WO2000021147A1 - Electrochemical radial cell engine - Google Patents

Electrochemical radial cell engine Download PDF

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Publication number
WO2000021147A1
WO2000021147A1 PCT/US1998/021057 US9821057W WO0021147A1 WO 2000021147 A1 WO2000021147 A1 WO 2000021147A1 US 9821057 W US9821057 W US 9821057W WO 0021147 A1 WO0021147 A1 WO 0021147A1
Authority
WO
WIPO (PCT)
Prior art keywords
electrochemical
engine
motor
cage
radial
Prior art date
Application number
PCT/US1998/021057
Other languages
French (fr)
Inventor
Salvatore Celeste
Original Assignee
Salvatore Celeste
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Salvatore Celeste filed Critical Salvatore Celeste
Priority to PCT/US1998/021057 priority Critical patent/WO2000021147A1/en
Publication of WO2000021147A1 publication Critical patent/WO2000021147A1/en

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Classifications

    • HELECTRICITY
    • H02GENERATION; CONVERSION OR DISTRIBUTION OF ELECTRIC POWER
    • H02KDYNAMO-ELECTRIC MACHINES
    • H02K11/00Structural association of dynamo-electric machines with electric components or with devices for shielding, monitoring or protection
    • H02K11/0094Structural association with other electrical or electronic devices
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B60VEHICLES IN GENERAL
    • B60KARRANGEMENT OR MOUNTING OF PROPULSION UNITS OR OF TRANSMISSIONS IN VEHICLES; ARRANGEMENT OR MOUNTING OF PLURAL DIVERSE PRIME-MOVERS IN VEHICLES; AUXILIARY DRIVES FOR VEHICLES; INSTRUMENTATION OR DASHBOARDS FOR VEHICLES; ARRANGEMENTS IN CONNECTION WITH COOLING, AIR INTAKE, GAS EXHAUST OR FUEL SUPPLY OF PROPULSION UNITS IN VEHICLES
    • B60K17/00Arrangement or mounting of transmissions in vehicles
    • B60K17/04Arrangement or mounting of transmissions in vehicles characterised by arrangement, location, or kind of gearing
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B60VEHICLES IN GENERAL
    • B60KARRANGEMENT OR MOUNTING OF PROPULSION UNITS OR OF TRANSMISSIONS IN VEHICLES; ARRANGEMENT OR MOUNTING OF PLURAL DIVERSE PRIME-MOVERS IN VEHICLES; AUXILIARY DRIVES FOR VEHICLES; INSTRUMENTATION OR DASHBOARDS FOR VEHICLES; ARRANGEMENTS IN CONNECTION WITH COOLING, AIR INTAKE, GAS EXHAUST OR FUEL SUPPLY OF PROPULSION UNITS IN VEHICLES
    • B60K8/00Arrangement or mounting of propulsion units not provided for in one of the preceding main groups
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M10/00Secondary cells; Manufacture thereof
    • H01M10/42Methods or arrangements for servicing or maintenance of secondary cells or secondary half-cells
    • H01M10/4214Arrangements for moving electrodes or electrolyte
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M12/00Hybrid cells; Manufacture thereof
    • H01M12/04Hybrid cells; Manufacture thereof composed of a half-cell of the fuel-cell type and of a half-cell of the primary-cell type
    • H01M12/06Hybrid cells; Manufacture thereof composed of a half-cell of the fuel-cell type and of a half-cell of the primary-cell type with one metallic and one gaseous electrode
    • HELECTRICITY
    • H02GENERATION; CONVERSION OR DISTRIBUTION OF ELECTRIC POWER
    • H02KDYNAMO-ELECTRIC MACHINES
    • H02K11/00Structural association of dynamo-electric machines with electric components or with devices for shielding, monitoring or protection
    • H02K11/30Structural association with control circuits or drive circuits
    • H02K11/33Drive circuits, e.g. power electronics
    • HELECTRICITY
    • H02GENERATION; CONVERSION OR DISTRIBUTION OF ELECTRIC POWER
    • H02KDYNAMO-ELECTRIC MACHINES
    • H02K7/00Arrangements for handling mechanical energy structurally associated with dynamo-electric machines, e.g. structural association with mechanical driving motors or auxiliary dynamo-electric machines
    • H02K7/02Additional mass for increasing inertia, e.g. flywheels
    • H02K7/025Additional mass for increasing inertia, e.g. flywheels for power storage
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M12/00Hybrid cells; Manufacture thereof
    • H01M12/08Hybrid cells; Manufacture thereof composed of a half-cell of a fuel-cell type and a half-cell of the secondary-cell type
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00Electrodes
    • H01M4/02Electrodes composed of, or comprising, active material
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M50/00Constructional details or processes of manufacture of the non-active parts of electrochemical cells other than fuel cells, e.g. hybrid cells
    • H01M50/50Current conducting connections for cells or batteries
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02EREDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E60/00Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
    • Y02E60/10Energy storage using batteries
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02EREDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E60/00Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
    • Y02E60/16Mechanical energy storage, e.g. flywheels or pressurised fluids
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02TCLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO TRANSPORTATION
    • Y02T10/00Road transport of goods or passengers
    • Y02T10/60Other road transportation technologies with climate change mitigation effect
    • Y02T10/62Hybrid vehicles

Definitions

  • This invention relates to an electrochemical engine having
  • a motor for supporting the motor and at least one
  • electrochemical reaction cell providing power for the engine with the
  • anode and/or cathode material has been materially depleted.
  • the present engine design incorporates at least one
  • electrochemical reaction cell having a cathode, a rotatable enclosure
  • the rotatable enclosure is preferably a perforated cage and the source
  • anode material is preferably composed of a multiplicity of individual
  • the radial engine of the present invention is able to sustain
  • present invention operates at substantially close to maximum
  • invention provides an overall engine performance comparable to the
  • reaction cell having a rotatable enclosure preferably in the form of a
  • Figure 1 is a side elevation in cross section of a preferred
  • Figure 2 is a top view of the electrochemical engine of
  • Figure 3 is an enlargement of a section on the right hand
  • Figure 4 is a top view of the electrochemical reaction cell
  • Figure 5 is a magnified view of a radial sector of the
  • Figure 6 is an enlarged view of the preferred air cathode
  • Figure 6a is a magnified view of an encircled section of
  • Figure 7 is a schematic diagram of a printed circuit board
  • electrochemical reaction cells and its interconnection preferably through a controller with the motor winding for the preferred electrochemical
  • FIG. 8 is an electrical block diagram of the controller
  • Figure 9 is a side elevation in cross section of another
  • Figure 1 0 is a cross sectional view of yet another
  • Figure 1 1 is a magnified view of the air cathode assembly
  • Figure 1 2 is a top view of the electrochemical reaction cell
  • present invention which comprises an engine block 1 2, a plurality of
  • electrochemical reaction cells 1 4 are arranged symmetrically around the
  • the motor 1 5 is of a conventional design such as a DC motor for operation with an
  • a fan (not shown) is mounted
  • Air cathodes 1 8 are deployed in the preferred embodiment for the
  • any conventional cathode may be used.
  • the fan is driven by the motor 1 5 to draw and exhaust air through the
  • the air is preferably drawn from the atmosphere through
  • the moving air not only supplies
  • the motor 1 5 is connected to the main drive shaft 1 9 of
  • the engine 1 0 which, in turn, is adapted to be connected to the
  • a gear assembly 20 connects the
  • the gear assembly 20 includes a main fly gear 21 and a
  • reaction cells 14 The slave gears 22 simultaneously rotate the
  • Each enclosure 28 contains the anode supply for the
  • electrochemical reaction cells 14 may be independently rotated
  • Each enclosure 28 should preferably be represented by a rotatable cage
  • each shaft 24 is rotatably connected through bushing members 25 and
  • the sleeve 27 is connected to
  • the rotatable cage 28 may be
  • the composition of the cage may be metal and more
  • the cage 28 should preferably have a covering
  • the rotatable cage 28 is filled with anode
  • Fluid electrolyte 34 preferably flows
  • screening of the cage 28 functions to contain the anode particles 32
  • the membrane 30 must however be sufficient to permit the fluid
  • permeable membrane 30 is not critical to the invention and may be
  • the cage 28 is separated from the cathode 1 8 by a space
  • electrolyte 34 is caused to circulate thought the cage 28 into the space
  • the end cap 36 is also
  • the cathode 1 8 is supported between an upper section 40
  • the upper section 40 of the engine block 1 2 is readily removable from
  • the anode particles 32 are exposed through the screening
  • anode particles 32 appear to the cathode 1 8 as having a "virtually
  • each anode particle 32 has the surface area of the
  • the cathode 1 8 is preferably of the same geometry as that
  • cathode 1 8 are of cylindrical geometry thereby defining the space
  • the anode particles 32 may be formed from any substance.
  • conventional anode material selected from the group including, for
  • anode particles will vary with the size of the cage 28 which in turn
  • cathode may be used such as e.g. potassium hydroxide (KOH) .
  • the fluid electrolyte need not be aqueous an aqueous fluid
  • the fluid electrolyte may be in the form of a
  • anode material although an air cathode is preferred.
  • An air cathode is preferred.
  • cathode as is well known in the art, is typically in the form of a sheet
  • the air cathode must contain an electrically
  • cathode 1 8 should be substantially hydrophobic to the aqueous
  • displaced oxide particles at the center of the cage 28 form a core of oxide particles which act as a filter for the fluid electrolyte 34 within
  • the cathode 1 8 but is also an "interface space" between fresh active
  • the electrolyte thickness is also essentially a constant.
  • reaction cell 1 4 until the anode supply is substantially exhausted.
  • Hydrogen gas is exhausted by the air flow current through the engine 10. Moreover because the anode particles 32 appear to the cathode 1 8
  • the electrochemical reaction cells 1 4 supply power to the electrochemical reaction cells 1 4
  • reaction cells 1 4 can be controlled by changing the electrical wiring
  • controller 47 as shown in Figures 7 and 8 respectively in response to
  • the wiring of the reaction cells 14 is
  • the printed circuit board 50 is positioned to make contact
  • the anode lead 49 may connect to the corresponding cage 28 of each reaction cell 14 or to the shaft 24 and
  • the printed circuit board 50 has
  • controller 47 is also connected to a wiring cable 53 which has a
  • windings in the engine 1 0 such as the armature windings (not shown)
  • the controller 47 as shown in Figure 8 contains a
  • microprocessor 58 which is programmed to rearrange the configuration
  • reaction cells 14 which will optimize the output discharge characteristic
  • microprocessor 58 is connected to a logic module 59 representing an
  • a feed back loop controller 60 which may itself be a
  • microprocessor for receiving logic information from the printed circuit
  • the output power relay unit 61 is preferably
  • a device 62 such as a speedometer and to an indicator
  • control panel 63 The controller 47 is also connected to a user
  • input/output accelerator control unit 65 which may also include operator override control 66.
  • unit 65 provides information to the controller 47 to know how much
  • the override control 66 enables an operator of the engine 10 to
  • the electrochemical cells 1 4 may be used in a
  • circuit board 50 circuit board 50, controller 47 and motor 1 5.
  • reaction cells 14 to deliver power to motor 1 5 sufficient to intitiate
  • each cage 28 each cage 28.
  • the electrochemical cells 1 4 may be recharged from any one of the electrochemical cells 1 4.
  • the electrochemical cells 1 4 may be recharged from any one of the electrochemical cells 1 4.
  • reaction cells occurs automatically when power is not demanded by the engine 1 0.
  • reaction cells 14 operate as a "fly wheel"
  • 1 4 may also be removed from the engine 10 by removing the upper
  • reaction cells 14 mounted in tandum so as to double the number of
  • reaction cells 14 with only a limited increase in the size of the engine
  • the controller 47 can provide better power control to the engine 10
  • block 1 2 for the arrangement in Figure 9 includes a plurality of air
  • electrochemical cell 14 In this embodiment the electrochemical
  • reaction cell 70 surrounds the motor 1 5 in a concentric arrangement
  • FIG 1 As shown in Figure 1 2 the hub 72 forms a carousel for
  • vanes 74 are located at the bottom end of the cage 28 to assist in the
  • cathode 75 which is functionally equivalent to air cathode 1 8 is
  • motor 1 5 and rotatable cage 28 rotate in unison and
  • the motor 1 5 includes an intake fan 1 6 which is
  • Figure 1 such that air is drawn into the engine 10 from the atmosphere and is forced to take a path around the air cathode 75.
  • the cage 28 rotates to compress the anode particles 32 against one

Abstract

An electrochemical radial cell engine comprising an engine block, a motor (15) supported by the engine block, at least one electrochemical reaction cell (14) including a rotatable enclosure containing a source of anode material, preferably in the form of a multiplicity of anode particles, a fluid electrolyte, a cathode surrounding and radially spaced from the rotatable enclosure and means for rotating the rotatable enclosure in response to rotation of the motor. The enclosure should preferably be represented by a perforated cage having a mesh size large enough to pass fluid electrolyte. Rotation of the cage causes the anode particles to be compressed by centrifugal forces which act upon the particles as the cage spins. This maximizes the operating efficiency of the electrochemical reaction cell(s) providing enhanced power for driving the engine.

Description

ELECTROCHEMICAL RADIAL CELL ENGINE
This invention relates to an electrochemical engine having
a motor, an engine block for supporting the motor and at least one
electrochemical reaction cell providing power for the engine with the
electrochemical reaction cell formed as an integral part of the engine
and comprising a rotatable enclosure in the form of a cage having
anode particles, fluid electrolyte and a cathode with the cathode being
radially spaced from the cage and means in said engine for causing the
enclosure to rotate to enhance the delivery of power to the engine.
BACKGROUND OF THE INVENTION
Prior art electrochemically driven engines utilize a passive
battery system to provide an electrochemical source of power for the
engine. The electrical capacity of the battery system which controls
engine performance decreases during normal engine operation.
Accordingly, research has been directed primarily to increasing the
output capacity of the battery system and to recharging systems to
repeatedly restore the battery system to its maximum capacity for
reuse within a reasonable time period. The design of the engine was
heretofore treated separately. Many of the problems attributable to the
use of an electrochemical source of power for driving an engine are
directly traceable to problems in the electrochemical power source
(battery system) associated with oxide buildup, dendrite formation,
gassing and passivation which reduce the electrical output discharge performance characteristic of the battery system and, in turn, materially
affect engine operation and performance. To compensate against the
degradation of battery capacity the conventional battery system needs
to be continually recharged after relatively short intervals of usage to
repeatedly restore the capacity of the battery well before the supply of
anode and/or cathode material has been materially depleted.
The present engine design incorporates at least one
electrochemical reaction cell as an integral part of the engine with the
electrochemical reaction cell having a cathode, a rotatable enclosure
containing a source of anode material and a source of fluid electrolyte.
The rotatable enclosure is preferably a perforated cage and the source
of anode material is preferably composed of a multiplicity of individual
anode particles. Upon rotation of the cage containing the anode
particles a dynamic interrelationship occurs between the operation of
the engine and the operation of the electrochemical reaction cell. This
dynamic interrelationship is caused by the rotation of the supply of
anode particles relative to the cathode during engine operation and
preferably in response to rotation of the engine motor. As the cage
spins centrifugal (centripetal) forces compress the anode particles
together and against the cage concomitantly with the electrochemical
reaction process between the fluid electrolyte and the anode and
cathode. Rotation of the cage causes a stratification to occur between
anode particles which have oxidized and the non-oxidized anode
particles so that only "fresh" anode particles, i.e. essentially non- oxidized particles, remain at the periphery of the cage adjacent to the
cathode with the oxidized particles drawn toward the inner core of the
cage. As a result of this stratification the formation of dendrites is
inhibited and there is no loss in electrical contact between anode
particles, particularly at the periphery of the cage, so that the interface
spacing between the "fresh" anode particles and the cathode surface
is maintained constant. The rotation of the cage also causes the fluid
electrolyte to circulate through the space representing the interface
between anode and cathode which has the effect of removing all
electrochemical by-product contamination thereby keeping the surface
of the anode particles at the periphery of the cage free of such
contamination. Accordingly, the discharge characteristic of the
electrochemical reaction cell (battery) does not drop off and instead
remains substantially constant with engine power demand. As a result
engine efficiency and performance does not degrade due to
electrochemical inefficiency as in conventional electrochemical systems.
Accordingly the radial engine of the present invention is able to sustain
a high operating efficiency until almost complete exhaustion of the
anode supply. In fact the electrochemical radial cell engine of the
present invention operates at substantially close to maximum
electrochemical efficiency without suffering substantial degradation in
battery performance until the anode supply is essentially exhausted.
Moreover, by integrating the electrochemical cell with the engine it is possible to provide auxiliary power in the form of both a source of
alternating current, direct current and/or pulsating DC.
The electrochemical radial cell engine of the present
invention provides an overall engine performance comparable to the
performance of a conventional engine using conventional fossils fuels
as their power source.
SUMMARY OF THE INVENTION
The electrochemical engine of the present invention
broadly comprises an engine block, at least one electrochemical
reaction cell having a rotatable enclosure preferably in the form of a
cage containing a source of anode material, a fluid electrolyte, a
cathode spaced apart from the enclosure to permit rotation of the
enclosure relative to the cathode, a motor supported by the engine
block and means for rotating the enclosure during rotation of the motor.
The rotation of the cage maintains the anode material under
compression due to centrifugal forces.
BRIEF DESCRIPTION OF THE DRAWINGS
Other objects and advantages of the present invention will
become apparent from the following detailed description of the inven¬
tion when read in conjunction with the accompanying drawings of
which: Figure 1 is a side elevation in cross section of a preferred
embodiment of the electrochemical engine of the present invention;
Figure 2 is a top view of the electrochemical engine of
Figure 1 ;
Figure 3 is an enlargement of a section on the right hand
side of Figure 1 which magnifies the electrochemical reaction cell in the
engine with part of the interior of the reaction cell exposed to show the
anode particles and the flow pattern for fluid electrolyte;
Figure 4 is a top view of the electrochemical reaction cell
of Figure 3 taken along the lines 4-4 showing the stratification of the
anode particles within the reaction cell;
Figure 5 is a magnified view of a radial sector of the
electrochemical reaction cell in Figure 4 taken along the lines 5-5 for
showing the details of construction of the electrochemical reaction cell;
Figure 6 is an enlarged view of the preferred air cathode
assembly for each electrochemical reaction cell in the electrochemical
engine of the present invention;
Figure 6a is a magnified view of an encircled section of
Figure 6 which shows the space for fluid flow between the air cathode
and the periphery of the cage containing the anode particles;
Figure 7 is a schematic diagram of a printed circuit board
showing the wiring interconnections between each of the
electrochemical reaction cells and its interconnection preferably through a controller with the motor winding for the preferred electrochemical
engine embodiment of the present invention;
Figure 8 is an electrical block diagram of the controller and
printed circuit board in Figure 7;
Figure 9 is a side elevation in cross section of another
embodiment of the present invention showing a tandem arrangement
of electrochemical reaction cells;
Figure 1 0 is a cross sectional view of yet another
embodiment of the electrochemical engine of the present invention
having only a single electrochemical reaction cell;
Figure 1 1 is a magnified view of the air cathode assembly
for the electrochemical reaction cell in the engine embodiment of Figure
1 0; and
Figure 1 2 is a top view of the electrochemical reaction cell
in Figure 10.
DETAILED DESCRIPTION OF THE INVENTION
Referring now to figures 1 -8 inclusive illustrating the
preferred embodiment of the electrochemical radial cell engine 10 of the
present invention which comprises an engine block 1 2, a plurality of
electrochemical reaction cells 1 4, with each reaction cell 1 4 being
supported by the engine block 1 2, and a motor 1 5. The plurality of
electrochemical reaction cells 1 4 are arranged symmetrically around the
motor 1 5 and preferably in a concentric arrangement. The motor 1 5 is of a conventional design such as a DC motor for operation with an
electrochemical source of power. A fan (not shown) is mounted
adjacent to the motor 1 5 with the fan having impeller vanes 1 6 as
shown in figure 2 for drawing air through the engine 1 0 to cool the
armature of the motor 1 5, exhaust hydrogen gas generated by the
electrochemical reaction cells 1 4 and to provide an adequate supply of
relatively high velocity air to the air cathodes 1 8 of the reaction cells
14. Air cathodes 1 8 are deployed in the preferred embodiment for the
cathode component of the electrochemical reaction cells 14. However,
it should be understood that the use of an air cathode is not essential
to the present invention i.e, any conventional cathode may be used.
The fan is driven by the motor 1 5 to draw and exhaust air through the
engine 10 in accordance with a preferred air flow path as identified by
arrows in Figures 1 and 2 respectively. The air is exhausted into the
atmosphere. The air is preferably drawn from the atmosphere through
the motor 1 5 so as to cool the motor armature windings (not shown)
and then to follow a preferred path past the air cathodes 1 8 as shown
in Figure 2. By passing first through the motor 1 5 the air will be
elevated somewhat in temperature before being directed past the air
cathodes 1 8 into the atmosphere. The moving air not only supplies
oxygen to the air cathodes 1 8 but also and provides a path to exhaust
gas generated by the electrochemical reaction in the electrochemical
reaction cells 1 4. The motor 1 5 is connected to the main drive shaft 1 9 of
the engine 1 0 which, in turn, is adapted to be connected to the
transmission of a vehicle (not shown) or to the drive train of any other
mechanism (not shown) which to be electrochemically driven by the
engine 10 of the present invention. A gear assembly 20 connects the
main drive shaft 1 9 of the engine 1 0 to the electrochemical reaction
cells 1 4. The gear assembly 20 includes a main fly gear 21 and a
plurality of secondary slave gears 22 with each of the secondary slave
gears 22 connected to a corresponding one of the plurality of
electrochemical reaction cells 1 4 as is more specifically shown in Figure
2. In the preferred embodiment of the present invention there exists
eight (8) electrochemical reaction cells 14 and eight (8) corresponding
secondary slave gears 22 with each reaction cell 1 4 having the same
reference number and with each slave gear 22 having the same
reference number for the sake of simplicity. Each one of the slave gears
22 is affixed to a separate cylindrical shaft 24 which, in turn, is
connected through the engine block 1 2 to one of the electrochemical
reaction cells 14. The slave gears 22 simultaneously rotate the
enclosures 28 of the reaction cells 14 in response to the rotation of the
main fly gear 21 so that each enclosure 28 will rotate about an axis
through the shaft 24 coaxial with the longitudinal axis of the motor 1 5
and in a common direction with the rotation of the main drive shaft 1 9
of the engine 10. Each enclosure 28 contains the anode supply for the
respective reaction cell 1 4. Although a gear arrangement is shown for rotating the enclosures 28 in response to the rotation of the main drive
shaft 1 9 it should be obvious that the enclosures 28 may be rotated
electromagnetically or by any other conventional mechanical or
electromechanical arrangement. Stated otherwise the use of the gear
arrangement 20 is not to be construed as essential to the invention.
Rotation of the enclosures 28 containing the anode supply
for each of the electrochemical reaction cells 14 may also be initiated
independent of the operation of motor 1 5 or in conjunction therewith
e.g. the electrochemical reaction cells 14 may be independently rotated
from an external source such as a solar cell or by other conventional
means. The speed of rotation will depend upon the size of the engine
10 and is not critical to the present invention. However the enclosures
28 must be rotated at a speed which will create a centrifugal force
sufficient to compress the anode particles within each enclosure 28.
Each enclosure 28 should preferably be represented by a rotatable cage
and will hereinafter for simplicity be referred to as a rotatable cage 28.
As shown in Figure 1 and more particularly in Figure 3
each shaft 24 is rotatably connected through bushing members 25 and
26 in the engine block 10 and is directly connected to a sleeve 27
forming the inner wall of the rotatable cage 28. The rotatable cage 28
is preferably of cylindrical configuration. The sleeve 27 is connected to
the outer periphery of the rotatable cage 28 preferably by means of a
plurality of radial dividers 29. End caps 31 and 33 are placed over the
opposite ends of the rotatable cage 28 thereby forming an enclosure. It should be understood that the construction of the cage 28 does not
require the use of the dividers 29. The rotatable cage 28 may be
formed in any desired manner preferably from screening having a
desired mesh size. The composition of the cage may be metal and more
preferably brass although it may also be composed from an alloy. In
addition to a metal mesh the cage 28 should preferably have a covering
sheathe surrounding the metal mesh represented preferably by a porous
permeable membrane 30. The rotatable cage 28 is filled with anode
material preferably in the form of a multiplicity of anode granulated
particles 32. Figure 3 shows part of the cylindrical cage 28 removed
exposing some of the anode particles 32 contained in the cage 28
whereas Figures 4 and 5 show the distribution of the anode particles
32 in the cage 28 during the electrochemical reaction process. The
mesh size of the cage 28 must readily permit fluid electrolyte 34 to
freely flow through the cage 28. Fluid electrolyte 34 preferably flows
through each reaction cell 14 in the direction shown by the arrows in
Figure 3. The porous permeable membrane 30 which surrounds the
screening of the cage 28 functions to contain the anode particles 32
within the cage 28 during rotation of the cage 28. The permeability of
the membrane 30 must however be sufficient to permit the fluid
electrolyte 34 to freely pass therethrough. The composition of the
permeable membrane 30 is not critical to the invention and may be
composed from any suitable polymeric material. The cage 28 is separated from the cathode 1 8 by a space
35 of predetermined dimension. Upon rotation of the cage 28 the fluid
electrolyte 34 is caused to circulate thought the cage 28 into the space
35 and then to pass through vent holes or passageways 38 and 39
located between the engine block 1 2 and the end caps 31 and 36
respectively forming a closed circulating loop as illustrated by the
arrows in Figure 3. The end caps 31 and 36 close the cage 28 to form
an enclosure for the anode particles 32. The end cap 36 is also
structured as an impeller as shown in figure 2 to assist in the controlled
flow of the fluid electrolyte 34.
The cathode 1 8 is supported between an upper section 40
of the engine block 1 2 and a lower section 41 . Although not shown a
seal is formed between the assembly of the cathode 1 8 and the engine
block 1 2 so that leakage of electrolyte 34 therebetween is prevented.
The upper section 40 of the engine block 1 2 is readily removable from
the engine 1 0 for assembling the electrochemical reaction cells 14,
filling the cage 28 of each reaction cell 1 4 with electrolyte 34,
replacing or substituting one or more of the electrochemical reaction
cells 1 4 and for maintenance purposes.
The anode particles 32 are exposed through the screening
of the cage 28 to the cathode 1 8. Upon rotation of the cage 28 the
anode particles 32 appear to the cathode 1 8 as having a "virtually
infinite surface area". "Virtually infinite surface area" is intended for
purposes of the present disclosure to identify a surface area caused by a rotation of the anode particles 32 into concentric cylindrical orbits in
response to the rotation of the cage 28 such that to the cathode 1 8 it
appears as if each anode particle 32 has the surface area of the
cylindrical orbit assumed by the particle. The spinning of the cage
permits continuous electrochemical reaction of each particle as the
particle spins in orbit causing reaction with the particle over a dynamic
surface area for an entire revolution thus providing a "virtual surface
area" for electrochemical activity much greater than the surface area
actually provided by the particle were it a passive operation. Moreover,
since a multiplicity of anode particles are present with each providing
a substantially enlarged surface area this results in substantially
enhancing the output discharge capacity of each reaction cell 1 4.
The cathode 1 8 is preferably of the same geometry as that
of the cage 28 with the separation therebetween defining the space 35.
In the preferred embodiments shown in the drawings both the cage 28
and cathode 1 8 are of cylindrical geometry thereby defining the space
35 as a radial space. Although the radial space 35 should be as small
as possible its dimension will vary substantially in correspondence with
the size of the engine 1 0.
The anode particles 32 may be formed from any
conventional anode material selected from the group including, for
example, zinc, magnesium, aluminum, lithium etc. The size of the
anode particles will vary with the size of the cage 28 which in turn
depends upon the size of the engine 1 0. Any conventional aqueous electrolyte compatible with the selected material choice for anode and
cathode may be used such as e.g. potassium hydroxide (KOH) .
Although the fluid electrolyte need not be aqueous an aqueous fluid
electrolyte is preferred. The fluid electrolyte may be in the form of a
liquid or may be microencapsulated or in a gelled composition. Any
conventional material may be used for the cathode compatible with the
choice of the anode material although an air cathode is preferred. An air
cathode, as is well known in the art, is typically in the form of a sheet
like member having opposite surfaces with one surface exposed to the
atmosphere and the other surface exposed to the electrolyte in the cell
such that during battery operation atmospheric oxygen dissociates
while metal from the anode oxidizes to provide electron flow between
the anode and cathode. The air cathode must contain an electrically
conductive element and be permeable to air. An illustration of the air
cathode 1 8 for the electrochemical radial cell engine of the present
invention is shown in Figure 6. The air cathode 1 8 is exposed to the
atmosphere through ports 44 formed within a supporting plastic
framework 45 connected to the manifold or engine block 1 2. The air
cathode 1 8 should be substantially hydrophobic to the aqueous
electrolyte so that aqueous electrolyte will not seep through. The
surface of the air cathode 1 8 facing electrolyte is formed from active
carbon containing finely divided hydrophobic polymeric material
whereas the opposing surface is composed of a conductive element such as a metal screen and faces the atmosphere. Figure 6a shows the
space 35 for the flow of fluid electrolyte 34.
Rotation of each cage 28 generates a centripetal
(centrifugal) force which compresses the anode particles 32 together
and up against the periphery of the cage 28. This assures good
electrical contact between the anode particles 32 and results in a
stratification of the anode particles as shown in Figure 4. The oxidized
particles are displaced by the larger non-oxidized particles which move
toward the periphery of the cage 28 while the displaced oxidized
particles move toward the center of the cage 28. The stratification of
particles as exemplified in Figure 4 results in the smaller particles i.e.
the oxidized anode particles and hydroxides congregating at the center
or core section of the cage 28. Partially oxidized particles will
congregate in a band at an intermediate position. The heavier non-
oxidized anode particles 32 which did not significantly take part in the
electrochemical reaction are forced to move toward the periphery of the
cage 28. This results in assuring a "fresh" supply of anode particles 32
in contact with one another at the periphery of the cage 28. The
rotation of the cage 28 also causes the fluid electrolyte 34 to circulate
through the cage 28 and through the radial space 35 between the
cathode 1 8 and cage 28. This causes removal of substantially all
contaminates in the cathode/anode interface spacing 35 and keeps the
surface of the anode particles 32 abutting the cage 28 clean. The
displaced oxide particles at the center of the cage 28 form a core of oxide particles which act as a filter for the fluid electrolyte 34 within
the closed fluid circulation path. Accordingly, the space 35 between the
active "fresh" anode particles which are in close engagement with one
another at the outer periphery of the cage 28 and the cathode surface
is essentially constant. It should be understood that the space 35 in the
present case is not only the physical space separating the cage 28 from
the cathode 1 8 but is also an "interface space" between fresh active
anode particles and the cathode. In conventional electrochemical
systems the "interface space" between the closest non-oxidized
particles and the cathode increases in dimension since the anode
particles closest to the cathode oxidize first and essentially remain fixed
in position. The electrolyte thickness is also essentially a constant. The
result of all this is to essentially prevent passivation and the formation
of dendrites and to cause the removal of substantially all oxides and by-
products from the active anode and cathode interface surfaces. The
constant removal of reaction-by-products from the anode/cathode
interface by the circulating fluid electrolyte within the space 35 and the
continual redistribution of anode particles 32 in the cage 28 in
accordance with the teaching of the present invention dramatically
minimizes ohmic effects by maintaining a low internal resistance
thereby causing the power output to be substantially constant. This
produces a level discharge characteristic for each of the electrochemical
reaction cell 1 4 until the anode supply is substantially exhausted.
Hydrogen gas is exhausted by the air flow current through the engine 10. Moreover because the anode particles 32 appear to the cathode 1 8
to constitute a virtually infinite surface area a much larger current
density is produced relative to that obtainable from any conventional
electrochemical battery source.
The electrochemical reaction cells 1 4 supply power to
drive the engine 10. The power delivered to the engine 10 from the
reaction cells 1 4 can be controlled by changing the electrical wiring
configuration of the reaction cells 14 i.e., by changing the electrical
wiring configuration between reaction cells 14 from a series or parallel
configuration to a specified combination of series and parallel
configuration. The wiring configuration between the reaction cells 1 5
may be controlled manually or may be fixed into different preset
configurations corresponding to specified engine output requirements
for different applications with adjustment through a switch or by
automatic control. The preferred arrangement involves automatically
varing the wiring configuration of the reaction cells 1 4 using a
controller 47 as shown in Figures 7 and 8 respectively in response to
engine power demand. The wiring of the reaction cells 14 is
accomplished through a printed circuit board 50 which is interposed
between the engine block 1 2 and the reactions cells 14 as shown in
Figure 1 . The printed circuit board 50 is positioned to make contact
with each electrochemical reaction cell 1 4 to provide an anode lead 48
for each reaction cell 1 4 and a correponding cathode lead 49 for each
reaction cell 1 4 respectively. The anode lead 49 may connect to the corresponding cage 28 of each reaction cell 14 or to the shaft 24 and
the cathode lead 49 to the cathode 18. The printed circuit board 50 has
an edge connector 52 which is connected to the controller 47. The
controller 47 is also connected to a wiring cable 53 which has a
receptacle 55 to which plug 56 is manually connected. The plug 56 is
connected to the wiring leads 33 which lead directly to appropriate
windings in the engine 1 0 such as the armature windings (not shown)
of the motor 1 5.
The controller 47 as shown in Figure 8 contains a
microprocessor 58 which is programmed to rearrange the configuration
of the reaction cells 1 4 to form a given series/parallel arrangement of
reaction cells 14 which will optimize the output discharge characteristic
of the engine 10 for any given set of engine operating conditions. The
microprocessor 58 is connected to a logic module 59 representing an
input/output modem for the microprocessor 58 to receives information
from a feed back loop controller 60 which may itself be a
microprocessor for receiving logic information from the printed circuit
board 50 identifying the wiring configuration of the reaction cells 1 4.
The logic module 59 and feed back loop controller 60 communicate
with an output power relay unit 61 to provide power from the reaction
cells to the motor 1 5. The output power relay unit 61 is preferably
connected to a device 62 such as a speedometer and to an indicator
control panel 63. The controller 47 is also connected to a user
input/output accelerator control unit 65 which may also include operator override control 66. The user input/output accelerator control
unit 65 provides information to the controller 47 to know how much
power is being demanded by the engine 1 0 so that it can respond
automatically by changing the wiring configuration of the reaction cells
1 4. The override control 66 enables an operator of the engine 10 to
override the operation through, for example, a number of manually
operated switches (not shown) indicative of certain situations in which
normal operation from the accelerator control 66 should be overridden.
Initially, the electrochemical cells 1 4 may be used in a
passive capacity to energize the motor 1 5 once the plug 56 is
connected to the receptacle 55 thereby interconnecting the printed
circuit board 50, controller 47 and motor 1 5. Although, in the passive
state, the cages 28 are not revolving an electrochemical reaction will
occur between the anode particles 32 and the cathode 1 8 in each of
the reaction cells 14 to deliver power to motor 1 5 sufficient to intitiate
rotation of the gear assembly 20 and, in turn, to start the rotation of
each cage 28.
The electrochemical cells 1 4 may be recharged from any
external source of power. Recharging from an external electrochemical
source may be carried out simply by connecting the electrochemical
cells 1 4 to an external source of power with the plug 56 from the
motor 1 5 disconnected from the controller 47. It should however be
understood that during normal engine operation recharging of the
reaction cells occurs automatically when power is not demanded by the engine 1 0. In this regard the reaction cells 14 operate as a "fly wheel"
when the engine does not draw power from the reaction cells 1 4.
When the engine 10 is not drawing power the motor 1 5 operates as a
generator for automatically recharging the reaction cells 14. By this
recharging mechanism the mechanical energy stored in the reaction
cells is substantially recaptured. There is also a gryroscopic effect due
to the rotating mass of each reaction cell 1 4 which will stabilize the
position of the engine keeping its attitiude essentially flat. During the
recharging operation the oxidation process reverses and the oxide
particles disassociate to cause a reformation of the anode particles. In
fact as a result of the rotation of the cages 28 during recharge the
recharging process is accelerated. A spent electrochemical reaction cell
1 4 may also be removed from the engine 10 by removing the upper
section 40 of the engine block 1 0 and readily replaced with a new
reaction cell 14.
The arrangement of reaction cells 1 4 in the embodiment
of figure 1 may be modified as shown in Figure 9 to include another set
of reaction cells 14 mounted in tandum so as to double the number of
reaction cells 14 with only a limited increase in the size of the engine
10. The controller 47 can provide better power control to the engine 10
with a larger number of electrochemical reaction cells 1 4. The engine
block 1 2 for the arrangement in Figure 9 includes a plurality of air
intake ports 46 and an air filter 51 . An alternate embodiment of the present invention is
shown in Figures 10-1 2 employing a single electrochemical reaction cell
70 including a single rotating cage 28 filled with a multiplicity of anode
particles 32 which operates funtionally equivalent to the
electrochemical cell 14. In this embodiment the electrochemical
reaction cell 70 surrounds the motor 1 5 in a concentric arrangement
with the main drive shaft 1 9 directly connected to the single reaction
cell 70 through a hub 72 without the need for the gear assembly 20 of
Figure 1 . As shown in Figure 1 2 the hub 72 forms a carousel for
rotating the cage 28 containing the anode particles 32. A plurality of
vanes 74 are located at the bottom end of the cage 28 to assist in the
control of the direction of flow of fluid electrolyte 34 through the cage
28 in a manner similar to that of Figure 3 with the vanes 74 being
functionally equivalent in operation to the vanes 36. For simplicity,
identical reference numbers are used to identify components in Figure
1 0 which are identical to their counterparts in Figure 1 . As such the
construction of the cage 28 is not elaborated upon. However, the air
cathode 75 which is functionally equivalent to air cathode 1 8 is
designed for to permit an air flow intake and air flow exhaust through
the engine 1 0 as shown in Figures 1 0 and 1 1 respectively. In this
embodiment the motor 1 5 and rotatable cage 28 rotate in unison and
at the same speed. The motor 1 5 includes an intake fan 1 6 which is
directly connected to the motor 1 5 in the same manner as shown in
Figure 1 such that air is drawn into the engine 10 from the atmosphere and is forced to take a path around the air cathode 75. The
embodiment of Figure 10 operates in a manner substantially equivalent
to the embodiment of Figure 1 in that when the motor 1 5 is energized
the cage 28 rotates to compress the anode particles 32 against one
another and against the cage 28.

Claims

What we claim is:
1 - An electrochemical radial cell engine comprising an engine block, a motor supported by the engine block and at least one electrochemical reaction cell having a rotatable enclosure containing a source of anode material, a fluid electrolyte, a cathode spaced apart from the enclosure to permit rotation of the enclosure relative to the cathode, and means for rotating the enclosure during rotation of the motor.
2- An electrochemical radial cell engine as defined in claim 1 wherein said rotatable enclosure is in the form of a cage rotatable within said engine.
3- An electrochemical radial cell engine as defined in claim
2 wherein said cathode and rotatable cage are each of cylindrical geometry and wherein the space between said cathode and anode is radial.
4- An electrochemical radial cell engine as defined in claim
3 wherein the source of anode material is a multiplicity of anode particles maintained under compression during the rotation of said cage by centrifugal force. 5- An electrochemical radial cell engine as defined in claim
4 wherein said rotatable cage has an outer periphery composed of a conductive material in the form of a screen.
6- An electrochemical radial cell engine as defined in claim
5 wherein said screen is covered by a fluid permeable membrane which permits fluid electrolyte to pass therethrough.
7- An electrochemical radial cell engine as defined in claim 4 wherein said cathode is an air cathode.
8- An electrochemical radial cell engine as defined in claim 7 wherein the composition of said anode particles are selected from the group consisting of: group 1 , 2 and 3 of the periodic table and alloys thereof. 9- An electrochemical radial cell engine as defined in claim 3 wherein the source of anode material is mercury.
1 0- An electrochemical radial cell engine as defined in claim 8 wherein said engine block and said electrochemical cell form a sealed enclosure for said fluid electrolyte with said fluid electrolyte having a closed circulation path extending through said rotatable cage and around said radial space.
1 1 - An electrochemical radial cell engine as defined in claim 1 0 wherein said radial space is constant in radial dimension around the periphery of said cage.
1 2- An electrochemical radial cell engine as defined in claim 1 1 further comprising a fan coupled to said motor for directing air through said motor and through said air cathode.
1 3- An electrochemical radial cell engine as defined in claim 1 2 wherein air is directed to flow first through said motor and then past said air cathode before being exhausted into the atmosphere.
1 4- An electrochemical radial cell engine as defined in claim 1 2 wherein said motor is either a DC or AC motor.
1 5- An electrochemical radial cell engine as defined in claim 8 further comprising a plurality of electrochemical cells arranged symmetrically around said motor.
1 6- An electrochemical radial cell engine as defined in claim 1 5 wherein said motor has a drive shaft in common with the drive shaft for said engine and said plurality of electrochemical cells are connected to the drive shaft of said motor.
1 7- An electrochemical radial cell engine as defined in claim 1 6 further comprising a gear assembly for connecting said plurality of electrochemical cells to said motor.
1 8- An electrochemical radial cell engine as defined in claim 1 7 wherein said gear assembly comprises a main gear and a plurality of slave gears with each slave gear connected to the rotatable cage.
1 9- An electrochemical radial cell engine as defined in claim 8 including only one electrochemical cell arranged concentrically about said motor and connected directly thereto.
20- An electrochemical radial cell engine as defined in claim 1 4 wherein said plurality of reaction cells are electrically connected in a configuration represented by a series, parallel or a combination of series and parallel connections. 21 - An electrochemical radial cell engine as defined in claim 20 further comprising a controller for automatically arranging the electrical configuration of said plurality of reaction cells in response to engine demand.
22- An electrochemical radial cell engine as defined in claim 20 wherein said plurality of reaction cells are electrically connected to a common printed circuit board.
23- An electrochemical radial cell engine as defined in claim 1 having a first set of a plurality of electrochemical reaction cells arranged symmetrically about said motor and a second set of electrochemical reaction cells arranged in tandem with said first set.
PCT/US1998/021057 1998-10-08 1998-10-08 Electrochemical radial cell engine WO2000021147A1 (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
PCT/US1998/021057 WO2000021147A1 (en) 1998-10-08 1998-10-08 Electrochemical radial cell engine

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Application Number Priority Date Filing Date Title
PCT/US1998/021057 WO2000021147A1 (en) 1998-10-08 1998-10-08 Electrochemical radial cell engine

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Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2009007058A1 (en) * 2007-07-12 2009-01-15 Neos International Gmbh Electrochemical power supply for underwater operation with integrated electromotor drive unit
CN108101211A (en) * 2017-12-20 2018-06-01 南通大学 A kind of livestock/poultry wastewater treatment system based on microbiological fuel cell

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GB2128946A (en) * 1982-10-20 1984-05-10 Robert Soderqvist Cattle Electrically propelled vehicles, and a combined energy source and energy reservoir therefor
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US5219672A (en) * 1991-08-12 1993-06-15 Tacticon Corporation Metal/air battery cell and assembly therefor
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GB2128946A (en) * 1982-10-20 1984-05-10 Robert Soderqvist Cattle Electrically propelled vehicles, and a combined energy source and energy reservoir therefor
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CN108101211A (en) * 2017-12-20 2018-06-01 南通大学 A kind of livestock/poultry wastewater treatment system based on microbiological fuel cell
CN108101211B (en) * 2017-12-20 2020-03-27 南通大学 Livestock wastewater treatment system based on microbial fuel cell

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