WO2001005876A1 - Thermoplastic vulcanizate with defined morphology for optimum elastic recovery - Google Patents
Thermoplastic vulcanizate with defined morphology for optimum elastic recovery Download PDFInfo
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- WO2001005876A1 WO2001005876A1 PCT/US2000/019300 US0019300W WO0105876A1 WO 2001005876 A1 WO2001005876 A1 WO 2001005876A1 US 0019300 W US0019300 W US 0019300W WO 0105876 A1 WO0105876 A1 WO 0105876A1
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J3/00—Processes of treating or compounding macromolecular substances
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J3/00—Processes of treating or compounding macromolecular substances
- C08J3/005—Processes for mixing polymers
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L101/00—Compositions of unspecified macromolecular compounds
Definitions
- thermoplastic vulcanizates or 'TPVs
- thermoplastic elastomers also referred to in the past as “thermoplastic elastomers” or “TPEs”
- TPEs thermoplastic elastomers
- the properties depend on the relative amounts of "hard” and “soft” phases provided by each component, and the properties of each component.
- the hard phase is typically provided by a readily available engineering thermoplastic resin, familiarly referred to as a "plastic” for brevity.
- the plastic is chosen from polyesters, polyamides and polyolefins which provide a continuous phase of the hard phase in which dispersed domains of the "soft" phase of an elastomer are present.
- Optimizing the elastic recovery of a TPV and confi ⁇ ning the physical nature of its defined morphology, is the subject of this invention. Confirmation is obtained with both photomicrographs and computer modelling.
- the photomicrographs are from an electron microscope, preferably a transmission electron microscope (TEM).
- TEM transmission electron microscope
- TEM transmission electron microscope
- elastomer is used herein to refer to a vulcanized blend of polyolefin and rubber which may be formulated to exhibit varying degrees of elasticity such that a test strip 2.5 cm wide and 2.5 mm thick may be stretched in the range from about 5% to 100% of its initial length and still return to it; further, such vulcanized elastomer is necessarily thermoplastic and re-processable.
- a TPV having a volume fraction of rubber particles greater than about 0.7 may have an elastic recovery in the range from about 50% to 60% at 50% compression; to get a higher elastic recovery one may modify the composition of the particular rubber dispersed in the continuous plastic phase, the ratio of the dispersed and continuous phases, the amounts and composition of the curing agent(s) used, the amount of processing oil, and other ingredients, and other factors, with the expectation that, with enough trial and error, one can make a TPV with an elastic recovery in the range from about 60% to 65%. How these factors influence the morphology of a TPV has been the subject of much study.
- Elastic recovery is that fraction of a given deformation that behaves elastically; a perfectly elastic material has a recovery of 100% while a perfectly plastic recovery has no elastic recovery, (see Whittington's Dictionary of Plastics 3rd Ed. 1993 Technomic PubUshing). Elastic recovery is an important property of a TPV which is expected to behave like a natural rubber for examples in application where a TPV is used in dynamic applications such as in hoses, and in sealing applications.
- a TPV is formulated with specified components including in addition to the rubber and plastic, plasticizers, processing aids and fillers, by melt- blending the ingredients within generally defined processing parameters, until by trial and error, a usable TPV is made.
- a "usable TPV" is one which can be used in a marketable product. In particular, how the components are confined in a mixing and melt-blending means, the rate at which mixing energy is inculcated, the time over which the components are melt-blended, and the conditions under which the TPV is cooled are derived from experience and by trial and error.
- a usable TPV contains particles of rubber the majority of which, that is greater than 50% by volume, are in the size range less than about 5 ⁇ m, some being as large as 10 ⁇ m and others being as small as 0.1 ⁇ m or smaller. Particles smaller than 0.1 ⁇ m are believed to be portions fractured from larger particles while the TPV is being melt-blended, and this very small size serves to define them as "very small” particles.
- a TPV preferred for its superior physical properties and acceptable elastic recovery has relatively large domains of rubber the majority of which are in the size range from about 1 - 5 ⁇ , preferably 1 - 3 ⁇ m, and this size range serves to define them as "large particles".
- the shape of all particles resembles that of a distorted ellipsoid or elongated ovoid, and this shape is particularly evident in large particles.
- the remaining rubber particles, in the size range larger than a "very small” particle and smaller than the mean diameter of the "large particles”, are defined as “small particles” or “mid-range particles” which also are generally ellipsoidal in shape. Because of the shape, the "diameter” referred to is the effective diameter, that is, the diameter the particle would have had if it was spherical.
- the elongated ovoid shape of the particles allows a high packing fraction of rubber particles in a unit volume of TPV, this being a characteristic of a usable TPV.
- the number of very small particles is of minor consequence in a TPV; the number of small and large particles is not. To date, there has been no clear teaching as to what effect the size of the particles and their distribution has in a TPV particularly with respect to its elastic recovery.
- thermoplastic vulcanizate of an elastomer and a plastic comprising particles of elastomer dispersed in a continuous phase of plastic, such that a majority of particles, and particularly a majority of large particles which are present in a major proportion by volume relative to the small particles, are adjacent at least one small particle critically spaced apart by ligaments, and at least 15% of the ligaments have a thickness less than 10% of the mean diameter of large particles, preferably less than 5% of the "mean large particle diameter", and the remaining ligaments have a thickness less than 50%, preferably from 15% to about 30% of the mean large particle diameter.
- the mean large particle diameter is in the range from 1 ⁇ m to 3 ⁇ m, most preferably about 1 ⁇ m; and, the small particle diameter is in the range from 1% to 60% of the mean large particle diameter, preferably from 10% to 40%.
- Figure 1 is a TEM photomicrograph of a TPV in which the dispersed rubber particles have a volume fraction of 0.77 at a magnification of 18,000 X.
- Figure 2 is a schematic illustration of a simplified idealized finite element analysis (FEA) model of four large particles adjacent a small particle.
- FEA finite element analysis
- Figure 3 is an example mesh 5-particle model of a representative TPV ('TPV-R") having a Shore A 73 hardness.
- Figures 4A - 4F are finite element meshes (showing particles only) for six micromechanical models.
- Figure 5 shows curves predicting TPV-R plane strain stress-strain behavior during loading to a strain of -0.50 and unloading from that strain, based on the micromechanical model.
- Figure 6 shows curves predicting TPV-R plane strain stress-strain behavior during loading to a strain of -0.70 and unloading from that strain, based on the micromechanical model.
- Figure 7 shows curves for a RVE Case 6 model predictions of the plane strain stress-strain behavior compared to experimental results for loading to/unloading from a strain of -0.30.
- Figures 8A - 8D are deformed meshes during loading and unloading (imposed strain of -0.70).
- TPVs which benefit greatly from having high elastic recovery in the range above 65%, preferably from about 70% to 95%, contain from about 55% to 95% volume fraction of rubber and have a hardness in the range from about Shore A 30 to Shore A 90.
- the TEM photomicrograph identified as Fig 1 shows the morphology of the TPV-R prepared in the illustrative example below. A sample of the TPV-R is microtomed and the surface stained with ruthenium tetroxide. The TEM image is obtained with an efficient backscattered electron detector which allows good differentiation between the phases and shows many distorted ellipsoidal EPDM particles in the 1 - 3 ⁇ m size range separated by regions of the continuous PP phase.
- EPDM may be made to include a wide range of olefin and non-conjugated diene comonomers, the EPDM used is a copolymer of ethylene, propylene and ethylidenenorbornene.
- the thermoplastic polyolefin is general purpose polypropylene (PP), sp. gr.
- the ingredients are preferably melt-blended in an extruder with a barrel temperature maintained in the range from about 160 °C to about 200 °C, samples being taken from material processed with a residence time ranging from about 2 min to 4 min, at a temperature ranging from about 170 °C to 180 °C.
- the melt-blended TPV has the following physical properties: Hardness 72 Shore A
- the volume fraction of rubber particles is 0.77. Though there is a substantial amount of clay, it is believed that most of the clay is in the rubber particles, and the remainder, being inert in the plastic phase, does not affect the properties of the PP so significantly as to affect the procedure used in the micromechanical model.
- the process for producing a TPV with substantially maximized elastic recovery comprises melt-blending ingredients of the TPV at appropriate processing conditions for sufficient time while providing enough energy at a rate sufficient to produce a matrix of plastic in which substantially all the large particles are adjacently disposed relative to at least one small particle which is adjacent to at least 3 large particles, the small particle and the large particles being in near- contiguous relationship such that the small particle is spaced apart from at least one large particle by at least two ligaments having a thickness less than 5% of the mean diameter of large particles in the matrix, and the remaining ligaments are in the range from more than 10% to about 50% of the mean large particle diameter.
- the melt-blending means is repetitively operated to produce an arbitrarily large amount of TPV which has optimal elastic recovery.
- Fig 1 The TEM photomicrograph, Fig 1, is representative of a sample with about 25% of the ligaments being critically thin; this sample showed the highest elastic recovery, about 50% from 25% compression; and about 70% recovery from 50% compression. As will be evident from the Table 2 presented below, these results are confirmed by FEA using a unique and novel modification of commercially available Abaqus software as described in greater detail below.
- the elastomer phase was modeled using a three-dimensional RVE based on a 5-particle model, and elastic properties measured for an EPDM rubber used in commercial Santoprene 73A rubber.
- the matrix phase was modeled using elastic viscoplastic properties measured for PP with 20% by weight oil.
- the rubber particles were assumed to be round and distributed in a hexagonal close packing array. Five particles are modeled to simulate the entire array using a plane strain finite element model in which the material being compressed is restrained between parallel planes, and the volume fraction of rubber is the same in each. It is assumed that there is no relative movement or "slip" at the boundary between a rubber particle and the continuous PP phase because they are cohesively bonded, that is, one phase cannot be separated from the other without tearing it out.
- Fig 2 there is shown a closely packed array of a 5-particle model, the small particle in the middle surrounded by 4 large particles.
- a 4-particle array with a small particle surrounded by 3 large particles will have 6 ligaments.
- the distribution of very small particles is ignored as their effect is believed to be insubstantial and there is no definitive data to indicate otherwise.
- the modelling of five particles in a matrix uniquely captures the interaction of the particles with one another as well as the interaction with the matrix. Some stages of deformation behavior are found to be matrix-dependent and other stages were particle-dependent.
- the 5-particle model predicts both the loading and the unloading behavior which was closely comparable to experimental results.
- the micromechanical model revealed that the hgaments of PP plastically deform early on in the deformation and are the controlling factors in the initial stiffness and "flow stress" of the system.
- the bulkier regions of PP are plastically essentially non- deformable; but deformation of thin hgaments provides the elastomer-hke behavior of the TPV.
- the rubber undergoes recovery while thin hgaments rotate and buckle to accommodate the recovery.
- a center small particle RM is nested between four large particles Rl, R2, R3 and R4 in the TPV-R.
- the plane strain nature of the model means that the particles are modelled as cylinders and the strain along the axis of the cylinder (i.e. into the paper) is restricted to be zero. Also note that symmetry boundary conditions are apphed to all edges of the model such that vertical lines experience uniform horizontal displacement and horizontal lines experience uniform vertical displacement. Because of the plane strain behavior of the model, simulated stress-strain curves are compared to experimental plane strain stress vs strain curves (as opposed to uniaxial stress vs. strain curves).
- Figure 3 depicts a typical finite element mesh for the five-particle RVE (5P-RVE) for the TPV-R.
- the 5P-RVE micromechanical model consists of a center small particle nested between four larger particles. Note that the two- dimensional plane strain nature of the model means that the "particles" are cylinders where the cylinder axes are co-axial with the constraint direction.
- the TPV-R particle volume fraction is 0.77 and the particle area fraction (in the 1-2 plane) of the model is approximated to be the volume fraction of particles (a reasonable approximation given the large volume fraction of particles and the thin ligaments of matrix bridging the particles).
- the radius of the four large particles can be independently set to permit the study the effect of varying particle size distribution on the mechanical response.
- the table below details the geometric configuration used in each simulation case in terms of the ratio of the radius of each large particle to that of the middle particle: TABLE 1
- the EPDM stress-strain behavior is modelled using the Arruda-Boyce constitutive model for rubber elasticity.
- Each RVE is subjected to an axial loading condition whereby the top edge is uniformly compressed in the 2-direction.
- the total force on edge AD, the RVE height H, and the RVE width W are monitored as a function of applied displacement.
- the RVE true stress vs. strain response is then computed exactly as done in the experiments.
- FIG. 4 shows the finite element mesh (depicting only the particles) for each of the six cases, the geometry of which is set forth in Table 1 above.
- Case 1 possesses perfect symmetry with respect to the relationship of each large particle radius to that of the middle particle. This sets up identical matrix ligament thicknesses between each large particle and RM.
- the asymmetry of the mesh appears as a shghtly smaller matrix hgament thickness bridging Rl and R3 with RM compared to the hgament thickness bridging R2 and R4 with RM.
- Case 4 possesses four different hgament lengths of similar dimensions to those in Cases 2 and 3.
- Case 5 possesses even smaller hgament thicknesses bridging Rl and R3 with RM than those of Cases 1, 2, 3 and 4.
- Case 6 is seen to possess extremely thin ligaments between two of the large particles and the middle particle.
- Figures 5 and 6 depict the true stress-true strain behavior to strains of -0.50 and -0.70 respectively, as computed by the six micromechanical models.
- each model predicts a somewhat different stress-strain behavior.
- Each model predicts a relatively stiff initial response followed by a "flow stress” where the term “flow stress” refers to the stress level at which a dramatic roll-over or decrease in slope occurs in the stress-strain curve.
- the flow stress is then followed by strain stiffening/hardening (an increase in stress with continued straining).
- strain stiffening/hardening an increase in stress with continued straining.
- the initial stiffness is somewhat influenced by the geometry, where a smaller hgament length produces a more compliant initial response. The most dramatic effect of geometry is seen in the level of the flow stress.
- Ligament Thickness Data may be plotted from analyses of various structures with equal volume ratio of elastomer and thermoplastic matrix. The mean particle diameter of the large particles is 1.0 ⁇ m. The data are given in Table 2 below.
- the model used herein is a 5 particle RVE that uses the Abaqus finite element analysis software.
- the rubber material is modeled using the Arruda Boyce 8 chain model for rubber.
- the plastic matrix is modeled using the elastic plastic theory mentioned earlier. Data for the rubber phase and plastic are measured separately using a Monsanto T-10 tensometer and an Instron tensometer with controUed strain rate and fit to these theories.
- the rubber was mixed in a Brabender internal mixer adding the curative components on a rubber null to keep the temperature below the vulcanization temperature. Samples were press-cured to the maximum cure point based on a rheometer cure curve.
- the rubber to plastic volume ratio is selected based on a typical commercially significant elastomeric material.
- the foUowing Table 3 sets forth data for theoretically formulated TPVs for which the "% recovery" values in itahcs are constructively presented and rounded off.
- the ratio of rubber: plastic is 77:23 and in each case the rubber is given a modulus of 0.25 MPa. This ratio is commercially significant and used in a soft rubbery material which is used in a wide variety of appUcations.
- the values generated for the TPVs compare a theoretical thermoplastic with varying stiffness, formulated with rubber properties maintained constant, on the assumption that the same rubber would be used in each recipe.
- the plastic stiffness in the range from 100 MPa to 2500 MPa covers the range for most commercially useful thermoplastics.
- the three values selected are based on the low, high and middle of the range. Only three of the several examples discussed previously are presented to span the Ugament thickness range.
- thermoplastic selected for tests are commercially interesting materials used to formulate TPVs which it is hoped wUl have optimum elastic recovery.
- the foUowing Table 5 presents recipes for rubber compounds used in various samples.
- the natural rubber (NR) used was SMR CV-60, the nitrile rubber (NBR) was Nipol 1022 and the ethylene acrylate rubber (AEM) was Vamac GLS.
- ⁇ SP-1045 resin is an alkyl pheol-formaldehyde resin 2 di-orthotolyl guanidine ⁇ DIAK is hexamethylenediamine carbamate
- the foUowing specific TPV compositions are prepared, each having a rubbe ⁇ plastic ratio of 77:23 by volume: EPDM/PP; NR/PE; NBR/PA6; and AEM/PBT.
- Other additives that might be added in commerciaUy useful compositions, additives such as, oils, plasticizers, stabilizers, fiUers, reinforcements, etc. are purposely not included in the recipe to avoid compUcating the problem of arriving at easUy comprehensible results for these demonstration purposes.
- the foUowing Table 6 sets forth the values for % recovery calculated for the four TPV compositions specified above.
- the value in itahcs is are constructively arrived at and rounded off whUe some questionable computer results were resolved to complete the demonstration with these various rubber/plastic pairs used for TPV composition.
- Olefmic plastics are preferred, including polymers and copolymers of lower olefins having from 1 to 4 carbon atoms, one or more of which monomer may have a functional group, typicaUy halogen, hydroxyl, carboxyl, and copolymers of alpha unsaturated diolefins.
- thermoplastic a non-polyolefinic plastic may be used, for example, one selected from the group consisting of polyamides, polycarbonates, polyesters, polysulfones, polylactones, polyacetals, acrylonitrile-butadiene-styrene (ABS), polyphenylene oxide (PPO), polyphenylene sulfide (PPS), styrene-acrylonitrile (SAN), polyimides, styrene-maleic anhydride (SMA) and aromatic polyketones, any of which may be used by itself or in combination with another.
- Most preferred engineering thermoplastic resins are polyamides and polyesters.
- CommerciaUy available polyamides having a Tg or melting temperature (Tm) above 100°C may be used but those having a Tm in the range from 160°C to about 280°C are preferred.
- Preferred polyamides are nylon 6, nylon 11, nylon 12, nylon 6,6, nylon 6,9, nylon 6,10, and nylon 6/6,6. Most preferred are nylon 6, nylon 6,6, nylon 11, nylon 12 and mixtures or copolymers thereof. Additional examples of suitable polyamides described in the Encyclopedia of Polymer Science and Technology, by Kirk & Othmer, Second Edition, Vol. 11, pages 315-476, are incorporated by reference thereto as if fuUy set forth herein.
- the polyamides generaUy have a number average molecular weight of from about 10,000 to about 50,000, and desirably from about 30,000 to about 40,0000.
- Suitable thermoplastic polyesters include the various ester polymers such as polyester, copolyester, or polycarbonate, polybutylene terephthalate (PBT), etc., a monofunctional epoxy endcapped derivative thereof, and mixtures thereof.
- the various polyesters can be either aromatic or aliphatic or combinations thereof and are generally directly or indirectly derived from the reactions of diols such as glycols having a total of from 2 to 6 carbon atoms and desirably from about 2 to about 4 carbon atoms with aUphatic acids having a total of from 2 to 20 carbon atoms and desirably from about 3 to about 15 or aromatic acids having a total of from about 8 to about 15 carbon atoms.
- aromatic polyesters are preferred such as polyethyleneterephthalate, polybutyleneterephthalate, polyethyleneisophthalate, polynaphthaleneterephthalate, and the like, as weU as endcapped epoxy derivative thereof, e.g., a monofunctional epoxy polybutyleneterephthalate.
- Various polycarbonates can also be utilized and the same are esters of carbonic acid.
- a suitable polycarbonate is that based on bisphenol A, i.e., poly(carbonyldioxy- l,4-phenyleneisopropyhdene-l,4-phenylene).
- the various ester polymers also include block polyesters such as those containing at least one block of a polyester and at least one rubbery block such as a polyether derived from glycols having from 2 to 6 carbon atoms, e.g., polyethylene glycol, or from alkylene oxides having from 2 to 6 carbon atoms.
- a preferred block polyester is polybutyleneterephthalate-b-polyethylene glycol which is available as Hytrel from DuPont.
- curable rubbers include halogenated olefinic, acrylate and nitrile rubbers, and sihcone.
- Rubbers useful in the blends include butyl rubber, halobutyl rubber, and EPR (ethylene/propylene rubber), acrylonitrile/butadiene rubber (NBR) and natural rubber. Combinations of two or more rubbers of different types can also be used.
- Thermoplastic elastomers which can be successfully foamed by the process of the invention are described in the foUowing U.S. patents, the disclosures of which are herein incorporated by reference: U.S. Pat. Nos.
- alkyl typically has 1 to 3 carbon atoms and includes a repeating unit with a functional group and another repeating unit chosen from ethyl acrylate, butyl acrylate, ethylhexyl acrylate, and the like.
- An olefinic repeating unit is chosen from an olefin having from 2 to 4 carbon atoms, and the molar ratio of such olefin units to acrylate repeating units is typically in the range from 0.5 to 1.5.
- a preferred functional group on an acrylic rubber is halogen, carboxyl, epoxy, or hydroxy. Suitable acrylate rubbers are commercially available.
- the curing of a rubber in each stage is effected in the presence of an effective amount of one or more curing agents present in an amount sufficient to result in a substantially complete cure of that rubber, namely at least 90 percent, though a lesser degree of cure, as low as about 80 percent may be acceptable.
- Curing agents for a particular rubber are usuaUy specified by the maker of the rubber.
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Priority Applications (6)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
AU63480/00A AU6348000A (en) | 1999-07-16 | 2000-07-14 | Thermoplastic vulcanizate with defined morphology for optimum elastic recovery |
JP2001511527A JP2003505552A (en) | 1999-07-16 | 2000-07-14 | Thermoplastic vulcanizates with defined morphology for optimal elastic recovery |
US10/069,083 US6579944B1 (en) | 1999-07-16 | 2000-07-14 | Thermoplastic vulcanizate with defined morphology for optimum elastic recovery |
DE60005964T DE60005964T2 (en) | 1999-07-16 | 2000-07-14 | THERMOPLASTIC VOLCANISATE WITH DEFINED MORPHOLOGY FOR OPTIMUM RECOVERY |
EP00950367A EP1198495B1 (en) | 1999-07-16 | 2000-07-14 | Thermoplastic vulcanizate with defined morphology for optimum elastic recovery |
KR1020027000569A KR20020033732A (en) | 1999-07-16 | 2000-07-14 | Thermoplastic vulcanizate with defined morphology for optimum elastic recovery |
Applications Claiming Priority (2)
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US14436299P | 1999-07-16 | 1999-07-16 | |
US60/144,362 | 1999-07-16 |
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WO2001005876A1 true WO2001005876A1 (en) | 2001-01-25 |
WO2001005876A9 WO2001005876A9 (en) | 2002-08-08 |
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PCT/US2000/019300 WO2001005876A1 (en) | 1999-07-16 | 2000-07-14 | Thermoplastic vulcanizate with defined morphology for optimum elastic recovery |
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US (1) | US6579944B1 (en) |
EP (1) | EP1198495B1 (en) |
JP (1) | JP2003505552A (en) |
KR (1) | KR20020033732A (en) |
AU (1) | AU6348000A (en) |
DE (1) | DE60005964T2 (en) |
ES (1) | ES2204667T3 (en) |
WO (1) | WO2001005876A1 (en) |
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KR102249833B1 (en) | 2020-03-30 | 2021-05-10 | 한국신발피혁연구원 | Tpv composition for weather strip joint having low compression set and manufacturing method for thereof |
Citations (1)
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US6207752B1 (en) * | 1997-12-10 | 2001-03-27 | Advanced Elastomer Systems Lp | Thermoplastic vulcanizates of carboxylated nitrile rubber and thermoplastic polyurethanes |
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- 2000-07-14 WO PCT/US2000/019300 patent/WO2001005876A1/en active IP Right Grant
- 2000-07-14 KR KR1020027000569A patent/KR20020033732A/en not_active Application Discontinuation
- 2000-07-14 DE DE60005964T patent/DE60005964T2/en not_active Expired - Fee Related
- 2000-07-14 US US10/069,083 patent/US6579944B1/en not_active Expired - Fee Related
- 2000-07-14 EP EP00950367A patent/EP1198495B1/en not_active Expired - Lifetime
- 2000-07-14 ES ES00950367T patent/ES2204667T3/en not_active Expired - Lifetime
- 2000-07-14 JP JP2001511527A patent/JP2003505552A/en not_active Withdrawn
- 2000-07-14 AU AU63480/00A patent/AU6348000A/en not_active Abandoned
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US5073597A (en) * | 1989-05-26 | 1991-12-17 | Advanced Elastomer Systems, L. P. | Dynamically vulcanized alloys having two copolymers in the crosslinked phase and a crystalline matrix |
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Cited By (1)
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WO2015061252A3 (en) * | 2013-10-21 | 2015-07-02 | Massachusetts Institute Of Technology | Tunable surface topography through particle-enhanced soft composites |
Also Published As
Publication number | Publication date |
---|---|
EP1198495A1 (en) | 2002-04-24 |
WO2001005876A9 (en) | 2002-08-08 |
JP2003505552A (en) | 2003-02-12 |
DE60005964D1 (en) | 2003-11-20 |
EP1198495B1 (en) | 2003-10-15 |
US6579944B1 (en) | 2003-06-17 |
AU6348000A (en) | 2001-02-05 |
ES2204667T3 (en) | 2004-05-01 |
DE60005964T2 (en) | 2004-08-12 |
KR20020033732A (en) | 2002-05-07 |
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