WO2001081284A2 - Process for the hydroxylation of aliphatic compounds - Google Patents
Process for the hydroxylation of aliphatic compounds Download PDFInfo
- Publication number
- WO2001081284A2 WO2001081284A2 PCT/EP2001/004854 EP0104854W WO0181284A2 WO 2001081284 A2 WO2001081284 A2 WO 2001081284A2 EP 0104854 W EP0104854 W EP 0104854W WO 0181284 A2 WO0181284 A2 WO 0181284A2
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- WIPO (PCT)
- Prior art keywords
- aliphatic compound
- distillation
- aliphatic
- hydroxylated product
- oxidant
- Prior art date
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- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C29/00—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring
- C07C29/48—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by oxidation reactions with formation of hydroxy groups
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P20/00—Technologies relating to chemical industry
- Y02P20/10—Process efficiency
Definitions
- the present invention relates to a process for hydroxylating aliphatic compounds using an oxidant over an oxidizing catalyst.
- Hydroxylated aliphatic compounds of commercial importance are alcohols of saturated or unsaturated, aliphatic compounds. Alcohols of these compounds are used in making detergents, soaps, surfactants, and freeze point depressants in lubricating oils. These alcohols currently are produced using relatively complex commercial processes, such as by oxo or hydroformylation of long chain olefins . Additional routes to make these alcohols are dehydrohalogenation of alkyl halides.
- the present invention provides a process comprising: continuously contacting, in a distillation column reactor comprising a reaction zone and a distillation zone, at least one, saturated or unsaturated, aliphatic compound with an oxidation catalyst and an oxidant under conditions effective to hydroxylate said aliphatic compound thereby producing a hydroxylated product, while maintaining at least a portion of said aliphatic compound in a liquid phase; continuously separating said hydroxylated product from the un-reacted aliphatic compound in the distillation zone under conditions effective to vaporize said un-reacted aliphatic compound and maintain said hydroxylated product in a liquid phase; and recovering the said separated hydroxylated product from the distillation column reactor.
- Figure 1 is a schematic representation of one embodiment of the present invention using a distillation column reactor.
- the present invention relates to a process for the direct hydroxylation of saturated or unsaturated, aliphatic compounds ("feedstocks"), particularly, feedstocks containing olefinic and/or paraffinic compounds, preferably having in the range from 6 to 30 carbon atoms, under catalytic distillation conditions. A portion of such feedstock is maintained in a liquid phase.
- the feedstock is hydroxylated by an oxidant in the presence of an oxidizing catalyst under conditions effective to hydroxylate said saturated or unsaturated, aliphatic compound, and preferably increase the stability and life of the catalyst.
- the invention relates to a catalytic distillation process for the oxidative hydroxylation of the aliphatic compounds to form the respective hydroxylated derivative at a temperature and a pressure that maintains at least a portion of the aliphatic compound in the liquid phase and manages the heat generated by the exothermic hydroxylation reaction. Reflux of the un-reacted aliphatic compound renders the reaction substantially isothermal. Reduced operating temperatures and heat management maximize the catalyst life by reducing and in some cases preventing catalyst coking.
- Aliphatic compounds that can be used as a feedstock can be saturated or unsaturated, linear, branched or cyclic.
- One aliphatic compound or a mixture of aliphatic compounds can be used as feedstock.
- the feedstock aliphatic compounds preferably have carbon atom numbers in the range of 6 to 30.
- the aliphatic compounds for example, can be paraffins, olefins, acetylenes, alicyclics, aldehydes, ketones, and alcohols, optionally substituted with halogens, aromatics, epoxides, nitriles and/or (additional) carbonyl groups.
- the aliphatic compounds can contain aromatic rings, the hydroxylation does not occur at the aromatic ring carbons.
- Preferred feedstocks include, for example, paraffins and/or olefins, more preferably having average carbon numbers in the range of 10-18 and alkylbenzenes having average carbon numbers in the range of 16-20.
- An especially preferred feedstock contains a mixture of saturated aliphatic compounds comprising a major amount of saturated aliphatic compounds having carbon atoms in the range of 15 to 18.
- Aliphatic compounds may be obtained from crude oil distillation fractions. Such crude oil distillation fractions may be treated to partially or, more preferably, completely remove sulphur and/or nitrogen containing components.
- One source of distillation fractions that can be used are paraffin fractions derived from hydrotreated kerosene that may contain a mixture of c 9 ⁇ c 18 paraffins.
- An additional source of aliphatic compounds may be obtained from a paraffinic composition such as obtainable from a Fischer-Tropsch process or from an ethylene oligomerisation process (a composition which comprises predominantly linear paraffins) .
- Linear paraffins obtained in a Fischer-Tropsch synthesis are particularly preferred because Fischer-Tropsch products are generally very low in their content of sulphur and nitrogen and they are cost effective.
- a Fisher-Tropsch process catalytically hydrogenates CO to produce compositions containing aliphatic molecular chains (aliphatic compounds) .
- the Fischer-Tropsch products may or may not comprise oxygenates.
- the product obtained from the Fischer-Tropsch process can be hydroisomerised, hydrocracked and/or fractionated, for example, by distillation or otherwise, in order to isolate a paraffinic product of the desired composition as the aliphatic compound useful for the process of the invention.
- aliphatic compound is provided from a stream obtained from a Fischer-Tropsch process further treated in a hydroisomerization and/or hydrocracking process.
- Such a hydroisomerisation process and/or subsequent separation are known, for example from US-A-5, 866,748 and US-B-6, 184 , 431, which are incorporated herein by reference.
- Distilled is used herein to mean the compound will vaporize and condense over a defined temperature range at a given pressure. Such that even high molecular weight aliphatic compounds can be hydroxylated using the process of the present invention.
- the hydroxylation reaction occurs simultaneously with the distillation, the hydroxylated product being removed from a catalytic zone as it is formed. Removal of the hydroxylated product minimizes side reactions and decomposition of the hydroxylated product.
- the distillation zone of the reactor is maintained at a temperature and a pressure sufficient to maintain any un-reacted aliphatic compound that travels from the catalytic zone to the distillation zone in the vapour phase, preferably at or above the boiling point of the aliphatic compound at a given pressure and a temperature that is below the boiling point of the hydroxylated product at the given pressure.
- the un-reacted aliphatic compound that travels from the catalytic zone to the distillation zone eventually reaches a point in the reactor where it boils, and as a result, the temperature of the reactor is controlled by the boiling point of the aliphatic compound at the system pressure.
- an aliphatic compound is hydroxylated under catalytic distillation conditions to form a hydroxylated product having a higher boiling point than the un-reacted aliphatic compound.
- the hydroxylation reaction is preferably catalyzed by an oxidation catalyst in the presence of an oxidant in a catalytic distillation reactor, also called distillation column reactor, at conditions that also allow for fractional distillation.
- the oxidation catalyst is preferably a molecular sieve catalyst, preferably a catalyst comprising zeolite.
- the catalytic distillation reactor comprises a catalytic zone and a distillation zone.
- the "catalytic zone” is defined as the portion of the reactor containing the catalyst where the oxidant and aliphatic react to form hydroxylated product.
- distillation zone also called the “fractionation zone” is defined as the portion of the reactor adapted to separate the hydroxylated product from the un-reacted aliphatic compound.
- the distillation zone is a conventional fractionation column design, preferably integral with and downstream of the reaction zone.
- the hydroxylated product has a higher boiling point than the oxidant and the un-reacted compound, and is separated from un-reacted aliphatic compound in the distillation zone of the reactor.
- the temperature along the reactor will vary depending upon the reactants and the products. The highest temperature will be in the bottom of the reactor, in the distillation zone, and the temperature along the column will be the boiling point of the composition at that point in the column under a given pressure.
- the reactor preferably is operated at a temperature and a pressure effective to vaporize the un- reacted aliphatic compound as it approaches the distillation zone of the reactor while maintaining the hydroxylated product in the liquid phase.
- the oxidant preferably remains in a gaseous state and un-reacted oxidant is withdrawn as overhead.
- the hydroxylated product is withdrawn from the distillation zone and any un-reacted compound may be allowed to reflux or it may be withdrawn from the distillation zone and added to the original feed as makeup.
- liquid phase In the catalytic distillation reactor, there exists both a liquid phase, or internal reflux, and a vapour phase.
- the liquid phase is more dense than a gas phase and allows for a more dense concentration of molecules for reaction over the catalyst.
- the fractionation or distillation separates hydroxylated product from un- reacted materials, providing the benefits of a combined liquid phase and vapour phase system while avoiding continual contact between the catalyst, the reactants, and the products.
- a number of possible catalytic distillation reactor configurations are useful with the present invention, including but not limited to an upflow reactor, a downflow reactor, and a horizontal flow reactor.
- the reactor contains a reaction or catalytic zone sized to accommodate a fixed catalyst bed and a distillation zone designed to separate the hydroxylated product from un- reacted materials.
- the distillation zone is integral with the reaction or catalytic zones. Examples of catalytic distillation reactors that can be used are found in U.S. Patent Nos .
- the catalytic zone and the distillation zone are in a single column.
- the catalytic zone contains an amount of catalyst and the distillation zone contains a number of conventional separation trays.
- the feed (stock) preferably is delivered to the column above the catalyst and the oxidant is fed to the column below the catalyst. Any un-reacted aliphatic compound is either withdrawn from the column once it leaves the catalytic zone, preferably as a vapour, and supplied as makeup or allowed to reflux.
- the overhead is withdrawn from the column above the catalytic zone and can contain a mixture consisting mostly of oxidant and a small amount of un-reacted compound.
- the oxidant preferably is separated from the un-reacted compound by conventional means and recycled as makeup.
- Suitable oxidation catalysts are those that will catalyzed the hydroxylation of the aliphatic compound in the presence of an oxidant.
- Oxidation catalysts that can be used include but are not necessarily limited to catalysts comprising molecular sieves (molecular sieve catalysts) , including zeolites and non-zeolite materials and mixtures thereof.
- the preferred zeolite catalysts contain one or more modified zeolites preferably in the acidic form. These zeolites should contain pore dimensions large enough to admit the entry of the aliphatic compounds.
- the preferred zeolites include, for example, zeolites of the structural types MFI (e.g., ZSM-5 ), MEL(e.g., ZSM-11), FER (e.g., ferrierite and ZSM-35) , FAU (e.g., zeolite Y) , BEA (e.g., beta) ,MFS (e.g., ZSM-57) , NES (e.g. NU-87), MOR (e.g.
- MFI e.g., ZSM-5
- MEL e.g., ZSM-11
- FER e.g., ferrierite and ZSM-35
- FAU e.g., zeolite Y
- BEA e.g., beta
- MFS
- CHA e.g., chabazite
- MTT e.g., ZSM-23
- MWW e.g., MCM-22 and SSZ-25
- EUO e.g. EU-1, ZSM-50, and TPZ-3
- OFF e.g., offretite
- MTW e.g., ZSM-12
- zeolites ITQ-1, ITQ-2, MCM-56, MCM-49, ZSM-48, SSZ-35, SSZ-39 and zeolites of the mixed crystalline phases such as, for example, zeolite PSH-3.
- zeolites The structural types and references to the synthesis of the various zeolites can be found in the "Atlas of Zeolite Structure Types" (published on behalf of the Structure Commission of the International Zeolite Association), by .M. Meier, D.H. Olson and Ch. Baerlocher, published by Butterworth- Heinemann, fourth revised edition, 1996. Such zeolites are commercially available from Zeolyst International, Inc. and Exxon Mobil Corporation. More preferably, the zeolite is a crystalline alumino-silicate that can contain trace amounts of boron from raw materials without on purpose adding boron sources to enrich boron content.
- the zeolite catalyst preferably comprises at least one metal selected from the group consisting of ruthenium, rhodium, iron, magnesium, cobalt, copper, titanium, and iridium, preferably from about 0.01 wt . % to about 5 wt.%, most preferably from about 0.1 wt . % to about 1.5 wt.%.
- the metal can be incorporated into the catalyst by any means known to those skilled in the art for incorporating metals into zeolites such as, by ion exchange, impregnation, co-mulling, physical admixing or during synthesis of the catalyst.
- the zeolite catalyst contains an amount of iron, preferably up to about 5 wt.%, more preferably from about 0.01 wt.% to about 1.5 wt.%. Additional examples of zeolite catalysts that can be used can be found in U.S. Patent Nos. 5,762,777; 5,808,167; 5,110,995;
- Non-zeolitic molecular sieves also may be used to catalyze the hydroxylation of aliphatics.
- Preferred non- zeolitic molecular sieves that can be used include but are not necessarily limited to microporous aluminium phosphates (AlPO's) or silica aluminium phosphates
- SAPO's SAPO's
- metals that are capable of being oxidized and reduced, such as the preferred metals, Co, V, Mn, Mg, Cu, Ti, and Fe.
- These catalysts consist of AlPO's or SAPO's with a fraction of the Al or phosphate ions being replaced during synthesis by a transition metal ion, from about 0.001 wt.% to about 0.6 wt.%, preferably 0.01 wt.% to about 0.4 wt.%.
- a Mn- containing AlPO has been shown to hydroxylate dodecene to dodecanol using air as the oxidant as described in Chem . Commun . 1999, pp.
- transition metal may be incorporated into the framework of the catalyst after synthesis of the catalyst using known means including but not necessarily limited to ion exchange, impregnation, co-mulling, and physical admixing. Additional examples of non-zeolitic molecular sieves that can be used and their methods of preparation can be found in U.S. Patent Nos. 4,683,217 and 4,758,419; European patent nos. EP 0 043 562, EP 0 158 976; J. Phys . Chem. 1990, vol. 94, pp. 6425-6464, and pp. 6431-6435.
- the vanadium-peroxide complexes can be used to hydroxylate aliphatic compounds. A description of this method can be found in U.S. Patent 5,912,391, incorporated by reference herein.
- any suitable oxidant may be used.
- preferred oxidants include but are not necessarily limited to, nitrous oxide, oxygen, air, and mixtures thereof, of which nitrous oxide is especially preferred.
- Nitrous oxide is a preferred oxidant for use with zeolite catalysts.
- the molar ratio of oxidant to aliphatic compound is from about 1:1000 to about 100:1, preferably from about 1:1000 to about 10:1, most preferably from about 1:100 to aboutl:!. In practice, the oxidant to aliphatic compound ratio is the stoichiometric ratio that will yield the desired product and allow safe operation.
- paraffins any saturated or unsaturated, aliphatic compound, preferably having carbon atoms in the range of 6 to 30.
- aliphatic compounds having an average carbon atom number in the range of from 8 to 20 e.g., certain paraffins and/or olefins
- the preferred feedstock is a paraffin or a cycloparaffin, respectively.
- the hydroxylated products will be CI ⁇ - I Q range alcohols or C]_Q-C]_2 range alcohols, respectively.
- catalytic distillation is carried out in a distillation column reactor at a temperature and pressure effective to hydroxylate the paraffin while fractionating or removing the hydroxylated product, the alcohol of the paraffin, from the oxidant and un-reacted paraffin.
- the temperature in the distillation zone of the reactor is higher than the temperature in the catalytic zone of the reactor.
- the temperature within the reactor is from about 50 °C, preferably from about 125 °C, more preferably from about 275 °C, to about 450 °C, preferably to about 425 °C, more preferably to about 390 °C such that the lower boiling components are vaporized and migrate toward the upper portion of the reactor while the higher boiling components migrate toward the lower portion of the reactor.
- the temperature in the lower portion of the column preferably is higher than the boiling point of paraffin but lower than the boiling point of the alcohol product to achieve an effective separation of the alcohol product from the paraffin.
- the pressure in the column is preferably in the range from about 0.2 atm to about 50 atm, preferably from about 0.5 atm to about 30 atm.
- Partial pressure of the feed in the column is in the range of from about 0.01 atm, preferably from 1 atm, more preferably from about 2 atm, to about 40 atm, preferably to about 30 atm, more preferably to about 25 atm.
- Inert (not reactive to the reactants) gases such as for example, nitrogen and argon can be used to dilute the reactants to achieve a lower partial pressure of the reactants.
- the temperature and pressure can be adjusted within the above referenced ranges by a person skilled in the art, by taking into account the critical temperature and pressure of the feedstock in such a way as to operate the reaction zone below such supercritical temperature and pressure.
- the hydroxylation reaction is preferably carried out at the reaction zone at a temperature in the range of about 270 °C to about 425 °C and a pressure in the range of about 5 to about 15 atm.
- the hydroxylation reaction is preferably carried out at the reaction zone at a temperature in the range of about 175 °C to about 345 °C and a pressure in the range of about 5 to about 15 atm.
- the paraffin may be added at any point in the reactor, for example it may be added above or to the fixed bed catalyst or to the reflux as makeup. At least a portion of the paraffin, preferably from about 10% to about 100%, is fed to the reactor in a liquid state.
- the oxidant preferably is a gas, and is preferably fed to the reactor at a point below the catalyst bed allowing the oxidant to flow upward into the catalyst bed where the oxidant contacts and reacts with the paraffin.
- the paraffin contacts the catalyst and the oxidant, and the paraffin is hydroxylated to form the alcohol product of paraffin.
- the resulting alcohol has a higher boiling point than paraffin, which allows for easy separation by fractional distillation.
- hexadecanol has a higher boiling point of 344 °C than hexadecane of 287 °C, which allows for easy separation by fractional distillation.
- the overhead taken from the distillation column preferably is partially condensed to separate the un- reacted paraffin from the un-reacted oxidant.
- the partially condensed overheads are passed to an accumulator where paraffin is collected and the gaseous oxidant is taken off.
- the paraffin and the oxidant can be fed back to the distillation column.
- heat generated by the hydroxylation reaction is removed from the reactor by the reflux of the un-reacted feedstock, allowing for isothermal operation of the system. Regulating the heat in the reactor also extends the catalyst life.
- the process can be used to hydroxylate other aliphatic compounds such as branched olefins to produce branched alcohols that are useful as surfactants.
- Linear alcohols may be produced by hydroxylating linear olefins in a similar manner.
- FIG. 1 illustrates one embodiment of the present invention for the production of a hydroxylated aliphatic or cyclic product.
- a distillation column reactor 10 has a middle portion that contains a catalyst 12 and a lower portion of the reactor that contains a conventional distillation column 14 with a sufficient number of trays to allow for the separation of the hydroxylated product from any un-reacted feed.
- the feedstock is fed to the reactor through line 16 above the catalyst 12 and the oxidant gas is fed to reactor 10 through line 18 below the catalyst 12.
- the reaction is exothermic and is initiated by contacting the oxidant and the feedstock in the presence of the catalyst.
- the hydroxylated products will have a higher boiling point than the un-reacted feedstock and the oxidant and is recovered from the column via line 20.
- the temperature in the reactor below the catalyst bed is higher than the boiling point of the feedstock and lower than the boiling point of the hydroxylated product to facilitate the separation of the un-reacted feedstock from the hydroxylated product.
- Un- reacted feedstock can be withdrawn from the reactor 10 via line 22 and added as makeup to the fresh feedstock fed through line 16 into the reactor 10. Alternatively, the un-reacted feedstock is allowed to reflux.
- the oxidant is withdrawn as overhead through line 24 and passed to a condenser 26 to separate any entrained feedstock from the oxidant. The recovered oxidant may then be added as makeup via line 28 to the fresh oxidant feed.
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Priority Applications (9)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
DZ013340A DZ3340A1 (en) | 2000-04-27 | 2001-04-26 | PROCESS FOR THE HYDROXYLATION OF ALIPHATIC COMPOUNDS |
AU70498/01A AU765188B2 (en) | 2000-04-27 | 2001-04-26 | Process for catalytic hydroxylation of, saturated or unsaturated, aliphatic compounds |
DE60104535T DE60104535T2 (en) | 2000-04-27 | 2001-04-26 | PROCESS FOR HYDROXYLATION OF ALIPHATIC COMPOUNDS |
MXPA02010512A MXPA02010512A (en) | 2000-04-27 | 2001-04-26 | Process for catalytic hydroxylation of, saturated or unsaturated, aliphatic compounds. |
JP2001578382A JP4290369B2 (en) | 2000-04-27 | 2001-04-26 | Method for hydroxylating aliphatic compounds |
AT01949301T ATE272036T1 (en) | 2000-04-27 | 2001-04-26 | METHOD FOR HYDROXYLATION OF ALIPHATIC COMPOUNDS |
CA002407408A CA2407408A1 (en) | 2000-04-27 | 2001-04-26 | Process for the catalytic hydroxylation of, saturated or unsaturated, aliphatic compounds |
EP01949301A EP1276707B1 (en) | 2000-04-27 | 2001-04-26 | Process for the hydroxylation of aliphatic compounds |
NO20025095A NO20025095L (en) | 2000-04-27 | 2002-10-23 | Process for catalytic hydroxylation of saturated or unsaturated aliphatic compounds |
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
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US55992600A | 2000-04-27 | 2000-04-27 | |
US09/559,926 | 2000-04-27 |
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WO2001081284A2 true WO2001081284A2 (en) | 2001-11-01 |
WO2001081284A3 WO2001081284A3 (en) | 2002-07-11 |
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PCT/EP2001/004854 WO2001081284A2 (en) | 2000-04-27 | 2001-04-26 | Process for the hydroxylation of aliphatic compounds |
Country Status (17)
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US (1) | US6548718B2 (en) |
EP (1) | EP1276707B1 (en) |
JP (1) | JP4290369B2 (en) |
CN (1) | CN1184175C (en) |
AR (1) | AR033669A1 (en) |
AT (1) | ATE272036T1 (en) |
AU (1) | AU765188B2 (en) |
CA (1) | CA2407408A1 (en) |
DE (1) | DE60104535T2 (en) |
DZ (1) | DZ3340A1 (en) |
GC (1) | GC0000280A (en) |
MX (1) | MXPA02010512A (en) |
MY (1) | MY126925A (en) |
NO (1) | NO20025095L (en) |
RU (1) | RU2280638C2 (en) |
WO (1) | WO2001081284A2 (en) |
ZA (1) | ZA200209168B (en) |
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- 2001-04-25 GC GCP20011311 patent/GC0000280A/en active
- 2001-04-26 AT AT01949301T patent/ATE272036T1/en not_active IP Right Cessation
- 2001-04-26 DZ DZ013340A patent/DZ3340A1/en active
- 2001-04-26 EP EP01949301A patent/EP1276707B1/en not_active Expired - Lifetime
- 2001-04-26 CN CNB018097138A patent/CN1184175C/en not_active Expired - Fee Related
- 2001-04-26 MY MYPI20011965A patent/MY126925A/en unknown
- 2001-04-26 RU RU2002131796/04A patent/RU2280638C2/en active
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- 2001-04-26 JP JP2001578382A patent/JP4290369B2/en not_active Expired - Fee Related
- 2001-04-26 CA CA002407408A patent/CA2407408A1/en not_active Abandoned
- 2001-04-26 AU AU70498/01A patent/AU765188B2/en not_active Ceased
- 2001-04-26 WO PCT/EP2001/004854 patent/WO2001081284A2/en active IP Right Grant
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2002
- 2002-10-23 NO NO20025095A patent/NO20025095L/en not_active Application Discontinuation
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Cited By (1)
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WO2015013350A1 (en) * | 2013-07-25 | 2015-01-29 | Shell Oil Company | PROCESS FOR PREPARING C10 to C30 ALCOHOLS |
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GC0000280A (en) | 2006-11-01 |
CA2407408A1 (en) | 2001-11-01 |
DZ3340A1 (en) | 2001-11-01 |
CN1184175C (en) | 2005-01-12 |
MXPA02010512A (en) | 2003-05-14 |
RU2280638C2 (en) | 2006-07-27 |
EP1276707B1 (en) | 2004-07-28 |
US20020002312A1 (en) | 2002-01-03 |
ATE272036T1 (en) | 2004-08-15 |
DE60104535T2 (en) | 2005-08-04 |
JP2003531183A (en) | 2003-10-21 |
DE60104535D1 (en) | 2004-09-02 |
AR033669A1 (en) | 2004-01-07 |
JP4290369B2 (en) | 2009-07-01 |
ZA200209168B (en) | 2003-10-03 |
US6548718B2 (en) | 2003-04-15 |
NO20025095L (en) | 2002-12-20 |
EP1276707A2 (en) | 2003-01-22 |
MY126925A (en) | 2006-10-31 |
AU765188B2 (en) | 2003-09-11 |
AU7049801A (en) | 2001-11-07 |
CN1429187A (en) | 2003-07-09 |
NO20025095D0 (en) | 2002-10-23 |
WO2001081284A3 (en) | 2002-07-11 |
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