WO2001030735A1 - Method for purifying acetone - Google Patents
Method for purifying acetone Download PDFInfo
- Publication number
- WO2001030735A1 WO2001030735A1 PCT/US2000/027905 US0027905W WO0130735A1 WO 2001030735 A1 WO2001030735 A1 WO 2001030735A1 US 0027905 W US0027905 W US 0027905W WO 0130735 A1 WO0130735 A1 WO 0130735A1
- Authority
- WO
- WIPO (PCT)
- Prior art keywords
- acetone
- oxidizing agent
- column
- mixture
- purifying
- Prior art date
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
- C07C45/78—Separation; Purification; Stabilisation; Use of additives
- C07C45/81—Separation; Purification; Stabilisation; Use of additives by change in the physical state, e.g. crystallisation
- C07C45/82—Separation; Purification; Stabilisation; Use of additives by change in the physical state, e.g. crystallisation by distillation
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
- C07C45/78—Separation; Purification; Stabilisation; Use of additives
- C07C45/85—Separation; Purification; Stabilisation; Use of additives by treatment giving rise to a chemical modification
Definitions
- the invention concerns a method for purifying acetone obtained from cumene by a combination of rectification and chemical processing to remove aldehyde impurities in order to produce high-quality commercial-grade acetone.
- the crude acetone-phenol mixture then undergoes rectification to separate a low-boiling "crude acetone fraction" containing acetone, water, cumene, aldehydes and alpha-metylstyrene, and a "crude phenol fraction” containing phenol and high-boiling compounds such as acetophenone and resins.
- the crude acetone fraction is further purified by rectification and/or chemical processing to produce commercial-grade acetone.
- the "crude acetone fraction" referred to above contains small amounts of aliphatic aldehydes, olefin and carbonyl impurities, specifically acetaldehyde, propionaldehyde, isobutylaldehyde, mesityl oxide, diacetone alcohol and hydroxyacetone, which are formed as by-products in the cumene hydroperoxide decomposition stage described above.
- aliphatic aldehydes, olefin and carbonyl impurities specifically acetaldehyde, propionaldehyde, isobutylaldehyde, mesityl oxide, diacetone alcohol and hydroxyacetone
- U.S. Patent No. 4,620,901 describes a special technology for an extractive distillation, using dimethyl formamide as a selective solvent to remove the aldehydes to a low level. But this method is made complicated by the fact that it requires expensive distillation equipment and produces acetone of unsatisfactory quality containing traces of solvent as an impurity that make the acetone unusable by most final end users.
- U.S. Patent No. 5,567,853 likewise describes a method which requires complex technology for extractive distillation by reacting the acetone fraction with a glycol solution containing compounds of alkali metals. But this method uses expensive solvents that can be regenerated only by using an additional distillation column, and the method produces a commercial acetone having a purity of only 98.3% w/w, which is not suitable for users of high-purity acetone, for example in the production of polycarbonate plastic.
- One goal of the invention was to design a method for purifying acetone that would produce a higher quality product.
- This invention represents a reliable, simple and economical process for removing aldehydes and olefin impurities from acetone by oxidizing the impurities present in the crude acetone fraction using an oxidizing agent added in an amount such that the acetone itself is not adversely affected in the production of high-quality aldehyde-free commercial-grade acetone.
- the crude acetone obtained from the process for manufacturing Cumene-Phenol which contains acetone, water, aldehydes, cumene and alpha-methylstyrene, is fed to a set-up for purifying acetone consisting of two rectifying columns.
- a set-up for purifying acetone consisting of two rectifying columns.
- the first rectifying column most of the low-boiling impurities of the acetone, including various aldehyde contaminants, are evaporated and removed as overhead product. All the remaining constituents, including the acetone, are removed from the column bottom and are fed to the second rectifying column.
- the acetone purification process is preferably accomplished at an alkaline to oxidizing agent ratio of 1 :0.01 - 1 : 100 in the first column feed, with the oxidizing agent being supplied at a rate of 0.05 - 50 g per 1000 ml of the first column feed.
- the oxidizing reagent is preferably fed in the form of a 0.1 - 20% aqueous solution.
- the oxidizing agent used may be hydrogen peroxide or another inorganic oxidizing agent, including such inorganic peroxide compounds as KMnO 4 , etc.
- a distinguishing feature of this invention is the special chemical treatment during the distillation of the crude acetone fraction with a two-component mixture consisting of an oxidizing and an alkaline agent.
- the two reagents used in the chemical treatment may be added separately or mixed, either to one of the rectifying columns or to both rectifying columns, using different places for feeding them, to optimize the oxidizing reactions and to remove the aldehyde impurities in the production of high-quality commercial-grade acetone, without negatively affecting the quality of the acetone by peroxidation.
- both the oxidizing and alkaline agent are added to both rectifying columns.
- the essence of the method consists in that, when the combined feed of the oxidizing and the alkaline reagents are present in the selected ratio, the optimal removal of aldehydes and unsaturated impurities is achieved with no harmi il side-reactions for the acetone.
- the ratio of the alkaline reagent to the oxidizing reagent achieved in the rectifying column should be held within a weight ratio range of alkali :oxidant from 1 :0.1 to 1 : 100.
- the oxidizing agent is preferably fed at a rate of 0.05-50 gram per 1000 ml of crude acetone fraction feed in the form of a 0.1 - 20% w/w aqueous solution.
- the oxidizing agent can be added to the feed into one and/or both columns, and also the to top and/or bottom part of at least one of the rectifying columns.
- This chemical oxidation treatment assumes the transfer of the low-boiling compounds, unsaturated and carbonyl-type impurities into their high-boiling derivatives, which are water-soluble and stable to thermal decomposition.
- These high-boiling derivatives go into the flask of the second rectifying column and can be easily removed from the acetone with the bottom product without being converted back into aldehydes during the distillation process.
- the "permanganate test” (permanganate time test, an oxidation test using a solution of potassium permanganate) is widely used as an analytical test for determining the total aldehydes and other reducing impurities present in commercial- grade aldehyde.
- the method calls for adding a small quantity of potassium permanganate to a sample of acetone and measuring the time required for the color to dissipate. A longer color dissipation time (the permanganate time) indicates a lower content of reducing substances in the sample and a higher quality of the acetone.
- Most of the acetone sold on the market must have a minimum permanganate time of 2 hours, but this may be difficult to achieve if the manufacturing plant is overloaded and is operating at above design capacity.
- typical permanganate times range from 0.5 hour to 3 hours for aldehyde contents of more than 50 ppm in the commercial-grade acetone. If the time is longer than 5 hours, the aldehyde content is below 10 ppm and the quality of the acetone is considered to be excellent.
- a stream of crude acetone fraction obtained from the standard Cumene-Phenol process, containing up to 65% acetone and corresponding amounts of water, cumene and alpha-methylstyrene is fed to a two-column rectifying set-up to be purified.
- This fraction also contains minor amounts, on the ppm level, of components such as acetaldehyde, propionaldehyde, methanol, mesityl oxide, diacetone alcohol, and phenol.
- the crude acetone fraction having the composition indicated above is supplied at a temperature of 49-50°C to the first rectifying column, which has an efficiency of 20-30 theoretical plates.
- a 20% aqueous solution of NaOH is supplied to the distilling flask of this same column at a rate of 3.3 g per 1000 ml of crude acetone feed.
- the temperature at the top of the first column is held at 55-56°C by using a high reflux ratio, with the small overhead fraction being withdrawn in the form of vapor at a rate of 1-2% of the weight of the feed stream, the vapor containing the greater part of the low-boiling impurities, including acetaldehyde, which condenses and is withdrawn as a by-product.
- the temperature of the flask is held at 75-80°C, and the bottom fraction, accounting for 98-99% of the weight of the feed stream, containing acetone, cumene, alpha-methylstyrene, water and various impurities, is sent on to the second rectifying column for further treatment.
- the second column had an efficiency of 45-55 theoretical plates and operated at a pressure at the top of the column of 500 mm Hg and a vapor temperature of 44-45 °C.
- the acetone is withdrawn from the top of the column in the form of vapor, completely condensed and a portion of the liquid is drawn off in the form of the end product, and another portion is returned to the top of the column in the form of reflux in a ratio of 1 :2.0 - 2.5.
- the quality of the commercial-grade acetone obtained was verified by the permanganate time test and a value of 2.5 hours was obtained.
- the two-pha e bottom product from the second distillation column contains the aqueous, cumene, and alpha-methylstyrene components of the feed stream with traces of carbonyls, aldol condensation products, phenol, and NaOH residues.
- Example 2-10 A series of experiments was undertaken using the crude acetone fraction similar in composition to that used in Example 1. The temperature, pressure and reflux ratio values for the two rectifying columns were likewise analogous to those used in Example 1.
- the aqueous solution of oxidizing agent H 2 O 2 was added to the rectifying column at different input places in the amounts indicated in Table 1.
- the oxidizing agent was added in the form of a 5% aqueous solution of H O 2
- Example 4 it was added in the form of a 3% aqueous solution
- Example 6 it was added in the form of a 10% aqueous solution.
- the amounts of NaOH alkaline reagent added in Examples 2-10 are as shown in Table 1.
- Example 12 a 2.5% aqueous solution of KMnO 4 was added as the oxidizing agent. All of the other conditions remained as in Example 1. As shown in Example 12, a 2.5% aqueous solution of KMnO 4 was added as the oxidizing agent. All of the other conditions remained as in Example 1. As shown in Example 12, a 2.5% aqueous solution of KMnO 4 was added as the oxidizing agent. All of the other conditions remained as in Example 1. As shown in Example 12,
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- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Crystallography & Structural Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Saccharide Compounds (AREA)
Abstract
Description
Claims
Priority Applications (6)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
BR0014911-0A BR0014911A (en) | 1999-10-22 | 2000-10-10 | Process for purifying acetone |
DE60031564T DE60031564D1 (en) | 1999-10-22 | 2000-10-10 | PROCESS FOR CLEANING ACETONE |
EP00968915A EP1226102B1 (en) | 1999-10-22 | 2000-10-10 | Method for purifying acetone |
JP2001533092A JP4653920B2 (en) | 1999-10-22 | 2000-10-10 | Acetone purification method |
MXPA02003959A MXPA02003959A (en) | 1999-10-22 | 2000-10-10 | Method for purifying acetone. |
AU78762/00A AU7876200A (en) | 1999-10-22 | 2000-10-10 | Method for purifying acetone |
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
RU99121965/04A RU99121965A (en) | 1999-10-22 | METHOD FOR CLEANING ACETONE | |
RU99121965 | 1999-10-22 |
Publications (1)
Publication Number | Publication Date |
---|---|
WO2001030735A1 true WO2001030735A1 (en) | 2001-05-03 |
Family
ID=20225985
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
PCT/US2000/027905 WO2001030735A1 (en) | 1999-10-22 | 2000-10-10 | Method for purifying acetone |
Country Status (11)
Country | Link |
---|---|
US (1) | US6340777B1 (en) |
EP (1) | EP1226102B1 (en) |
JP (1) | JP4653920B2 (en) |
KR (1) | KR100738718B1 (en) |
CN (1) | CN1210244C (en) |
AT (1) | ATE343559T1 (en) |
AU (1) | AU7876200A (en) |
BR (1) | BR0014911A (en) |
DE (1) | DE60031564D1 (en) |
MX (1) | MXPA02003959A (en) |
WO (1) | WO2001030735A1 (en) |
Cited By (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO2010077724A1 (en) * | 2008-12-09 | 2010-07-08 | Sabic Innovative Plastics Ip B.V. | Method for purifying acetone |
WO2010077725A1 (en) * | 2008-12-09 | 2010-07-08 | Sabic Innovative Plastics Ip B.V. | Method for purifying acetone |
CN102329200A (en) * | 2011-07-19 | 2012-01-25 | 天津基准化学试剂有限公司 | Method for preparing high-voltage electrophoresis reagent acetone |
US8710274B2 (en) | 2012-05-04 | 2014-04-29 | Lyondell Chemical Technology, L.P. | Method of purifying crude acetone stream |
CN104367014A (en) * | 2014-11-24 | 2015-02-25 | 志邦厨柜股份有限公司 | Embedded type kitchen cabinet handle |
Families Citing this family (11)
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EP1847522A1 (en) * | 2006-04-18 | 2007-10-24 | INEOS Phenol GmbH & Co. KG | Process for removal of hydroxyacetone from phenol |
KR100879635B1 (en) * | 2007-08-27 | 2009-01-21 | 한국화학연구원 | New method for the separation of acetone from waste |
CN101190879B (en) * | 2007-12-21 | 2010-07-21 | 天津大学 | Magnetization rectification method for reclaiming acetone from waste acetone menstruum |
US8322383B2 (en) * | 2009-05-27 | 2012-12-04 | Praxair Technology, Inc. | Cylinder preparation for high purity acetylene |
CN101759537B (en) * | 2010-01-28 | 2014-06-18 | 安徽时联特种溶剂股份有限公司 | Method for producing HPLC-grade acetone |
JP5550072B2 (en) * | 2010-06-02 | 2014-07-16 | 田岡化学工業株式会社 | Method for producing 9-fluorenones |
US8889915B2 (en) * | 2013-03-14 | 2014-11-18 | Kellogg Brown & Root Llc | Methods and systems for separating acetone and phenol from one another |
CN103449994A (en) * | 2013-09-09 | 2013-12-18 | 成都红胜科技发展有限公司 | Purifying process of cyclobutanone |
TWI668206B (en) * | 2017-06-29 | 2019-08-11 | 美商環球油品有限責任公司 | Process and apparatus for removing aldehydes from acetone |
EP3466915B1 (en) * | 2017-10-06 | 2019-11-27 | SABIC Global Technologies B.V. | Method of purifying acetone |
CN111995510A (en) * | 2020-09-11 | 2020-11-27 | 吉化集团油脂化工有限公司 | Fine acetone tower treatment method for improving acetone product quality |
Citations (8)
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US1542538A (en) * | 1921-11-04 | 1925-06-16 | U S Ind Alcohol Co Inc | Process of purifying acetone |
US2906676A (en) * | 1956-12-21 | 1959-09-29 | Hercules Powder Co Ltd | Process for purifying crude acetone |
US3129147A (en) * | 1964-04-14 | Recovery of acetone by distillation in | ||
SU288745A1 (en) * | 1968-08-09 | 1973-02-08 | К. В. Вильшау, Н. И. Самсонова , В. Н. Андросова | |
US4340447A (en) * | 1980-05-27 | 1982-07-20 | Bp Chemicals Limited | Process for the recovery of pure acetone from cumene hydroperoxide cleavage reaction product |
GB2116177A (en) * | 1982-02-25 | 1983-09-21 | Sumitomo Chemical Co | A method for purifying acetone |
CS229772B1 (en) * | 1982-08-20 | 1984-06-18 | Vanko Milan | Device and method of purifying of technical acetone |
SU1232665A1 (en) * | 1983-07-11 | 1986-05-23 | Предприятие П/Я А-1909 | Method of purifying acetone |
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US2971893A (en) | 1958-05-29 | 1961-02-14 | Hercules Powder Co Ltd | Phenol purification |
NL6917912A (en) * | 1968-12-10 | 1970-06-12 | ||
US3668256A (en) | 1969-08-13 | 1972-06-06 | Allied Chem | Purification of acetone |
DE2405730C3 (en) | 1974-02-07 | 1980-12-11 | Deutsche Texaco Ag, 2000 Hamburg | Process for the production of practically anhydrous acetone by means of extractive distillation |
JPS55157531A (en) | 1979-05-25 | 1980-12-08 | Sumitomo Chem Co Ltd | Recovery of acetone |
US4329510A (en) | 1979-08-07 | 1982-05-11 | Mitsui Petrochemical Industries, Ltd. | Process for purifying ketones |
EP0085289A1 (en) | 1981-12-24 | 1983-08-10 | Monsanto Company | Process for direct neutralization of product mixture resulting from acid catalyzed cleavage of alkyl aromatic hydroperoxides |
US4584063A (en) | 1982-06-28 | 1986-04-22 | Lloyd Berg | Separation of acetone from methanol by extractive distillation |
US4501645A (en) | 1983-11-01 | 1985-02-26 | Lloyd Berg | Separation of methanol from acetone by extractive distillation |
US4626600A (en) | 1984-05-11 | 1986-12-02 | General Electric Company | Process for purifying acetone |
US4620901A (en) | 1985-11-04 | 1986-11-04 | Lloyd Berg | Separation of acetone from methanol by extractive distillation |
US4722769A (en) | 1986-04-24 | 1988-02-02 | Allied Corporation | Process for recovery of acetone |
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US5762764A (en) | 1996-08-29 | 1998-06-09 | Arco Chemical Technology, L.P. | Purification of acetone |
-
2000
- 2000-09-25 US US09/668,996 patent/US6340777B1/en not_active Expired - Lifetime
- 2000-10-10 CN CNB008145083A patent/CN1210244C/en not_active Expired - Fee Related
- 2000-10-10 BR BR0014911-0A patent/BR0014911A/en not_active Application Discontinuation
- 2000-10-10 AU AU78762/00A patent/AU7876200A/en not_active Abandoned
- 2000-10-10 JP JP2001533092A patent/JP4653920B2/en not_active Expired - Fee Related
- 2000-10-10 AT AT00968915T patent/ATE343559T1/en not_active IP Right Cessation
- 2000-10-10 MX MXPA02003959A patent/MXPA02003959A/en unknown
- 2000-10-10 DE DE60031564T patent/DE60031564D1/en not_active Expired - Lifetime
- 2000-10-10 EP EP00968915A patent/EP1226102B1/en not_active Expired - Lifetime
- 2000-10-10 KR KR1020027004916A patent/KR100738718B1/en not_active IP Right Cessation
- 2000-10-10 WO PCT/US2000/027905 patent/WO2001030735A1/en active IP Right Grant
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US3129147A (en) * | 1964-04-14 | Recovery of acetone by distillation in | ||
US1542538A (en) * | 1921-11-04 | 1925-06-16 | U S Ind Alcohol Co Inc | Process of purifying acetone |
US2906676A (en) * | 1956-12-21 | 1959-09-29 | Hercules Powder Co Ltd | Process for purifying crude acetone |
SU288745A1 (en) * | 1968-08-09 | 1973-02-08 | К. В. Вильшау, Н. И. Самсонова , В. Н. Андросова | |
US4340447A (en) * | 1980-05-27 | 1982-07-20 | Bp Chemicals Limited | Process for the recovery of pure acetone from cumene hydroperoxide cleavage reaction product |
GB2116177A (en) * | 1982-02-25 | 1983-09-21 | Sumitomo Chemical Co | A method for purifying acetone |
CS229772B1 (en) * | 1982-08-20 | 1984-06-18 | Vanko Milan | Device and method of purifying of technical acetone |
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Title |
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CHEMICAL ABSTRACTS, vol. 107, no. 20, 16 November 1987, Columbus, Ohio, US; abstract no. 178647, VANKO, MILAN ET AL: "Apparatus and method for purifying technical-grade acetone" XP002160892 * |
DATABASE WPI Section Ch Derwent World Patents Index; Class E17, AN 1973-53192U, XP002160893 * |
Cited By (8)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO2010077724A1 (en) * | 2008-12-09 | 2010-07-08 | Sabic Innovative Plastics Ip B.V. | Method for purifying acetone |
WO2010077725A1 (en) * | 2008-12-09 | 2010-07-08 | Sabic Innovative Plastics Ip B.V. | Method for purifying acetone |
CN102245553A (en) * | 2008-12-09 | 2011-11-16 | 沙伯基础创新塑料知识产权有限公司 | Method for purifying acetone |
CN102245554A (en) * | 2008-12-09 | 2011-11-16 | 沙伯基础创新塑料知识产权有限公司 | Method for purifying acetone |
CN102245553B (en) * | 2008-12-09 | 2014-01-01 | 沙伯基础创新塑料知识产权有限公司 | Method for purifying acetone |
CN102329200A (en) * | 2011-07-19 | 2012-01-25 | 天津基准化学试剂有限公司 | Method for preparing high-voltage electrophoresis reagent acetone |
US8710274B2 (en) | 2012-05-04 | 2014-04-29 | Lyondell Chemical Technology, L.P. | Method of purifying crude acetone stream |
CN104367014A (en) * | 2014-11-24 | 2015-02-25 | 志邦厨柜股份有限公司 | Embedded type kitchen cabinet handle |
Also Published As
Publication number | Publication date |
---|---|
KR20020040888A (en) | 2002-05-30 |
US6340777B1 (en) | 2002-01-22 |
BR0014911A (en) | 2002-06-11 |
JP2003512447A (en) | 2003-04-02 |
JP4653920B2 (en) | 2011-03-16 |
DE60031564D1 (en) | 2006-12-07 |
AU7876200A (en) | 2001-05-08 |
CN1379751A (en) | 2002-11-13 |
ATE343559T1 (en) | 2006-11-15 |
EP1226102B1 (en) | 2006-10-25 |
CN1210244C (en) | 2005-07-13 |
KR100738718B1 (en) | 2007-07-12 |
MXPA02003959A (en) | 2002-10-23 |
EP1226102A1 (en) | 2002-07-31 |
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