WO2000054001A1 - A method and apparatus for fly rock control in small charge blasting - Google Patents
A method and apparatus for fly rock control in small charge blasting Download PDFInfo
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- WO2000054001A1 WO2000054001A1 PCT/IB2000/000308 IB0000308W WO0054001A1 WO 2000054001 A1 WO2000054001 A1 WO 2000054001A1 IB 0000308 W IB0000308 W IB 0000308W WO 0054001 A1 WO0054001 A1 WO 0054001A1
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- flyrock
- pressure wave
- hole
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Classifications
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- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F42—AMMUNITION; BLASTING
- F42D—BLASTING
- F42D5/00—Safety arrangements
- F42D5/04—Rendering explosive charges harmless, e.g. destroying ammunition; Rendering detonation of explosive charges harmless
- F42D5/055—Silencing means for blasting operations
-
- E—FIXED CONSTRUCTIONS
- E21—EARTH OR ROCK DRILLING; MINING
- E21C—MINING OR QUARRYING
- E21C37/00—Other methods or devices for dislodging with or without loading
- E21C37/16—Other methods or devices for dislodging with or without loading by fire-setting or by similar methods based on a heat effect
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F42—AMMUNITION; BLASTING
- F42D—BLASTING
- F42D1/00—Blasting methods or apparatus, e.g. loading or tamping
- F42D1/08—Tamping methods; Methods for loading boreholes with explosives; Apparatus therefor
- F42D1/18—Plugs for boreholes
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F42—AMMUNITION; BLASTING
- F42D—BLASTING
- F42D3/00—Particular applications of blasting techniques
- F42D3/04—Particular applications of blasting techniques for rock blasting
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F42—AMMUNITION; BLASTING
- F42D—BLASTING
- F42D5/00—Safety arrangements
- F42D5/04—Rendering explosive charges harmless, e.g. destroying ammunition; Rendering detonation of explosive charges harmless
- F42D5/045—Detonation-wave absorbing or damping means
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F42—AMMUNITION; BLASTING
- F42D—BLASTING
- F42D5/00—Safety arrangements
- F42D5/04—Rendering explosive charges harmless, e.g. destroying ammunition; Rendering detonation of explosive charges harmless
- F42D5/045—Detonation-wave absorbing or damping means
- F42D5/05—Blasting mats
Definitions
- the present invention is directed generally to methods and devices for small charge blasting of rock and other materials and specifically to methods and devices for controlling pressure wave emissions and/or flyrock generated by the small-charge blasting process.
- Airblast refers to pressure waves in air emanating from a rapid release of energy (e.g., a blast). Airblast noise is the audible part of the airblast energy spectrum, having frequencies in the range from 20 to 20,000 Hz. Airblast concussion is the inaudible part of the airblast energy spectrum, having a frequency content below 20 Hz.
- Noise refers to pressure waves in air generated by equipment other than the small charge blasting equipment, such as the drill during formation of one or more holes for small charge blasting and/or the impact breaker during removal of fractured material.
- Flyrock refers to rock particles thrown into the air by the rapid release of energy (e.g., blast). Flyrock may be in the form of a shower of small pieces at relatively high velocities (20 to 50 m/s typical), which typically originate from the collar region of the drill hole. Flyrock may also be in the form of larger pieces of rock at relatively low velocity (1 to 10 m/s typical), which typically originate in the mass of rock excavated from the crater formed by the blasting event.
- Objectives of the present invention include providing a drilling and blasting methodology for excavating rock, particularly hard rock, in airblast, noise, and/or flyrock restricted areas, such as urban settings, and providing a methodology and apparatus(es) for use with small-charge blasting techniques for controlling and/or suppressing airblast in airblast restricted areas, controlling and/or suppressing equipment noise in noise restricted areas, and/or for controlling and/or suppressing flyrock in flyrock restricted areas.
- a method for selecting one or more flyrock control devices for use with small-charge blasting of a material that is near a flyrock restricted area broadly includes the steps of:
- step (d) if the uncontrolled flyrock distance of step (b) is more than the flyrock distance requirement of step (a), selecting one or more flyrock control devices from a menu of flyrock control devices to produce a desired degree of flyrock control.
- "Uncontrolled flyrock distance” refers to the probable flight distance of flyrock from the hole. The method provides an operator with versatility in meeting the unique requirements of each job and a relatively low cost and simple excavation technique that complies with the demanding requirements in flyrock restricted areas.
- controlled fracturing is performed by drilling a hole in the material to be broken, inserting a sealing member, which can be a stemming bar, a gas injector barrel, or other pressurizing device, into the drill hole, and releasing a pressurized working fluid rapidly into a portion of the drill hole, usually the bottom portion.
- a sealing member which can be a stemming bar, a gas injector barrel, or other pressurizing device, into the drill hole, and releasing a pressurized working fluid rapidly into a portion of the drill hole, usually the bottom portion.
- Seal refers to partial or total blockage of the hole to inhibit the escape of the fluid from the drill hole.
- “Sealing member” refers to any downhole device capable of sealing a pressurized working fluid in the bottom of a hole, including without limitation loosely consolidated or unconsolidated particles such as sand, gravel, rock fragments and the like, and a solid material such as grout, a stemming bar, a gas injector barrel, and the like.
- the pressurized fluid is typically generated by combustion of a propellant or explosive source, by an electrical discharge into a conductive fluid, or by compression of the working fluid.
- the fractured material is thereafter removed from the face by an impact breaker and mucking equipment. Because of the relatively low weight of the energetic substance used to generate the working fluid and the relatively low pressure wave and flyrock emissions, equipment and personnel commonly remain in the area of the hole during the small charge blast.
- the menu of flyrock control devices preferably includes at least: (i) a collar flyrock control device located at or near the opening of the hole and engaged with a sealing member positioned in the hole, the collar flyrock control device having a surface for suppressing or deflecting flyrock,
- the determining step (a) can include a number of substeps to determine the flyrock distance requirement.
- the substeps can include: determining at least one of (a) a job flyrock distance requirement (i.e., the "job flyrock distance requirement” refers to flyrock distance restrictions that are unique to the specific job, such as imposed by regulatory authorities or by the surroundings of the job, e.g., nearby structures or thoroughfares), (b) a personnel flyrock distance requirement (i.e., the "personnel flyrock distance requirement” refers to flyrock distance restrictions that are generally applied by the operator to protect personnel and are independent of the specific job), and (c) a machine flyrock distance requirement (i.e., the "machine flyrock distance requirement” refers to flyrock distance restrictions that are generally applied by the operator to protect equipment and are independent of the specific job) and comparing at least two of the job flyrock distance requirement, the personnel flyrock distance requirement, and the machine flyrock distance requirement with the more restrictive being the flyrock distance requirement.
- the uncontrolled flyrock distance is typically a function of (a) the degree of preexisting fracturing of the rock and the type of rock and (b) the energy released by the blast.
- the function is often construed from the measured results of many shots of the small charge blast being used.
- the energy released may be replaced by a mass of the explosive or propellant used.
- the method can include additional steps. Specifically, the steps include: determining a pressure wave level requirement at a selected distance from the material to be broken; determining an unsuppressed pressure wave level at the selected distance produced by the small-charge blast in the absence of a pressure wave suppression device; if the unsuppressed pressure wave level is more than the pressure wave level requirement, selecting one or more pressure wave suppression devices from a menu of pressure wave suppression devices to produce a desired degree of pressure wave suppression.
- the menu of pressure wave suppression devices preferably includes at least:
- a downhole pressure wave suppression device located in a hole in the material for directing flow of the working fluid through one or more nonlinear pathways and/or for contacting at least a portion of the working fluid with a thermal energy absorbing material having a plurality of heat transfer surfaces
- a collar pressure wave suppression device (which may be combined with the collar flyrock control device) located at or near the opening of the drill hole for directing flow of the working fluid through one or more nonlinear pathways and/or for contacting at least a portion of the working fluid with a thermal energy absorbing material having a plurality of heat transfer surfaces,
- the mat noted above having features for directing flow of the working fluid through one or more nonlinear pathways in the mat and/or for absorbing thermal energy from the working fluid by contacting the working fluid with a plurality of heat transfer surfaces,
- the enclosure noted above having features for containing the equipment noise and/or working fluid and impeding the discharge of the noise and/or working fluid into the ambient atmosphere,
- the barrier noted above including a material for absorbing and/or deflecting at least a portion of the airblast energy
- a plurality of atomized liquid droplets (preferably having a droplet size ranging from about 0.01 to about 0.1 mm) suspended in the air adjacent to the surface of the material during the blast to absorb thermal energy from the working fluid.
- the first determining step can include a number of substeps to determine the pressure wave level requirement.
- the substeps can include: determining an operator pressure wave requirement (i.e., the "operator pressure wave requirement” refers to pressure wave restrictions that are generally applied by the operator and are independent of the specific job, such as mandated by the operator to protect personnel and equipment) at the selected distance from the material to be broken; determining a job pressure wave requirement (i.e., the "job pressure wave requirement” refers to pressure wave restrictions that are unique to the specific job, such as imposed by regulatory authorities or by the surroundings of the job, e.g., nearby structures or thoroughfares) at the selected distance from the material to be broken; and comparing the operator pressure wave requirement with the job pressure wave requirement with the more restrictive (e.g., lesser) of the operator pressure wave requirement and the job pressure wave requirement being the pressure wave level requirement.
- Thejob pressure wave requirement is the maximum allowable pressure wave level for the pressure wave restricted area.
- the job pressure wave requirement can be the maximum allowable noise level
- the operator pressure wave requirement(s) in small charge blasting typically includes a machine pressure wave requirement(s) and/or a personnel pressure wave requirement(s).
- the equipment and personnel commonly remain at or near the hole during the blast. Because of the small charge used in the blast, complete excavation of the blasting site during blasting, as normally is the case in conventional large charge blasting, is often unnecessary and even undesirable for reasons of productivity.
- the small charge blasting operator commonly formulates requirements unique to small charge blasting and independent of the specific job to protect equipment from pressure wave emissions of the blast ("the machine pressure wave requirement”) and from flyrock ("the machine flyrock distance requirement”) and personnel from pressure wave emissions of the blast (“the personnel pressure wave requirement”) and from flyrock (“the personnel flyrock distance requirement”).
- the selecting step can further include the following substeps: comparing the pertinent pressure wave level requirement(s) with the corresponding unsuppressed pressure wave level(s) to determine a desired pressure wave level reduction; comparing the desired pressure wave level reduction(s) with a pressure wave level reduction associated with a plurality of the pressure wave suppression devices; and based on the comparing step, selecting a sufficient number of pressure wave suppression devices to realize the desired pressure wave level reduction.
- each of the pressure wave suppression devices in the menu will realize a specific level of pressure wave suppression, usually obtained by field measurements.
- the appropriate pressure wave suppression devices for a given application are commonly selected based not only on the desired pressure wave level reduction but also on the requirements of the job, cost considerations, and the like.
- a number of the pressure wave suppression devices selected in the process remain in place during the repeated drilling and small charge blasting sequences. This is so because only one or at most a few holes are shot at any one time because the small charge blasting machine can only seal one hole at a time.
- conventional large charge blasting a large number of holes are simultaneously shot and the pressure wave suppression devices are thereafter removed to remove fractured material and drill new holes and repositioned during the next blasting cycle.
- a flyrock control device engages a sealing member positioned in the hole.
- the device has a surface adjacent to a free surface of the material for deflecting or suppressing flyrock in the vicinity of the hole opening.
- the surface is preferably substantially flat or convex to inhibit ricocheting of the flyrock away from the material being broken.
- the surface can be in contact with the free surface of the material.
- an airblast and flyrock suppression device is provided that is an enclosure substantially surrounding and enclosing the opening of the hole.
- the enclosure has an interior surface that substantially absorbs the kinetic energy of the flyrock.
- the enclosure can be a suspended canopy or a rigid boxlike structure.
- the enclosure can include a plurality of leakage vents for discharging the gas released by the energetic material into the ambient atmosphere at a controlled rate.
- the enclosure encloses a sufficient volume such that the gas pressure within the enclosure is controlled to an average overpressure of preferably no more than about 15 KPa during formation and propagation of a fracture from the hole.
- the volume of the enclosure preferably is at least about 4 cubic meters and more preferably ranges from about 4 to about 100 cubic meters.
- Figure 1 is a decision tree that can used by a small-charge blasting estimator and/or operator to select the airblast suppression, noise abatement, and flyrock control devices appropriate to a particular excavation job.
- Figure 2 is an exemplary plot of flyrock trajectories in both the vertical and horizontal directions.
- Figure 3 is a cutaway side view of a sealing member which includes a series of high-pressure baffles for disrupting and de-energizing the flow of high pressure working fluid in the drill hole.
- Figure 4 is a cutaway cross-sectional view of a device for intercepting flyrock that originates from the collar region of a drill hole.
- Figures 5 A and 5B respectively are a cutaway side view taken along line 5 A-5A of Figure 5B and a cutaway plan view taken along line 5B-5B of Figure 5 A of a collar shroud installed around the collar of a drill hole and secured by the stemming or gas- injecting means.
- Figure 5 C is a cutaway side view of an alternative embodiment of a collar shroud decoupled from the stemming or gas injecting device.
- Figure 6 is a cutaway side view of an alternative embodiment of a collar shroud for use with a drill.
- Figures 7A and 7B are respectively a cutaway side view taken along line 7A-7A of Figure 7B and plan view of a ground shroud installed such that several shots can be fired before the shroud is moved.
- Figures 8 A and 8B are respectively a cutaway side view and exploded view of a section through a wall of an enclosure that is attached to the proximal end of a boom of a small-charge blasting machine.
- Figure 8C is an isometric view of another configuration of an enclosure.
- Figure 8D is a cutaway side view of an enclosure that is affixed to the supporting cable such as might be used on an excavation apparatus for hole drilling, small charge blasting, and impact breaking in shaft excavation.
- Figure 9 is a cutaway side view of a moveable barrier for pressure wave suppression and flyrock control.
- Figure 10 is a plan view of a layout of the relative positions of pressure wave- flyrock barriers might be deployed to protect an area from the small-charge blasting work site.
- Figure 11 is a side view of a small charge excavation machine in firing position with an atomized spray pattern for pressure wave suppression.
- Figure 12 is a cross-sectional side view of a gas generator according to one embodiment.
- Figure 13 is a partially cutaway side view of the gas generator of Fig. 12.
- Figure 14 is a partially cutaway side view of a gas generator according to another embodiment.
- the first step 20 in selecting appropriate pressure wave and flyrock suppression device(s) is to characterize the unsuppressed pressure wave and flyrock emissions 24 of the small charge excavation process.
- the drilling noise characteristics of a particular drilling device, the airblast and flyrock characteristics of a particular small-charge blasting method, and the noise characteristics of a particular impact breaker are generally determined by field measurements.
- the characteristics of both equipment noise and airblast can be characterized by a peak amplitude versus distance curve and an energy amplitude versus frequency curve. The former shows the decay of peak amplitude with distance and the latter shows at which frequencies the energy of the pressure waves are concentrated.
- the unsuppressed pressure wave amplitude for the small charge blasting process at a given distance from the hole to be drilled/blasted is often a function of the energy of the small charge blast.
- the dependence of airblast on distance may be expressed in terms of propellant or explosive weight used (since their energy densities are usually all in the range of about 3.5 to about 4.5 MJ/kg).
- the functional relationship is usually plotted on a log-log plot showing either pressure or decibels as a function of scaled distance where scaled distance is the actual distance divided by the cube root of the charge energy or weight.
- flyrock can be characterized statistically by a probability distribution function that relates charge weight and rock type with the distribution of flyrock at varying distances from the hole or by a plot such as that in Figure 2 generated for a specific charge weight and rock type.
- job and operator pressure wave requirements e.g., job and operator airblast requirements 30 and/or job and operator equipment noise requirements 32, if different
- job and operator flyrock requirements 34 and any other pertinent pressure wave and flyrock requirements are determined.
- Each excavation job and particularly urban excavation work has a number of unique job pressure wave restrictions on air-blast and noise. These may be simple restrictions such as a noise level not to be exceeded at a certain distance from the job site.
- the restrictions may be more elaborate and contain not-to-exceed levels for pulsed, intermittent and continuous air/blast noise levels at several distances and under certain atmospheric conditions.
- the pressure wave restrictions are expressed as the peak pressure wave amplitude at one or more distances from the work area or shot point and often will specify the range of frequencies where the peak amplitude requirements apply.
- the operator pressure wave requirement(s) commonly include the personnel and machine pressure wave requirements.
- the operator might have a near-field pressure wave limit imposed as a safety measure to comply with the operating company' s internal requirements. In complying with this, the operator may have to add additional pressure wave suppression devices.
- the operator selects 36 the most stringent requirement(s) as the requirement(s) to be complied with.
- the most stringent pressure wave requirement(s) is the requirement(s) that mandates the lowest pressure wave emissions
- the most stringent flyrock distance requirement(s) is the requirement(s) that mandates the lowest flyrock trajectory distance from the jobsite.
- the pressure wave requirements for airblast will be different from the pressure wave requirements for equipment noise. In such cases, the most stringent pressure wave requirement(s) is determined for each type of pressure wave emissions.
- the operator determines 38 the difference between the unsuppressed pressure wave emissions and the most stringent pressure wave requirement(s). Because airblast requirements are typically more demanding than noise and flyrock requirements, the process first focuses on selecting appropriate pressure wave devices for suppressing airblast energy followed by determinations whether additional devices are required for attenuating equipment noise and/or flyrock. As will be appreciated, in some applications equipment noise or flyrock may be the more demanding requirement and the process would be reconfigured to consider that requirement first followed by verification that the devices chosen also comply with the less restrictive requirements.
- the difference of step 38 may be adjusted 40 upwards (or sometimes downwards) based on safety factors, atmospheric conditions, and other factors.
- the difference (or the unsuppressed pressure wave emissions) may be increased by a suitable safety factor to ensure compliance with pertinent regulations.
- the difference may be adjusted based on the forecasted atmospheric conditions received from an outside service. Such special conditions might include strong atmospheric temperature inversions, heavy low cloud cover or heavy fog. These type of atmospheric conditions can reflect noise and airblast energy initially radiated upwards back down toward the ground and may even focus noise and airblast energy in a specific location quite far from the work site.
- the estimator/operator may have access to services that provide such information or he may have to use his judgement.
- the operator determines 42 whether the difference is positive or negative. If the difference is negative or zero, the small charge process is airblast compliant 1008 without the need for airblast pressure wave attenuation devices. If the difference is positive (i.e., the unsuppressed pressure wave levels exceed the pressure wave level requirement), the operator in box 44 selects a sufficient number of cost effective pressure wave suppression devices from a menu of such devices to attenuate the difference. If possible, the operator selects the combination of devices that minimizes capital and operating costs, controls equipment noise to meet the job pressure wave specification, and controls flyrock to meet the job flyrock specification.
- the adjusted differences may be 40 to 50 dB at a first distance from the jobsite and 60 to 70 dB at a second distance from the jobsite with the first distance being less than the second distance.
- the menu must characterize the devices at least in terms of the amount of pressure wave attenuation they provide at specified distances from the drill hole/jobsite. This is usually expressed in terms of dB of attenuation at the specified distance. Most well designed passive devices will provide in the range of about 10 to 20 dB of pressure wave attenuation at a specified distance relatively close to the hole/jobsite. Some devices will of course provide an amount of attenuation that is indirectly proportional to the distance from the jobsite.
- the pressure wave attenuations determined for each pressure wave suppression device may contain a safety factor (i.e., be stated conservatively) to ensure that the devices will suppress the stated amounts of pressure wave energy.
- An example of such a menu might be:
- pressure wave suppression devices can suppress both equipment noise and airblast, some devices will provide differing degrees of attenuation for airblast and equipment noise. For example, some devices will have higher attenuation of airblast and have little or no attenuation of equipment noise.
- the downhole baffle device and ground mats attenuate at most only a small fraction of the drilling noise while a collar shroud, flexible rig canopy, rigid rig enclosure, wall sound absorbing barriers, and stand alone sound barriers are effective in attenuating equipment noise such as drilling noise.
- Other devices that are able to suppress the type of pressure waves but not airblast energy may not be listed in the menu. For example, devices not listed in the menu above include, additional muffling for engines; a noise suppression collar for the rock drill; and a separate noise abatement enclosure for an impact hammer.
- flyrock verification step 50 requires the operator to compare the more stringent of the personnel, machine, and job flyrock distance requirements with the unsuppressed flyrock distance(s) to determine if flyrock protection is necessary. If the pertinent flyrock distance requirement(s) is less than the unsuppressed flyrock distance(s), flyrock control equipment is required. In that event, the devices selected above are analyzed to determine whether they are able to suppress flyrock and comply with the requirements, If not, yet another menu of flyrock control devices is considered to select additional devices to suppress the flyrock.
- ground mats, collar shrouds and barriers will be sufficient to meet flyrock control requirements.
- additional devices such as ground mats or a collar shroud may be required to achieve adequate flyrock control.
- the operator may also require some close- in flyrock control to protect the excavating machine or some other piece of equipment used at or near the work face. After applying the above-noted steps, the operator should be in full compliance 52 with job and operator pressure wave and flyrock requirements and all pressure wave requirements.
- process steps may vary somewhat depending on the job type (surface excavation, basement excavation, partially enclosed excavation, shaft, tunnel, drift or cavern).
- job type surface excavation, basement excavation, partially enclosed excavation, shaft, tunnel, drift or cavern.
- process steps were described generally with reference to pressure wave and flyrock restrictions in an urban environment.
- Down hole pressure wave suppression devices are aimed at intercepting and controlling the airblast adjacent to the source of the small charge blast event in the drill hole and around the barrel or sealing member.
- rigid impact resistant annular housing fits around and is connected to the sealing member and functions like a silencer on a gun.
- the housing is substantially open at the both the downhole and uphole ends, and has a series of internal baffle plates and/or dead-end chambers and/or attenuation material that cause the pressurized working fluid that leaks up the drill hole to negotiate a series of separate paths of unequal length (nonlinear pathways).
- the coherence of the airblast that exits the silencer is eroded such that the peak pressure of the airblast is diminished and its pulse width is lengthened, resulting in a lower amplitude, lower frequency air-blast than would be otherwise generated.
- the baffles and/or dead-end chambers and attenuation material will also increase the surface area over which the energetic working fluid must flow thereby enhancing heat transfer from the working fluid to the baffle plates. This acts to de-energize the pressurized working fluid that leaks up the drill hole which, in turn, acts to reduce the peak amplitude and pulse width of the resultant airblast wave.
- FIG. 3 An example of such a down hole airblast silencer device is shown in Figure 3.
- the silencer 2001 is firmly connected to the sealing member 2002 which is inserted into a drill hole 2003.
- the small-charge blasting agent or working fluid
- the sealing member 2002 seals the bottom portion 2004 by a sealing surface or other sealing device 2005 near the hole bottom.
- the silencer 2001 is located uphole of the sealing surface 2005 and substantially fills the cross-sectional area of the hole.
- the down hole end 2006 of the silencer 2001 is open or perforated to allow the flow of high-pressure gases to enter.
- the inside of the silencer includes a plurality of baffles 2007, a plurality of dead-end chambers 2008 and/or attenuation material 2009.
- the uphole end 2010 of the silencer 2001 is also open or perforated to allow the high-pressure gases to escape in a less coherent and less energetic state than they entered.
- the gas pressures that the silencer device is exposed to are typically in the range of about 5,000 to about 50,000 psi.
- Collar Pressure Wave and Flyrock Suppression Devices Collar Pressure wave and flyrock suppression devices intercept and control the energetic working fluid that escapes from the collar (i.e., opening area) of the drill hole and/or stop small pieces of relatively high velocity flyrock that originate from the collar of the drill hole.
- the collar pressure wave suppression device can have the same features as the downhole silencer device except that the collar devices are commonly much larger, have a larger internal volume and are positioned outside the drill hole over the collar of the drill hole instead of inside the hole.
- FIG. 5 A An example of a collar shroud device for airblast suppression is shown in Figure 5 A.
- the collar shroud 5001 is typically rigidly connected to the proximal end of the sealing member 5002 such that when the sealing member 5002 is inserted in a drill hole 5003, the body of the collar shroud 5001 and a flexible skirt 5005 contact the region around the collar of the drill hole 5006 to form a rough seal.
- the down hole end 5007 of the collar shroud 5001 is open or perforated to allow the flow of high-pressure gases to enter from the hole.
- the inside of the collar shroud includes a plurality of baffles 5008, a plurality of dead-end chambers 5009 and/or the attenuation material 5010 which together form non-linear pathways of different lengths and a large surface area for heat transfer.
- the uphole end 5011 of the collar shroud 5001 is also open or perforated to allow the high-pressure gases to escape in a less coherent and less energetic state than they entered.
- the heavy flexible outer skirt 5005 further contains the escaping gases. This outer flexible skirt 5005 may be made from flexible air conditioning duct material, heavy canvas or industrial conveyor belt, and the like.
- This outer flexible skirt 5005 may or may not be included as part of the collar shroud 5001 and may be attached to the uphole end 5011 of the collar shroud 5001 and the downhole end 5007 by any number of means (such as by a heavy chain as shown)or directly to the sealing member.
- the collar shroud 5001 is shown in plan view in Figure 5B which shows the hole for the sealing member 5013 , perforations 5014 on the uphole end 5011 and the flexible outer skirt 5005.
- the collar shroud 5001 shown in plan view 5015 may be either round, rectangular, or any other shape.
- FIG. 5C An alternate embodiment of a collar shroud device is shown in Figure 5C.
- This embodiment shows a collar shroud 5021 that is decoupled from the sealing member 5023 by any suitable device 5022, such as a spring. It also shows internal baffles 5024 that are shock-isolated from the main body 5025 by rubber or shock isolation elements 5026. The nonlinear escape path of the working fluid is shown by arrows.
- the rigid collar shroud must contain substantially undiluted but expanded energetic working fluid, it must be of robust construction.
- the gas pressures are in the range of about 1,000 to about 5,000 psi.
- the internal volume of the collar shroud is preferably in the range of about 0.03 m 3 to 2 m 3 , more preferably in the range of about
- Figure 6 depicts a collar shroud for suppressing pressure waves generated during the drilling of the hole.
- the drill has a drill steel that is decoupled from the collar shroud 102 so that the drill steel may rotate freely from the shroud 102.
- This shroud 102 is designed to substantially attenuate the noise emanating from the drill hole 104 as a result of the percussive hammering of the rock by the drill bit 105 at the downhole end of the drill steal.
- the shroud like the other collar devices discussed above, surrounds and encloses the hole from the exterior environment.
- the proximal end 106 of the device is rigid and made from a suitable high strength material such as steel plate.
- the distal end 107 of the device is a flexible shroud such that when the drill slide 103 is positioned next to the rock face 108 for drilling, the flexible end 107 can conform to the rock face 108 to seal the pressure wave emissions in the shrouded area 109 and thereby impede the release of or attenuate the pressure waves in the exterior environment.
- the flexible end 107 may be made from a deformable material such as a heavy industrial plastic, rubber, canvas and the like. The flexible end 107 will also allow drilling fluids (water and air) and rock dust to escape through the rough seal formed with the rock face 108.
- the outside of the noise suppression device may be further covered with one or more additional layers 110 of acoustic material such as heavy industrial plastic, rubber, canvas or other commercially available acoustic materials.
- acoustic material such as heavy industrial plastic, rubber, canvas or other commercially available acoustic materials.
- Noise from the drill motor piston hammering on the proximal end of the drill steel can be suppressed by wrapping the drill motor and proximal end of the drill steel with a noise absorbing material such as a heavy rubber sheath.
- a collar shroud can also be used only for intercepting and controlling small, higher velocity flyrock originating in the drill hole or at the collar of the drill hole used for the small charge blast.
- the collar of the drill hole in particular, is often the source of smaller, higher velocity flyrock.
- the collar shroud is used only for flyrock control, its internal construction may be simplified by removing the internal baffles, dead-end chambers and internal attenuation material. The flyrock will be substantially stopped by the bottom plate and flexible outer skirt.
- FIG. 4 shows a cross-sectional view of a collar flyrock suppression shroud 201 positioned around and enclosing the collar 202 of the hole 203 for intercepting flyrock that originates from the collar region of the drill hole during small-charge blasting.
- a sealing member 204 is shown inserted into a drill hole 203 in firing position. Since some or all of the gases generated in the drill hole when the gas-generating device 204 is fired can escape up the drill hole 203, there is a strong potential for these gases to accelerate at high velocities broken or partially broken rock 205 in the collar region 202.
- the collar shroud 201 is solidly attached at its proximal end 206 to the sealing member 204 such that when the sealing member 204 is positioned in the drill hole for firing, the shroud 201 substantially blocks the line-of-flight of the flyrock that would originate in the collar region 202 of the drill hole 203.
- the flyrock shroud 201 may be made from a heavy impact resistant material such as steel, impact resistant plastics or composite materials, and the like.
- the shape of the flyrock shroud 201 may be convex as shown or in the shape of a cylindrical housing with its open end facing towards the entrance of the drill hole 203.
- a shroud of mesh or chain links 207 or another deformable impact resistant material may be attached to the distal end 208 of the flyrock shroud 201 so as to further intercept flyrock that is accelerated laterally.
- Ground pressure wave and flyrock suppression devices intercept and control the air-blast that escapes from fissures or fractures existing or created around the working face centered on the drill hole used for the small charge blast.
- a series of perforated mats are laid on top of each other over an area around the hole collar.
- the perforations in the adjacent, stacked mats are of differing sizes and/or are misaligned to form a labyrinth of gas passageways.
- the mats are covered by a mat that is substantially impermeable to the flow of gas to force the working fluid through a labyrinth formed by the overlapping and interlinked meshes and/or perforations.
- the labyrinth forces the pressurized working fluid to negotiate a series of intricate passage ways of differing lengths and de-energizes the pressurized fluid by forcing the fluid to contact a large surface area to create conditions for significant heat transfer to the mesh.
- the gas pressures that this apparatus is exposed to are typically in the range of about 1,000 to about 10,000 psi.
- the ground mat 6001 may be formed from a plurality of separate mats 6003 a-c and 6004a-c covered by the impermeable mat 6000 such as shown in Figure 7A.
- the mats may be formed from compliant industrial mesh mats 6003 and/or perforated rubber or canvas 6004 or other similar types of flexible, deformable, perforated mats.
- the impermeable mat can be made from heavy rubber, conveyor belt or plastic sheet or from a lighter gauge sheet metal or from a combination of such materials layered together to form a strong but impermeable mat.
- several holes 6006 are formed in the mat as needed for drilling of successive holes and placement of successive small charge blasting shots in the holes.
- the ground shroud is used only for fiyrock control, its layered construction may be simplified by using only one or two layers of material.
- the ground shroud can be made from one layer of heavy chain link mesh, or from two layers of lighter chain link mesh, or from a layer of lighter chain link mesh and a layer of heavy canvas or rubber mat and the upper impermeable layer omitted.
- Enclosures for pressure wave and flyrock suppression are aimed at intercepting and controlling the expanded air-blast in the immediate vicinity of the small charge blast around the undercarrier or rig stationed at the working face as well as equipment noise and flyrock.
- An enclosure is erected over the boom of the undercarrier or around the entire undercarrier or, in the case of a shaft rig, over the entire shaft rig.
- the enclosure may not be strongly coupled to the rock to be broken (as is the case for the collar or ground shrouds) but can be suspended over the work area from an independent structure that may or may not be the undercarrier or rig.
- the enclosure can be of a lighter weight construction than a collar shroud.
- the enclosure may include controlled leakage vents to facilitate controlled dissipation of the gas.
- FIG 8 A shows a cutaway side view of a rigid type canopy 7001 that is attached to the end of a boom 7002 of a small-charge blasting machine.
- a sealing member 7003 is mounted on the boom 7002.
- the enclosure 7001 is constructed of a heavy rigid outer shell 7005 (such as metallic plate) which may be lined on the inside with one or more thick rubber or canvas membranes 7006a, b which can both mitigate sound transmission through the shell 7005 and absorb flyrock impacts.
- the rigid canopy 7001 may have several large or many small holes or vents 7008 on its body 7009 or in its top 7010 to allow controlled venting of the gases during and after a shot.
- the enclosure 7001 may also have a flexible skirt 7011 that can form a rough seal 7012 with the ground to deflect the airblast and flyrock into the enclosure 7001.
- the inside of the enclosure 7001 may be further lined with a impact resistant layer 7013 for flyrock protection and/or with a pressure wave absorbent material 7014 for pressure wave mitigation.
- FIG. 8C depicts another configuration of a rigid-type canopy 300 that is designed to be attached to the feed holder or boom assembly of a small-charge blasting machine.
- both the rock drill apparatus and the sealing member are housed in within the canopy 300 so that all pressure waves and machine noise as well as flyrock from the collar region are captured in the enclosure.
- the outside of the canopy 301 may be fabricated from sheet metal, light steel plate, or another heavy rigid material attached to a frame structure fabricated from wood, aluminum, steel, or other types of structural members.
- One or more pressure wave absorbing, dissipating, and/or reflecting layers 307 are used to line the interior of the enclosure.
- the layer 307 may be held in place and protected by a impact resistant layer 306 of heavy industrial plastic, rubber, canvas or metallic mesh 307 and the like that is impact resistant and capable of resisting flyrock.
- a hinged door 304 for access to the rock drill and/or small charge blasting device.
- Figure 8D shows a cutaway side view of a heavy flexible type canopy 8001 shown affixed to the supporting cable 8002 such as might be used on a small-charge blasting apparatus 8003 used for shaft excavation.
- the flexible canopy formed from heavy flexible materials such as industrial conveyor belt, heavy canvas or a flexible sandwich such as heavy aluminum foil on either side of an acoustic material (e.g. ethyl vinyl acetate, poly vinyl chloride or other such plastic or foamed materials) such that it will absorb and deaden the airblast and equipment noise.
- the enclosure should form a heavy flexible bag type structure to contain the over-pressure.
- the enclosure may have a flap or door that can be secured shut during firing of the shot.
- the canopy 8001 is attached to a rigid support frame 8004 that may be constructed from wood or structural steel members.
- the canopy 8001 is draped onto the ground to form a rough seal 8005.
- the volume 8006 inside the canopy is sufficient to dilute the energy of the airblast as described above.
- the canopy 8001 may have several large or many small holes on its body 8007 or in its top 8008 to allow controlled venting of the gases during and after a shot.
- the internal volume of the flexible canopy is preferably in the range of about 50 m 3 to 200 m 3 , more preferably in the range of about 50 m 3 to 100 m 3 , and most preferably in the range of about 75 m 3 to 100 m 3 .
- the internal volume of the rigid enclosure is preferably in the range of about 1 m 3 to 10 m 3 , more preferably in the range of about 2 m 3 to 10 m 3 , and most preferably in the range of about 2 m 3 to 5 m 3 .
- the enclosures described above can be used to contain equipment other than a small charge blasting device to suppress pressure waves.
- the enclosures can contain a drill, an impact breaker, and the like.
- the pressure wave and flyrock suppression barriers intercept, absorb and/or deflect the noise or substantially weakened air-blast in the intermediate to far-field region of the small charge blast.
- Barriers of sound absorbent material are erected between the work area and the areas to be protected from noise (buildings, residences, playgrounds etc) .
- the barriers are located such that they absorb and/or deflect the noise energy up and over or away from the areas to be protected.
- the noise barriers may be assembled as a lining for the shaft.
- FIG. 9 shows a cutaway side view of the construction for a pressure wave and flyrock suppression barrier 9001.
- the barrier frame 9002 may be constructed from wood beams or structural steel members. The vertical members may be inserted into holes 9003 in the ground for support if the barriers are free-standing.
- the main barrier structure or skin 9004 may be made from plywood or sheet metal and covered with sound absorbent material such as acoustic tile, heavy canvas or industrial conveyor belt.
- Figure 10 shows how such barriers 10001 may be deployed around a work site 10002 to protect airblast and flyrock sensitive areas 10003.
- the angle " ⁇ " defined by a line extending from the work site 10002 to the structure and a line extending from the work site to the end of the barrier 10001 is typically at least about 30 and no more than about 90 degrees with about 45 degrees being preferred.
- Stand alone barriers may be typically 2 to 4 meters high and anchored typically 0.5 to 1 meters into the ground.
- the airblast that escapes from the drill hole or fragmented rock around the shot point moves at a velocity equal to or greater than the speed of sound.
- the pulse width of the airblast immediately around the shot point is on the order of a few milliseconds. It is possible to extract energy from the airblast or escaping working fluid by causing it to pass through a cloud of atomized fluid particles or spray.
- the spray must be atomized to increase the surface area of spray particles. For a given mass of fluid, the total surface area is proportional to the cube root of the number of droplets.
- the mechanism of extracting energy is by convective and conductive heat transfer of hot gases to fluid particles.
- the resultant fog cloud can extract significant energy from the airblast and expanded working fluid, and therefore reduce the amplitude and pulse width of the airblast near the source.
- the atomized fluid spray has the advantage that it is relatively easy to generate and apply compared to some of the mechanical airblast suppression apparatuses. Further, the spray has the beneficial side effect of helping to suppress dust.
- the droplet size ranges preferably from about 1 mm to 0.01 mm, more preferably from about 0.5 mm to 0.01 mm and most preferably from about 0.1 mm to 0.01 mm.
- the volume of fluid suspended around the working face at the time of firing is dependent on the charge weight of the explosive or propellant used.
- the volume of fluid ranges preferably from about 10 liters per kg of charge to 2000 liters per kg, more preferably from about 50 liters per kg to 2000 liters per kg and most preferably from about 100 liters per kg to 2000 liters per kg.
- Figure 11 shows a typical small charge excavation machine 11001 in firing position at the work face 11002.
- a small charge blasting device 11003 is positioned in a drill hole 11004.
- a spray system 11005 for atomizing a fluid such as water may be mounted on the machine 11001 and used to create a spray pattern 11006 that envelopes the working area 11007 between the machine 11001 and the drill hole 11004.
- FIG. 12 An embodiment of a novel gas generator device that may be used as part of the present invention to introduce a pressurized working fluid rapidly into a portion of the drill hole and to seal the hole is shown in Fig. 12. It includes a cartridge 14004 containing a propellant charge 14008 which is hand-inserted into a cartridge housing 14012.
- the cartridge 14004 may be contained completely inside the cartridge housing 14012 or the distal end of the cartridge 14004 may protrude a small distance beyond the muzzle end 14016 of the cartridge housing 14012 (typically about one third or less of the overall cartridge length protrudes beyond the muzzle end 14016 of the cartridge housing 14012).
- the cartridge 14004 may be made with a metallic base 14020 attached to a plastic cartridge body 14024. Alternately, the cartridge 14004 may be formed from only one material such as a plastic, compressed paper, or any other suitable material including combustible material used for consumable ammunition.
- the cartridge housing 14012 is then attached to the end of a long stemming bar 14028 by means of a full thread, an interrupted thread, a bayonet type lug, or another suitable attachment mechanism.
- the stemming bar 14028 is then attached to the end of a long stemming bar 14028 by means of a full thread, an interrupted thread, a bayonet type lug, or another suitable attachment mechanism.
- the stemming bar can be mounted to any suitable undercarriage, that may or may not include a drill for performing the drilling function.
- the propellant 14008 in the cartridge 14004 is initiated and the propellant 14008 is burned to completion generating a controlled high pressure in the bottom portion of the hole.
- the propellant 14008 may be initiated by a mechanical firing pin 14036, which is itself actuated by a firing pin assembly 14040, striking a percussion primer 14044 inserted in the cartridge base 14020.
- an electric primer may be used and initiated by a current pulse transmitted through an electrical contact with a wire pair running down the stemming bar.
- the initiator can utilize any other initiation method, including inductive coupling.
- the drill hole 14032 is formed by a reamer/pilot bit combination such that the distal portion 14048 of the drill hole 14032 is a smaller diameter than the proximal portion 14052 of the drill hole 14032.
- the outside of the cartridge housing 14012 has a slight taper 14056 (smaller diameter towards the distal end) so that the insertion will be stopped when the outside of the cartridge housing 14012 comes to rest on the step or ridge 14060 formed between the distal portion 14048 and the proximal portion 14052 of the drill hole 14032.
- the taper 14056 is preferably in the range of 0.5 to 3 degrees and most preferably in the range of 0.5 to 1.5 degrees.
- the ridge 14060 of the stepped drill hole 14032 and the taper 14056 of the cartridge housing 14012 form a seal 15004 restricting the flow of pressurized gas in the hole bottom 15008 during the rock-breaking process.
- the partial cut-away at the distal end of the cartridge housing 14012 illustrates that the cartridge body
- the cartridge housing 14012 may have a straight, constant diameter portion 16004 at its tip that is a reasonably tight fit in the distal portion 14048 of the drill hole 14032.
- This sealing method provides a gap 16008 that remains roughly constant, even as the device recoils away from the hole bottom 15008 after firing.
- the diameter of the distal portion 14048 of the drill hole 14032 is preferably in the range of 30 to 150 mm and most preferably in the range of 50 to 120 mm.
- the amount of propellant 14008 is preferably in the range of 100 to 750 grams and most preferably in the range of 200 to 450 grams.
- the length (L) of the pilot hole (distal portion 14048 of the drill hole 14032), expressed in terms of bottom hole diameters (D), is preferably in the L D range of 0.5 to 6 and most preferably in the L/D range of 1 to 3.
- the total volume available to the high pressure propellant gas products is such that the average density of the gas is preferably in the range of 100 to 750 kg/m 3 and most preferably in the range of 200 to 500 kg/m 3 .
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- Engineering & Computer Science (AREA)
- General Engineering & Computer Science (AREA)
- Life Sciences & Earth Sciences (AREA)
- General Life Sciences & Earth Sciences (AREA)
- Mining & Mineral Resources (AREA)
- Geochemistry & Mineralogy (AREA)
- Geology (AREA)
- Drilling And Exploitation, And Mining Machines And Methods (AREA)
- Earth Drilling (AREA)
Abstract
Description
Claims
Priority Applications (4)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP2000604183A JP2002539410A (en) | 1999-03-11 | 2000-02-24 | Method and apparatus for controlling fly lock during small charge blasting |
EP00909572A EP1171749A1 (en) | 1999-03-11 | 2000-02-24 | A method and apparatus for fly rock control in small charge blasting |
CA002365675A CA2365675A1 (en) | 1999-03-11 | 2000-02-24 | A method and apparatus for fly rock control in small charge blasting |
AU31852/00A AU3185200A (en) | 1999-03-11 | 2000-02-24 | A method and apparatus for fly rock control in small charge blasting |
Applications Claiming Priority (6)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US12427599P | 1999-03-11 | 1999-03-11 | |
US09/289,527 | 1999-04-09 | ||
US09/289,527 US6332401B1 (en) | 1999-03-11 | 1999-04-09 | Method and apparatus for pressure wave suppression in small-charge blasting |
US09/288,735 | 1999-04-09 | ||
US09/288,735 US6321655B1 (en) | 1999-03-11 | 1999-04-09 | Method and apparatus for flyrock control in small charge blasting |
US60/124,275 | 1999-04-09 |
Publications (1)
Publication Number | Publication Date |
---|---|
WO2000054001A1 true WO2000054001A1 (en) | 2000-09-14 |
Family
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Family Applications (2)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
PCT/IB2000/000308 WO2000054001A1 (en) | 1999-03-11 | 2000-02-24 | A method and apparatus for fly rock control in small charge blasting |
PCT/IB2000/000446 WO2000054002A1 (en) | 1999-03-11 | 2000-02-24 | A method and apparatus for pressure wave suppression in small-charge blasting |
Family Applications After (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
PCT/IB2000/000446 WO2000054002A1 (en) | 1999-03-11 | 2000-02-24 | A method and apparatus for pressure wave suppression in small-charge blasting |
Country Status (5)
Country | Link |
---|---|
EP (2) | EP1159581A1 (en) |
JP (2) | JP2002539410A (en) |
AU (3) | AU722846B1 (en) |
CA (2) | CA2365678A1 (en) |
WO (2) | WO2000054001A1 (en) |
Cited By (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO2002075115A1 (en) * | 2001-03-13 | 2002-09-26 | Brandrill Torrex (Proprietary) Limited | A method of sinking a shaft |
WO2003009974A1 (en) * | 2001-07-26 | 2003-02-06 | Nicolaas Daniel Lombard Burger | Rock drill silencing apparatus |
CN115342696A (en) * | 2022-09-06 | 2022-11-15 | 南昌大学 | Rock foundation excavation forming construction method |
Families Citing this family (8)
Publication number | Priority date | Publication date | Assignee | Title |
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KR101336754B1 (en) | 2012-11-09 | 2013-12-05 | 국방과학연구소 | Real time impact pressure detecting warhead ballistic and manufacturing method thereof |
CN108894745B (en) * | 2018-09-19 | 2024-01-30 | 重庆科技学院 | Rock drill orifice air pressure plugging device and method |
CN109596770B (en) * | 2018-11-27 | 2021-07-23 | 西安近代化学研究所 | Propellant powder explosion fragment pressure relief combustion stopping device |
CN110849229B (en) * | 2019-11-20 | 2022-06-07 | 中铁隧道局集团有限公司 | A big gun hole noise eliminator for reducing tunnel blasting noise |
CN112729035B (en) * | 2020-12-25 | 2023-02-28 | 上海二十冶建设有限公司 | Integral static blasting device for relatively complete rock stratum and construction method thereof |
CN113670154B (en) * | 2021-10-08 | 2023-06-02 | 冯壮雄 | Mine blasting damping wall protection device and use method thereof |
CN116988831B (en) | 2023-09-27 | 2023-12-12 | 太原理工大学 | Roof fracture form-based coal mine initial mining period I-shaped filling method |
CN117842622A (en) * | 2024-01-18 | 2024-04-09 | 徐州奔蓝机械科技有限公司 | Remote control inspection robot for mining rubber belt conveyor |
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WO1999061864A1 (en) * | 1998-05-27 | 1999-12-02 | Lewis, Alan, | Borehole closure plug |
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US3945319A (en) * | 1974-10-24 | 1976-03-23 | William Kevin Meagher | Blasting mat |
US4315463A (en) * | 1980-02-05 | 1982-02-16 | Arcand Leo H | Blasting mat |
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IL136683A0 (en) * | 1997-12-12 | 2001-06-14 | Ca Solicitor General | Apparatus and method for blast supression |
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1999
- 1999-08-27 AU AU44777/99A patent/AU722846B1/en not_active Ceased
-
2000
- 2000-02-24 EP EP00914327A patent/EP1159581A1/en not_active Withdrawn
- 2000-02-24 WO PCT/IB2000/000308 patent/WO2000054001A1/en not_active Application Discontinuation
- 2000-02-24 CA CA002365678A patent/CA2365678A1/en not_active Abandoned
- 2000-02-24 EP EP00909572A patent/EP1171749A1/en not_active Withdrawn
- 2000-02-24 WO PCT/IB2000/000446 patent/WO2000054002A1/en not_active Application Discontinuation
- 2000-02-24 JP JP2000604183A patent/JP2002539410A/en active Pending
- 2000-02-24 AU AU31852/00A patent/AU3185200A/en not_active Abandoned
- 2000-02-24 CA CA002365675A patent/CA2365675A1/en not_active Abandoned
- 2000-02-24 JP JP2000604184A patent/JP2002539411A/en active Pending
- 2000-02-24 AU AU35721/00A patent/AU3572100A/en not_active Abandoned
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AU4121093A (en) * | 1992-06-15 | 1993-12-23 | Orica Explosives Technology Pty Ltd | Method of uphole loading |
WO1999061864A1 (en) * | 1998-05-27 | 1999-12-02 | Lewis, Alan, | Borehole closure plug |
Cited By (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO2002075115A1 (en) * | 2001-03-13 | 2002-09-26 | Brandrill Torrex (Proprietary) Limited | A method of sinking a shaft |
WO2003009974A1 (en) * | 2001-07-26 | 2003-02-06 | Nicolaas Daniel Lombard Burger | Rock drill silencing apparatus |
CN115342696A (en) * | 2022-09-06 | 2022-11-15 | 南昌大学 | Rock foundation excavation forming construction method |
CN115342696B (en) * | 2022-09-06 | 2023-09-29 | 南昌大学 | Rock foundation excavation forming construction method |
Also Published As
Publication number | Publication date |
---|---|
JP2002539410A (en) | 2002-11-19 |
EP1159581A1 (en) | 2001-12-05 |
CA2365675A1 (en) | 2000-09-14 |
AU3572100A (en) | 2000-09-28 |
AU3185200A (en) | 2000-09-28 |
CA2365678A1 (en) | 2000-09-14 |
WO2000054002A1 (en) | 2000-09-14 |
JP2002539411A (en) | 2002-11-19 |
EP1171749A1 (en) | 2002-01-16 |
AU722846B1 (en) | 2000-08-10 |
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