual emulsion may alternatively be routed to a second stage separator operating at a lower pressure, thereby eliminating the need of a pump. According to a preferred embodiment, the system comprises a liquid-liquid cyclone for the pre-treatment or pre-separation of the emulsion before the latter is subjected to separation by means of gravitational settling in the separator tank. Preferably, this cyclone is arranged at the inlet, inside the separator tank. By means of this cyclone complex emulsions that would otherwise be difficult to separate through gravity settling are treated for the purpose of making them easier to separate in the subsequent gravity separation step.
Further advantages and features of the present invention will be described in the following, detailed description and in the appended claims.
Brief description of the drawings
The invention will now be described more in detail with reference to the drawings, in which:
Fig. 1 is a schematic view of a first embodiment of the inventive system, and
Fig. 2 is a schematic view of a further development of the inventive system according to Fig. 1.
Detailed description of preferred embodiments
Fig. 1 shows the inventive system according to a first embodiment. The system is connected to a plurality of wells 1-4 from which oil is extracted. Together with the oil, water and gas, sand is also expected to get extracted from the wells 1-4. The ratio between these components is likely to change with time. Individual ratio differences between the wells are also likely to exist.
The oil-water-gas mixtures with their content of sand are gathered in a common line or conducting means 5. As there might be different pressures in the different wells 1-4 the system comprises valve arrangements 6 for regulating the individual contributions from the wells 1-4. The resulting mixture is then conducted via the conducting means 5 to a gas/liquid cyclone 7 which separates the gas and the oil/water in separate streams flowing in separate conduits, preferably tubes or pipes, 8, 9. The cyclone 7 preferably has the same features as the cyclone disclosed in the applicants Norwegian patent application no. NO 19993985. Thereby optimum emulsion control in the cyclone can be obtained. This is important in order to make it possible to assess the changing emulsion properties that will be experienced during the life time of the field. In addition, the cyclone 7 is designed for the purpose of removing sand from the oil- water emulsion. A sand outlet from the cyclone 7 is schematically shown and denoted 10 in fig. 1.
The system also comprises at least one gravity separator 11 designed and arranged for the purpose of separating oil from water in the oil-water emulsion delivered to it via the oil-water emulsion tube or pipe 9. In the gravity separator 11 gas still remaining in the oil- water emul- sion is also removed from the emulsion as it is allowed to ascend to an upper part of the separator tank 11 while, simultaneously, the water is separated from the oil through gravitational settling in a lower region of the separator 11. Accordingly, the separator 11 comprises a gas outlet 12, a water outlet 13 and an oil outlet 14.
In the emulsion delivery line 9 from the cyclone 7 to the separator 11 the system comprises a coalescer 15 by means of which the emulsion is pretreated. This pre-treatment preferably includes subjecting the emulsion to microwave radiation by means of a microwave device for the purpose of accomplishing a separate heating of only the water, but not the oil, in the emulsion, and thereby obtaining a kind of pre-separation of the components of the emulsion before the latter reaches the gravity separator 11. The coalescer 15 preferably also comprises a coalescing medium which gets in contact with the emulsion and which has such a polarity that it attracts one of the emulsion components substantially more than it attracts the other component. For example, when the emulsion comprises water droplets in a continous oil phase, a polar polymer such as PA or PMMA is a preferred coalescing medium. The main feature of the inline coalescer is the ability to increase the droplet size of the dispersed phase in the emulsion or liquid stream. Alternatively or as a supplement to the microwave device, the coalescer may include an electrostatic device or an ultrasound generator.
The system also comprises a liquid/liquid cylone 16 arranged for the purpose of pre- separating oil from water in the oil-water emulsion before the latter is subjected to the gravity separation process in the separator 11. The cyclone 16 is arranged inside the gravity separator tank 11. The coalescer 15 is arranged upstream of the cyclone 16 as seen in the emulsion flow direction. By means of the cyclone 16 complex emulsions are treated such that they become easier to separate through gravity separation in the separator 11. The cyclone 16 is primarily adapted to the separation of one liquid from another, and not for the separation of a gas from a liquid. Thereby, a low cyclone flow speed can be used, which is an advantage when seeking to avoid complex emulsions.
In line with the tube or pipe 8 for conducting the gas from the gas/liquid separator 7 the system comprises a defoamer 17 for removing foam from the gas. Here the gas is conducted via the tube or pipe 8 all the way into the upper part of the separator tank 11. As foam is removed from the gas by means of the defoamer 17 before it is introduced into the separator tank 11, special defoamer arrangements inside the separator 11 can be avoided, which is an advantage. The defoamer 17 is arranged to break the foam into its main components, in this case gas, oil and water. The defoamer 17 preferably comprises an ultrasound generator or a mechanical shear device, for the purpose of subjecting the gas/foam to ultrasound or mechanical shear that breaks or splits the foam, thereby contributing to lesser need of any chemical agents for accomplishing a defoaming effect.
As an alternative or supplement to the means for conducting the gas into the separator tank 11 via the tube/pipe 8, the system may include means (not shown) for routing the gas directly to a scrubber upstream of a gas compressor with just a pressure balance connection to the separator tank. Such means preferably comprises a separate pump and valve arrangement. The alternative gas tube/pipe is indicated by reference number 18 in fig. 1.
Fig. 2 shows a second embodiment of the inventive system, which is a further development of the embodiment shown in fig. 1. Here, the system comprises two further liquid-sand cyclones 19, 20 arranged downstream the cyclone 7 in the flow direction of a sand-liquid slurry sepa- rated from the cyclone 7 via the sand outlet 10 mentioned above. The gas-liquid-sand cyclone 7 defines a first cyclone in which there is a first pressure fall as the slurry comprising residual emulsion and sand is separated from the major part of the emulsion which is conducted via the tube or pipe 9 from the first cyclone 7. The sand-liquid cyclones 19, 20 define second cyclones in which the residual emulsion is separated from the sand. In at least one of the second cyclones 19, 20 the pressure fall is substantially larger than in the first cyclone 7. A slurry consisting of residual emulsion and sand, but with less emulsion than the slurry that is introduced into it, is extracted via the tube or pipe 21 from a first one 19 to a second one 20 of the sand-liquid cyclones. Via another pipe or tube 22 residual emulsion separated from the slurry in the cyclone 19 is conducted to the main emulsion line 9 by means of a pump 23 and further conducted to the coalescer 15 and the gravity separator 11. In the second one 20 of the second cyclones 19, 20 the slurry delivered via the pipe/tube 21 is further separated, and the obtained emulsion or liquid is separated and conducted via a pipe/tube 24 to the main emulsion line 9 and further on to the gravity separator 11. Via a sand outlet 25 sand is removed from the last one 20 of the second cyclones 19, 20. Thanks to the stepwise separation of sand from emulsion by means of the first cyclone 7 and the second cyclones 19, 20 the pressure fall in the first cyclone 7 can be kept at a fairly low level, which is advantageous from an economical as well as practical and technical point of view. The emulsion reaching the gravity separator 11 will have a very low sand content, and therefore there will be less need of a repeated removal of sand from the bottom of the gravity separator 11.
Even though the embodiment according to fig. 2 comprises two second cyclones it should be understood that the number of second cyclones is purely a matter of optimisation in each single case, and that the inventive system might comprise other numbers of such cyclones for obtaining a stepwise separation of oil-water emulsion from sand. It should also be understood that pump and/or valve arrangements are likely to be needed for the purpose of delivering the emulsions via the pipes/tubes 22, 24 to the main emulsion line 9.
The design of the inventive system promotes subsea applications in which the whole system is arranged at the bottom of the sea instead of at least partly on an offshore platform. Such a subsea system preferably comprises a pipeline for the direct transportation of oil obtained from the gravity separator or separators 11 to land-based plants. Of course, it might as well comprise a pipeline for the transportation of gas from any of the cyclones or gravity separators to land-based plants or consumers. Accordingly the invention also includes such subsea systems and applications. Of course, the invention is also applicable to land-based sites, and it may be implemented on any top side arrangement on land as well as offshore.
Of course, a plurality of alternative embodiments will be obvious for a man skilled in the art without leaving the scope of invention, as defined in the appended claims, supported by the description and the drawings. However, the claimed subject matter also covers such alternative embodiments.
For example, the number of second cyclones 19, 20 is optional and subject to process optimisation in each single case.

Claims

Claims
1. A method for separating a mixture, in which the mixture comprising an oil-water emulsion together with gas is conducted to a separator tank (11) for separating the oil from the water, characterised in that at least a substantial part of the gas is separated from the emulsion before the emulsion is introduced into the separator tank (11).
2. A method according to claim 1, characterised in that the gas separated from the emulsion is conducted separately to the separator tank (11) and/or to a compressor, preferably via a scrub- ber.
3. A method according to claim 1 or 2, characterised in that the gas is subjected to a defoaming operation before being introduced into the separator tank (11).
4. A method according to any one of claims 1-3, characterised in that the oil-water emulsion, after having been separated from the gas and before being introduced into the separator tank (11), is subjected to a coalescing operation in which the droplet size of the dispersed phase in the emulsion is increased.
5. A method according to any one of claims 1-4, characterised in that the oil-water emulsion, from which gas has been separated, is introduced into the separator tank (11) via a liquid- liquid cyclone (16) for further separating the phases of the emulsion.
6. A method according to any one of claims 1-5, characterised in that the emulsion comprises sand, and that at least a substantial part of the sand is separated from the emulsion before the emulsion is introduced into the separator tank (11).
7. A method according to claim 6, characterised in that the sand is separated from the emulsion by means of a first cyclone (7) with a first pressure fall and that, subsequently, a slurry containing residual emulsion and the sand thereby separated is conducted to and treated in a second cyclone (19, 20) with a second pressure fall for the purpose of separating the sand from the residual emulsion, the second pressure fall being substantially larger than the first pressure fall.
8. A method according to any one of claims 1-7, characterised in that the separation is performed offshore, and that the separation of the sand and/or gas is performed by means of one or more devices (7, 11, 19, 20) located in a submerged position.
9. A system for separating a mixture that comprises an oil-water emulsion together with gas, comprising a separator tank (11) for separating the oil from the water in the emulsion, and means for separating gas from the emulsion, characterised in that the means (7) for separating the gas from the oil-water emulsion is arranged separately upstream of the separator tank (11).
10. A system according to claim 9, characterised in that it comprises a conduit (8) for separately conducting the separated gas from the gas separation means (7) to the separator tank (11).
11. A system according to claim 9 or 10, characterised in that it comprises a defoamer (17) for removing foam from the separated gas before the latter is introduced into the separator tank
(11).
12. A system according to claim 11, characterised in that the defoamer (17) is arranged to break the foam into gas and liquid.
13. A system according to claim 11 or 12, characterised in that the defoamer (17) comprises an ultrasound generator.
14. A system according to claim 11 or 12, characterised in that the defoamer (17) comprises a mechanical shear device.
15. A system according to any one of claims 9-14, characterised in that it comprises means (7, 19, 20) for separating sand from the extracted oil-water emulsion, said sand separating means (7, 19, 20) being arranged upstream of the separator tank (11) in the emulsion flow line (9) in order to remove sand from the emulsion before the emulsion is introduced into the separator tank (11).
16. A system according to claim 15, characterised in that the means (7, 19, 20) for separating sand from the emulsion comprises a first cyclone (7) in which there is a first pressure fall as a slurry comprising residual emulsion and the sand is separated from the major part of the emulsion, and at least one second cyclone (19, 20) for separating the sand from the residual emulsion under a second pressure fall, the second pressure fall being substantially larger than the first pressure fall.
17. A system according to claim 16, characterised in that it comprises a conduit (22, 24) for conducting the residual emulsion separated from the sand in the second cyclone (19, 20) to the separator tank (11).
18. A system according to any one of claims 9-17, characterised in that it comprises a liquid- liquid cyclone (16) for the pre-treatment of the emulsion before it is subjected to separation by means of gravitational settling in the separator tank (11).
19. A system according to claim 16 and any one of claims 9-18, characterised in that the first cyclone (7) is a three phase separator in which the gas, oil-water emulsion and sand/emulsion- slurry are separated from each other.
20. A system according to any one of claims 9-19, characterised in that it comprises a coalescer (15) for the treatment of emulsion which has been separated from the gas and which is conducted to the separator tank (11).
21. A system according to claim 18 and 20, characterised in that the coalescer (15) is located upstream of the liquid/liquid cyclone (16) as seen in the emulsion flow direction.
22. A system according to claim 21, characterised in that the coalescer (15) comprises a microwave device.
23. A system according to claim 21, characterised in that the coalescer (15) comprises an ultrasound generator.
24. A system according to claim 21, characterised in that the coalescer (15) comprises an electrostatic device.
25. Use of a system according to any one of claims 9-24 in an offshore system for offshore extraction and separation of oil.
AMENDED CLAIMS
[received by the International Bureau on 07 September 2001 (07.09.01); original claims 1-25 replaced by new claims 1-23 ( 4 pages)]
l.A method for separating phases of a mixture comprising an oil-water emulsion together with gas, said emulsion is conducted to a separator tank (11) for separating the oil from the water, wherein at least a substantial part of the gas is separated from the emulsion before the emulsion is introduced into the separator tank (11), characterised in that the oil-water emulsion, from which gas has been separated, is introduced into the separator tank (11) via a liquid-liquid cyclone (16) for further separating the phases of the emulsion, said liquid-liquid cyclone (16) being located inside the separator tank (11).
2. A method according to claim 1, characterised in that the gas separated from the emulsion is conducted separately to the separator tank (11) and/or to a scrubber.
3. A method according to claim 1 or 2, characterised in that the gas is subjected to a defoam- ing operation before being introduced into the separator tank (11).
4. A method according to any one of claims 1-3, characterised in that the emulsion, after having been separated from the gas and before being introduced into the separator tank (11), is subjected to a coalescing operation in which the droplet size of the dispersed phase in the emulsion is increased.
5. A method according to any one of claims 1-4, characterised in that the emulsion comprises sand, and that at least a substantial part of the sand is separated from the emulsion before the emulsion is introduced into the separator tank (11).
6. A method according to claim 5, characterised in that the sand is separated from the emulsion by means of a first cyclone (7) with a first pressure fall and that, subsequently, a slurry containing residual emulsion and the sand thereby separated is conducted to and treated in a second cyclone (19, 20) with a second pressure fall for the purpose of separating the sand from the residual emulsion, the second pressure fall being substantially larger than the first pressure fall.
7. A method according to any one of claims 1-6, characterised in that the separation is performed offshore, and that the separation of the sand and/or gas is performed by means of one or more devices (7, 11, 19, 20) located in a submerged position.
8. A system for separating phases of a mixture that comprises an oil-water emulsion together with gas, comprising a separator tank (11) for separating the oil from the water in the emulsion, and means (7) for separating the gas from the oil-water emulsion arranged separately upstream of the separator tank (11), characterised in that it comprises a liquid-liquid cyclone (16) for the pretreatment of the emulsion before the emulsion is subjected to separation by means of gravitational settling in the separator tank (11), said liquid-liquid cyclone (16) being located inside the separator tank (11).
9. A system according to claim 8, characterised in that it comprises a conduit (8) for separately conducting the separated gas from the gas separation means (7) to the separator tank (11).
10. A system according to claim 8 or 9, characterised in that it comprises a defoamer (17) for removing foam from the separated gas before the latter is introduced into the separator tank
(11).
11. A system according to claim 10, characterised in that the defoamer (17) is arranged to break the foam into gas and liquid.
12. A system according to claim 10 or 11, characterised in that the defoamer (17) comprises an ultrasound generator.
13. A system according to claim 10 or 11, characterised in that the defoamer (17) comprises a mechanical shear device.
14. A system according to any one of claims 8-13, characterised in that it comprises means (7, 19, 20) for separating sand from the extracted oil-water emulsion, said sand separating means (7, 19, 20) being arranged upstream the separator tank (11) in the emulsion flow line (9) in order to remove sand from the emulsion before the emulsion is introduced into the separator tank (11).
15. A system according to claim 14, characterised in that the means (7, 19, 20) for separating sand from the emulsion comprises a first cyclone (7) in which there is a first pressure fall as a slurry comprising residual emulsion and the sand is separated from the major part of the emulsion, and at least one second cyclone (19, 20) for separating the sand from the residual emulsion under a second pressure fall, the second pressure fall being substantially larger than the first pressure fall.
16. A system according to claim 15, characterised in that it comprises a conduit (22, 23) for conducting the residual emulsion separated from the sand in the second cyclone (19, 20) to the separator tank (11).
17. A system according to claim 15 and any one of claims 8-16, characterised in that the first cyclone (7) is a three phase separator in which the gas, emulsion and sand/emulsion slurry are separated from each other.
18. A system according to any one of claims 8-17, characterised in that it comprises a coalescer (15) for the treatment of emulsion which has been separated from the gas and which is conducted to the separator tank (11).
19. A system according to claim 18, characterised in that the coalescer (15) is located upstream the liquid/liquid cyclone (16) as seen in the emulsion flow direction.
20. A system according to claim 18 or 19, characterised in that the coalescer (15) comprises a microwave device.
21. A system according to claim 18 or 19, characterised in that the coalescer (15) comprises an ultrasound generator.
22. A system according to claim 18 or 19, characterised in that the coalescer (15) comprises an electrostatic device.
23. Use of a system according to any one of claims 8-22 in an offshore system for offshore extraction and separation of oil.
PCT/IB2001/000673 2000-05-04 2001-04-23 A method and a system for separating a mixture WO2001083075A1 (en)

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BRPI0110496B1 (en) 2016-08-02
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NO20002350L (en) 2001-11-05
ATE454197T1 (en) 2010-01-15
EP1284800B1 (en) 2010-01-06
BR0110496A (en) 2003-04-01
US6872239B2 (en) 2005-03-29

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