WO1998042214A2 - Edible lipid-proteins films and coatings - Google Patents
Edible lipid-proteins films and coatings Download PDFInfo
- Publication number
- WO1998042214A2 WO1998042214A2 PCT/GB1998/000846 GB9800846W WO9842214A2 WO 1998042214 A2 WO1998042214 A2 WO 1998042214A2 GB 9800846 W GB9800846 W GB 9800846W WO 9842214 A2 WO9842214 A2 WO 9842214A2
- Authority
- WO
- WIPO (PCT)
- Prior art keywords
- film
- protein
- emulsion
- calcium
- component
- Prior art date
Links
Classifications
-
- A—HUMAN NECESSITIES
- A23—FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
- A23P—SHAPING OR WORKING OF FOODSTUFFS, NOT FULLY COVERED BY A SINGLE OTHER SUBCLASS
- A23P20/00—Coating of foodstuffs; Coatings therefor; Making laminated, multi-layered, stuffed or hollow foodstuffs
- A23P20/20—Making of laminated, multi-layered, stuffed or hollow foodstuffs, e.g. by wrapping in preformed edible dough sheets or in edible food containers
-
- A—HUMAN NECESSITIES
- A21—BAKING; EDIBLE DOUGHS
- A21D—TREATMENT, e.g. PRESERVATION, OF FLOUR OR DOUGH, e.g. BY ADDITION OF MATERIALS; BAKING; BAKERY PRODUCTS; PRESERVATION THEREOF
- A21D13/00—Finished or partly finished bakery products
- A21D13/20—Partially or completely coated products
- A21D13/26—Partially or completely coated products the coating forming a barrier against migration
-
- A—HUMAN NECESSITIES
- A23—FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
- A23P—SHAPING OR WORKING OF FOODSTUFFS, NOT FULLY COVERED BY A SINGLE OTHER SUBCLASS
- A23P20/00—Coating of foodstuffs; Coatings therefor; Making laminated, multi-layered, stuffed or hollow foodstuffs
- A23P20/10—Coating with edible coatings, e.g. with oils or fats
-
- A—HUMAN NECESSITIES
- A23—FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
- A23P—SHAPING OR WORKING OF FOODSTUFFS, NOT FULLY COVERED BY A SINGLE OTHER SUBCLASS
- A23P20/00—Coating of foodstuffs; Coatings therefor; Making laminated, multi-layered, stuffed or hollow foodstuffs
- A23P20/10—Coating with edible coatings, e.g. with oils or fats
- A23P20/11—Coating with compositions containing a majority of oils, fats, mono/diglycerides, fatty acids, mineral oils, waxes or paraffins
Definitions
- the present invention relates to edible films and coatings which are suitable for use as moisture barriers in foods (such as multicomponent foods), to emulsions and dry mixes for preparing such films, to foods incorporating them and to processes for producing the films, emulsions, mixes and foods.
- the invention relates to films comprising lipid and hydrocolloid conglomerates in which the lipid component is derived from an dried fat composition and/or the hydrocolloid component comprises a starchy leguminous seed protein (such as pea protein).
- the various components have different moisture levels.
- food products include pizzas (in which a moist topping is associated with a crisp base), pies (in which a moist filling is held within a relatively dry crust), quiches and crumbles.
- edible films and coatings can be divided into three classes: hydrocolloids, lipids and composites.
- Typical hydrocolloids include proteins, cellulose derivatives, plant gums (such as alginates and pectins), starches and other polysaccharides.
- Typical lipids include waxes, acylglycerols and fatty acids.
- Composite films contain both lipid and hydrocolloid components.
- a composite film can be formulated as a bilayer in which one layer is a hydrocolloid and the other a lipid, or as a conglomerate in which the lipid and hydrocolloid components are interspersed throughout the film.
- Conglomerate films can be particularly effective as moisture barriers, since the lipid component acts as a hydrophobic barrier while the hydrocolloid component(s) act as a supporting matrix which imparts structural stability to the film and prevents breakdown of the lipid barrier. In the absence of a supporting matrix, lipid layers alone cannot form robust, continuous films or coatings. Thus, the hydrocolloid component(s) help maintain the physical integrity of the barriers during subsequent food processing, storage and/or cooking.
- Hydrocolloid components known to be suitable for use in conglomerate films include carbohydrates and proteins. Suitable film-forming proteins include gelatin, casein, soy protein, whey protein, wheat gluten and zein. Suitable film-forming carbohydrates include starches, plant gums and chemically modifies starches.
- Charged hydrocolloids can be very useful for film formation: alginates and pectins gel on the addition of polyvalent ions (usually calcium) .
- WO 87/03453 describes an edible laminated (layered) film for retarding water transfer among components of a multicomponent food product.
- the film includes a base film having a hydrophilic polymer layer and a base film lipid layer.
- the base film lipid layer has a hydrophobic surface presented away from the hydrophilic polymer layer and an additional lipid layer laminated to the hydrophobic surface of the base film lipid layer.
- GB 2 262 245 describes an edible moisture barrier laminated film suitable for use in various food products.
- the film comprises an edible insoluble fibrous protein and an edible polysaccharide having a coating of an edible hydrophobic material on at least a portion of a surface thereof.
- US 4 293 572 discloses a water in oil emulsion or colloidal dispersion prepared from an emulsified triglyceride or an emulsifier only in combination with an aqueous solution of dextrin or other soluble saccharide or polysaccharide.
- the emulsion, prepared by the addition of heat and agitation, is thereafter applied to the surface of a food product and allowed to set, after which further processing of the food may be effected.
- GB 2 242 815 describes a conglomerate barrier coating comprising a mixture of an edible fat and a milk protein in the form of a membrane.
- the coating preferably comprises a melted dispersion of full cream milk powder and sugar in cocoa butter.
- the barrier may be used, like those of the present invention, in the preparation of a heterogeneous food product containing components of different water activities comprising applying a dispersion of the moisture barrier coating onto one of the food components and then forming the two food components into the heterogeneous food product.
- the amount of coating used is selected to be effective to retard moisture migration from the food component with the higher water activity into the coated food component.
- EP 0 638 488 describes an edible moisture barrier suitable for use with microwaved food products.
- the barrier comprises a carbohydrate sheet support carrying a water-repellent lipid layer. The barrier dissolves and/or melts on heating.
- WO 86/00501 discloses an edible pre-formed film for retarding moisture transfer among components of food having different vapor pressures, comprising a hydrophilic polymer layer and a lipid layer adhered to the hydrophilic polymer layer such that the film has a thickness in the range 0.035 to 0.1 50 mm.
- the exposed surface of the lipid layer is oriented toward the higher vapour pressure component of the food such that when the film is placed between components of a food having different vapour pressures, the film can retard moisture transfer between the food components.
- an edible composite film or coating for use as a moisture barrier in a foodstuff comprising a conglomerate of lipid and hydrocolloid components wherein the lipid component is derived from an dried fat composition.
- dried fat composition is used herein to define fat preparations (often in powder form) which have been produced by solidifying a fat emulsion or suspension, usually in the presence of a carrier. Most dried fat compositions are spray dried emulsions of fat in association with protein and/or carbohydrate carriers. A wide variety of different dried fat compositions are commercially available.
- the dried fat compositions of the invention are used as a lipid source in the edible films. In this capacity, they have been found to exhibit surprising advantages.
- the term fat is intended to encompass oils and processed fats.
- the finely dispersed fat particles present in dried fat compositions very efficiently form emulsions or suspensions when mixed at room temperatures as part of an aqueous system. This permits the production of films in which the lipid component is evenly distributed throughout the film matrix, which leads to improved moisture barrier properties.
- the dried fat composition comprises 50-80% fat (e.g. about 75%); 10-30% carbohydrate (e.g. about
- the fat in the dried fat composition is capable of forming a uniform micro-emulsion or micro-suspension when mixed with high shear at 20-30° C.
- the dried fat compositions of the invention can be used as the basis of effective emulsions or dispersions without the need for heating a mixture of fat and hydrocolloid in the preparation of an initial emulsion.
- the hydrocolloid component preferably comprises (or consists of) a starchy leguminous seed protein.
- starchy leguminous seed protein is a term of art which is used in contradistinction to the non-starch leguminous seeds typical of the Lupi ⁇ ae and Glycinae subfamilies (to which the lupin and soybean species belong).
- the starchy leguminous seed proteins include those derived from representatives of the Viciae and Phaseolae subfamilies (for example, the pea and fababean species).
- the starchy leguminous seed proteins have been found to be particularly useful as hydrocolloid components in the film of the invention, because they exhibit good gel forming properties without imparting excessive viscosity to the emulsion used as an intermediate in the production of the films of the invention (see infra) .
- a particularly preferred starchy leguminous seed protein for use according to the invention is pea protein.
- the proteins for use in the present invention need not be pure preparations, but can be provided as crude isolates or concentrates. In general, the proteins used in the invention are more or less complex heterogeneous mixtures of different protein species. Thus, the pea protein for use in the invention may comprise any of a number of different pea protein fractions.
- the edible film preferably comprises (or consists of) a conglomerate of a lipid component (e.g. derived from an dried fat composition), a protein component, a gelled plant gum, an emuisifier, and optionally a buffering agent and/or plasticiser.
- a lipid component e.g. derived from an dried fat composition
- the invention provides an edible composite film for use as a moisture barrier in a foodstuff, the film comprising a conglomerate of lipid and hydrocolloid components wherein the hydrocolloid component comprises (or consists of) a starchy leguminous seed protein, or lupin protein.
- the starchy leguminous seed protein is a pea protein and the lipid component is derived from an dried fat composition.
- the film may comprises (or consists of) a conglomerate of a lipid component (e.g. derived from an dried fat composition), a protein component, a gelled plant gum, an emulsifier and optionally a buffering agent and/or a plasticiser.
- the invention in a third aspect, relates to an edible composite film for use as a moisture barrier in a foodstuff, the film comprising (or consisting of) a conglomerate of: a lipid component; a protein component; a gelled plant gum; an emulsifier; water; and optionally a buffering agent and/or a plasticiser.
- lipid is intended to encompass neutral lipids of glycerides (esters of glycerol and fatty acids) and waxes (esters of long chain monohydric alcohols and fatty acids).
- Particularly preferred lipids for use in the invention include hydrophobic compounds such as fats, oils, acetylated monoglycerides, polyglycerides, acylglycerols, fatty acids and waxes.
- the lipid component for use in the present invention may comprise soya, palm or coconut (e.g. hydrogenated soya, palm or coconut) fats, butter fat, milk fat, palm kernel oil, sunflower seed oil, rapeseed oil, cocoa butter, lard, fish oil, cottonseed oil, olive oil, groundnut oil and their processed counterparts or derivatives.
- the lipid component is preferably derived from an dried fat composition, while the protein component may comprise a starchy leguminous seed protein (for example, a pea protein).
- the films or coatings of the invention may contain a lipid or lipid source (e.g. an dried fat composition) at: 20-40%; 21-39%; 22- 38%; 23-37%; 24-36%; 25-35%; 26-34%; 27-33%; 28-32%; 29-31%; or about 30%.
- a lipid or lipid source e.g. an dried fat composition
- They may contain protein at: 1-35%; 1- 25%; 1-20%; 1-18%; 1-14%; 1-13%; 1-12%; 1-11%; 2-16%; 3-15%; 4-14%; 5-13%; 6-12%; 5-11%; 6-10%; 7-9% or about
- 8% may contain gelled plant gum at: 0.1-5.%; 0.1-3.2%; 0.1-3.0%; 0.1-2.8%; 0.1-2.6%; 0.1-2.4%; 0.1-2.2%; 0.1- 2.0%; 0.1-1.9%; 0.1-1.8%; 0.1-1.7%; 0.1-1.6%; 0.1-1.5%; 0.2-1.4%; 0.3-1.3%; 0.4-1.2%; 0.5-1.1%; 0.5-1.0%; 0.5- 0.9%; 0.5-0.8%; 0.6-0.7%; or about 0.65%.
- plasticiser at: 0-14%; 1-13%; 2-12%; 3-11%; 4-10%; 5-9%; 6- 8%; or about 7%.
- emulsifier at: 0.1-2.0%; 0.1-1.9%; 0.1-1.8%; 0.1-1.7%; 0.1-1.6%; 0.1-1.5%; 0.1- 1.4%; 0.1-1.2%; 0.1-1.1%; 0.1-1.0%; 0.2-0.9%; 0.3-0.8%; 0.4-0.7%; 0.5-0.6%; or about 0.55%.
- buffering agent at: 0.1-2.0%; 0.1-1.9%; 0.1-1.8%; 0.1-1.7%; 0.1-1.6%; 0.1-1.5%; 0.1-1.4%; 0.1-1.2%; 0.1-1.1%; 0.1- 1.0%; 0.2-0.9%; 0.3-0.8%; 0.4-0.7%; 0.5-0.6%; or about 0.55%. All percentages are expressed as w/w with respect to the total weight of the ungelled film emulsion or the wet film immediately after gelling or setting.
- the dried fat composition for use in the invention is preferably spray dried.
- the film of the invention preferably comprises a hydrocolloid component which acts as a supporting matrix for the lipid component.
- the hydrocolloid component preferably comprises a protein, such as a film-forming and/or emulsifying protein. It may also comprise a charged hydrocolloid component and/or a gelled plant gum. In preferred embodiments, the hydrocolloid component comprises a mixture of film-forming protein and a gelled plant gum (such as alginate or pectin).
- the protein is selected from any one of: gelatin; casein; soy protein; whey protein; wheat gluten; zein; albumen; starchy leguminous seed protein; mixtures of any of the foregoing proteins.
- pea protein for example a pea protein isolate or concentrate.
- the hydrocolloid component preferably comprises: alginate; pectin; carrageenan; cellulose; agar; seaweed extract; mixtures of any of the foregoing.
- the gelled plant gum is a low viscosity alginate (e.g. sodium alginate).
- a low viscosity alginate e.g. sodium alginate
- Such alginates are easily selected from a wide range of commercially available alginates having different properties.
- Low viscosity alginates are particularly useful as hydrocolloid components in the film of the invention because they may retain good elastic properties without imparting excessive viscosity to the emulsion used as an intermediate in the production of the films of the invention (see infra). This significantly improves the handling characteristics of the emulsion, facilitating its application to various foods. They are particularly advantageous when the emulsion is to be applied to a food product by spraying.
- the alginate may advantageously be a highly elastic, medium gel strength alginate. Such alginates are particularly advantageous in conjunction with foods which are subject to physical stress during cooking or preparation, such as microwaveable pies.
- the gum may be gelled with a mono-, di- or polyvalent cation, preferably with a calcium ion.
- the gelling cations for use in the invention may be encapsulated to achieve delayed release of the gelling agents and so prevent premature setting of the emulsion during processing.
- the calcium ion is derived from calcium lactate, calcium chloride, calcium carbonate, calcium hydroxide, calcium citrate, calcium ascorbate and hydrated salts thereof.
- the film of the invention may further comprise a plasticiser, such as a polyol (e.g. glycerol); and/or sorbitol; and/or ethanolamine; and/or tocopherol; and/or an acetylated monoglyceride; and/or polyethylene glycol; and/or sucrose; and/or phospholipid (eg lecithin).
- a plasticiser such as a polyol (e.g. glycerol); and/or sorbitol; and/or ethanolamine; and/or tocopherol; and/or an acetylated monoglyceride; and/or polyethylene glycol; and/or sucrose; and/or phospholipid (eg lecithin).
- Preferred plasticisers such as lecithin also act as emulsifiers.
- the film may also comprise an emulsifier, for example lecithin (e.g. soya lecithin); and/or beeswax; and/or glycerol monostearate; and/or isopropyl palmitate; and/or lauric acid; and/or lauryl alcohol; and/or sodium oleate; and/or potassium oleate; and/or sorbitan monostearate; and/or stearyl alcohol; and/or triethanolamine oleate soap; and/or acetylated monoglycerides; and/or oleic acid; and/or palm oil; and/or fatty acids; and/or glycol monostearates; and/or polyol monostearates.
- lecithin e.g. soya lecithin
- beeswax e.g. soya lecithin
- glycerol monostearate e.g. soya lecithin
- the film may also comprise a buffering agent (e.g. an acidity regulator).
- a buffering agent e.g. an acidity regulator
- Any of a wide variety of food acceptable buffering agents may be used, and in preferred embodiments the buffering agent is sodium polyphosphate.
- the film of the invention may further comprise various minor ingredients which provide incidental functions.
- the films may include an antimicrobial agent, one or more vitamins, an antioxidant, a flavour, a pigment or mixtures thereof.
- the invention also contemplates a dry mix (e.g. in the form of a powder) for use as a hydratable base in the preparation of the film of any one of the preceding claims, the mix comprising lipid and hydrocolloid sources, wherein: the lipid source comprises (or consists of) an dried fat composition; and/or the hydrocolloid source comprises (or consists of) a starchy leguminous seed protein; and/or the mix comprises (or consists of): (i) a lipid source (e.g. an dried fat composition); and (ii) a protein component (e.g. a starchy leguminous seed protein); and (iii) a gellable plant gum; and (iv) an emulsifier.
- a dry mix e.g. in the form of a
- the dry mix of the invention further comprises a buffering agent; and/or a plasticiser; and/or a gelling salt.
- the gelling salt is preferably a source of mono-, di- or polyvalent ions.
- the gelling salt is a calcium salt, for example a sparingly soluble calcium salt (e.g. calcium lactate, calcium carbonate or calcium hydroxide, calcium chloride and/or an encapsulated gelling agent) which gels the plant gum after a time delay (e.g. of 30 to 1 200 seconds) following hydration of the mix.
- a time delay e.g. of 30 to 1 200 seconds
- the dry mix comprises a lipid source present at: 40-80%; 42-78%; 44-76%; (iv) 46-74%; 48-72%; 50-70%; 52-68%; 54-66%; 56-64%; 58-62%; or about 60%. All percentages are expressed as w/w with respect to the total weight of the dry mix.
- the mix comprises a gellable plant gum, for example at: 0.2-10.0%; 0.2-6.4%; 0.2-6.0%; 0.2-5.6%; 0.2-5.2%; 0.2- 4.8%; 0.2-4.4%; 0.2-4.0%; 0.2-3.8%; 0.2-3.6%; 0.2-3.4%; 0.2-3.2%; 0.2-3.0%; 0.4-2.8%; 0.6-2.6%; 0.8-2.4%; 1 .0- 2.2%; 1.0-2.0%; 1.0-1 .8%; 1.0-1.6%; 1.2-1.4%; about 1.3%. All percentages are expressed as w/w with respect to the total weight of the dry mix.
- the mix may also comprise an emulsifier, for example present at: 0.2-4.0%; 0.2-3.8%; 0.2-3.6%; 0.2-3.4%; 0.2-3.2%; 0.2- 3.0%; 0.2-2.8%; 0.2-2.4%; 0.2-2.2%; 0.2-2.0%; 0.4-1 .8%;
- the dry mix also comprises a buffering agent, e.g. present at: 0.2-4.0%; 0.2-3.8%; 0.2-3.6%; 0.2-3.4%; 0.2- 3.2%; 0.2-3.0%; 0.2-2.8%; 0.2-2.4%; 0.2-2.2%; 0.2-2.0%; 0.4-1.8%; 0.6-1.6%; 0.8-1.4%; 1.0-1.2%; about 1 %. All percentages are expressed as w/w with respect to the total weight of the dry mix.
- a buffering agent e.g. present at: 0.2-4.0%; 0.2-3.8%; 0.2-3.6%; 0.2-3.4%; 0.2- 3.2%; 0.2-3.0%; 0.2-2.8%; 0.2-2.4%; 0.2-2.2%; 0.2-2.0%; 0.4-1.8%; 0.6-1.6%; 0.8-1.4%; 1.0-1.2%; about 1 %. All percentages are expressed as w/w with respect to the total weight of the dry mix.
- the hydrocolloid source for use in the dry mix of the invention may be a gellable plant gum or charged hydrocolloid source, for example a hydrocolloid source which gels to form a hydrocolloid component as hereinbefore defined.
- the emulsifier may be as hereinbefore defined.
- the mix may further comprise a buffering agent, for example as hereinbefore defined.
- the mix further comprises an antimicrobial agent, one or more vitamins, an antioxidant, a flavour, a pigment or mixtures thereof.
- the invention also contemplates a moisture barrier system (e.g. a kit for preparing a moisture barrier for use in a foodstuff) comprising, as separate components: the dry mix of the invention as hereinbefore defined and a gelling salt solution.
- a moisture barrier system e.g. a kit for preparing a moisture barrier for use in a foodstuff
- a gelling salt solution comprising, as separate components: the dry mix of the invention as hereinbefore defined and a gelling salt solution.
- the moisture barrier system may optionally further comprise a liquid plasticiser (e.g. a polyol, such as glycerol, or any of the other plasticisers as hereinbefore defined.
- a liquid plasticiser e.g. a polyol, such as glycerol, or any of the other plasticisers as hereinbefore defined.
- the film may is produced by first preparing a dry mix of lipid and hydrocolloid components and then adding water and glycerol to produce an emulsion. The emulsion may then be set or gelled by the addition of gelling salt (or by the slow release of sparingly soluble gelling salt-derived ions solubilized from the dry mix after the addition of water).
- the gelling salt solution is preferably a calcium salt solution, for example a gelling salt solution at 1 -10% w/v.
- the gelling salt solution preferably contains mono-, di- or polyvalent cations (for example a calcium salt). Particularly preferred is a solution of calcium chloride (e.g. at about 5% w/v).
- the invention provides an emulsion or suspension (e.g. a microemulsion or microsuspension) comprising the dry mix of the invention in admixture with water (for example at about 50-60% w/w).
- emulsions/suspensions the gellable plant gum is preferably in an ungelled state.
- the emulsion of the invention may be formulated such that no gelling salt is present.
- Such emulsions may have a low viscosity, making them convenient to handle and easy to apply to a foodstuff. They can be set or gelled into stable films or coatings by contacting them with a gelling salt, conveniently in a separate processing step. The gellable plant gum present in the emulsion/suspension will then set or gel to provide a robust matrix which supports the lipid component, so forming a stable moisture barrier in situ.
- the invention also contemplates a foodstuff comprising the film or emulsion of the invention.
- Preferred foodstuffs include baked foodstuffs, cold eating pies (for example apple pie), hot eating pie (for example meat pie, e.g. pork pie), savoury pie, pizza, turnover, cake, quiche, topped doughnut, filled pastries and ice creams in cones.
- cold eating pies for example apple pie
- hot eating pie for example meat pie, e.g. pork pie
- savoury pie for example pizza, turnover, cake, quiche, topped doughnut, filled pastries and ice creams in cones.
- the invention also embraces a process for producing the edible composite film of the invention comprising the steps of preparing a dry mix as hereinbefore defined and then hydrating the dry mix to produce an emulsion (or suspension) as hereinbefore defined.
- the process may be a two stage process, further comprising the step of gelling the emulsion to produce the film.
- the dry mix is preferably hydrated by high shear mixing with water.
- the emulsion for use in the process of the invention preferably comprises ungelled plant gum.
- the dry mix preferably comprises a gelling salt and the plant gum may then be gelled when the gelling salt is dissolved on hydration of the dry mix.
- complete gelling may be achieved between 30 and 1 200 seconds after mixing. This facilitates handling of the emulsion prior to (and during) application to the foodstuff, while obviating the need for a separate gelling step (e.g. involving the addition of gelling salt) in situ.
- the dry mix does not include a gelling salt and the plant gum is gelled by adding a gelling salt solution to the emulsion.
- the gelling salt solution is preferably sprayed onto the emulsion.
- the emulsion may be cast to yield a shaped self-supporting film.
- the emulsion may be cast, cut or formed into various shapes (e.g. a disc shape) .
- Such films find particular application in the production of pie bases, ice cream cones, pastry bases or pizza crusts.
- Also contemplated by the invention is a process for preparing a foodstuff comprising the steps of producing an edible composite film by the process as defined above and then applying the film to the foodstuff.
- the invention contemplates a process for preparing a foodstuff comprising the steps of producing an emulsion comprising ungelled plant gum as defined above, applying the emulsion to the foodstuff and then gelling the plant gum in the emulsion to produce an edible composite film which acts as a moisture barrier in the foodstuff.
- the plant gum may be gelled by cations present in the emulsion or by contacting the emulsion with a gelling salt in situ.
- the emulsion/suspension of the invention may be applied to the foodstuff by any convenient method, for example by spraying, brushing, ladling, dipping, casting, pouring, spreading, panning, enrobing or rolling.
- the invention also contemplates a method for preventing the transfer of moisture between constituents of a multi-component food product comprising the step of interposing the film of the invention between the food constituents.
- the film may be interposed between the food constituents by providing a first food constituent, applying the film to the first constituent and then providing a second food constituent to produce a multi-component food product in which the film is interposed between the first and second constituent.
- the film may be wrapped about a foodstuff or applied thereon as a coating to prevent moisture transfer between the foodstuff and the atmosphere.
- the film is preferably interposed between the food constituents by the steps of: providing a first food constituent; applying an emulsion or suspension as hereinbefore defined to the first constituent; gelling the emulsion to produce a film as hereinbefore defined; and then providing a second food constituent to produce a multi-component food product in which the film is interposed between the first and second constituents.
- SatroTM fat is a spray dried fat composition of hardened vegetable fat containing 72.5% fat, 10.0% protein and 13.7% carbohydrates. Satro FP72TM was used.
- This dry mix was then mixed with glycerol and water at ambient temperature (about 22°C) using a SilversonTM mixer to form a stable, homogeneous emulsion.
- the emulsion was then brushed onto an apple pie base.
- the emulsion was set in situ by spraying a small quantity of 5% CaCI 2 in water onto the emulsion on the pie base. After air drying for five minutes, apple filling was added and the pie baked.
- the viscosity of the emulsion was 7800 centipoise.
- a film was prepared as described in Example 1 , except that whey protein was used instead of the soya protein.
- the viscosity of the emulsion was 6000 centipoise.
- the WVT (g/s.m.m) was 0.0010. The film was robust and effectively prevented migration of moisture in the apple filling into the pie crust.
- a film was prepared as described in Example 1 , except that albumen was used instead of the soya protein.
- the viscosity of the emulsion was 6600 centipoise.
- the WVT (g/s.m.m) was 0.0005.
- the film was robust and effectively prevented migration of moisture in the apple filling into the pie crust.
- a film was prepared as described in Example 1 , except that pea was used instead of the soya protein.
- the viscosity of the emulsion was 5000 centipoise, and the emulsion was applied to the pie crust by spraying.
- the WVT (g/s.m.m) was 0.0003. The film was robust and effectively prevented migration of moisture in the apple filling into the pie crust.
- a film was prepared as described in Example 1 , except that gluten was used instead of the soya protein.
- the viscosity of the emulsion was 1300 centipoise, and the emulsion was applied to the pie crust by spraying.
- the WVT (g/s.m.m) was 0.0006. The film was robust and effectively prevented migration of moisture in the apple filling into the pie crust.
- a film was prepared as described in Example 1 , except that pectin was used instead of the alginate. The performance was similar, except that the film was somewhat less robust.
- a film was prepared as described in Example 1 , except that De Kievit Grasa 60A1 1 8TM was used instead of the SatroTM.
- This fat is a spray dried suspension of hydrogenated soya at 60%, carbohydrate at 30% and protein at 5% .
- the viscosity of the emulsion was 8800 centipoise, and the emulsion was applied to the pie crust by brushing.
- the WVT g/s.m.m
- the film was robust and effectively prevented migration of moisture in the apple filling into the pie crust.
- a film was prepared as described in Example 1 , except that De Kievit Crema 72DTM was used instead of the SatroTM.
- This fat is a spray dried suspension of hydrogenated soya at 72%, carbohydrate at 1 5% and protein at 9%.
- the viscosity of the emulsion was 1 8600 centipoise, and the emulsion was applied to the pie crust by brushing.
- the WVT g/s.m.m
- the film was robust and effectively prevented migration of moisture in the apple filling into the pie crust.
- a film was prepared as described in Example 1 , except that De
- This fat is a spray dried suspension of coconut oil at 50%, carbohydrate at 26% and protein at 1 8% .
- the viscosity of the emulsion was 9200 centipoise, and the emulsion was applied to the pie crust by brushing.
- the WVT g/s.m.m
- the film was robust and effectively prevented migration of moisture in the apple filling into the pie crust.
- a film was prepared as described in Example 1 , except that De Kievit Lata 70HTM was used instead of the SatroTM.
- This fat is a spray dried suspension of hydrogenated coconut oil at 70%, carbohydrate at 15% and protein at 10%.
- the viscosity of the emulsion was 58000 centipoise, and the emulsion was applied to the pie crust by brushing.
- the WVT g/s.m.m was 0.0050.
- the film was robust and effectively reduced migration of moisture in the apple filling into the pie crust.
- the emulsion was prepared by first dry mixing the lecithin, tetron, alginate, fat and gluten protein to form a uniform, free flowing dry mix.
- This dry mix was then mixed with glycerol and water at ambient temperature (about 22°C) using a SilversonTM mixer to form a stable, homogeneous emulsion.
- the emulsion was then brushed onto an apple pie base.
- the emulsion was set in situ by spraying a small quantity of 5% CaCI 2 in water onto the emulsion on the pie base. After air drying for five minutes, apple filling was added and the pie baked.
- a film was prepared as described in Example 1 2, except that pea was used instead of the gluten protein.
- the viscosity, WVT (g/s.m.m) and film characteristics were similar to that described for Example 5.
- Example 14 An emulsion was made to the following recipe:
- a film was prepared as described in Example 1 .
- the viscosity, WVT (g/s.m.m) and film characteristics were similar to that described for Example 1 .
- a film was prepared as described in Example 14 except that the emulsion was set by mixing with a solution of 50% CaSO and 0.25% xanthan gum.
Landscapes
- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Food Science & Technology (AREA)
- Polymers & Plastics (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- General Preparation And Processing Of Foods (AREA)
- Medicinal Preparation (AREA)
Abstract
Description
Claims
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
AU67380/98A AU6738098A (en) | 1997-03-26 | 1998-03-20 | Edible films and coatings |
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
GBGB9706300.2A GB9706300D0 (en) | 1997-03-26 | 1997-03-26 | Edible films and coatings |
GB9706300.2 | 1997-03-26 |
Publications (2)
Publication Number | Publication Date |
---|---|
WO1998042214A2 true WO1998042214A2 (en) | 1998-10-01 |
WO1998042214A3 WO1998042214A3 (en) | 1999-01-14 |
Family
ID=10809915
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
PCT/GB1998/000846 WO1998042214A2 (en) | 1997-03-26 | 1998-03-20 | Edible lipid-proteins films and coatings |
Country Status (3)
Country | Link |
---|---|
AU (1) | AU6738098A (en) |
GB (1) | GB9706300D0 (en) |
WO (1) | WO1998042214A2 (en) |
Cited By (20)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP1080643A1 (en) * | 1999-08-31 | 2001-03-07 | Unilever Plc | Blends for barrier layers for food products |
US6461654B1 (en) | 1999-08-31 | 2002-10-08 | Unilever Patent Holdings Bv | Blends for barrier layers for food products |
EP1472934A1 (en) * | 2003-04-01 | 2004-11-03 | Kraft Foods Holdings, Inc. | Edible moisture barrier for food products |
EP1683734A1 (en) | 2005-01-20 | 2006-07-26 | Kraft Foods Holdings, Inc. | Food modifier transferable article |
EP1698239A1 (en) * | 2003-12-19 | 2006-09-06 | Fuji Oil Company, Limited | Acidic protein food or drink and material thereof |
WO2006132909A1 (en) * | 2005-06-06 | 2006-12-14 | Solae, Llc | Edible moisture barrier compositions and methods for preparation thereof |
WO2009064436A1 (en) * | 2007-11-13 | 2009-05-22 | Bunge Oils, Inc. | Protein-containing food product and coating for a food product and method of making same |
WO2011123949A1 (en) | 2010-04-09 | 2011-10-13 | Fruitsymbiose Inc. | Edible coating composition and uses thereof |
WO2012015303A1 (en) * | 2010-07-28 | 2012-02-02 | Unifine Food & Bake Ingredients B.V. | Glazing agent for baked goods |
US8323721B2 (en) | 2005-12-22 | 2012-12-04 | Bunge Oils, Inc. | Phytosterol esterification product and method of making same |
WO2013083392A1 (en) * | 2011-12-09 | 2013-06-13 | Unilever N.V. | Edible coating composition |
EP2866580A1 (en) * | 2012-06-29 | 2015-05-06 | Nestec S.A. | Heat resistant moisture barrier for foods |
EP2873330A1 (en) * | 2007-05-16 | 2015-05-20 | Kraft Foods R & D, Inc. | Edible composition as moisture barrier and moisture resistant structure |
EP3092903A4 (en) * | 2014-01-07 | 2017-09-06 | Production and Innovation on Edible Coatings S.L. | Edible coating for preserving pieces of fruit, production method and application thereof |
US9808017B2 (en) | 2011-02-25 | 2017-11-07 | Kraft Foods R&D, Inc. | Food product with a moulded body |
CN109401339A (en) * | 2018-11-02 | 2019-03-01 | 南京财经大学 | A kind of preparation and application of the acylated rapeseed protein film of edibility |
CN109924241A (en) * | 2017-12-19 | 2019-06-25 | 丰益(上海)生物技术研发中心有限公司 | Coating liquid composition, Its Preparation Method And Use |
US10829621B2 (en) | 2013-01-11 | 2020-11-10 | Monosol, Llc | Edible water-soluble film |
CN116158462A (en) * | 2022-12-24 | 2023-05-26 | 青岛农业大学 | Nut dampproof film coating liquid and preparation method and application thereof |
US11912856B2 (en) | 2021-06-23 | 2024-02-27 | Loliware, Inc. | Bio-based, biodegradable compositions and articles made therefrom |
Citations (13)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3323922A (en) * | 1965-08-09 | 1967-06-06 | Pillsbury Co | Protective coatings |
EP0048123A1 (en) * | 1980-09-12 | 1982-03-24 | Merck & Co. Inc. | Gelled algin emulsions |
WO1986005363A1 (en) * | 1985-03-12 | 1986-09-25 | Christian Best | Coloured food composition mainly used for decorative purposes |
FR2590122A1 (en) * | 1985-11-15 | 1987-05-22 | Gel Dor | PULVERULENT FOOD COMPOSITION BASED ON FAT AND GELLING AGENTS, COATING PRODUCTS AND BAKED SUCCEDANES RESULTING FROM COOKING AQUEOUS EMULSIONS CONTAINING THE SAME |
US4762721A (en) * | 1985-05-07 | 1988-08-09 | Thomas J. Lipton, Inc. | Oil-in-water emulsion glazing agent for foodstuffs |
US5019403A (en) * | 1989-12-13 | 1991-05-28 | The United States Of America As Represented By The Secretary Of Agriculture | Coatings for substrates including high moisture edible substrates |
EP0465801A1 (en) * | 1990-07-10 | 1992-01-15 | Societe Des Produits Nestle S.A. | Coating composition |
EP0471558A2 (en) * | 1990-08-14 | 1992-02-19 | Unilever Plc | Moisture barrier and its preparation |
EP0486076A1 (en) * | 1990-10-18 | 1992-05-20 | Vink, née Pinckaers, Maria Agnes Antonia | Material for covering or coating food products and method for the production thereof |
EP0547551A1 (en) * | 1991-12-16 | 1993-06-23 | National Starch and Chemical Investment Holding Corporation | Edible films |
EP0594258A1 (en) * | 1992-10-20 | 1994-04-27 | Friesland (Frico Domo) Coöperatie B.A. | Edible emulsion for coating foodstuffs |
EP0643916A2 (en) * | 1993-08-31 | 1995-03-22 | Unilever N.V. | Choux-mixes |
US5543164A (en) * | 1994-06-17 | 1996-08-06 | The Regents Of The University Of California | Water-insoluble protein-based edible barrier coatings and films |
-
1997
- 1997-03-26 GB GBGB9706300.2A patent/GB9706300D0/en active Pending
-
1998
- 1998-03-20 WO PCT/GB1998/000846 patent/WO1998042214A2/en active Application Filing
- 1998-03-20 AU AU67380/98A patent/AU6738098A/en not_active Abandoned
Patent Citations (13)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3323922A (en) * | 1965-08-09 | 1967-06-06 | Pillsbury Co | Protective coatings |
EP0048123A1 (en) * | 1980-09-12 | 1982-03-24 | Merck & Co. Inc. | Gelled algin emulsions |
WO1986005363A1 (en) * | 1985-03-12 | 1986-09-25 | Christian Best | Coloured food composition mainly used for decorative purposes |
US4762721A (en) * | 1985-05-07 | 1988-08-09 | Thomas J. Lipton, Inc. | Oil-in-water emulsion glazing agent for foodstuffs |
FR2590122A1 (en) * | 1985-11-15 | 1987-05-22 | Gel Dor | PULVERULENT FOOD COMPOSITION BASED ON FAT AND GELLING AGENTS, COATING PRODUCTS AND BAKED SUCCEDANES RESULTING FROM COOKING AQUEOUS EMULSIONS CONTAINING THE SAME |
US5019403A (en) * | 1989-12-13 | 1991-05-28 | The United States Of America As Represented By The Secretary Of Agriculture | Coatings for substrates including high moisture edible substrates |
EP0465801A1 (en) * | 1990-07-10 | 1992-01-15 | Societe Des Produits Nestle S.A. | Coating composition |
EP0471558A2 (en) * | 1990-08-14 | 1992-02-19 | Unilever Plc | Moisture barrier and its preparation |
EP0486076A1 (en) * | 1990-10-18 | 1992-05-20 | Vink, née Pinckaers, Maria Agnes Antonia | Material for covering or coating food products and method for the production thereof |
EP0547551A1 (en) * | 1991-12-16 | 1993-06-23 | National Starch and Chemical Investment Holding Corporation | Edible films |
EP0594258A1 (en) * | 1992-10-20 | 1994-04-27 | Friesland (Frico Domo) Coöperatie B.A. | Edible emulsion for coating foodstuffs |
EP0643916A2 (en) * | 1993-08-31 | 1995-03-22 | Unilever N.V. | Choux-mixes |
US5543164A (en) * | 1994-06-17 | 1996-08-06 | The Regents Of The University Of California | Water-insoluble protein-based edible barrier coatings and films |
Cited By (31)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP1080643A1 (en) * | 1999-08-31 | 2001-03-07 | Unilever Plc | Blends for barrier layers for food products |
US6461654B1 (en) | 1999-08-31 | 2002-10-08 | Unilever Patent Holdings Bv | Blends for barrier layers for food products |
EP1472934A1 (en) * | 2003-04-01 | 2004-11-03 | Kraft Foods Holdings, Inc. | Edible moisture barrier for food products |
JP4613825B2 (en) * | 2003-12-19 | 2011-01-19 | 不二製油株式会社 | Acidic protein food and drink and its materials |
EP1698239A1 (en) * | 2003-12-19 | 2006-09-06 | Fuji Oil Company, Limited | Acidic protein food or drink and material thereof |
JPWO2005058071A1 (en) * | 2003-12-19 | 2007-07-12 | 不二製油株式会社 | Acidic protein food and drink and its materials |
EP1698239A4 (en) * | 2003-12-19 | 2008-05-21 | Fuji Oil Co Ltd | Acidic protein food or drink and material thereof |
US8367145B2 (en) | 2003-12-19 | 2013-02-05 | Fuji Oil Company, Limited | Acidic protein food or drink and material thereof |
EP1683734A1 (en) | 2005-01-20 | 2006-07-26 | Kraft Foods Holdings, Inc. | Food modifier transferable article |
WO2006132909A1 (en) * | 2005-06-06 | 2006-12-14 | Solae, Llc | Edible moisture barrier compositions and methods for preparation thereof |
US8323721B2 (en) | 2005-12-22 | 2012-12-04 | Bunge Oils, Inc. | Phytosterol esterification product and method of making same |
EP2873330A1 (en) * | 2007-05-16 | 2015-05-20 | Kraft Foods R & D, Inc. | Edible composition as moisture barrier and moisture resistant structure |
WO2009064436A1 (en) * | 2007-11-13 | 2009-05-22 | Bunge Oils, Inc. | Protein-containing food product and coating for a food product and method of making same |
EP2555640A1 (en) * | 2010-04-09 | 2013-02-13 | Fruitsymbiose Inc. | Edible coating composition and uses thereof |
EP2555640A4 (en) * | 2010-04-09 | 2014-04-02 | Fruitsymbiose Inc | Edible coating composition and uses thereof |
WO2011123949A1 (en) | 2010-04-09 | 2011-10-13 | Fruitsymbiose Inc. | Edible coating composition and uses thereof |
WO2012015303A1 (en) * | 2010-07-28 | 2012-02-02 | Unifine Food & Bake Ingredients B.V. | Glazing agent for baked goods |
US9138007B2 (en) | 2010-07-28 | 2015-09-22 | Dawn Foods, Inc. | Glazing agent for baked goods |
US9808017B2 (en) | 2011-02-25 | 2017-11-07 | Kraft Foods R&D, Inc. | Food product with a moulded body |
WO2013083392A1 (en) * | 2011-12-09 | 2013-06-13 | Unilever N.V. | Edible coating composition |
CN104010520A (en) * | 2011-12-09 | 2014-08-27 | 荷兰联合利华有限公司 | Edible coating composition |
EA028455B1 (en) * | 2011-12-09 | 2017-11-30 | Юнилевер Н.В. | Edible coating composition and coated food product |
EP2866580A1 (en) * | 2012-06-29 | 2015-05-06 | Nestec S.A. | Heat resistant moisture barrier for foods |
RU2635447C2 (en) * | 2012-06-29 | 2017-11-13 | Нестек С.А. | Heating-resistant moisture-holding barrier for food products |
US10829621B2 (en) | 2013-01-11 | 2020-11-10 | Monosol, Llc | Edible water-soluble film |
US11945936B2 (en) | 2013-01-11 | 2024-04-02 | Monosol, Llc | Edible water-soluble film |
EP3092903A4 (en) * | 2014-01-07 | 2017-09-06 | Production and Innovation on Edible Coatings S.L. | Edible coating for preserving pieces of fruit, production method and application thereof |
CN109924241A (en) * | 2017-12-19 | 2019-06-25 | 丰益(上海)生物技术研发中心有限公司 | Coating liquid composition, Its Preparation Method And Use |
CN109401339A (en) * | 2018-11-02 | 2019-03-01 | 南京财经大学 | A kind of preparation and application of the acylated rapeseed protein film of edibility |
US11912856B2 (en) | 2021-06-23 | 2024-02-27 | Loliware, Inc. | Bio-based, biodegradable compositions and articles made therefrom |
CN116158462A (en) * | 2022-12-24 | 2023-05-26 | 青岛农业大学 | Nut dampproof film coating liquid and preparation method and application thereof |
Also Published As
Publication number | Publication date |
---|---|
GB9706300D0 (en) | 1997-05-14 |
WO1998042214A3 (en) | 1999-01-14 |
AU6738098A (en) | 1998-10-20 |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
WO1998042214A2 (en) | Edible lipid-proteins films and coatings | |
EP1586242B1 (en) | Multilayer edible moisture barrier for food products | |
US4762721A (en) | Oil-in-water emulsion glazing agent for foodstuffs | |
CA2370410C (en) | Shelf-stable, bakeable savory cheese product and process for preparing it | |
RU2344617C2 (en) | Bakeable, smudging, sweet, cream fillers with decreased humidity and the method of cooking | |
CA2044428C (en) | Coating composition | |
JPH0626502B2 (en) | Food | |
MXPA05000734A (en) | Scrambled egg snack food. | |
EP1247460A2 (en) | Oven-stable edible moisture barrier | |
JP4211217B2 (en) | Edible oil and fat substitute | |
US3946120A (en) | High protein bread substitute and method for preparing same | |
JP4519092B2 (en) | Fried bakery, method for producing the same, and dough for producing the fried bakery | |
WO2006002734A1 (en) | Moisture barrier | |
US20210244041A1 (en) | Baking Ingredients Suitable for Fat Replacement | |
WO2003024253A1 (en) | Moisture-barrier edible coating layer for foods | |
MX2007015223A (en) | Edible moisture barrier compositions and methods for preparation thereof. | |
NZ336290A (en) | Method for coating cheese with a hydrophobic layer and a hydrophilic layer and resulting coated cheese | |
JP3468008B2 (en) | Fried bakery products and method for producing the same | |
JP2017012093A (en) | Chilled pan and manufacturing method therefor | |
JPS6137897B2 (en) | ||
JPH0369489B2 (en) | ||
JPS6153003B2 (en) | ||
EP2866580A1 (en) | Heat resistant moisture barrier for foods | |
JPS61265048A (en) | Confectionery having multilayer structure | |
WO2004008868A1 (en) | Shelf-stable, bakeable savory cheese product and process for preparing it |
Legal Events
Date | Code | Title | Description |
---|---|---|---|
AK | Designated states |
Kind code of ref document: A2 Designated state(s): AL AM AT AU AZ BA BB BG BR BY CA CH CN CU CZ DE DK EE ES FI GB GE GH GM GW HU ID IL IS JP KE KG KP KR KZ LC LK LR LS LT LU LV MD MG MK MN MW MX NO NZ PL PT RO RU SD SE SG SI SK SL TJ TM TR TT UA UG US UZ VN YU ZW |
|
AL | Designated countries for regional patents |
Kind code of ref document: A2 Designated state(s): GH GM KE LS MW SD SZ UG ZW AM AZ BY KG KZ MD RU TJ TM AT BE CH DE DK ES FI FR GB GR IE IT LU MC NL PT SE BF BJ CF CG CI CM GA GN ML MR NE SN TD TG |
|
DFPE | Request for preliminary examination filed prior to expiration of 19th month from priority date (pct application filed before 20040101) | ||
AK | Designated states |
Kind code of ref document: A3 Designated state(s): AL AM AT AU AZ BA BB BG BR BY CA CH CN CU CZ DE DK EE ES FI GB GE GH GM GW HU ID IL IS JP KE KG KP KR KZ LC LK LR LS LT LU LV MD MG MK MN MW MX NO NZ PL PT RO RU SD SE SG SI SK SL TJ TM TR TT UA UG US UZ VN YU ZW |
|
AL | Designated countries for regional patents |
Kind code of ref document: A3 Designated state(s): GH GM KE LS MW SD SZ UG ZW AM AZ BY KG KZ MD RU TJ TM AT BE CH DE DK ES FI FR GB GR IE IT LU MC NL PT SE BF BJ CF CG CI CM GA GN ML MR NE SN TD TG |
|
121 | Ep: the epo has been informed by wipo that ep was designated in this application | ||
REG | Reference to national code |
Ref country code: DE Ref legal event code: 8642 |
|
NENP | Non-entry into the national phase in: |
Ref country code: JP Ref document number: 1998545217 Format of ref document f/p: F |
|
122 | Ep: pct application non-entry in european phase |