WO1999061243A1 - Eliminating adhesion difference due to glass orientation in laminated safety glass - Google Patents
Eliminating adhesion difference due to glass orientation in laminated safety glass Download PDFInfo
- Publication number
- WO1999061243A1 WO1999061243A1 PCT/US1998/010580 US9810580W WO9961243A1 WO 1999061243 A1 WO1999061243 A1 WO 1999061243A1 US 9810580 W US9810580 W US 9810580W WO 9961243 A1 WO9961243 A1 WO 9961243A1
- Authority
- WO
- WIPO (PCT)
- Prior art keywords
- glass
- adhesion
- sheet
- polyvinylbutyral
- leveling agent
- Prior art date
Links
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B17/00—Layered products essentially comprising sheet glass, or glass, slag, or like fibres
- B32B17/06—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material
- B32B17/10—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material of synthetic resin
- B32B17/10005—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material of synthetic resin laminated safety glass or glazing
- B32B17/1055—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material of synthetic resin laminated safety glass or glazing characterized by the resin layer, i.e. interlayer
- B32B17/10761—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material of synthetic resin laminated safety glass or glazing characterized by the resin layer, i.e. interlayer containing vinyl acetal
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B17/00—Layered products essentially comprising sheet glass, or glass, slag, or like fibres
- B32B17/06—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material
- B32B17/10—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material of synthetic resin
- B32B17/10005—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material of synthetic resin laminated safety glass or glazing
- B32B17/1055—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material of synthetic resin laminated safety glass or glazing characterized by the resin layer, i.e. interlayer
- B32B17/10688—Adjustment of the adherence to the glass layers
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/04—Oxygen-containing compounds
- C08K5/09—Carboxylic acids; Metal salts thereof; Anhydrides thereof
- C08K5/098—Metal salts of carboxylic acids
Definitions
- Adhesion between the glass and the interlayer is the most critical , controllable parameter related to the penetration resistance of laminated safety glass. If the adhesion is too high, the laminate fails as a monolithic unit upon impact, and hence does not offer the occupant of a motor vehicle much protection. If the adhesion is too low, sharp pieces would separate from the laminate on impact, and could thus cause injury to the occupant.
- Laminated safety glass today are mainly made from float glass.
- the automobile windshield is made from two pieces of float glass which have been bent either by heat sagging or by heating followed by form-pressing.
- the bent glass pieces are bonded together by a plasticized polyvinylbutyral (PVB) interlayer.
- PVB polyvinylbutyral
- the glass is cast onto and transported on top of a bath of molten tin. While one of the surfaces is in contact with tin (the tin-side), the other is usually in contact with an inert atmosphere such as nitrogen (the air-side). Consequently, the chemistry of the two surfaces of the same glass sheet can be quite different.
- the difference in surface chemistry manifests itself in the adhesion between the glass and the PVB interlayer.
- the difference in adhesion often referred to as asymmetric adhesion, can be so much that a laminate is deemed usable as a windshield in one glass orientation, but not in another.
- This invention is also applicable to other glass/adhesive sheet laminar structures in which asymmetric adhesion is experienced.
- a glass/adhesive sheet laminar structure comprising at least two layers of glass and a sheet of plasticized polyvinylbutyral (PVB), said polyvinylbutyral having blended therein an ionizable metal salt as an adhesion control additive to provide a preselected level of adhesion between said layers of glass and said sheet of polyvinylbutyral which is suitable for use as automobile windshields and side windows and body glass, and incorporating another ionizable metal salt which provides a cation different from that provided by the adhesion control additive such that the content of the cation which is provided by the leveling agent is between 0.03 and 1.35, and preferably 0.07 to 1.1 milliequivalents/kg (meq/kg) of sheeting.
- PVB plasticized polyvinylbutyral
- the second metal salt may be a salt of an alkaline earth metal such as magnesium or calcium or a transition metal such as zinc or copper, or Group IV metal such as tin.
- an alkaline earth metal such as magnesium or calcium or a transition metal such as zinc or copper, or Group IV metal such as tin.
- this small amount of salt or leveling agent is adequate in reducing, and in some cases, essentially eliminating asymmetric adhesion without other deleterious effects on the overall performance on the laminate such as haze.
- the adhesion level of the PVB interlayers may be controlled by conventional means by adjusting the amount of adhesion control additive.
- FIGURE 1 is a diagrammatic illustration of a jig used for deterrnining the compressive shear strength of a laminate.
- Plasticized PVB sheeting is prepared by processes well known in the art. Preparation of plasticized PVB is disclosed in Phillips, U.S. 4,276,351 which is hereby incorporated by reference. A wide variety of adhesion control additives can be used with polyvinylbutyral sheeting.
- a process for preparing such sheeting is disclosed in Moynihan, U.S. 4,292.372 which is hereby incorporated by reference.
- melt exiting the extruder is at 200-220°C. It is passed through a gear pump and a melt filter, and then through a slot die and forms a sheeting of 0.76mm nominal thickness.
- the adhesion control additive is added as an aqueous side-stream directly into the melt.
- the leveling agent if it is water-soluble, is added either as a direct aqueous side- stream into the melt, or preferably as a mixed solution combined with the adhesion control additive . If the leveling agent is not readily soluble in water, it may be added as a solution in an organic solvent directly into the melt or as a solution in the plasticizer which is fed to the extruder..
- inorganic acids includes sulfuric acid, nitric acid, and hydrochloric acid.
- Monobasic organic acids include formic acid, acetic acid, as well as linear carboxylic acids having 1-12 carbon atoms and branched carboxylic acids having 3-12 carbon atoms.
- Polybasic organic acids refer to acids with two or more carboxylic acid groups, and they encompass oxalic acid, succinic acid, oxaloacetic acid, citric acid, and ethylenediamine tetraacetic acid.
- adhesion control additive In addition to an adhesion control additive and a leveling agent, usual adjuvants such as antioxidants, colorants and ultraviolet absorbers which do not adversely affect the functioning of the adhesion control additive may be included in the PVB composition.
- surface energy modifying agents consisting of silicones, hydrolyzed silanes, fluorine-containing surfactant, salts of a medium-to long-chain carboxylic acid or a combination thereof may be added for reducing air- related defect.
- Air-related defects in the laminate include air bubbles and worm- like defects which form as a result of having trapped air and air absorbed into the PVB interlayer during autoclaving.
- Adhesion of the laminate i.e. of the PVB interlayer to glass, is determined using the compressive shear strength test using jig 10, 12 shown in FIG. 1.
- Laminates for adhesion determination are prepared by first conditioning the polyvinylbutyral interlayer at 23°C ⁇ 2°C in an environment of 23 ⁇ 3% relative humidity overnight before laminating. Referring to FIG. 1, interlayer 18 is then sandwiched between two pieces of annealed float glass 16 and 20 of dimension 12"xl2" (305 mm x 305 mm) and 2.3 mm nominal thickness which have been washed and rinsed in demineralized water.
- Two laminates are made from each PVB interlayer: one with the interlayer with both the tin-sides of the glass pieces (ATT A); one with the interlayer in contact with both the air-sides of the glass pieces (TAAT).
- the glass/PVB/glass assemblies are then heated in an oven set at 90-100°C for 30 minutes. Thereafter, each is passed through a set of nip rolls so that the air in the void spaces between the glass and the interlayer may be squeezed out, and the edge of the assembly sealed.
- the assembly at this stage is called a pre-press.
- the pre-press is then placed in an air autoclave where the temperature is raised to 135°C and pressure to 200 psig (14.3 bar). These conditions are maintained for 20 minutes, after which, the air is cooled , while no more air is added to the autoclave. After 20 minutes of cooling when the air temperature in the autoclave is under 50°C, the excess air pressure is vented.
- the compressive shear strength of the laminate prepared as prescribed above is determined using the method detailed here.
- Six l"xl" (25 mm x 25 mm) chips are sawed from the laminate. The chips are conditioned in a room controlled at 23°C ⁇ 2°C and 50% ⁇ 1% relative humidity for one hour prior to testing.
- the compressive shear strength of the chip is determined using jig 12 shown in FIG. 1.
- the chip, 16, 18, 20, is placed on the cut-out on the lower half of jig 12, and the upper half is then placed on top of the chip.
- a cross-head is lowered at the rate of 0.1 inch per minute (2.5 mm per minute) until it contacts the upper piece of the device.
- the compressive shear strength of the chip is the shear stress required to cause adhesive failure.
- the precision of this test is such that one standard deviation is typically 6% of the average result of six chips.
- a glass/PVB/glass laminate tested in this way for adhesion which has compressive shear strength of 1500 psi to about 2700 psi (1050 N/cm 2 to 1850 N/cm 2 ) is considered most suitable for use in automobile windshields and side- glass.
- a laminate is made from each PVB interlayer tested.
- the TAAT orientation is used.
- the laminate is assembled and de-aired as discussed in the adhesion section, except that a hotter and longer autoclave cycle is used.
- the hold time is 90 minutes at 150°C and 225 psig (15.3 bar) pressure.
- Haze is measured following the procedure described in ASTM D-1003 using a Hazegard hazemeter from Gardner. Haze levels higher than 0.4% are considered undesirable for use as windshields.
- Plasticized polyvinylbutyral sheeting (commercially available from E.I.duPont de Nemours & Co. as Butacite®) in which the plasticizer was tetra- ethylene glycol di-heptanoate was used to prepare laminates in the method described above. Sheeting with two levels of adhesivity were used. Adhesion of the laminates made in two glass orientations (TAAT and ATT A) was measured. Results are shown in Table 1. Comparative Example C3
- the polyvinylbutyral interlayer in this example was similar to that in Example C3, except that a leveling agent, magnesium sulfate, was added such that the concentration of magnesium was 0.40 meq/kg. Adhesion and haze results are shown in Table 1.
- Example 2 a leveling agent, magnesium sulfate, was added such that the concentration of magnesium was 0.40 meq/kg. Adhesion and haze results are shown in Table 1.
- the polyvinylbutyral interlayer in this example is similar to that in Example 1, except that sheeting was made by feeding the adhesion control additive, potassium formate, and the leveling agent, magnesium sulfate, as a mixed solution.
- the resulting potassium level in the sheeting was 381 ppm, and the magnesium level was 0.11 meq/kg.
- Adhesion and haze data are shown in Table 1.
- the polyvinyl butyral interlayer in this example was the similar to that used in Example 1, except that the potassium level of the adhesion control additive was 300 ppm, and magnesium neodecanoate was added as a leveling agent to the melt in the extruder as a solution in mineral spirits and plasticizer so that the magnesium concentration in the bulk of the PVB sheeting was 0.50 meq/kg. Adhesion and haze results are shown in Table 1.
- the polyvinylbutyral interlayer in this example was similar to that in Example 2, except that the potassium concentration from the adhesion control additive, potassium formate, was 405 ppm, and that a leveling agent disodium magnesium ethylenediamine tetracetate was added such that the concentration of magnesium was 0.14 meq/kg in the sheeting. Laminates were prepared and adhesion was measured. Results are shown in Table 1.
- the polyvinylbutyral interlayer in this example is the same as that in Example 1 in that the potassium level from the potassium formate adhesion-control additive was 350 ppm, but the leveling agent was magnesium from magnesium acetate. The magnesium level in the sheeting was 0.58 meq/kg. Adhesion and data are shown in Table 1.
- the polyvinyl butyral interlayer in this example was the similar to that used in Example 3, except that the potassium level from the adhesion control additive was 400 ppm, and 0.007 part of ⁇ -glycidoxypropyltrimethoxy silane and 0.07 part of polyoxyethylene-modified silicone oil was also added as surface energy modifiers, and the concentration of magnesium in the bulk of the PVB sheeting was 1.0 meq/kg. Adhesion and haze results are shown in Table 1.
- the polyvinyl butyral interlayer in this example was the similar to that used in Example 1 except that the potassium level in the bulk of the sheeting due to the adhesion control additive was 300 ppm, and calcium acetate was added as the leveling agent so that the calcium concentration in the bulk of the PVB sheeting was 1.0 meq/kg. Adhesion and haze results are shown in Table 1.
- the polyvinyl butyral interlayer in this example was the similar to that used in Example 7, except that zinc acetate was used as an leveling agent. It was added so that the zinc concentration in the bulk of the PVB sheeting was 0.83 meq/kg. Adhesion and haze results are shown in Table 1.
- the polyvinylbutyral interlayer in this example (commercially available material under the tradename Butacite®) was the same as that used in Comparative Example Cl, except that the interlayer was dip-coated in a bath containing a 0.012% aqueous solution of magnesium sulfate at 25 ft/minute (7.6 m/minute). The resulting sheeting was analyzed by ion chromatography and was found to contain 0.17 meq/kg of magnesium on a bulk basis. The resulting sheeting was dried and conditioned in an environment of 23 ⁇ 2% relative humidity prior to laminating. Adhesion results are shown in Table 1.
- the polyvinylbutyral interlayer in this example was the same as that in Comparative Example Cl. However, the glass was dipped in a solution of magnesium sulfate in demineralized water and dried before laminating. The concentration of the magnesium ions in the solution was 10 mg/liter. Adhesion of the laminates in TAAT and ATTA orientations were measured. Data are shown in Table 1. It was surprising that such a low concentration of magnesium ions 10 parts per million in the solution was able to substantially lower the difference in adhesions between the two glass orientations. Comparative Example C4
- the polyvinyl butyral interlayer in this example was similar to that used in Example 1, except the potassium level from the adhesion control additive was 300 ppm and the magnesium level from the leveling agent is 1.5 meq/kg. Adhesion and haze results are shown in Table 1. The haze level was also high enough that such a laminate may not be preferred as automotive windshields. Comparative Example C5
- the polyvinyl butyral interlayer in this example was made in the same way as that in Comparative Example C3 except that magnesium in the from of magnesium formate was used as the sole adhesion control additive.
- the magnesium level was 4.2 meq/kg. No other leveling agent was used.
- Adhesion and haze results are in Table 1. Adhesion in the ATTA orientation was higher than that in the TAAT orientation. This shows that the use of magnesium alone does not have the desired leveling effect. Comparative Example C6
- the polyvinylbutyral interlayer in this example was the same as that in Example 2 except that no leveling agent was added.
- the level of potassium from the adhesion control additive, potassium formate, was 385 ppm.
- Adhesion in this example is lower than that in Example 2 although the concentrations of adhesion control additive in both were nearly identical. This shows that the magnesium in the PVB interlayer in Example 2 did not act as an adhesion control additive, but rather as a agent to temper the effect due to glass orientation in the laminate.
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- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Joining Of Glass To Other Materials (AREA)
- Laminated Bodies (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Abstract
Description
Claims
Priority Applications (7)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
DE69809801T DE69809801T3 (en) | 1998-05-22 | 1998-05-22 | REMOVAL OF ADHESION DIFFERENCES MADE IN GLASS ORIENTATIONS IN HISTORIZED SAFETY GLASS |
EP98923716A EP1094939B2 (en) | 1998-05-22 | 1998-05-22 | Eliminating adhesion difference due to glass orientation in laminated safety glass |
JP2000550679A JP4115086B2 (en) | 1998-05-22 | 1998-05-22 | Elimination of differences in adhesion depending on glass orientation in laminated safety glass |
PCT/US1998/010580 WO1999061243A1 (en) | 1998-05-22 | 1998-05-22 | Eliminating adhesion difference due to glass orientation in laminated safety glass |
US09/701,107 US6599630B1 (en) | 1998-05-22 | 1998-05-22 | Eliminating adhesion difference due to glass orientation in laminated safety glass |
CA002330071A CA2330071C (en) | 1998-05-22 | 1998-05-22 | Eliminating adhesion difference due to glass orientation in laminated safety glass |
AU75942/98A AU7594298A (en) | 1998-05-22 | 1998-05-22 | Eliminating adhesion difference due to glass orientation in laminated safety glass |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
PCT/US1998/010580 WO1999061243A1 (en) | 1998-05-22 | 1998-05-22 | Eliminating adhesion difference due to glass orientation in laminated safety glass |
Publications (1)
Publication Number | Publication Date |
---|---|
WO1999061243A1 true WO1999061243A1 (en) | 1999-12-02 |
Family
ID=22267127
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
PCT/US1998/010580 WO1999061243A1 (en) | 1998-05-22 | 1998-05-22 | Eliminating adhesion difference due to glass orientation in laminated safety glass |
Country Status (6)
Country | Link |
---|---|
EP (1) | EP1094939B2 (en) |
JP (1) | JP4115086B2 (en) |
AU (1) | AU7594298A (en) |
CA (1) | CA2330071C (en) |
DE (1) | DE69809801T3 (en) |
WO (1) | WO1999061243A1 (en) |
Cited By (8)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO2003078521A1 (en) * | 2002-03-12 | 2003-09-25 | E.I. Du Pont De Nemours And Company | Low-color stiff pvb laminates |
US7189457B2 (en) | 2003-12-12 | 2007-03-13 | E. I. Du Pont De Nemours And Company | Use of PET film primed with polyallylamine coatings in laminated glass glazing constructions |
EP1997847A1 (en) * | 2007-05-30 | 2008-12-03 | Kuraray Europe GmbH | Use of lithium salts as anti-adhesive agents for films in composite safety glazing |
US7462664B2 (en) | 2002-07-31 | 2008-12-09 | E. I. Du Pont De Nemours And Company | Polyvinylbutyral interlayer sheet with improved adhesion to glass and a process for preparing same |
US7642307B2 (en) | 2002-03-12 | 2010-01-05 | E.I. Du Pont De Nemours And Company | Low-color stiff PVB laminates |
US7687560B2 (en) | 2002-03-12 | 2010-03-30 | E.I. Du Pont De Nemours And Company | Low-color PVB sheet and a process for making same |
WO2013124596A1 (en) * | 2012-02-24 | 2013-08-29 | Saint-Gobain Glass France | Thermoplastic sheet for a heads-up display system |
EP3189964A1 (en) * | 2016-01-06 | 2017-07-12 | Asahi Glass Company, Limited | Laminated glass |
Families Citing this family (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE102004030411A1 (en) * | 2004-06-23 | 2006-01-19 | Kuraray Specialities Europe Gmbh | Solar module as laminated safety glass |
JP4758844B2 (en) * | 2006-07-31 | 2011-08-31 | 積水化学工業株式会社 | Laminated glass interlayer film and laminated glass |
DE102007005845A1 (en) * | 2007-02-01 | 2008-08-07 | Kuraray Europe Gmbh | Process for the production of solar modules in the roll composite process |
JPWO2016121559A1 (en) * | 2015-01-26 | 2017-11-02 | 旭硝子株式会社 | Laminated glass |
JP6913779B2 (en) * | 2015-03-30 | 2021-08-04 | 三井・ダウポリケミカル株式会社 | Laminates and laminated glass |
DE102021134101B4 (en) | 2021-12-21 | 2023-11-09 | SCHOTT Glass Ibérica SL | Laminated glass with improved residual load-bearing capacity and process for its production |
Citations (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP0161583A2 (en) * | 1984-05-12 | 1985-11-21 | Hoechst Aktiengesellschaft | Reduction of the adhesion to glass of thermoplastic plasticizers containing polyvinylbutyral moulding compositions |
EP0373139A1 (en) * | 1988-12-05 | 1990-06-13 | Monsanto Company | Laminated safety glass and polymeric laminate for use therein |
WO1996028504A1 (en) * | 1995-03-14 | 1996-09-19 | E.I. Du Pont De Nemours And Company | Process for preparing polyvinylbutyral sheet |
Family Cites Families (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3271235A (en) † | 1965-09-21 | 1966-09-06 | Monsanto Co | Laminated safety glass |
DE1596902B1 (en) † | 1967-11-17 | 1971-11-04 | Monsanto Co | Process for the production of glass composite panes with a polyvinyl butyral intermediate layer, which are characterized by increased impact resistance |
MX9102723A (en) † | 1990-12-20 | 1992-07-31 | Monsanto Co | PLASTIC SHEET, LAMINATED GLASSWORK AND METHOD TO CONTROL THE ADHESION OF THE SHEET TO SUCH GLASSWARE AND REDUCE THE BLOCKING OF SUCH SHEET. |
DE4309638A1 (en) † | 1993-03-25 | 1994-09-29 | Hoechst Ag | Plasticized polyvinyl butyrals with improved adhesion-reducing properties compared to silicate glass, process for their production and their use |
AU721829B2 (en) † | 1997-07-17 | 2000-07-13 | Sekisui Chemical Co., Ltd. | Interlayer for laminated glass and laminated glass |
-
1998
- 1998-05-22 JP JP2000550679A patent/JP4115086B2/en not_active Expired - Lifetime
- 1998-05-22 CA CA002330071A patent/CA2330071C/en not_active Expired - Lifetime
- 1998-05-22 AU AU75942/98A patent/AU7594298A/en not_active Abandoned
- 1998-05-22 EP EP98923716A patent/EP1094939B2/en not_active Expired - Lifetime
- 1998-05-22 DE DE69809801T patent/DE69809801T3/en not_active Expired - Lifetime
- 1998-05-22 WO PCT/US1998/010580 patent/WO1999061243A1/en active IP Right Grant
Patent Citations (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP0161583A2 (en) * | 1984-05-12 | 1985-11-21 | Hoechst Aktiengesellschaft | Reduction of the adhesion to glass of thermoplastic plasticizers containing polyvinylbutyral moulding compositions |
EP0373139A1 (en) * | 1988-12-05 | 1990-06-13 | Monsanto Company | Laminated safety glass and polymeric laminate for use therein |
WO1996028504A1 (en) * | 1995-03-14 | 1996-09-19 | E.I. Du Pont De Nemours And Company | Process for preparing polyvinylbutyral sheet |
Cited By (11)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO2003078521A1 (en) * | 2002-03-12 | 2003-09-25 | E.I. Du Pont De Nemours And Company | Low-color stiff pvb laminates |
US7642307B2 (en) | 2002-03-12 | 2010-01-05 | E.I. Du Pont De Nemours And Company | Low-color stiff PVB laminates |
US7687560B2 (en) | 2002-03-12 | 2010-03-30 | E.I. Du Pont De Nemours And Company | Low-color PVB sheet and a process for making same |
US7462664B2 (en) | 2002-07-31 | 2008-12-09 | E. I. Du Pont De Nemours And Company | Polyvinylbutyral interlayer sheet with improved adhesion to glass and a process for preparing same |
US7189457B2 (en) | 2003-12-12 | 2007-03-13 | E. I. Du Pont De Nemours And Company | Use of PET film primed with polyallylamine coatings in laminated glass glazing constructions |
EP1997847A1 (en) * | 2007-05-30 | 2008-12-03 | Kuraray Europe GmbH | Use of lithium salts as anti-adhesive agents for films in composite safety glazing |
WO2013124596A1 (en) * | 2012-02-24 | 2013-08-29 | Saint-Gobain Glass France | Thermoplastic sheet for a heads-up display system |
FR2987363A1 (en) * | 2012-02-24 | 2013-08-30 | Saint Gobain | THERMOPLASTIC SHEET FOR HIGH HEAD VISUALIZATION SYSTEM |
US9857571B2 (en) | 2012-02-24 | 2018-01-02 | Sekisui Chemical Co., Ltd. | Thermoplastic sheet for a heads-up display system |
EA029637B1 (en) * | 2012-02-24 | 2018-04-30 | Секисуй Кемикал Ко., Лтд. | Thermoplastic sheet for a heads-up display system |
EP3189964A1 (en) * | 2016-01-06 | 2017-07-12 | Asahi Glass Company, Limited | Laminated glass |
Also Published As
Publication number | Publication date |
---|---|
AU7594298A (en) | 1999-12-13 |
EP1094939B2 (en) | 2010-11-24 |
JP2002516201A (en) | 2002-06-04 |
EP1094939B1 (en) | 2002-11-27 |
DE69809801T3 (en) | 2011-06-09 |
CA2330071C (en) | 2007-10-02 |
EP1094939A1 (en) | 2001-05-02 |
DE69809801D1 (en) | 2003-01-09 |
DE69809801T2 (en) | 2003-07-24 |
CA2330071A1 (en) | 1999-12-02 |
JP4115086B2 (en) | 2008-07-09 |
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