WO2001064698A3 - Macrocyclic ligands and complexes thereof - Google Patents

Macrocyclic ligands and complexes thereof Download PDF

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Publication number
WO2001064698A3
WO2001064698A3 PCT/GB2001/000911 GB0100911W WO0164698A3 WO 2001064698 A3 WO2001064698 A3 WO 2001064698A3 GB 0100911 W GB0100911 W GB 0100911W WO 0164698 A3 WO0164698 A3 WO 0164698A3
Authority
WO
WIPO (PCT)
Prior art keywords
complexes
macrocyclic ligands
macrocyclic
ligands
iii
Prior art date
Application number
PCT/GB2001/000911
Other languages
French (fr)
Other versions
WO2001064698A2 (en
Inventor
Peter Gerald Edwards
Paul David Newman
Original Assignee
Univ Cardiff
Peter Gerald Edwards
Paul David Newman
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Univ Cardiff, Peter Gerald Edwards, Paul David Newman filed Critical Univ Cardiff
Priority to AU2001237557A priority Critical patent/AU2001237557A1/en
Publication of WO2001064698A2 publication Critical patent/WO2001064698A2/en
Publication of WO2001064698A3 publication Critical patent/WO2001064698A3/en

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Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F17/00—Metallocenes
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F17/00—Metallocenes
    • C07F17/02—Metallocenes of metals of Groups 8, 9 or 10 of the Periodic Table
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F9/00—Compounds containing elements of Groups 5 or 15 of the Periodic Table
    • C07F9/02—Phosphorus compounds
    • C07F9/547—Heterocyclic compounds, e.g. containing phosphorus as a ring hetero atom
    • C07F9/6564—Heterocyclic compounds, e.g. containing phosphorus as a ring hetero atom having phosphorus atoms, with or without nitrogen, oxygen, sulfur, selenium or tellurium atoms, as ring hetero atoms
    • C07F9/6568—Heterocyclic compounds, e.g. containing phosphorus as a ring hetero atom having phosphorus atoms, with or without nitrogen, oxygen, sulfur, selenium or tellurium atoms, as ring hetero atoms having phosphorus atoms as the only ring hetero atoms
    • C07F9/65683—Heterocyclic compounds, e.g. containing phosphorus as a ring hetero atom having phosphorus atoms, with or without nitrogen, oxygen, sulfur, selenium or tellurium atoms, as ring hetero atoms having phosphorus atoms as the only ring hetero atoms the ring phosphorus atom being part of a phosphine

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Biochemistry (AREA)
  • General Health & Medical Sciences (AREA)
  • Molecular Biology (AREA)

Abstract

A complex of formula (I) where M represents Fe(II), Co(III) or Mn(I); n is 0 or 1; x represents an optionally substituted ring system selected from (a), (b).
PCT/GB2001/000911 2000-03-01 2001-03-01 Macrocyclic ligands and complexes thereof WO2001064698A2 (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
AU2001237557A AU2001237557A1 (en) 2000-03-01 2001-03-01 Macrocyclic ligands and complexes thereof

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
GB0004962A GB0004962D0 (en) 2000-03-01 2000-03-01 Macrocyclic ligands and complexes thereof
GB0004962.7 2000-03-01

Publications (2)

Publication Number Publication Date
WO2001064698A2 WO2001064698A2 (en) 2001-09-07
WO2001064698A3 true WO2001064698A3 (en) 2002-01-31

Family

ID=9886760

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/GB2001/000911 WO2001064698A2 (en) 2000-03-01 2001-03-01 Macrocyclic ligands and complexes thereof

Country Status (3)

Country Link
AU (1) AU2001237557A1 (en)
GB (1) GB0004962D0 (en)
WO (1) WO2001064698A2 (en)

Citations (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO1990012050A1 (en) * 1989-04-07 1990-10-18 Salutar, Inc. Chelants
EP0458397A2 (en) * 1990-05-21 1991-11-27 Unilever N.V. Bleach activation
WO1994000439A1 (en) * 1992-06-30 1994-01-06 Unilever Plc Synthesis of 1,4,7-triazacyclononane derivatives
WO1994004485A1 (en) * 1992-08-19 1994-03-03 Mallinckrodt Medical, Inc. LIGANDS FOR Ga-68 PET HEART APPLICATIONS
JPH06256512A (en) * 1993-03-05 1994-09-13 Rikagaku Kenkyusho Laminated macrocyclic polyamine derivative and its production
GB2279950A (en) * 1993-07-13 1995-01-18 Unilever Plc Synthesis of N,N'-bis (2-hydroxyethyl) ethylenediamines
WO1997007123A1 (en) * 1995-08-11 1997-02-27 University College Cardiff Consultants Limited Cyclic phosphines, phosphine oxides and complexes thereof
JPH10279411A (en) * 1997-03-31 1998-10-20 Lion Corp Mildew-removing agent composition

Patent Citations (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO1990012050A1 (en) * 1989-04-07 1990-10-18 Salutar, Inc. Chelants
EP0458397A2 (en) * 1990-05-21 1991-11-27 Unilever N.V. Bleach activation
WO1994000439A1 (en) * 1992-06-30 1994-01-06 Unilever Plc Synthesis of 1,4,7-triazacyclononane derivatives
WO1994004485A1 (en) * 1992-08-19 1994-03-03 Mallinckrodt Medical, Inc. LIGANDS FOR Ga-68 PET HEART APPLICATIONS
JPH06256512A (en) * 1993-03-05 1994-09-13 Rikagaku Kenkyusho Laminated macrocyclic polyamine derivative and its production
GB2279950A (en) * 1993-07-13 1995-01-18 Unilever Plc Synthesis of N,N'-bis (2-hydroxyethyl) ethylenediamines
WO1997007123A1 (en) * 1995-08-11 1997-02-27 University College Cardiff Consultants Limited Cyclic phosphines, phosphine oxides and complexes thereof
JPH10279411A (en) * 1997-03-31 1998-10-20 Lion Corp Mildew-removing agent composition

Non-Patent Citations (18)

* Cited by examiner, † Cited by third party
Title
BADER K.G.: "Synthese des 1,4,7-Triphenyl-1,4,7-triphosphacyclononans", 1995, DIPLOMARBEIT, TECHNISCHE UNIVERSITÄT, MUNICH, XP002179387 *
COLES ET AL.: "1,5,9-Triphosphacyclododecane complexes of Molybdenum and tungsten", J. CHEM. SOC. DALTON TRANSACTIONS, no. 7, 1995, pages 1139 - 1145, XP001024877 *
COLES S J ET AL: "THE LIBERATION, CHARACTERISATION AND X-RAY CRYSTAL STRUCTURE OF 1,5,9-TRIPHOSPHA-1,5,-TRIS(2-PROPYL)CYCLODODECANE", CHEMICAL COMMUNICATIONS, ROYAL SOCIETY OF CHEMISTRY, GB, no. 3, 7 February 1996 (1996-02-07), pages 293 - 294, XP000608172, ISSN: 1359-7345 *
CONOLLY: "The synthesis and characterisation of Cr,Mo;W and Mn carbonyl Thioether complexes", 1998, XVIIITH INTERNATIONAL CONFERENCE ON ORGANOMETALLIC CHEMISTRY, BOOK OF ABSTRACTS PART II, MUNICH, XP002179386 *
DIEL B N ET AL: "METAL-TEMPLATED SYNTHESIS OF A MACROCYCLIC TRIPHOSPHINE-MOLYBDENUM COMPLEX, FAC-(CO)3MO(PHC3H6)3", JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, AMERICAN CHEMICAL SOCIETY, WASHINGTON, DC, US, vol. 104, no. 17, 1982, pages 4700 - 4701, XP000608359, ISSN: 0002-7863 *
EDWARDS ET AL.: "Chromium and molybdenum complexes of tertiary alkyl and pendant donor triphosphamacrocycles", J. CHEM. SOC. DALTON TRANSACTIONS, no. 2, 1997, pages 193 - 197, XP001024878 *
EDWARDS ET AL.: "Triphosphamacrocycle complexes of rhodium(III), iron(II) and ruthenium(II) - Erratum to Document cited in CA127:319054", J. CHEM. SOC. DALTON TRANSACTIONS, no. 22, 1997, pages 4462, XP001024880 *
EDWARDS ET AL.: "Triphosphamacrocycle complexes of rhodium(III), iron(II) and ruthenium(II)", J. CHEM. SOC. DALTON TRANSACTIONS, no. 18, 1997, pages 3201 - 3206, XP001024879 *
EDWARDS P G ET AL: "STEREOSELECTIVE SYNTHESIS OF 1,5,9-TRIPHOSPHACYCLODODECANE AND TERTIARY DERIVATIVES", INORGANIC CHEMISTRY, AMERICAN CHEMICAL SOCIETY, EASTON, US, vol. 35, no. 16, 1996, pages 4563 - 4568, XP000607383, ISSN: 0020-1669 *
HELPS ET AL: "Syntheses of C- and N-functionalized derivatives of 1,5,9-triazacyclododecane", JOURNAL OF THE CHEMICAL SOCIETY, PERKIN TRANSACTIONS 1, CHEMICAL SOCIETY. LETCHWORTH, GB, no. 11, 1989, pages 2079 - 2082, XP002161005, ISSN: 1472-7781 *
JONES ET AL.: "The template synthesis of triaryl functionalised 1,5,9-triphosphacyclododecane on molybdenum usind organocopper reagents", J. CHEM. SOC. DALTON TRANSACTIONS, no. 7, 1999, pages 1045 - 1046, XP001024876 *
KYBA ET AL.: "POLYPHOSPHINO MACROCYCLIC LIGAND SYSTEMS", JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, AMERICAN CHEMICAL SOCIETY, WASHINGTON, DC, US, vol. 99, 1977, pages 8053 - 8054, XP000608358, ISSN: 0002-7863 *
KYBA ET AL.: "Synthesis of unusual Phosphine Ligands...", INORGANIC CHEMISTRY, vol. 24, 1985, pages 1613 - 1616, XP001031895 *
NICHOLAS PAUL COOPER: "The Synthesis of Triphosphine Macrocycles and Complexes of other multidentate Phosphines", 1991, UNIVERSITY OF WALES, PH.D. THESIS, XP002179385 *
PATENT ABSTRACTS OF JAPAN vol. 018, no. 656 (C - 1286) 13 December 1994 (1994-12-13) *
PATENT ABSTRACTS OF JAPAN vol. 1999, no. 01 29 January 1999 (1999-01-29) *
PRICE ET AL.: "A new template for the synthesis of triphosphorous macrocycles", CHEMICAL COMMUNICATIONS, no. 11, 2000, pages 899 - 900, XP001024883 *
SCOTT: "Novel Heterocycles comprising alternating Phosphorous Atoms and alkyne units", JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, vol. 112, no. 21, 1990, pages 7823 - 7825, XP001024881 *

Also Published As

Publication number Publication date
GB0004962D0 (en) 2000-04-19
WO2001064698A2 (en) 2001-09-07
AU2001237557A1 (en) 2001-09-12

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