WATER-SOLUBLE ALUMINIUM AND ALUMINIUM ALLOYS COLD
ROLLING OIL COMPOSITION
The present invention relates to a water-soluble aluminium and aluminium alloys cold rolling oil composition and to a process for cold rolling aluminium and aluminium alloys .
The aluminium and aluminium alloys rolling industry expresses the need to maximize the efficiency of their cold rolled metal manufacturing process. In general terms, this means that there is a wish to operate at higher rolling speeds and to produce more marketable products per operating shift. Additionally, there is also a wish to minimize the number of passes through the mill taken to achieve a given level of reduction. Both these routes require that quality and surface finish be not compromised.
On the other hand, there is a need to increase mill safety by reducing the fire risks and the emissions of oil mists .
The invention thus provides an oil composition for cold rolling mills that enables to prepare emulsions which affords the following customer benefits: - a high reduction ratio;
- a better rolling ability (i.e. a lower rolling force and a reduced power consumption ) as compared to the rolling ability obtained with oil compositions of the prior art; - a good surface finish quality; a high lubricity (plate-out properties, roll coating) ; a non- stained final product; a safer mill environment and better working conditions; and it can be used to prepare articles which are intended to be used in contact with food.
1 CONFIRMATION COW
The invention is effective on any type of cold rolling, be it reversible or not, of the Sendzimir type (e.g. 1-2, 1-2-3, 1-2-3-4), or of Z-high type (e.g. 2-hιgh, 4-hιgh, 6-hιgh) , be it a reversible mill, a tandem mill, etc ..
Especially, the invention exhibits high reduction and rolling capabilities while providing an excellent strip surface finish when rolling at high speed. The invention is also suited to Z-high rolling mill technology where high reduction ratio at low speed is obtained.
The prior art does not teach or even suggest the instant invention.
Thus, the invention provides a water-soluble aluminium and aluminium alloys cold rolling oil composition comprising a white mineral oil and, based on the total weight of the composition, from 30 to 95% and preferably from 50 to 85% of isobutyl stearate .
The invention further provides a process for preparing the oil composition. The invention further provides an emulsion containing the oil composition and a process for preparing this emulsion.
In addition, the invention provides the use of the oil composition of the invention to prepare emulsions intended to be used m a aluminium or aluminium alloy cold rolling process .
The invention also provides a process for cold rolling aluminium and aluminium alloys sheets, comprising applying an effective amount of the emulsion of the invention. Finally, the invention provides the use of the emulsion m an aluminium or aluminium alloy cold rolling process .
The invention is now disclosed in more details m the following specification and m reference to the drawings m which:
Figure 1 is a graph showing the roll force as a function of the strip speed at a constant reduction rate of
50%, when using the emulsion of the invention and a neat oil of the prior art;
Figure 2 is a graph showing the roll force as a function of the strip speed at a constant reduction rate of 60%, when using the emulsion of the invention and a neat oil of the prior art;
Figure 3 shows the surface of a strip after cold rolling with an emulsion of the invention;
Figure 4 shows the surface of a strip after cold rolling with a neat oil of the prior art;
Figure 5 is a graph showing the roll force as a function of the strip speed at a constant reduction rate, when using an emulsion of the invention at a concentration of 9% and with an emulsion of the invention at a concentration of 13%;
Figure 6 is a graph showing the roll force as a function of the strip speed at a constant reduction rate, when using an emulsion of the invention prepared at 25 °C and an emulsion of the invention prepared at 40 °C.
The water-soluble oil compositions of the invention are neat oil concentrates generally intended to be diluted in water to give oil-m-water emulsions.
By "white mineral oil" , it is herein intended very highly refined oils which consist entirely of saturated components, all aromatics having generally been removed by treatment with fuming sulphuric acid or by selective hydrogenation. Their name reflects the fact that they are virtually colourless and the most highly refined medicinal white oils are used m medical products and in the food industry.
The white mineral oils used in the invention are preferably those which can be safely used as a component of nonfood articles intended for use in contact with food. These oils are described in 21 CFR Ch. 1 §178.3620 (a) and
(b) of the Food and Drug Administration, HHS .
Thus, the oil composition and emulsion according to the invention are adapted to be used as a component of nonfood articles intended for use m contact with food.
White oils are for example sold by the company SIP Limited of LONDON. A preferred white mineral oil is SPC 5L.
The white mineral oil typically has a viscosity from 4 to 30 cSt at 40°C, preferably from 4.5 to 6 cSt at 40°C. Viscosity can be adjusted by using a viscosity adjuster (such as kerosene) , if needed.
The water-soluble oil composition may comprise classical additives, such as surfactants, coupling agents or cosurfactants , friction reducing agents or lubricity agents, corrosion inhibitors or anti-oxidants , extreme- pressure and anti-wear agents, bactericides and fungicides, anti-foammg agents, anti-rust agents.
Examples of anti-foammg agents are silicone based, especially polydimethylsiloxane .
Examples of corrosion inhibitors are hindered phenols and zinc dialkyldithiophosphates (ZDDP) .
Examples of extreme-pressure and anti-wear agents are dilauryl phosphate, didodecyl phosphite, trialkylphosphate such as tri (2 -ethylhexyl) phosphate , tπcresylphosphate (TCP), zinc dialkyl (or diaryl) dithiophosphates (ZDDP), phospho-sulphurized fatty oils, zmc dialkyldithiocarbamate) , mercaptobenzothiazole , sulphurized fatty oils, sulphurized terpenes, sulphurized oleic acid, alkyl and aryl polysulphides , sulphurized sperm oil, sulphurized mineral oil, sulphur chloride treated fatty oils, chlornaphta xanthate, cetyl chloride, chlorinated paraffimc oils, chlorinated paraffin wax sulphides, chlorinated paraffin wax, and zmc dialkyl (or diaryl) dithiophosphates (ZDDP), tπcresylphosphate (TCP), tπxylylphosphate (TXP) , dilauryl phosphate, respectively. Examples of corrosion inhibitors or anti-oxidants are radical scavengers such as phenolic antioxidants (sterically hindered), ammic antioxidants, organo-copper
salts, hydroperoxides decomposers, butylated hydroxytoluene .
Examples of anti-rust agents are amme derivative of alkenyl succinic anhydride. Examples of friction reducing agents or lubricity agents are fatty alcohols having a carbon number m the range from 12 to 18, fatty esters having a carbon number in the range from 12 to 18, like glycerol monooleate
Further elements on base oils and additives can be found m "Chemistry And Technology Of Lubricants", R.M. Mortier and S.T Orszulik, VCH Publishers, Inc, First published in 1992
The oil composition is prepared by blending the base oil and the other ingredients under stirring or with any mixing device, preferably whilst controlling the temperature so that is does not exceed 50°C, and more preferably, 40°C.
An oil-m-water emulsion is prepared by diluting under stirring the oil composition of the invention m water.
The water preferably is distilled water which has been prewarmed to a temperature of from 20° to 45°C, more preferably of from 20°C to 30°C.
The emulsion generally comprises water and, based on the total volume of the emulsion, from 0.5 to 30%, preferably from 10 to 15%, by volume, of the oil composition.
The aluminium alloys to which the invention applies are any aluminum alloys, including 1000, 2000, 3000, 5000, 6000, 7000 series.
The cold rolling process can be the classical process. The oil temperature is generally maintained at a temperature below 70°C, preferably below 40°C.
The process is preferably carried out on a breakdown rolling mill, on a tandem rolling mill or on a finishing rolling mill. The instant oil composition allows a significant reduction of the number of passes With conventional prior art oils, the number of passes was typically 5 to 7. The oil composition of the invention allows lowering this number by 1 pass, which is a significant improvement.
The following examples illustrate the invention without limiting it. All parts and ratios are given by weight, unless otherwise stated.
Examples A composition is prepared by mixing the ingredients of Table 1 m the order m which they appear m this table. The temperature is maintained at a maximum of 40°C to ensure a complete dissolution and homogeneisation of the ingredients without impairing the properties of the emulsion.
The characteristics of the composition of Table 1 are set out m Table 2.
An emulsion is prepared by diluting under stirring the o l composition of Table 1 m distilled water at 40°C. The characteristics of the obtained emulsion are given in Table 3.
1) : The emulsion stability was determined according to the following procedure. 470 ml of distilled water at room temperature or test temperature were measured into a 800 -ml beaker. A 50 -ml stirrer having four paddles was attached to a stirring motor so that the paddles were positioned 25mm above the bottom of the beaker. A 50 -ml dropping funnel was positioned such that the outlet was 15mm from the beaker wall. The stirrer was turned on and the rate adjusted to
1000 rpm. The sample was then heated up to a temperature of 35 ± 1°C. 30 ml of the test oil were added to the dropping funnel The dropping rate was adjusted such that all the oil was transferred to the water within 120 ± 20 seconds. The stirring was then continued for an additional 60 seconds while the sample temperature was maintained at 35°+l°C. The resulting emulsion was poured into a 500-ml graduated cylinder and allow to stand at room temperature for 20 hours After 20 hours, the upper layer (yellow cream + oil) was read m volume percent.
EXPERIMENTAL TESTING
The used mill test was a non-reversmg single stand 2- high rolling mill with coiler and decoiler designed for 30 mm wide sheets, which can take up to 0.6 mm thick strips of about 1000 m length.
Roll diameter was 92 mm with surface roughness Ra of 0.4 micron. Strips of AA5182 approximately 30 mm wide by 0.55 mm thick, were rolled with each of the test products, with the maximum strip rolling speed being 600 m/mm m this configuration.
a) Comparative tests As prior art oil, a neat oil having a viscosity of 1.7 cSt at 40°C and comprising 90 wt % of high flash point desulfuπzed kerosene and 10 wt % of lauryl alcohol, was used.
The roll force as a function of the strip speed at a constant reduction rate was measured with the emulsion of Table 3 and with the neat oil of the prior art.
Figure 1 shows the results obtained with a reduction rate of 50%.
Figure 2 shows the results obtained with a reduction rate of 60%.
It appears from theses figures that the emulsion of the invention brings a much better rolling performance than the prior art neat oil .
In addition, both cases, the macroscopic surface finish of the rolled strip, as observed m a microscopic surface analysis, is brighter on the strip rolled with the emulsion of the invention, than on the strip rolled with the neat oil of the prior art.
Figures 3 and 4 show the results of the microscopic surface analysis of strips rolled with the emulsion of the invention (Fig 3) and with the neat oil of the prior art
(Fig. 4) . (Magnification : 200 times, reduction rate : 50%, speed : 400 m/mm)
b) Emulsion concentration
The influence of the emulsion concentration on rolling performance was determined as follows.
The roll force as a function of the strip speed at a constant reduction rate (50%) was measured with the emulsion of Table 3 (13%) and with a second emulsion prepared m the same way, except that the concentration of the oil composition of Table 1 was only 9%.
The results are shown on Figure 5.
At low and high strip speeds, better results are obtained with the 13% emulsion.
c) Emulsion preparation temperature
The influence of the emulsion preparation temperature on rolling performance was determined as follows.
The roll force as a function of the strip speed at a constant reduction rate (50%) was measured with the emulsion of Table 3 (13%) and with an emulsion prepared m the same way as the emulsion of Table 3, except that the dilution was carried out at 25°C.
The results are shown on Figure 6.
It appears that both emulsions provide high similar rolling performances.
At low strip speed or when the best surface finish is desired, better results are obtained with the emulsion prepared at 40°C.
d) Hydrolysis Test
A hydrolysis test called Rolls Royce Test (RR IOCS was performed with the composition of Table 1. 250 ml of sample were introduced with 25 ml distilleα water into a conical flask under stirring and then kept a; 90°C.
Every 24 hours, 15 ml samples were taken from t.ie flask, dried and the total acidity determined (ASTM D 974 . The total acid number increase was also determmeα after 5 days .
The result was 0.4 mg KOH/g of composition.
To draw a comparison, the same test was carried o_*. with a composition identical to the composition of Table 1, except that linear butyl-stearate was used instead of isobutyl -stearate . The result was then 1.1 mg KOH/g of composition.
Therefore the isobutyl steartate containing composition has a better stability to hydrolysis than the linear butyl-stearate containing composition.