WO2000025999A1 - Method and arrangement for the continuous production of lignocellulose-containing boards - Google Patents

Method and arrangement for the continuous production of lignocellulose-containing boards Download PDF

Info

Publication number
WO2000025999A1
WO2000025999A1 PCT/SE1999/001964 SE9901964W WO0025999A1 WO 2000025999 A1 WO2000025999 A1 WO 2000025999A1 SE 9901964 W SE9901964 W SE 9901964W WO 0025999 A1 WO0025999 A1 WO 0025999A1
Authority
WO
WIPO (PCT)
Prior art keywords
steam
air
emissions
press
unit
Prior art date
Application number
PCT/SE1999/001964
Other languages
French (fr)
Inventor
Göran Lundgren
Olof Melander
Kurt Schedin
Original Assignee
Valmet Fibertech Ab
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Valmet Fibertech Ab filed Critical Valmet Fibertech Ab
Priority to KR1020017005412A priority Critical patent/KR20010080924A/en
Priority to AU14327/00A priority patent/AU1432700A/en
Priority to JP2000579418A priority patent/JP2002528304A/en
Priority to CA002347678A priority patent/CA2347678A1/en
Priority to EP99971372A priority patent/EP1178879A1/en
Priority to PL99347900A priority patent/PL347900A1/en
Priority to NZ511558A priority patent/NZ511558A/en
Publication of WO2000025999A1 publication Critical patent/WO2000025999A1/en
Priority to NO20012136A priority patent/NO20012136L/en

Links

Classifications

    • BPERFORMING OPERATIONS; TRANSPORTING
    • B27WORKING OR PRESERVING WOOD OR SIMILAR MATERIAL; NAILING OR STAPLING MACHINES IN GENERAL
    • B27NMANUFACTURE BY DRY PROCESSES OF ARTICLES, WITH OR WITHOUT ORGANIC BINDING AGENTS, MADE FROM PARTICLES OR FIBRES CONSISTING OF WOOD OR OTHER LIGNOCELLULOSIC OR LIKE ORGANIC MATERIAL
    • B27N3/00Manufacture of substantially flat articles, e.g. boards, from particles or fibres
    • B27N3/08Moulding or pressing
    • B27N3/24Moulding or pressing characterised by using continuously acting presses having endless belts or chains moved within the compression zone

Definitions

  • the present invention relates to a method of producing continuously ligno- cellulosic boards in accordance with the preamble of claim 1 , and to an arrangement for carrying out the method.
  • the manufacture of such boards includes the following main method steps: disintegration of the raw material to fibres and/or particles of appropriate size, drying the particles and/or fibres to a determined moisture ratio and gluing the material either prior to or subsequent to said drying process, shaping the glued material to form a mat, which may comprise several layers, and optionally cold pre-pressing the mat, pre-heat- ing said mat, water-spraying mat surfaces etc., and heat pressing the mat in a dis- continuous press or in a continuous press while subjecting the material simultaneously to pressure and heat so as to obtain a finished board.
  • a well-known problem with present day manufacturing technology irrespective of whether it involves discontinuous presses or continuous presses, is that gases are generated in the press during the compression process, which takes place at high temperatures. These gases consist of water vapour (steam), different volatile substances dissolved from wood and glue, so-called Volatile Organic Compounds (VOC), and gaseous phenol from wood and glue, etc. It has been found that long-time exposure to these substances results in irritation, and that they are also harmful to personal health when present in sufficiently high con- centrations. Consequently, the authorities in the majority of countries in which boards are manufactured in accordance with the aforesaid methods have elaborated a set of rules and regulations that state the emission concentrations that are permitted in work places and the permitted concentrations permitted in emissions to atmosphere.
  • VOC Volatile Organic Compounds
  • the object of the present invention is to provide a method and an arrangement for producing lignocellulosic boards without VOC-emissions or formaldehyde-emissions to the workshop areas concerned and to the ambient environment, and also obviating the need to install expensive purification equipment.
  • This object is achieved with a method and an arrangement according to the invention that have the characteristic features set forth in respective claims.
  • a fibrous mat 1 previously formed in the manufacturing process is compressed in a continuous steam-injection press 2 to form a board or sheet 3, which is then passed through an after-conditioning unit 4.
  • steam is delivered and injected into the mat through wires 6.
  • the temperature rises very quickly to above 100°C; a typical temperature is above 120°C.
  • the mat is herewith formed into a solid board 3.
  • the pressure falls as the board leaves the nip between the steam-injection rolls 5, and the temperature therewith drops very quickly to about 100°C. This takes place by virtue of the extremely rapid vaporisation of part of the enclosed moisture.
  • VOC- emissions and formaldehyde-emissions accompany the departing steam. Because this process takes place between two gas-permeable wires 6, the steam and the gases departing with the steam are able to leave the board a- cross the whole of its width. Steam and other emissions are captured before being able to escape into the workshop area or to ambient atmosphere, by a suction unit 8 provided to this end inside the press. Air heated to a temperature in excess of 100°C is transported to this suction unit. The hot air is used together with leakage air from the surroundings as a vehicle gas for the steam and said other emissions. The hot air, leakage air, steam and emissions are transported to a heating plant 9 in the factory, for combustion. A hot air delivery unit 11 is connected to a curing zone 10 in the press 2, and the hot air supplied is then passed to the suction unit 8.
  • the temperature is maintained at a high level partly to prevent the emissions and the steam from condensing out to the suction system and partly to utilize the fact that the moisture carrying capacity of the air, calculated per kilogram of air, increases with increasing temperatures. This enables the total air volumes and gas volumes to be maintained at levels which do not exceed the volumes of combustion air that are required by the standard plant system to generate the heat and process steam necessary for the production of such board material. Consequently, no other equipment need be installed to prevent emissions to the sur- roundings.
  • the board is passed into the after-conditioning unit 4 (see SE 504 638) where a pre-determined volume of air heated to a pre-determined temperature and having a pre-determined moisture content is sucked through the board so as to obtain a desired board moisture content and temperature.
  • the air leaving the after-conditioning unit will also contain emissions of VOC and formaldehyde, although in smaller quantities; measurements taken in a pilot plant have shown that the major part of the emissions occur in the continuous steam-injection press.
  • a suction unit 12 is arranged in the after-conditioning unit 4. Air is sucked in at 13 and heated by a heater 14 and is supplied with steam through the conduit 15.
  • the air leaving the after-conditioning unit is transported to the hot air supply unit 11 of the steam-injection press 2 and its curing zone 10, by means of a suction fan 16. As it passes to the supply unit 11 , the air is given additional energy through the medium of a heat exchanger 17. If the air from the after-conditioning unit 4 is in excess, the excess can be mixed with the flow from the press 2 in a closed hood 18 and passed to the heating plant 9. If there is a deficiency of air to the curing zone 10, the suction fan 16 draws-in extra air through the closed hood 18. The air leaving the after-conditioning unit 4 is thus used as hot input air for the internal suction unit 8 of the continuous steam-injection press. Measurements have shown that these volumes are sufficient to fulfil the requisite transport volumes needed for the continuous steam-injection press.
  • the board 3 may optionally also be passed through a surface-densifying press in accordance with SE 502 272 (not shown in the drawing).
  • This latter press also in- eludes a special suction unit that functions to capture in said press those emissions that are transported to the combustion plant of the factory with the aid of hot air, for the production of heat and steam.

Abstract

The present invention relates to a method and to an arrangement for the continuous production of lignocellulosic boards, wherein material is disintegrated into particles and/or fibres, glued, dried and formed into a mat (1). The mat is pressed in a continuous steam-injection press (2) into board form (3) and then passed through an after-conditioning unit (4). Gaseous emissions and steam occurrent in the press process are captured. Hot air is supplied to prevent condensation of the gaseous emissions and the steam when leakage air from the surroundings is admixed therewith and also to transport the steam and emissions to a combustion plant for combustion.

Description

METHOD AND ARRANGEMENT FOR THE CONTINUOUS PRODUCTION OF LIGNOCELLULOSE-CONTAINING BOARDS
The present invention relates to a method of producing continuously ligno- cellulosic boards in accordance with the preamble of claim 1 , and to an arrangement for carrying out the method.
Methods of producing boards from lignocellulose-based raw materials are well known to the art and have found wide use in practice. The manufacture of such boards includes the following main method steps: disintegration of the raw material to fibres and/or particles of appropriate size, drying the particles and/or fibres to a determined moisture ratio and gluing the material either prior to or subsequent to said drying process, shaping the glued material to form a mat, which may comprise several layers, and optionally cold pre-pressing the mat, pre-heat- ing said mat, water-spraying mat surfaces etc., and heat pressing the mat in a dis- continuous press or in a continuous press while subjecting the material simultaneously to pressure and heat so as to obtain a finished board.
A well-known problem with present day manufacturing technology, irrespective of whether it involves discontinuous presses or continuous presses, is that gases are generated in the press during the compression process, which takes place at high temperatures. These gases consist of water vapour (steam), different volatile substances dissolved from wood and glue, so-called Volatile Organic Compounds (VOC), and gaseous phenol from wood and glue, etc. It has been found that long-time exposure to these substances results in irritation, and that they are also harmful to personal health when present in sufficiently high con- centrations. Consequently, the authorities in the majority of countries in which boards are manufactured in accordance with the aforesaid methods have elaborated a set of rules and regulations that state the emission concentrations that are permitted in work places and the permitted concentrations permitted in emissions to atmosphere. Since present day press technology involves the use of homogenous heating plates or steel bands, only a minor part of the gases generated in press will leave the boards through their edges in the compression process. However, the major part of these gases will leave the board as it exits from the press. The influence of these gases on the working environment can be limited to some extent with the aid of protective casings and covers, although air at room temperature is normally used as transport air because of the large size of the presses. Consequently, this air volume will normally exceed the requirement of combustion air in the standard heating plant of the factory. This has necessitated the installation of complicated and expensive equipment in connection with the majority of plants in which lignocellulosic sheets and boards are produced. For instance, the plants will normally include so-called RTO (Regenerated Thermal Oxidizer) units or scrubber systems for purifying press gases.
The object of the present invention is to provide a method and an arrangement for producing lignocellulosic boards without VOC-emissions or formaldehyde-emissions to the workshop areas concerned and to the ambient environment, and also obviating the need to install expensive purification equipment. This object is achieved with a method and an arrangement according to the invention that have the characteristic features set forth in respective claims.
The invention will now be described in more detail with reference to the accompanying drawing, which is a schematic longitudinal section view of an arrangement in accordance with the invention. The plant illustrated in the drawing is based on the plants disclosed in SE
502 272 and SE 504 638, which describe two continuous steam-press processes. A fibrous mat 1 previously formed in the manufacturing process is compressed in a continuous steam-injection press 2 to form a board or sheet 3, which is then passed through an after-conditioning unit 4. As the fibre mat 1 passes into the nip between two steam-injection rolls 5, steam is delivered and injected into the mat through wires 6. The temperature rises very quickly to above 100°C; a typical temperature is above 120°C. The mat is herewith formed into a solid board 3. The pressure falls as the board leaves the nip between the steam-injection rolls 5, and the temperature therewith drops very quickly to about 100°C. This takes place by virtue of the extremely rapid vaporisation of part of the enclosed moisture. VOC- emissions and formaldehyde-emissions accompany the departing steam. Because this process takes place between two gas-permeable wires 6, the steam and the gases departing with the steam are able to leave the board a- cross the whole of its width. Steam and other emissions are captured before being able to escape into the workshop area or to ambient atmosphere, by a suction unit 8 provided to this end inside the press. Air heated to a temperature in excess of 100°C is transported to this suction unit. The hot air is used together with leakage air from the surroundings as a vehicle gas for the steam and said other emissions. The hot air, leakage air, steam and emissions are transported to a heating plant 9 in the factory, for combustion. A hot air delivery unit 11 is connected to a curing zone 10 in the press 2, and the hot air supplied is then passed to the suction unit 8.
The temperature is maintained at a high level partly to prevent the emissions and the steam from condensing out to the suction system and partly to utilize the fact that the moisture carrying capacity of the air, calculated per kilogram of air, increases with increasing temperatures. This enables the total air volumes and gas volumes to be maintained at levels which do not exceed the volumes of combustion air that are required by the standard plant system to generate the heat and process steam necessary for the production of such board material. Consequently, no other equipment need be installed to prevent emissions to the sur- roundings.
Subsequent to the board having been produced in the continuous steam injection press 2, the board is passed into the after-conditioning unit 4 (see SE 504 638) where a pre-determined volume of air heated to a pre-determined temperature and having a pre-determined moisture content is sucked through the board so as to obtain a desired board moisture content and temperature. The air leaving the after-conditioning unit will also contain emissions of VOC and formaldehyde, although in smaller quantities; measurements taken in a pilot plant have shown that the major part of the emissions occur in the continuous steam-injection press. For this purpose, a suction unit 12 is arranged in the after-conditioning unit 4. Air is sucked in at 13 and heated by a heater 14 and is supplied with steam through the conduit 15. The air leaving the after-conditioning unit is transported to the hot air supply unit 11 of the steam-injection press 2 and its curing zone 10, by means of a suction fan 16. As it passes to the supply unit 11 , the air is given additional energy through the medium of a heat exchanger 17. If the air from the after-conditioning unit 4 is in excess, the excess can be mixed with the flow from the press 2 in a closed hood 18 and passed to the heating plant 9. If there is a deficiency of air to the curing zone 10, the suction fan 16 draws-in extra air through the closed hood 18. The air leaving the after-conditioning unit 4 is thus used as hot input air for the internal suction unit 8 of the continuous steam-injection press. Measurements have shown that these volumes are sufficient to fulfil the requisite transport volumes needed for the continuous steam-injection press.
Subsequent to having passed through the after-conditioning unit 4, the board 3 may optionally also be passed through a surface-densifying press in accordance with SE 502 272 (not shown in the drawing). This latter press also in- eludes a special suction unit that functions to capture in said press those emissions that are transported to the combustion plant of the factory with the aid of hot air, for the production of heat and steam.

Claims

1. A method for the continuous production of lignocellulosic boards, in which the material is disintegrated into particle and/or fibre form, glued, dried and formed into a mat (1) which is compressed in a continuous steam-injection press (2) into board form (3) and the board is thereafter passed through an after-conditioning unit (4), characterized by capturing steam and gaseous emissions generated in the press process, and supplying hot air to said process for the purpose of preventing condensation of the gaseous emissions and said steam when admixing said emissions and steam with leakage air from the surroundings and also to prevent condensation of said leakage air from the surroundings, and for transporting the emissions to a combustion plant (9) for combustion.
2. A method according to claim 1 , characterized in that the hot air and the leakage air from the surroundings are supplied in an amount which is at most equal to the amount of combustion air required by the heating plant (9).
3. A method according to claim 1 or 2, characterized by supplying to a curing zone (10) in the press (2) air that has a temperature in excess of 100°C.
4. A method according to any one of claims 1-3, characterized by supplying energy to the suction air from the after-conditioning unit (4) so that the temperature will exceed 100°C, and thereafter using the air as vehicle air for the transportation of emissions from the steam-injection press (2).
5. An arrangement for carrying out the method according to any one of claims 1-4, said arrangement including a continuos steam-injection press (2) and an after-conditioning unit (4), characterized by a suction unit (8) arranged in the steam-injection press (2) and functioning to capture gaseous emissions and steam and to transport said emissions and steam to a combustion plant (9), and further characterized by a unit (11) for supplying hot air to the suction unit (8).
6. An arrangement according to claim 5, characterized in that the hot air supply unit (11) is connected for air supply purposes to a suction unit (12) in the after-conditioning unit (4), and in that a heater (17) is connected to a transport conduit between said units.
PCT/SE1999/001964 1998-11-02 1999-11-01 Method and arrangement for the continuous production of lignocellulose-containing boards WO2000025999A1 (en)

Priority Applications (8)

Application Number Priority Date Filing Date Title
KR1020017005412A KR20010080924A (en) 1998-11-02 1999-11-01 Method and arrangement for the continuous production of lignocellulose-containing boards
AU14327/00A AU1432700A (en) 1998-11-02 1999-11-01 Method and arrangement for the continuous production of lignocellulose-containing boards
JP2000579418A JP2002528304A (en) 1998-11-02 1999-11-01 Method and apparatus for continuous production of lignocellulose-containing plates
CA002347678A CA2347678A1 (en) 1998-11-02 1999-11-01 Method and arrangement for the continuous production of lignocellulose-containing boards
EP99971372A EP1178879A1 (en) 1998-11-02 1999-11-01 Method and arrangement for the continuous production of lignocellulose-containing boards
PL99347900A PL347900A1 (en) 1998-11-02 1999-11-01 Method and arrangement for the continuous production of lignocellulose-containing boards
NZ511558A NZ511558A (en) 1998-11-02 1999-11-01 Method and arrangement for the continuous production of lignocellulose-containing boards, with gas emission and steam captured and hot air supplied to take mixture to combustion chamber
NO20012136A NO20012136L (en) 1998-11-02 2001-04-30 Process and apparatus for continuous plate production contain lignocellulose

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
SE9803741-9 1998-11-02
SE9803741A SE513105C2 (en) 1998-11-02 1998-11-02 Methods and apparatus for continuous production of lignocellulosic discs

Publications (1)

Publication Number Publication Date
WO2000025999A1 true WO2000025999A1 (en) 2000-05-11

Family

ID=20413150

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/SE1999/001964 WO2000025999A1 (en) 1998-11-02 1999-11-01 Method and arrangement for the continuous production of lignocellulose-containing boards

Country Status (12)

Country Link
EP (1) EP1178879A1 (en)
JP (1) JP2002528304A (en)
KR (1) KR20010080924A (en)
CN (1) CN1094414C (en)
AU (1) AU1432700A (en)
CA (1) CA2347678A1 (en)
CZ (1) CZ20011475A3 (en)
NO (1) NO20012136L (en)
NZ (1) NZ511558A (en)
PL (1) PL347900A1 (en)
SE (1) SE513105C2 (en)
WO (1) WO2000025999A1 (en)

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE10361837B4 (en) * 2003-10-10 2009-09-03 Walter, Karl, Dr. Apparatus and method for the continuous production of slabs, beams, profiles or the like from mats of chips and / or fibers
WO2014195445A1 (en) * 2013-06-07 2014-12-11 Dieffenbacher GmbH Maschinen- und Anlagenbau Press for producing boards of material and method for operating such a press

Families Citing this family (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101646536B (en) * 2007-01-17 2013-03-06 株式会社伊藤园 Method for producing wooden board

Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
SE502272C2 (en) * 1994-01-28 1995-09-25 Sunds Defibrator Ind Ab Process for making lignocellulosic discs

Patent Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
SE502272C2 (en) * 1994-01-28 1995-09-25 Sunds Defibrator Ind Ab Process for making lignocellulosic discs

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE10361837B4 (en) * 2003-10-10 2009-09-03 Walter, Karl, Dr. Apparatus and method for the continuous production of slabs, beams, profiles or the like from mats of chips and / or fibers
WO2014195445A1 (en) * 2013-06-07 2014-12-11 Dieffenbacher GmbH Maschinen- und Anlagenbau Press for producing boards of material and method for operating such a press

Also Published As

Publication number Publication date
AU1432700A (en) 2000-05-22
CA2347678A1 (en) 2000-05-11
SE9803741L (en) 2000-05-03
EP1178879A1 (en) 2002-02-13
CZ20011475A3 (en) 2001-10-17
SE513105C2 (en) 2000-07-10
PL347900A1 (en) 2002-04-22
CN1325336A (en) 2001-12-05
NZ511558A (en) 2003-01-31
CN1094414C (en) 2002-11-20
NO20012136D0 (en) 2001-04-30
JP2002528304A (en) 2002-09-03
SE9803741D0 (en) 1998-11-02
NO20012136L (en) 2001-07-02
KR20010080924A (en) 2001-08-25

Similar Documents

Publication Publication Date Title
US6605245B1 (en) Apparatus and method for continuous formation of composites having filler and thermoactive materials
RU2068339C1 (en) Device and method for continuous manufacture of wood particle boards
CA2153280C (en) Preheating particles in manufacture of pressed board
CA2735682C (en) Method of making wood-fiber insulating boards
US20010024727A1 (en) Apparatus and method for continuous formation of composites having filler and thermoactive materials, and products made by the method
RU98100438A (en) METHOD FOR PRODUCING THERMOACTIVE BINDING COMPOSITE
EP1202860A1 (en) Composites having filler and thermoactive materials
JP2655708B2 (en) Method and apparatus for producing fiberboard sheets
EP1178879A1 (en) Method and arrangement for the continuous production of lignocellulose-containing boards
US20030136280A1 (en) Modified high-temperature pressing apparatus
US4218832A (en) Apparatus for processing wood products using heat from a boiler for indirectly heating drying gas
JP3650622B2 (en) Board manufacturing equipment
US6328843B1 (en) Method for producing boards made of wood-based material and synthetic boards in a continuously operating press
EP0819043B1 (en) Method of manufacturing lignocellulosic board
US5989465A (en) Method of manufacturing a board
US5989468A (en) Method of continuous production of lignocellulosic boards
DE60029010T2 (en) METHOD FOR DRYING LIGNOCELLULOSE-CONTAINING MATERIAL
WO1995000304A1 (en) Process for manufacturing building panels or other articles from plant matter and a production line for carrying out the said process
US3630456A (en) Method of manufacturing fiberboard
RU2046821C1 (en) Method of making fuel briquet from wood waste
CA2347935C (en) Method and system for recovering voc and hap emissions
RU2345186C2 (en) Method for production and processing of wood fibre and installation for its realisation
PL180929B1 (en) Method of making lignocellulose boards
US20020046655A1 (en) Method and system for recovering VOC emissions
WO2000044985A1 (en) Method and arrangement for the production of lignocellulose-containing boards

Legal Events

Date Code Title Description
WWE Wipo information: entry into national phase

Ref document number: 99812842.2

Country of ref document: CN

ENP Entry into the national phase

Ref document number: 2000 14327

Country of ref document: AU

Kind code of ref document: A

AK Designated states

Kind code of ref document: A1

Designated state(s): AE AL AM AT AT AU AZ BA BB BG BR BY CA CH CN CR CU CZ CZ DE DE DK DK DM EE EE ES FI FI GB GD GE GH GM HR HU ID IL IN IS JP KE KG KP KR KZ LC LK LR LS LT LU LV MA MD MG MK MN MW MX NO NZ PL PT RO RU SD SE SG SI SK SK SL TJ TM TR TT TZ UA UG US UZ VN YU ZA ZW

AL Designated countries for regional patents

Kind code of ref document: A1

Designated state(s): GH GM KE LS MW SD SL SZ TZ UG ZW AM AZ BY KG KZ MD RU TJ TM AT BE CH CY DE DK ES FI FR GB GR IE IT LU MC NL PT SE BF BJ CF CG CI CM GA GN GW ML MR NE SN TD TG

121 Ep: the epo has been informed by wipo that ep was designated in this application
DFPE Request for preliminary examination filed prior to expiration of 19th month from priority date (pct application filed before 20040101)
ENP Entry into the national phase

Ref document number: 2347678

Country of ref document: CA

Ref document number: 2347678

Country of ref document: CA

Kind code of ref document: A

WWE Wipo information: entry into national phase

Ref document number: PV2001-1475

Country of ref document: CZ

WWE Wipo information: entry into national phase

Ref document number: 1020017005412

Country of ref document: KR

ENP Entry into the national phase

Ref document number: 2000 579418

Country of ref document: JP

Kind code of ref document: A

WWE Wipo information: entry into national phase

Ref document number: 511558

Country of ref document: NZ

WWE Wipo information: entry into national phase

Ref document number: 1999971372

Country of ref document: EP

WWE Wipo information: entry into national phase

Ref document number: 09830864

Country of ref document: US

WWP Wipo information: published in national office

Ref document number: 1020017005412

Country of ref document: KR

REG Reference to national code

Ref country code: DE

Ref legal event code: 8642

WWP Wipo information: published in national office

Ref document number: PV2001-1475

Country of ref document: CZ

WWP Wipo information: published in national office

Ref document number: 1999971372

Country of ref document: EP

WWR Wipo information: refused in national office

Ref document number: PV2001-1475

Country of ref document: CZ

WWW Wipo information: withdrawn in national office

Ref document number: 1020017005412

Country of ref document: KR

WWW Wipo information: withdrawn in national office

Ref document number: 1999971372

Country of ref document: EP