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WO2000010698A3 - Fischer-tropsch processes using catalysts on mesoporous supports - Google Patents

Fischer-tropsch processes using catalysts on mesoporous supports

Info

Publication number
WO2000010698A3
WO2000010698A3 PCT/US1999/018994 US9918994W WO2000010698A3 WO 2000010698 A3 WO2000010698 A3 WO 2000010698A3 US 9918994 W US9918994 W US 9918994W WO 2000010698 A3 WO2000010698 A3 WO 2000010698A3
Authority
WO
Grant status
Application
Patent type
Prior art keywords
fischer
tropsch
catalyst
stream
hydrocarbons
Prior art date
Application number
PCT/US1999/018994
Other languages
French (fr)
Other versions
WO2000010698A2 (en )
Inventor
Leo E Manzer
Stephan Schwarz
Original Assignee
Conoco Inc
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10GCRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G2/00Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon
    • C10G2/30Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon from carbon monoxide with hydrogen
    • C10G2/32Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon from carbon monoxide with hydrogen with the use of catalysts
    • C10G2/33Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon from carbon monoxide with hydrogen with the use of catalysts characterised by the catalyst used
    • C10G2/331Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon from carbon monoxide with hydrogen with the use of catalysts characterised by the catalyst used containing group VIII-metals
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS, COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J21/00Catalysts comprising the elements, oxides, or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium, or hafnium
    • B01J21/06Silicon, titanium, zirconium or hafnium; Oxides or hydroxides thereof
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS, COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/38Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
    • B01J23/40Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals of the platinum group metals
    • B01J23/46Ruthenium, rhodium, osmium or iridium
    • B01J23/462Ruthenium
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS, COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/74Iron group metals
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS, COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/74Iron group metals
    • B01J23/75Cobalt
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS, COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/89Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with noble metals
    • B01J23/8913Cobalt and noble metals
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS, COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/89Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with noble metals
    • B01J23/8933Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with noble metals also combined with metals, or metal oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS, COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00Catalysts comprising molecular sieves
    • B01J29/03Catalysts comprising molecular sieves not having base-exchange properties
    • B01J29/0308Mesoporous materials not having base exchange properties, e.g. Si-MCM-41
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS, COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00Catalysts comprising molecular sieves
    • B01J29/04Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B01J29/041Mesoporous materials having base exchange properties, e.g. Si/Al-MCM-41
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS, COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00Catalysts, in general, characterised by their form or physical properties
    • B01J35/0013Colloids
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS, COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/02Impregnation, coating or precipitation
    • B01J37/0236Drying, e.g. preparing a suspension, adding a soluble salt and drying
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C1/00Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon
    • C07C1/02Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon from oxides of a carbon
    • C07C1/04Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon from oxides of a carbon from carbon monoxide with hydrogen
    • C07C1/0425Catalysts; their physical properties
    • C07C1/043Catalysts; their physical properties characterised by the composition
    • C07C1/0435Catalysts; their physical properties characterised by the composition containing a metal of group 8 or a compound thereof
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10GCRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G2/00Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon
    • C10G2/30Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon from carbon monoxide with hydrogen
    • C10G2/32Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon from carbon monoxide with hydrogen with the use of catalysts
    • C10G2/33Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon from carbon monoxide with hydrogen with the use of catalysts characterised by the catalyst used
    • C10G2/331Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon from carbon monoxide with hydrogen with the use of catalysts characterised by the catalyst used containing group VIII-metals
    • C10G2/332Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon from carbon monoxide with hydrogen with the use of catalysts characterised by the catalyst used containing group VIII-metals of the iron-group
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10GCRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G2/00Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon
    • C10G2/30Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon from carbon monoxide with hydrogen
    • C10G2/32Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon from carbon monoxide with hydrogen with the use of catalysts
    • C10G2/33Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon from carbon monoxide with hydrogen with the use of catalysts characterised by the catalyst used
    • C10G2/331Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon from carbon monoxide with hydrogen with the use of catalysts characterised by the catalyst used containing group VIII-metals
    • C10G2/333Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon from carbon monoxide with hydrogen with the use of catalysts characterised by the catalyst used containing group VIII-metals of the platinum-group
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10GCRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G2/00Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon
    • C10G2/30Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon from carbon monoxide with hydrogen
    • C10G2/32Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon from carbon monoxide with hydrogen with the use of catalysts
    • C10G2/33Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon from carbon monoxide with hydrogen with the use of catalysts characterised by the catalyst used
    • C10G2/334Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon from carbon monoxide with hydrogen with the use of catalysts characterised by the catalyst used containing molecular sieve catalysts

Abstract

This invention provides a process for producing hydrocarbons. The process involves contacting a feed stream comprising hydrogen and carbon monoxide with a catalyst in a reaction zone maintained at conversion-promoting conditions effective to produce an effluent stream comprising hydrocarbons, and uses a catalyst including (a) at least one catalytic metal for Fischer-Tropsch reactions (e.g., iron, cobalt, nickel and/or ruthenium) and (b) a non-layered mesoporous support which exhibits an X-ray diffraction after calcination that has at least one peak at a d-spacing of greater than 18 Ångstrom units.
PCT/US1999/018994 1998-08-20 1999-08-19 Fischer-tropsch processes using catalysts on mesoporous supports WO2000010698A3 (en)

Priority Applications (12)

Application Number Priority Date Filing Date Title
US9719298 true 1998-08-20 1998-08-20
US9719398 true 1998-08-20 1998-08-20
US9719498 true 1998-08-20 1998-08-20
US60/097,193 1998-08-20
US60/097,192 1998-08-20
US60/097,194 1998-08-20
US37700799 true 1999-08-18 1999-08-18
US09/376,873 1999-08-18
US09/377,007 1999-08-18
US09/377,008 1999-08-18
US09376873 US6319872B1 (en) 1998-08-20 1999-08-18 Fischer-Tropsch processes using catalysts on mesoporous supports
US09377008 US6235677B1 (en) 1998-08-20 1999-08-18 Fischer-Tropsch processes using xerogel and aerogel catalysts by destabilizing aqueous colloids

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
CA 2341175 CA2341175A1 (en) 1998-08-20 1999-08-19 Fischer-tropsch processes using catalysts on mesoporous supports
EP19990943789 EP1109622A4 (en) 1998-08-20 1999-08-19 Fischer-tropsch processes using catalysts on mesoporous supports

Publications (2)

Publication Number Publication Date
WO2000010698A2 true WO2000010698A2 (en) 2000-03-02
WO2000010698A3 true true WO2000010698A3 (en) 2000-10-26

Family

ID=27557542

Family Applications (3)

Application Number Title Priority Date Filing Date
PCT/US1999/018994 WO2000010698A3 (en) 1998-08-20 1999-08-19 Fischer-tropsch processes using catalysts on mesoporous supports
PCT/US1999/018895 WO2000010704A1 (en) 1998-08-20 1999-08-19 Fischer-tropsch processes using xerogel and aerogel catalysts by destabilizing aqueous colloids
PCT/US1999/018962 WO2000010705A1 (en) 1998-08-20 1999-08-19 Fischer-tropsch processes using xerogel and aerogel catalysts

Family Applications After (2)

Application Number Title Priority Date Filing Date
PCT/US1999/018895 WO2000010704A1 (en) 1998-08-20 1999-08-19 Fischer-tropsch processes using xerogel and aerogel catalysts by destabilizing aqueous colloids
PCT/US1999/018962 WO2000010705A1 (en) 1998-08-20 1999-08-19 Fischer-tropsch processes using xerogel and aerogel catalysts

Country Status (3)

Country Link
EP (2) EP1128905A1 (en)
CA (2) CA2341174A1 (en)
WO (3) WO2000010698A3 (en)

Families Citing this family (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US6548440B1 (en) 1999-05-26 2003-04-15 Science & Technology Corporation @ Unm Synthesis of attrition-resistant heterogeneous catalysts using templated mesoporous silica
WO2002002229A3 (en) 2000-07-03 2003-01-23 Conoco Inc Fischer-tropsch processes and catalysts using aluminum borate supports
CA2428180A1 (en) * 2000-11-08 2002-05-16 Idemitsu Kosan Co., Ltd. Catalyst for hydrocarbon reforming and method of reforming hydrocarbon with the same
US6727289B2 (en) 2001-01-12 2004-04-27 Conocophillips Company Boron promoted catalysts and fischer-tropsch processes
DE60224925D1 (en) * 2001-03-29 2008-03-20 Idemitsu Kosan Co A catalytic process for reforming of hydrocarbon by using the catalyst
US7067453B1 (en) 2001-07-13 2006-06-27 Innovatek, Inc. Hydrocarbon fuel reforming catalyst and use thereof
EP2666540A1 (en) * 2012-05-22 2013-11-27 Karlsruher Institut für Technologie Process for catalytic hydrodesoxygenation of furane derivatives and/or pyrolysis oils, the catalyst and the process of making thereof.
US9290425B2 (en) * 2013-06-20 2016-03-22 Standard Alcohol Company Of America, Inc. Production of mixed alcohols from synthesis gas
FR3018810B1 (en) 2014-03-20 2017-06-09 Ifp Energies Now Fischer-Tropsch process using a catalyst based on a Group VIIIB metal oxide and a carrier comprising alumina, silica and phosphorus

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US5110572A (en) * 1990-01-25 1992-05-05 Mobil Oil Corp. Synthesis of mesoporous crystalline material using organometallic reactants
US5156828A (en) * 1991-07-18 1992-10-20 Mobil Oil Corporation Method for manufacturing synthetic mesoporous crystalline material
US5211934A (en) * 1990-01-25 1993-05-18 Mobil Oil Corp. Synthesis of mesoporous aluminosilicate
US5215738A (en) * 1985-05-03 1993-06-01 Sri International Benzamide and nicotinamide radiosensitizers
US5227353A (en) * 1991-07-24 1993-07-13 Mobil Oil Corporation Hydroprocessing catalyst composition
US5238676A (en) * 1990-01-25 1993-08-24 Mobil Oil Corporation Method for modifying synthetic mesoporous crystalline materials
US5366945A (en) * 1992-12-22 1994-11-22 Mobil Oil Corp. Supported heteropoly acid catalysts

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US5215738A (en) * 1985-05-03 1993-06-01 Sri International Benzamide and nicotinamide radiosensitizers
US5110572A (en) * 1990-01-25 1992-05-05 Mobil Oil Corp. Synthesis of mesoporous crystalline material using organometallic reactants
US5211934A (en) * 1990-01-25 1993-05-18 Mobil Oil Corp. Synthesis of mesoporous aluminosilicate
US5238676A (en) * 1990-01-25 1993-08-24 Mobil Oil Corporation Method for modifying synthetic mesoporous crystalline materials
US5156828A (en) * 1991-07-18 1992-10-20 Mobil Oil Corporation Method for manufacturing synthetic mesoporous crystalline material
US5227353A (en) * 1991-07-24 1993-07-13 Mobil Oil Corporation Hydroprocessing catalyst composition
US5366945A (en) * 1992-12-22 1994-11-22 Mobil Oil Corp. Supported heteropoly acid catalysts

Non-Patent Citations (1)

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Title
See also references of EP1109622A4 *

Also Published As

Publication number Publication date Type
WO2000010698A2 (en) 2000-03-02 application
CA2341174A1 (en) 2000-03-02 application
EP1109622A4 (en) 2002-01-23 application
CA2341175A1 (en) 2000-03-02 application
WO2000010704A1 (en) 2000-03-02 application
WO2000010705A1 (en) 2000-03-02 application
EP1109622A2 (en) 2001-06-27 application
EP1128905A1 (en) 2001-09-05 application

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