WO1999059189A1 - Low-pressure mercury-vapor discharge lamp - Google Patents

Low-pressure mercury-vapor discharge lamp Download PDF

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Publication number
WO1999059189A1
WO1999059189A1 PCT/IB1999/000774 IB9900774W WO9959189A1 WO 1999059189 A1 WO1999059189 A1 WO 1999059189A1 IB 9900774 W IB9900774 W IB 9900774W WO 9959189 A1 WO9959189 A1 WO 9959189A1
Authority
WO
WIPO (PCT)
Prior art keywords
electrode
mercury
low
electrode shield
pressure mercury
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Ceased
Application number
PCT/IB1999/000774
Other languages
English (en)
French (fr)
Inventor
Cornelis J. M. Denissen
Cornelis R. Ronda
Wilhelmus M. P. Van Kemenade
Henricus P. M. Gubbels
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Koninklijke Philips NV
Philips AB
Philips Svenska AB
Original Assignee
Koninklijke Philips Electronics NV
Philips AB
Philips Svenska AB
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Koninklijke Philips Electronics NV, Philips AB, Philips Svenska AB filed Critical Koninklijke Philips Electronics NV
Priority to DE69911538T priority Critical patent/DE69911538T2/de
Priority to EP99914706A priority patent/EP0995223B1/en
Priority to KR1020007000098A priority patent/KR100560229B1/ko
Priority to JP2000548907A priority patent/JP2002515636A/ja
Publication of WO1999059189A1 publication Critical patent/WO1999059189A1/en
Anticipated expiration legal-status Critical
Ceased legal-status Critical Current

Links

Classifications

    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01JELECTRIC DISCHARGE TUBES OR DISCHARGE LAMPS
    • H01J61/00Gas-discharge or vapour-discharge lamps
    • H01J61/02Details
    • H01J61/04Electrodes; Screens; Shields
    • H01J61/10Shields, screens, or guides for influencing the discharge
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01JELECTRIC DISCHARGE TUBES OR DISCHARGE LAMPS
    • H01J61/00Gas-discharge or vapour-discharge lamps
    • H01J61/02Details
    • H01J61/04Electrodes; Screens; Shields
    • H01J61/045Thermic screens or reflectors
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01JELECTRIC DISCHARGE TUBES OR DISCHARGE LAMPS
    • H01J61/00Gas-discharge or vapour-discharge lamps
    • H01J61/70Lamps with low-pressure unconstricted discharge having a cold pressure < 400 Torr
    • H01J61/72Lamps with low-pressure unconstricted discharge having a cold pressure < 400 Torr having a main light-emitting filling of easily vaporisable metal vapour, e.g. mercury

Definitions

  • the invention relates to a low-pressure mercury-vapor discharge lamp comprising a discharge vessel, which discharge vessel encloses a discharge space containing a filling of mercury and an inert gas in a gastight manner, electrodes being arranged in the discharge space for generating and maintaining a discharge in said discharge space, and an electrode shield at least substantially surrounding at least one of the electrodes.
  • mercury is the primary component for (efficiently) generating ultraviolet (UV) light.
  • An inner surface of the discharge vessel may be provided with a luminescent layer containing a luminescent material (for example a fluorescent powder) for converting UV to other wavelengths, for example to UV-B and UV-A for tanning purposes (sunbed lamps) or to visible radiation.
  • a luminescent material for example a fluorescent powder
  • Such discharge lamps are therefore also referred to as fluorescent lamps.
  • a low-pressure mercury- vapor discharge lamp of the type mentioned in the opening paragraph is known from DE-A 1 060 991.
  • the electrode shield surrounding the electrode is made from thin sheet titanium.
  • an electrode shield which is also referred to as anode shield or cathode shield, blackening at an inner surface of the discharge vessel is counteracted.
  • titanium serves as the getter for chemically binding oxygen, nitrogen and/or carbon.
  • a drawback of the use of a metal or metal alloy is that it may cause a short- circuit of the electrode wires.
  • the metals in the electrode shield may amalgamate with the mercury present in the lamp and, thus, absorb mercury.
  • the known lamp requires a relatively high dose of mercury to obtain a sufficiently long service life. Injudicious processing of the known lamp after its service life has ended adversely affects the environment. It is an object of the invention to provide a low-pressure mercury-vapor discharge lamp of the type mentioned in the opening paragraph, which has a relatively low mercury consumption.
  • the low-pressure mercury-vapor discharge lamp in accordance with the invention is characterized in that the electrode shield is made from a ceramic material.
  • the electrodes of such discharge lamps include an (emitter) material having a low so-called work function (reduction of the work function voltage) for supplying electrons to the discharge (cathode function) and receiving electrons from the discharge (anode function).
  • work function reduction of the work function voltage
  • Known materials having a low work function are, for example, barium (Ba), strontium (Sr) and calcium (Ca). It has been observed that, during operation of low-pressure mercury-vapor discharge lamps, material (barium and strontium) of the electrode(s) is subject to volatilization.
  • the emitter material is deposited on the inner surface of the discharge vessel. It has further been found that the above-mentioned Ba (and Sr), which is deposited elsewhere in the discharge vessel, no longer participates in the light- generating process.
  • the deposited (emitter) material further forms mercury-containing amalgams on the inner surface, as a result of which the quantity of mercury available for the discharge operation decreases (gradually), which may adversely affect the service life of the lamp. In order to compensate for such a loss of mercury during the service life of the lamp, a relatively high dose of mercury is necessary, which is undesirable from the point of view of environmental protection.
  • the inventors have recognized that the provision of an electrode shield, which surrounds the electrode(s) and is made from a ceramic material, reduces the reactivity of materials in the electrode shield relative to the mercury present in the discharge vessel, leading to the formation of amalgams (Hg-Ba, Hg-Sr).
  • the use of an electrically insulating material precludes the development of short circuits in the electrode wires and/or in a number of windings of the electrode(s).
  • the known lamp has an electrode shield of an electroconductive material, which, in addition, relatively readily forms an amalgam with mercury. The mercury consumption of the discharge lamp is limited by substantially reducing the degree to which the material of the shield surrounding the electrode(s) reacts with mercury.
  • the material of the electrode shield includes at least an oxide of at least one element of the series formed by magnesium, aluminium, titanium, zirconium, yttrium and the rare earths.
  • the electrode shield is made from a ceramic material which comprises aluminium oxide.
  • Particularly suitable electrode shields are manufactured from so-called densely sintered Al 2 O 3 , also referred to as DGA.
  • An additional advantage of the use of aluminium oxide is that an electrode shield made of such a material is resistant to relatively high temperatures (> 250°C). At such relatively high temperatures, there is an increased risk that the (mechanical) strength of the electrode shield decreases, thus adversely affecting the shape of the electrode shield.
  • the temperature of the electrode shield must not be too high to prevent that the metal or one of the metals of the metal alloy begins to deform or evaporate, thereby giving rise to undesirable blackening of the inner surface of the discharge vessel.
  • (Emitter) material originating from the electrode(s) and deposited on an electrode shield of aluminium oxide which is at a much higher temperature cannot or hardly react with the mercury present in the discharge, as result of said high temperature, so that the formation of mercury-containing amalgams is at least substantially precluded.
  • an electrode shield in accordance with the invention serves a dual purpose.
  • the material originating from the electrode(s) is deposited on the inner surface of the discharge lamp, and, on the other hand, it is precluded that (emitter) material deposited on the electrode shield forms amalgams with the mercury present in the discharge lamp.
  • the temperature of the electrode shield exceeds 250°C.
  • An additional advantage of the use of a ceramic electrode shield of aluminium oxide, which surrounds the electrode, is achieved in lamps which are operated on a ballast which can be dimmed, for example a so-called high-frequency regulating (HFR) dimming ballast, in which, particularly at dimmed light intensities, excessive evaporation of electrode- emitter material may occur, said electrode generally being additionally heated under said conditions while using a so-called "bias current".
  • HFR high-frequency regulating
  • the electrode shield captures this material and effectively precludes the formation of amalgams. As a result, the mercury consumption of the low-pressure mercury-vapor discharge lamp is limited.
  • the shape of the electrode shield and its position relative to the electrode influence the temperature of the electrode shield.
  • a further embodiment of the low-pressure mercury-vapor discharge lamp in accordance with the invention is characterized in that the electrode shield is tubular in shape. Electrodes in low-pressure mercury-vapor discharge lamp are generally elongated and cylindrically symmetric, for example a coil with windings about a 4 longitudinal axis. A tubularly shaped electrode shield harmonizes very well with such a shape of the electrode. Preferably, an axis of symmetry of the electrode shield extends substantially parallel to, or substantially coincides with, the longitudinal axis of the electrode. In the latter case, the average distance from an inside of the electrode shield to an external dimension of the electrode is at least substantially constant.
  • a particularly preferred embodiment of the low-pressure mercury-vapor discharge lamp is characterized in accordance with the invention in that an inner circumference d s of the electrode shield meets the relation: 1.25 x de ⁇ dg ⁇ 2.5 x de, where d e is an outer circumference of the electrode.
  • the temperature of the electrode shield during operation of the low-pressure mercury-vapor discharge lamp is so high that it is at least substantially precluded that (emitter) material deposited on the electrode shield by evaporation or so-called sputtering from the electrode(s), reacts with the mercury present in the discharge, so as to form amalgams.
  • the lower limit, 1.25 x d e , of the inner circumference d s of the electrode shield ensures that (mechanized) mounting of the electrode shield does not lead to too small an interspace between the electrode shield and the electrode.
  • An inner circumference d s of the electrode shield below 2.5 x d e ensures that, in operation, the temperature of the (emitter) material deposited on the electrode shield is in the desired temperature range to effectively counteract the formation of amalgams.
  • the electrode shield is provided with a slit on a side facing the discharge space. A slit in the electrode shield in the direction of the discharge causes a relatively short discharge path between the electrodes of the low-pressure mercury-vapor discharge lamp. This is favorable for a high efficiency of the lamp.
  • the slit preferably extends parallel to the axis of symmetry of the electrode shield (so-called lateral slit in the electrode shield).
  • the aperture or slit in the electrode shield faces away from the discharge space.
  • the electrode shield is tubular in shape and not provided with a slit.
  • Fig. 1 is a cross-sectional view of an embodiment of the low-pressure mercury- vapor discharge lamp in accordance with the invention in longitudinal section; 5
  • Fig. 2 shows a detail of Fig. 1, which is partly drawn in perspective
  • Fig. 3 A shows an embodiment of the electrode shield about the electrode as shown in Fig. 2;
  • Fig. 3B shows an alternative embodiment of the electrode shield about the electrode as shown in Fig. 3 A;
  • Fig. 4 shows the mercury consumption of a low-pressure mercury-vapor discharge lamp with an electrode shield in accordance with the invention, operated on a cold- start ballast with a short cycle, in comparison with the mercury consumption of a known discharge lamp
  • Fig. 5 shows the mercury consumption of a low-pressure mercury-vapor discharge lamp with an electrode shield in accordance with the invention, operated on a dimmed ballast with a long cycle, in comparison with the mercury consumption of a known discharge lamp.
  • Fig. 1 shows a low-pressure mercury-vapor discharge lamp comprising a glass discharge vessel 10 having a tubular portion 11 about a longitudinal axis 2, which discharge vessel transmits radiation generated in the discharge vessel 10 and is provided with a first and a second end portion 12a; 12b, respectively.
  • the tubular part 11 has a length of 120 cm and an inside diameter of 24 mm.
  • the discharge vessel 10 encloses, in a gastight manner, a discharge space 13 containing a filling of 1 mg mercury and an inert gas, for example argon.
  • the wall of the tubular part is generally coated with a luminescent layer (not shown in Fig.
  • the end portions 12a; 12b each support an electrode 20a; 20b arranged in the discharge space 13.
  • the electrode 20a; 20b is a winding of tungsten covered with an electron-emitting substance, in this case a mixture of barium oxide, calcium oxide and strontium oxide.
  • the current-supply conductors 30a, 30a'; 30b, 30b' are connected to contact pins 31a, 31a'; 31b, 31b' which are secured to a lamp cap 32a, 32b.
  • an electrode ring is arranged (not shown in Fig. 1) on which a glass capsule for proportioning mercury is clamped.
  • an amalgam comprising mercury and an alloy of PbBiSn is provided in an exhaust tube which is in communication with the discharge vessel 10.
  • the electrode 20a; 20b is surrounded by an electrode shield 22a; 22b having a length l s , which electrode shield is manufactured, in accordance with the invention, from a ceramic material.
  • Fig. 2 is a partly perspective view of a detail shown in Fig. 1, the end portion 12a supporting the electrode 20a via the current supply conductors 30a, 30a'.
  • the elecfrode 20a is surrounded by a tubular elecfrode shield 22a, which is supported by a supporting wire 26a, which is provided in the end portion 12a.
  • Figs. 3 A and 3B are cross-sectional views of two embodiments of the tubular electrode shield 22a.
  • the cross-sectional views shown in Figs. 3 A and 3B are rotated through 90° relative to the longitudinal axis 2 in Fig. 2.
  • the electrode 20a is very schematically shown as a part of a winding, said electrode having an outer circumference which is referenced d e .
  • the cylindrically symmetrical electrode shield 20a has an inner circumference referenced d s .
  • the electrode shield may also be of (regular) polygonal shape, for example an at least substantially cubical or hexagonal electrode shield.
  • the electrode shield 22a is provided with a lateral slit 25a; 25 a' with an aperture which is referenced d s ⁇ .
  • the electrode shield precludes that (emitter) material originating from the electrode is deposited on the inner wall of the discharge vessel, thereby preventing undesirable blackening.
  • the temperature of (emitter) material deposited on the ceramic electrode shield is so high during operation of the low-pressure mercury-vapor discharge lamp that the material cannot form mercury- containing amalgams, so that a considerable reduction in mercury consumption of the lamp is achieved.
  • low-pressure mercury-vapor discharge lamps manufactured in accordance with the invention were compared to known discharge lamps.
  • Fig. 4 the mercury consumption of a low-pressure mercury-vapor discharge lamp comprising an electrode shield in accordance with the invention is compared with the mercury consumption of a known discharge lamp, the discharge lamps being operated on a so-called cold-starting ballast with a short switching cycle in which the lamp, alternately, burns for 15 minutes and is switched off for 5 minutes.
  • the electrode provided with a tubular DGA electrode shield exhibited a mercury consumption in the area of the electrode of 25 ⁇ g (curve a), whereas the known lamp exhibited a mercury consumption in the area of the electrode of 148 ⁇ g (curve b).
  • the use of the DGA tube in accordance with the invention causes the mercury consumption in the area of the electrode to be reduced by approximately 70%.
  • the mercury consumption of a low-pressure mercury- vapor discharge lamp comprising an electrode shield in accordance with the invention is compared with the mercury consumption of a known discharge lamp, the discharge lamps being operated on a dimmed ballast for 1250 hours with a long switching cycle in which the lamps alternately burn for 165 minutes and are switched off for 15 minutes.
  • the electrode comprising a tubular DGA electrode shield exhibited a mercury consumption in the area of the electrode of 25 ⁇ g (curve a'), whereas the known lamp exhibited a mercury consumption in the area of the electrode of 225 ⁇ g (curve b').
  • the discharge vessel does not necessarily have to be elongated and tubular; it may alternatively take different shapes.
  • the discharge vessel may have a curved shape (for example meander-shaped).
  • the invention is embodied in each novel characterizing part and each combination of characterizing parts.

Landscapes

  • Vessels And Coating Films For Discharge Lamps (AREA)
  • Discharge Lamp (AREA)
PCT/IB1999/000774 1998-05-08 1999-04-29 Low-pressure mercury-vapor discharge lamp Ceased WO1999059189A1 (en)

Priority Applications (4)

Application Number Priority Date Filing Date Title
DE69911538T DE69911538T2 (de) 1998-05-08 1999-04-29 Niederdruckquecksilberdampfentladungslampe
EP99914706A EP0995223B1 (en) 1998-05-08 1999-04-29 Low-pressure mercury-vapor discharge lamp
KR1020007000098A KR100560229B1 (ko) 1998-05-08 1999-04-29 저압 수은 방전등
JP2000548907A JP2002515636A (ja) 1998-05-08 1999-04-29 低圧水銀蒸気放電灯

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
EP98201548 1998-05-08
EP98201548.9 1998-05-08

Publications (1)

Publication Number Publication Date
WO1999059189A1 true WO1999059189A1 (en) 1999-11-18

Family

ID=8233708

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/IB1999/000774 Ceased WO1999059189A1 (en) 1998-05-08 1999-04-29 Low-pressure mercury-vapor discharge lamp

Country Status (8)

Country Link
US (2) US6359385B1 (enExample)
EP (1) EP0995223B1 (enExample)
JP (1) JP2002515636A (enExample)
KR (1) KR100560229B1 (enExample)
CN (1) CN1278369C (enExample)
DE (1) DE69911538T2 (enExample)
TW (1) TW435811U (enExample)
WO (1) WO1999059189A1 (enExample)

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2001039244A1 (en) * 1999-11-24 2001-05-31 Koninklijke Philips Electronics N.V. Low-pressure mercury-vapor discharge lamp
WO2001067486A1 (en) * 2000-03-09 2001-09-13 Koninklijke Philips Electronics N.V. Low-pressure mercury-vapor discharge lamp

Families Citing this family (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
TW435811U (en) * 1998-05-08 2001-05-16 Koninkl Philips Electronics Nv Low-pressure mercury-vapor discharge lamp
US9298513B2 (en) * 2004-10-07 2016-03-29 International Business Machines Corporation Method and structure for autonomic application differentiation/specialization
US20060238146A1 (en) * 2005-04-25 2006-10-26 Moisin Mihail S Methods and apparatus to enhance operation of fluorescent lamps
US7737639B2 (en) * 2008-03-13 2010-06-15 General Electric Company Fluorescent lamps having desirable mercury consumption and lumen run-up times

Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE1060991B (de) * 1957-02-15 1959-07-09 Patra Patent Treuhand Einrichtung zur Verhinderung stoerender Schwaerzungen an Leuchtstofflampen
SU972613A2 (ru) * 1981-04-08 1982-11-07 Предприятие П/Я А-3609 Электродный узел газоразр дной лампы

Family Cites Families (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2228327A (en) * 1929-05-04 1941-01-14 Hans J Spanner Discharge device
US2862131A (en) * 1951-02-27 1958-11-25 Saint Gobain Glass for glow discharge lamps such as fluorescent luminescent lamps and the like
US2959702A (en) * 1958-07-02 1960-11-08 Westinghouse Electric Corp Lamp and mount
US2946909A (en) * 1959-03-30 1960-07-26 Westinghouse Electric Corp Discharge device
US4032813A (en) * 1974-08-19 1977-06-28 Duro-Test Corporation Fluorescent lamp with reduced wattage consumption having electrode shield with getter material
US4093893A (en) * 1976-11-22 1978-06-06 General Electric Company Short arc fluorescent lamp
US5686795A (en) * 1995-10-23 1997-11-11 General Electric Company Fluorescent lamp with protected cathode to reduce end darkening
CN1146010C (zh) * 1997-03-27 2004-04-14 皇家菲利浦电子有限公司 低压汞放电灯
TW435811U (en) * 1998-05-08 2001-05-16 Koninkl Philips Electronics Nv Low-pressure mercury-vapor discharge lamp
TW423703U (en) * 1998-05-08 2001-02-21 Koninkl Philips Electronics Nv Low-pressure mercury vapor discharge lamp

Patent Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE1060991B (de) * 1957-02-15 1959-07-09 Patra Patent Treuhand Einrichtung zur Verhinderung stoerender Schwaerzungen an Leuchtstofflampen
SU972613A2 (ru) * 1981-04-08 1982-11-07 Предприятие П/Я А-3609 Электродный узел газоразр дной лампы

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
DATABASE WPI Week 8337, Derwent World Patents Index; AN 1983-763663/37 *

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2001039244A1 (en) * 1999-11-24 2001-05-31 Koninklijke Philips Electronics N.V. Low-pressure mercury-vapor discharge lamp
WO2001067486A1 (en) * 2000-03-09 2001-09-13 Koninklijke Philips Electronics N.V. Low-pressure mercury-vapor discharge lamp

Also Published As

Publication number Publication date
EP0995223A1 (en) 2000-04-26
US6525473B2 (en) 2003-02-25
JP2002515636A (ja) 2002-05-28
TW435811U (en) 2001-05-16
DE69911538D1 (de) 2003-10-30
CN1278369C (zh) 2006-10-04
CN1273692A (zh) 2000-11-15
US6359385B1 (en) 2002-03-19
US20020074942A1 (en) 2002-06-20
DE69911538T2 (de) 2004-06-03
KR100560229B1 (ko) 2006-03-10
EP0995223B1 (en) 2003-09-24
KR20010021540A (ko) 2001-03-15

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