WO2001062344A1 - Apparatus and method for suppressing fires - Google Patents
Apparatus and method for suppressing fires Download PDFInfo
- Publication number
- WO2001062344A1 WO2001062344A1 PCT/GB2001/000740 GB0100740W WO0162344A1 WO 2001062344 A1 WO2001062344 A1 WO 2001062344A1 GB 0100740 W GB0100740 W GB 0100740W WO 0162344 A1 WO0162344 A1 WO 0162344A1
- Authority
- WO
- WIPO (PCT)
- Prior art keywords
- container
- fire
- nozzles
- atomised
- water
- Prior art date
Links
Classifications
-
- A—HUMAN NECESSITIES
- A62—LIFE-SAVING; FIRE-FIGHTING
- A62C—FIRE-FIGHTING
- A62C13/00—Portable extinguishers which are permanently pressurised or pressurised immediately before use
- A62C13/02—Portable extinguishers which are permanently pressurised or pressurised immediately before use with pressure gas produced by chemicals
- A62C13/22—Portable extinguishers which are permanently pressurised or pressurised immediately before use with pressure gas produced by chemicals with incendiary substances producing pressure gas
-
- A—HUMAN NECESSITIES
- A62—LIFE-SAVING; FIRE-FIGHTING
- A62C—FIRE-FIGHTING
- A62C35/00—Permanently-installed equipment
- A62C35/02—Permanently-installed equipment with containers for delivering the extinguishing substance
- A62C35/023—Permanently-installed equipment with containers for delivering the extinguishing substance the extinguishing material being expelled by compressed gas, taken from storage tanks, or by generating a pressure gas
Definitions
- the present invention relates generally to apparatus for suppressing fires, and to a method of suppressing a fire in a protected environment in order to afford occupants thereof a window of opportunity to escape without inhaling the hot combustion products which are a major cause of injury and death in fires.
- Water-jet fire extinguishers comprising a generally cylindrical container housing water and physical or chemical means for generating a propellant gas (or stored compressed gas) when triggered manually by an operator utilising a lever or other mechanism to rupture an enclosed bulb or other frangible container or to open a valve. This drives the water in the vessel out in a jet which is directed by the user at the seat of the flame.
- the theory of such extinguishers is that the water will cool the combustible material, partly by the transfer of heat to the water to raise it to its boiling point, and partly by the evaporation of the water, and the steam will displace the air thus starving the fire.
- Powder extinguishers which comprise a container of a fire retardant powder which is driven from the vessel explosively by the triggering mechanism and directed at the fire by the user.
- fire retardant chemicals primarily act by denying the fire access to oxygen.
- the cylinder is filled with a fire suppressant or extinguishant material although it is described that dry powder or water may also be used.
- the pressure generator operates to raise the pressure within the vessel very rapidly when triggered, to a very high level (1200 psi (8.27 MPa)) the rate of increase being in the order of 500 psi/ms (3.45 MPams).
- the apparatus is intended to operate in such a way that substantially all of the extinguishant is discharged from the apparatus within less than 70 ms.
- US patent 5 224 550 describes another fire suppressant or explosion protection system in which a detonating cord or explosive fuse is caused to ignite to cause a rapid generation of gas so as rapidly to discharge the fire suppressant materials from the container.
- the present invention is, on the other hand, based on the premise that in the majority of environments at risk to fire there is no predictable seat for the fire and, consequently, the fire suppressant apparatus or extinguisher device must be capable of attacking a fire wherever in the environment it commences. This is particularly true, for example, in the domestic environment where individual rooms such as kitchens, dining rooms, lounges etc have furniture which itself is potentially combustible, as well as carpets, curtains and other soft furnishings all spaced in a configuration which differs from room to room. No automatic self-contained fire extinguisher currently available can provide protection automatically for such environments.
- the present invention seeks to provide an improved self-contained fire extinguisher or suppressant apparatus which does not require a high pressure vessel, which can be located in a convenient location within a room and nevertheless provide protection for the entire volume of the room, is not subject to the loss over time of pressure in a propellant for a liquid medium contained in the apparatus, and which is capable, when activated, of expelling the fire suppressant medium in the form of a mist or fog.
- fire suppressant apparatus comprises a container for a liquid fire suppressant material, at least one low pressure atomisation nozzle in communication with the interior of the container, and means for generating a propellant gas within the container whereby to maintain the interior of the container at a superatmospheric pressure sufficient to cause the suppressant liquid to be atomised as it passes through the nozzle for a time period sufficient to evacuate the contents of the container.
- the means for generating a propellant gas preferably comprise the combustible, non- explosive fuel material which burns without requiring atmospheric oxygen.
- the charge of such material is preferably sufficient to burn over a period of at least several seconds, preferably from 10 to 20 seconds.
- the present invention is based on the concept of creating a window of opportunity for persons within a closed environment subject to a fire to escape alive and undamaged by inhalation of hot combustion products or noxious gases.
- a mist or fog of fire suppressant material especially if the fire suppressant is water, the atmosphere is cooled by the Joule effect of atomisation, which lowers the temperature of the atomised droplets below ambient temperature.
- the atomisation nozzle is capable of producing atomised droplets of the fire suppressant liquid at least a major proportion of which are less than lOO ⁇ m in size, and preferably between 25 ⁇ m and 75 ⁇ m, such droplets will be suspended in the atmosphere for a considerable period of time, between 3 and 15 seconds. Indeed, tests have established that water droplets of lOO ⁇ m fall from a height of 2 m in approximately 3 seconds whereas water droplets at 50 ⁇ m will remain suspended for 30 seconds and water droplets of lO ⁇ m for 10 minutes.
- the fog thus generated remains carried on the atmosphere and can be influenced by atmospheric movements. It will be appreciated that, in a closed environment such as the room in a building or the passenger compartment of a railway train, aircraft or road going vehicle, the occurrence of a fire at one point in the closed environment will cause circulated convection currents.
- the atomised droplets issuing from the fire suppressant apparatus can be carried by the convection currents down to a low level and laterally towards the source of the fire where they can act both to cool it, partly due to the low temperature of the water droplets and partly by the absorption of the heat for vaporisation, at the same time excluding atmospheric oxygen from the region of the fire.
- the entire volume of the protected environment is thus quickly filled with water droplets suppressing the generation of hot combustion products and allowing anyone in the environment a window of opportunity to escape to raise the alarm, obtain further fire fighting equipment or to call for professional fire fighters.
- the mist or fog generated by the fire suppressant apparatus of the present invention fails to extinguish the fire completely, it nevertheless suppresses it for sufficiently long to allow anyone present to escape and/or institute further measures for fire fighting.
- the gas generating device will continue to generate propellant gas for 15 to 20 seconds, which is slightly less than the amount of time necessary to eject the entirety of the liquid fire suppressant from the container. The residual pressure in the container will then eject the last of the liquid without generating excess pressure or jetting gases straight from the combustion.
- a single atomisation nozzle may be provided, it is within the ambit of the present invention to provide apparatus having a plurality of low pressure nozzles all communicating with the interior of the container. Whether the nozzles deliver atomised droplets of fire suppressant liquid in different directions or the same direction is immaterial since it is the convection currents within the room which are expected to convey the droplets to the fire rather than the kinetic energy of the droplets as they are ejected from the apparatus.
- the nozzle or nozzles is or are mounted recessed below the surface of the container and covered with a or a respective cap or cover engaged to the container in such a way that it or they can be pushed off by the increased pressure when the propellant gas is generated.
- a small pocket of gas, in particular air under the or each cap, which is compressed by the working pressure of the liquid to blow off the cap or caps.
- the surface of the fire suppressant apparatus can be painted so as to conceal the precise location of the nozzles.
- the or each cap or cover may be snap-engaged in an or a respective opening in the container.
- a particularly convenient shape for the container is substantially spherical, although a cylindrical shape with domed ends may also be employed.
- a tetrahedron shape may be employed so that the apparatus can be fitted into a corner of the compartment and have a substantially flat face directed in towards the compartment in a way which does not draw attention to the presence of the apparatus in the carriage.
- the ignition of the gas-generating means may be achieved by electrical or electronic ignition means which, preferably, includes a heat sensor operable to trigger the combustion of the gas generator means if the ambient temperature rises above a threshold value.
- the ignition means may also include means for detecting the rate of change of the ambient temperature, operable in conjunction with the said heat sensor to trigger the combustion of the gas generator if the rate of temperature increase exceeds a predetermined rate and/or if the absolute temperature exceeds a predetermined threshold at least for a predetermined time interval.
- the container does not have to withstand high pressures it may be formed as a low pressure plastics vessel.
- plastics material is of particular advantage since it is light in weight and allows the atomisation nozzles to be integrally formed in the body of the container.
- the present invention also comprehends a method of surpressing or extinguishing a fire in a protected environment, comprising generating a mist or fog of atomised water droplets at least the majority of which are less than lOO ⁇ m size, and preferably between 25 ⁇ m and 75 ⁇ m, and allowing the atomised droplets to be conveyed to the fire by the convection currents set up within the protected environment by the fire itself.
- the water from which the atomised droplets are formed may have a fire retardant chemical dissolved or suspended therein so as to provide a further enhanced fire suppressant effect.
- FIG. 1 is a sectional view of apparatus embodying the principles of the present invention.
- Figure 2 is a side view of a nozzle suitable for use in the apparatus of Figure 1.
- the apparatus shown comprises a generally spherical container 11 of low-pressure plastics material sufficiently large to contain about 3 litres of water. A diameter of about 20 centimetres, equivalent to a small football, is sufficient for this purpose.
- the container has two upstanding lugs 12, 13 by means of which it can be suspended from a bracket generally indicated 14 which can be securely fixed to a wall such as by the fixing pins or screws 15, 16 illustrated.
- an L- shaped bracket such as that illustrated by the reference numeral 14 in the drawing is preferred as this allows the device to be secured to a wall rather than the ceiling, but nevertheless to be located substantially at the level of the ceiling.
- nozzles 17, 18, housing respective low pressure atomisation nozzles 19, 20 are formed in the wall of the container 11 in the wall of the container 11.
- These nozzles are not of the pin-impact type, but rather a line-impact type which allows accurate atomisation of liquid passing therethrough over an extended contact line, which can be further extended by making it helical.
- individual discrete nozzles are illustrated, it is possible for nozzles to a suitable design to be formed integrally upon moulding of the container 11. Nozzles of this nature have the advantage of being particularly robust, and tests have established they will still function largely to produce atomised droplets even if slightly damaged by impact.
- the nozzles should produce a majority of atomised droplets in the region of 50 ⁇ m at the working pressures generated by a propellant gas the means for generation of which will be described in more detail below.
- the time taken for them to fall from ceiling height to a floor is in the region of 30 seconds, which is long enough for the convection currents set up by a fire to convey them across a room to exert their fire-suppressant influence.
- the nozzles 19, 20 do not need to impart to the water droplets sufficient kinetic energy to convey them large distances, it being sufficient for them to be carried away from the immediate vicinity of the nozzle, and this results in avoiding the need for high pressure propellants.
- Figure 2 illustrates, on an enlarged scale, a suitable nozzle, represented as the nozzle 19, having a body 30 with a threaded section 31, for screwing the nozzle into position in an opening in the wall of the container 11, and a forwardly extending helical impact atomising member 32 which breaks the spray exiting an orifice (not shown) in the body 30 with a very fine aerosol with particles mostly in the region of 50 ⁇ m.
- the helical input line ensures a high rate of delivery even at the fine atomisation rate mentioned above.
- the propellant gas is generated by a combustible material, for example one produced by Atlantic Research Company under the Trade Name "Arcite” which is combustible even in an enclosed environment without an external supply of oxygen. Moreover, this material burns slowly and is stable and safe to be left in a domestic environment for long periods without risk of ignition.
- a combustible material for example one produced by Atlantic Research Company under the Trade Name "Arcite” which is combustible even in an enclosed environment without an external supply of oxygen. Moreover, this material burns slowly and is stable and safe to be left in a domestic environment for long periods without risk of ignition.
- the combustible material 21 is housed in a container 22, which may be a metal or ceramic casing having openings 23, 24 to allow gas resulting from combustion to escape into the interior chamber 25 of the container 11. These openings 23, 24 are open to the interior chamber and allow liquid to enter the casing 22. Upon generation of appropriate pressure by combustion of the material 21, any liquid in the casing 22 is ejected into the interior 25 of the container 11 along with the generated gas.
- the combustible material 21 is ignitable even in the presence of water and the combustion thereof is unaffected by the presence of water.
- Combustion of the material 21 is initiated by an electronic ignitor 26 powered by a battery 27 which also supplies a heat sensor 28 the output signal from which triggers the operation of the ignitor 26.
- a processor 29 which includes a battery state circuit and a timer, is connected to the sensor 28 and to the ignitor 26 and programmed to determine the rate of increase of temperature as well as the absolute temperature so that anomalous temperature variations for a short period, or slowly varying temperatures not likely to indicate the presence of a fire do not trigger spurious energisations of the ignitor 26.
- the interior 25 of the vessel 11 is filled with water which completely immerses the gas generator 22 with no included air.
- covers 26, 27 which are snap engaged into place in the recesses 17, 18 and the outer surfaces of which are substantially flush with the outer surface of the container 11. These covers 26, 27 cannot be removed manually from the recesses 17, 18 as there are no points of purchase at which an individual may dislodge the caps or covers from their position. Tampering or corruption therefore is unlikely.
- the apparatus of the present invention thus comprises a self-contained low-pressure device which produces a water fog when triggered.
- the atomised droplets of the water fog have a limited droplet size which allows them to remain in the atmosphere for an extended time period, and the gas generator operates to generate gas for an extended time period so that the water within the chamber 25 is expelled relatively slowly, typically in a time period of 15 to 20 seconds without the generation of a high pressure so that the vessel 11 can be made of a low pressure plastics material.
- the propellant charge burns to produce nitrogen, carbon dioxide and water which are, themselves, not noxious gases, and the excess gas within the vessel when the water is all expelled, itself escapes through the nozzles and helps further to disperse the atomised water droplets towards the seat of the fire.
- the method of fire suppression using a low-energy water fog has the advantage that the fog itself acts as a heat shield between the fire and the rest of the room, and absorbs radiated heat as well as slowing the convective flow by lowering the temperature of the fire seat. This, therefore, stops the fire jumping from one source of combustible material to another by radiated heat.
- the low-temperature water droplets can be inhaled by a person in the room without damage.
- Fire retardant chemicals may be included in aqueous solution or suspension in the water within the chamber 25, and this offers the advantage of providing a smoke cleansing effect by absorbing smoke particles in the atomised droplets. This is beneficial as human lungs can handle the inhalation of water droplets better than the inhalation of smoke particles.
- the device may be used as a security device by incorporating a dye in the liquid within the chamber 25 and having further triggering means linked to an intruder detector such as a passive infra-red detector.
- the dye may, for example, be one which only shows up under ultra-violet light. If an intruder enters the room when the alarm is set, therefore, the device of the invention is triggered to issue a fine mist which will saturate the intruders skin and clothes as well as coating any items within the room so that both the intruder himself (or herself) and any stolen goods can readily be identified at a later date.
- the gas generating system in the canister 22 is shown located at an upper position within the container 11 it could be located at other positions, for example at a lower position between the nozzles 19, 20, or at an "equatorial" position midway between the upper and lower positions. It could even be freely located within the interior, unsecured to the interior wall, as long as it is connected to the wire from the sensor 29 for triggering purposes, of course, the replaceable battery would then have to be positioned differently.
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- Health & Medical Sciences (AREA)
- Public Health (AREA)
- Business, Economics & Management (AREA)
- Emergency Management (AREA)
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Fire-Extinguishing By Fire Departments, And Fire-Extinguishing Equipment And Control Thereof (AREA)
- Feeding, Discharge, Calcimining, Fusing, And Gas-Generation Devices (AREA)
Abstract
Description
Claims
Priority Applications (5)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
AU33921/01A AU3392101A (en) | 2000-02-26 | 2001-02-22 | Apparatus and method for suppressing fires |
IL15147001A IL151470A (en) | 2000-02-26 | 2001-02-22 | Apparatus and method for suppressing fires |
US10/220,078 US20030168225A1 (en) | 2000-02-26 | 2001-02-22 | Apparatus and method for suppressing fires |
EP01905957A EP1259297A1 (en) | 2000-02-26 | 2001-02-22 | Apparatus and method for suppressing fires |
JP2001561402A JP2003525668A (en) | 2000-02-26 | 2001-02-22 | Fire suppression device and method |
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
GB0004458A GB2359487A (en) | 2000-02-26 | 2000-02-26 | Fire extinguishing or security device |
GB0004458.6 | 2000-02-26 |
Publications (1)
Publication Number | Publication Date |
---|---|
WO2001062344A1 true WO2001062344A1 (en) | 2001-08-30 |
Family
ID=9886380
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
PCT/GB2001/000740 WO2001062344A1 (en) | 2000-02-26 | 2001-02-22 | Apparatus and method for suppressing fires |
Country Status (7)
Country | Link |
---|---|
EP (1) | EP1259297A1 (en) |
JP (1) | JP2003525668A (en) |
KR (1) | KR20030025906A (en) |
AU (1) | AU3392101A (en) |
GB (1) | GB2359487A (en) |
IL (1) | IL151470A (en) |
WO (1) | WO2001062344A1 (en) |
Cited By (7)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO2004030765A1 (en) | 2002-10-02 | 2004-04-15 | Michael Porat | Emergency escape mask |
NL1039848A (en) * | 2012-10-11 | 2014-04-14 | Bandit N V | Adjustable connector for fog-generating device. |
NL1039847C2 (en) * | 2012-10-11 | 2014-04-14 | Bandit N V | Removable connector for fog-generating device. |
WO2013104351A3 (en) * | 2012-01-10 | 2014-05-01 | Chs Gmbh | Protection device |
WO2015049500A1 (en) * | 2013-10-02 | 2015-04-09 | Plumis, Ltd. | Marker deployment |
CN116771406A (en) * | 2023-06-28 | 2023-09-19 | 山东科技大学 | Water curtain combustion and explosion suppression device capable of being pushed by rapidly generating gas and application method thereof |
EP4417314A1 (en) | 2023-02-15 | 2024-08-21 | Universite Mohamed VI Polytechnique | Method for processing phosphate ores containing heavy metals by reverse flotation |
Families Citing this family (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
RU2615971C1 (en) * | 2015-12-17 | 2017-04-11 | Леонид Олегович Дубрава | Device for bulk firefighting |
RU2649548C1 (en) * | 2017-04-11 | 2018-04-03 | Леонид Олегович Дубрава | Device for three-dimensional aerosol fire fighting |
Citations (7)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US2631675A (en) * | 1949-12-24 | 1953-03-17 | Specialties Dev Corp | Discharge apparatus |
US3773111A (en) | 1971-04-05 | 1973-11-20 | B Dunn | Fire extinguishing apparatus |
US5224550A (en) | 1987-03-11 | 1993-07-06 | Parker Hannifin Corporation | Explosion suppression system |
EP0693303A2 (en) | 1994-07-21 | 1996-01-24 | Kidde Technologies Inc. | Discharging fire and explosion suppressants |
US5887662A (en) * | 1992-10-20 | 1999-03-30 | Sundholm; Goeran | Method and installation for fighting fire |
EP0956883A1 (en) * | 1998-05-15 | 1999-11-17 | Snpe | Fire extinguishing device with thermochemical gas generator |
GB2337700A (en) * | 1998-05-27 | 1999-12-01 | Phillip Raymond Michael Denne | Fire extinguisher |
Family Cites Families (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
GB1100271A (en) * | 1964-01-24 | 1968-01-24 | George Brough Ltd | Improvements in or relating to fire prevention |
US3684019A (en) * | 1971-05-07 | 1972-08-15 | Howard W Emmons | Method for fighting a fire |
JPS5086900A (en) * | 1973-12-06 | 1975-07-12 | ||
GB2136687B (en) * | 1983-03-10 | 1986-10-29 | Frederick Bradley | Fire suppressing device |
US5660236A (en) * | 1994-07-21 | 1997-08-26 | Kidde Technologies, Inc. | Discharging fire and explosion suppressants |
WO2000015304A1 (en) * | 1998-09-01 | 2000-03-23 | Vladimir Ivanovich Kuznetsov | Powder fire-extinguishing module and variants |
-
2000
- 2000-02-26 GB GB0004458A patent/GB2359487A/en not_active Withdrawn
-
2001
- 2001-02-22 WO PCT/GB2001/000740 patent/WO2001062344A1/en not_active Application Discontinuation
- 2001-02-22 IL IL15147001A patent/IL151470A/en not_active IP Right Cessation
- 2001-02-22 AU AU33921/01A patent/AU3392101A/en not_active Abandoned
- 2001-02-22 JP JP2001561402A patent/JP2003525668A/en active Pending
- 2001-02-22 EP EP01905957A patent/EP1259297A1/en not_active Withdrawn
- 2001-02-22 KR KR1020027011194A patent/KR20030025906A/en not_active Application Discontinuation
Patent Citations (7)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US2631675A (en) * | 1949-12-24 | 1953-03-17 | Specialties Dev Corp | Discharge apparatus |
US3773111A (en) | 1971-04-05 | 1973-11-20 | B Dunn | Fire extinguishing apparatus |
US5224550A (en) | 1987-03-11 | 1993-07-06 | Parker Hannifin Corporation | Explosion suppression system |
US5887662A (en) * | 1992-10-20 | 1999-03-30 | Sundholm; Goeran | Method and installation for fighting fire |
EP0693303A2 (en) | 1994-07-21 | 1996-01-24 | Kidde Technologies Inc. | Discharging fire and explosion suppressants |
EP0956883A1 (en) * | 1998-05-15 | 1999-11-17 | Snpe | Fire extinguishing device with thermochemical gas generator |
GB2337700A (en) * | 1998-05-27 | 1999-12-01 | Phillip Raymond Michael Denne | Fire extinguisher |
Non-Patent Citations (1)
Title |
---|
See also references of EP1259297A1 |
Cited By (12)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO2004030765A1 (en) | 2002-10-02 | 2004-04-15 | Michael Porat | Emergency escape mask |
WO2013104351A3 (en) * | 2012-01-10 | 2014-05-01 | Chs Gmbh | Protection device |
US9573005B2 (en) | 2012-01-10 | 2017-02-21 | Chs Gmbh | Protection device |
NL1039848A (en) * | 2012-10-11 | 2014-04-14 | Bandit N V | Adjustable connector for fog-generating device. |
NL1039847C2 (en) * | 2012-10-11 | 2014-04-14 | Bandit N V | Removable connector for fog-generating device. |
BE1021439B1 (en) * | 2012-10-11 | 2015-11-20 | Bandit N.V. | ADJUSTABLE CONNECTOR FOR FOG-GENERATING DEVICE |
BE1021440B1 (en) * | 2012-10-11 | 2015-11-20 | Bandit N.V. | REMOVABLE CONNECTOR FOR FOG-GENERATING DEVICES |
WO2015049500A1 (en) * | 2013-10-02 | 2015-04-09 | Plumis, Ltd. | Marker deployment |
US10074253B2 (en) | 2013-10-02 | 2018-09-11 | Plumis, Ltd. | Marker deployment |
EP4417314A1 (en) | 2023-02-15 | 2024-08-21 | Universite Mohamed VI Polytechnique | Method for processing phosphate ores containing heavy metals by reverse flotation |
WO2024172639A1 (en) | 2023-02-15 | 2024-08-22 | Universite Mohammed VI Polytechnique | Method for treating phosphate ores containing heavy metals by reverse flotation |
CN116771406A (en) * | 2023-06-28 | 2023-09-19 | 山东科技大学 | Water curtain combustion and explosion suppression device capable of being pushed by rapidly generating gas and application method thereof |
Also Published As
Publication number | Publication date |
---|---|
IL151470A (en) | 2005-11-20 |
KR20030025906A (en) | 2003-03-29 |
IL151470A0 (en) | 2003-04-10 |
AU3392101A (en) | 2001-09-03 |
GB0004458D0 (en) | 2000-04-19 |
GB2359487A (en) | 2001-08-29 |
EP1259297A1 (en) | 2002-11-27 |
JP2003525668A (en) | 2003-09-02 |
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