WO1998039388A1 - Naphtalenedicarboxylate contenant un melange de polyamide/polyester a propriete de retention de saveur amelioree - Google Patents

Naphtalenedicarboxylate contenant un melange de polyamide/polyester a propriete de retention de saveur amelioree Download PDF

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Publication number
WO1998039388A1
WO1998039388A1 PCT/US1998/004311 US9804311W WO9839388A1 WO 1998039388 A1 WO1998039388 A1 WO 1998039388A1 US 9804311 W US9804311 W US 9804311W WO 9839388 A1 WO9839388 A1 WO 9839388A1
Authority
WO
WIPO (PCT)
Prior art keywords
acid
polyamide
molecular weight
nylon
diol
Prior art date
Application number
PCT/US1998/004311
Other languages
English (en)
Inventor
Timothy Edward Long
Steven Lee Stafford
Emily Tedrow Bell
Original Assignee
Eastman Chemical Company
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Eastman Chemical Company filed Critical Eastman Chemical Company
Priority to BR9808301-5A priority Critical patent/BR9808301A/pt
Priority to JP53880698A priority patent/JP2001514681A/ja
Priority to EP98908969A priority patent/EP0964893A1/fr
Publication of WO1998039388A1 publication Critical patent/WO1998039388A1/fr

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L67/00—Compositions of polyesters obtained by reactions forming a carboxylic ester link in the main chain; Compositions of derivatives of such polymers
    • C08L67/02—Polyesters derived from dicarboxylic acids and dihydroxy compounds

Definitions

  • acetaldehyde acetaldehyde
  • AA acetaldehyde
  • the container market for carbonated and still mineral water requires exceptionally low levels of acetaldehyde (AA) in the container side wall in order to avoid the diffusion of the AA into the water leading to an undesirable water taste.
  • AA is an inherent side product which is generated during the polymerization melt phase and subsequent processing steps.
  • variables such as catalyst selection influence the amount of residual AA.
  • this level of AA is still perceived to be too high for some applications.
  • taste testing has indicated that humans can taste 20 ppb differences in AA. Consequently, there has been significant interest in reducing the residual AA content as low as possible.
  • the present invention involves naphthalenedicarboxylate polyester/polyamide blends having surprisingly low AA.
  • the present invention further discloses naphthalenedicarboxylate containing polyester/polyamide blends which are formed by mixing a polyester base resin with a concentrate containing the polyamide.
  • polyester (A), of the present invention is selected from polyethylene naphthalenedicarboxylate (PEN) or copolyesters thereof.
  • the acid component of polyester (A) contains repeat units from at least about 50 mole percent naphthlenedicarboxylic acid and at least about 50 mole percent ethylene glycol, based on 100 mole percent dicarboxylic acid and 100 mole percent diol.

Landscapes

  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Compositions Of Macromolecular Compounds (AREA)
  • Polyamides (AREA)

Abstract

La présente invention concerne des compositions à mélange de polyesters présentant des propriétés de rétention de saveur et de couleur améliorées comprenant (A) 98,0 % à 99,95 % en poids d'un polyester constitué (1) d'un composant d'acide dicarboxylique comprenant des unités de répétition d'au moins 50 % en moles d'acide naphtalénedicarboxylique; et (2) un composant de diol comprenant des unités de répétition d'au moins 50 % en moles d'éthylène glycol sur la base de 100 % en moles d'acide dicarboxylique et de 100 % en moles de diol; et (B) 2,0 % à 0,05 % en poids d'un polyamide dans lequel les poids associés de (A) et (B) font un total de 100 %.
PCT/US1998/004311 1997-03-05 1998-03-05 Naphtalenedicarboxylate contenant un melange de polyamide/polyester a propriete de retention de saveur amelioree WO1998039388A1 (fr)

Priority Applications (3)

Application Number Priority Date Filing Date Title
BR9808301-5A BR9808301A (pt) 1997-03-05 1998-03-05 Composições de poliéster tendo propriedades melhoradas de retenção de sabor, e, processo para formação de uma mistura
JP53880698A JP2001514681A (ja) 1997-03-05 1998-03-05 風味保持性の改良されたナフタレンジカルボキシレート含有ポリエステル／ポリアミドブレンド
EP98908969A EP0964893A1 (fr) 1997-03-05 1998-03-05 Naphtalenedicarboxylate contenant un melange de polyamide/polyester a propriete de retention de saveur amelioree

Applications Claiming Priority (4)

Application Number Priority Date Filing Date Title
US3600897P 1997-03-05 1997-03-05
US3398998A 1998-03-03 1998-03-03
US09/033,989 1998-03-03
US60/036,008 1998-03-03

Publications (1)

Publication Number Publication Date
WO1998039388A1 true WO1998039388A1 (fr) 1998-09-11

Family

ID=26710414

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/US1998/004311 WO1998039388A1 (fr) 1997-03-05 1998-03-05 Naphtalenedicarboxylate contenant un melange de polyamide/polyester a propriete de retention de saveur amelioree

Country Status (4)

Country Link
EP (1) EP0964893A1 (fr)
JP (1) JP2001514681A (fr)
BR (1) BR9808301A (fr)
WO (1) WO1998039388A1 (fr)

Cited By (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2000022043A1 (fr) * 1998-10-09 2000-04-20 Eastman Chemical Company Melanges de polyester/polyamide a couleur amelioree
WO2001009245A1 (fr) * 1999-07-30 2001-02-08 Eastman Chemical Company Melanges de polyester-polyamide caracterises par une faible permeabilite aux gaz et par un trouble limite
US6191209B1 (en) * 1999-06-30 2001-02-20 Ciba Specialty Chemicals Corporation Polyester compositions of low residual aldehyde content
EP1167447A2 (fr) * 2000-06-28 2002-01-02 SINCO RICERCHE S.p.A. Mélange maítre de polyarylène-amide pour la préparation de résines polyester
WO2004020519A1 (fr) * 2002-08-30 2004-03-11 The Coca-Cola Company Polyester a teneur reduite en acetaldehyde et procede mettant en oeuvre un catalyseur d'hydrogenation
US6790499B2 (en) 2000-12-29 2004-09-14 Ciba Speicalty Chemicals Corporation Polyester compositions of low residual aldehyde content
US6908650B2 (en) 2001-03-02 2005-06-21 Ciba Specialty Chemicals Corporation Polyester and polyamide compositions of low residual aldehyde content
US6916881B2 (en) 1999-09-27 2005-07-12 Ciba Specialty Chemicals Corporation Polyester compositions of low residual aldehyde content
US7138457B2 (en) 2001-08-13 2006-11-21 Ciba Specialty Chemicals Corporation Polyester compositions of low residual aldehyde content
WO2007001551A1 (fr) * 2005-06-17 2007-01-04 Eastman Chemical Company Melanges de polymeres transparents contenant du polyester comprenant un cyclobutanediol, articles produits a partir de ces derniers

Families Citing this family (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR101055230B1 (ko) * 2003-01-31 2011-08-08 엠 앤드 지 폴리메리 이탈리아 에스.피.에이. 시각 헤이즈를 차폐하기 위한 흡광 조성물을 포함하는 물품및 관련 방법

Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5340884A (en) * 1992-04-02 1994-08-23 Eastman Kodak Company Polyamide concentrate useful for producing blends having improved flavor retaining property and clarity
WO1997015629A1 (fr) * 1995-10-25 1997-05-01 Eastman Chemical Company Melange de polyester/polyamides ameliore en maintien de saveur et en transparence

Patent Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5340884A (en) * 1992-04-02 1994-08-23 Eastman Kodak Company Polyamide concentrate useful for producing blends having improved flavor retaining property and clarity
WO1997015629A1 (fr) * 1995-10-25 1997-05-01 Eastman Chemical Company Melange de polyester/polyamides ameliore en maintien de saveur et en transparence

Non-Patent Citations (2)

* Cited by examiner, † Cited by third party
Title
"POLY(ETHYLENE NAPHTHALENEDICARBOXYLATE)/POLYAMIDE BLENDS", RESEARCH DISCLOSURE, no. 283, November 1987 (1987-11-01), pages 661/662, XP000026955 *
"POLY(ETHYLENE NAPHTHALENEDICARBOXYLATE)/POLYAMIDE BLENDS", RESEARCH DISCLOSURE, no. 294, 1 October 1988 (1988-10-01), pages 780 - 784, XP000112386 *

Cited By (18)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US6239233B1 (en) 1998-10-09 2001-05-29 Eastman Chemical Company Polyester/polyamide blends with improved color
WO2000022043A1 (fr) * 1998-10-09 2000-04-20 Eastman Chemical Company Melanges de polyester/polyamide a couleur amelioree
US6191209B1 (en) * 1999-06-30 2001-02-20 Ciba Specialty Chemicals Corporation Polyester compositions of low residual aldehyde content
WO2001009245A1 (fr) * 1999-07-30 2001-02-08 Eastman Chemical Company Melanges de polyester-polyamide caracterises par une faible permeabilite aux gaz et par un trouble limite
US6444283B1 (en) 1999-07-30 2002-09-03 Eastman Chemical Company Polyester-polyamide blends with reduced gas permeability and low haze
US6916881B2 (en) 1999-09-27 2005-07-12 Ciba Specialty Chemicals Corporation Polyester compositions of low residual aldehyde content
EP1167447A2 (fr) * 2000-06-28 2002-01-02 SINCO RICERCHE S.p.A. Mélange maítre de polyarylène-amide pour la préparation de résines polyester
US6630542B2 (en) 2000-06-28 2003-10-07 Sinco Ricerche S.P.A. Preparation of polyester resins using a masterbatch of polyaryleneamide
AU777598B2 (en) * 2000-06-28 2004-10-21 APG Polytech, LLC Preparation of polyester resins using a masterbatch of polyaryleneamide
EP1167447A3 (fr) * 2000-06-28 2002-11-20 SINCO RICERCHE S.p.A. Mélange maítre de polyarylène-amide pour la préparation de résines polyester
US6790499B2 (en) 2000-12-29 2004-09-14 Ciba Speicalty Chemicals Corporation Polyester compositions of low residual aldehyde content
US6908650B2 (en) 2001-03-02 2005-06-21 Ciba Specialty Chemicals Corporation Polyester and polyamide compositions of low residual aldehyde content
US7022390B2 (en) 2001-03-02 2006-04-04 Ciba Specialty Chemicals Corporation Polyester and polyamide compositions of low residual aldehyde content
US7138457B2 (en) 2001-08-13 2006-11-21 Ciba Specialty Chemicals Corporation Polyester compositions of low residual aldehyde content
WO2004020519A1 (fr) * 2002-08-30 2004-03-11 The Coca-Cola Company Polyester a teneur reduite en acetaldehyde et procede mettant en oeuvre un catalyseur d'hydrogenation
US7041350B1 (en) 2002-08-30 2006-05-09 The Coca-Cola Company Polyester composition and articles with reduced acetaldehyde content and method using hydrogenation catalyst
WO2007001551A1 (fr) * 2005-06-17 2007-01-04 Eastman Chemical Company Melanges de polymeres transparents contenant du polyester comprenant un cyclobutanediol, articles produits a partir de ces derniers
WO2007001574A1 (fr) * 2005-06-17 2007-01-04 Eastman Chemical Company Procede de preparation d'articles en forme transparents de polyesters comprenant du cyclobutanediol

Also Published As

Publication number Publication date
JP2001514681A (ja) 2001-09-11
BR9808301A (pt) 2000-05-16
EP0964893A1 (fr) 1999-12-22

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