WO2000049123A1 - Compositions d'amelioration de l'aspect de textiles, comprenant des polyamines de haut poids moleculaire - Google Patents

Compositions d'amelioration de l'aspect de textiles, comprenant des polyamines de haut poids moleculaire Download PDF

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Publication number
WO2000049123A1
WO2000049123A1 PCT/US2000/003941 US0003941W WO0049123A1 WO 2000049123 A1 WO2000049123 A1 WO 2000049123A1 US 0003941 W US0003941 W US 0003941W WO 0049123 A1 WO0049123 A1 WO 0049123A1
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Prior art keywords
mixtures
agents
fabric
alkyl
formula
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PCT/US2000/003941
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English (en)
Inventor
Janet Sue Littig
Dieter Boeckh
Oliver Borzyk
Michael Ehle
Frederick Anthony Hartman
John Cort Severns
Shulin Zhang
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The Procter & Gamble Company
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Priority to AU29969/00A priority Critical patent/AU2996900A/en
Publication of WO2000049123A1 publication Critical patent/WO2000049123A1/fr

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Classifications

    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16—Organic compounds
    • C11D3/20—Organic compounds containing oxygen
    • C11D3/2003—Alcohols; Phenols
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/0005—Other compounding ingredients characterised by their effect
    • C11D3/001—Softening compositions
    • C11D3/0015—Softening compositions liquid
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16—Organic compounds
    • C11D3/20—Organic compounds containing oxygen
    • C11D3/2068—Ethers
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16—Organic compounds
    • C11D3/37—Polymers
    • C11D3/3703—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • C11D3/3723—Polyamines or polyalkyleneimines
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16—Organic compounds
    • C11D3/20—Organic compounds containing oxygen
    • C11D3/2003—Alcohols; Phenols
    • C11D3/2006—Monohydric alcohols
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16—Organic compounds
    • C11D3/20—Organic compounds containing oxygen
    • C11D3/2003—Alcohols; Phenols
    • C11D3/2041—Dihydric alcohols

Definitions

  • the present invention relates to fab ⁇ c care compositions which provide fab ⁇ c enhancement benefits while reducing the damage to fab ⁇ c from abrasion.
  • the compositions of the present invention comp ⁇ se one or more fab ⁇ c abrasion reducing polymers as well as other ingredients which provide a benefit to the consumer inter alia fab ⁇ c softening, anti-static, dye fixation.
  • Short fibers are dislodged from woven and knit fab ⁇ c/textile structures by the mechanical action of laundering. These dislodged fibers may form lint, fuzz or "pills" which are visible on the surface of fab ⁇ cs and diminish the appearance of newness of the fab ⁇ c. Such a problem of fab ⁇ c abrasion is even more acute after multiwash cycles.
  • compositions which provide fab ⁇ c with protection against damage done due to fabnc abrasion there exists a long felt need for compositions which provide fab ⁇ c with protection against damage done due to fabnc abrasion.
  • compositions which provide a remedy for fab ⁇ c abrasion damage SUMMARY OF THE INVENTION
  • high molecular weight polyalkyleneimmes preferably polyethyleneimmes, having a molecular weight of at least about 5200 daltons, are suitable for use in rinse-added fabric care compositions to provide fab ⁇ c appearance benefits inter aha mitigation of fabric damage via bleaching agents, prevention of fabric mechanical damage.
  • a first aspect of the present invention relates to rinse-added fabric enhancement or fabric care compositions comprising: a) from about 0.01% by weight, of a polyalkyleneimine having the formula:
  • a further aspect of the present invention provides a method for enhancing the color fidelity of fabric while reducing the damage to fabric due to the interaction of laundry adjunct ingredients and damage due to mechanical wear.
  • This method comprises the step of contacting an article of fab ⁇ c with the compositions of the present invention in an aqueous solution.
  • the present invention further provides laundry pre-soak compositions which are used to pre-treat fabric which have not been previously treated with a composition of the present invention.
  • the disclosed pre-treatment compositions provide fabric and fabric color protection though the wash to the treated articles.
  • the present invention relates to fabric enhancement compositions which comprise from about 0.01%), preferably from about 0.1%, more preferably from 0.25%, most preferably from about 0.5%> to about 20%, preferably to about 10%, more preferably to about 5% by weight, of one or more high molecular weight polyalkyleneimmes, preferably polyethyleneimmes.
  • the polyalkyleneimmes of the present invention have the general formula:
  • R units comprising pnmary, secondary and tertiary amine nitrogens connected by R units which are linking units.
  • the primary units cap or terminate the main polyalkyleneimine chain as well as any branch chains whereas the secondary and tertiary units are randomly distributed throughout the polyalkyleneimine molecule chain.
  • the units which make up the polyalkyleneimine backbones are primary amine units having the formula:
  • R is C 2 -C 4 linear alkylene, C 3 -C 4 branched alkylene, and mixtures thereof; preferably R is ethylene.
  • the prefered polyalkyleneimmes of the present invention are polyethyleneimmes (PEI ' s) wherein 100% of the R units are ethylene.
  • molecular weight is "an average molecular weight of the polyalkyleneimmes present in the material which is incorporated into the present compositions".
  • a particular sample of polyalkyleneimine, especially as the average molecular weight increases, will comprise an admixture of polyamine having a range of molecular weights.
  • the lowest average molecular weight of the polyalkyleneimmes of the present invention is about 5200 dalton, wherein the lowest molecular weight of any polyalkyleneimine present in the 5200 dalton sample is 5000 dalton. Therefore there is a range for the preferred lowest average molecular weight of plus or minus 200 dalton.
  • the average molecular weight of the polyalkyleneimmes is from about 10,000 dalton, most preferably from about 20,000 dalton to about 320,000 dalton, preferably to about 200,000 dalton, more preferably to about 150,000 dalton.
  • the polyalkyleneimmes of the present invention which have an average molecular weight of about 320,000 dalton will preferably comprise polyalkyleneimmes which do not exceed 500,000 dalton molecular weight.
  • the indices w, x, and y reflect the possible relative ratios of the primary, secondary, and tertiary backbone units possible in the polyalkyleneimmes of the present invention and do not necessary reflect the minimum nor maximum molecular weight of a polyamine which is present in the admixture.
  • the index w, for non-cyclic polyalkyleneimmes, will always equal the value of x + 1.
  • the preferred maximal ratio of secondary units to tertiary units is 1 to 20 (x equal to 50 and y equal to 100) and would comprise a highly branched polyalkyleneimine.
  • the preferred minimal ratio of secondary units to tertiary units is 125 to 1 (x equal to 2500 and y equal to 20) which for the purposes of the present invention is a "linear polyalkyleneimine".
  • linear polyalkyleneimine is defined as “polyamines wherein less than 1 tertiary unit is present for every 100 secondary unit which is present.”
  • substantially linear polyalkylene-imine is defined as “polyamines wherein the ratio of secondary units to tertiary units is from about 100 secondary units present for every 1 tertiary unit present to about 2 secondary units present for 1 tertiary unit present (from about 100:1 to about 2:1).”
  • substantially branched polyalkyleneimine is defined as "polyamines wherein the ratio of secondary units to tertiary units is from about 2 secondary units present for every 1 tertiary unit present to about 1 secondary unit present for every 2 tertiary unit present (from about 2:1 to about 1 :2).
  • branched polyalkyleneimine is defined as "polyamines wherein the ratio of secondary units to tert
  • the formulator may wish to include a "substantially linear polyalkyleneimine” having an average molecular weight of about 200,000 in one compositions and a "substantially branched polyalkyleneimine” having an average molecular weight of about 40,000 daltons in another embodiment.
  • the polyalkyleneimmes of the present invention can be prepared, for example, by polymerizing ethyleneimine in the presence of a catalyst such as carbon dioxide, sodium bisulfite, sulfuric acid, hydrogen peroxide, hydrochloric acid, acetic acid, etc.
  • a catalyst such as carbon dioxide, sodium bisulfite, sulfuric acid, hydrogen peroxide, hydrochloric acid, acetic acid, etc.
  • Specific methods for preparing the polyalkyleneimmes of the present invention are disclosed in U.S. Patent 2,182,306, Ulrich et al., issued December 5, 1939; U.S. Patent 3,033,746, Mayle et al., issued May 8, 1962; U.S. Patent 2,208,095, Esselmann et al., issued July 16, 1940; U.S. Patent 2,806,839, Crowther, issued September 17, 1957; and U.S. Patent 2,553,696, Wilson, issued May 21, 1951; all herein incorporated by reference.
  • An example of a preferred polyalkyleneimine according to the present invention is a polyethyleneimine having an average molecular weight of about 25,000 dalton (PEI 25,000) wherein the average ratio of secondary units to tertiary units is from about 4: 1 to about 1:1.
  • PEI 25,000 average molecular weight of about 25,000 dalton
  • the present invention relates to fabric care compositions which comprise: a) from about 0.01%, preferably from about 0.1% to about 20%, preferably to about
  • a fabric abrasion polymer comprising: i) at least one monomeric unit comprising an amide moiety; ii) at least one monomeric unit comprising an N-oxide moiety; iii) and mixtures thereof; c) optionally from about 1%, preferably from about 10%, more preferably from about 20% to about 80%, preferably to about 60%, more preferably to about 45% by weight, of a fabric softening active; d) optionally less than about 15% by weight, of a principal solvent, preferably said principal solvent has a ClogP of from about 0.15 to about 1; e) optionally from about 0.001% to about 90% by weight, of one or more dye fixing agents; g) optionally from about 0.01% to about 50% by weight, of one or more cellulose reactive dye fixing agents; h) optionally from about 0.01% to about 15% by weight, of a chlorine
  • the fabric care compositions of the present invention comprise one or more polyamidoamine polymers as described herein.
  • fabric care compositions is defined as "a composition which provides care to the fabric non-limiting examples of which include stand-alone compositions, detergent additives, fabric softening compositions inter alia rinse-added softening composition, dryer-added softening compositions".
  • the compositions of the present invention provide an efficient fabric abrasion reduction.
  • efficient fabric abrasion reduction is defined herein as "fabric which has been treated by the herein described compositions have an improved appearance relative to fabrics which have been un-treated by the herein disclosed compositions.
  • compositions of the present invention comprise from about 0.01%, preferably from about 0.1% to about 20%, preferably to about 10% by weight, of a fabric abrasion reducing polymer.
  • the prefered reduced abrasion polymers of the present invention are water-soluble polymers.
  • water-soluble is defined as "a polymer which when dissolved in water at a level of 0.2% by weight, or less, at 25° C, forms a clear, isotropic liquid".
  • the fabric abrasion reducing polymers useful in the present invention have the formula:
  • unit P is a polymer backbone which comprises units which are homopolymeric or copolymeric.
  • D units are defined herein below.
  • homopolymeric is defined as "a polymer backbone which is comprised of units having the same unit composition, i.e., formed from polymerization of the same monomer".
  • copolymeric is defined as "a polymer backbone which is comprised of units having a different unit composition, i.e., formed from the polymerization of two or more monomers”.
  • P backbones preferably comprise units having the formula:
  • each R unit is independently hydrogen, C,-C 12 alkyl, C 6 -C 12 aryl, and D units as described herein below; preferably C,-C 4 alkyl.
  • Each L unit is independently selected from heteroatom-containing moieties, non-limiting examples of which are selected from the group consisting of:
  • index p is from 1 to about 6; units which have dye transfer inhibition activity:
  • R 1 is hydrogen, C,-C 12 alkyl, C 6 -C 12 aryl, and mixtures thereof.
  • R 2 is C r C )2 alkyl, C r C 12 alkoxy, C 6 -C 12 aryloxy, and mixtures thereof; preferably methyl and methoxy.
  • R 3 is hydrogen C C 12 alkyl, C 6 -C 12 aryl, and mixtures thereof; preferably hydrogen or C,-C 4 alkyl, more preferably hydrogen.
  • R 4 is C r C 12 alkyl, C 6 -C 12 aryl, and mixtures thereof.
  • the backbones of the fabric abrasion reducing polymers of the present invention comprise one or more D units which are units which comprise one or more units which provide a dye transfer inhibiting benefit.
  • the D unit can be part of the backbone itself as represented in the general formula:
  • the D unit may be incorporated into the backbone as a pendant group to a backbone unit having, for example, the formula:
  • the number of D units depends upon the formulation. For example, the number of D units will be adjusted to provide water solubility of the polymer as well as efficacy of dye transfer inhibition while providing a polymer which has fabric abrasion reducing properties.
  • the molecular weight of the fabric abrasion reducing polymers of the present invention are from about 500, preferably from about 1,000, more preferably from about 100,000 most preferably from 160,000 to about 6,000,000, preferably to about 2,000,000, more preferably to about 1,000,000, yet more preferably to about 500,000, most preferably to about 360,000 daltons.
  • the value of the index n is selected to provide the indicated molecular weight, and providing for a water solubility of least 100 ppm, preferably at least about 300 ppm, and more preferably at least about 1 ,000 ppm in water at ambient temperature which is defined herein as 25°C.
  • Non-limiting examples of preferred D units are D units which comprise an amide moiety.
  • Examples of polymers wherein an amide unit is introduced into the polymer via a pendant group includes polyvinylpyrrolidone having the formula:
  • polyvinyloxazolidone having the formula:r polyvmylmethyloxazolidone having t e ormula:
  • each R' is independently hydrogen, C,-C 6 alkyl, or both R' units can be taken together to form a ring comp ⁇ smg 4-6 carbon atoms; polymethacrylamides and N-substituted polymethacrylamides having the general formula:
  • each R' is independently hydrogen, C r C 6 alkyl, or both R' units can be taken together to form a ring comprising 4-6 carbon atoms; poly(N-acrylylglycmam ⁇ de) having the formula:
  • each R' is independently hydrogen, C C 6 alkyl, or both R' units can be taken together to form a ring comprising 4-6 carbon atoms.
  • D unit wherein the nitrogen of the dye transfer inhibiting moiety is incorporated into the polymer backbone is a poly(2-ethyl-2-oxazoline) having the formula:
  • the fabric abrasion reducing polymers of the present invention can comprise any mixture of dye transfer inhibition units which provides the product with suitable properties.
  • the preferred polymers which comprise D units which are amide moieties are those which have the nitrogen atoms of the amide unit highly substituted so the nitrogen atoms are in effect shielded to a varying degree by the surrounding non-polar groups. This provides the polymers with an amphiphilic character.
  • Non-limiting examples include polyvinyl-pyrrolidones, polyvinyloxazolidones, N,N-disubstituted polyacrylamides, and N,N-disubstituted polymethacrylamides. A detailed description of physico-chemical properties of some of these polymers are given in "Water-Soluble Synthetic Polymers: Properties and Behavior", Philip
  • the amide containing polymers may be present partially hydrolyzed and/or crosslinked forms.
  • a preferred polymeric compound for the present invention is polyvinylpyrrolidone (PVP).
  • PVP polyvinylpyrrolidone
  • This polymer has an amphiphilic character with a highly polar amide group conferring hydrophilic and polar-attracting properties, and also has non-polar methylene and methine groups, in the backbone and/or the ring, conferring hydrophobic properties.
  • the rings may also provide planar alignment with the aromatic rings in the dye molecules.
  • PVP is readily soluble in aqueous and organic solvent systems.
  • PVP is available ex ISP, Wayne, New Jersey, and BASF Corp., Parsippany, New Jersey, as a powder or aqueous solutions in several viscosity grades, designated as, e.g., K-12, K-15, K-25, and K-30. These K-values indicate the viscosity average molecular weight, as shown below:
  • PVP K-12, K-15, and K-30 are also available ex Polysciences, Inc. Warrington, Pennsylvania, PVP K-15, K-25, and K-30 and poly(2-ethyl-2-oxazoline) are available ex Aldrich Chemical Co., Inc., Milwaukee, Wisconsin.
  • PVP K30 (40,000) through to K90 (360,000) are also commercially available ex BASF under the tradename Luviskol or commercially available ex ISP. Still higher molecular PVP like PVP 1.3MM, commercially available ex Aldrich is also suitable for use herein.
  • PVP-type of material suitable for use in the present invention are polyvinylpyrrolidone-co-dimethylaminoethylmethacrylate, commercially available commercially ex ISP in a quaternised form under the tradename Gafquat® or commercially available ex Aldrich Chemical Co. having a molecular weight of approximately 1.0MM; polyvinylpyrrolidone-co-vinyl acetate, available ex BASF under the tradename Luviskol®, available in vinylpyrrolidone:vinylacetate ratios of from 3:7 to 7:3.
  • Polymers Comprising N-oxide Units are polyvinylpyrrolidone-co-dimethylaminoethylmethacrylate, commercially available commercially ex ISP in a quaternised form under the tradename Gafquat® or commercially available ex Aldrich Chemical Co. having a molecular weight of approximately 1.0MM; polyvinylpyrrolidone-co-vinyl acetate
  • Another D unit which provides dye transfer inhibition enhancement to the fabric abrasion reducing polymers described herein, are N-oxide units having the formula:
  • R 1 , R 2 , and R 3 can be any hydrocarbyl unit (for the purposes of the present invention the term "hydrocarbyl" does not include hydrogen atom alone).
  • the N-oxide unit may be part of a polymer, such as a polyamine, i.e., polyalkyleneamine backbone, or the N-oxide may be part of a pendant group attached to the polymer backbone.
  • a polymer which comprises an the N-oxide unit as a part of the polymer backbone is polyethyleneimine N-oxide.
  • Non-limiting examples of groups which can comprise an N-oxide moiety include the N-oxides of certain heterocycles mter alia pyridine, pyrrole, imidazole, pyrazole, pyrazine, pyrimidine, pyridazine, piperidine, pyrrolidine, pyrrolidone, azolidine, mo ⁇ holine.
  • a preferred polymer is poly(4- vinylpyriding N-oxide, PVNO).
  • the N-oxide unit may be pendant to the ring, for example, aniline oxide.
  • N-oxide comprising polymers of the present invention will preferably have a ration of N- oxidized amine nitrogen to non-oxidized amine nitrogen of from about 1 :0 to about 1 :2, preferably to about 1 :1, more preferably to about 3:1.
  • the amount of N-oxide units can be adjusted by the formulator.
  • the formulator may co-polymerize N-oxide comprising monomers with non N-oxide comprising monomers to arrive at the desired ratio of N-oxide to non N-oxide amino units, or the formulator may control the oxidation level of the polymer during preparation.
  • the amine oxide unit of the polyamine N-oxides of the present invention have a Pk, less than or equal to 10, preferably less than or equal to 7, more preferably less than or equal to 6.
  • the average molecular weight of the N-oxide comprising polymers which provide a dye transfer inhibitor benefit to reduced fabric abrasion polymers is from about 500 daltons, preferably from about 100,000 daltons, more preferably from about 160,000 daltons to about 6,000,000 daltons, preferably to about 2,000,000 daltons, more preferably to about 360,000 daltons.
  • a further example of polymers which are fabric abrasion reducing polymers which have dye transfer inhibition benefits are polymers which comprise both amide units and N-oxide units as described herein above.
  • Non-limiting examples include co-polymers of two monomers wherein the first monomer comprises an amide unit and the second monomer comprises an N- oxide unit.
  • oligomers or block polymers comprising these units can be taken together to form the mixed amide/N-oxide polymers.
  • the resulting polymers must retain the water solubility requirements described herein above.
  • the above described fabric abrasion reducing polymers of the invention it is most preferred that they have a molecular weight in the range as described herein above. This range is typically higher than the range for polymers which render only dye transfer inhibition benefits alone. Indeed, the higher molecular weight of the abrasion reducing polymers provides for reduction of fabric abrasion which typically occurs subsequent to treatment, for example during garment use, especially in a later washing procedure. Not to be bound by theory, it is believed that the high molecular weight enables the deposition of the polymer on the fabric surface and provides sufficient substantivity so that the polymer is capable of remaining on the fabric during subsequent use and subsequent laundering of the fabric.
  • compositions of the present invention optionally comprise from about 0.001%, preferably from about 0.5% to about 90%, preferably to about 50%, more preferably to about 10%), most preferably to about 5% by weight, of one or more dye fixing agents.
  • Dye fixing agents are well-known, commercially available materials which are designed to improve the appearance of dyed fabrics by minimizing the loss of dye from fabrics due to washing. Not included within this definition are components which can in some embodiments serve as fabric softener actives.
  • Cationic fixatives are available under various trade names from several suppliers. Representative examples include: CROSCOLOR PMF (July 1981, Code No. 7894) and CROSCOLOR NOFF (January 1988, Code No. 8544) ex Crosfield; INDOSOL E-50 (February 27, 1984, Refi No. 6008.35.84; polyethyleneamine-based) ex Sandoz; SANDOFIX TPS, ex Sandoz, is a preferred dye fixative for use herein.
  • SANDOFIX SWE a cationic resinous compound ex Sandoz
  • REWIN SRF REWIN SRF-O
  • REWIN DWR ex CHT-Beitlich GMBH
  • Tinofix® ECO Tinofix® FRD
  • Solfm® ex Ciba-Geigy.
  • a preferred dye fixing agent for use in the compositions of the present invention is CARTAFIX CB® ex Clariant.
  • Dye fixing agents suitable for use in the present invention are ammonium compounds such as fatty acid-diamine condensates ter alia the hydrochloride, acetate, metosulphate and benzyl hydrochloride salts of diamine esters.
  • Non-limiting examples include oleyldiethyl aminoethylamide, oleylmethyl diethylenediamine methosulphate, monostearylethylene diaminotrimethylammonium methosulphate.
  • N-oxides of tertiary amines are suitable for use as dye fixatives in the compositions of the present invention.
  • compositions of the present invention optionally comprise from about 0.01%, preferably from about 0.05%>, more preferably from about 0.5%> to about 50%, preferably to about 25%, more preferably to about 10% by weight, most preferably to about 5% by weight, of one or more cellulose reactive dye fixing agents.
  • the cellulose reactive dye fixatives may be suitably combined with one or more dye fixatives described herein above in order to comprise a "dye fixative system".
  • cellulose reactive dye fixing agent is defined herein as "a dye fixative agent which reacts with the cellulose fibers upon application of heat or upon a heat treatment either in situ or by the formulator".
  • the cellulose reactive dye fixing agents suitable for use in the present invention can be defined by the following test procedure.
  • Cellulose Reactivity Test (CRT) Cellulose Reactivity Test
  • All four swatches (the two control swatches and the two treated swatches, one of each which has been treated by the ironing calender) are washed separately in Launder-O-Meter pots under typical conditions with a commercial detergent used at the recommended dosage for A hour at 60°C, followed by a thorough rinsing of 4 times 200 ml of cold water and subsequently line dried.
  • DE values the computed color difference
  • ASTM D2244 the computed color difference
  • DE values relate to the magnitude and direction of the difference between two psychophysical color stimuli defined by tristimulus values, or by chromaticity coordinates and luminance factor, as computed by means of a specified set of color-difference equations defined in the CIE 1976 CIELAB opponent-color space, the Hunter opponent-color space, the Friele-Mac Adam-Chickering color space or any equivalent color space.
  • the lower the DE value for a sample the closer the sample is to the un-tested sample and the greater the color fastness benefit.
  • the candidate is a cellulose reactive dye fixing agent for the pu ⁇ oses of the invention.
  • cellulose reactive dye fixing agents are compounds which contain a cellulose reactive moiety
  • non limiting examples of these compounds include halogeno-triazines, vinyl sulphones, epichlorhydrine derivatives, hydroxyethylene urea derivatives, formaldehyde condensation products, polycarboxylates, glyoxal and glutaraldehyde derivatives, and mixtures thereof. Further examples can be found in “Textile Processing and Properties", Tyrone L. Vigo, at page 120 to 121, Elsevier (1997), which discloses specific electrophilic groups and their corresponding cellulose affinity.
  • Preferred hydroxyethylene urea derivatives include dimethyloldihydroxyethylene, urea, and dimethyl urea glyoxal.
  • Preferred formaldehyde condensation products include the condensation products derived from formaldehyde and a group selected from an amino-group, an imino-group, a phenol group, an urea group, a cyanamide group and an aromatic group.
  • Commercially available compounds among this class are Sandofix WE 56 ex Clariant, Zetex E ex Zeneca and Levogen BF ex Bayer.
  • Preferred polycarboxylates derivatives include butane tetracarboxilic acid derivatives, citric acid derivatives, polyacrylates and derivatives thereof.
  • a most preferred cellulosic reactive dye fixing agents is one of the hydroxyethylene urea derivatives class commercialized under the tradename of Indosol CR ex Clariant. Still other most preferred cellulosic reactive dye fixing agents are commercialized under the tradename Rewin DWR and Rewin WBS ex CHT R. Beitlich. Chlorine Scavengers
  • the compositions of the present invention optionally comprise from about 0.01%, preferably from about 0.02%, more preferably from about 0.25% to about 15%>, preferably to about 10%, more preferably to about 5% by weight, of a chlorine scavenger.
  • Suitable chlorine scavengers include ammonium salts having the formula:
  • each R is independently hydrogen, C,-C 4 alkyl, C r C 4 substituted alkyl, and mixtures thereof, preferably R is hydrogen or methyl, more preferably hydrogen.
  • R 1 is hydrogen C r C 9 alkyl, C,-C 9 substituted alkyl, and mixtures thereof, preferably R is hydrogen.
  • X is a compatible anion, non-limiting examples include chloride, bromide, citrate, sulfate; preferably X is chloride.
  • Non-limiting examples of preferred chlorine scavengers include ammonium chloride, ammonium sulfate, and mixtures thereof; preferably ammonium chloride.
  • compositions of the present invention optionally comprise from about 0.005%, preferably from about 0.5%, more preferably from about 0.1% to about 1%, preferably to about 0.5%, more preferably to about 0.25%, most preferably to about 0.2% by weight, of one or more crystal growth inhibitors.
  • crystal Growth Inhibition Test is used to determine the suitability of a material for use as a crystal growth inhibitor.
  • the suitability of a material to serve as a crystal growth inhibitor according to the present invention can be determined by evaluating in vitro the growth rate of certain inorganic micro- crystals.
  • the procedure of Nancollas et al., described in "Calcium Phosphate Nucleation and Growth in Solution", Prog. Crystal Growth Charact., Vol 3, 77-102, (1980), inco ⁇ orated herein by reference, is a method which is suitable for evaluating compounds for their crystal growth inhibition.
  • the graph below serves as an example of a plot indicating the time delay (t-lag) in crystal formation afforded by a hypothetical crystal growth inhibitor.
  • t-lag provides a measure of the compound's efficiency with respect to delaying the growth of calcium phosphate crystal.
  • Exemplary Procedure Combine in a suitable vessel, 2.1M KC1 (35 mL), 0.0175M CaCl 2 (50mL), 0.01M KH 2 P0 4 (50mL), and de-ionized water (350mL).
  • a standard pH electrode equipped with a Standard Calomel Reference electrode is inserted and the temperature adjusted to 37° C while purging of the solution of oxygen. Once the temperature and pH are stabilized, a solution of the crystal growth inhibitor to be test is then added.
  • a typical inhibitor test concentration is 1 x 10 "6 M.
  • the solution is titrated to pH 7.4 with 0.05M KOH.
  • the mixture is then treated with 5 mL's of a hydroxyapatite slurry.
  • the hydroxyapatite slurry can be prepared by digesting Bio-Gel ® HTP hydroxyapatite powder (100 g) in 1 L of distilled water the pH of which is adjusted to 2.5 by the addition of sufficient 6N HCl and subsequently heating the solution until all of the hydroxyapatite is dissolved (heating for several days may be necessary).
  • the temperature of the solution is then maintained at about 22° C while the pH is adjusted to 12 by the addition of a solution of 50% aqueous KOH.
  • the solution is heated and the resulting slurry is allowed to settle for two days before the supernatant is removed.
  • 1.5 L of distilled water is added, the solution stirred, then after settling again for 2 days the supernatant is removed. This rinsing procedure is repeated six more time after which the pH of the solution is adjusted to neutrality using 2N HCl.
  • the resulting slurry can be stored at 37°C for eleven months.
  • Crystal growth inhibitors which are suitable for use in the present invention have a t-lag of at least 10 minutes, preferably at least 20 minutes, more preferably at least 50 minutes, at a concentration of 1 x 10 "6 M.
  • Crystal growth inhibitors are differentiated form chelating agents by the fact that crystal growth inhibitors have a low binding affinity of heavy metal ions, i.e., copper.
  • crystal growth inhibitors have an affinity for copper ions in a solution of 0.1 ionic strength when measured at 25° C, of less than 15, preferably less than 12.
  • the preferred crystal growth inhibitors of the present invention are selected from the group consisting of carboxylic compounds, organic diphosphonic acids, and mixtures thereof.
  • the following are non-limiting examples of preferred crystal growth inhibitors.
  • Non-limiting examples of carboxylic compounds which serve as crystal growth inhibitors include glycolic acid, phytic acid, polycarboxylic acids, polymers and co-polymers of carboxylic acids and polycarboxylic acids, and mixtures thereof.
  • the inhibitors may be in the acid or salt form.
  • the polycarboxylic acids comprise materials having at least two carboxylic acid radicals which are separated by not more than two carbon atoms (e.g., methylene units).
  • the preferred salt forms include alkali metals; lithium, sodium, and potassium; and alkanolammonium.
  • the polycarboxylates suitable for use in the present invention are further disclosed in U.S. 3,128,287, U.S. 3,635,830, U.S.
  • polycarboxylates include ether hydroxypolycarboxylates, polyacrylate polymers, copolymers of maleic anhydride and the ethylene ether or vinyl methyl ethers of acrylic acid. Copolymers of 1,3,5-trihydroxybenzene, 2, 4, 6-trisulphonic acid, and carboxymethyloxysuccinic acid are also useful.
  • Alkali metal salts of polyacetic acids for example, ethylenediamine tetraacetic acid and nitrilotriacetic acid
  • the alkali metal salts of polycarboxylates for example, mellitic acid, succinic acid, oxydisuccinic acid, polymaleic acid, benzene 1,3,5-tricarboxylic acid, carboxymethyloxysuccinic acid, are suitable for use in the present invention as crystal growth inhibitors.
  • the polymers and copolymers which are useful as crystal growth inhibitors have a molecular weight which is preferably greater than about 500 daltons to about 100,000 daltons, more preferably to about 50,000 daltons.
  • Examples of commercially available materials for use as crystal growth inhibitors include, polyacrylate polymers Good-Rite® ex BF Goodrich, Acrysol® ex Rohm & Haas, Sokalan® ex BASF, and Norasol® ex Norso Haas.
  • Polycarboxylate crystal growth inhibitors include citrates, e.g., citric acid and soluble salts thereof (particularly sodium salt), 3,3-dicarboxy-4-oxa-l,6-hexanedioates and related compounds further disclosed in U.S. 4,566,984 inco ⁇ orated herein by reference, C5-C20 alkyl, C5-C20 alkenyl succinic acid and salts thereof, of which dodecenyl succinate, lauryl succinate, myristyl succinate, palmityl succinate, 2-dodecenylsuccinate, 2-pentadecenyl succinate, are non- limiting examples.
  • Other suitable polycarboxylates are disclosed in U.S. 4,144,226, U.S. 3,308,067 and U.S. 3,723,322, all of which are inco ⁇ orated herein by reference.
  • Organic diphosphonic acid are also suitable for use as crystal growth inhibitors.
  • organic diphosphonic acid is defined as "an organo- diphosphonic acid or salt which does not comprise a nitrogen atom”.
  • Preferred organic diphosphonic acids include C r C 4 diphosphonic acid, preferably C 2 diphosphonic acid selected from the group consisting of ethylene diphosphonic acid, ⁇ -hydroxy-2 phenyl ethyl diphosphonic acid, methylene diphosphonic acid, vinylidene- 1,1 -diphosphonic acid , l,2-dihydroxyethane-l,l- diphosphonic acid, hydroxy-ethane 1,1 diphosphonic acid, the salts thereof, and mixtures thereof. More preferred is hydroxyethane- 1,1 -diphosphonic acid (HEDP).
  • HEDP hydroxyethane- 1,1 -diphosphonic acid
  • PBTC 2-phosphonobutane-l,2,4-tricarboxylic acid
  • compositions of the present invention optionally comprise at least about 1%, preferably from about 10%, more preferably from about 20% to about 80%, more preferably to about 60%, most preferably to about 45% by weight, of the composition of one or more fabric softener actives.
  • the preferred fabric softening actives according to the present invention are amines having the formula:
  • each R is independently Ci -Cg alkyl, Ci -Cg hydroxyalkyl, benzyl, and mixtures thereof;
  • R ⁇ is preferably Ci 1 -C22 linear alkyl, C1 1 -C22 branched alkyl, C 1-C22 linear alkenyl, C j 1-C22 branched alkenyl, and mixtures thereof;
  • Q is a carbonyl moiety independently selected from the units having the formula:
  • R ⁇ is hydrogen, Ci -C4 alkyl, preferably hydrogen; R ⁇ is Ci -C4 alkyl, preferably hydrogen or methyl; preferably Q has the formula: O O
  • X is a softener compatible anion, preferably the anion of a strong acid, for example, chloride, bromide, methylsulfate, ethylsulfate, sulfate, nitrate and mixtures thereof, more preferably chloride and methyl sulfate.
  • the anion can also, but less preferably, carry a double charge, in which case X' " ' represents half a group.
  • the index m has a value of from 1 to 3; the index n has a value of from 1 to 4, preferably 2 or 3, more preferably 2.
  • One embodiment of the present invention provides for amines and quaternized amines having two or more different values for the index n per molecule, for example, a softener active prepared from the starting amine methyl(3-aminopropyl)(2-hydroxyethyl)amine.
  • More preferred softener actives according to the present invention have the formula:
  • O — 0-C-R ! is a fatty acyl moiety.
  • Suitable fatty acyl moieties for use in the softener actives of the present invention are derived from sources of triglycerides including tallow, vegetable oils and/or partially hydrogenated vegetable oils including inter alia canola oil, safflower oil, peanut oil, sunflower oil, corn oil, soybean oil, tall oil, rice bran oil. Yet more preferred are the Diester Quaternary Ammonium Compounds (DEQA's) wherein the index m is equal to 2.
  • the formulator can choose any of the above mentioned sources of fatty acyl moieties, or alternatively, the formulator can mix sources of triglyceride to form a "customized blend".
  • the fatty acyl composition may vary, as in the case of vegetable oil, from crop to crop, or from variety of vegetable oil source to variety of vegetable oil source.
  • DEQA's which are prepared using fatty acids derived from natural sources are preferred.
  • a preferred embodiment of the present invention provides softener actives comprising R! units which have at least about 3%, preferably at least about 5%>, more preferably at least about 10%>, most preferably at least about 15% C ⁇ 1 -C22 alkenyl, including polyalkenyl (polyunsaturated) units inter alia oleic, hnoleic, lmolemc.
  • the term "mixed chain fatty acyl units” is defined as "a mixture of fatty acyl units comp ⁇ smg alkyl and alkenyl chains having from 10 carbons to 22 carbon atoms including the carbonyl carbon atom, and in the case of alkenyl chains, from one to three double bonds, preferably all double bonds in the cis configuration".
  • R! units of the present invention it is preferred that at least a substantial percentage of the fatty acyl groups are unsaturated, e.g., from about 25%, preferably from about 50% to about 70%, preferably to about 65%.
  • the total level of fabric softening active containing polyunsaturated fatty acyl groups can be from about 3%, preferably from about 5%, more preferably from about 10%> to about 30%, preferably to about 25%, more preferably to about 18%.
  • cis and trans isomers can be used, preferably with a cisl trans ratio is of from 1: 1, preferably at least 3: 1, and more preferably from about 4: 1 to about 50: 1, more preferably about 20:1, however, the minimum being 1 :1.
  • the level of unsaturation contained withm the tallow, canola, or other fatty acyl unit chain can be measured by the Iodine Value (IV) of the corresponding fatty acid, which in the present case should preferably be m the range of from 5 to 100 with two categories of compounds being distinguished, having a IV below or above 25. Indeed, for compounds having the formula:
  • the R! units suitable for use in the lsotropic liquids present invention can be further characterized m that the Iodine Value (IV) of the parent fatty acid, said IV is preferably from about 10, more preferably from about 50, most preferably from about 70, to a value of about 140, preferably to about 130, more preferably to about 115.
  • formulators may wish to add an amount of fatty acyl units which have Iodine Values outside the range listed herein above. For example, "hardened stock" (IV less than or equal to about 10) may be combined with the source of fatty acid admixture to adjust the properties of the final softener active.
  • a prefered source of fatty acyl units especially fatty acyl units having branching, for example, "Guerbet branching", methyl, ethyl, etc. units substituted along the primary alkyl chain
  • synthetic sources of fatty acyl units are also suitable.
  • the formulator may with to add one or more fatty acyl units having a methyl branch at a "non-naturally occuring" position, for example, at the third carbon of a C ⁇ chain.
  • acyl units whihc are not found in significant (greater than about 0.1%) quantities is common fats and oils which serve as feedstocks for the source of triglycerides described herein.” If the desired branched chain fatty acyl unit is unavailable from readily available natural feedstocks, therefore, synthetic fatty acid can be suitably admixed with other synthetic materials or with other natural triglyceride derived sources of acyl units.
  • synthetic fatty acid can be suitably admixed with other synthetic materials or with other natural triglyceride derived sources of acyl units.
  • the following are examples of preferred softener actives according to the present invention.
  • N,N-di(tallowoyl-oxy-ethyl)-N,N-dimethyl ammonium chloride where the tallow chains are at least partially unsaturated and N,N-di(canoloyl-oxy-ethyl)-N,N- dimethyl ammonium chloride, N,N-di(tallowyl-oxy-ethyl)-N-methyl, N-(2-hydroxyethyl) ammonium methyl sulfate; N,N-di(canolyl-oxy-ethyl)-N-methyl, N-(2-hydroxyethyl) ammonium methyl sulfate; and mixtures thereof.
  • compositions of the present invention may also optionally comprise a principal solvent.
  • the level of principal solvent present in the compositions of the present invention is typically less than about 95%, preferably less than about 50%), more preferably less than about 25%, most preferably less than about 15% by weight.
  • Some embodiments of isotropic liquid embodiments of the present invention may comprise no principal solvent but may substitute instead a suitable nonionic surfactant.
  • the principal solvents of the present invention are primarily used to obtain liquid compositions having sufficient clarity and viscosity. Principal solvents must also be selected to minmize solvent odor impact in the composition. For example, isopropyl alcohol is not an effective principal solvent in that it does not serve to produce a composition having suitable viscosity. Isopropanol also fails as a suitable principal solvent because it has a relatively strong odor.
  • Principal solvents are also selected for their ability to provide stable compositions at low temperatures, preferably compositions comprising suitable principal solvents are clear down to about 4° C and have the ability to fully recover their clarity if stored as low as about 7° C.
  • the principal solvents according to the present invention are selected base upon their octanol/water partition coefficient (P).
  • P octanol/water partition coefficient
  • the octanol/water partition coefficient is a measure of the ratio of the concentrations of a particular principal solvent in octanol and water at equilibrium.
  • the partition coefficients are conveniently expressed and reported as their logarithm to the base 10; logP.
  • logP logP
  • ClogP The "calculated logP” (ClogP) is determined by the fragment approach of Hansch and Leo ( cfi, A. Leo, in Comprehensive Medicinal Chemistry, Vol. 4, C. Hansch, P. G. Sammens, J. B. Taylor and C. A. Ransden, Eds., p. 295, Pergamon Press, 1990, inco ⁇ orated herein by reference). The fragment approach is based on the chemical structure of each HR species, and takes into account the numbers and types of atoms, the atom connectivity, and chemical bonding.
  • ClogP values are the most reliable and widely used estimates for octanol water partitioning. It will be understood by those skilled in the art that experimental log P values could also be used. Experimental log P values represent a less preferred embodiment of the invention. Where experimental log P values are used, the one hour log P values are preferred. Other methods that can be used to compute ClogP include, e.g., Crippen's fragmentation method as disclosed in J. Chem. Inf. Comput. Sci., 27a,21 (1987); Viswanadhan's fragmentation method as disclosed in J. Chem. Inf. Comput. Sci., 29, 163 (1989); and Broto's method as disclosed in Eur. J. Med. Chem. - Chim. Theor., 19, 71 (1984).
  • the principal solvents suitable for use in the present invention are selected from those having a ClogP of from about 0.15 to about 1, preferably from about 0.15 to about 0.64, more preferably from about 0.25 to about 0.62, most preferably form about 0.4 to about 0.6.
  • the principal solvent is at least to some degree an asymmetric molecule, preferably having a melting, or solidification point which allows the principal solvent to be liquid at or near room temperature.
  • Low molecular weight principal solvents may be desirable for some embodiments. More preferred molecules are highly asymmetrical.
  • a preferred composition of the present invention comprises from about 0.1%, preferably from about 5%, more preferably form about 10% to about 80%, preferably to about 50%, more preferably to about 25% by weight, of a hydrophobic polyamine dispersant having the formula:
  • R, R 1 and B are suitably described in U.S. 5,565,145 Watson et al., issued October 15, 1996 inco ⁇ orated herein by reference, and w, x, and y have values which provide for a backbone prior to substitution of preferably at least about 1200 daltons, more preferably 1800 daltons.
  • R 1 units are preferably alkyleneoxy units having the formula:
  • the fabric softening embodiments of the compositions of the present invention may also optionally, but preferably comprise, one or more electrolytes for control of phase stability, viscosity, and/or clarity.
  • electrolytes inter alia calcium chloride, magnesium chloride may be key to insuring initial product clarity and low viscosity, or may affect the dilution viscosity of liquid embodiments, especially isotropic liquid embodiments.
  • the formulator must insure proper dilution viscosity, includes the following example.
  • Isotropic or non-isotropic liquid fabric softener compositions can be introduced into the rinse phase of laundry operations via an article of manufacture designed to dispense a measured amount of said composition.
  • the article of manufacture is a dispenser which delivers the softener active only during the rinse cycle.
  • These dispensers are typically designed to allow an amount of water equal to the volume of softener composition to enter into the dispenser to insure complete delivery of the softener composition.
  • An electrolyte may be added to the compositions of the present invention to insure phase stability and prevent the diluted softener composition from "gelling out” or from undergoing an undesirable or unacceptable viscosity increase. Prevention of gelling or formation of a "swelled", high viscosity solution insures thorough delivery of the softener composition.
  • the level of electrolyte is also influenced by other factors inter alia the type of fabric softener active, the amount of principal solvent, and the level and type of nonionic surfactant.
  • triethanol amine derived ester quaternary amines suitable for use as softener actives according to the present invention are typically manufactured in such a way as to yield a distribution of mono- , di-, and tri- esterified quaternary ammonium compounds and amine precursors. Therefore, as in this example, the variability in the distribution of mono-, di-, and tri- esters and amines may predicate a different level of electrolyte.
  • ionizable salts can be used.
  • suitable salts are the halides of the Group IA and IIA metals of the Periodic Table of the elements, e.g., calcium chloride, sodium chloride, potassium bromide, and lithium chloride.
  • the ionizable salts are particularly useful during the process of mixing the ingredients to make the compositions herein, and later to obtain the desired viscosity.
  • the amount of ionizable salts used depends on the amount of active ingredients used in the compositions and can be adjusted according to the desires of the formulator. Typical levels of salts used to control the composition viscosity are from about 20 to about 10,000 parts per million (ppm), preferably from about 20 to about 5,000 ppm, of the composition.
  • Alkylene polyammonium salts can be inco ⁇ orated into the composition to give viscosity control in addition to or in place of the water-soluble, ionizable salts above, In addition, these agents can act as scavengers, forming ion pairs with anionic detergent carried over from the main wash, in the rinse, and on the fabrics, and can improve softness performance. These agents can stabilized the viscosity over a broader range of temperature, especially at low temperatures, compared to the inorganic electrolytes. Specific examples of alkylene polyammonium salts include L-lysine, monohydrochloride and 1,5-diammonium 2-methyl pentane dihydrochloride. Cationic Charge Boosters
  • compositions or the present invention may optionally comprise one or more cationic charge boosters, especially to the rinse-added fabric softening embodiments of the present invention.
  • ethanol is used to prepare many of the below listed ingredients and is therefore a source of solvent into the final product formulation.
  • the formulator is not limited to ethanol, but instead can add other solvents inter alia hexyleneglycol to aid in formulation of the final composition. This is especially true in clear, translucent, isotropic compositions.
  • An optional composition of the present invention comprises at least about 0.2% > , preferably from about 0.2% to about 10%, more preferably from about 0.2% to about 5% by weight, of a cationic charge booster having the formula:
  • Rl, R 2 , R3, and R ⁇ are each independently C1 -C22 alkyl, C3-C22 alkenyl, R ⁇ -Q- (CH2) m -, wherein R ⁇ is Ci -C22 alkyl, and mixtures thereof, m is from 1 to about 6; X is an anion.
  • R* is C6-C22 alkyl, Cg-C22 alkenyl, and mixtures thereof, more preferably Ci 1 -Ci g alkyl, Ci 1 -Ci g alkenyl, and mixtures thereof;
  • R2, R3 S and R ⁇ are each preferably Ci - C4 alkyl, more preferably each R 2 , R , and R ⁇ are methyl.
  • the formulator may similarly choose R 1 to be a R ⁇ -Q-(CH2) m - moiety wherein R$ is an alkyl or alkenyl moiety having from 1 to 22 carbon atoms, preferably the alkyl or alkenyl moiety when taken together with the Q unit is an acyl unit derived preferably derived from a source of triglyceride selected from the group consisting of tallow, partially hydrogenated tallow, lard, partially hydrogenated lard, vegetable oils and/or partially hydrogenated vegetable oils, such as, canola oil, safflower oil, peanut oil, sunflower oil, corn oil, soybean oil, tall oil, rice bran oil, etc. and mixtures thereof.
  • An example of a fabric softener cationic booster comprising a R ⁇ -Q-(CH2) m - moiety has the formula: wherein R -Q- is an oleoyl units and m is equal to 2.
  • X is a softener compatible anion, preferably the anion of a strong acid, for example, chloride, bromide, methylsulfate, ethylsulfate, sulfate, nitrate and mixtures thereof, more preferably chloride and methyl sulfate.
  • a strong acid for example, chloride, bromide, methylsulfate, ethylsulfate, sulfate, nitrate and mixtures thereof, more preferably chloride and methyl sulfate.
  • a preferred embodiment of the present invention contains at least about 0.2%, preferably from about 0.2% to about 5%, more preferably from about 0.2% to about 2% by weight, of one or more polyvinyl amines having the formula
  • y is from about 3 to about 10,000, preferably from about 10 to about 5,000, more preferably from about 20 to about 500.
  • Polyvinyl amines suitable for use in the present invention are available from BASF.
  • one or more of the polyvinyl amine backbone -NH2 unit hydrogens can be substituted by an alkyleneoxy unit having the formula:
  • RlO (RlO) x R2 wherein Rl is C2-C4 alkylene, R 2 is hydrogen, Ci -C4 alkyl, and mixtures thereof; x is from 1 to 50.
  • the polyvinyl amine is reacted first with a substrate which places a 2-propyleneoxy unit directly on the nitrogen followed by reaction of one or more moles of ethylene oxide to form a unit having the general formula:
  • a preferred composition of the present invention comprises at least about 0.2%, preferably from about 0.2% to about 10%, more preferably from about 0.2% to about 5% by weight, of a cationic charge booster having the formula:
  • R is substituted or unsubstituted C2-C12 alkylene, substituted or unsubstituted C2-C12 hydroxyalkylene; each R* is independently Ci -C4 alkyl, each R 2 is independently C1-C22 alkyl, C3-C22 alkenyl, R ⁇ -Q-(CH2) m -, wherein R ⁇ is Ci -C22 alkyl, C3-C22 alkenyl, and mixtures thereof; m is from 1 to about 6; Q is a carbonyl unit as defined hereinabove; and mixtures thereof; X is an anion.
  • R is ethylene; Rl is methyl or ethyl, more preferably methyl; at least one R 2 is preferably Ci -C4 alkyl, more preferably methyl. Preferably at least one R 2 is Ci 1 -C22 alkyl, Cj 1 -C22 alkenyl, and mixtures thereof.
  • the formulator may similarly choose R 2 to be a R ⁇ -Q-(CH2) m - moiety wherein R ⁇ is an alkyl moiety having from 1 to 22 carbon atoms, preferably the alkyl moiety when taken together with the Q unit is an acyl unit derived preferably derived from a source of triglyceride selected from the group consisting of tallow, partially hydrogenated tallow, lard, partially hydrogenated lard, vegetable oils and/or partially hydrogenated vegetable oils, such as, canola oil, safflower oil, peanut oil, sunflower oil, corn oil, soybean oil, tall oil, rice bran oil, etc. and mixtures thereof.
  • R ⁇ is an alkyl moiety having from 1 to 22 carbon atoms, preferably the alkyl moiety when taken together with the Q unit is an acyl unit derived preferably derived from a source of triglyceride selected from the group consisting of tallow, partially hydrogenated tallow, lard, partially hydrogenated l
  • An example of a fabric softener cationic booster comprising a R ⁇ -Q-(CH2) m - moiety has the formula: where in R is methyl, one R 2 units is methyl and the other R 2 unit is R ⁇ -Q-(CH2) m - wherein R ⁇ -Q- is an oleoyl unit and m is equal to 2.
  • X is a softener compatible anion, preferably the anion of a strong acid, for example, chloride, bromide, methylsulfate, ethylsulfate, sulfate, nitrate and mixtures thereof, more preferably chlo ⁇ de and methyl sulfate.
  • a strong acid for example, chloride, bromide, methylsulfate, ethylsulfate, sulfate, nitrate and mixtures thereof, more preferably chlo ⁇ de and methyl sulfate.
  • compositions containing both saturated and unsaturated diester quaternary ammonium compounds can be prepared that are stable without the addition of concentration aids.
  • the compositions of the present invention may require organic and/or inorganic concentration aids to go to even higher concentrations and/or to meet higher stability standards depending on the other ingredients
  • concentration aids which typically can be viscosity modifiers may be needed, or preferred, for ensuring stability under extreme conditions when particular softener active levels are used.
  • the surfactant concentration aids are typically selected from the group consisting of (1) single long chain alkyl cationic surfactants; (2) nonionic surfactants, (3) amine oxides, (4) fatty acids; and (5) mixtures thereof.
  • Preferred dispersibihty aids are GENAMINE ® and GENAPOL ® ex Cla ⁇ ant
  • a preferred embodiment comprises both a cocoyl ethoxylated amine and a cocoyl ethoxylated alcohol, wherein the ethoxylation is approximately 10, each of which are available as GENAMINE ® and GENAPOL ® .
  • a preferred example of the use of this admixture is a composition which compnes, for example, 0.2% GENAMINE ® and 0.1% GENAPOL ® .
  • the total level is from 0.1%, preferably from
  • compositions 0.3%, more preferably from 3%, even more preferably from 4%, and most preferably from 5% to 25%, preferably to 17%, more preferably to 15%, most preferably to 13% by weight, of the composition.
  • These materials can either be added as part of the active softener raw material, e.g., the mono-long chain alkyl cationic surfactant and/or the fatty acid which are reactants used to form the fab ⁇ c softener active as discussed hereinbefore, or added as a separate component.
  • the total level of dispersibihty aid includes any amount that may be present as part of the softener active.
  • certain soil release agents provide not only the below described soil release properties but are added for their suitability in maintaining proper viscosity, especially in the dispersed phase, non-isotropic compositions.
  • Polymeric soil release agents are characterized by having both hydrophilic segments, to hydrophilize the surface of hydrophobic fibers, such as polyester and nylon, and hydrophobic segments, to deposit upon hydrophobic fibers and remain adhered thereto through completion of the rinsing cycle and, thus, serve as an anchor for the hydrophilic segments. This can enable stains occurring subsequent to treatment with the soil release agent to be more easily cleaned in later washing procedures.
  • soil release agents will generally comprise from about 0.01% to about 10.0%, by weight, of the detergent compositions herein, typically from about 0.1% to about 5%, preferably from about 0.2% to about 3.0%.
  • compositions of the present invention optionally comprise from about 0.01%, preferably from about 0.75%, more preferably from 10%, most preferably from about 15% to about 50%, preferably to about 35%, more preferably to about 30%, most preferably to about 5% by weight, of one or more linear or cyclic polyamines which provide bleach protection.
  • Linear Polyamines which provide bleach protection.
  • the bleach protection polyamines of the present invention have the formula:
  • R 1 is hydrogen or an alkyleneoxy unit having the formula:
  • R 3 is ethylene, 1 ,2-propylene, 1 ,2-butylene, or mixtures thereof; preferably R 3 is ethylene or 1 ,2-propylene, more preferably 1,2-propylene.
  • R 4 is hydrogen, C,-C 4 alkyl, and mixtures thereof; preferably hydrogen.
  • R 1 may comprise any mixture of alkyleneoxy units.
  • R 2 is hydrogen, R 1 , -RN(R') 2 , and mixtures thereof; preferably at least one R 2 is hydrogen when n is equal to 2. The integer n is 1 or 2.
  • a prefered bleach protection linear polyamine has a backbone wherein R is 1,3- propylene, R 2 is hydrogen, or alkoxy, and n is equal to 2 is N,N'-bis(3-aminopropyl)-l,3- propylenediamine (TPTA).
  • Cyclic Amines The bleach protection cyclic polyamines of the present invention comprise polyamine backbones having the formula:
  • L is a linking unit, said linking unit comprising a ring having at least 2 nitrogen atoms;
  • R is hydrogen, -(CH 2 ) k N(R 1 ) 2 , and mixtures thereof; wherein each index k independently has the value from 2 to 4, preferably 3.
  • the backbone of the cyclic amines including R units is 200 daltons or less.
  • R 1 is hydrogen or an alkyleneoxy unit having the formula:
  • R 3 is ethylene, 1,2-propylene, 1 ,2-butylene, or mixtures thereof; preferably R 3 is ethylene or 1,2-propylene, more preferably 1,2-propylene.
  • R 4 is hydrogen, C,-C 4 alkyl, and mixtures thereof; preferably hydrogen.
  • R 1 may comprise any mixture of alkyleneoxy units. Examples of preferred optional polyamines of the present invention have the formula:
  • the present invention also relates to a method for enhancing the fabric integrity inter alia dye fidelity while reducing the damage to fabric due to the interaction of laundry adjunct ingredients and damage due to mechanical wear.
  • the method includes the step of contacting fabric with an aqueous solution containing a least 50 ppm, preferably at least about 100 ppm, more preferably at least about 200 ppm, said composition comprising: a) from about 0.01% by weight, of a polyamido compound having the formula:
  • PA is a grafted or non-grafted polyamine backbone unit
  • B is a unit which serves to crosslink two or more PA units to form a (PA) W (B) X polyamido crosslinked section
  • L is a unit which serves to crosslink two or more (PA) W (B) X units
  • w and x have values such that the ratio of w to x is from 0.8 : 1 to 1.4 : 1
  • y and z have values such that said polyamido compound comprises from about 0.3 to 2 parts by weight of said L unit
  • b) from about 1% to about 80% by weight, of a fabric softening active
  • the balance carriers and adjunct ingredients are examples of the balance carriers and adjunct ingredients.
  • contacting is defined as "intimate contact of a fabric with an aqueous solution of the hereinabove described composition which comprises a fabric abrasion reducing polymer.”
  • Contacting typically occurs by soaking, washing, rinsing, spraying the composition onto fabric, but can also include contact of a substrate inter alia a material onto which the composition has been absorbed, with the fabric.
  • Laundering is a preferred process. Temperatures for laundering can take place at a variety of temperatures, however, laundering typically occurs at a temperature less than about 30° C, preferably from about 5° C to about 25° C.
  • rinse-added fabric enhancement compositions of the present invention which comprise one or more high molecular weight polyalkyleneimine, said compositions providing fabric benefits inter alia enhanced color fidelity, reduced fabric abrasion.
  • a preferred composition comprises: a) from about 0.01%, preferably from about 0.1%, more preferably from 0.25%, most preferably from about 0.5% to about 20%, preferably to about 10%, more preferably to about 5%> by weight, of the herein described high molecular weight polyalkyleneimmes; b) from about 1%, preferably from about 10%, more preferably from about 20% to about 80%, preferably to about 60%, more preferably to about 45% by weight, of a fabric softening active; c) from about 0.1%, preferably from about 0.5% to about 50%, preferably to about
  • a further preferred example of a laundry detergent composition according to the present invention comprises: a) from about 0.01 %>, preferably from about 0.1 %, more preferably from 0.25%, most preferably from about 0.5% to about 20%, preferably to about 10%, more preferably to about 5% by weight, of the herein described high molecular weight polyalkyleneimmes; b) from about 1%>, preferably from about 10%, more preferably from about 20% to about 80%, preferably to about 60%, more preferably to about 45% by weight, of a fabric softening active; c) from about 1%, preferably from about 5% to about 30%, preferably to about 20% by weight, of a bleaching system, said bleaching system comprising: i) from about 25%, preferably from about 50%>, more preferably from about 75%, to about 99.95%, preferably to about 95% by weight, a source of hydrogen peroxide; ii) from about 0.05%, preferably from about 2.5%, more preferably from about 5% to about 75%
  • the present invention also relates to a method for enhancing the color fidelity of fabric while reducing the damage to fabric due to the interaction of laundry adjunct ingredients and damage due to mechanical wear.
  • the method includes the step of contacting fabric with an aqueous solution containing a least 50 ppm, preferably at least about 100 ppm, more preferably at least about 200 ppm, of a composition which comprises laundry detergent composition which comprises: a) from about 0.01 %>, preferably from about 0.1 %, more preferably from 0.25%, most preferably from about 0.5% to about 20%, preferably to about 10%, more preferably to about 5% by weight, of the herein described high molecular weight polyalkyleneimmes; b) from about 1%, preferably from about 10%, more preferably from about 20% to about 80%, preferably to about 60%>, more preferably to about 45% by weight, of a fabric softening active; and c) the balance carriers and adjunct ingredients.
  • compositions illustrate the present invention.
  • Minors can include perfume, dye, acid, preservatives, etc.
  • N,N'-bis(2-hydroxybutyl)-N,N'-bis[3-N,N-bis(2-hydroxybutyl)aminopropyl]-l,3- propylenediamine which is N,N'-bis(3-aminopropyl)-l,3-propylenediamine wherein each hydrogen of the backbone is replaced by a 2-hydroxybutyl moiety.
  • compositions which prevent the fading of dye from fabric, especially cotton fabric are included in the following examples.
  • Polyalkyleneimine having a molecular weight of 1800 and an average ethoxylation per backbone nitrogen of approximately 1.
  • Polyalkyleneimine having a molecular weight of 1800 and an average ethoxylation per backbone nitrogen of approximately 7.
  • Suitable enzymes include cellulase, lipase, protease, peroxidase, and mixtures thereof.

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  • Oil, Petroleum & Natural Gas (AREA)
  • Wood Science & Technology (AREA)
  • Organic Chemistry (AREA)
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Abstract

L'invention concerne des compositions de traitement de textiles comprenant: a) environ 0,01 % en poids d'une polyalkylène-imine correspondant à la formule (I) dans laquelle R représente alkylène linéaire C2-C4, alkylène ramifié C3-C4 ainsi que des mélanges de ceux-ci, B représente une continuation de la polyalkylène-amine, par branchement, w est égal à y+1, x représente un nombre entier compris entre environ 50 et environ 2500, y représente un nombre entier compris entre environ 20 et environ 1000; b) environ 1 à environ 80 % en poids d'un agent adoucissant de textiles et c) le solde étant composé d'excipients et d'ingrédients d'adjonction. Ces compositions dotent des textiles colorés d'une certaine protection contre les effets nocifs de l'usure mécanique et de l'exposition à des ingrédients de lavage ajoutés, entre autres, des matériaux de blanchiment ou des matériaux se diluant dans l'eau, entre autres des ions métalliques lourds.
PCT/US2000/003941 1999-02-19 2000-02-16 Compositions d'amelioration de l'aspect de textiles, comprenant des polyamines de haut poids moleculaire WO2000049123A1 (fr)

Priority Applications (1)

Application Number Priority Date Filing Date Title
AU29969/00A AU2996900A (en) 1999-02-19 2000-02-16 Fabric enhancement compositions comprising high molecular weight polyamines

Applications Claiming Priority (2)

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US12094299P 1999-02-19 1999-02-19
US60/120,942 1999-02-19

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WO2000049123A1 true WO2000049123A1 (fr) 2000-08-24

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PCT/US2000/003941 WO2000049123A1 (fr) 1999-02-19 2000-02-16 Compositions d'amelioration de l'aspect de textiles, comprenant des polyamines de haut poids moleculaire

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AR (1) AR022631A1 (fr)
AU (1) AU2996900A (fr)
WO (1) WO2000049123A1 (fr)

Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0043622A1 (fr) * 1980-01-07 1982-01-13 THE PROCTER & GAMBLE COMPANY Composition d'adoucissement pour matières textiles

Patent Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0043622A1 (fr) * 1980-01-07 1982-01-13 THE PROCTER & GAMBLE COMPANY Composition d'adoucissement pour matières textiles

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AR022631A1 (es) 2002-09-04
AU2996900A (en) 2000-09-04

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