WO2000010698A3 - Fischer-tropsch processes using catalysts on mesoporous supports - Google Patents

Fischer-tropsch processes using catalysts on mesoporous supports Download PDF

Info

Publication number
WO2000010698A3
WO2000010698A3 PCT/US1999/018994 US9918994W WO0010698A3 WO 2000010698 A3 WO2000010698 A3 WO 2000010698A3 US 9918994 W US9918994 W US 9918994W WO 0010698 A3 WO0010698 A3 WO 0010698A3
Authority
WO
WIPO (PCT)
Prior art keywords
fischer
catalysts
tropsch processes
mesoporous supports
hydrocarbons
Prior art date
Application number
PCT/US1999/018994
Other languages
French (fr)
Other versions
WO2000010698A2 (en
Inventor
Leo E Manzer
Stephan Schwarz
Original Assignee
Conoco Inc
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority claimed from US09/376,873 external-priority patent/US6319872B1/en
Priority claimed from US09/377,008 external-priority patent/US6235677B1/en
Application filed by Conoco Inc filed Critical Conoco Inc
Priority to CA002341175A priority Critical patent/CA2341175A1/en
Priority to AU56818/99A priority patent/AU757374B2/en
Priority to EP99943789A priority patent/EP1109622A4/en
Publication of WO2000010698A2 publication Critical patent/WO2000010698A2/en
Publication of WO2000010698A3 publication Critical patent/WO2000010698A3/en

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G2/00—Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon
    • C10G2/30—Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon from carbon monoxide with hydrogen
    • C10G2/32—Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon from carbon monoxide with hydrogen with the use of catalysts
    • C10G2/33—Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon from carbon monoxide with hydrogen with the use of catalysts characterised by the catalyst used
    • C10G2/331—Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon from carbon monoxide with hydrogen with the use of catalysts characterised by the catalyst used containing group VIII-metals
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J21/00—Catalysts comprising the elements, oxides, or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium, or hafnium
    • B01J21/06—Silicon, titanium, zirconium or hafnium; Oxides or hydroxides thereof
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
    • B01J23/40—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals of the platinum group metals
    • B01J23/46—Ruthenium, rhodium, osmium or iridium
    • B01J23/462—Ruthenium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/74—Iron group metals
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/74—Iron group metals
    • B01J23/75—Cobalt
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/89—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with noble metals
    • B01J23/8913—Cobalt and noble metals
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/89—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with noble metals
    • B01J23/8933—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with noble metals also combined with metals, or metal oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/03—Catalysts comprising molecular sieves not having base-exchange properties
    • B01J29/0308—Mesoporous materials not having base exchange properties, e.g. Si-MCM-41
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B01J29/041—Mesoporous materials having base exchange properties, e.g. Si/Al-MCM-41
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/20—Catalysts, in general, characterised by their form or physical properties characterised by their non-solid state
    • B01J35/23—Catalysts, in general, characterised by their form or physical properties characterised by their non-solid state in a colloidal state
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/02—Impregnation, coating or precipitation
    • B01J37/0236—Drying, e.g. preparing a suspension, adding a soluble salt and drying
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C1/00—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon
    • C07C1/02—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon from oxides of a carbon
    • C07C1/04—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon from oxides of a carbon from carbon monoxide with hydrogen
    • C07C1/0425—Catalysts; their physical properties
    • C07C1/043—Catalysts; their physical properties characterised by the composition
    • C07C1/0435—Catalysts; their physical properties characterised by the composition containing a metal of group 8 or a compound thereof
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G2/00—Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon
    • C10G2/30—Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon from carbon monoxide with hydrogen
    • C10G2/32—Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon from carbon monoxide with hydrogen with the use of catalysts
    • C10G2/33—Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon from carbon monoxide with hydrogen with the use of catalysts characterised by the catalyst used
    • C10G2/331—Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon from carbon monoxide with hydrogen with the use of catalysts characterised by the catalyst used containing group VIII-metals
    • C10G2/332—Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon from carbon monoxide with hydrogen with the use of catalysts characterised by the catalyst used containing group VIII-metals of the iron-group
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G2/00—Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon
    • C10G2/30—Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon from carbon monoxide with hydrogen
    • C10G2/32—Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon from carbon monoxide with hydrogen with the use of catalysts
    • C10G2/33—Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon from carbon monoxide with hydrogen with the use of catalysts characterised by the catalyst used
    • C10G2/331—Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon from carbon monoxide with hydrogen with the use of catalysts characterised by the catalyst used containing group VIII-metals
    • C10G2/333—Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon from carbon monoxide with hydrogen with the use of catalysts characterised by the catalyst used containing group VIII-metals of the platinum-group
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G2/00—Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon
    • C10G2/30—Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon from carbon monoxide with hydrogen
    • C10G2/32—Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon from carbon monoxide with hydrogen with the use of catalysts
    • C10G2/33—Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon from carbon monoxide with hydrogen with the use of catalysts characterised by the catalyst used
    • C10G2/334—Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon from carbon monoxide with hydrogen with the use of catalysts characterised by the catalyst used containing molecular sieve catalysts

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • General Chemical & Material Sciences (AREA)
  • Dispersion Chemistry (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Catalysts (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)

Abstract

This invention provides a process for producing hydrocarbons. The process involves contacting a feed stream comprising hydrogen and carbon monoxide with a catalyst in a reaction zone maintained at conversion-promoting conditions effective to produce an effluent stream comprising hydrocarbons, and uses a catalyst including (a) at least one catalytic metal for Fischer-Tropsch reactions (e.g., iron, cobalt, nickel and/or ruthenium) and (b) a non-layered mesoporous support which exhibits an X-ray diffraction after calcination that has at least one peak at a d-spacing of greater than 18 Ångstrom units.
PCT/US1999/018994 1998-08-20 1999-08-19 Fischer-tropsch processes using catalysts on mesoporous supports WO2000010698A2 (en)

Priority Applications (3)

Application Number Priority Date Filing Date Title
CA002341175A CA2341175A1 (en) 1998-08-20 1999-08-19 Fischer-tropsch processes using catalysts on mesoporous supports
AU56818/99A AU757374B2 (en) 1998-08-20 1999-08-19 Fischer-tropsch processes using catalysts on mesoporous supports
EP99943789A EP1109622A4 (en) 1998-08-20 1999-08-19 Fischer-tropsch processes using catalysts on mesoporous supports

Applications Claiming Priority (12)

Application Number Priority Date Filing Date Title
US9719498P 1998-08-20 1998-08-20
US9719298P 1998-08-20 1998-08-20
US9719398P 1998-08-20 1998-08-20
US60/097,194 1998-08-20
US60/097,193 1998-08-20
US60/097,192 1998-08-20
US37700799A 1999-08-18 1999-08-18
US09/376,873 1999-08-18
US09/376,873 US6319872B1 (en) 1998-08-20 1999-08-18 Fischer-Tropsch processes using catalysts on mesoporous supports
US09/377,008 1999-08-18
US09/377,007 1999-08-18
US09/377,008 US6235677B1 (en) 1998-08-20 1999-08-18 Fischer-Tropsch processes using xerogel and aerogel catalysts by destabilizing aqueous colloids

Publications (2)

Publication Number Publication Date
WO2000010698A2 WO2000010698A2 (en) 2000-03-02
WO2000010698A3 true WO2000010698A3 (en) 2000-10-26

Family

ID=27557542

Family Applications (3)

Application Number Title Priority Date Filing Date
PCT/US1999/018895 WO2000010704A1 (en) 1998-08-20 1999-08-19 Fischer-tropsch processes using xerogel and aerogel catalysts by destabilizing aqueous colloids
PCT/US1999/018994 WO2000010698A2 (en) 1998-08-20 1999-08-19 Fischer-tropsch processes using catalysts on mesoporous supports
PCT/US1999/018962 WO2000010705A1 (en) 1998-08-20 1999-08-19 Fischer-tropsch processes using xerogel and aerogel catalysts

Family Applications Before (1)

Application Number Title Priority Date Filing Date
PCT/US1999/018895 WO2000010704A1 (en) 1998-08-20 1999-08-19 Fischer-tropsch processes using xerogel and aerogel catalysts by destabilizing aqueous colloids

Family Applications After (1)

Application Number Title Priority Date Filing Date
PCT/US1999/018962 WO2000010705A1 (en) 1998-08-20 1999-08-19 Fischer-tropsch processes using xerogel and aerogel catalysts

Country Status (4)

Country Link
EP (2) EP1109622A4 (en)
AU (3) AU746882B2 (en)
CA (2) CA2341174A1 (en)
WO (3) WO2000010704A1 (en)

Families Citing this family (14)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US6548440B1 (en) 1999-05-26 2003-04-15 Science & Technology Corporation @ Unm Synthesis of attrition-resistant heterogeneous catalysts using templated mesoporous silica
AU1675402A (en) 2000-07-03 2002-01-14 Conoco Inc Fischer-tropsch processes and catalysts using aluminum borate supports
KR100825157B1 (en) 2000-11-08 2008-04-24 이데미쓰 고산 가부시키가이샤 Catalyst for hydrocarbon reforming and method of reforming hydrocarbon with the same
AU2002245459B2 (en) 2001-01-12 2005-10-13 Conocophillips Company Boron promoted catalysts and fischer-tropsch processes
EP1894622B1 (en) 2001-03-29 2012-03-14 Idemitsu Kosan Co., Ltd. Process for reforming a hydrocarbon
US7067453B1 (en) 2001-07-13 2006-06-27 Innovatek, Inc. Hydrocarbon fuel reforming catalyst and use thereof
EP2666540A1 (en) * 2012-05-22 2013-11-27 Karlsruher Institut für Technologie Process for catalytic hydrodesoxygenation of furane derivatives and/or pyrolysis oils, the catalyst and the process of making thereof.
US9290425B2 (en) * 2013-06-20 2016-03-22 Standard Alcohol Company Of America, Inc. Production of mixed alcohols from synthesis gas
US10875820B2 (en) 2013-06-20 2020-12-29 Standard Alcohol Company Of America, Inc. Catalyst for converting syngas to mixed alcohols
FR3018810B1 (en) 2014-03-20 2017-06-09 Ifp Energies Now FISCHER-TROPSCH PROCESS USING GROUP VIIIB METAL CATALYST AND OXIDE SUPPORT COMPRISING ALUMINA, SILICA AND PHOSPHORUS
CN111375439B (en) * 2020-04-22 2022-09-20 陕西延长石油（集团）有限责任公司 Method and catalyst for preparing epoxypropane by liquid-phase propylene in one step
CN112588292A (en) * 2020-12-17 2021-04-02 大唐国际化工技术研究院有限公司 By TiO2Methanation catalyst with aerogel as carrier and preparation method and application thereof
CN112517019A (en) * 2020-12-17 2021-03-19 大唐国际化工技术研究院有限公司 By TiO2Methanation catalyst with aerogel as carrier and preparation method and application thereof
CN114671452B (en) * 2022-03-03 2023-09-01 滁州学院 Method for preparing massive cerium oxide aerogel by taking epoxy compound as gel accelerator

Citations (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5110572A (en) * 1990-01-25 1992-05-05 Mobil Oil Corp. Synthesis of mesoporous crystalline material using organometallic reactants
US5156828A (en) * 1991-07-18 1992-10-20 Mobil Oil Corporation Method for manufacturing synthetic mesoporous crystalline material
US5211934A (en) * 1990-01-25 1993-05-18 Mobil Oil Corp. Synthesis of mesoporous aluminosilicate
US5215738A (en) * 1985-05-03 1993-06-01 Sri International Benzamide and nicotinamide radiosensitizers
US5227353A (en) * 1991-07-24 1993-07-13 Mobil Oil Corporation Hydroprocessing catalyst composition
US5238676A (en) * 1990-01-25 1993-08-24 Mobil Oil Corporation Method for modifying synthetic mesoporous crystalline materials
US5366945A (en) * 1992-12-22 1994-11-22 Mobil Oil Corp. Supported heteropoly acid catalysts

Family Cites Families (11)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3977993A (en) * 1975-03-12 1976-08-31 Gulf Research & Development Company Metal oxide aerogels
US4469814A (en) * 1982-12-10 1984-09-04 Coal Industry (Patents) Limited Catalysts
US4717708A (en) * 1983-12-27 1988-01-05 Stauffer Chemical Company Inorganic oxide aerogels and their preparation
US5028634A (en) * 1989-08-23 1991-07-02 Exxon Research & Engineering Company Two stage process for hydrocarbon synthesis
US5215737A (en) * 1990-01-25 1993-06-01 Mobil Oil Corp. Synthesis of mesoporous aluminosilicate
EP0641257B1 (en) * 1991-07-24 1999-04-28 Mobil Oil Corporation Hydroprocessing catalyst
FR2694013B1 (en) * 1992-07-27 1994-09-30 Inst Francais Du Petrole Cobalt-based catalyst and process for converting synthesis gas to hydrocarbons.
US5395805A (en) * 1993-03-25 1995-03-07 Regents Of The University Of California Method for making monolithic metal oxide aerogels
DE19745905A1 (en) * 1997-10-17 1999-04-22 Hoechst Ag Supported catalysts with high sintering stability and process for their production
US5958363A (en) * 1998-10-29 1999-09-28 The Regents Of The University Of California Method for making monolithic metal oxide aerogels
US6333016B1 (en) * 1999-06-02 2001-12-25 The Board Of Regents Of The University Of Oklahoma Method of producing carbon nanotubes

Patent Citations (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5215738A (en) * 1985-05-03 1993-06-01 Sri International Benzamide and nicotinamide radiosensitizers
US5110572A (en) * 1990-01-25 1992-05-05 Mobil Oil Corp. Synthesis of mesoporous crystalline material using organometallic reactants
US5211934A (en) * 1990-01-25 1993-05-18 Mobil Oil Corp. Synthesis of mesoporous aluminosilicate
US5238676A (en) * 1990-01-25 1993-08-24 Mobil Oil Corporation Method for modifying synthetic mesoporous crystalline materials
US5156828A (en) * 1991-07-18 1992-10-20 Mobil Oil Corporation Method for manufacturing synthetic mesoporous crystalline material
US5227353A (en) * 1991-07-24 1993-07-13 Mobil Oil Corporation Hydroprocessing catalyst composition
US5366945A (en) * 1992-12-22 1994-11-22 Mobil Oil Corp. Supported heteropoly acid catalysts

Also Published As

Publication number Publication date
AU5681899A (en) 2000-03-14
AU5575199A (en) 2000-03-14
EP1109622A2 (en) 2001-06-27
CA2341174A1 (en) 2000-03-02
WO2000010705A1 (en) 2000-03-02
EP1128905A1 (en) 2001-09-05
EP1109622A4 (en) 2002-01-23
WO2000010698A2 (en) 2000-03-02
AU746882B2 (en) 2002-05-02
AU757374B2 (en) 2003-02-20
CA2341175A1 (en) 2000-03-02
WO2000010704A1 (en) 2000-03-02
AU5572199A (en) 2000-03-14

Similar Documents

Publication Publication Date Title
WO1999061143A3 (en) Fischer-tropsch processes and catalysts using fluorided alumina supports
WO2000010698A3 (en) Fischer-tropsch processes using catalysts on mesoporous supports
Aiello et al. Hydrogen production via the direct cracking of methane over Ni/SiO2: catalyst deactivation and regeneration
MY118696A (en) Process for the preparation of hydrocarbons
MY118875A (en) Catalyst activation process
Nakagawa et al. Partial oxidation of methane to synthesis gas over supported iridium catalysts
PL345190A1 (en) Catalytic partial oxidation with two catalytically-active metals
ZA86706B (en) Co hydrogenation with molybdenum on wide-pore carbon catalysts
WO2001036352A8 (en) Regeneration procedure for fischer-tropsch catalyst
MY125370A (en) Reducing fischer-tropsch catalyst attrition losses in high agitation reaction systems
WO2001036323A3 (en) Cobalt-based catalysts and process for producing synthesis gas
MY122154A (en) Process for the selective hydrogenation of hydro-formylation mixtures
MY118369A (en) One step conversion of methanol to hydrogen and carbon dioxide
MY110136A (en) Process for the elimination of mercury from hydrocarbons by passage over a presulphurated catalyst
CA2237747A1 (en) New process for the preparation of azithromycin
BR9002209A (en) PROCESS FOR THE PREPARATION OF HYDROCARBONS BY CATALYTIC REACTION OF CARBON MONOXIDE WITH HYDROGEN AND HYDROCARBONS
MXPA00001461A (en) Process for production of aromatic amines
BR8306388A (en) PROCESS FOR THE PREPARATION OF HYDROCARBONS BY THE CATALYTIC REACTION OF CARBON MONOXIDE AND HYDROGEN
CO4180614A1 (en) PROCESS FOR THE PREPARATION OF CARBON MONOXIDE AND HYDROGEN
CA2265643A1 (en) Fischer-tropsch catalyst and process for preparing hydrocarbons
Ahmad et al. Deactivation behaviour of intermetallic Ga‐Ni catalyst in CO2 hydrogenation to methanol
CA2445918A1 (en) Pressure swing catalyst regeneration procedure for fischer-tropsch catalyst
Lee et al. Comparison of single-stage and two-stage CO2 hydrogenation for methanol synthesis gain and phase margins
TH12449B (en) Process for preparing hydrocarbon fuels
TH15378A (en) Process for partial oxidation with hydrocarbon catalysts.

Legal Events

Date Code Title Description
AK Designated states

Kind code of ref document: A2

Designated state(s): AE AL AM AT AU AZ BA BB BG BR BY CA CH CN CU CZ DE DK EE ES FI GB GD GE GH GM HR HU ID IL IN IS JP KE KG KP KR KZ LC LK LR LS LT LU LV MD MG MK MN MW MX NO NZ PL PT RO RU SD SE SG SI SK SL TJ TM TR TT UA UG UZ VN YU ZA ZW

AL Designated countries for regional patents

Kind code of ref document: A2

Designated state(s): GH GM KE LS MW SD SL SZ UG ZW AM AZ BY KG KZ MD RU TJ TM AT BE CH CY DE DK ES FI FR GB GR IE IT LU MC NL PT SE BF BJ CF CG CI CM GA GN GW ML MR NE SN TD TG

121 Ep: the epo has been informed by wipo that ep was designated in this application
DFPE Request for preliminary examination filed prior to expiration of 19th month from priority date (pct application filed before 20040101)
AK Designated states

Kind code of ref document: A3

Designated state(s): AE AL AM AT AU AZ BA BB BG BR BY CA CH CN CU CZ DE DK EE ES FI GB GD GE GH GM HR HU ID IL IN IS JP KE KG KP KR KZ LC LK LR LS LT LU LV MD MG MK MN MW MX NO NZ PL PT RO RU SD SE SG SI SK SL TJ TM TR TT UA UG UZ VN YU ZA ZW

AL Designated countries for regional patents

Kind code of ref document: A3

Designated state(s): GH GM KE LS MW SD SL SZ UG ZW AM AZ BY KG KZ MD RU TJ TM AT BE CH CY DE DK ES FI FR GB GR IE IT LU MC NL PT SE BF BJ CF CG CI CM GA GN GW ML MR NE SN TD TG

WWE Wipo information: entry into national phase

Ref document number: 56818/99

Country of ref document: AU

ENP Entry into the national phase

Ref document number: 2341175

Country of ref document: CA

Ref country code: CA

Ref document number: 2341175

Kind code of ref document: A

Format of ref document f/p: F

WWE Wipo information: entry into national phase

Ref document number: 2001/01412

Country of ref document: ZA

Ref document number: 200101412

Country of ref document: ZA

WWE Wipo information: entry into national phase

Ref document number: 1999943789

Country of ref document: EP

REG Reference to national code

Ref country code: DE

Ref legal event code: 8642

WWP Wipo information: published in national office

Ref document number: 1999943789

Country of ref document: EP

WWW Wipo information: withdrawn in national office

Ref document number: 1999943789

Country of ref document: EP

WWG Wipo information: grant in national office

Ref document number: 56818/99

Country of ref document: AU