WO2001074969A3 - Process for softening fischer-tropsch wax with mild hydrotreating - Google Patents

Process for softening fischer-tropsch wax with mild hydrotreating Download PDF

Info

Publication number
WO2001074969A3
WO2001074969A3 PCT/US2001/040314 US0140314W WO0174969A3 WO 2001074969 A3 WO2001074969 A3 WO 2001074969A3 US 0140314 W US0140314 W US 0140314W WO 0174969 A3 WO0174969 A3 WO 0174969A3
Authority
WO
WIPO (PCT)
Prior art keywords
fischer
wax
tropsch wax
tropsch
synthesis gas
Prior art date
Application number
PCT/US2001/040314
Other languages
French (fr)
Other versions
WO2001074969A2 (en
Inventor
Robert Jay Wittenbrink
Daniel Francis Riley
Original Assignee
Exxonmobil Res & Eng Co
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Family has litigation
First worldwide family litigation filed litigation Critical https://patents.darts-ip.com/?family=24165735&utm_source=google_patent&utm_medium=platform_link&utm_campaign=public_patent_search&patent=WO2001074969(A3) "Global patent litigation dataset” by Darts-ip is licensed under a Creative Commons Attribution 4.0 International License.
Priority to KR1020027013145A priority Critical patent/KR100745922B1/en
Priority to AU5386201A priority patent/AU5386201A/en
Priority to AU2001253862A priority patent/AU2001253862B2/en
Priority to EP01927411A priority patent/EP1268712B2/en
Priority to DE60104835T priority patent/DE60104835T3/en
Application filed by Exxonmobil Res & Eng Co filed Critical Exxonmobil Res & Eng Co
Priority to CA2403971A priority patent/CA2403971C/en
Priority to AT01927411T priority patent/ATE273369T1/en
Priority to BR0109730-0A priority patent/BR0109730A/en
Priority to JP2001572646A priority patent/JP2003529665A/en
Publication of WO2001074969A2 publication Critical patent/WO2001074969A2/en
Publication of WO2001074969A3 publication Critical patent/WO2001074969A3/en
Priority to NO20024807A priority patent/NO20024807L/en

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G73/00—Recovery or refining of mineral waxes, e.g. montan wax
    • C10G73/02—Recovery of petroleum waxes from hydrocarbon oils; Dewaxing of hydrocarbon oils
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G73/00—Recovery or refining of mineral waxes, e.g. montan wax
    • C10G73/42—Refining of petroleum waxes
    • C10G73/44—Refining of petroleum waxes in the presence of hydrogen or hydrogen-generating compounds

Landscapes

  • Chemical & Material Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
  • Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)
  • Catalysts (AREA)

Abstract

A novel process for forming hydrocarbon waxes from synthesis gas is disclosed. This invention teaches a process whereby a Fischer-Tropsch wax can be formulated such that the wax softness as defined by ASTM Standard Test Method for Needle Penetration of waxes (ASTM D- 1321) can be adjusted to within a region most preferred for end use applications while simultaneously removing undesirable impurities, such as oxygenates (e.g., primary alcohols), olefins, and trace levels of aromatics. In a Fischer-Tropsch reactor, Fischer-Tropsch wax is formed from synthesis gas in a catalyzed reaction. The Fischer-Tropsch wax is then subjected to a relatively mild hydroprocessing over a hydroisomerization catalyst under conditions such that essentially no boiling point conversion is obtained, but yet chemical conversions (e.g., hydrogenation and mild isomerization) occur yielding a high purity, hydrocarbon wax product of reduced hardness.
PCT/US2001/040314 2000-04-04 2001-03-16 Process for softening fischer-tropsch wax with mild hydrotreating WO2001074969A2 (en)

Priority Applications (10)

Application Number Priority Date Filing Date Title
JP2001572646A JP2003529665A (en) 2000-04-04 2001-03-16 Method for softening Fischer-Tropsch wax by mild hydrotreatment
AU5386201A AU5386201A (en) 2000-04-04 2001-03-16 Process for softening fischer-tropsch wax with mild hydrotreating
AU2001253862A AU2001253862B2 (en) 2000-04-04 2001-03-16 Process for softening fischer-tropsch wax with mild hydrotreating
EP01927411A EP1268712B2 (en) 2000-04-04 2001-03-16 Process for softening fischer-tropsch wax with mild hydrotreating
DE60104835T DE60104835T3 (en) 2000-04-04 2001-03-16 WEAKNESS PROCESSING FOR FISCHER TROPHY GROWTH THROUGH HYDRO TREATMENT UNDER MILD CONDITIONS
KR1020027013145A KR100745922B1 (en) 2000-04-04 2001-03-16 Process for softening fischer-tropsch wax with mild hydrotreating
CA2403971A CA2403971C (en) 2000-04-04 2001-03-16 Process for softening fischer-tropsch wax with mild hydrotreating
AT01927411T ATE273369T1 (en) 2000-04-04 2001-03-16 PLASTICIZING PROCESS FOR FISCHER TROPICAL WAXES BY HYDROTREATMENT UNDER MILD CONDITIONS
BR0109730-0A BR0109730A (en) 2000-04-04 2001-03-16 Process for forming hydrocarbon wax product from synthesis gas and hydrocarbon wax product
NO20024807A NO20024807L (en) 2000-04-04 2002-10-04 Procedure for softening Fischer-Tropsch wax by mild hydration refining

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US09/542,894 US6776898B1 (en) 2000-04-04 2000-04-04 Process for softening fischer-tropsch wax with mild hydrotreating
US09/542,894 2000-04-04

Publications (2)

Publication Number Publication Date
WO2001074969A2 WO2001074969A2 (en) 2001-10-11
WO2001074969A3 true WO2001074969A3 (en) 2002-08-29

Family

ID=24165735

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/US2001/040314 WO2001074969A2 (en) 2000-04-04 2001-03-16 Process for softening fischer-tropsch wax with mild hydrotreating

Country Status (15)

Country Link
US (1) US6776898B1 (en)
EP (1) EP1268712B2 (en)
JP (1) JP2003529665A (en)
KR (1) KR100745922B1 (en)
AR (1) AR029504A1 (en)
AT (1) ATE273369T1 (en)
AU (2) AU5386201A (en)
BR (1) BR0109730A (en)
CA (1) CA2403971C (en)
DE (1) DE60104835T3 (en)
ES (1) ES2225527T5 (en)
NO (1) NO20024807L (en)
PT (1) PT1268712E (en)
TW (1) TW576870B (en)
WO (1) WO2001074969A2 (en)

Families Citing this family (17)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
MXPA03007088A (en) 2001-02-13 2003-11-18 Shell Int Research Lubricant composition.
AR032930A1 (en) 2001-03-05 2003-12-03 Shell Int Research PROCEDURE TO PREPARE AN OIL BASED OIL AND GAS OIL
AR032932A1 (en) 2001-03-05 2003-12-03 Shell Int Research PROCEDURE TO PREPARE A LUBRICANT BASED OIL AND OIL GAS
AR032941A1 (en) 2001-03-05 2003-12-03 Shell Int Research A PROCEDURE TO PREPARE A LUBRICATING BASE OIL AND BASE OIL OBTAINED, WITH ITS VARIOUS USES
DE10126516A1 (en) * 2001-05-30 2002-12-05 Schuemann Sasol Gmbh Process for the preparation of microcrystalline paraffins
RU2280675C2 (en) * 2001-06-15 2006-07-27 Шелл Интернэшнл Рисерч Маатсхаппий Б.В. Micro-crystalline wax and method of production of such wax
DE10256431A1 (en) 2002-05-31 2004-01-15 SCHÜMANN SASOL GmbH Microcrystalline paraffin, process for the preparation of microcrystalline paraffins and use of the microcrystalline paraffins
EP1534802B1 (en) * 2002-07-18 2005-11-16 Shell Internationale Researchmaatschappij B.V. Process to prepare a microcrystalline wax and a middle distillate fuel
WO2006067104A1 (en) * 2004-12-20 2006-06-29 Shell Internationale Research Maatschappij B.V. Gasoline cracking
US20060222828A1 (en) * 2005-04-01 2006-10-05 John Boyle & Company, Inc. Recyclable display media
ATE432323T1 (en) 2005-11-10 2009-06-15 Shell Int Research BITUMEN COMPOSITION
RU2407777C2 (en) * 2006-03-30 2010-12-27 Ниппон Ойл Корпорейшн Diesel fuel composition
EP2142440B1 (en) 2007-05-10 2020-07-01 Shell International Research Maatschappij B.V. Paraffin wax composition
CN101724511B (en) * 2008-10-28 2012-02-29 中国石油化工股份有限公司 Candle raw material composition
CN111359542A (en) * 2019-03-15 2020-07-03 南京延长反应技术研究院有限公司 Micro-interface reinforced diesel hydrofining reaction system and method
CN114174474A (en) 2019-08-08 2022-03-11 国际壳牌研究有限公司 Microcrystalline wax
KR102365335B1 (en) 2019-12-12 2022-02-18 한국화학연구원 Direct Method for Preparing Liquid―phase Hydrocarbon Mixture of Gasoline Range by Using Syngas

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0145042A2 (en) * 1983-10-14 1985-06-19 Shell Internationale Researchmaatschappij B.V. Hydrocarbon conversion processes and modified refractory oxides which can be used in such processes
EP0435619A1 (en) * 1989-12-29 1991-07-03 Mobil Oil Corporation Wax hydroisomerization process
US5750819A (en) * 1996-11-05 1998-05-12 Exxon Research And Engineering Company Process for hydroconversion of paraffin containing feeds

Family Cites Families (26)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2668866A (en) † 1951-08-14 1954-02-09 Shell Dev Isomerization of paraffin wax
US2668790A (en) † 1953-01-12 1954-02-09 Shell Dev Isomerization of paraffin wax
US3658689A (en) † 1969-05-28 1972-04-25 Sun Oil Co Isomerization of waxy lube streams and waxes
JPS5242506A (en) † 1975-10-02 1977-04-02 Toa Nenryo Kogyo Kk Hydrotreating process of petroleum wax
FR2553430B1 (en) * 1983-10-14 1986-02-21 Shell Int Research PROCESS FOR THE HYDRO-ISOMERIZATION OF OIL WAXES
US4568663A (en) 1984-06-29 1986-02-04 Exxon Research And Engineering Co. Cobalt catalysts for the conversion of methanol to hydrocarbons and for Fischer-Tropsch synthesis
CA1312066C (en) * 1986-10-03 1992-12-29 William C. Behrmann Surface supported particulate metal compound catalysts, their use in hydrocarbon synthesis reactions and their preparation
CA1310287C (en) † 1987-12-18 1992-11-17 Exxon Research And Engineering Company Process for the hydroisomerization of fischer-tropsch wax to produce lubricating oil
US5059299A (en) † 1987-12-18 1991-10-22 Exxon Research And Engineering Company Method for isomerizing wax to lube base oils
US4943672A (en) 1987-12-18 1990-07-24 Exxon Research And Engineering Company Process for the hydroisomerization of Fischer-Tropsch wax to produce lubricating oil (OP-3403)
CA2038774C (en) † 1990-04-04 2001-09-25 Eric Herbolzheimer Slurry bubble column
US5348982A (en) 1990-04-04 1994-09-20 Exxon Research & Engineering Co. Slurry bubble column (C-2391)
US5032249A (en) 1990-08-28 1991-07-16 Conoco Inc. Fractionation process for petroleum wax
FR2676749B1 (en) † 1991-05-21 1993-08-20 Inst Francais Du Petrole PROCESS FOR HYDROISOMERIZATION OF PARAFFINS FROM THE FISCHER-TROPSCH PROCESS USING H-Y ZEOLITE CATALYSTS.
US5187138A (en) † 1991-09-16 1993-02-16 Exxon Research And Engineering Company Silica modified hydroisomerization catalyst
MY108946A (en) 1992-07-14 1996-11-30 Shell Int Research Process for the distillation of fischer-tropsch products
EP0583836B2 (en) † 1992-08-18 2002-02-13 Shell Internationale Researchmaatschappij B.V. Process for the preparation of hydrocarbon fuels
RU2116332C1 (en) † 1992-10-28 1998-07-27 Шелл Интернэшнл Рисерч Маатсхаппий Б.В. Method and catalyst for preparing oil body
US5260239A (en) 1992-12-18 1993-11-09 Exxon Research & Engineering Company External catalyst rejuvenation system for the hydrocarbon synthesis process
EP0668342B1 (en) 1994-02-08 1999-08-04 Shell Internationale Researchmaatschappij B.V. Lubricating base oil preparation process
MY115180A (en) † 1994-10-24 2003-04-30 Shell Int Research Synthetic wax for food applications
ZA97448B (en) † 1996-02-02 1997-07-31 Exxon Research Engineering Co Hydroisomerization with reduced hydrocracking.
US5911874A (en) * 1996-06-28 1999-06-15 Exxon Research And Engineering Co. Raffinate hydroconversion process
CA2267115C (en) * 1996-11-05 2004-12-21 Exxon Research And Engineering Company Supported hydroconversion catalyst and process of preparation thereof
US5935417A (en) * 1996-12-17 1999-08-10 Exxon Research And Engineering Co. Hydroconversion process for making lubricating oil basestocks
US5905094A (en) * 1997-10-21 1999-05-18 Exxon Research And Engineering Co. Slurry hydrocarbon synthesis with reduced catalyst attrition and deactivation

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0145042A2 (en) * 1983-10-14 1985-06-19 Shell Internationale Researchmaatschappij B.V. Hydrocarbon conversion processes and modified refractory oxides which can be used in such processes
EP0435619A1 (en) * 1989-12-29 1991-07-03 Mobil Oil Corporation Wax hydroisomerization process
US5750819A (en) * 1996-11-05 1998-05-12 Exxon Research And Engineering Company Process for hydroconversion of paraffin containing feeds

Also Published As

Publication number Publication date
DE60104835T3 (en) 2009-12-24
NO20024807D0 (en) 2002-10-04
ES2225527T5 (en) 2009-11-02
US6776898B1 (en) 2004-08-17
DE60104835D1 (en) 2004-09-16
CA2403971C (en) 2010-10-05
EP1268712B1 (en) 2004-08-11
CA2403971A1 (en) 2001-10-11
WO2001074969A2 (en) 2001-10-11
AU2001253862B2 (en) 2005-10-27
EP1268712B2 (en) 2009-06-10
NO20024807L (en) 2002-10-04
EP1268712A2 (en) 2003-01-02
DE60104835T2 (en) 2005-09-15
KR100745922B1 (en) 2007-08-02
ATE273369T1 (en) 2004-08-15
KR20030007490A (en) 2003-01-23
JP2003529665A (en) 2003-10-07
ES2225527T3 (en) 2005-03-16
AR029504A1 (en) 2003-07-02
BR0109730A (en) 2004-02-10
AU5386201A (en) 2001-10-15
PT1268712E (en) 2004-12-31
TW576870B (en) 2004-02-21

Similar Documents

Publication Publication Date Title
WO2001074969A3 (en) Process for softening fischer-tropsch wax with mild hydrotreating
KR102291290B1 (en) Method for ketonisation of biological material
JP4740128B2 (en) Method for producing Fischer-Tropsch product
US20080161615A1 (en) Method of converting feedstocks coming from renewable sources into high-quality gas-oil fuel bases
US20110015459A1 (en) Process for the preparation of light fuels
UA90907C2 (en) Process for manufacture of diesel range hydrocarbons
US11970666B2 (en) Method for producing renewable fuel
AU2001253862A1 (en) Process for softening fischer-tropsch wax with mild hydrotreating
US20050145544A1 (en) Methods for treating organic compounds and treated organic compounds
WO2005047424A3 (en) Integrated process for the production of lubricating base oils and liquid fuels from fischer-tropsch materials using split feed hydroprocessing
WO2003040067A3 (en) Slurry hydrocarbon synthesis with liquid hydroisomerization in the synthesis reactor
EP1272592B9 (en) Process for adjusting the hardness of fischer-tropsch wax by blending
CA2419909C (en) Process for the purification of isooctane and/or diisobutylene
FI129664B (en) Method for producing renewable fuel
JP2845872B2 (en) Treatment method for heavy oil pyrolysis light fraction
CN113046126A (en) Method for improving diesel oil yield of process for producing diesel oil by Fischer-Tropsch synthesis oil
KR970001512A (en) How to convert residual hydrocarbon oil

Legal Events

Date Code Title Description
AK Designated states

Kind code of ref document: A2

Designated state(s): AU BR CA JP KR NO SG ZA

AL Designated countries for regional patents

Kind code of ref document: A2

Designated state(s): AT BE CH CY DE DK ES FI FR GB GR IE IT LU MC NL PT SE TR

121 Ep: the epo has been informed by wipo that ep was designated in this application
DFPE Request for preliminary examination filed prior to expiration of 19th month from priority date (pct application filed before 20040101)
AK Designated states

Kind code of ref document: A3

Designated state(s): AU BR CA JP KR NO SG ZA

AL Designated countries for regional patents

Kind code of ref document: A3

Designated state(s): AT BE CH CY DE DK ES FI FR GB GR IE IT LU MC NL PT SE TR

WWE Wipo information: entry into national phase

Ref document number: 2002/07431

Country of ref document: ZA

Ref document number: 200207431

Country of ref document: ZA

WWE Wipo information: entry into national phase

Ref document number: 2403971

Country of ref document: CA

WWE Wipo information: entry into national phase

Ref document number: 1020027013145

Country of ref document: KR

ENP Entry into the national phase

Ref country code: JP

Ref document number: 2001 572646

Kind code of ref document: A

Format of ref document f/p: F

WWE Wipo information: entry into national phase

Ref document number: 2001253862

Country of ref document: AU

WWE Wipo information: entry into national phase

Ref document number: 2001927411

Country of ref document: EP

WWP Wipo information: published in national office

Ref document number: 2001927411

Country of ref document: EP

WWP Wipo information: published in national office

Ref document number: 1020027013145

Country of ref document: KR

WWG Wipo information: grant in national office

Ref document number: 2001927411

Country of ref document: EP

WWG Wipo information: grant in national office

Ref document number: 2001253862

Country of ref document: AU