WO1999057364A1 - Process for producing pulp with a mixture of formic acid and acetic acid as cooking chemical - Google Patents
Process for producing pulp with a mixture of formic acid and acetic acid as cooking chemical Download PDFInfo
- Publication number
- WO1999057364A1 WO1999057364A1 PCT/FI1999/000372 FI9900372W WO9957364A1 WO 1999057364 A1 WO1999057364 A1 WO 1999057364A1 FI 9900372 W FI9900372 W FI 9900372W WO 9957364 A1 WO9957364 A1 WO 9957364A1
- Authority
- WO
- WIPO (PCT)
- Prior art keywords
- cooking
- pulp
- acid
- acetic acid
- formic acid
- Prior art date
Links
Classifications
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21C—PRODUCTION OF CELLULOSE BY REMOVING NON-CELLULOSE SUBSTANCES FROM CELLULOSE-CONTAINING MATERIALS; REGENERATION OF PULPING LIQUORS; APPARATUS THEREFOR
- D21C3/00—Pulping cellulose-containing materials
- D21C3/20—Pulping cellulose-containing materials with organic solvents or in solvent environment
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21C—PRODUCTION OF CELLULOSE BY REMOVING NON-CELLULOSE SUBSTANCES FROM CELLULOSE-CONTAINING MATERIALS; REGENERATION OF PULPING LIQUORS; APPARATUS THEREFOR
- D21C3/00—Pulping cellulose-containing materials
- D21C3/003—Pulping cellulose-containing materials with organic compounds
Definitions
- the invention relates to a process based on formic acid cooking for producing pulp from herbaceous plants and deciduous trees by using acetic acid as an additional cooking chemical.
- the pulp produced in this manner can be used, for instance, in fine paper and board production as a short-fibered material
- the invention also relates to a process for adjusting the hemicellulose content of the pulp in the formic-acid-based pulping process by using acetic acid as an additional cooking chemical.
- Hemicellulose is found in plants in amount of 15 to 30% of the dry matter content Hemicellulose and cellulose molecules are not chemically bound to each other, but they are linked by hydrogen bonds and van der Waals forces Typically, hemicellulose is relatively easily hydrolyzed by the effect of strong alkalis and acids
- Finnish Patent Application 933 729 discloses a process for producing pulp by using acetic acid as the main cooking chemical and formic acid as an additional cooking chemical In this method, temperature has to be raised high to 130 to 190 °C, whereby the hemicellulose starts decomposing into furfural, and in addition, losses of formic acid arise from the elevated tem- perature.
- acetic acid is inherently formed to some extent during the process, since acetyl groups bound in the hemicellulose break up during the cooking and pulp washing.
- the amounts are insignificant, in the order of less than 1 % of the total amount of cooking acid, so they have no effect on the hemicellulose content of the pulp 2
- the object of the invention is to provide a process based on formic acid cooking for producing pulp from herbaceous plants and deciduous trees.
- the process is characterized by employing acetic acid as an additional cooking chemical.
- the object of the invention is also to provide a process for adjusting the hemicellulose content of the pulp in connection with the formic acid cooking by using acetic acid as an additional cooking chemical.
- acetic acid as an additional cooking chemical.
- the invention relates to a process based on formic acid cooking for producing pulp from herbaceous plants and deciduous trees by using acetic acid as an additional cooking chemical.
- the process is preferably a single- stage formic acid process.
- the amount of formic acid in the cooking acid is within the range of 80 to 40% and the amount of acetic acid 8 to 50%, pref- erably 10 to 40%, particularly preferably 15 to 40%.
- the total content of organic acids in the cooking acid is typically 75 to 90% (the rest being water).
- the cooking acid refers to an acid composition to be fed into cooking.
- Cooking temperature is 110 to 140 °C, preferably 115 to 125 °C and a typical cooking time is 20 to 80 min.
- Cooking pressure is typically within the range of 1.5 to 3 bar.
- cooking is typically performed in a single-stage, continuous, pressurized, vertical-tube reactor, in which the cooking temperature is provided by hot acids and acid vapours returned from the evaporating plant and the distillation.
- the cooking acids are in general 3 allowed to impregnate into the raw material to be cooked, for instance, in a horizontal tube reactor, in which the acid impregnation temperature is typically about 80 °C and the impregnation time is 5 to 30 min.
- a regenerated mixed acid containing formic acid and acetic acid is preferably used as a cooking chemical.
- Regeneration of cooking chemicals is typically performed by evaporation and distillation in such a way that a strong cooking liquor is evaporated in a multistage evaporator to a concentration of 50 to 80% (dry solids content) of dissolved solids and water is distilled from the diluted acids by overpressure to a total concentration of 80 to 90% of formic acid and acetic acid, and this mixed acid is returned to cooking.
- the acetic acid obtained from the process is typically distilled in pressure columns to the effect that pure acetic acid is obtained as a bottom product and strong formic acid and acetic acid mixture is obtained as an overhead product, which is returned to cooking.
- the regeneration of the acetic acid is facilitated and it can be performed with fewer regeneration columns than in known processes.
- the use of acetic acid together with formic acid as a cooking chemical thus improves the process economy also in regeneration of chemi- cals. If the acetic acid concentration of the cooking chemical is allowed to exceed 30%, such a feed composition level is achieved in three-component distillation that water, formic acid and acetic acid can be separated with two columns (otherwise 3 to 4 columns would be needed).
- the cooking liquor is separated from the prepared pulp by pressing or by filter washing, and counter-current washing with water is performed on the pulp with multi-stage filters typically using a low dilution factor of 0.7 to 1.3, to the effect that the total acid concentration of the recovered washing acid is 50 to 70%.
- the bound formic acid is removed from the pulp typically at a tern- 4 perature of 50 to 95 °C, the acid concentration being 5 to 50%, residence time being 1 to 3 hours.
- bleaching with oxidizing bleaching chemicals is performed after the cooking.
- the oxidizing bleach is preferably a hydrogen peroxide bleach.
- the pulp, treated in accordance with the invention, obtained from the cooking and bleaching steps, is supplied to a pa- permaking process of fine grade paper, in which long-fibred pulp (reinforcing fibre) is combined therewith in a suitable proportion.
- a suitable proportion is e.g. 30 to 80% of short-fibred pulp from herbaceous plants or deciduous trees, the rest being reinforcing fibre, depending on the fibre length of the plants.
- Herbaceous plants need not be refined for the preparation of a pulp mix.
- the invention also relates to a process for adjusting the hemicellulose content of the pulp in connection with producing a formic-acid-based pulp by using acetic acid as a cooking chemical.
- the conditions of the process i.e. the amounts of formic acid and acetic acid, cooking temperature and cooking times are the same as those described above.
- the hemicellulose content of the pulp can be adjusted to suit the raw material used (herbaceous plants and deciduous trees), and in addition, to suit each use of the pulp.
- xylose content indicating the hemicellulose content of the pulp can thus be adjusted in the desired manner.
- acetic acid preferably 10 to 40%, because in this manner the strength properties of the paper can also be improved.
- Excessive use of acetic acid is not preferable, since in that case the kappa number tends to remain excessively high in the temperature range where the use of formic acid is most preferable. If the kappa number is lowered by raising the temperature, a range is easily achieved, where losses of formic acid start arising as a result of thermal decomposition.
- acetic acid is used only in minor quantities, preferably 10 to 15%. If it is desired to emphasize strength 5 properties and yield, acetic acid is used in a larger quantity, preferably 20 to 50%.
- acetic acid is used in very small quantities, i.e. less than 10%.
- the process of the invention can use herbaceous plants and deciduous trees as raw material.
- Herbaceous plants generally refer to non-wood sources of fibre.
- the most important sources of fibre include straw, e.g. cereal straw (rice, wheat, rye, oats, barley); grasses, e.g. esparto grass, sabai grass and lemon grass; reeds, e.g. papyrus, common reed, sugar cane and bamboo; bast fibres, e.g.
- stalks of common flax stalks of linseed flax, kenaf, jute and hemp
- leaf fibres e.g. manilla hemp and sisal
- seed-coat fibres such as cotton and cotton linters.
- birch is useful, for instance.
- the process is also found to suit e.g. chestnut, which is not considered particularly suitable for pulping so far.
- Herbaceous plants used as raw material need not be pretreated, for instance, by fractionating, but the stalks, leaves, knots and spikes of the herbaceous plants can be cooked such as they are discharged from a chaffcutter in the harvesting phase, in 5 to 15 cm long pieces of straw and leaves. Thus biomass is not wasted, and short fibres are not lost.
- Example 1 Reed canary grass pulp (600 kg) was prepared from non- fractionated reed canary grass chaff with foliage. Cooking conditions were as follows: formic acid content of the cooking liquor was 70 to 75%, acetic acid content 10% and water content 15 to 20%; cooking temperature 115 to 120 °C, pressure 1.5 bar and cooking time 50 min. The obtained cellulose was bleached with two-stage alkaline hydrogen peroxide bleaching.
- Fine paper was prepared on a pilot scale from the reed canary grass pulp obtained in this manner, using a fibre composition 50% reed canary grass pulp and 50% pine pulp prepared by sulphate process.
- the reed canary grass pulp was not refined.
- High-quality commercial pine/birch sulphate pulp (50% pine pulp and 50% birch pulp) was used as reference pulp. Pulps were run at speeds of 900 to 1380 m/min. The runability of the reed canary grass pulp was very good at all speeds, in comparison with the reference pulp, the reed canary grass pulp run in the same conditions was better as regards opacity, light scattering, bulk, smoothness and porosity.
- RCG reed canary grass
- P pine kraft pulp
- B birch kraft pulp
- D.S. dry solids
- cd cross direction
- md machine direction
- Chestnut chips were cooked in following conditions: formic acid content of the cooking liquor 72%, acetic acid content 10% and water content 18%, cooking temperature 120 °C, pressure 2.0 bar and cooking time 50 min.
- Two-stage alkaline peroxide bleaching was performed on the obtained pulp.
- the Schopper-Riegler number of brown pulp was 18.5, kappa number 27.6 and tensile index of a sheet test 76.2 unground.
- the Schopper-Riegler number of bleached pulp was 18.0, brightness 81.9% ISO and tensile index 37.5 unground.
- Reed canary grass pulp was prepared from non-fractionated reed canary grass chaff with foliage.
- pulp absorption was performed at 80 °C for 20 min.
- Five cookings and a zero-test (with formic acid alone) were performed in conditions described in Table 2 here below.
- the table shows cooking temperatures and cooking times as well as the formic acid and acetic acid contents of the cooking liquor (the rest being water).
- Cooking pressure was within the range of 1.5 to 2.5 bar. Kappa number, xylose content and pulp yield were determined on the obtained pulp, which appear from Table 2, too.
- the obtained pulps were bleached by using two-stage alkaline per- 8 oxide bleaching.
- Table 3 shows the xylose content, yield and tensile index of the bleached pulps.
- Bleached reed canary grass pulp was prepared from non- fractionated reed canary grass chaff with foliage.
- Cooking conditions were as follows: formic acid content of the cooking liquor 53%, acetic acid content 30% and water content 17%.
- Cooking temperature was 119 °C.
- Cooking pressure was 1.8 bar.
- the reed canary grass pulp was mixed with bleached, dried pine sulphate pulp ground in PFI mill (2500 rpm).
- the mixed chemical pulp (reed canary grass/pine 50:50) was prepared into paper sheets and the technical properties thereof were measured. Tensile strength index of a paper sheet was 68.4, tear index 5.2 and bulk 1.28. These values met the requirements set for fine paper.
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- Paper (AREA)
Abstract
Description
Claims
Priority Applications (7)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CA002331089A CA2331089C (en) | 1998-05-05 | 1999-05-04 | Process for producing pulp with a mixture of formic acid and acetic acid as cooking chemical |
DE69939016T DE69939016D1 (en) | 1998-05-05 | 1999-05-04 | METHOD FOR THE PRODUCTION OF PULP WITH A MIXTURE OF ACETIC ACID AND ANTIC ACID AS COOKING CHEMICALS |
HU0101935A HU228481B1 (en) | 1998-05-05 | 1999-05-04 | Process for producing pulp with a mixture of formic acid and acetic acid as cooking chemical |
BRPI9910160-2A BR9910160B1 (en) | 1998-05-05 | 1999-05-04 | process based on formic acid cooking to produce pulp from herbaceous plants and deciduous trees by the use of acetic acid as an additional cooking chemical and adjusting the pulp hemicellulose content and its use. |
EP99922214A EP1084291B1 (en) | 1998-05-05 | 1999-05-04 | Process for producing pulp with a mixture of formic acid and acetic acid as cooking chemical |
AU39344/99A AU755788B2 (en) | 1998-05-05 | 1999-05-04 | Process for producing pulp with a mixture of formic acid and acetic acid as cooking chemical |
US09/674,678 US6562191B1 (en) | 1998-05-05 | 1999-05-04 | Process for producing pulp with a mixture of formic acid and acetic acid as cooking chemical |
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
FI980995A FI116390B (en) | 1998-05-05 | 1998-05-05 | Process for making pulp |
FI980995 | 1998-05-05 |
Publications (1)
Publication Number | Publication Date |
---|---|
WO1999057364A1 true WO1999057364A1 (en) | 1999-11-11 |
Family
ID=8551657
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
PCT/FI1999/000372 WO1999057364A1 (en) | 1998-05-05 | 1999-05-04 | Process for producing pulp with a mixture of formic acid and acetic acid as cooking chemical |
Country Status (12)
Country | Link |
---|---|
US (1) | US6562191B1 (en) |
EP (1) | EP1084291B1 (en) |
CN (1) | CN1170031C (en) |
AT (1) | ATE399900T1 (en) |
AU (1) | AU755788B2 (en) |
BR (1) | BR9910160B1 (en) |
CA (1) | CA2331089C (en) |
DE (1) | DE69939016D1 (en) |
ES (1) | ES2308840T3 (en) |
FI (1) | FI116390B (en) |
HU (1) | HU228481B1 (en) |
WO (1) | WO1999057364A1 (en) |
Cited By (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO2002053829A1 (en) * | 2000-12-29 | 2002-07-11 | Chempolis Oy | Method for producing furfural, acetic acid and formic acid from spent pulp-cooking liquor |
US7097738B2 (en) * | 2001-07-13 | 2006-08-29 | Chempolis Oy | Process for producing pulp |
EP2336222A1 (en) * | 2009-12-17 | 2011-06-22 | Shell Internationale Research Maatschappij B.V. | Process for treating lignocellulosic biomass material |
EP2374930A1 (en) * | 2008-12-09 | 2011-10-12 | Shandong Fuyin Paper & Environmental Protection Technology Co., Ltd | Raw paper and production method and application thereof |
WO2015104506A1 (en) | 2014-01-10 | 2015-07-16 | Arkema France | Hydrogen peroxide compositions for the delignification of plant matter, and uses thereof |
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US7771565B2 (en) * | 2006-02-21 | 2010-08-10 | Packaging Corporation Of America | Method of pre-treating woodchips prior to mechanical pulping |
FI121811B (en) * | 2007-06-01 | 2011-04-29 | Upm Kymmene Corp | New dispersions and processes for their preparation |
FI123052B (en) * | 2011-09-23 | 2012-10-15 | Chempolis Oy | Pretreatment method for producing water soluble sugars from lignocellulosic material |
CN103131017B (en) * | 2011-11-22 | 2016-03-16 | 济南圣泉集团股份有限公司 | A kind of technique extracting xylogen from lignocellulose biomass |
CN103898786B (en) * | 2012-12-25 | 2016-02-10 | 济南圣泉集团股份有限公司 | A kind of comprehensive utilization process of biomass material |
US9540244B2 (en) * | 2013-06-05 | 2017-01-10 | Mississippi State University | Methods for synthesizing graphene from a lignin source |
CN103669101A (en) * | 2013-12-11 | 2014-03-26 | 苏州谊恒印务有限公司 | Preparation method of corncob printing paper pulp |
CN103643587A (en) * | 2013-12-11 | 2014-03-19 | 苏州谊恒印务有限公司 | Preparation method of tung branch printing paper pulp |
CN103643585A (en) * | 2013-12-11 | 2014-03-19 | 苏州谊恒印务有限公司 | Preparation method of sweet potato powder printing paper pulp |
CN103643586A (en) * | 2013-12-11 | 2014-03-19 | 苏州谊恒印务有限公司 | Preparation method of greening waste printing paper pulp |
CN105239435B (en) * | 2015-09-02 | 2018-03-27 | 广州市楹晟生物科技有限公司 | A kind of processing method of lignocellulose raw material |
CN106256956A (en) * | 2016-08-31 | 2016-12-28 | 防城港市绿华源农林科技有限公司 | A kind of manufacture method of Herba Cymbopogonis Citrari paper |
CN107034717B (en) * | 2017-05-19 | 2018-08-03 | 广西金荣纸业有限公司 | A kind of preprocess method preparing sinocalamus latiflorus true qualities paper pulp |
CN107044063B (en) * | 2017-05-19 | 2018-08-03 | 广西金荣纸业有限公司 | A kind of once pretreatment immersion liquid A and its application |
CN107119477B (en) * | 2017-05-19 | 2018-09-21 | 广西金荣纸业有限公司 | A kind of sinocalamus latiflorus true qualities paper pulp and its preparation process |
CN109706769B (en) * | 2018-12-29 | 2021-10-01 | 齐鲁工业大学 | Method for separating lignocellulose by blending small molecular aldehyde organic matter with organic acid |
Citations (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP0584675A1 (en) * | 1992-08-25 | 1994-03-02 | GEBRÜDER KÄMMERER PROJEKT AGENTUR GmbH | Wood pulping with acetic acid and formic acid |
WO1995021960A1 (en) * | 1994-02-11 | 1995-08-17 | Valtion Teknillinen Tutkimuskeskus | Process and device for digesting cellulose material in a carboxylic acid mixture |
Family Cites Families (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3553076A (en) * | 1968-01-22 | 1971-01-05 | Weyerhaeuser Co | Non-catalytic process for the production of cellulose from lignocellulosic materials using acetic acid |
FI74750C (en) | 1985-03-22 | 1988-03-10 | Keskuslaboratorio | Process for preparing bleached cellulose pulp from lignin-containing raw material. |
GB8721528D0 (en) | 1987-09-14 | 1987-10-21 | Shell Int Research | Pulping lignocellulose-containing material |
US5656130A (en) * | 1995-04-28 | 1997-08-12 | Union Camp Holding, Inc. | Ambient temperature pulp bleaching with peroxyacid salts |
FI103899B1 (en) * | 1996-11-06 | 1999-10-15 | Chempolis Oy | A process for preparing a particularly light pulp |
-
1998
- 1998-05-05 FI FI980995A patent/FI116390B/en not_active IP Right Cessation
-
1999
- 1999-05-04 CN CNB998058114A patent/CN1170031C/en not_active Expired - Fee Related
- 1999-05-04 EP EP99922214A patent/EP1084291B1/en not_active Expired - Lifetime
- 1999-05-04 CA CA002331089A patent/CA2331089C/en not_active Expired - Fee Related
- 1999-05-04 AT AT99922214T patent/ATE399900T1/en active
- 1999-05-04 WO PCT/FI1999/000372 patent/WO1999057364A1/en active IP Right Grant
- 1999-05-04 ES ES99922214T patent/ES2308840T3/en not_active Expired - Lifetime
- 1999-05-04 HU HU0101935A patent/HU228481B1/en not_active IP Right Cessation
- 1999-05-04 BR BRPI9910160-2A patent/BR9910160B1/en not_active IP Right Cessation
- 1999-05-04 AU AU39344/99A patent/AU755788B2/en not_active Ceased
- 1999-05-04 DE DE69939016T patent/DE69939016D1/en not_active Expired - Lifetime
- 1999-05-04 US US09/674,678 patent/US6562191B1/en not_active Expired - Fee Related
Patent Citations (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP0584675A1 (en) * | 1992-08-25 | 1994-03-02 | GEBRÜDER KÄMMERER PROJEKT AGENTUR GmbH | Wood pulping with acetic acid and formic acid |
WO1995021960A1 (en) * | 1994-02-11 | 1995-08-17 | Valtion Teknillinen Tutkimuskeskus | Process and device for digesting cellulose material in a carboxylic acid mixture |
Non-Patent Citations (1)
Title |
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B. SAAKE ET AL.: "Erzeugung von Zellstoffen nach dem Formacell-Verfahren", DAS PAPIER, no. 10A, 1995, pages V1 - V7 * |
Cited By (7)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO2002053829A1 (en) * | 2000-12-29 | 2002-07-11 | Chempolis Oy | Method for producing furfural, acetic acid and formic acid from spent pulp-cooking liquor |
US6955743B2 (en) | 2000-12-29 | 2005-10-18 | Chempolis Oy | Method for producing furfural, acetic acid and formic acid from spent pulp-cooking liquor |
US7097738B2 (en) * | 2001-07-13 | 2006-08-29 | Chempolis Oy | Process for producing pulp |
EP2374930A1 (en) * | 2008-12-09 | 2011-10-12 | Shandong Fuyin Paper & Environmental Protection Technology Co., Ltd | Raw paper and production method and application thereof |
EP2374930A4 (en) * | 2008-12-09 | 2013-05-22 | Shandong Fuyin Paper & Environmental Prot Technology Co Ltd | Raw paper and production method and application thereof |
EP2336222A1 (en) * | 2009-12-17 | 2011-06-22 | Shell Internationale Research Maatschappij B.V. | Process for treating lignocellulosic biomass material |
WO2015104506A1 (en) | 2014-01-10 | 2015-07-16 | Arkema France | Hydrogen peroxide compositions for the delignification of plant matter, and uses thereof |
Also Published As
Publication number | Publication date |
---|---|
EP1084291A1 (en) | 2001-03-21 |
CN1170031C (en) | 2004-10-06 |
US6562191B1 (en) | 2003-05-13 |
FI980995A0 (en) | 1998-05-05 |
HUP0101935A2 (en) | 2001-09-28 |
BR9910160A (en) | 2001-01-09 |
FI116390B (en) | 2005-11-15 |
AU3934499A (en) | 1999-11-23 |
DE69939016D1 (en) | 2008-08-14 |
BR9910160B1 (en) | 2010-11-30 |
HU228481B1 (en) | 2013-03-28 |
AU755788B2 (en) | 2002-12-19 |
CA2331089C (en) | 2007-11-13 |
CA2331089A1 (en) | 1999-11-11 |
ATE399900T1 (en) | 2008-07-15 |
EP1084291B1 (en) | 2008-07-02 |
CN1299424A (en) | 2001-06-13 |
FI980995A (en) | 1999-11-06 |
HUP0101935A3 (en) | 2002-10-28 |
ES2308840T3 (en) | 2008-12-01 |
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