WO1999047575A1

WO1999047575A1 - Process to make low-molecular weight sma

Info

Publication number: WO1999047575A1
Application number: PCT/EP1999/000856
Authority: WO
Inventors: Luc Louis Théophile VERTOMMEN; Auke Gerardus Talma; Hendrik Jan Willem Van Den Haak
Original assignee: Akzo Nobel N.V.
Priority date: 1998-03-17
Filing date: 1999-02-05
Publication date: 1999-09-23
Also published as: AU2925899A; TW400337B; EP1082369A1; JP2002506895A; CA2324076A1; KR20010041928A

Abstract

The invention pertains to a process to make low-molecular weight (block) copolymers of one or more vinyl and one or more maleic monomers, by radically polymerizing said monomers in the presence of an initer.

Description

PROCESS TO MAKE LOW-MOLECULAR WEIGHT SMA

The present invention relates to a process to make (block) copolymers of vinyl and maleic monomers with a low molecularweight.

Low-molecular weight copolymers of vinyl and maleic monomers, typically comprising styrene and maleic anhydride (LW-SMA), are used in a variety of applications for various purposes. It is known that they can act as pigment dispersant, viscosity modifier, compatibilizer, emulsifier, protective colloid, and the like. Whether they can be used and if so, how efficiently, depends to a large extent on the molecular weight and the molecular weight distribution of the copolymer. For this reason there have been significant efforts to develop processes that allow control over the molecular weight when copolymerizing styrene and maleic anhydride. BE 710138, published in 1968, discloses a process for producing LW-SMA by cotelomerizing the monomers at 150-270°C, using specific telogens (solvents that act as chain transfer agents), without the addition of radical-forming activators and solely under the influence of heat. US 3,451 ,979 (1969) discloses a polymerization process at 175-250°C wherein the molecularweight is controlled by using monocyclic hydrocarbons having a nucleus of 6 carbon atoms, such as cumene and p-cymene, as a solvent. In DE-OS-1 930 217, published in 1970, it is proposed to make LW-SMA by using specific hydroxyalkyi mercaptans in a solution or precipitation polymerization process. US 4,180,637 (1979) discloses a solvent polymerization process wherein LW-SMA is produced by using a hydroxide or a nucleophilic salt of a monovalent ammonium or alkali metal cation. Finally, DD-A 259408 (1988) discloses a solvent polymerization process at 40-100°C wherein LW-SMA is produced by using a chain transfer agent which is a derivative of a thiocarbonic acid.

It is observed that in all of these processes of the prior art, either a reactive solvent (a solvent with chain transfer activity) or specific chain transfer agents (CTAs) are proposed. However, to our knowledge, reactive solvents typically are not used, since they will contaminate the resulting polymer or will require extensive drying steps for their removal from said polymer. Also, the use of sulfur- or metal-containing CTAs is limited to applications wherein the presence of such atoms can be tolerated. In this respect we would like to mention that LW-SMA comprising a sulfur-containing CTA may suffer from discolouration, unpleasant smell, and/or accelerated ageing. Besides these disadvantages, we have found that none of these processes allows for an accurate prediction of the molecular weight of the resulting polymer. Typically, a trial and error approach is needed to find the necessary concentration of reactants under certain reaction conditions. Needless to say, changing one of the parameters of the process (e.g. temperature, in an effort to optimize reactor output) will make it necessary to again optimize the process to obtain LW-SMA with the desired molecular weight. Such continuous optimization not only requires time and effort but also results in waste product not meeting the specifications.

Also, the LW-SMA of the prior art is not easily modified further when a certain use demands different properties. Particularly in the field of compatibilization, the various uses often require a compound with properties that are only partially met by the known LW-SMAs. Hence there is a need for LW-SMAs that can easily be modified.

Furthermore, it is well-known that in conventional LW-SMA production processes, the styrene and the maleic anhydride monomer will have a strong preference for copolymerization in an alternating form. This means that if the monomer feed deviates from a molar ratio of 1 :1 , depending on the process conditions, first an alternating copolymer and later a homopolymeris formed of the excess monomer (resulting in two distinct polymers that are difficult to separate and of which only one type has the desired properties). If the surplus monomer does not homopolymerize, this monomer's conversion rates will be correspondingly low and it will contaminate the formed copolymer. Both results are undesired.

Surprisingly, we have now found a new polymerization process wherein the disadvantages are largely overcome. It was found that just one type of copolymer is formed, irrespective of the monomer ratio, and that the molecular weight of the LW-SMA is very close to easily calculated theoretical values, resulting in substantially reduced optimization efforts and that block copolymers with desired properties can be obtained.

The process is characterized in that use is made of a specific type of molecular weight control agent, viz. initers. Preferably, the initers used have a structure according to formula I): χ₂

R O N / y

Xβ^ \

X₅ i)

wherein:

♦ R represents a group which has at least one carbon atom and is such that the free radical R^« is capable of initiating the free radical polymerization of unsaturated monomers;

♦ at most five of the groups represented by X X₆ are the same or different linear or branched, substituted or unsubstituted (cyclo) alkyl groups, and/or two or more of the groups X X₆ may be linked to form cyclic structures comprising the -CNC- moiety, ♦ the complementary groups X₁ through X₆ are functional groups independently selected from substituted or unsubstituted aryl, cyano, nitro, dialkoxyphosphonyl, R'O-, R'OC(O)-, R'C(O)O-, R'C(O)OC(O)-₍ R'R'NC(O)-,

R'C(O)NR'-, R'C(O)NR'C(O)-, and R'C(O)-, wherein each of R' is, independently, hydrogen or a substituted or unsubstituted hydrocarbyl group, or, alternatively, -CX^X₂X₃ and/or -CX₄X₅X₆ represent a substituted or unsubstituted aryl group. However, also conventional initers may be used, such as products with a tetramethylpiperidineoxy(TEMPO) moiety. Furthermore, as is known in the art, it is possible to combine a peroxide and a conventional stable free radical agent to form an initer in situ. In such cases the preferred ratio of peroxide to stable free radical agent is about 1 :2 on a molar basis, so that each of the two radicals formed during decomposition of the peroxide can be linked to one stable free radical.

The hydrocarbyl groups R' of the preferred initers may independently be either alkyl, aryl, alkaryl, aralkyl, and/or cycloalkyl. Preferably, the substituted or unsubstituted hydrocarbyl group contains less than 30, more preferably less than 15, atoms.

The term "initer" as used herein defines compounds that can initiate and control a polymerization reaction by thermal decomposition, optionally in the presence of an accelerator. The initer must be capable of forming, upon thermal decomposition, two radical fragments of which one must have the predominant tendency to initiate the polymerization reaction, i.e. by forming a stable covalent bond with a monomer molecule thereby transfering the radical to said monomer, whereas the other radical fragment is predominantly a stable free radical as is known in the art. Preferred compounds are of formula I). It is believed that the carbon-centred radical formed upon decomposition initiates the polymerization, whereas the nitroxide radical will function as a stable free radical, terminating the growing chain. Without the invention being limited to such a theory, it is further believed that the termination reaction is reversible at the polymerization temperature, so that monomers can be inserted between the last monomeric unit and the nitroxide moiety of the initer. This sets these types of compounds apart from regular chain transfer agents which terminate a growing chain and, subsequently, initiate a new, separate chain.

It is noted that the preferred inititers are described in International application No. PCT/EP97/05009 of the same applicant. However, it is not disclosed therein that these compounds are particularly suitable for the production of LW-SMA (block) copolymers and that by using the compounds for this particular class of polymers, all the disadvantages of the prior art can be overcome.

Presumably, the polymerization process according to the invention is a "pseudo-living polymerization process," which term stands for the radical polymerization process in which ethylenically unsaturated monomers are polymerized by means of at least one initer. According to a non-limiting theory, the polymerization kinetics in such a process depend, amongst others, on the thermal decomposition rate of the initer that is used.

With respect to the initers of formula I), it is preferred that X X₆ are not linked to form cyclic structures. Furthermore, it is preferred that each of X^Xe contains fewer than 30 carbon atoms. More preferably, each of X X₆ contains fewer than 10 carbon atoms, in order to produce initers with a low molecular weight. Most preferably, at most five of X X₆ are independently selected from methyl, ethyl, propyl, isopropyl, butyl, sec.butyl, tert.butyl, and cyclohexyl. Furthermore, it is preferred that the process involves the use of initers of formula I) wherein the functional group is selected from substituted or unsubstituted aryl, cyano, dialkoxyphosphonyl, R'C(O)O-, and R'OC(O)-. Of the aryl groups, phenyl, toluyl, and naphthyl are preferred. More preferred is a process wherein the initer possesses a cyano, phenyl, R'C(O)O- or dialkoxyphosphonyl group. Even more preferred is a process where the initer possesses a cyano or phenyl group. Preferably, these initers can be used without toxic by-products being formed.

Non-limiting examples of functional groups of the initer further include methylether, ethylether, propylether, butylether, poly(alkylether), methylketone, ethylketone, propylketone, isopropylketone, butylketone, isobutylketone, tert.butylketone, diethoxyphosphonyl, ethoxypropoxyphosphonyl, dipropoxy- phosphonyl, dibutoxyphosphonyl,diisobutoxyphosphonyl,-C(O)OCH₃, -C(O)OC₂H₅, and C_rC₂₀ carboxylicacid esters.

The R group may bear one or more of the ONC(X₁.₃)C(X₄.₆) functions, as long as each of the radicals R* formed upon the scission of one or more of the R-O bonds is capable of initiating the free radical polymerization of an unsaturated monomer. Furthermore, it is preferred that R is not of a polymeric nature, meaning that R preferably does not comprise more than approximately 4 recurring units incorporated through radical polymerization of one or more unsaturated monomers. Preferably, R does not contain more than two of such recurring units. Most preferred are compounds wherein R equals C(X₁.₃) or C(X₄.₆).

The process to make the LW-SMA can be conducted at various temperatures, typically ranging from 50 to 200°C. More preferably, the polymerization temperature is from 80 to 150°C. Depending on the polymerization temperature that is chosen, an initer or, less preferably, a combination of a conventional stable free radical agent and a peroxide, with an acceptable decomposition rate is selected. From, for instance, Macromolecules, 1995, 28, 8722-8728, it is known that the use of electron-withdrawing functional groups will stabilize the R-O bond of the preferred initers, whereas electron-donating functional groups will labilize it. Given this information and the teaching of this document, the man skilled in the art will have no problem selecting suitable types and numbers of functional groups to obtain usable initers. Before conducting actual polymerization experiments, the half-life of the preferred initers may be determined in one or more well-known ways, this in order to establish at which temperature it can be used.

The amount of initer to be used in the process according to the invention depends on the molecular weight of the resulting LW-SMA that is desired. More specifically, the process according to the invention results in polymers with a number average molecular weight (Mn) close to the theoretical value (Mth), calculated from (M_ιnιter + [monomer]/[initer]*M_monomer)^*conversion, wherein M_monomer '^s the average molecularweight of the repeating monomeric units. For a perfectly alternating styrene maleic anhydride copolymer M_monomer is about (104+98)/2 = 101. Because LW-SMAs are generally considered to be polymers having a molecularweight from about 1000 to about 20 000 Dalton, this means that ideally the molar amount of initer to be used is about 0.1 to 0.005 times the molar amount of monomer. In practice, the molar amount of initer will vary from 0.15 to 0.001 times the molar amount of monomer in the polymerizing system. More preferably, the molar amount of initer is from 0.12 to 0.005 times the molar amount of monomer.

The ethylenically unsaturated monomers typically polymerized in the process according to the invention are styrene and maleic anhydride. However, the process according to the invention is not limited to a process wherein only these two monomers are employed. Instead of maleic anhydride also other 8

maleic monomers like citraconic anhydride, itaconic anhydride, maleic acid, fumaric acid, citraconic acid, itaconic acid, half-esters of said acids with C_rC₁₈ monohydric alcohols, such as methyl maleate and sec.butyl maleate, maleimides, citraconimides, itaconimides, and/or mixtures of these monomers, optionally together with maleic anhydride, can be used. Similarly, (part of) the styrene may be replaced by other vinyl monomers like α-olefins; isoprene; butadiene; acrylonitrile; vinyl chloride; vinyl esters of organic acids, such as vinyl acetate and vinyl stearate; (alkyl)(meth)acrylicacid or esters thereof, such as methylmethacrylate; vinyl phosphonic acid or esters thereof; vinyl pyridine; vinyl alkyl ethers, such as vinyl methyl ether and vinyl isobutyl ether; and other vinyl aromatic compounds or derivatives thereof, such as styrene phosphonic acid, styrene phosphonic esters, vinyl toluene, vinyl xylene, 2,4- dimethylstyrene, 2,5-dichlorostyrene, 2-methyl-4-chlorostyrene, and so forth. Preferably, at least styrene and maleic anhydride are used in the process according to the invention. More preferably, the amount of both maleic anhydride and styrene is at least 10% by weight of the final polymer. Most preferred is a process resulting in an LW-SMA containing at least 30% w/w of styrene and maleic anhydride.

The molar ratio between the two types of monomers in the process is not critical. Independent of the ratio that is used, essentially one type of polymer is formed. If one monomer is used in excess, this monomer, depending on its structure, will homopolymerize at a later stage in the process to form a separate block which is attached to the polymer formed in the previous step when both types of monomers were still present. This is in contrast to, for instance, conventional batch polymerization processes, where the excess monomer is formed as a homopolymer which is not attached to previously formed copolymer. Therefore, when the molecular ratio of the first formed polymer does not equal the monomer ratio of the monomer feed, the process of the invention will result in a block copolymer with blocks having an alternating styrene-maleic anhydride structure and a block with a different structure, depending on the monomer type and ratio used. In order to obtain an LW-SMA with the desired properties, it is preferred that the ratio of vinyl to maleic monomer ranges from 0.6 to 5, with a ratio between 0.8 and 3 being more preferred. Because styrene blocks, attached to the alternating styrene- maleic anhydride copolymer, are easily formed, it is preferred to use a slight molar excess of styrene vis-a-vis maleic anhydride.

If so desired, it is possible to introduce new monomer(s) into the polymerizing system, preferably after more than 50, more preferably more than 90% w/w, of the LW-SMA monomers have reacted, in order to create a block copolymer having an LW-SMA block and a block consisting of one or more of the monomers present after the introduction of the new monomers. What type of block will be formed will depend to a large extent on the copolymerization parameters of the monomers that are present. Such a step may be repeated to create block copolymers having three or more distinct types of blocks in the molecule. Preferably, the newly added monomers are selected from the vinyl monomers as described above. The building of such block copolymers is not possible with the LW-SMAs of the prior art, since the polymerization in conventional processes is terminated by chain transfer, disproportionation or combination reactions. It is believed that in the process according to the invention, the nitroxide moiety of the initer, as indicated above, remains at one end of the polymer chain and allows the further insertion of monomer when such monomer is introduced. Preferably, the LW-SMA blocks have a combined length of at least 5, preferably more than 10, monomeric units (of either type of monomer) before the next block is formed.

Although the process according to the invention can be conducted in various ways, e.g. as mass, suspension, emulsion, or solvent polymerization, a solvent polymerization process is preferred. More preferably, the process is a solvent 10

polymerization process wherein the solvent is non-reactive, meaning that less than 5% of all end groups of the resulting polymer consists of a solvent moiety. The total concentration of monomer in said solvent polymerization process can vary over a wide range and is only limited by reactor efficiency and the solubility of the monomer (and formed polymer) in the solvent. More specifically, the solubility of the monomer/polymer will depend on the type of solvent, the temperature, and the monomer type and ratio used. Typically, concentrations of monomer of less than 10% by volume (% v/v) are considered to be uneconomical, whereas concentrations of over 85 % v/v typically result in viscosity / solubility problems. A preferred monomer concentration therefore is 20-65% v/v, based on the total volume of solvent and monomer.

Solvents that can be used in the process according to the invention include, but are not limited to, ethers, such as dioxane and tetrahydrofuran; ketones, such as acetone, methylethyl ketone, and the like; esters, such as ethyl acetate and methoxypropyl acetate; aromatic solvents, such as toluene and xylene; products like dimethyl formamide and nitropropane; as well as mixtures thereof.

In the preferred process according to the invention, wherein initers are used, use may be made of further additives such as conventional radical generating species, including organic peroxides, azo-initiators and UV-initiators; stable free radicals; and chain transfer agents. Also, use can be made of accelerators, additives catalyzing the decomposition of radical forming species as used in the process. Furthermore, if so desired, adjuvants like pigments, stabilizers, colloids, fillers etc. may be added at the start or during the polymerization, as long as they do not interfere in the polymerization process. Alternatively, the adjuvants are added to the polymer (solution) after the polymerization. 11

The initers as used in the process according to the invention may be produced in various conventional ways as described in, for instance, J. Chem. Soc, 1954, 1920-1924). Reactants and reaction conditions are chosen such that during the synthesis at least one of the two carbon-centred radicals attached to the nitrogen atom will bear a functional group. This is most easily achieved by selecting the proper concentration of one or more of the functional group bearing carbon-centred radical precursors. Preferably, the functional group bearing carbon-free radical is obtained by the decomposition of one or more appropriate azo, C-C or other initiators such as diacyl peroxides with a high decarboxylation rate. Depending on the use of the initer, it may be preferable to react only one type of carbon-centred radical (containing a functional group) with the NO gas.

Alternatively, compounds according to the invention can be produced by the well-known reaction of a nitroso compound under influence of heat or with carbon-centred radicals, as described by T. Kolasa, A. Chimiak, and A. Kitowski in J. Prakt. Chem., 1975, 317, 252-256.

The invention will be further illustrated by the following examples.

Experimental

The chemicals used in the following examples were all reagent grade unless specified otherwise. Styrene was supplied by Baker (Baker PA grade). The styrene was freed of inhibitor by a treatment with an alkaline AI₂O₃ column before use. Methyl isobutyl ketone (MIBK) solvent was supplied by Fluka. Perkadox® AIBN (2,2'-azobis[isobutyronitrile]), Lucidol® (75% dibenzoyl peroxide, 25% water), as well as the initers that were used, were supplied by Akzo Nobel or synthesized as laid down in the available documentation. 12

The conversion of monomer into polymer was determined in conventional ways by gas chromatographic (GC) analysis for monomer, using monochlorobenzeneas the internal standard.

The number average molecular weight (Mn), the weight average molecular weight (Mw), and the dispersity (D) of the polymers were analyzed in conventional ways by means of size exclusion chromatography, using THF as the eluent. Polystyrene samples were used as calibration standards.

Polymers were isolated from the solution by precipitation in n-pentane and subsequent drying to constant weight in a vacuum oven at 50°C (20-100 hours).

Polymers were occasionallyfurther characterized by means of 300 or 400MHz ¹H and 100 MHz ¹³C NMR.

No attempt was made to optimize yields.

Example 1

Preparation of initer

N , N ,O-Tris-( 1 -cyano- 1 -methylethvh hvdroxylamine ((IBN)₃NO)

A solution of Perkadox AIBN (152.7 g, 0.93 mol) in 1500 ml of toluene was stirred, flushed with nitrogen gas, and heated to 76°C. A stream of nitrogen 13

monoxide (5 l/hr) was passed through the solution, and a deep greenish/blue colour appeared. Heating was continued for 2 hours at 76°C, 1 hour at 82°C, 30 minutes at 88°C, 15 minutes at 94°C, and finally 15 minutes at 119°C to achieve complete decomposition of the AIBN. Residual nitrogen monoxide was removed by flushing the reaction mixture with nitrogen gas, at which point the colouration changed to yellow. The solvent was removed at the rotary evaporator, and the resulting solution was steam-distilled to remove the byproduct tetramethyl succinonitrile. Next, the water/product mixture was left to cool down to room temperature, and the product precipitated. This solid was removed by filtration, dissolved in dichloromethane, and then dried with magnesium sulfate. Evaporation of the solvent gave 84.3 g (58%) of a yellow solid, the (IBN)₃NO.

14

Examples 2-4

Polymerizations were conducted in a 250 ml three-necked flask which was fitted with an argon gas inlet, a reflux condenser, an inlet through which reactants could be added, and a magnetic stirrer. Argon was flushed through and over the reaction mixture throughout the polymerization. Unless stated otherwise, 60 ml of methyl isobutyl ketone solvent (MIBK) was purged with argon and heated to a polymerization temperature of 114°C. When this temperature was reached, a solution of 9.5 g of styrene, 9.0 g of maleic anhydride, and the various amounts of initer of Example 1 , in 20 ml MIBK, was added in 2 hours at a rate of approximately 0.33 ml/min. Thereafter, the mixture was kept at the polymerization temperature for another 4 hours. The following results were obtained.

Experiment mol% of initer M_th M_n Styrene on monomers (Dalton) (Dalton) conversion

(%)

2 4 2760 3200 >99

3 6.7 1740 2000 >99

4 6.7 1740 2200 98

For Example 3, the following results were obtained during the polymerization.

Time Styrene conversion M_n (hours) (%) (Dalton)

2 34 1750

3 87 1950

4 96 2050

5 99 2075

6 >99 2050

The obtained polymers were odourless. 15

Examples 5 and 6

Following the same procedure as described for Examples 2-4, a solution of 12.4 g of styrene, 5.8 g of maleic anhydride, and the indicated amount of initer, in 20 ml MIBK, was dosed. The following result were obtained.

(%)

5 3.2 2784 3000 80

6 3.2 2944 3200 85

Formation of homopolystyrene was not observed, and the polymer was odourless.

Example 7

Using the equipment as described for Examples 2-4, a mixture of 40 ml of MIBK, 25.8 g of maleic anhydride, 27.1 g of styrene, and 2.54 g of initer of Example 1 was purged with argon, heated to 114°C, and reacted at this temperature for 6 hours, with the following result.

Experiment mol% of initer M_th Styrene on monomers (Dalton) (Dalton) conversion

(%)

7 2 5284 6000 >99

The obtained polymer was odourless. 16

Example 8

Example 5 was repeated. However, at the end of the 4-hour polymerization, the temperature was maintained at 114°C and 53.4 g of butyl acrylate were dosed to the reaction mixture in two hours. The butyl acrylate had been purified before use in the same way the styrene monomer was purified. After addition of the butyl acrylate, the mixture was further reacted for 4 hours at 114°C.

It was found that 50% of the butyl acrylate was polymerized, while analysis with size exclusion chromatography, using a refractive index and a UV detector, showed that only a single polymer was formed. NMR analysis showed it to comprise both polybutyl acrylate units and styrene maleic anhydride units.

This block copolymer is considered very suitable to serve as a coupling agent.

Comparative Examples A and B

Example 5 was repeated, but instead of 6.7% initer, 3.4% of either dibenzoyl peroxide or AIBN was used. However, in both cases an insoluble polymer with a number averaged molecular weight much higher than 10 000 was rapidly formed.

Comparative Example C

Example 2 was repeated, except that 0.5 mol% of AIBN was used in combination with 5 mol% of dodecyl mercaptan (dodecanethiol), based on the total amount of monomers.

Because the chain transfer activity parameter of dodecyl mercaptan in this polymerization system is not known, it is impossible to predict, without further experimentation, what the molecularweight of the resulting polymer would be. Using the indicated large amounts of both chain transfer agent and azo- initiator was expected to result in a very low-molecular weight SMA. However, 17

when more than 99% w/w of the styrene was polymerized, the resulting polymer had a number averaged molecular weight of 3500, which was far higher than expected. Furthermore, the obtained polymer had an undesired unpleasant smell.

Example 9

Using a three-necked flask of 100 ml, a mixture of 5.17 g (0.022 mole) of (IBN)₃NO, 11.51 g (0.11 mole) of styrene, 10.83 g (0.11 mole) of maleic anhydride, and 25 g of methoxypropyl acetate was flushed with Argon and heated to 120°C by submerging the flask in an oil bath. The flask was kept in the bath for 4 hours at this temperature of 120°C.

The resulting polymer was analyzed by means of GPC with the following results: Mn=1166, Mw=2350, and Mp=2172 Dalton.

Claims

18Claims

1. A process for preparing low-molecular weight copolymers of one or more vinyl and one or more maleic monomers, by radically polymerizing said monomers in the presence of a molecular weight control agent, characterized in that the molecularweight control agent is an initer.

2. A process according to claim 1 wherein the initer is a compound of formula I) x₂

R O N / y

y \ ^╧çs i) wherein:

ΓÖª R represents a group which has at least one carbon atom and is such that the free radical R^┬╗ is capable of initiating the free radical polymerization of unsaturated monomers; ΓÖª at most five of the groups represented by X X₆ are the same or different linear or branched, substituted or unsubstituted (cyclo) alkyl groups, and/or two or more of the groups X_rX₆ may be linked to form cyclic structures comprising the -CNC- moiety,

ΓÖª the complementary groups X through X₆ are functional groups independently selected from substituted or unsubstituted aryl, cyano, nitro, dialkoxyphosphonyl, R'O-, R'OC(O)-, R'C(O)O-, R'C(O)OC(O)-, R'R'NC(O)-, R'C(O)NR'-, R'C(O)NR'C(O)-, and R'C(O)-, wherein each of R' is, independently, hydrogen or a substituted or unsubstituted hydrocarbyl group, or, alternatively, -CX^^ and/or - CX₄X₅X₆ represent a substituted or unsubstituted aryl group. 19

3. A process according to claim 1 or 2, characterized in that the monomers to be polymerized comprise at least styrene and maleic anhydride.

4. A process according to claim 3, characterized in that styrene and maleic anhydride are both present in an amount of at least 10% by weight, preferably 30% by weight, of the total monomer composition.

5. A process according to any one of the preceding claims, characterized in that the initer of formula I) comprises a functional group selected from the group consisting of phenyl, cyano, dialkoxyphosphonyl, R'C(O)O-, and ROC(O)-, wherein R' has the meaning as defined above.

6. A process according to claim 5 wherein the functional group is a cyano, phenyl, R'C(O)O- or dialkoxyphosphonyl group, more preferably a cyano or phenyl group.

7. A process according to any one of the preceding claims wherein the polymerization is conducted at a temperature of between 50 and 200┬░C.

8. A process according to any one of the preceding claims wherein the molar amount of the initer is from 0.15 to 0.001 times the molar amount of monomer.

9. A process according to any one of the preceding claims wherein the molar ratio of vinyl monomer to maleic monomer ranges from 0.6 to 5.0. 20

10. A process according to any one of the preceding claims, characterized in that the polymerization is conducted in a solvent which dissolves both monomers.

11. A process according to any one of the preceding claims wherein one or more ethylenically unsaturated monomers are added after a copolymer of vinyl and maleic monomer has been formed, to produce a block copolymer comprising at least one such LW-SMA block.

12. A process according to claim 11 wherein the length of the vinyl and maleic monomer-based copolymer block is at least 5 monomeric units before the additional monomer is introduced into the reaction mixture.

13. Low-molecular weight styrene maleic anhydride (block) copolymer obtainable by a process according to any one of claims 1-12.