WO2000068509A1 - A directional reflector material and the producing method of the same - Google Patents
A directional reflector material and the producing method of the same Download PDFInfo
- Publication number
- WO2000068509A1 WO2000068509A1 PCT/CN1999/000066 CN9900066W WO0068509A1 WO 2000068509 A1 WO2000068509 A1 WO 2000068509A1 CN 9900066 W CN9900066 W CN 9900066W WO 0068509 A1 WO0068509 A1 WO 0068509A1
- Authority
- WO
- WIPO (PCT)
- Prior art keywords
- glass beads
- substrate
- glass
- material according
- mosaic
- Prior art date
Links
Classifications
-
- E—FIXED CONSTRUCTIONS
- E01—CONSTRUCTION OF ROADS, RAILWAYS, OR BRIDGES
- E01F—ADDITIONAL WORK, SUCH AS EQUIPPING ROADS OR THE CONSTRUCTION OF PLATFORMS, HELICOPTER LANDING STAGES, SIGNS, SNOW FENCES, OR THE LIKE
- E01F9/00—Arrangement of road signs or traffic signals; Arrangements for enforcing caution
- E01F9/50—Road surface markings; Kerbs or road edgings, specially adapted for alerting road users
- E01F9/506—Road surface markings; Kerbs or road edgings, specially adapted for alerting road users characterised by the road surface marking material, e.g. comprising additives for improving friction or reflectivity; Methods of forming, installing or applying markings in, on or to road surfaces
- E01F9/524—Reflecting elements specially adapted for incorporation in or application to road surface markings
-
- E—FIXED CONSTRUCTIONS
- E01—CONSTRUCTION OF ROADS, RAILWAYS, OR BRIDGES
- E01F—ADDITIONAL WORK, SUCH AS EQUIPPING ROADS OR THE CONSTRUCTION OF PLATFORMS, HELICOPTER LANDING STAGES, SIGNS, SNOW FENCES, OR THE LIKE
- E01F9/00—Arrangement of road signs or traffic signals; Arrangements for enforcing caution
- E01F9/60—Upright bodies, e.g. marker posts or bollards; Supports for road signs
- E01F9/604—Upright bodies, e.g. marker posts or bollards; Supports for road signs specially adapted for particular signalling purposes, e.g. for indicating curves, road works or pedestrian crossings
- E01F9/619—Upright bodies, e.g. marker posts or bollards; Supports for road signs specially adapted for particular signalling purposes, e.g. for indicating curves, road works or pedestrian crossings with reflectors; with means for keeping reflectors clean
Definitions
- the present invention relates to a directional reflective material and a manufacturing method thereof, and more particularly, to a directional reflective material used for obvious signs such as reflective marking tapes, traffic barriers, building decoration and advertising, and a manufacturing method thereof.
- the object of the present invention is to provide a directional reflective material with good self-cleaning properties, glass beads are not easy to fall off, abrasion-resistant, pressure-resistant, aging-resistant, and durable.
- the present invention provides a directional reflective material, which includes a substrate and glass beads, and a fusion layer is formed between the substrate and the glass beads, so as to firmly fuse the glass beads on the substrate.
- the present invention also provides a method for manufacturing a retroreflective material, including the following steps:
- the glass beads are very strong, the glass beads are not easy to fall off, wear resistance, pressure resistance, aging resistance, and good durability; glass, mosaic, ceramic, or enamel are used as the substrate. It has good self-cleaning performance and good directional reflection effect.
- FIG. 1 is a sectional view of a directional reflective material according to the present invention
- FIG. 2 is a cross-sectional view of another directional reflective material according to the present invention.
- FIG. 3 is a schematic diagram of a method of manufacturing a retroreflective material according to the present invention.
- a directional reflective material of the present invention includes a base body 3 and glass beads 1.
- the base body 3 may be glass or mosaic.
- the embedded depth of the glass beads 1 in the matrix 3 is 20% to 60% of the diameter of the glass beads 1, preferably 55% to 60%.
- FIG. 3 is a schematic diagram of a method of manufacturing the retroreflective material described in FIG. 1, and the glass beads are embedded in the glass or mosaic substrate 3 by a rolling and spreading method. As shown in FIG.
- the unshaped glass or mosaic fluid is pressed into glass or mosaic of a certain thickness by the opposing rollers 6, and then rolled and cut into a geometric glass or mosaic substrate 3 by a counter cutting roller 5.
- the drum 5 is provided with a plurality of horizontal grooves 8.
- the depth of the horizontal grooves 8 is 40% to 80%, preferably 40% to 45%, of the diameter of the glass beads 1.
- the glass beads are conveyed into the horizontal grooves 8 through the glass bead conveying channel 7. During rolling, part of the glass beads 1 is hidden in the horizontal groove 8 during rolling, and the other part is pressed into the molten glass or mosaic substrate 3.
- the glass The surface of the bead 1 is fused with the glass or mosaic substrate 3, which is very strong. At the same time, it ensures the transparency and roundness of the glass beads and ensures the retroreflective effect.
- the white, yellow, and red of the glass or mosaic substrate are transparent glass.
- the reflective layer of the beads reaches the retroreflective index of the traffic sign.
- another directional reflective material of the present invention includes a base body 3 and glass beads 1.
- the base body 3 may be ceramic or enamel, and a fusion layer 4 is formed between the base body 3 and the glass beads 1.
- the thickness of the enamel layer 2 is 20% to 60% of the diameter of the glass bead 1, preferably 55% to 60%.
- the depth of the glass beads 1 embedded in the matrix 3 is 20% to 60% of the diameter of the glass beads 1, preferably 55% to 60%.
- the method for manufacturing a retroreflective material shown in Figure 2 is as follows: First, press the ceramic into shape, then fire it into an unglazed green body, spray the unglazed green body with a low-melting glass enamelled material, and send it to a stove to sinter it to After annealing at 800 ° C ⁇ 90 ° C, a device for spraying glass beads 1 is installed in the annealing section of the cooker. While the low-temperature glaze is at 700 ° C ⁇ 900 ° C, the glass beads 1 are uniformly sprayed or sprinkled on the enamel layer of the ceramic substrate. 2, at this time, the glass beads 1 fall into the enamel layer 2, and the surface of the glass beads 1 is fused with the enamel layer 2.
- the method for manufacturing another directional reflective material shown in FIG. 2 is as follows: In the annealing phase of the enamel product, the glass beads 1 are sprayed or sprinkled at a temperature of 700 ° C to 900 ° C, and the glass beads 1 are fused to the enamel layer 2 of the enamel. Products have a reflective effect. This method can be used to manufacture a variety of transportation products such as highway guardrails, reflective pillars, etc., and wide mouths.
- the directional reflective material sheet made of a mosaic or ceramics as a substrate can be used for making a cursor line tape. Apply a layer of water-soluble glue on the paper tape, and paste the above piece of directional reflective material on the paper tape. There is a gap between the sheets. Glass beads are scattered in the gap, and the glass beads are also adhered by the water-soluble glue to obtain Yonggu Changjie road anti-cursor line belt.
Landscapes
- Engineering & Computer Science (AREA)
- Architecture (AREA)
- Civil Engineering (AREA)
- Structural Engineering (AREA)
- Optical Elements Other Than Lenses (AREA)
- Road Signs Or Road Markings (AREA)
Abstract
The invention provides a directional reflector material, which includes a base (3) and glass beads (1), and comprises fusion zone (4) between the base (3) and glass beads (1) for firmly fusing glass beads (1) onto the base (1). Also provided is a method of producing a directional reflector material, the method comprising the steps of: a) making the temperature of the base (3) reach 700 °C∩900 °C; b) spreading the glass beads (1) over the surface of the base (3), fusing the surface of glass beads (1) with the base (3); c) lowering the temperature of the base (3) which spreaded with glass beads (1) immediately and smoothly.
Description
一种定向反光材料及其制造方法 技术领域 Technical field of directional reflective material
本发明涉及一种定向反光材料及其制造方法， 尤其是涉及用于明显标志如反光 标线带、 交通护栏、 建筑装饰和广告的定向反光材料及其制造方法。 The present invention relates to a directional reflective material and a manufacturing method thereof, and more particularly, to a directional reflective material used for obvious signs such as reflective marking tapes, traffic barriers, building decoration and advertising, and a manufacturing method thereof.
背景技术 Background technique
目前世界各国道路划线采用在油漆表面粘玻璃珠产生定向反光的方法， 中国专 利 97202912号和国际申请号为 PCT US95 U8686的专利申请公开了用有机粘结剂将 基体和玻璃珠粘结在一起的方法， 上述方法及其产品在使用中有一些问题： 油漆划 线的有机粘结剂易粘污物变黑， 自洁性能差， 粘结的玻璃珠易脱落， 失去反光和诱 导作用， 有机粘结剂也易脱落， 尤其是在水泥路面半年就脱落了。 因此需反复划线， 耗费人力、 物力， 浪费很大， 并影响交通安全， 反光膜颜色和粘结剂在七至十年左 右褪色脱落， 不能在建筑物上作持久装饰广告。 At present, the road marking of various countries around the world adopts a method of producing directional reflection by adhering glass beads on the surface of paint. The patent applications of Chinese Patent No. 97202912 and International Application No. PCT US95 U8686 disclose that the substrate and the glass beads are bonded together with an organic binder There are some problems in the use of the above method and its products: the organic binder of the paint scribing is easy to stick to the dirt, the self-cleaning performance is poor, the bonded glass beads are easy to fall off, and the reflection and induction are lost. Organic The adhesive is also easy to fall off, especially on the cement pavement in half a year. Therefore, it is necessary to repeatedly draw lines, which consumes manpower, material resources, a great waste, and affects traffic safety. The color of the reflective film and the adhesive fade and fall off in about seven to ten years, and it cannot be used as a durable decorative advertisement on the building.
本发明的目的是提供一种自洁性好， 玻璃珠不易脱落， 耐磨、 耐压、 抗老化， 持 久性强的定向反光材料。 The object of the present invention is to provide a directional reflective material with good self-cleaning properties, glass beads are not easy to fall off, abrasion-resistant, pressure-resistant, aging-resistant, and durable.
发明内容 Summary of the Invention
为了实现上述目的， 本发明提供了一种定向反光材料， 包括基体和玻璃珠， 基 体和玻璃珠之间有熔结层， 用以将所述玻璃珠牢固地熔结在所述基体上。 In order to achieve the above object, the present invention provides a directional reflective material, which includes a substrate and glass beads, and a fusion layer is formed between the substrate and the glass beads, so as to firmly fuse the glass beads on the substrate.
本发明还提供了一种制造定向反光材料的方法， 包括以下步骤： The present invention also provides a method for manufacturing a retroreflective material, including the following steps:
a、 使基体温度处于 70(rC〜900°C ; a, make the substrate temperature at 70 (rC ~ 900 ° C ;
b、 将玻璃珠散布于基体表面， 使玻璃珠表面与基体熔结； b. Spread the glass beads on the surface of the substrate, so that the surface of the glass beads and the substrate are fused;
c、 立即将散布有玻璃珠的基体平稳降温。 c. Immediately cool the substrate with the glass beads scattered.
由于是采用熔结的方法将玻璃珠表面与基体熔结在一起， 十分牢固， 玻璃珠不 易脱落， 耐磨、 耐压、 抗老化， 持久性好； 采用玻璃、 马赛克、 陶瓷或搪瓷作为基 体， 有很好的自洁性， 并且具有良好的定向反光效果。 Because the glass bead surface and the substrate are fused together by a fusion method, the glass beads are very strong, the glass beads are not easy to fall off, wear resistance, pressure resistance, aging resistance, and good durability; glass, mosaic, ceramic, or enamel are used as the substrate. It has good self-cleaning performance and good directional reflection effect.
附图概述 Overview of the drawings
下面结合附图和实施例对本发明进一步说明： The invention is further described below with reference to the drawings and embodiments:
图 1是本发明的一种定向反光材料的剖面图； FIG. 1 is a sectional view of a directional reflective material according to the present invention;
图 2是本发明的另一种定向反光材料的剖面图； 2 is a cross-sectional view of another directional reflective material according to the present invention;
图 3是制造本发明的一种定向反光材料的方法的示意图。 FIG. 3 is a schematic diagram of a method of manufacturing a retroreflective material according to the present invention.
本发明的最伟实施方式 The greatest embodiment of the invention
参见图 1， 本发明的一种定向反光材料包括基体 3和玻璃珠 1， 基体 3可以是玻 璃或马赛克， 基体 3和玻璃珠 1之间有熔结层 4， 玻璃珠 1可熔结在玻璃或马赛克基 体 3的单面或双面。 玻璃珠 1在基体 3中的嵌入深度为玻璃珠 1直径的 20 %〜60 %， 最好是 55 %〜60%。
图 3 是制造图 1 中所述定向反光材料的方法的示意图,釆用滚压散布的方法将玻 璃珠嵌入玻璃或马赛克基体 3 中。 如图 3 所示， 未成型的玻璃或马赛克流体经过对 置的滚筒 6压制成一定厚度的玻璃或马赛克， 再经过对切滚筒 5 滚压切割成几何形 状的玻璃或马赛克基体 3， 在对切滚筒 5上设置若干横槽 8， 横槽 8的深度是玻璃珠 1直径的 40%〜80 %， 最好是 40 %〜45 %， 通过玻璃珠输送通道 7将玻璃珠输送到 横槽 8中， 滚压时玻璃珠 1 的一部分在滚压过程中藏入横槽 8 中， 另一部分压入熔 融的玻璃或马赛克基体 3 中， 滚压时的温度在 700°C〜900°C时， 玻璃珠 1表面与玻 璃或马赛克基体 3 熔结为一体， 非常牢固， 同时又确保了玻璃珠的透明度、 圆度不 变， 保障了逆反射作用， 玻璃或马赛克基体的白色、 黄色、 红色作为透明玻璃珠的 反射层， 达到了交通标志的逆反射指标。 Referring to FIG. 1, a directional reflective material of the present invention includes a base body 3 and glass beads 1. The base body 3 may be glass or mosaic. There is a fusion layer 4 between the base body 3 and the glass beads 1, and the glass beads 1 may be fused to glass. Or one or both sides of the mosaic base 3. The embedded depth of the glass beads 1 in the matrix 3 is 20% to 60% of the diameter of the glass beads 1, preferably 55% to 60%. FIG. 3 is a schematic diagram of a method of manufacturing the retroreflective material described in FIG. 1, and the glass beads are embedded in the glass or mosaic substrate 3 by a rolling and spreading method. As shown in FIG. 3, the unshaped glass or mosaic fluid is pressed into glass or mosaic of a certain thickness by the opposing rollers 6, and then rolled and cut into a geometric glass or mosaic substrate 3 by a counter cutting roller 5. The drum 5 is provided with a plurality of horizontal grooves 8. The depth of the horizontal grooves 8 is 40% to 80%, preferably 40% to 45%, of the diameter of the glass beads 1. The glass beads are conveyed into the horizontal grooves 8 through the glass bead conveying channel 7. During rolling, part of the glass beads 1 is hidden in the horizontal groove 8 during rolling, and the other part is pressed into the molten glass or mosaic substrate 3. When the rolling temperature is 700 ° C ~ 900 ° C, the glass The surface of the bead 1 is fused with the glass or mosaic substrate 3, which is very strong. At the same time, it ensures the transparency and roundness of the glass beads and ensures the retroreflective effect. The white, yellow, and red of the glass or mosaic substrate are transparent glass. The reflective layer of the beads reaches the retroreflective index of the traffic sign.
参见图 2， 本发明的另一种定向反光材料包括基体 3和玻璃珠 1， 基体 3可以是 陶瓷或搪瓷， 基体 3和玻璃珠 1之间有熔结层 4， 玻璃珠熔结在所述陶瓷或搪瓷的釉 质层 2上。 釉质层 2的厚度是玻璃珠 1直径的 20%〜60%， 最好是 55 %〜60 %。 玻 璃珠 1在基体 3中的嵌入深度为玻璃珠 1直径的 20 %〜60 %， 最好是 55 %〜60 %。 Referring to FIG. 2, another directional reflective material of the present invention includes a base body 3 and glass beads 1. The base body 3 may be ceramic or enamel, and a fusion layer 4 is formed between the base body 3 and the glass beads 1. Ceramic or enamel layer 2. The thickness of the enamel layer 2 is 20% to 60% of the diameter of the glass bead 1, preferably 55% to 60%. The depth of the glass beads 1 embedded in the matrix 3 is 20% to 60% of the diameter of the glass beads 1, preferably 55% to 60%.
制造图 2 所示的一种定向反光材料的方法如下： 首先将陶瓷压制成型， 再烧成 无釉坯体， 用低熔点的玻搪釉料喷涂无釉坯体后， 送入灶中烧结到 800°C〜90(TC后 退火。 在灶具退火段安装了撒布玻璃珠 1 的装置， 趁低温釉在 700°C〜900°C时将玻 璃珠 1均匀地喷或撒在陶瓷基体的釉质层 2上， 此时玻璃珠 1坠入釉质层 2中， 玻 璃珠 1的表面同釉质层 2熔结。 The method for manufacturing a retroreflective material shown in Figure 2 is as follows: First, press the ceramic into shape, then fire it into an unglazed green body, spray the unglazed green body with a low-melting glass enamelled material, and send it to a stove to sinter it to After annealing at 800 ° C ~ 90 ° C, a device for spraying glass beads 1 is installed in the annealing section of the cooker. While the low-temperature glaze is at 700 ° C ~ 900 ° C, the glass beads 1 are uniformly sprayed or sprinkled on the enamel layer of the ceramic substrate. 2, at this time, the glass beads 1 fall into the enamel layer 2, and the surface of the glass beads 1 is fused with the enamel layer 2.
制造图 2 所示的另一种定向反光材料的方法如下： 在搪瓷产品退火阶段， 温度 为 700Ό〜900Ό时喷或撒玻璃珠 1， 使玻璃珠 1熔结在搪瓷的釉质层 2上， 所得的 制品具有反光效果。 此方法可用于制造高速公路的护栏、 反光柱等多种交通产品和 ) 口广口口。 The method for manufacturing another directional reflective material shown in FIG. 2 is as follows: In the annealing phase of the enamel product, the glass beads 1 are sprayed or sprinkled at a temperature of 700 ° C to 900 ° C, and the glass beads 1 are fused to the enamel layer 2 of the enamel. Products have a reflective effect. This method can be used to manufacture a variety of transportation products such as highway guardrails, reflective pillars, etc., and wide mouths.
本发明中以马赛克或陶瓷为基体制成的定向反光材料片可用于制作反光标线 带。 在纸带上涂一层水溶性胶， 将上述定向反光材料片粘贴在纸带上， 片与片之间 有间隙， 间隙中撒入玻璃珠， 玻璃珠也被水溶性胶粘住， 从而得到永固常洁道路反 光标线带。
In the present invention, the directional reflective material sheet made of a mosaic or ceramics as a substrate can be used for making a cursor line tape. Apply a layer of water-soluble glue on the paper tape, and paste the above piece of directional reflective material on the paper tape. There is a gap between the sheets. Glass beads are scattered in the gap, and the glass beads are also adhered by the water-soluble glue to obtain Yonggu Changjie road anti-cursor line belt.
Claims
1、 一种定向反光材料， 包括基体和玻璃珠， 其特征是所述基体和所述玻璃珠之 间有熔结层， 用以将所述玻璃珠牢固地熔结在所述基体上。 1. A directional reflective material, comprising a substrate and glass beads, characterized in that a fusion layer is formed between the substrate and the glass beads, and is used to firmly fuse the glass beads on the substrate.
2、 根据权利要求 1所述的定向反光材料， 其中所述基体是玻璃或马赛克。 2. The retroreflective material according to claim 1, wherein the substrate is glass or mosaic.
3、 根据权利要求 1 所述的定向反光材料， 其中所述基体是陶瓷或搪瓷， 所述玻 璃珠熔结在所述陶瓷或搪瓷的釉质层上。 3. The retroreflective material according to claim 1, wherein the substrate is ceramic or enamel, and the glass beads are fused on the ceramic or enamel enamel layer.
4、 根据权利要求 3 所述的定向反光材料， 其中所述釉质层的厚度是所述玻璃珠 直径的 20%〜60%。 4. The retroreflective material according to claim 3, wherein the thickness of the enamel layer is 20% to 60% of the diameter of the glass beads.
5、 根据权利要求 1或 2或 3所述的定向反光材料， 其中所述玻璃珠在所述基体 中的嵌入深度是所述玻璃珠直径的 20%〜60%。 5. The retroreflective material according to claim 1 or 2 or 3, wherein an embedment depth of the glass beads in the matrix is 20% to 60% of a diameter of the glass beads.
6、 一种制造定向反光材料的方法， 其特征是包括以下步骤： 6. A method for manufacturing a directional reflective material, which comprises the following steps:
a、 使基体温度处于 700T：〜 900Ό ; a, so that the substrate temperature is at 700T: ~ 900Ό;
b、 将玻璃珠散布于所述基体表面， 使所述玻璃珠表面与所述基体熔结； c、 立即将散布有所述玻璃珠的所述基体平稳降温。 b. spreading the glass beads on the surface of the substrate so that the surface of the glass beads and the substrate are sintered; c. immediately cooling the substrate in which the glass beads are dispersed.
7、 根据权利要求 6所述的制造定向反光材料的方法， 其中步骤 b所述的散布是 采用滚压方法散布。 7. The method for manufacturing a retroreflective material according to claim 6, wherein the dispersing in step b is dispersing using a rolling method.
8、 根据权利要求 7 所述的制造定向反光材料的方法， 其中所述滚压方法包括以 下步骤： 8. The method for manufacturing a retroreflective material according to claim 7, wherein the rolling method includes the following steps:
a、 使未成型的玻璃或马赛克流体经过对置的滚筒压制成一定厚度的玻璃或马赛 克； a. The unshaped glass or mosaic fluid is pressed through opposite rollers to form a certain thickness of glass or Marseille;
b、 将所述玻璃或马赛克再经过设置有若干横槽的对切滚筒滚压切割成几何形状 的玻璃或马赛克基体， 同时通过玻璃珠输送通道将所述玻璃珠输送到所述横 槽中， 滚压时所述玻璃珠的一部分在滚压过程中藏入横槽中， 另一部分压入 熔融的玻璃或马赛克基体中， 使所述玻璃珠表面与所述玻璃或马赛克基体熔 结为一体。 b. rolling said glass or mosaic into a geometric glass or mosaic substrate through a counter-cut roller provided with a plurality of horizontal grooves, and conveying said glass beads into said horizontal grooves through a glass bead conveying channel, During rolling, a part of the glass beads is hidden in the horizontal groove during the rolling process, and another part is pressed into the molten glass or mosaic substrate, so that the surface of the glass beads and the glass or mosaic substrate are fused and integrated.
9、 根据权利要求 6、 7或 8所述的制造定向反光材料的方法， 其中所述基体是玻 璃或马赛克。 9. The method for manufacturing a retroreflective material according to claim 6, 7 or 8, wherein the substrate is glass or mosaic.
10、 根据权利要求 6所述的制造定向反光材料的方法， 其中步骤 b所述的散布是 采用喷或撒的方法散布。 10. The method for manufacturing a retroreflective material according to claim 6, wherein the spreading in step b is by spraying or scattering.
11、 根据权利要求 6或 10所述的制造定向反光材料的方法， 其中所述基体是陶瓷 或搪瓷。 11. The method for manufacturing a retroreflective material according to claim 6 or 10, wherein the substrate is ceramic or enamel.
3 3
替换页（细则第 26条）
Replacement page (Article 26)
Priority Applications (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| PCT/CN1999/000066 WO2000068509A1 (en) | 1999-05-11 | 1999-05-11 | A directional reflector material and the producing method of the same |
| AU38089/99A AU3808999A (en) | 1999-05-11 | 1999-05-11 | A directional reflector material and the producing method of the same |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| PCT/CN1999/000066 WO2000068509A1 (en) | 1999-05-11 | 1999-05-11 | A directional reflector material and the producing method of the same |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| WO2000068509A1 true WO2000068509A1 (en) | 2000-11-16 |
Family
ID=4575122
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| PCT/CN1999/000066 WO2000068509A1 (en) | 1999-05-11 | 1999-05-11 | A directional reflector material and the producing method of the same |
Country Status (2)
| Country | Link |
|---|---|
| AU (1) | AU3808999A (en) |
| WO (1) | WO2000068509A1 (en) |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2012162925A1 (en) * | 2011-06-03 | 2012-12-06 | Qian Hongcheng | Directional reflective ceramic plate |
| CN103966920A (en) * | 2014-04-11 | 2014-08-06 | 王兆进 | Processing method of wallpaper with acrylic beads |
| CN103964676A (en) * | 2014-05-06 | 2014-08-06 | 湖州远光路标涂料有限公司 | All-weather high-refraction reflective micro-crystal ceramic bead |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4462547A (en) * | 1977-10-21 | 1984-07-31 | Baltimore Paint & Chemical Co., A Division Of Dutch Boy, Inc. | Method of applying marking lines to a road surface |
| US4815818A (en) * | 1984-12-18 | 1989-03-28 | Eagle Industries, Inc. | Three-dimensional flexible reflectors |
| US5039557A (en) * | 1989-10-26 | 1991-08-13 | White Terrence H | Method for embedding reflective beads in thermoplastic pavement marking lines |
-
1999
- 1999-05-11 AU AU38089/99A patent/AU3808999A/en not_active Abandoned
- 1999-05-11 WO PCT/CN1999/000066 patent/WO2000068509A1/en active Application Filing
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4462547A (en) * | 1977-10-21 | 1984-07-31 | Baltimore Paint & Chemical Co., A Division Of Dutch Boy, Inc. | Method of applying marking lines to a road surface |
| US4815818A (en) * | 1984-12-18 | 1989-03-28 | Eagle Industries, Inc. | Three-dimensional flexible reflectors |
| US5039557A (en) * | 1989-10-26 | 1991-08-13 | White Terrence H | Method for embedding reflective beads in thermoplastic pavement marking lines |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2012162925A1 (en) * | 2011-06-03 | 2012-12-06 | Qian Hongcheng | Directional reflective ceramic plate |
| CN103966920A (en) * | 2014-04-11 | 2014-08-06 | 王兆进 | Processing method of wallpaper with acrylic beads |
| CN103964676A (en) * | 2014-05-06 | 2014-08-06 | 湖州远光路标涂料有限公司 | All-weather high-refraction reflective micro-crystal ceramic bead |
Also Published As
| Publication number | Publication date |
|---|---|
| AU3808999A (en) | 2000-11-21 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| JP2944628B1 (en) | Non-flammable artificial marble and its manufacturing method | |
| US20130089704A1 (en) | Temporary Outdoor Graphic Film | |
| US4080228A (en) | Aggregate product and method of applying to surfaces | |
| WO2000068509A1 (en) | A directional reflector material and the producing method of the same | |
| CN206829532U (en) | A kind of reflective ceramic tile in diffusing reflection tunnel | |
| CN101691310B (en) | Technology for producing glass ceramic composite boards | |
| CN1359436A (en) | Directional reflector material and the producing method of the same | |
| CN101691311A (en) | Technology for producing glass ceramic composite boards | |
| KR101456012B1 (en) | A manufacturing method for Mosaic wall painting | |
| JPH01100084A (en) | Production of spray-coated tile | |
| CN2908663Y (en) | Anti-slip glass floorings | |
| AU2013101431A4 (en) | A Composite Tile and Method of its Manufacture | |
| CN208899799U (en) | A kind of enamelled pressed steel | |
| KR101410298B1 (en) | Manufacturing method for decoration pannel and the decoration pannel thereof | |
| CN202577877U (en) | Floor tiles and floor formed by paving same | |
| JPH09291656A (en) | Torch-waterproof method | |
| CN1203989A (en) | Ceramic bead/grain glass bead reflecting marking strip and its making method | |
| EP0623224A1 (en) | Glass beads embedded into high density polyethylene substrate for use as retroreflective articles, namely fencing | |
| JP2905085B2 (en) | Surface decorative building materials | |
| JP2004075509A (en) | Ornamental glass and method of manufacturing the same | |
| JP2010018458A (en) | Plate glass | |
| US10611134B2 (en) | Groutless patterns for pavement surfaces using thermoplastic preforms | |
| JP2005206387A (en) | Glass laminate and its production method | |
| TW202344737A (en) | Road marking made of hot melt material achieve efficacy and purpose of environmental protection, safety, simple construction, and practical benefit | |
| CN211775345U (en) | Novel reflection of light ceramic tile |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| WWE | Wipo information: entry into national phase |
Ref document number: 99816532.8 Country of ref document: CN |
|
| AK | Designated states |
Kind code of ref document: A1 Designated state(s): AE AL AM AT AU AZ BA BB BG BR BY CA CH CN CU CZ DE DK EE ES FI GB GD GE GH GM HR HU ID IL IN IS JP KE KG KP KR KZ LC LK LR LS LT LU LV MD MG MK MN MW MX NO NZ PL PT RO RU SD SE SG SI SK SL TJ TM TR TT UA UG US UZ VN YU ZA ZW |
|
| AL | Designated countries for regional patents |
Kind code of ref document: A1 Designated state(s): GH GM KE LS MW SD SL SZ UG ZW AM AZ BY KG KZ MD RU TJ TM AT BE CH CY DE DK ES FI FR GB GR IE IT LU MC NL PT SE BF BJ CF CG CI CM GA GN GW ML MR NE SN TD TG |
|
| DFPE | Request for preliminary examination filed prior to expiration of 19th month from priority date (pct application filed before 20040101) | ||
| 121 | Ep: the epo has been informed by wipo that ep was designated in this application | ||
| NENP | Non-entry into the national phase |
Ref country code: CA |
|
| REG | Reference to national code |
Ref country code: DE Ref legal event code: 8642 |
|
| 122 | Ep: pct application non-entry in european phase |