WO2001059806A1 - Through-the-lens collection of secondary particles for a focused ion beam system - Google Patents

Through-the-lens collection of secondary particles for a focused ion beam system Download PDF

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Publication number
WO2001059806A1
WO2001059806A1 PCT/US2001/004441 US0104441W WO0159806A1 WO 2001059806 A1 WO2001059806 A1 WO 2001059806A1 US 0104441 W US0104441 W US 0104441W WO 0159806 A1 WO0159806 A1 WO 0159806A1
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WO
WIPO (PCT)
Prior art keywords
target
lens
secondary particles
detector
primary
Prior art date
Application number
PCT/US2001/004441
Other languages
French (fr)
Inventor
Robert L. Gerlach
Mark W. Utlaut
Original Assignee
Fei Company
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Fei Company filed Critical Fei Company
Priority to AU2001238148A priority Critical patent/AU2001238148A1/en
Priority to EP01910553A priority patent/EP1259974A4/en
Priority to JP2001559034A priority patent/JP2003524867A/en
Publication of WO2001059806A1 publication Critical patent/WO2001059806A1/en

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Classifications

    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01JELECTRIC DISCHARGE TUBES OR DISCHARGE LAMPS
    • H01J37/00Discharge tubes with provision for introducing objects or material to be exposed to the discharge, e.g. for the purpose of examination or processing thereof
    • H01J37/02Details
    • H01J37/04Arrangements of electrodes and associated parts for generating or controlling the discharge, e.g. electron-optical arrangement or ion-optical arrangement
    • H01J37/08Ion sources; Ion guns
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01JELECTRIC DISCHARGE TUBES OR DISCHARGE LAMPS
    • H01J37/00Discharge tubes with provision for introducing objects or material to be exposed to the discharge, e.g. for the purpose of examination or processing thereof
    • H01J37/30Electron-beam or ion-beam tubes for localised treatment of objects
    • H01J37/305Electron-beam or ion-beam tubes for localised treatment of objects for casting, melting, evaporating, or etching
    • H01J37/3053Electron-beam or ion-beam tubes for localised treatment of objects for casting, melting, evaporating, or etching for evaporating or etching
    • H01J37/3056Electron-beam or ion-beam tubes for localised treatment of objects for casting, melting, evaporating, or etching for evaporating or etching for microworking, e. g. etching of gratings or trimming of electrical components
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01JELECTRIC DISCHARGE TUBES OR DISCHARGE LAMPS
    • H01J2237/00Discharge tubes exposing object to beam, e.g. for analysis treatment, etching, imaging
    • H01J2237/06Sources
    • H01J2237/08Ion sources
    • H01J2237/0822Multiple sources
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01JELECTRIC DISCHARGE TUBES OR DISCHARGE LAMPS
    • H01J2237/00Discharge tubes exposing object to beam, e.g. for analysis treatment, etching, imaging
    • H01J2237/06Sources
    • H01J2237/08Ion sources
    • H01J2237/0822Multiple sources
    • H01J2237/0825Multiple sources for producing different ions simultaneously
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01JELECTRIC DISCHARGE TUBES OR DISCHARGE LAMPS
    • H01J2237/00Discharge tubes exposing object to beam, e.g. for analysis treatment, etching, imaging
    • H01J2237/244Detection characterized by the detecting means

Definitions

  • the present invention relates to the field of focused ion beam (FIB) systems, and in particular, to the collection of secondary particles in FIB systems.
  • FIB focused ion beam
  • Thin film head trimming and other nanofabrication applications suffer from throughput limitations, that is, the focused ion beam systems are unable to process products as quickly as desired.
  • One approach to increasing processing speed is to increase the current in a given beam, thereby increasing the rate at which material is removed or deposited.
  • the second approach employs multiple FIB units, each having a separate ion source and acceleration
  • An object of the present invention is to provide for the collection of secondary
  • the present invention includes a method of increasing the throughput of a FIB
  • the invention also includes several novel aspects of the FIB system, including the modular design of the gun chambers, the design of the electrodes, including their electrical isolation, the secondary particle collection system, and the electrode voltage application scheme.
  • a preferred FIB system of the present invention comprises multiple ion guns, each preferably including a Liquid Metal Ion Source (LMIS) and associated with a corresponding FIB optical column.
  • LMIS Liquid Metal Ion Source
  • the beams from the multiple columns are directed to one or more targets in a primary vacuum chamber.
  • the multiple guns increase the number of ions impacting the target or targets and therefore increase the processing rate.
  • the multiple beams can operate
  • the multiple columns share a primary vacuum chamber and can share other facilities, such as power supplies, a computer and
  • each FIB gun is placed in a vacuum chamber, referred to as a gun
  • gun chambers each containing one or more FIB guns, can be placed in parallel to form a large array of guns for operating on one or more targets in the primary vacuum chamber.
  • ganged vacuum valve for each gun chamber can isolate the gun chamber from the main chamber.
  • the gun chambers can be evacuated and sealed prior to installation, thereby avoiding the loss of production that would occur if the gun chamber were evacuated after installation.
  • gun chambers can be replaced
  • a gun chamber can be replaced as a module in the field, with the repairs or replacements of individual guns
  • Each gun has a corresponding ion optical column, with some of the column elements preferably being placed below the guns in the main system chamber to form an array of columns.
  • the present invention also includes systems for collecting secondary particles.
  • secondary particles are collected along the optical axis of the ion beam column.
  • the secondary particles are then either deflected off the ion beam column axis to a detector or the secondary particles are detected by a detector positioned along
  • the on-axis detector may be positioned on
  • the secondary particles are accelerated through the final
  • This through-the-lens detector arrangement allows the sample to be placed close to the final lens, thus shortening its focal length and providing improved column optical performance (greater current into the same beam diameter).
  • the system for collecting secondary particles through the final ion lens can be used on multi-column or single column ion beam systems.
  • a conductive plate is used to detect the secondary particles.
  • FIG. 1 is a side, cross-sectional view of a single FIB column set containing five FIB columns.
  • FIG. 2 A is a top view of three column sets fastened together to form a 15 column
  • FIG. 2B is a side view of these three column sets.
  • FIG. 3 is an end cross sectional view of a gun set using high voltage insulators.
  • FIG. 4 is a cross-sectional view of a FIB column using a through-the-lens secondary
  • FIG. 5 is a cross-sectional view of another FIB column using a through-the-lens secondary particle detector.
  • FIG. 6 is an electron optics computer simulation of the secondary electron trajectories from the sample through the lenses of FIG. 4.
  • optical elements are sufficiently electrically isolated to maintain
  • the number of high voltage power is the required high operating voltages. In some embodiments, the number of high voltage power
  • the voltage level of the high voltage power supplies are also reduced from that of conventional
  • FIGS. 1, 2A, and 2B show a multi-column FIB array using LMIS's.
  • FIG. 1 shows a
  • multi-column FIB system 108 that includes a gun vacuum chamber 110 and a primary vacuum
  • Gun chamber 1 10 is a single, sealable vacuum chamber that includes a set of ion guns 114.
  • Gun chamber 110 can be replaced as a unit and has its own vacuum pump, preferably
  • an ion pump (not shown).
  • the entire gun chamber 1 10 can be replaced with another gun chamber 110 that is already evacuated to an ultra
  • multi-column system 108 does not need to remain out of production while the gun chamber is being evacuated.
  • Each ion gun 114 includes an emitter 120, a suppressor 122, an extractor 124, an
  • acceleration lens 126 a deceleration lens 128 and a ground element 169.
  • deceleration lens 128 a deceleration lens 128 and a ground element 169.
  • FIG. 1 shows a lens 1 comprising four lens elements, other lens designs can be used for lens 1.
  • lens 1 could alternatively be positioned in primary vacuum chamber 112.
  • Each ion gun 114 forms part of an ion optical column 136 that also includes an
  • each gun 114 selectively controls the bottom of each gun 114 .
  • the isolation valves 150 of the column in a gun chamber 1 10 are preferably "ganged,” that is, connected in a manner so that
  • the detectors 164 for the columns 136 are constructed
  • a gas injection system can optionally be used with apparatus of FIG. 1 to inject a gas for ion beam assisted deposition or for enhanced etching.
  • the gun elements that is, emitters 120, suppressors 122, extractors 124, acceleration lenses 126, deceleration lenses 128, and ground element 169 are preferably contained in gun chamber 1 10.
  • the number of guns in gun chamber 110 is preferably limited to about five. If one
  • the set of ganged isolation valves 150 for the set of guns simultaneously isolates the beam holes 168 in the ion beam paths at the bottom of gun chamber 110 from the primary vacuum chamber 112.
  • Valves 150 are preferably formed by a bar 172 that moves relative to bottom portion 174 of gun chamber 110. When valves 150 are open, the openings in bar 172 line up with the
  • holes in bar 172 are offset from the holes in bottom portion 174, and O-rings 176 form a seal between a solid portion of bar 172 and bottom portion 174.
  • Primary chamber 112 can be
  • primary chamber 1 12 can be
  • chamber 1 10 to primary chamber 1 12 are conventional and not shown.
  • FIG. 2A shows a top view of an arrangement of multiple linear gun chambers 110
  • FIG. 2 A shows an outlet 210 from each gun
  • FIG. 2B is a side view of the multiple gun chamber system of FIG. 2A.
  • FIG. 2B is a side view of the multiple gun chamber system of FIG. 2A.
  • FIG. 1 shows also a location for high voltage feed-throughs 212, a flange 214 at the top of a gun chamber 110, and an actuator 216 for ganged gate valves 150.
  • This construction technique can also be used to construct optical elements in the primary vacuum chamber. Using a single bar to form corresponding lens elements in different columns with a gun chamber can reduce the number of high voltage power
  • FIG. 3 is a cross-sectional view of a gun chamber 110 showing bars 310 used to form
  • Bars 310 form suppressors 122, extractors 124, acceleration lenses 126, and deceleration lenses 128. Bars 310 are electrically isolated from each other and from the chamber itself using HV (High Voltage) insulator disks 312 composed preferably of a ceramic material.
  • HV High Voltage
  • the assembly can optionally be
  • the optical elements can be formed directly by the holes in a conductive bar, as shown with regard to acceleration lenses 126. A common voltage is thus applied to all lenses formed by the bar, reducing the number of high voltage power supplies required for the multi- column system. The number of high voltage power supplies can be further reduced by using a
  • Optical elements can also be formed by inserts placed into holes in a bar.
  • FIG. 1 shows the use of lens inserts 178 in the bar 310 forming deceleration lenses 128.
  • the bar in which lenses 128 are formed is constructed from an insulating material, for example, a ceramic material such as alumina, and the lens inserts are composed of a conductive material, preferably a titanium alloy which has is low thermal coefficient of expansion that is similar to
  • the alumina bar provides high voltage isolation to the individual lenses
  • Voltage is applied to the individual lenses by wires connected to the lenses in a conventional manner, such as conductive silver epoxy or using connector pins.
  • metal films can be placed upon the insulator bar to replace the wires.
  • Another method of providing high voltage insulation to lenses 128 entails using a
  • conductive bar 310 with an insulating insert placed in a hole in the bar, and then a conductive lens placed in the insulating insert.
  • Such inserts can be glued into insulator material, which can
  • Lenses formed by inserts can also be post machined, that is,
  • individually isolate lenses can be particularly useful for suppressor lenses 122, extractor lenses 124, or individual elements of lens 1 or lens 2.
  • FIG. 1 shows inserts used only on the deceleration lens 128. Deceleration lens 128
  • Isolating lens elements allows the voltages in individual columns to be controlled. For example, the voltage on one of extractor lenses 124 can be individually boosted about 2 kV above the common extractor voltage to start or restart the individual emitter in the corresponding column.
  • the extractor lens 124 can then return to or near the common extractor voltage for normal operation.
  • Optical elements that are isolated can still use the common high voltage supply, but isolated elements can also be floated at a voltage above or below the common voltage, thereby
  • Charged particle signal detection capability for imaging can be accomplished by a traditional side mounted electron multiplier or scintillator means, or by other novel methods
  • channel plate detectors have been positioned along the ion column optical axis between the final lens and the sample, but channel plates at this location increase the lens focal
  • the ion beam column optical axis to a detector or the secondary particles are detected by a
  • the detector positioned along the optical axis and having a hole for passing the ion beam.
  • detector may be positioned on either side of the final lens.
  • the beam current can be greater than a nanoampere.
  • an amplifier or amplifiers can be attached directly to detector plate 164 below lens 2 to detect a current caused by secondary charged particles.
  • detectors 164 for the columns 136 are constructed so that each column's secondary electrons are independently detected.
  • the individual detectors could be
  • Detector 164 can be electrically biased to
  • TTL through-the-lens
  • secondary particles travel back through the final lens, they can be detected by an on-axis collection system, such as one similar to detectors 164 (Fig. 1), a channel plate, or a scintillation detector, or by a preferred off-axis detection system as described below.
  • an on-axis collection system such as one similar to detectors 164 (Fig. 1), a channel plate, or a scintillation detector, or by a preferred off-axis detection system as described below.
  • FIB column a short focal length final lens.
  • the optics in a FIB column is significantly different from a low voltage SEM column, such as the Krans et al. design.
  • a typical FIB column operates
  • the final lens is an einzel lens - the center element is at a high
  • This bending magnet is designed so as not to disturb the primary ion beam very much.
  • gallium primary ions have the same charge as electrons but each gallium ion has a mass about 160,000 times the mass of an electron. Furthermore, the electron energies are typically about 15 times less than the ion energy. Using Equation 2, we see that the cyclotron
  • radius for the primary ions is typically about 1550 times larger than the electron cyclotron radius
  • the disturbance to the primary ion beam path is small.
  • the path deviation is only about 1.2 milli-radians, which can be very easily corrected with beam steering. It can also be shown that the predominate aberration introduced into the primary ion beam by the magnetic field is chromatic and can mostly be neglected.
  • FIG. 4 shows such a TTL detection system for an ion column 410 in which low energy secondary electrons from the sample, having energies of about 5 eV (electron volts), are
  • the TTL system in FIG. 4 utilizes a magnetic deflector 414 to deflect the secondary electrons 418 off to the side while allowing the high mass-
  • An electron detector 424 such as a scintillator, continuous dynode multiplier, or channel plate, is then placed to the side for
  • a sample 426 and a lower lens element 428 are
  • An upper lens element 430 is biased to between
  • electrostatic deflector plates 432 and deflector 414 are biased to between about +500 and +5000 volts to continue this upward velocity of secondary
  • FIG. 6 is an electron optics computer simulation of the secondary electrons traveling from the sample back through the lens shown in FIG. 4.
  • the approximately 5 eV secondary electrons are accelerated rapidly by the lens element 440, which is at high positive potential, such
  • FIG. 5 shows an alternate ion column 508 design using a TTL secondary electron detector.
  • a sample 510 and a lower final lens element 512 are each biased about -2000 V
  • sample 510 and lower final lens element 512 can be biased to about +2000 V.
  • Center lens element 514 is biased to approximately +20,000 V.
  • electrostatic deflector elements 520 and deflector 414 need not be positively biased, which simplifies the electronics and the optics construction. If the ion beam systems include other
  • these devices are also biased to the same potential as the sample.
  • the apparatus in FIG. 4 also may be used to detect secondary positive ions from the sample.
  • the lens 2 element 440 is biased to a negative
  • FIG. 5 potentials in FIG. 5 may be changed to collect and detect positive secondary ions.
  • a quadrupole or other mass spectrometer can also be placed in the position of detector 424 to perform
  • the appropriate biasing of the column and detector may be employed to detect either positive or negative ions.
  • the ion beams are typically tilted
  • This +/- 3 degree tilt can be achieved, for example, by tilting every other row of
  • An advantage of the invention is an increase in the processing speed by providing a system including multiple ion guns capable of operating simultaneously on one or more targets.
  • Another advantage of the invention is that it provides a system in which the multiple ion guns operate on one or more targets in a single primary vacuum chamber.
  • Another advantage of the invention is that it provides a system in which the multiple
  • ion guns are in a gun chamber capable of being vacuum isolated from the main chamber, that is,
  • the gun chamber is capable of being evacuated or exposed to atmosphere independently, without disrupting the vacuum in the main chamber.
  • Another advantage of the invention is that it provides a system in which the multiple
  • ion guns are positioned in multiple gun chambers, each gun chamber containing one or more ion
  • each gun chamber capable of being vacuum isolated from the main chamber and from each other.
  • Another advantage of the invention is that it provides a multiple ion gun system in
  • Another advantage of the invention is that it provides a system in which an ion gun or
  • set of ion guns in one chamber can be replaced while maintaining a vacuum in the main chamber
  • Another advantage of the invention is that it provides a system that uses multiple ion guns and provides the capability to detect secondary particles emitted from a sample at the target
  • Another advantage of the invention is that it provides charged particle optical elements in parallel for multiple columns and a method of efficiently manufacturing such
  • Another advantage of the invention is that it provides such charged particle optical elements with at least one of the optical elements being individually controllable.
  • Another advantage of the invention is that it provides an electrode design for a multiple column focused ion beam system that reduces the number of high voltage power
  • Another advantage of the invention is that it provides a multiple column focused ion beam system using fewer high voltage power supplies than the number of columns.
  • Another advantage of the invention is that it provides an electrode design and voltage
  • Another advantage of the invention is that it reduces the cost of processing multiple
  • Another advantage of the invention is that individual emitters can be restarted by

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  • Chemical & Material Sciences (AREA)
  • Analytical Chemistry (AREA)
  • Physics & Mathematics (AREA)
  • Engineering & Computer Science (AREA)
  • Plasma & Fusion (AREA)
  • Electron Sources, Ion Sources (AREA)
  • Other Investigation Or Analysis Of Materials By Electrical Means (AREA)
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Abstract

Secondary particles (418) are collected along the optical axis of a focused ion beam system (508) thereby eliminating the need for side-mounted detectors that make close packing of multiple columns difficult and that require the final lens to be spaced further away from the target (510). Secondary particles can be collected through the lens and then diverted away from the optical axis of the ion column for detection without significantly degrading the resolution of the focused ion beam (420). Secondary particles can also be collected using a conductive plate connected to an amplifier to detect the electrical current caused by the secondary particles.

Description

Through-the-Lens Collection of Secondary Particles for a Focused Ion Beam System
Technical Field of the Invention [1000] The present invention relates to the field of focused ion beam (FIB) systems, and in particular, to the collection of secondary particles in FIB systems.
Background of the Invention
[1001] Thin film head trimming and other nanofabrication applications suffer from throughput limitations, that is, the focused ion beam systems are unable to process products as quickly as desired. One approach to increasing processing speed is to increase the current in a given beam, thereby increasing the rate at which material is removed or deposited.
Unfortunately, systems are approaching fundamental limits for beam current within the small beam diameters required.
[1002] Another solution to increasing throughput is simply to use additional FIB systems. Because FIB systems are complex and include a variety of subsystems, each individual system is costly.
[1003] To increase throughput in electron beam lithography and semiconductor inspection areas, researchers have begun using multiple electron field emitters or photoemission sources in a
single system. For example, multiple electron beam systems are described in U.S. Pat. No.
4,390,789 to Smith for "Electron Beam Array Lithography System Employing Multiple Parallel
Array Optics Channels and Method of Operation" and U.S. Pat. No. 5,981 ,962 to Groves et al. for a "Distributed Direct Write Lithography System Using Multiple Variable Shaped Electron Beams." [1004] These multi-beam electron beam system designs do not readily transfer to ion beam
systems because the ion optical columns operate at much higher voltages and therefore present design problems that, are not present in electron beam systems. Designing an array of high
voltage FIB columns that operate at beam voltages of about +30,000 V presents problems that are quite different from those involved in designing an array of electron beam columns, which typically operate between about -500 to -5000 V, for lithography or inspection. Moreover, the
higher voltage power supplies are bulkier and more costly than low voltage ones required for
electron beam systems, making it difficult to produce a compact and competitively priced
ulticolumn FIB system.
[1005] U.S. Pat. No. 5,945,677 to Leung et al. for a "Focused Ion Beam System" describes
two approaches for multiple ion beam systems using one or more plasma ion sources. In the first approach, a single multicusp plasma ion source is used to produce multiple beamlets. The second approach employs multiple FIB units, each having a separate ion source and acceleration
column. Such systems are complex, and no large area source, multiple column systems are currently commercially available. Furthermore, multicusp sources, which are about 100 times
less bright than liquid metal field ion sources, have so far not achieved sufficient brightness to be
commercially practical.
[1006] Thus, a practical, cost effective solution for increasing focused ion beam throughput while maintaining resolution is still needed.
Summary of the Invention
[1007] An object of the present invention is to provide for the collection of secondary
charged particles in focused ion beam systems in a manner that allows for efficient collection and a more compact system design. [1008] The present invention includes a method of increasing the throughput of a FIB
system, a FIB system capable of increased throughput, and a method of making and using the
FIB system. The invention also includes several novel aspects of the FIB system, including the modular design of the gun chambers, the design of the electrodes, including their electrical isolation, the secondary particle collection system, and the electrode voltage application scheme.
Although this disclosure describes a FIB system having multiple ion optical columns, many of
the innovation described herein, such as the secondary particle collection techniques, are also
applicable to systems having a single ion optical column.
[1009] A preferred FIB system of the present invention comprises multiple ion guns, each preferably including a Liquid Metal Ion Source (LMIS) and associated with a corresponding FIB optical column. The beams from the multiple columns are directed to one or more targets in a primary vacuum chamber. The multiple guns increase the number of ions impacting the target or targets and therefore increase the processing rate. For example, the multiple beams can operate
on different wafers, or on different parts of a single wafer, with the wafer or wafers being in a
single primary vacuum chamber. Because each of the multiple columns has substantially the
same resolution and beam current as that of a column in a single gun FIB system, accuracy and
precision is not degraded as processing speed is increased. Because the multiple columns share a primary vacuum chamber and can share other facilities, such as power supplies, a computer and
a user interface, the initial cost and operating cost of a system of the invention is greatly reduced
compared to the costs associated with multiple, separate complete FIB systems.
[1010] Preferably, each FIB gun is placed in a vacuum chamber, referred to as a gun
chamber, that can be evacuated independently from the primary vacuum chamber. Multiple such
gun chambers, each containing one or more FIB guns, can be placed in parallel to form a large array of guns for operating on one or more targets in the primary vacuum chamber. A common,
ganged vacuum valve for each gun chamber can isolate the gun chamber from the main chamber.
Moreover, the gun chambers can be evacuated and sealed prior to installation, thereby avoiding the loss of production that would occur if the gun chamber were evacuated after installation. By separating the gun chamber or chambers from the main chamber, gun chambers can be replaced
without disrupting the vacuum in the main chamber, thereby avoiding the introduction of contaminants and saving the time required to re-evacuate the main chamber. By having guns in
separate gun chambers, some guns can be replaced without disturbing others. A gun chamber can be replaced as a module in the field, with the repairs or replacements of individual guns
being performed at the factory.
[1011] Each gun has a corresponding ion optical column, with some of the column elements preferably being placed below the guns in the main system chamber to form an array of columns.
To reduce complexity and to increase the placement precision between columns, column
elements can be made common between the columns by using bars with precision cut holes to
form the lens elements.
[1012] The present invention also includes systems for collecting secondary particles. As
opposed to convention side-mounted detectors, secondary particles are collected along the optical axis of the ion beam column. The secondary particles are then either deflected off the ion beam column axis to a detector or the secondary particles are detected by a detector positioned along
the axis and having a hole for passing the ion beam. The on-axis detector may be positioned on
either above or below the final lens. .
[1013] In one preferred embodiment, the secondary particles are accelerated through the final
lens in a manner such that the resolution of the ion beam is not significantly degraded and then the secondary particles are deflected away from the ion column optical axis toward a detector.
This through-the-lens detector arrangement allows the sample to be placed close to the final lens, thus shortening its focal length and providing improved column optical performance (greater current into the same beam diameter). The system for collecting secondary particles through the final ion lens can be used on multi-column or single column ion beam systems. In another
preferred embodiment, a conductive plate is used to detect the secondary particles.
[1014] The foregoing has outlined rather broadly the features and technical advantages of the present invention in order that the detailed description of the invention that follows may be better
understood. Additional features and advantages of the invention will be described hereinafter
which form the subject of the claims of the invention. It should be appreciated by those skilled in
the art that the conception and specific embodiment disclosed may be readily utilized as a basis for modifying or designing other structures for carrying out the same purposes of the present
invention. It should also be realized by those skilled in the art that such equivalent constructions
do not depart from the spirit and scope of the invention as set forth in the appended claims.
Brief Description of the Drawings
[1015] For a more complete understanding of the present invention, and the advantages
thereof, reference is now made to the following descriptions taken in conjunction with the accompanying drawings, in which:
[1016] FIG. 1 is a side, cross-sectional view of a single FIB column set containing five FIB columns.
[1017] FIG. 2 A is a top view of three column sets fastened together to form a 15 column
array.
[1018] FIG. 2B is a side view of these three column sets. [1019] FIG. 3 is an end cross sectional view of a gun set using high voltage insulators.
[1020] FIG. 4 is a cross-sectional view of a FIB column using a through-the-lens secondary
particle detector.
[1021] FIG. 5 is a cross-sectional view of another FIB column using a through-the-lens secondary particle detector.
[1022] FIG. 6 is an electron optics computer simulation of the secondary electron trajectories from the sample through the lenses of FIG. 4.
Detailed Description of the Preferred Embodiments
[1023] The embodiments described below accomplish several difficult design goals for
multi-column FIB systems. The optical elements are sufficiently electrically isolated to maintain
the required high operating voltages. In some embodiments, the number of high voltage power
supplies is reduced from the number that would be required in multiple independent columns.
The voltage level of the high voltage power supplies are also reduced from that of conventional
FIB systems. In addition, the difficulties of keeping multiple LMIS's (Liquid Metal Ion Sources) operating and maintained with minimum down time is addressed by using a vacuum sealable,
multiple gun chamber as described below. Many of the innovation described herein, such as the
secondary particle collection techniques, are also applicable to systems having a single ion
optical column.
[1024] FIGS. 1, 2A, and 2B show a multi-column FIB array using LMIS's. FIG. 1 shows a
multi-column FIB system 108 that includes a gun vacuum chamber 110 and a primary vacuum
chamber 1 12. Gun chamber 1 10 is a single, sealable vacuum chamber that includes a set of ion guns 114. Gun chamber 110 can be replaced as a unit and has its own vacuum pump, preferably
an ion pump (not shown). When one of the guns 114 in gun chamber 1 10 fails, the entire gun chamber 1 10 can be replaced with another gun chamber 110 that is already evacuated to an ultra
high vacuum and ready to begin operation. Thus, multi-column system 108 does not need to remain out of production while the gun chamber is being evacuated.
[1025] Each ion gun 114 includes an emitter 120, a suppressor 122, an extractor 124, an
acceleration lens 126, a deceleration lens 128 and a ground element 169. The four elements 124,
126, 128 and 169 of each column together are referred as the "lens 1" of the column. Although
FIG. 1 shows a lens 1 comprising four lens elements, other lens designs can be used for lens 1.
Also, some or all of the elements of lens 1 could alternatively be positioned in primary vacuum chamber 112.
[1026] Each ion gun 114 forms part of an ion optical column 136 that also includes an
aperture 152, a steering element 154, a blanking element and Faraday cup 156, dual deflection
elements 160 and 161, second lens elements 163, 162 and 165 (referred to collectively as the
"lens 2"), and a detector 164. At the bottom of each column is a work piece or target 170, such
as a semiconductor wafer. An isolation valve 150 at the bottom of each gun 114 selectively
closes a beam hole 168, thereby vacuum isolating gun chamber 110. The isolation valves 150 of the column in a gun chamber 1 10 are preferably "ganged," that is, connected in a manner so that
all valves are opened or closed together. The detectors 164 for the columns 136 are constructed
so that each column's secondary electrons can be independently detected. The aperture 152
preferably comprises an automatic variable aperture. Such apertures are known and details are
not shown in FIG. 1. A gas injection system can optionally be used with apparatus of FIG. 1 to inject a gas for ion beam assisted deposition or for enhanced etching. The construction and
operation of such systems are known and are described, for example, in U.S. Pat. No. 5,435,850 to Rasmussen. [1027] The gun elements, that is, emitters 120, suppressors 122, extractors 124, acceleration lenses 126, deceleration lenses 128, and ground element 169 are preferably contained in gun chamber 1 10. The number of guns in gun chamber 110 is preferably limited to about five. If one
of the emitters 120 fails, then the exchange of a five-gun set is easier and less costly than replacing a larger number of guns, such as ten or more guns. Moreover, the restarting of five
emitters in parallel is also much less prone to failure than restarting a larger number simultaneously. The set of ganged isolation valves 150 for the set of guns simultaneously isolates the beam holes 168 in the ion beam paths at the bottom of gun chamber 110 from the primary vacuum chamber 112.
[1028] Valves 150 are preferably formed by a bar 172 that moves relative to bottom portion 174 of gun chamber 110. When valves 150 are open, the openings in bar 172 line up with the
openings 169 in bottom portion 174. To seal gun chamber 110, bar 172 is shifted so that the
holes in bar 172 are offset from the holes in bottom portion 174, and O-rings 176 form a seal between a solid portion of bar 172 and bottom portion 174. Before shifting bar 172, it is
preferably lowered away from O-rings 176 to prevent damage to the O-rings that can create contamination and vacuum leakage. After bar 172 is shifted, it is raised again into contact with O-rings 176 to create a vacuum seal to isolate gun chamber 1 10. Primary chamber 112 can be
exposed to air when gun chamber 110 is removed or alternatively, primary chamber 1 12 can be
made sealable by using a second set of valves (not shown). Details of the mounting of gun
chamber 1 10 to primary chamber 1 12 are conventional and not shown.
[1029] A multiple ion column system could use a single gun chamber 110 or multiple gun chambers. FIG. 2A shows a top view of an arrangement of multiple linear gun chambers 110
grouped to form a two-dimensional array of fifteen guns. The number of guns per gun chamber can be varied, as well as the number of gun chambers to produce a system having the desired number of FIB columns for a particular application. FIG. 2 A shows an outlet 210 from each gun
chamber 110 to an associated ion pump.
[1030] FIG. 2B is a side view of the multiple gun chamber system of FIG. 2A. FIG. 2B
shows also a location for high voltage feed-throughs 212, a flange 214 at the top of a gun chamber 110, and an actuator 216 for ganged gate valves 150.
[1031] The construction of the optical elements, such as extractors 124, acceleration lenses 126, and deceleration lenses 128 in gun chamber 110, can be simplified by using flat bars
with holes to form lens elements. This construction technique can also be used to construct optical elements in the primary vacuum chamber. Using a single bar to form corresponding lens elements in different columns with a gun chamber can reduce the number of high voltage power
supplies required.
[1032] FIG. 3 is a cross-sectional view of a gun chamber 110 showing bars 310 used to form
optical elements. Bars 310 form suppressors 122, extractors 124, acceleration lenses 126, and deceleration lenses 128. Bars 310 are electrically isolated from each other and from the chamber itself using HV (High Voltage) insulator disks 312 composed preferably of a ceramic material.
Other means, such as dielectric balls, can be used to isolate the gun HV elements. The assembly
may be glued together using a suitable epoxy or other means known in the art. After the bars and
insulators are installed in the casing of gun chamber 110, the assembly can optionally be
machined to provide additional accuracy in shaping and aligning the lens elements.
[1033] The optical elements can be formed directly by the holes in a conductive bar, as shown with regard to acceleration lenses 126. A common voltage is thus applied to all lenses formed by the bar, reducing the number of high voltage power supplies required for the multi- column system. The number of high voltage power supplies can be further reduced by using a
common high voltage supply for corresponding bars in multiple gun chambers. Conductive bars
are typically made of a titanium alloy having a low thermal coefficient of expansion.
[1034] Optical elements can also be formed by inserts placed into holes in a bar. For example, FIG. 1 shows the use of lens inserts 178 in the bar 310 forming deceleration lenses 128.
The bar in which lenses 128 are formed is constructed from an insulating material, for example, a ceramic material such as alumina, and the lens inserts are composed of a conductive material, preferably a titanium alloy which has is low thermal coefficient of expansion that is similar to
that of the alumina bar. The alumina bar provides high voltage isolation to the individual lenses
128 with respect to the bars 310. Voltage is applied to the individual lenses by wires connected to the lenses in a conventional manner, such as conductive silver epoxy or using connector pins.
Alternatively, metal films can be placed upon the insulator bar to replace the wires.
[1035] Another method of providing high voltage insulation to lenses 128 entails using a
conductive bar 310, with an insulating insert placed in a hole in the bar, and then a conductive lens placed in the insulating insert. Such inserts can be glued into insulator material, which can
then be glued into the bars. Lenses formed by inserts can also be post machined, that is,
machined after assembly, for additional accuracy in shape and alignment. These construction
methods that individually isolate lenses can be particularly useful for suppressor lenses 122, extractor lenses 124, or individual elements of lens 1 or lens 2.
[1036] FIG. 1 shows inserts used only on the deceleration lens 128. Deceleration lens 128
can be operated near ground potential, which simplifies the power supply requirements for lens 1.
Isolating lens elements allows the voltages in individual columns to be controlled. For example, the voltage on one of extractor lenses 124 can be individually boosted about 2 kV above the common extractor voltage to start or restart the individual emitter in the corresponding column.
The extractor lens 124 can then return to or near the common extractor voltage for normal operation. Optical elements that are isolated can still use the common high voltage supply, but isolated elements can also be floated at a voltage above or below the common voltage, thereby
reducing the number of high voltage power supplies required.
[1037] Charged particle signal detection capability for imaging can be accomplished by a traditional side mounted electron multiplier or scintillator means, or by other novel methods
described below. Traditional side-mounted secondary particle collection systems require that the final lens be placed at a sufficient distance from the sample to accommodate the particle collection apparatus. Increasing the distance from final lens to the sample necessitates using a final lens having a longer focal length, which typically degrades the resolution of the FIB system.
In the prior art, channel plate detectors have been positioned along the ion column optical axis between the final lens and the sample, but channel plates at this location increase the lens focal
length, suffer reliability problems and do not have a long life.
[1038] In the embodiments described below, secondary particles are collected along the
optical axis of the ion beam column. The secondary particles are then either deflected away from
the ion beam column optical axis to a detector or the secondary particles are detected by a
detector positioned along the optical axis and having a hole for passing the ion beam. The
detector may be positioned on either side of the final lens.
[1039] For many nanofabrication applications, the beam current can be greater than a nanoampere. At this level of current, an amplifier or amplifiers can be attached directly to detector plate 164 below lens 2 to detect a current caused by secondary charged particles. As
described above, detectors 164 for the columns 136 are constructed so that each column's secondary electrons are independently detected. For example, the individual detectors could be
electrically isolated each other, for example, by using inserts as described above, or secondary particle collection could be performed using only one column at a time during imaging. Separate
detector plates for each column could also be used. Detector 164 can be electrically biased to
collect positive or negative charged particles. Skilled persons can readily determine an appropriate bias by adjusting the bias to provide an adequate electrical current for detection without significantly degrading the resolution of the ion beam.
[1040] Alternatively, secondary particles, electrons or positive or negative ions, can be collected through the final lens, referred to as through-the-lens (TTL) collection. . After the
secondary particles travel back through the final lens, they can be detected by an on-axis collection system, such as one similar to detectors 164 (Fig. 1), a channel plate, or a scintillation detector, or by a preferred off-axis detection system as described below.
[1041] Through-the-lens electron detection in an electron beam column is known and
described, for example, in PCT Publication WO 99/34397 of Krans et al. In the Krans et al. design, the lens 2 center element and upper element (and optionally the lower element) are biased
to positive potentials to draw the electrons from the sample up and above the lens, where- they are
detected by a channel plate electron multiplier, which is oriented roughly perpendicularly to the
ion column axis and which has a hole in its center to pass the primary beam.
[1042] It is preferable to use a TTL detection system in focused ion beam systems to provide
a short focal length final lens. However, the optics in a FIB column is significantly different from a low voltage SEM column, such as the Krans et al. design. A typical FIB column operates
at about 30 kV beam voltages and the final lens is an einzel lens - the center element is at a high
positive potential and the upper and lower elements are at ground potential. Thus significant modification to the ion optics, different from those described by Krans et al. for an electron column, are required to provide TTL capability in an ion column.
[1043] A key realization is that the mass-to-charge ratio for ions employed in FIB systems is
orders of magnitude higher than for electrons, and in addition, the energies are much higher.
Thus a simple magnetic field transverse to the primary and secondary electron beam paths can be
employed to deflect the electrons off-axis with minimal disturbance to the primary ion beam. As an example, applicants used gallium ions with 30 kV beam voltage and electrons extracted upwards from the sample through the final lens with voltages of 2000 V.
[1044] The strength of the bending magnet is given by the cyclotron radius equation
R = m v / B e (1) where m is the mass, v is the velocity of the charged particle, B is the magnetic field strength, and e is the electron charge. Substituting the energy and mass into Equation 1 gives
R = (2 E m)1 2/ B e (2)
For electrons, it can be shown that B R(gauss-cm) = 3.37 E (where E is in eV). Therefore, if we
use R = 5 mm and E = 2000 V for the secondary electrons accelerated upward beyond the final lens, then B = 301.4 gauss.
[1045] This bending magnet is designed so as not to disturb the primary ion beam very much.
Fortunately, gallium primary ions have the same charge as electrons but each gallium ion has a mass about 160,000 times the mass of an electron. Furthermore, the electron energies are typically about 15 times less than the ion energy. Using Equation 2, we see that the cyclotron
radius for the primary ions is typically about 1550 times larger than the electron cyclotron radius
or about 7.75 meters. Hence the disturbance to the primary ion beam path is small. In fact the path deviation is only about 1.2 milli-radians, which can be very easily corrected with beam steering. It can also be shown that the predominate aberration introduced into the primary ion beam by the magnetic field is chromatic and can mostly be neglected.
[1046] FIG. 4 shows such a TTL detection system for an ion column 410 in which low energy secondary electrons from the sample, having energies of about 5 eV (electron volts), are
accelerated up through the lens 412 by positive potentials on the elements of lens 412, the
deflector plates 432 and magnetic deflector 414. The TTL system in FIG. 4 utilizes a magnetic deflector 414 to deflect the secondary electrons 418 off to the side while allowing the high mass-
to-charge ratio primary ions 420 to pass nearly straight through column 410. Alternatively, a Wein filter or an electrostatic deflection device could be used. An electron detector 424, such as a scintillator, continuous dynode multiplier, or channel plate, is then placed to the side for
collecting and amplifying the electron signal for processing by standard FIB video electronics.
[1047] In the embodiment of FIG. 4, a sample 426 and a lower lens element 428 are
maintained at approximately ground potential. An upper lens element 430 is biased to between
about +500 and +5000 volts with respect to ground to continue the secondary electron velocities
upward beyond the lens 412. Similarly, electrostatic deflector plates 432 and deflector 414 are biased to between about +500 and +5000 volts to continue this upward velocity of secondary
electrons 418 towards electron detector 424, the input of which are similarly biased.
[1048] FIG. 6 is an electron optics computer simulation of the secondary electrons traveling from the sample back through the lens shown in FIG. 4. The approximately 5 eV secondary electrons are accelerated rapidly by the lens element 440, which is at high positive potential, such
as about 20,000 Volts. These electrons are decelerated as they pass through the lens element 430 and the deflection electrodes 432, but the secondary electrons still maintain trajectories that remain relatively close to the column axis. Magnetic deflector 414 or other separation device
then directs the electrons toward the detector 424.
[1049| FIG. 5 shows an alternate ion column 508 design using a TTL secondary electron detector. A sample 510 and a lower final lens element 512 are each biased about -2000 V
negative to propel the electrons back through the lens. If it is desired to collect secondary positive ions instead of electrons, sample 510 and lower final lens element 512 can be biased to about +2000 V. Center lens element 514 is biased to approximately +20,000 V. Lens element
516, electrostatic deflector elements 520 and deflector 414 need not be positively biased, which simplifies the electronics and the optics construction. If the ion beam systems include other
devices, such as gas injectors, these devices are also biased to the same potential as the sample.
[1050] The apparatus in FIG. 4 also may be used to detect secondary positive ions from the sample. To collect secondary positive ions, the lens 2 element 440 is biased to a negative
potential. (Lens 2 is then an acceleration lens). In addition, electrostatic deflector 432, the
deflector 414 and the input of particle detector 424 are negatively biased. Similarly, the
potentials in FIG. 5 may be changed to collect and detect positive secondary ions. A quadrupole or other mass spectrometer can also be placed in the position of detector 424 to perform
Secondary Ion Mass Spectrometry. The appropriate biasing of the column and detector may be employed to detect either positive or negative ions.
[1051] For thin film head trimming or other applications, the ion beams are typically tilted
about +1-3 degrees with respect to the normal to the sample surface. This beam tilting is to
achieve undercutting or to yield cuts to the sides of the head with walls more normal to the head surface. This +/- 3 degree tilt can be achieved, for example, by tilting every other row of
columns by about +/- 3 degrees with respect to the normal to the sample surface. [1052] The inventions described above can be embodied in a variety of systems, and the advantages delineated below can be provided in many or all of the embodiments. Because the
embodiments will vary with the goals of a particular application, not all advantages will be provided, or need to be provided, in all embodiments.
[1053] An advantage of the invention is an increase in the processing speed by providing a system including multiple ion guns capable of operating simultaneously on one or more targets.
[1054] Another advantage of the invention is that it provides a system in which the multiple ion guns operate on one or more targets in a single primary vacuum chamber.
[1055] Another advantage of the invention is that it provides a system in which the multiple
ion guns are in a gun chamber capable of being vacuum isolated from the main chamber, that is,
the gun chamber is capable of being evacuated or exposed to atmosphere independently, without disrupting the vacuum in the main chamber.
[1056] Another advantage of the invention is that it provides a system in which the multiple
ion guns are positioned in multiple gun chambers, each gun chamber containing one or more ion
guns and each gun chamber capable of being vacuum isolated from the main chamber and from each other.
[1057] Another advantage of the invention is that it provides a multiple ion gun system in
which a portion of the ion column elements are in the primary vacuum chamber.
[1058] Another advantage of the invention is that it provides a system in which an ion gun or
set of ion guns in one chamber can be replaced while maintaining a vacuum in the main chamber
and in other gun chambers. [1059] Another advantage of the invention is that it provides a system that uses multiple ion guns and provides the capability to detect secondary particles emitted from a sample at the target
point of each of the multiple guns.
[1060] Another advantage of the invention is that it provides charged particle optical elements in parallel for multiple columns and a method of efficiently manufacturing such
elements.
[1061] Another advantage of the invention is that it provides such charged particle optical elements with at least one of the optical elements being individually controllable.
110621 Another advantage of the invention is that it provides an electrode design for a multiple column focused ion beam system that reduces the number of high voltage power
supplies required for the system.
[1063] Another advantage of the invention is that it provides a multiple column focused ion beam system using fewer high voltage power supplies than the number of columns.
[1064] Another advantage of the invention is that it provides an electrode design and voltage
application scheme that reduces the voltage requirement of the high voltage power supply.
[1065] Another advantage of the invention is that it reduces the cost of processing multiple
targets simultaneously from the cost of using multiple, single beam focused ion beam systems.
[1066] Another advantage of the invention is that individual emitters can be restarted by
individually increasing the extraction voltage of that particular gun and not disturb the other gun
voltages. This can be achieved either by increasing the extractor voltage with respect to the
emitter/ suppressor elements by using isolated extractor elements, or by increasing the emitter/ suppressor voltage with respect to the common extractor voltage for that particular gun. [1067] Although the present invention and its advantages have been described in detail, it should be understood that various changes, substitutions and alterations can be made to the embodiments described herein without departing from the spirit and scope of the invention as defined by the appended claims. Moreover, the scope of the present application is not intended to be limited to the particular embodiments of the process, machine, manufacture, composition of
matter, means, methods and steps described in the specification. As one of ordinary skill in the
art will readily appreciate from the disclosure of the present invention, processes, machines, manufacture, compositions of matter, means, methods, or steps, presently existing or later to be developed that perform substantially the same function or achieve substantially the same result as
the corresponding embodiments described herein may be utilized according to the present invention. Accordingly, the appended claims are intended to include within their scope such
processes, machines, manufacture, compositions of matter, means, methods, or steps.
We claim as follows:

Claims

1. A focused ion beam apparatus including a detector for detecting secondary particles,
comprising: an ion gun for generating primary ions and directing them toward a target; a lens for focusing the primary ions onto the target and for passing secondary particles
emitted from the target and traveling in a direction opposite to that of the primary ions; and a detector for detecting the secondary particles emitted from the target and passing
through the lens.
2. The apparatus of claim 1 in which at least a portion of the lens is biased to a positive electrical potential relative to the target to accelerate negatively charged secondary particles
toward the lens and away from the target.
3. The apparatus of claim 1 in which: the primary ions travel along a primary ion path; and the detector is positioned off the primary ion path and further comprising
a secondary particle deflector for deflecting away from the primary ion path secondary particles that travel through the lens and toward the detector, the secondary particle deflector
allowing the primary ion beam to pass toward the target.
4. The apparatus of claim 3 in the secondary particle deflector comprises a magnetic
deflector, a Wein filter, or an electrostatic deflector.
5. The apparatus of claim 1 in which the detector is positioned along the primary ion
path and has a hole for passage of the primary ions.
6. The apparatus of claim 5 in which the detector comprises a conductive plate a
scintillator, or a channel plate multiplier
7. The apparatus of claim 1 in which the target is maintained near ground electrical
potential.
8. The apparatus of claim 1 in which the detector is maintained near ground electrical
potential
9. The apparatus of claim 1 in which the detector is maintained at a potential that is
positive with respect to the target to collect secondary electrons or negatively charged secondary ions or in which the secondary particle detector is maintained at a potential that is negative with
respect to the target to collect secondary positive ions.
10. The apparatus of claim 1 in which the lens includes multiple lens elements, the lens element closest to the target being maintained at approximately the same electrical potential as
the target.
11. The apparatus of claim 1 in which the lens includes multiple lens elements, the lens
element farthest from the target being maintained at approximately the same electrical potential
as the detector.
12. The apparatus of claim 1 further comprising a primary beam deflection electrode
positioned between the secondary particle deflector and the lens.
13. A focused ion beam apparatus including a detector for detecting secondary particles, comprising:
an ion gun for generating primary ions and directing them toward a target; a final lens for focusing the primary ions onto the target; and a conductive plate for detecting secondary particles emitted from the target by the impact
of the primary ions.
14. The apparatus of claim 13 in which the final lens defines an optical axis and in which the conductive plate is positioned essentially along the optical axis and has a hole for passing the
ion beam.
15. The apparatus of claim 14 in which the conductive plate has a surface for the secondary particles to impact, the surface being substantially peφendicular to the optical axis.
16. The apparatus of claim 13 in which the secondary particles contacting the conductive plate cause a secondary particle electrical current and further comprising an amplifier for
amplifying the secondary particle electrical current.
17. The apparatus of claim 13 in which the conductive plate is positioned between the target and the final lens.
18. The apparatus of claim 13 in which the conductive plate is electrically biased to
collect secondary particles of a particular charge.
19. A method of collecting and detecting secondary particles emitted from a target in a
focused ion beam column having a final ion lens and a primary ion path, comprising: accelerating secondary particles away from the target and through the final ion lens; and
detecting the secondary particles that have traveled through the final lens.
20. The method of claim 19 in which accelerating the secondary particles away from the
target includes providing an accelerating voltage on at least a portion of the final ion lens.
21. The method of claim 19 further comprising deflecting the secondary particles away
from the primary ion path and towards a detector.
22. The method of claim 21 in which deflecting the secondary particles away from the
primary ion path and towards a detector comprises deflecting the secondary particles using an
electric field, a magnetic field, or a combination of an electric field and a magnetic field.
23. The method of claim 19 in which detecting the secondary particles includes detecting the secondary particles using a detector positioned along the primary ion path, the detector
including a hole for passage of the primary ions.
24. The method of claim 19 in which the final lens includes multiple lens elements and in which accelerating the secondary particles away from the target includes maintaining the lens element closest to the target at the same electrical potential as the target and maintaining at least
one of the other final lens elements at an electrical potential with respect to the target to
accelerate the secondary particles away from the target.
25. The method of claim 24 in which maintaining the lens element closest to the target at
the same electrical potential as the target includes maintaining the target at approximately ground potential.
26. The method of claim 24 in which detecting the secondary particles that have traveled
through the final lens includes maintaining the detector at approximately ground potential.
PCT/US2001/004441 2000-02-09 2001-02-08 Through-the-lens collection of secondary particles for a focused ion beam system WO2001059806A1 (en)

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JP2001559034A JP2003524867A (en) 2000-02-09 2001-02-08 Lens through capture of secondary particles for focused ion beam systems

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EP1259974A4 (en) 2003-08-06
US20010032938A1 (en) 2001-10-25
AU2001238148A1 (en) 2001-08-20
EP1259974A1 (en) 2002-11-27
JP2003524867A (en) 2003-08-19

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