WO2000020265A1 - Wiper blade and stem with enhanced mechanical properties, and method for obtaining same - Google Patents

Wiper blade and stem with enhanced mechanical properties, and method for obtaining same Download PDF

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Publication number
WO2000020265A1
WO2000020265A1 PCT/FR1999/002279 FR9902279W WO0020265A1 WO 2000020265 A1 WO2000020265 A1 WO 2000020265A1 FR 9902279 W FR9902279 W FR 9902279W WO 0020265 A1 WO0020265 A1 WO 0020265A1
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WO
WIPO (PCT)
Prior art keywords
fibers
wiper blade
heel
hinge
blade according
Prior art date
Application number
PCT/FR1999/002279
Other languages
French (fr)
Inventor
Catherine Evo
Original Assignee
Valeo Systemes D'essuyage Service Propriete Industrielle
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Publication date
Application filed by Valeo Systemes D'essuyage Service Propriete Industrielle filed Critical Valeo Systemes D'essuyage Service Propriete Industrielle
Publication of WO2000020265A1 publication Critical patent/WO2000020265A1/en

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Classifications

    • BPERFORMING OPERATIONS; TRANSPORTING
    • B60VEHICLES IN GENERAL
    • B60SSERVICING, CLEANING, REPAIRING, SUPPORTING, LIFTING, OR MANOEUVRING OF VEHICLES, NOT OTHERWISE PROVIDED FOR
    • B60S1/00Cleaning of vehicles
    • B60S1/02Cleaning windscreens, windows or optical devices
    • B60S1/04Wipers or the like, e.g. scrapers
    • B60S1/32Wipers or the like, e.g. scrapers characterised by constructional features of wiper blade arms or blades
    • B60S1/38Wiper blades
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29CSHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C48/00Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired form; Apparatus therefor
    • B29C48/022Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired form; Apparatus therefor characterised by the choice of material
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29CSHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C48/00Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired form; Apparatus therefor
    • B29C48/03Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired form; Apparatus therefor characterised by the shape of the extruded material at extrusion
    • B29C48/12Articles with an irregular circumference when viewed in cross-section, e.g. window profiles
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29CSHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C48/00Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired form; Apparatus therefor
    • B29C48/25Component parts, details or accessories; Auxiliary operations
    • B29C48/30Extrusion nozzles or dies
    • B29C48/304Extrusion nozzles or dies specially adapted for bringing together components, e.g. melts within the die
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29KINDEXING SCHEME ASSOCIATED WITH SUBCLASSES B29B, B29C OR B29D, RELATING TO MOULDING MATERIALS OR TO MATERIALS FOR MOULDS, REINFORCEMENTS, FILLERS OR PREFORMED PARTS, e.g. INSERTS
    • B29K2105/00Condition, form or state of moulded material or of the material to be shaped
    • B29K2105/06Condition, form or state of moulded material or of the material to be shaped containing reinforcements, fillers or inserts
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29LINDEXING SCHEME ASSOCIATED WITH SUBCLASS B29C, RELATING TO PARTICULAR ARTICLES
    • B29L2031/00Other particular articles
    • B29L2031/30Vehicles, e.g. ships or aircraft, or body parts thereof
    • B29L2031/305Wipers
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B60VEHICLES IN GENERAL
    • B60SSERVICING, CLEANING, REPAIRING, SUPPORTING, LIFTING, OR MANOEUVRING OF VEHICLES, NOT OTHERWISE PROVIDED FOR
    • B60S1/00Cleaning of vehicles
    • B60S1/02Cleaning windscreens, windows or optical devices
    • B60S1/04Wipers or the like, e.g. scrapers
    • B60S1/32Wipers or the like, e.g. scrapers characterised by constructional features of wiper blade arms or blades
    • B60S1/38Wiper blades
    • B60S2001/3827Wiper blades characterised by the squeegee or blade rubber or wiping element
    • B60S2001/3829Wiper blades characterised by the squeegee or blade rubber or wiping element characterised by the material of the squeegee or coating thereof

Definitions

  • Wiper blade and blade with improved mechanical properties and method for obtaining such a blade
  • the invention relates to the field of wiping, and more particularly the wiper blades of a motor vehicle and the blades of these brushes.
  • the wiper blade obtained by extrusion or by molding, is made of an elastically deformable material.
  • the molding can be carried out from rubber blanks, by vulcanization or pre-vulcanization.
  • the extruded or molded blade has three parts, successively succeeding along the median axis of the section of transverse symmetry of the blade:
  • a connecting part forming a hinge of articulation between the two other parts;
  • a lip part generally in the shape of an arrow, to perform the wiping function by scraping in cooperation with the surface of the window to be wiped.
  • the problem is to be able to have a blade of which each part can perform different functions requiring different qualities, even antagonistic: rigidity of the heel part to allow its mounting on an articulated support structure of the broom, resistance of the part of connection to tensile / compression forces and alternating bending while remaining flexible, flexibility of the lip part for effective wiping.
  • the blade is generally made of an elastic material, a synthetic elastomer or a natural rubber.
  • rigidity or mechanical strength it is known to provide longitudinal reinforcing vertebrae in the heel part and in the connecting part.
  • the vertebrae are made in the form of reinforcing plates, inserted into housings during extrusion, or inserts embedded in the body of material. The shape and location of these vertebrae are adapted to obtain the desired properties without excessively affecting the flexibility and elasticity of the blade.
  • the invention aims to distribute the bearing pressures uniformly in order to obtain stiffening and homogeneous resistance optimized, respectively for the heel and the hinge. To do this, it is proposed to incorporate fibers into the material of these parts.
  • the invention relates to a wiper blade, in particular for a motor vehicle, comprising a blade of elastically deformable material having a heel portion for mounting on a wiper support, a scraping lip portion to ensure wiping in cooperation with the surface of a window to be wiped, and a hinge part between the heel and lip parts, in the material of which reinforcing fibers made adherent are incorporated with homogeneous fiber rates in the hinge and in the heel, the rate of fibers in the heel being greater than or equal to the rate of fibers in the hinge.
  • the fiber levels are homogeneous in the sense that the fibers are distributed homogeneously in the heel and the hinge of the blade, without being limited to constant values, that is to say covering, for example, uniformly variable values.
  • the fibers can be fillers of polymers produced by the textile industry, chosen from the group of aramids, polyesters and polyamides.
  • the fibers can also be made of glass filaments.
  • the fiber content is advantageously between 2 and 10 parts per 100 parts by weight in the hinge, and between 10 and 20 parts per 100 parts in the heel.
  • the fibers are made adherent or "adhered” by chemical pretreatment to facilitate their adhesion to the elastic material, so as not to cause delamination between the fibers and the elastic material. They are pretreated for example by treatment of the RFL (“Resorcinol Formaldehyde Latex”) type or by coating with a polymer. In this case, the dispersion in the material and therefore homogenization are favored.
  • RFL Resorcinol Formaldehyde Latex
  • the textile fibers are cut or pulped.
  • the fibers In cut form, the fibers have an average length and a diameter adapted to the dimensions and to the nature of the elastic material used, in order to obtain a reinforcement optimized in quality and duration.
  • the cut fibers In an exemplary embodiment, the cut fibers have an average length of the order of 1 to a few millimeters, preferably from 1 to 3 mm.
  • the pulp is in the form of fiber agglomerates, obtained from fibers from continuous filaments, according to a three-dimensional network.
  • the fibers are predispersed in a polymeric binder before being incorporated;
  • pre-pasta pulp has optimized isotropic mechanical properties, without any difficulty in dispersing appearing in the mixture based on elastic material;
  • the fiber material is combined with vertebrae of dimension substantially reduced compared to that of known vertebrae.
  • the blade according to the present invention has improved resistance to chemical agents, in particular to windshield washer fluid, as well as excellent resistance to temperature and to aging.
  • the invention also relates to a process for obtaining a wiper blade according to the above teaching, in which the fibers can advantageously be pre-dispersed or precut.
  • a first mode called "open mixer”
  • the fibers are incorporated in a mixer after plasticization of the masterbatch of the elastic material, the incorporation of the fibers being carried out gradually, before the incorporation of the vulcanization system.
  • the elastomeric polymer, half of the fillers of the mixture and half of the fibers are kneaded in the mixer for a given time, then the rest of the fibers and fillers are introduced and kneaded at the same time, before the introduction and kneading of the other finishing ingredients.
  • FIG. 2 a view similar to that of Figure 1 illustrating a second embodiment according to the invention.
  • the cross-sectional view shows a wiper blade, or squeegee 10 for a wiper blade (not shown) of a motor vehicle.
  • the blade 10 has a heel part 12, a connecting part 14 and a scraping part 16.
  • the heel 12 which extends longitudinally, is designed to be received in a series of claws (not shown) of a support for blade with articulated structure, belonging to a wiper blade.
  • the heel 12 is solid with respect to the other parts of the blade.
  • the elastomeric material, used to form the blade 10 in this embodiment, is reinforced in the heel by aramid fibers cut 18, uniformly dispersed in the material and incorporated into the elastomeric material during extrusion according to a process described below.
  • aramid fibers cut 18 uniformly dispersed in the material and incorporated into the elastomeric material during extrusion according to a process described below.
  • the scraping part 16 has, in cross section, an arrow-shaped lip whose tip 20 cooperates with the window to be wiped.
  • the scraping part 16 is connected to the heel 12 by the central connecting strip 14, which is extruded at the same time as the heel and the scraping part 16.
  • the connecting strip 14 extends longitudinally in the median plane P-P of the cross section of the blade.
  • the elastomeric material of the connecting strip 14 is reinforced by aramid fibers, uniformly dispersed in the material and incorporated into it during extrusion according to a process described below.
  • the percentage of fibers relative to the material thus loaded represents approximately 6% in the strip.
  • the incorporation of the fibers does not stop clearly at the junction of the strip 14 with the lip 16, but advantageously extends around this junction in order to reinforce it effectively.
  • the aramid fibers 18 are cut and have an average length of the order of 1 mm.
  • the fibers are in pulp, in the form of agglomerates 19, obtained by grinding aramid fibers, to form a three-dimensional network.
  • These pulp fibers are known under the trade name TWARON ® ® Rhenogran or if they are predispersed in a polymeric binder. Whether the fibers are cut or ground, they are pretreated before extrusion so that they can adhere intimately to the elastomeric material or rubber during extrusion. This treatment is a chemical treatment of the type
  • the incorporation of pretreated fibers, and possibly pre-dispersed, into the elastomeric material is carried out during kneading in an open mixer.
  • the fibers are incorporated into the open mixer after plasticization of the masterbatch, under known speed and temperature conditions, the incorporation of the fibers being carried out gradually, before incorporation of the vulcanization system.
  • the flow of fibers made directive according to known techniques, makes it possible to directly and selectively load the heel and the binding strip until the concentration levels respectively targeted are reached, ie approximately 15 and 6% in the preceding examples. The mixture thus loaded is taken out at the end of extrusion.
  • the incorporation is carried out in an internal mixer, of the Banbury type.
  • the temperature of the mixer being from 30 to 50 ° C and the speed from 70 to 80 rpm.
  • a first kneading relates to the polymer, half of fillers and half of pretreated fibers.
  • the second half-charge of fibers and the rest of the charges are incorporated and kneaded for a period equal to that of the first kneading.
  • the other finishing ingredients, plasticizer and carbon black are incorporated for a final kneading which lasts, in the embodiment, three times the time interval covering the first two kneading.
  • coextrusion with the base material of the lip is finally carried out to obtain the lip blade without fibers.
  • the invention is not limited to the embodiments described and shown. It is for example possible to provide a decreasing fiber concentration along the connecting hinge, between a value close to that of the heel and a value close to zero at the scraping lip.
  • the lip can also be reinforced with fibers with a low concentration rate, for example from one to a few parts / phr.
  • a pre-pasta pulp has optimized isotropic mechanical properties, without any difficulty in dispersing appearing in the mixture based on elastic material.
  • the hinge may comprise one or two pairs of lateral wings, which extend on either side of the hinge, and possibly integrated into the scraping part, reference 21 in FIGS. 1 and 2, to ensure protecting the blade from the brush holder claws and isolating the scraping lip from the rest of the brush.
  • These wings, as well as the lip itself, can also be loaded with fibers in accordance with the invention at a rate substantially lower than that of the connecting hinge.

Abstract

The invention aims at distributing uniformly the pressure so as to provide optimised homogeneous rigidity and resistance, for the heel and the hinge of the blade respectively. More particularly, the invention concerns a wiper stem (10) made of elastically deformable material, for example elastomer, and comprises a heel part (12) for being mounted on a wiper-holder, a scraping lip portion (16) for wiping in co-operation with the surface of a window pane to be wiped, and a hinge part (14) between the heel and lip portions. In the stem material, reinforcing fibres (18) provided with adhesive properties are incorporated with homogeneous fibre ratios in the hinge and the heel, the fibre ratio in the heel being not less than the fibre ratio in the hinge.

Description

Balai et lame d'essuie-glace à propriétés mécaniques améliorées, et procédé d'obtention d'une telle lame Wiper blade and blade with improved mechanical properties, and method for obtaining such a blade
L'invention concerne le domaine de l'essuyage, et plus particulièrement les balais d'essuie-glace de véhicule automobile et les lames de ces balais.The invention relates to the field of wiping, and more particularly the wiper blades of a motor vehicle and the blades of these brushes.
La lame de balai d'essuyage, obtenue par extrusion ou par moulage, est composée d'un matériau élastiquement deformable. Le moulage peut être effectué à partir d'ébauches caoutchouc, par vulcanisation ou prévulcanisation. La lame extrudée ou moulée comporte trois parties, de succédant successivement le long de l'axe médian de la section de symétrie transversale de la lame:The wiper blade, obtained by extrusion or by molding, is made of an elastically deformable material. The molding can be carried out from rubber blanks, by vulcanization or pre-vulcanization. The extruded or molded blade has three parts, successively succeeding along the median axis of the section of transverse symmetry of the blade:
- une partie talon, pour réaliser le montage de la lame sur une armature à palonniers et étriers, l'armature et la lame constituant le balai ;- a heel part, for mounting the blade on a frame with spreaders and stirrups, the frame and the blade constituting the broom;
- une partie de liaison, formant une charnière d'articulation entre les deux autres parties ; - et une partie lèvre, généralement en forme de flèche, pour réaliser la fonction d'essuyage par raclage en coopération avec la surface de la vitre à essuyer.- a connecting part, forming a hinge of articulation between the two other parts; - And a lip part, generally in the shape of an arrow, to perform the wiping function by scraping in cooperation with the surface of the window to be wiped.
Un exemple de réalisation d'une telle lame est décrit dans le brevet FR-A-2 253 649 (ou 94 01 057).An exemplary embodiment of such a blade is described in patent FR-A-2 253 649 (or 94 01 057).
Le problème posé est de pouvoir disposer d'une lame dont chaque partie puisse assurer des fonctions différentes nécessitant des qualités différentes, voire antagonistes : rigidité de la partie talon pour permettre son montage sur une structure articulée de support du balai, résistance de la partie de liaison aux efforts de traction/compression et aux flexions alternées tout en restant flexible, souplesse de la partie lèvre pour effectuer un essuyage efficace. La lame est généralement constituée en un matériau élastique, un élastomère synthétique ou un caoutchouc naturel. Afin d'obtenir une rigidité ou une résistance mécanique, il est connu de prévoir des vertèbres longitudinales de renfort dans la partie talon et dans la partie de liaison. Les vertèbres sont réalisées sous forme de plaques de renfort, insérées dans des logements lors de l'extrusion, ou d'inserts noyés dans le corps en matériau. La forme et la localisation de ces vertèbres sont adaptées afin d'obtenir les propriétés recherchées sans nuire excessivement à la flexibilité et à l'élasticité de la lame.The problem is to be able to have a blade of which each part can perform different functions requiring different qualities, even antagonistic: rigidity of the heel part to allow its mounting on an articulated support structure of the broom, resistance of the part of connection to tensile / compression forces and alternating bending while remaining flexible, flexibility of the lip part for effective wiping. The blade is generally made of an elastic material, a synthetic elastomer or a natural rubber. In order to obtain rigidity or mechanical strength, it is known to provide longitudinal reinforcing vertebrae in the heel part and in the connecting part. The vertebrae are made in the form of reinforcing plates, inserted into housings during extrusion, or inserts embedded in the body of material. The shape and location of these vertebrae are adapted to obtain the desired properties without excessively affecting the flexibility and elasticity of the blade.
Cependant, l'addition des vertèbres augmente la déformation de la lame au niveau de son support, en particulier autour des griffes de maintien. De plus, ce type de solution diminue la durée de vie de la lame qui s'use, se déforme, et risque de se déchirer, en particulier au niveau de la charnière, plus rapidement qu'une lame sans vertèbre.However, the addition of the vertebrae increases the deformation of the blade at the level of its support, in particular around the retaining claws. In addition, this type of solution reduces the life of the blade which wears out, deforms, and risks becoming tear, especially at the hinge, faster than a blade without a vertebra.
Afin de pallier ces inconvénients, et notamment afin d'améliorer la résistance à la compression et la tenue au fluage pour diminuer la déformation rémanente de la lame, l'invention vise à répartir uniformément les pressions d'appui afin d'obtenir une rigidification et une résistance homogènes optimisées, respectivement pour le talon et la charnière. Pour ce faire, il est proposé d'incorporer des fibres dans le matériau de ces parties.In order to overcome these drawbacks, and in particular in order to improve the compressive strength and the creep resistance to reduce the residual deformation of the blade, the invention aims to distribute the bearing pressures uniformly in order to obtain stiffening and homogeneous resistance optimized, respectively for the heel and the hinge. To do this, it is proposed to incorporate fibers into the material of these parts.
Plus précisément, l'invention a pour objet un balai d'essuie-glace, en particulier pour véhicule automobile, comportant une lame en matériau elastiquement deformable ayant une partie talon de montage sur un support d'essuie-glace, une partie lèvre de raclage pour assurer l'essuyage en coopération avec la surface d'une vitre à essuyer, et une partie charnière entre les parties talon et lèvre, dans le matériau de laquelle des fibres de renfort rendues adhérentes sont incorporées avec des taux de fibres homogènes dans la charnière et dans le talon, le taux de fibres dans le talon étant supérieur ou égal au taux de fibres dans la charnière.More specifically, the invention relates to a wiper blade, in particular for a motor vehicle, comprising a blade of elastically deformable material having a heel portion for mounting on a wiper support, a scraping lip portion to ensure wiping in cooperation with the surface of a window to be wiped, and a hinge part between the heel and lip parts, in the material of which reinforcing fibers made adherent are incorporated with homogeneous fiber rates in the hinge and in the heel, the rate of fibers in the heel being greater than or equal to the rate of fibers in the hinge.
Les taux de fibres sont homogènes en ce sens que les fibres sont réparties de manière homogène dans le talon et la charnière de la lame, sans être limités à des valeurs constantes, c'est-à-dire couvrant par exemple des valeurs uniformément variables.The fiber levels are homogeneous in the sense that the fibers are distributed homogeneously in the heel and the hinge of the blade, without being limited to constant values, that is to say covering, for example, uniformly variable values.
Les fibres peuvent être des charges de polymères produites par l'industrie textile, choisies dans le groupe des aramides, polyesters et polyamides. Les fibres peuvent également être en filaments de verre. Le taux de fibres est avantageusement compris entre 2 et 10 parts pour 100 parts en poids dans la charnière, et entre 10 et 20 parts pour 100 parts dans le talon.The fibers can be fillers of polymers produced by the textile industry, chosen from the group of aramids, polyesters and polyamides. The fibers can also be made of glass filaments. The fiber content is advantageously between 2 and 10 parts per 100 parts by weight in the hinge, and between 10 and 20 parts per 100 parts in the heel.
Les fibres sont rendues adhérentes ou « adhérisées » par prétraitement chimique pour faciliter leur adhésion au matériau élastique, afin de ne pas provoquer de délaminage entre les fibres et le matériau élastique. Elles sont prétraitées par exemple par traitement de type RFL (« Resorcinol Formaldéhyde Latex ») ou par enrobage d'un polymère. Dans ce cas, la dispersion dans le matériau et donc l'homogénéisation sont favorisées.The fibers are made adherent or "adhered" by chemical pretreatment to facilitate their adhesion to the elastic material, so as not to cause delamination between the fibers and the elastic material. They are pretreated for example by treatment of the RFL (“Resorcinol Formaldehyde Latex”) type or by coating with a polymer. In this case, the dispersion in the material and therefore homogenization are favored.
Selon deux formes de mise en œuvre, les fibres textiles se présentent coupées ou en pulpe.According to two forms of implementation, the textile fibers are cut or pulped.
Sous forme coupée, les fibres ont une longueur moyenne et un diamètre adaptées aux dimensions et à la nature du matériau élastique utilisé, afin d'obtenir un renfort optimisé en qualité et en durée. Dans un exemple de réalisation, les fibres coupées ont une longueur moyenne de l'ordre de 1 à quelques millimètres, de préférence de 1 à 3 mm.In cut form, the fibers have an average length and a diameter adapted to the dimensions and to the nature of the elastic material used, in order to obtain a reinforcement optimized in quality and duration. In an exemplary embodiment, the cut fibers have an average length of the order of 1 to a few millimeters, preferably from 1 to 3 mm.
La pulpe se présente sous la forme d'agglomérats de fibres, obtenu à partir de fibres issues de filaments continus, selon un réseau tridimensionnel.The pulp is in the form of fiber agglomerates, obtained from fibers from continuous filaments, according to a three-dimensional network.
Selon des modes particuliers de réalisation :According to particular embodiments:
- les fibres sont prédispersées dans un liant polymérique avant d'être incorporées ;- the fibers are predispersed in a polymeric binder before being incorporated;
- une pulpe préempâtée présente des propriétés mécaniques isotropes optimisées, sans qu'apparaissent de difficultés de dispersion dans le mélange à base de matériau élastique ;- a pre-pasta pulp has optimized isotropic mechanical properties, without any difficulty in dispersing appearing in the mixture based on elastic material;
- le matériau à fibres est combiné à des vertèbres de dimension sensiblement diminuée par rapport à celle des vertèbres connues.- The fiber material is combined with vertebrae of dimension substantially reduced compared to that of known vertebrae.
La lame selon la présente invention présente une tenue améliorée aux agents chimiques, notamment au liquide de lave-glace, ainsi qu'une excellente tenue en température et au vieillissement.The blade according to the present invention has improved resistance to chemical agents, in particular to windshield washer fluid, as well as excellent resistance to temperature and to aging.
L'invention se rapporte également à un procédé d'obtention d'une lame d'essuie-glace conforme à l'enseignement ci-dessus, dans lequel les fibres peuvent être avantageusement prédispersées ou précoupées. Selon un premier mode, dit « à mélangeur ouvert », les fibres sont incorporées dans un mélangeur après plastification du mélange maître du matériau élastique, l'incorporation des fibres se faisant de façon progressive, avant l'incorporation du système de vulcanisation.The invention also relates to a process for obtaining a wiper blade according to the above teaching, in which the fibers can advantageously be pre-dispersed or precut. According to a first mode, called "open mixer", the fibers are incorporated in a mixer after plasticization of the masterbatch of the elastic material, the incorporation of the fibers being carried out gradually, before the incorporation of the vulcanization system.
Selon un autre mode de mise en œuvre, dit à « mélangeur interne », le polymère élastomère, une moitié de charges du mélange et une moitié des fibres sont malaxées dans le mélangeur pendant un temps donné, puis le reste des fibres et des charges sont introduites et malaxées pendant le même temps, avant l'introduction et le malaxage des autres ingrédients de finition.According to another embodiment, known as an “internal mixer”, the elastomeric polymer, half of the fillers of the mixture and half of the fibers are kneaded in the mixer for a given time, then the rest of the fibers and fillers are introduced and kneaded at the same time, before the introduction and kneading of the other finishing ingredients.
D'autres caractéristiques et avantages de l'invention apparaîtront à la lecture de la description détaillée d'exemples de réalisation qui suit, accompagnée des figures annexées qui représentent respectivement :Other characteristics and advantages of the invention will appear on reading the detailed description of exemplary embodiments which follows, accompanied by the appended figures which represent respectively:
- la figure 1 , une vue en coupe transversale d'une lame d'essuie-glace selon une première forme de réalisation conforme à l'invention ; et- Figure 1, a cross-sectional view of a wiper blade according to a first embodiment according to the invention; and
- la figure 2, une vue similaire à celle de la figure 1 illustrant une deuxième forme de réalisation conforme à l'invention. Sur la figure 1 , la vue en coupe transversale présente une lame, ou raclette, d'essuyage 10 pour un balai d'essuyage (non représenté) d'un véhicule automobile.- Figure 2, a view similar to that of Figure 1 illustrating a second embodiment according to the invention. In Figure 1, the cross-sectional view shows a wiper blade, or squeegee 10 for a wiper blade (not shown) of a motor vehicle.
La lame 10 comporte une partie talon 12, une partie de liaison 14 et une partie de raclage 16. Le talon 12, qui s'étend longitudinalement, est prévu pour être reçu dans une série de griffes (non représentées) d'un support de lame à structure articulée, appartenant à un balai d'essuie-glace. Le talon 12 est massif au regard des autres parties de la lame.The blade 10 has a heel part 12, a connecting part 14 and a scraping part 16. The heel 12, which extends longitudinally, is designed to be received in a series of claws (not shown) of a support for blade with articulated structure, belonging to a wiper blade. The heel 12 is solid with respect to the other parts of the blade.
Le matériau élastomère, utilisé pour constituer la lame 10 dans cet exemple de réalisation, est renforcé dans le talon par des fibres d'aramide coupées 18, uniformément dispersées dans le matériau et incorporées dans le matériau élastomère lors de l'extrusion selon un procédé décrit ci-après. En poids, le pourcentage de fibres par rapport au matériau ainsi chargé représente environ 15%.The elastomeric material, used to form the blade 10 in this embodiment, is reinforced in the heel by aramid fibers cut 18, uniformly dispersed in the material and incorporated into the elastomeric material during extrusion according to a process described below. By weight, the percentage of fibers relative to the material thus loaded represents approximately 15%.
Dans les formes de mise en œuvre illustrées, la partie de raclage 16 présente, en section transversale, une lèvre en forme de flèche dont la pointe 20 coopère avec la vitre à essuyer. La partie de raclage 16 est reliée au talon 12 par la bande médiane de liaison 14, qui est extrudée en même temps que le talon et la partie de raclage 16.In the illustrated embodiments, the scraping part 16 has, in cross section, an arrow-shaped lip whose tip 20 cooperates with the window to be wiped. The scraping part 16 is connected to the heel 12 by the central connecting strip 14, which is extruded at the same time as the heel and the scraping part 16.
La bande de liaison 14 s'étend longitudinalement dans le plan médian P-P de la section transversale de la lame. Conformément à l'invention, le matériau élastomère de la bande de liaison 14 est renforcée par des fibres d'aramide, uniformément dispersées dans le matériau et incorporées dans celui-ci lors de l'extrusion selon un procédé décrit ci-après. En poids, le pourcentage de fibres par rapport au matériau ainsi chargé représente environ 6% dans la bande. L'incorporation des fibres ne s'arrête pas de manière nette au niveau de la jonction de la bande 14 avec la lèvre 16, mais déborde avantageusement autour de cette jonction afin de la renforcer efficacement.The connecting strip 14 extends longitudinally in the median plane P-P of the cross section of the blade. According to the invention, the elastomeric material of the connecting strip 14 is reinforced by aramid fibers, uniformly dispersed in the material and incorporated into it during extrusion according to a process described below. By weight, the percentage of fibers relative to the material thus loaded represents approximately 6% in the strip. The incorporation of the fibers does not stop clearly at the junction of the strip 14 with the lip 16, but advantageously extends around this junction in order to reinforce it effectively.
Dans la première forme de réalisation illustrée à la figure 1 , les fibres d'aramide 18 sont coupées et présentent une longueur moyenne de l'ordre de 1 mm. Dans la deuxième forme de réalisation illustrée à la figure 2, les fibres se présentent en pulpe, sous la forme d'agglomérats 19, obtenus par broyage de fibres d'aramide, pour former un réseau tridimensionnel. Ces fibres en pulpe sont connues sous la dénomination commerciale TWARON® ou RHENOGRAN® si elles sont prédispersées dans un liant polymérique. Que les fibres soient coupées ou broyées, elles sont prétraitées avant l'extrusion afin de pouvoir adhérer intimement au matériau élastomère ou au caoutchouc lors de l'extrusion. Ce traitement est un traitement chimique de typeIn the first embodiment illustrated in FIG. 1, the aramid fibers 18 are cut and have an average length of the order of 1 mm. In the second embodiment illustrated in Figure 2, the fibers are in pulp, in the form of agglomerates 19, obtained by grinding aramid fibers, to form a three-dimensional network. These pulp fibers are known under the trade name TWARON ® ® Rhenogran or if they are predispersed in a polymeric binder. Whether the fibers are cut or ground, they are pretreated before extrusion so that they can adhere intimately to the elastomeric material or rubber during extrusion. This treatment is a chemical treatment of the type
« RFL ». Un enrobage des fibres par un polymère dispersif peut également être réalisé."RFL". Coating of the fibers with a dispersive polymer can also be carried out.
L'incorporation des fibres prétraitées, et éventuellement prédispersées, au matériau élastomère est réalisée lors d'un malaxage en mélangeur ouvert. Selon ce procédé, les fibres sont incorporées dans le mélangeur ouvert après plastification du mélange maître, dans des conditions de vitesse et de température connues, l'incorporation des fibres se faisant de façon progressive, avant incorporation du système de vulcanisation. Le flux de fibres, rendu directif selon des techniques connues, permet de charger directement et sélectivement le talon et la bande de liaison jusqu'à atteindre les taux de concentration respectivement visés, soient environ 15 et 6% dans les exemples précédents. Le mélange ainsi chargé est sorti en fin d'extrusion.The incorporation of pretreated fibers, and possibly pre-dispersed, into the elastomeric material is carried out during kneading in an open mixer. According to this process, the fibers are incorporated into the open mixer after plasticization of the masterbatch, under known speed and temperature conditions, the incorporation of the fibers being carried out gradually, before incorporation of the vulcanization system. The flow of fibers, made directive according to known techniques, makes it possible to directly and selectively load the heel and the binding strip until the concentration levels respectively targeted are reached, ie approximately 15 and 6% in the preceding examples. The mixture thus loaded is taken out at the end of extrusion.
En variante, l'incorporation est réalisée en mélangeur interne, de type Banbury. La température du mélangeur étant de 30 à 50°C et la vitesse de 70 à 80 rpm. Pendant une durée de 30 secondes, un premier malaxage concerne le polymère, une moitié de charges et une moitié de fibres prétraitées. A l'issu de cette opération, la seconde demi-charge de fibres et le reste des charges sont incorporés et malaxés pendant une durée égale à celle du premier malaxage. Les autres ingrédients de finition, plastifiant et noir de carbone, sont incorporés pour un malaxage final qui dure, dans l'exemple de réalisation, trois fois l'intervalle de temps couvrant les deux premiers malaxages. Que ce soit en mélageur ouvert ou interne, une coextrusion avec le matériau de base de la lèvre est finalement opérée pour obtenir la lame à lèvre sans fibres.As a variant, the incorporation is carried out in an internal mixer, of the Banbury type. The temperature of the mixer being from 30 to 50 ° C and the speed from 70 to 80 rpm. During a period of 30 seconds, a first kneading relates to the polymer, half of fillers and half of pretreated fibers. At the end of this operation, the second half-charge of fibers and the rest of the charges are incorporated and kneaded for a period equal to that of the first kneading. The other finishing ingredients, plasticizer and carbon black, are incorporated for a final kneading which lasts, in the embodiment, three times the time interval covering the first two kneading. Whether in an open or internal mixer, coextrusion with the base material of the lip is finally carried out to obtain the lip blade without fibers.
L'invention n'est pas limitée aux exemples de réalisation décrits et représentés. Il est par exemple possible de prévoir une concentration en fibres décroissante le long de la charnière de liaison, entre une valeur proche de celle du talon et une valeur proche de zéro au niveau de la lèvre de raclage. La lèvre peut également être renforcée de fibres à faible taux de concentration, par exemple de une à quelques parts/phr. Une pulpe préempâtée présente des propriétés mécaniques isotropes optimisées, sans qu'apparaissent de difficultés de dispersion dans le mélange à base de matériau élastique.The invention is not limited to the embodiments described and shown. It is for example possible to provide a decreasing fiber concentration along the connecting hinge, between a value close to that of the heel and a value close to zero at the scraping lip. The lip can also be reinforced with fibers with a low concentration rate, for example from one to a few parts / phr. A pre-pasta pulp has optimized isotropic mechanical properties, without any difficulty in dispersing appearing in the mixture based on elastic material.
Il est également possible de combiner le matériau à fibres à des vertèbres de dimensions sensiblement diminuées par rapport à celles des vertèbres adaptées à ce type d'application.It is also possible to combine the fiber material with vertebrae of dimensions considerably reduced compared to those of the vertebrae adapted to this type of application.
Par ailleurs, la charnière peut comporter une ou deux paires d'ailes latérales, qui s'étendent de part et d'autre de la charnière, et éventuellement intégrées à la partie de raclage, référence 21 sur les figures 1 et 2, pour assure la protection de la lame Visà-vis des griffes du support du balai et isoler la lèvre de raclage du reste du balai. Ces ailes, ainsi que la lèvre elle-même, peuvent être également chargées en fibres conformément à l'invention selon un taux sensiblement inférieur à celui de la charnière de liaison.Furthermore, the hinge may comprise one or two pairs of lateral wings, which extend on either side of the hinge, and possibly integrated into the scraping part, reference 21 in FIGS. 1 and 2, to ensure protecting the blade from the brush holder claws and isolating the scraping lip from the rest of the brush. These wings, as well as the lip itself, can also be loaded with fibers in accordance with the invention at a rate substantially lower than that of the connecting hinge.
De plus, afin de lisser les défauts d'aspect éventuels qui résulteraient de l'extrusion du mélange caoutchouc chargé de fibres, l'homme du métier peut augmenter le nombre de parts de plastifiant. Par ailleurs, en diminuant le taux de noir de carbone par rapport à celui habituellement pratiqué dans ce type de technique, le mélange initial est bien adapté à l'extrusion de fibres conformément à l'enseignement de la présente invention. In addition, in order to smooth out any appearance defects which would result from the extrusion of the rubber mixture filled with fibers, a person skilled in the art can increase the number of parts of plasticizer. Furthermore, by reducing the level of carbon black compared to that usually practiced in this type of technique, the initial mixture is well suited to the extrusion of fibers in accordance with the teaching of the present invention.

Claims

REVENDICATIONS
1. Balai d'essuie-glace, en particulier pour véhicule automobile, comportant une lame en matériau elastiquement deformable, et comportant une partie talon (12) de montage sur un support d'essuie-glace, une partie lèvre (16) de raclage pour assurer l'essuyage en coopération avec la surface d'une vitre à essuyer, et une partie charnière (14) entre les parties talon et lèvre, caractérisé en ce que la lame comporte des fibres de renfort (18,19) adhérisées et incorporées dans le matériau avec des taux de fibres homogènes dans la charnière (14) et dans le talon (12), le taux de fibres dans le talon étant supérieur ou égal au taux de fibres dans la charnière.1. Wiper blade, in particular for a motor vehicle, comprising a blade of elastically deformable material, and comprising a heel portion (12) for mounting on a wiper support, a lip portion (16) for scraping to ensure wiping in cooperation with the surface of a window to be wiped, and a hinge part (14) between the heel and lip parts, characterized in that the blade comprises reinforcing fibers (18,19) adhered and incorporated in the material with homogeneous fiber rates in the hinge (14) and in the heel (12), the fiber rate in the heel being greater than or equal to the fiber rate in the hinge.
2. Lame d'essuie-glace pour balai selon la revendication 1 , caractérisée en ce que les fibres sont choisies parmi des fibres textiles du groupe comprenant des aramides, polyesters, polyamides, et des filaments de verre. 2. A wiper blade for a broom according to claim 1, characterized in that the fibers are chosen from textile fibers from the group comprising aramids, polyesters, polyamides, and glass filaments.
3. Lame d'essuie-glace selon la revendication 2, caractérisée en ce que les fibres textiles sont empâtées par enrobage, afin de favoriser la dispersion des fibres dans le matériau.3. Wiper blade according to claim 2, characterized in that the textile fibers are pasted by coating, in order to promote the dispersion of the fibers in the material.
4. Lame d'essuie-glace selon l'une des revendications 2 et 3, caractérisée en ce que les fibres textiles sont utilisées sous forme coupée (18) selon une longueur moyenne comprise sensiblement entre 1 et 3 mm.4. Wiper blade according to one of claims 2 and 3, characterized in that the textile fibers are used in cut form (18) with an average length of substantially between 1 and 3 mm.
5. Lame d'essuie-glace selon l'une quelconque des revendications 2 à 4, caractérisée en ce que les fibres textiles sont utilisées sous forme de pulpe (19) formée par un agglomérat de fibres obtenu par broyage de filaments continus pour former un réseau tridimensionnel. 5. Wiper blade according to any one of claims 2 to 4, characterized in that the textile fibers are used in the form of pulp (19) formed by an agglomerate of fibers obtained by grinding continuous filaments to form a three-dimensional network.
6. Lame d'essuie-glace selon l'une quelconque des revendications 2 à 5, caractérisée en ce que le taux de fibres est compris entre 2 et 10 parts/phr dans la charnière, et entre 10 et 20 parts pour 100 parts dans le talon.6. Wiper blade according to any one of claims 2 to 5, characterized in that the fiber content is between 2 and 10 parts / phr in the hinge, and between 10 and 20 parts per 100 parts in the heel.
7. Lame d'essuie-glace selon l'une quelconque des revendications 2 à 6, caractérisée en ce que la charnière comporte au moins une paire d'ailes latérales, qui s'étend de part et d'autre, ces ailes étant également chargées en fibres selon un taux égal ou inférieur à celui de la charnière de liaison.7. Wiper blade according to any one of claims 2 to 6, characterized in that the hinge comprises at least one pair of lateral wings, which extends on either side, these wings also being loaded with fibers at a rate equal to or less than that of the connecting hinge.
8. Procédé d'obtention d'une lame d'essuie-glace selon l'une quelconque des revendications précédentes, caractérisé en ce qu'il consiste à utiliser un mélangeur ouvert dans lequel les fibres prétraitées pour être adhésives sont incorporées après plastification du mélange maître, l'incorporation des fibres se faisant de façon progressive avant incorporation du système de vulcanisation, les fibres étant amenées en flux directif pour charger le talon et la charnière de liaison jusqu'à atteindre les taux de concentration respectivement visés, une coextrusion finale étant opérée avec le matériau de la lèvre pour constituer la lame. 8. Method for obtaining a wiper blade according to any one of the preceding claims, characterized in that it consists in using an open mixer in which the fibers pretreated to be adhesive are incorporated after plasticization of the mixture master, the incorporation of the fibers being done so progressive before incorporation of the vulcanization system, the fibers being brought in directional flow to load the heel and the connecting hinge until reaching the respectively targeted concentration rates, a final coextrusion being effected with the material of the lip to constitute the blade .
9. Procédé d'obtention d'une lame d'essuie-glace selon l'une quelconque des revendications 1 à 8, caractérisé en ce qu'il consiste à malaxer pendant un temps donné, dans un mélangeur à température initiale de 30 à 50°C, la charge de polymère élastique avec une première moitié de charges et une moitié de fibres prétraitées pour être adhésives, puis à réaliser un deuxième malaxage avec l'autre demi-charge de fibres et le reste des charges pendant une durée équivalente, puis à introduire les autres ingrédients de finition et à malaxer l'ensemble, une coextrusion finale étant opérée pour constituer une lame à lèvre.9. A method of obtaining a wiper blade according to any one of claims 1 to 8, characterized in that it consists in kneading for a given time, in a mixer at an initial temperature of 30 to 50 ° C, the load of elastic polymer with a first half of fillers and half of fibers pretreated to be adhesive, then to carry out a second kneading with the other half-load of fibers and the rest of the fillers for an equivalent duration, then to introduce the other finishing ingredients and to knead the whole, a final coextrusion being operated to constitute a lip blade.
10. Procédé d'obtention par extrusion d'une lame d'essuie-glace selon l'une des revendications 8 et 9, caractérisé en ce que le prétraitement des fibres est d'ordre chimique obtenu par un procédé de type RFL.10. A method of obtaining by extrusion of a wiper blade according to one of claims 8 and 9, characterized in that the pretreatment of the fibers is chemical obtained by a method of RFL type.
11. Procédé d'obtention par extrusion d'une lame d'essuie-glace selon la revendication 9, caractérisé en ce que la vitesse de rotation du mélangeur est de l'ordre de 70 à 80 rpm et en ce que le malaxage final dure de l'ordre de trois fois la durée des deux premiers malaxages. 11. A method of obtaining by extrusion of a wiper blade according to claim 9, characterized in that the speed of rotation of the mixer is of the order of 70 to 80 rpm and in that the final kneading lasts about three times the duration of the first two mixes.
12. Procédé d'obtention par extrusion d'une lame d'essuie-glace selon l'une des revendications 8 et 9, caractérisé en ce que le prétraitement des fibres est d'ordre mécanique obtenu par enrobage par un polymère présentant des propriétés dispersives.12. Method for obtaining by extrusion of a wiper blade according to one of claims 8 and 9, characterized in that the pretreatment of the fibers is mechanical obtained by coating with a polymer having dispersive properties .
13. Procédé d'obtention selon l'une des revendications 8 et 9, caractérisé en ce que la concentration en fibres décroît le long de la charnière de liaison, entre une valeur proche de celle du talon et une valeur proche de zéro au niveau de la lèvre de raclage. 13. Method of obtaining according to one of claims 8 and 9, characterized in that the fiber concentration decreases along the connecting hinge, between a value close to that of the heel and a value close to zero at the scraping lip.
PCT/FR1999/002279 1998-10-05 1999-09-24 Wiper blade and stem with enhanced mechanical properties, and method for obtaining same WO2000020265A1 (en)

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FR98/12427 1998-10-05
FR9812427A FR2784069B1 (en) 1998-10-05 1998-10-05 WIPER BLADE AND WIPER BLADE WITH IMPROVED MECHANICAL PROPERTIES, AND METHOD FOR OBTAINING SUCH A BLADE

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DE10248790A1 (en) * 2002-10-19 2004-05-19 Volkswagen Ag Windscreen wiper for vehicle, has rod-shaped elements embedded in rubber-elastic blade and distributed over its length and over its breadth so as to cross each other and to form framework or grid
WO2010094742A1 (en) 2009-02-20 2010-08-26 Robert Bosch Gmbh Wiper blade for a window wiper and method for the production of said wiper blade
CN109562741A (en) * 2016-05-13 2019-04-02 法雷奥系统公司 Wiper blade for windscreen wiper frame

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FR2851534B1 (en) * 2003-02-24 2006-04-28 Rhodia Performance Fibres WIPER BLADE / CLEANING A VEHICLE WIPER BLADE
DE102012004797A1 (en) * 2012-03-08 2013-09-12 GM Global Technology Operations LLC (n.d. Ges. d. Staates Delaware) Wiper strip of windscreen wiper assembly of motor car, has wiper lip that is provided with flexible sheath which is partially filled with filling with filling material

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Publication number Priority date Publication date Assignee Title
DE10248790A1 (en) * 2002-10-19 2004-05-19 Volkswagen Ag Windscreen wiper for vehicle, has rod-shaped elements embedded in rubber-elastic blade and distributed over its length and over its breadth so as to cross each other and to form framework or grid
WO2010094742A1 (en) 2009-02-20 2010-08-26 Robert Bosch Gmbh Wiper blade for a window wiper and method for the production of said wiper blade
DE102009001043A1 (en) 2009-02-20 2010-08-26 Robert Bosch Gmbh Wiper blade for a windscreen wiper and method for its production
US8893348B2 (en) 2009-02-20 2014-11-25 Robert Bosch Gmbh Wiper blade for a window wiper and method for the production of said wiper blade
CN109562741A (en) * 2016-05-13 2019-04-02 法雷奥系统公司 Wiper blade for windscreen wiper frame
CN109562741B (en) * 2016-05-13 2022-11-01 法雷奥系统公司 Wiper blade for a windscreen wiper frame

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