WO2000021887A1 - Method of formulating alkali metal salts - Google Patents
Method of formulating alkali metal salts Download PDFInfo
- Publication number
- WO2000021887A1 WO2000021887A1 PCT/CA1999/000905 CA9900905W WO0021887A1 WO 2000021887 A1 WO2000021887 A1 WO 2000021887A1 CA 9900905 W CA9900905 W CA 9900905W WO 0021887 A1 WO0021887 A1 WO 0021887A1
- Authority
- WO
- WIPO (PCT)
- Prior art keywords
- liquor
- sulfate
- sodium bicarbonate
- set forth
- bicarbonate
- Prior art date
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01D—COMPOUNDS OF ALKALI METALS, i.e. LITHIUM, SODIUM, POTASSIUM, RUBIDIUM, CAESIUM, OR FRANCIUM
- C01D7/00—Carbonates of sodium, potassium or alkali metals in general
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01D—COMPOUNDS OF ALKALI METALS, i.e. LITHIUM, SODIUM, POTASSIUM, RUBIDIUM, CAESIUM, OR FRANCIUM
- C01D7/00—Carbonates of sodium, potassium or alkali metals in general
- C01D7/02—Preparation by double decomposition
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01D—COMPOUNDS OF ALKALI METALS, i.e. LITHIUM, SODIUM, POTASSIUM, RUBIDIUM, CAESIUM, OR FRANCIUM
- C01D5/00—Sulfates or sulfites of sodium, potassium or alkali metals in general
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01D—COMPOUNDS OF ALKALI METALS, i.e. LITHIUM, SODIUM, POTASSIUM, RUBIDIUM, CAESIUM, OR FRANCIUM
- C01D5/00—Sulfates or sulfites of sodium, potassium or alkali metals in general
- C01D5/06—Preparation of sulfates by double decomposition
- C01D5/08—Preparation of sulfates by double decomposition with each other or with ammonium sulfate
-
- C—CHEMISTRY; METALLURGY
- C05—FERTILISERS; MANUFACTURE THEREOF
- C05D—INORGANIC FERTILISERS NOT COVERED BY SUBCLASSES C05B, C05C; FERTILISERS PRODUCING CARBON DIOXIDE
- C05D1/00—Fertilisers containing potassium
- C05D1/02—Manufacture from potassium chloride or sulfate or double or mixed salts thereof
-
- C—CHEMISTRY; METALLURGY
- C05—FERTILISERS; MANUFACTURE THEREOF
- C05D—INORGANIC FERTILISERS NOT COVERED BY SUBCLASSES C05B, C05C; FERTILISERS PRODUCING CARBON DIOXIDE
- C05D7/00—Fertilisers producing carbon dioxide
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P20/00—Technologies relating to chemical industry
- Y02P20/50—Improvements relating to the production of bulk chemicals
- Y02P20/582—Recycling of unreacted starting or intermediate materials
Definitions
- the present invention relates to a method of formulating alkali earth salts and more particularly, the present invention relates to a method of generating food grade sodium bicarbonate and fertilizer grade potassium sulfate.
- the present invention has applicability in the fertilizer art. DISCLOSURE OF THE INVENTION
- One object of one embodiment of the present invention is to provide a method of formulating food grade sodium bicarbonate and potassium sulfate, characterized in that the method comprises the steps of: a) providing a source of liquid sodium sulfate; b) providing a source of ammonium bicarbonate; c) contacting the sodium sulfate and the ammonium bicarbonate; d) precipitating sodium bicarbonate and forming a liquor; e) precipitating sodium bicarbonate and forming a liquor by contacting the liquor from step d) with sodium sulfate; f) saturating the liquor from step e) with sodium sulfate; g) filtering solids from the liquor of step f); h) contacting the liquor from step g) with sulfuric acid to precipitate carbonates; i) cooling the liquor from step h) to 0°C to form Glauber's salt precipitate; j) heating the liquor from step i) to between 30° to 40°C; and k) precipit
- a further object of one embodiment of the present invention is to provide a method of formulating food grade sodium bicarbonate and potassium sulfate, characterized in that the method comprises the steps of: a) providing a source of liquid sodium sulfate; b) providing a source of ammonium bicarbonate; c) contacting the sodium sulfate and the ammonium bicarbonate; d) precipitating sodium bicarbonate and forming a liquor; e) precipitating sodium bicarbonate and forming a liquor by contacting the liquor from step e) with sodium sulfate; f) saturating the liquor from step e) with anhydrous sodium sulfate; g) filtering solids from the liquor of step f); h) contacting the liquor from step g) with at least one of ammonium bicarbonate, ammonia gas or carbon dioxide to precipitate sodium bicarbonate; i) cooling the liquor from step h) to 0°C to a precipitate of sodium bicarbonate and sodium s
- Glauber's salt solubility in the system is contemplated by the ammonium sulfate-sodium sulfate phase diagram.
- Figure 1 is a process flow diagram illustrating a first part of one process according to the present invention
- Figure 1a illustrates a second part of the process illustrated in Figure 1;
- Figure 1 b illustrates a third part of the process illustrated in Figure 1 ;
- Figure 2 is a is a process flow diagram illustrating a first part of a variation of the process according to the present invention
- Figure 2a illustrates a second part of the process illustrated in Figure 2; and Figure 2b illustrates a third part of the process illustrated in Figure 2.
- Figures 1 through 1b illustrate the process according to a first embodiment.
- the solution is mixed in vessel 14 at 40°C to a specific gravity of 1.30.
- the solution is filtered in filter 16 which, as an example, may comprise a 5 micron filter.
- the solids 18 are disposed of while the filtrate 20 is passed into a first sodium bicarbonate crystallization vessel 27.
- Feeds of water, ammonia and carbon dioxide all denoted by numeral 24 are reacted in vessel 22 in order to synthesize ammonium bicarbonate.
- Formulated ammonium bicarbonate is centrifuged in centrifuge 26, with the solid product being passed into crystallization vessel 27.
- a recycle loop 28 recirculates ammonium bicarbonate solids and liquor into reaction vessel 29.
- the result of the combination in vessel 29 is the formulation of sodium bicarbonate.
- the mixture is filtered by filter 30 and centrifuged.
- the sodium bicarbonate is washed with water in vessel 32, centrifuged in centrifuge 34 and the solid retained as food grade sodium bicarbonate.
- the wash water is returned to vessel 14.
- the liquor from filter 30 has a specific gravity of 1.25 with the contents including approximately 10.4% sodium sulfate, 17.1% ammonium sulfate, 8% sodium bicarbonate and excess ammonium bicarbonate for reaction with the Glauber's salt (discussed herein after ).
- the liquor is reacted in a vessel 36 at 40°C with Glauber's salt formulated in the cooling phase of the process, which will be discussed later, to produce sodium bicarbonate from the excess of ammonium bicarbonate from crystallization vessel 29.
- the ammonium bicarbonate may be added to the second stage (vessel 36) as solid, slurry or solution.
- vessel 46 contains sulfuric acid to precipitate carbonate compounds.
- the so treated liquor is cooled to 0°C in chiller 48 to recover Glauber's salt and filtered in filter 50.
- the recovered Glauber's salt is returned to the sodium bicarbonate crystallization vessel 36.
- the filtrate contains 25.25% by weight ammonium sulfate and up to 11 % by weight sodium sulfate and is passed into a vessel 52 heated to between 30°C and 40°C and combined with solids 65 from filter 66.
- the solution is filtered in filter 56, with the solid fraction containing approximately by weight, 5% potassium chloride, 80% - 85% potassium sulfate, 10% - 15% ammonium sulfate.
- the solid fraction is combined in vessel 58 with water and potassium chloride brine from vessel 60.
- the potassium sulfate solid is centrifuged and filtered in filter 62 and recrystallized with a solution of potassium chloride at
- the liquor or filtrate from the potassium sulfate operations and specifically from filter 56 is processed in accordance with the unit operations set forth in Figure 1 c.
- the liquor is evaporated in evaporator in order to concentrate the ammonium chloride liquor such that upon cooling the potassium chloride and residual sulphates are minimized in solution.
- the solution is filtered with filter 66 with the solid material 67 recycled to vessel 54.
- the filtrate containing approximately 22% to 30% ammonium chloride is reacted with lime in reactor 68 with liberated ammonia recycled.
- the calcium chloride formed may be passed to a settler 70 or scrubber 72 depending on intended subsequent uses.
- sodium bicarbonate is produced in crystallization unit 22 and undergoes generally similar steps as set forth for Figures 1 through 1 B.
- the brine or filtrate is saturated with anhydrous sodium sulfate in vessel 36 and filtered with filter 38 to remove insolubles which are discarded.
- the filtrate from this operation is reacted with ammonium bicarbonate in vessel 80.
- the filtrate could be reacted with ammonia or carbon dioxide to precipitate the sodium bicarbonate.
- the solution is filtered with filter 82 and the sodium bicarbonate remains. The latter is combined with the sodium bicarbonate from filter 30 and then washed, centrifuged and dried. These steps are not shown.
- the filtrate remaining has a composition of approximately, on a by weight basis, 10% sodium sulfate, 24% ammonium sulfate and 8% sodium bicarbonate.
- the solution has a specific gravity of 1.285 at 40°C.
- the filtrate solution is cooled in a chiller 84 to approximately 0°C in order to produce a filtrate containing approximately, on a by weight basis 5% sodium sulfate, 28% ammonium sulfate and 6% sodium bicarbonate.
- the solution is filtered with filter 86 and precipitated sodium bicarbonate and sodium sulfate are recycled back to the bicarbonate crystallization vessel 32, while the filtrate is reacted with potassium chloride in vessel 88 to synthesize first stage potassium sulfate in a purity range of about 75% to 90%.
- the solid potassium sulfate is repulped with potassium chloride brine from vessel 92 in vessel 94. This results in high quality, high grade potassium sulfate.
- the product is washed with water in a conventional washing stage 96 with recycle to vessel 94.
- the solution from filter 90 is evaporated in evaporator 98 ( Figure 2A) to concentrate ammonium chloride liquor whereby upon cooling the potassium chloride and sulfates are minimized.
- the filtrate from filter 100 containing ammonium chloride, potassium chloride and potassium sulfate is passed into evaporator 102.
- the sodium bicarbonate backs the reaction and as a result, ammonia and carbon dioxide are released. These gases are then scrubbed/handled using suitable techniques.
- the calcium chloride generated is then discarded or sold.
- Brine composition is : 5.0% Na 2 SO 4 which mean 60g Na 2 SO 4 precipitates as 136g of Na2SO410H 2 O precipitate and remove 76g of H 2 O.
- Feed Solution from#1 412 g (NH 4 ) 2 SO 4
- the exit brine from the K 2 SO 4 circuit has the following composition:
- This brine is than heated and reacted with lime to recover the ammonia and bypass the evaporator.
- the KCI reports to the CaCI 2 brine rather than being recovered in the evaporator. This represents a 15 to 20 % loss of K to the CaCI 2 brine.
- the KCI in the CaCI 2 brine can be reduced to as low as 1.0% by adding solid Na 2 SO 4 to CaCI 2 /KCI brine.
- the potassium is effectively collected as apprecipitated of syngenite (CaSO 4 • K 2 SO 4 • xH 2 O) at 0 to 100°C with preferred temperatures of 20 to 30°C so that SO 4 solubility is kept to minimum and the reaction occurs at a reasonable rate.
- the exit brine can be deep well disposed of and cake can be blended into the K 2 SO 4 product as binder or further processed to remove the CaSO 4 .
- the cake can be reacted with (NH 4 ) 2 HCO 3 from the NaHCO 3 process feed and the CaSO 4 reacts quickly to produce a brine of (NH 4 ) 2 SO 4 and K 2 SO 4 and a filter CaCI 3 precipitate which is disposed of.
- the (NHa) 2 SO 4 /K 2 SO 4 brine is recycled to
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- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Inorganic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Fertilizers (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Treating Waste Gases (AREA)
- Compounds Of Alkaline-Earth Elements, Aluminum Or Rare-Earth Metals (AREA)
Abstract
Description
Claims
Priority Applications (14)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
SI9920082A SI20636A (en) | 1998-10-13 | 1999-09-30 | Method of formulating alkali metal salts |
PL99347098A PL347098A1 (en) | 1998-10-13 | 1999-09-30 | Method of formulating alkali metal salts |
JP2000575800A JP2002527330A (en) | 1998-10-13 | 1999-09-30 | How to mix alkali metal salts |
UA2001042328A UA73096C2 (en) | 1998-10-13 | 1999-09-30 | Method for formulating alkali metal salts (variants) |
SK500-2001A SK5002001A3 (en) | 1998-10-13 | 1999-09-30 | Method of formulating alkali metal salts |
KR1020017004656A KR20010088870A (en) | 1998-10-13 | 1999-09-30 | Method of formulating alkali metal salts |
BR9914543-0A BR9914543A (en) | 1998-10-13 | 1999-09-30 | Alkali metal salts formulation process |
AU58457/99A AU751236B2 (en) | 1998-10-13 | 1999-09-30 | Method of formulating alkali metal salts |
NZ510786A NZ510786A (en) | 1998-10-13 | 1999-09-30 | Method of formulating alkali metal salts |
EA200100340A EA002709B1 (en) | 1998-10-13 | 1999-09-30 | Method of formulating alkali metal salts |
HU0104062A HUP0104062A3 (en) | 1998-10-13 | 1999-09-30 | Method of formulating alkali metal salts |
EP99945817A EP1121327A1 (en) | 1998-10-13 | 1999-09-30 | Method of formulating alkali metal salts |
HR20000125A HRP20000125A2 (en) | 1998-10-13 | 2000-03-07 | Method of formulating alkali metal salts |
NO20011851A NO20011851L (en) | 1998-10-13 | 2001-04-10 | Process for forming alkali metal salts |
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US10396998P | 1998-10-13 | 1998-10-13 | |
US60/103,969 | 1998-10-13 |
Publications (1)
Publication Number | Publication Date |
---|---|
WO2000021887A1 true WO2000021887A1 (en) | 2000-04-20 |
Family
ID=22297990
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
PCT/CA1999/000905 WO2000021887A1 (en) | 1998-10-13 | 1999-09-30 | Method of formulating alkali metal salts |
Country Status (22)
Country | Link |
---|---|
EP (1) | EP1121327A1 (en) |
JP (1) | JP2002527330A (en) |
KR (1) | KR20010088870A (en) |
CN (2) | CN1515491A (en) |
AU (1) | AU751236B2 (en) |
BR (1) | BR9914543A (en) |
CA (1) | CA2284967A1 (en) |
CZ (1) | CZ20011176A3 (en) |
EA (1) | EA002709B1 (en) |
HR (1) | HRP20000125A2 (en) |
HU (1) | HUP0104062A3 (en) |
ID (1) | ID28729A (en) |
NO (1) | NO20011851L (en) |
NZ (1) | NZ510786A (en) |
PL (1) | PL347098A1 (en) |
SI (1) | SI20636A (en) |
SK (1) | SK5002001A3 (en) |
TR (1) | TR200100960T2 (en) |
UA (1) | UA73096C2 (en) |
WO (1) | WO2000021887A1 (en) |
YU (1) | YU27101A (en) |
ZA (1) | ZA200001142B (en) |
Cited By (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO2001030698A1 (en) * | 1999-10-25 | 2001-05-03 | Airborne Industrial Minerals Inc. | Method for formulating food grade sodium bicarbonate |
EP1421043A1 (en) * | 1998-06-22 | 2004-05-26 | William J. Rigby | A process for manufacturing potassium sulfate fertilizer and other metal sulfates |
WO2004071957A1 (en) * | 2003-02-11 | 2004-08-26 | Airborne Industrial Minerals, Inc. | Method for recovering purified sodium bicarbonate and ammonium sulfate |
Families Citing this family (7)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP4812253B2 (en) * | 2001-08-29 | 2011-11-09 | リグビィ、ウィリアム、ジェイ. | Method for producing potassium sulfate fertilizer and other metal sulfates |
JP5404180B2 (en) * | 2009-05-22 | 2014-01-29 | 日立造船株式会社 | Sodium extraction device |
CN102503636A (en) * | 2011-10-27 | 2012-06-20 | 山西师范大学 | Ammonium chloride agglomerating prilling method |
FR3007753A1 (en) * | 2013-06-26 | 2015-01-02 | Solvay | PROCESS FOR THE PREPARATION OF ALKALI METAL BICARBONATE PARTICLES |
CN104556154B (en) * | 2014-12-30 | 2017-04-12 | 东莞市英硫净水服务有限公司 | Comprehensive utilization technology of residual liquid after evaporation of heavy salt water |
CN109052434B (en) * | 2018-10-19 | 2021-06-04 | 四川金象赛瑞化工股份有限公司 | Method for jointly producing soda ash and composite nitrogen fertilizer by taking mirabilite and ammonium bicarbonate as raw materials |
CN111895722B (en) * | 2020-09-04 | 2024-03-01 | 江西智联塑化科技有限公司 | Conduction oil cooling device for pentaerythritol stearate preparation |
Citations (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CA2032627A1 (en) * | 1990-12-18 | 1992-06-19 | Jack S. Thompson | Process for producing sodium carbonate and ammonium sulphate from sodium sulphate |
CN1064459A (en) * | 1991-12-28 | 1992-09-16 | 邓绍齐 | The comprehensive use of chromium-containing sulfate |
CN1089235A (en) * | 1993-12-29 | 1994-07-13 | 张祥林 | The method of the single-phase decomposition system sodium bicarbonate of sodium sulfate and bicarbonate of ammonia |
CN1104178A (en) * | 1994-11-01 | 1995-06-28 | 何永汉 | Method for production of Lemery salt |
WO1997000829A1 (en) * | 1995-06-23 | 1997-01-09 | Ormiston Mining & Smelting Co. Ltd. | Method for production of sodium bicarbonate, sodium carbonate and ammonium sulfate from sodium sulfate |
SK279011B6 (en) * | 1995-04-05 | 1998-05-06 | Považské Chemické Závody | Method for conversion of ammonium sulphate to potassium sulphate |
-
1999
- 1999-09-29 CA CA002284967A patent/CA2284967A1/en not_active Abandoned
- 1999-09-30 AU AU58457/99A patent/AU751236B2/en not_active Ceased
- 1999-09-30 WO PCT/CA1999/000905 patent/WO2000021887A1/en not_active Application Discontinuation
- 1999-09-30 UA UA2001042328A patent/UA73096C2/en unknown
- 1999-09-30 SI SI9920082A patent/SI20636A/en unknown
- 1999-09-30 ID IDW00200101051A patent/ID28729A/en unknown
- 1999-09-30 TR TR2001/00960T patent/TR200100960T2/en unknown
- 1999-09-30 CN CNA021462313A patent/CN1515491A/en active Pending
- 1999-09-30 CZ CZ20011176A patent/CZ20011176A3/en unknown
- 1999-09-30 JP JP2000575800A patent/JP2002527330A/en active Pending
- 1999-09-30 EA EA200100340A patent/EA002709B1/en not_active IP Right Cessation
- 1999-09-30 KR KR1020017004656A patent/KR20010088870A/en not_active Application Discontinuation
- 1999-09-30 SK SK500-2001A patent/SK5002001A3/en unknown
- 1999-09-30 YU YU27101A patent/YU27101A/en unknown
- 1999-09-30 NZ NZ510786A patent/NZ510786A/en unknown
- 1999-09-30 CN CNB998143782A patent/CN1156397C/en not_active Expired - Fee Related
- 1999-09-30 PL PL99347098A patent/PL347098A1/en unknown
- 1999-09-30 HU HU0104062A patent/HUP0104062A3/en unknown
- 1999-09-30 EP EP99945817A patent/EP1121327A1/en not_active Withdrawn
- 1999-09-30 BR BR9914543-0A patent/BR9914543A/en not_active Application Discontinuation
-
2000
- 2000-03-07 ZA ZA200001142A patent/ZA200001142B/en unknown
- 2000-03-07 HR HR20000125A patent/HRP20000125A2/en not_active Application Discontinuation
-
2001
- 2001-04-10 NO NO20011851A patent/NO20011851L/en unknown
Patent Citations (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CA2032627A1 (en) * | 1990-12-18 | 1992-06-19 | Jack S. Thompson | Process for producing sodium carbonate and ammonium sulphate from sodium sulphate |
CN1064459A (en) * | 1991-12-28 | 1992-09-16 | 邓绍齐 | The comprehensive use of chromium-containing sulfate |
CN1089235A (en) * | 1993-12-29 | 1994-07-13 | 张祥林 | The method of the single-phase decomposition system sodium bicarbonate of sodium sulfate and bicarbonate of ammonia |
CN1104178A (en) * | 1994-11-01 | 1995-06-28 | 何永汉 | Method for production of Lemery salt |
SK279011B6 (en) * | 1995-04-05 | 1998-05-06 | Považské Chemické Závody | Method for conversion of ammonium sulphate to potassium sulphate |
WO1997000829A1 (en) * | 1995-06-23 | 1997-01-09 | Ormiston Mining & Smelting Co. Ltd. | Method for production of sodium bicarbonate, sodium carbonate and ammonium sulfate from sodium sulfate |
Non-Patent Citations (4)
Title |
---|
DATABASE CHEMABS [online] CHEMICAL ABSTRACTS SERVICE, COLUMBUS, OHIO, US; DENG, SHAOQI ET AL: "Manufacture of sodium bicarbonate, potassium sulfate and ammonium chlorid from chromium-containing sodium sulfate solution", XP002125122, retrieved from STN Database accession no. 118:127744 CA * |
DATABASE CHEMABS [online] CHEMICAL ABSTRACTS SERVICE, COLUMBUS, OHIO, US; HE, YONGHAN: "One-step process for production of potassium sulfate", XP002125124, retrieved from STN Database accession no. 124:11907 CA * |
DATABASE CHEMABS [online] CHEMICAL ABSTRACTS SERVICE, COLUMBUS, OHIO, US; KULLA, STEFAN ET AL: "Conversion of ammonium sulfate to potassium sulfate in fertilizer production", XP002125123, retrieved from STN Database accession no. 130:153153 CA * |
DATABASE CHEMABS [online] CHEMICAL ABSTRACTS SERVICE, COLUMBUS, OHIO, US; ZHANG, XIANGLIN ET AL: "Manufacture of sodium bicarbonate from sodium sulfate and ammonium bicarbonate by single-phase decomposition", XP002125121, retrieved from STN Database accession no. 123:174340 CA * |
Cited By (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP1421043A1 (en) * | 1998-06-22 | 2004-05-26 | William J. Rigby | A process for manufacturing potassium sulfate fertilizer and other metal sulfates |
EP1421043A4 (en) * | 1998-06-22 | 2006-01-25 | William J Rigby | A process for manufacturing potassium sulfate fertilizer and other metal sulfates |
WO2001030698A1 (en) * | 1999-10-25 | 2001-05-03 | Airborne Industrial Minerals Inc. | Method for formulating food grade sodium bicarbonate |
US6475458B1 (en) | 1999-10-25 | 2002-11-05 | Airborne Industrial Minerals Inc. | Method for formulating food grade sodium bicarbonate |
WO2004071957A1 (en) * | 2003-02-11 | 2004-08-26 | Airborne Industrial Minerals, Inc. | Method for recovering purified sodium bicarbonate and ammonium sulfate |
Also Published As
Publication number | Publication date |
---|---|
EP1121327A1 (en) | 2001-08-08 |
SI20636A (en) | 2002-02-28 |
CN1330612A (en) | 2002-01-09 |
AU751236B2 (en) | 2002-08-08 |
YU27101A (en) | 2003-10-31 |
BR9914543A (en) | 2001-06-26 |
NO20011851L (en) | 2001-06-12 |
HUP0104062A2 (en) | 2002-04-29 |
CZ20011176A3 (en) | 2001-09-12 |
JP2002527330A (en) | 2002-08-27 |
CN1515491A (en) | 2004-07-28 |
PL347098A1 (en) | 2002-03-25 |
KR20010088870A (en) | 2001-09-28 |
SK5002001A3 (en) | 2001-10-08 |
EA002709B1 (en) | 2002-08-29 |
UA73096C2 (en) | 2005-06-15 |
NO20011851D0 (en) | 2001-04-10 |
ID28729A (en) | 2001-06-28 |
HUP0104062A3 (en) | 2003-03-28 |
ZA200001142B (en) | 2000-10-23 |
CN1156397C (en) | 2004-07-07 |
CA2284967A1 (en) | 2000-04-13 |
AU5845799A (en) | 2000-05-01 |
TR200100960T2 (en) | 2001-08-21 |
EA200100340A1 (en) | 2001-10-22 |
NZ510786A (en) | 2002-05-31 |
HRP20000125A2 (en) | 2001-02-28 |
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MXPA01002553A (en) | Process for producing potassium sulfate from potash and sodium sulfate |
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