WO1998029479A1 - Film elastomere comprenant un elastomere en polyethylene catalyse par metallocene et son procede de production - Google Patents

Film elastomere comprenant un elastomere en polyethylene catalyse par metallocene et son procede de production Download PDF

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Publication number
WO1998029479A1
WO1998029479A1 PCT/US1997/023262 US9723262W WO9829479A1 WO 1998029479 A1 WO1998029479 A1 WO 1998029479A1 US 9723262 W US9723262 W US 9723262W WO 9829479 A1 WO9829479 A1 WO 9829479A1
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Prior art keywords
film
length
article
filler
ethylene
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PCT/US1997/023262
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English (en)
Inventor
Sharon Watkins Gwaltney
Cindy Janja Milicevic
Susan Elaine Shawver
Paul Windsor Estey
William B. Haffner
Ann L. Mccormack
Kevin G. Hetzler
Rob L. Jacobs
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Kimberly-Clark Worldwide, Inc.
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Priority to AU53844/98A priority Critical patent/AU5384498A/en
Publication of WO1998029479A1 publication Critical patent/WO1998029479A1/fr

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    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J5/00—Manufacture of articles or shaped materials containing macromolecular substances
    • C08J5/18—Manufacture of films or sheets
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2323/00—Characterised by the use of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Derivatives of such polymers
    • C08J2323/02—Characterised by the use of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Derivatives of such polymers not modified by chemical after treatment
    • C08J2323/04—Homopolymers or copolymers of ethene
    • C08J2323/08—Copolymers of ethene

Definitions

  • the present invention is directed to breathable elastomeric films utilizing metallocene catalyzed polyethylene elastomers.
  • the present invention is directed to a method of making such films.
  • the invention also includes breathable laminates of the films to one or more substrates, and methods of making the laminates .
  • the present invention is directed to breathable elastomeric films.
  • Such materials have a wide variety of uses, especially in the areas of limited use and disposable items.
  • Films have been traditionally used to provide barrier properties in limited use or disposable items.
  • limited use or disposable it is meant that the product and/or component is used only a small number of times or possibly only once before being discarded.
  • Examples of such products include, but are not limited to, surgical and health care related products such as surgical drapes and gowns, disposable work wear such as coveralls and lab coats and personal care absorbent products such as diapers, training pants, incontinence garments, sanitary napkins, bandages, wipes and the like.
  • films are used as the outer covers with the purpose of preventing body wastes from contaminating the clothing, bedding and other aspects of the surrounding environment of use.
  • films are used to prevent cross exchange of microorganisms between the wearer and the patient. While these films can be effective barriers, they are not aesthetically pleasing because their surfaces are smooth and either feel slick or tacky. They are also visually flat and "plasticy" thereby making them less desirable in apparel applications and other uses where they are in contact with human skin. It would be more preferable if these items were more cloth-like from both a tactile and visual standpoint.
  • infant diapers that have the feel and appearance of traditional cloth undergarments are perceived as premium products and may, in some cases, overcome the tendency to believe that they need to be covered by outer garments for aesthetic reasons.
  • Garment-like adult incontinence products could improve the self-image of the incontinent individual.
  • more garment-like isolation gowns would help the hospital environment feel less foreign and threatening to the patient and increase the comfort of the wearer.
  • Lamination of films have been used to create materials which are both impervious and somewhat clothlike in appearance and texture.
  • the outer covers on disposable diapers are but one example.
  • Surgical gowns and drapes are other examples. See, in this regard, coassigned U.S. Patent No. 4,379,102 dated April 5, 1983.
  • a primary purpose of the film in such laminations is to provide barrier properties.
  • Apparel made from laminations of these breathable or microporous films are more comfortable to wear by reducing the moisture vapor concentration and the consequent skin hydration underneath the apparel item. There is therefore a need for an elastic breathable film and process that provides a film with both the cloth-like aesthetics and the fit and comfort that are desired.
  • the present invention relates to a breathable elastomeric film that includes a metallocene catalyzed polyethylene polymeric resin material and at least 30% by weight of a filler having a particle size that contributes to pore formation.
  • the polymeric resin material has a density of from about 0.850 to about 0.917 g/cc.
  • the film includes from about 45 to about 60% filler by weight of the filled resin .
  • the resin material is selected from copolymers of ethylene and 1-butene, copolymers of ethylene and 1-hexene, copolymers of ethylene and 1-octene and combinations thereof.
  • the breathable film has an immediate recovery length that is at least about 50% of its elongation following a stretch cycling that achieved a stretched length of about 160% of the unbiased length.
  • the film of the present invention may have an immediate recovery length that is at least about 50% its elongation length following a stretch cycling that achieved a stretched length of about 200% of the unbiased length.
  • the present invention also is directed to a process for preparing a breathable elastomeric film of the present invention, including providing a polymeric resin including a metallocene catalyzed polyethylene polymeric material; adding to the polymeric resin at least 30% by weight of a filler having a particle size that contributes to pore formation to form a filled resin; forming a film having a first length from the filled resin; and stretching the film to form a microporous film.
  • the process of the invention is applicable to films formed by various processes, i.e., cast or blown films.
  • the microporous film is stretched to a second length that is from about 160 to about 400% of the first length.
  • the preferred film of the present invention has a water vapor transmission rate (WVTR) of from about 300 to about 4,500 grams per square meter per 24 hours (measured by ASTM Test E 96-80 with Celgard® 2500 as control) . More preferably, the film of the present invention has a WVTR of from about 1,000 to about 4,000 g/m 2 24 hrs.
  • WVTR water vapor transmission rate
  • Such films have a wide variety of uses including, but not limited to, applications in personal care absorbent articles including diapers, training pants, sanitary napkins, incontinence devices, bandages and the like. These same films also may be used in items such as surgical drapes and gowns as well as various articles of clothing either as the entire article or simply as a component thereof.
  • Figure 1 is a schematic side view of a process for forming a laminate according to the present invention.
  • Figure 2 is a cross-section side view of a film/nonwoven laminate according to the present invention.
  • Figure 3 is a partially cut away top plan view of an exemplary personal care absorbent article, in this case a diaper, which may utilize a film made according to the present invention.
  • the present invention is directed to breathable elastomeric films that include metallocene-catalyzed ethylene-based polymers.
  • metallocene-catalyzed ethylene-based polymers includes those polymer materials that are produced by the polymerization of at least ethylene using metallocenes or constrained geometry catalysts, a class of organometallic complexes, as catalysts.
  • a common metallocene is ferrocene, a complex with a metal sandwiched between two cyclopentadienyl (Cp) ligands.
  • Metallocene process catalysts include bis (n-butylcyclopentadienyl) titanium dichloride, bis (n-butylcyclopentadienyl) zirconium dichloride, bis (cyclopentadienyl) scandium chloride, bis (indenyl) zirconium dichloride, bis (methylcyclopentadienyl) titanium dichloride, bis (methylcyclopentadienyl) zirconium dichloride, cobaltocene, cyclopentadienyltitanium trichloride, ferrocene, hafnocene dichloride, isopropyl (cyclopentadienyl, -1-flourenyl) zirconium dichloride, molybdocene dichloride, nickelocene, niobocene dichloride, ruthenocene, titanocene dichloride, zirconocene chloride hydride, zirconoc
  • Co-catalysts are materials such as methylaluminoxane (MAO) which is the most common, other alkylaluminums and boron containing compounds like tris (pentafluorophenyl) boron, lithium tetrakis (pentafluorophenyl) boron, and dimethylanilinium tetrakis (pentafluorophenyl) boron.
  • MAO methylaluminoxane
  • the metallocene-catalyzed ethylene-based polymers used in the present invention impart stretch and recovery properties to the film.
  • the metallocene catalyzed ethylene-based polymer is selected from copolymers of ethylene and 1-butene, copolymers of ethylene and 1-hexene, copolymers of ethylene and 1- octene and combinations thereof.
  • preferred materials include AffinityTM brand elastomeric metallocene-derived copolymers of ethylene and 1-octene, both available from Dow Plastics of Freeport, Texas.
  • Particularly preferred materials also include ExactTM brand elastomer metallocene-derived copolymers and terpolymers of ethylene and 1-butene and copolymers of ethylene and 1-hexene, available from Exxon Chemical Company of Houston, TX.
  • the material used in the present invention has a density of from about 0.850 to about 0.899 g/cc. More preferably, the material used in the present invention has a density of from about 0.860 to about 0.899 g/cc, even more preferably from about 0.870 to about 0.899 g/cc.
  • the melt index range of some useful materials is between about 1 to about 15 dg/min and advantageously may be in the range of from about 5 to about 10 dg/min. Specific examples of suitable materials can be found in U.S. Patent Nos. 5,472,775 and 5,272,236, both assigned to the Dow Chemical Company. The entire content of these patents is incorporated herein by reference.
  • the film layer also includes a filler which enables development of micropores during orientation of the film.
  • a "filler” is meant to include particulates and other forms of materials which can be added to the polymer and which will not chemically interfere with or adversely affect the extruded film but is able to be uniformly dispersed throughout the film.
  • the fillers will be in particulate form and usually will have somewhat of a spherical shape with average particle sizes in the range of about 0.5 to about 8 microns.
  • the film will usually contain at least 30 percent (%) , preferably about 40 to about 70 percent, filler based upon the total weight of the film layer.
  • filler More preferably, from about 45 to about 60 percent of filler is present in the film.
  • organic and inorganic fillers are contemplated to be within the scope of the present invention provided that they do not interfere with the film formation process, the breathability of the resultant film or its ability to bond to another layer such as a fibrous polyolefin nonwoven web.
  • fillers examples include calcium carbonate (CaC0 3 ) , various kinds of clay, silica (Si ⁇ 2 ) , alumina, barium sulfate, sodium carbonate, talc, magnesium sulfate, titanium dioxide, zeolites, aluminum sulfate, cellulose-type powders, diatomaceous earth, magnesium sulfate, magnesium carbonate, barium carbonate, kaolin, mica, carbon, calcium oxide, magnesium oxide, aluminum hydroxide, pulp powder, wood powder, cellulose derivative, polymer particles, chitin and chitin derivatives.
  • the filler particles may optionally be coated with a fatty acid, such as stearic acid, and behenic acid which may facilitate the free flow of the particles (in bulk) and their ease of dispersion into the polymer matrix.
  • the WVTR of the film of the present invention that may be used as a component in a limited-use or disposable item is from about 300 to about 4,500, more preferably from about 1,000 to about 4,000 g/m 2 /24 hrs.
  • the preferred films of the present invention are also elastic.
  • elastic is used herein to mean any material which, upon application of a biasing force, is stretchable, that is, elongatable, to a stretched, biased length which is at least about 150 percent of its relaxed unbiased length, and which will recover at least 50 percent of its elongation upon release of the stretching, elongating force.
  • a hypothetical example would be a one (1) inch sample of a material which is elongatable to at least 1.50 inches and which, upon being elongated to 1.50 inches and released, will recover to a length of not more than 1.25 inches.
  • Many elastic materials may be stretched by much more than 50 percent of their relaxed length, for example, 100 percent or more, and many of these will recover to substantially their original relaxed length, for example, to within 105 percent of their original relaxed length, upon release of the stretching force.
  • These properties can be obtained by first preparing a polymeric resin of a metallocene catalyzed ethylene- based polymer filling the resin with filler, extruding a film from the filled resin and thereafter stretching or orienting the filled film in at least one direction, usually, the machine direction.
  • the resultant film is microporous and has increased strength properties in the orientation direction.
  • FIG. 1 illustrates a general approach in orienting a filled film 10, such as one of the present invention.
  • filled film 10 is unwound and directed to a film stretching unit 44 such as a machine direction orienter, which is a commercially available device from vendors such as the Marshall and Williams Company of Buffalo, Rhode Island.
  • a film stretching unit 44 such as a machine direction orienter, which is a commercially available device from vendors such as the Marshall and Williams Company of Buffalo, Rhode Island.
  • Such an apparatus 44 has a plurality of stretching rollers 46 moving at progressively faster speeds relative to the pair disposed before it.
  • These rollers 46 apply an amount stress and thereby progressively stretch filled film 10 to a stretch length in the machine direction of the film which is the direction of travel of filled film 10 through the process as shown in Figure 1.
  • the stretch rollers 46 may be heated for better processing.
  • unit 44 also include rollers (not shown) upstream and/or downstream from the stretch rollers 46 that can be used to preheat the film 10 before orienting and/
  • the stretched length is from about 160 to about 500%, more preferably from about 200 to about 400% of the unbiased length of the film prior to stretching. If desired, film 10 is directed out of apparatus 44 so that the stress is removed to allow the stretched film 10 to relax.
  • filled film 10 may be attached to one or more support layers 30 to form a laminate 32.
  • a conventional fibrous nonwoven web forming apparatus 48 such as a pair of spunbond machines, is used to form the support layer 30.
  • the long, essentially continuous fibers 50 are deposited onto a forming wire 52 as an unbonded web 54 and the unbonded web 54 is then sent through a pair of bonding rolls 56 to bond the fibers together and increase the tear strength of the resultant web support layer 30.
  • One or both of the rolls are often heated to aid in bonding.
  • one of the rolls 56 is also patterned so as to impart a discrete bond pattern with a prescribed bond surface area to the web 30.
  • the other roll is usually a smooth anvil roll but this roll also may be patterned if so desired.
  • the laminating rolls 58 may be heated.
  • at least one of the rolls may be patterned to create a discrete bond pattern with a prescribed bond surface area for the resultant laminate 32. Generally, the maximum bond point surface area for a given area of surface on one side of the laminate 32 will not exceed about 50 percent of the total surface area.
  • Figure 1 were bonded together through thermal point bonding, other bonding means can also be used. Suitable alternatives include, for example, adhesive bonding and the use of tackifiers.
  • adhesive bonding an adhesive such as a hot melt adhesive is applied between the film and fiber to bind the film and fiber together.
  • the adhesive can be applied by, for example, melt spraying, printing or meltblowing.
  • Various types of adhesives are available, including those produced from amorphous polyalphaolefins, ethylene vinyl acetate-based hot melts, and Kraton ® brand adhesives available from Shell Chemical of Houston, TX and RextacTM Brand Adhesives from Rexene of Odessa, TX.
  • the tackifier When the film and support layer (s) is bonded with tackifiers, the tackifier may be incorporated into the film itself.
  • the tackifier essentially serves to increase adhesion between the film and fiber layers.
  • the film and fiber laminate may subsequently be thermally point-bonded, although generally very little heat is required since the tackifier tends to increase the pressure sensitivity of the film and a bond somewhat like and adhesive bond can be formed.
  • useful tackifers include WingtackTM 95, available from Goodyear Tire & Rubber Co. of Akron, OH, and EscorezTM 5300, available from Exxon Chemical Company of Houston, TX.
  • the direction of elasticity in the laminate may be tailored by the state of the film, i.e..
  • the support layers 30 as shown in Figure 2 are fibrous nonwoven webs.
  • the manufacture of such fibrous nonwoven webs is known.
  • Such fibrous nonwoven webs can add additional properties to filled film 10, such as a more soft, cloth-like feel. This is particularly advantageous when filled film 10 is being used as a barrier layer to liquids in such applications as outer covers for personal care absorbent articles and as barrier materials for hospital, surgical, and clean room applications such as, for example, surgical drapes, gowns and other forms of apparel.
  • Attachment of the support layers 30 to the filled film 10 may be by the use of a separate adhesive such as hot-melt and solvent based adhesives or through the use of heat and/or pressure
  • the support layer in a laminate containing the film layer of the present invention can be necked polypropylene spunbond, crimped polypropylene spunbond, bonded carded webs, elastomeric spunbond or meltblown fabrics produced from elastomeric resins.
  • a particularly advantageous support layer is a fibrous nonwoven web.
  • Such webs may be formed from a number of processes including, but not limited to, spunbonding, meltblowing and bonded carded web processes.
  • Meltblown fibers are formed by extruding molten thermoplastic material through a plurality of fine, usually circular, capillaries as molten threads or filaments into a high velocity usually heated gas stream such as air, which attenuates the filaments of molten thermoplastic material to reduce their diameters.
  • meltblown fibers are carried by the high velocity usually heated gas stream and are deposited on a collecting surface to form a web of randomly dispersed meltblown fibers.
  • the meltblown process is well-known and is described in various patents and publications, including NRL Report 4364, "Manufacture of Super-Fine Organic Fibers" by B. A. Wendt, E. L. Boone and D. D. Fluharty; NRL Report 5265, "An Improved Device For The Formation of Super-Fine Thermoplastic Fibers" by K. D. Lawrence, R. T. Lukas, J. A. Young; U.S. Patent No. 3,676,242, issued July 11, 1972, to Prentice; and U.S. Patent No.
  • Spunbond fibers are formed by extruding a molten thermoplastic material as filaments from a plurality of fine, usually circular, capillaries in a spinnerette with the diameter of the extruded filaments then being rapidly reduced, for example, by non-educative or educative fluid-drawing or other well-known spunbonding mechanisms.
  • the production of spunbond nonwoven webs is illustrated in patents such as Appel et al., U.S. Patent No. 4,340,563; Matsuki, et al., U.S. Patent No.
  • a plurality of support layers 30 also may be used.
  • Such materials can include, for example, spunbond/meltblown laminates and spunbond/meltblown/spunbond laminates such as are taught in Brock et al., U.S. Patent No. 4,041,203 which is incorporated herein by reference in its entirety.
  • Bonded carded webs are made from staple fibers which are usually purchased in bales. The bales are placed in a picker which separates the fibers. Next the fibers are sent through a combing or carding unit which further breaks apart and aligns the staple fibers in the machine direction so as to form a machine direction-oriented fibrous nonwoven web. Once the web has been formed, it is then bonded by one or more of several bonding methods.
  • One bonding method is powder bonding wherein a powdered adhesive is distributed throughout the web and then activated, usually by heating the web and adhesive with hot air.
  • Another bonding method is pattern bonding wherein heated calender rolls or ultrasonic bonding equipment is used to bond the fibers together, usually in a localized bond pattern though the web can be bonded across its entire surface if so desired.
  • through-air bonding equipment is, for many applications, especially advantageous.
  • the process shown in Figure 1 also may be used to create a three layer laminate.
  • the only modification to the previously described process is to feed a supply 62 of a second fibrous nonwoven web support layer 30a into the laminating rolls 58 on a side of filled film 10 opposite that of the other fibrous nonwoven web support layer 30.
  • one or both of the support layers may be formed directly in-line, as is support layer 30.
  • the supply of one or both support layers may be in the form of a pre-formed roll 62, as is support layer 30a.
  • the second support layer 30a is fed into the laminating rolls 58 and is laminated to filled film 10 in the same fashion as the first support layer 30.
  • filled film 10 and the breathable laminate 32 may be used in a wide variety of applications not the least of which includes personal care absorbent articles such as diapers, training pants, incontinence devices and feminine hygiene products such as sanitary napkins.
  • An exemplary article 80 in this case a diaper, is shown in Figure 4 of the drawings.
  • most such personal care absorbent articles 80 include a liquid permeable top sheet or liner 82, a back sheet or outercover 84 and an absorbent core 86 disposed between and contained by the top sheet 82 and back sheet 84.
  • Articles 80 such as diapers may also include some type of fastening means 88 such as adhesive fastening tapes or mechanical hook and loop type fasteners to maintain the garment in place on the wearer, stretch region 90 in the waist area may also be provided for greater comfort
  • Filled film 10 by itself or in other forms such as the film/support layer laminate 32 may be used to form various portions of the article including, but not limited to, stretch region 90, the top and the back sheet 84. If the film or laminate is to be used as the liner 82, it will most likely have to be apertured or otherwise made to be liquid permeable. When using a film/nonwoven laminate as the outercover 84, it is usually advantageous to place the nonwoven side facing out away from the user. In addition, in such embodiments it may be possible to utilize the nonwoven portion of the laminate as the loop portion of the hook and loop combination.
  • filled film and breathable film/support layer laminates include, but are not limited to, surgical drapes and gowns, wipers, barrier materials and articles of clothing or portions thereof including such items as workwear and lab coats.
  • a 3" wide by 6" long strip of the sample material was pulled to an elongated length of 160% and 200% of the original grip distance of 3 inches.
  • the sample is elongated at a rate of 20 in/min for two cycles. Upon return after the second cycle, the elongation at which no load is first detected is recorded. This value is used as the final length in the immediate recovery calculation below.
  • the sample is then held at zero elongation for one minute. At this time, the sample is elongated until a load is detected. This value is used as the final length to calculate delayed recovery.
  • a 3 inch wide by 6 inch long strip of each sample is stretched to 160% of its unbiased length.
  • the stretching apparatus was SINTECH Model 1/5 or Model 2/5 from Syntech Division of MTS Systems Corp. , Research Triangle Park, NC 27709-4226. This cycle of 60% elongation was repeated two times. The % hysteresis loss was calculated in accordance to Equation III below.
  • the zero load extension value which is the distance that the jaws of the tensile test equipment move at the beginning of the second cycle before a load is registered by the equipment, was obtained from the tensile test equipment.
  • the sample was held at 60% elongation for one minute. The sample is then returned to zero elongation. Upon this return, the length at which no load is initially detected is used as the final length for the Immediate Set calculation below:
  • the sample is then held at zero elongation for one minute. At that time the sample is elongated until a load is detected. The length at which this load is detected is used to calculate Delayed Set:
  • Recovery is defined as the difference between immediate set and delayed set. No recovery indicates that the two values were identical.
  • the water vapor transmission rate (WVTR) for the sample materials was calculated in accordance with ASTM
  • CELGARD® 2500 film is a microporous polypropylene film.
  • the test dish was a number 60-1 Vapometer pan distributed by Thwing-Albert Instrument Company of Philadelphia, Pennsylvania. One hundred milliliters of water were poured into each Vapometer pan and individual samples of the test materials and control material were placed across the open tops of the individual pans.
  • Screw-on flanges were tightened to form a seal along the edges of the pan, leaving the associated test material or control material exposed to the ambient atmosphere over a 6.5 centimeter diameter circle having an exposed area of approximately 33.17 square centimeters.
  • the pans were placed in a forced air oven at 100°F (32 °C) for 1 hour to equilibrate.
  • the oven was a constant temperature oven with external air circulating through it to prevent water vapor accumulation inside.
  • a suitable forced air oven is, for example, a Blue M Power-O-Matic 60 oven distributed by Blue M Electric Company of Blue Island, Illinois.
  • Test WVTR (grams weight loss over 24 hours) x 315.5 g/m 2 /24hrs
  • the relative humidity within the oven was not specifically controlled.
  • the 20-inch wide 1.5 mils thick film was then stretch-oriented in the machine direction (MD) at a stretch ratio of 5.4X (fast niproll speed divided by the slow nip speed) , all rolls being at room temperature (65- 70 °F) .
  • Film inlet speed was 30 fpm, outlet speed 162 fpm on the MDO, and the stretched film was wound up at about 98 fpm so that the film could be wound up under the lowest tension. This gives an effective stretch ratio of 3.25X from film inlet to the MDO to the winder.
  • the film was completely whitened indicating porosity, with a measured WVTR of 1618 g/m 2 /day. The film displayed very good elastic behavior in both the CD and MD direction.
  • EXXAIRETM XBF-511W A commercially available breathable film, EXXAIRETM XBF-511W, available from Exxon Chemical Company of Houston, TX, was also tested using some of the above test procedures.
  • This film essentially inelastic, has an undisclosed amount of filler, it is a uniaxially oriented microporous LLDPE film with WVTR of 3840 g/m 2 /day as measured by the test procedure described above. Cycle testing was done perpendicular to the direction of orientation. The values obtained are listed in Table III below:
  • a cast film of the following composition (% by weight) was extruded:
  • the extruded 1.5-mil thick film was then stretch- oriented in the machine direction at a stretch ratio of 4X, the preheat rolls, slow and fast niprolls set at 170°F and the annealing roll at 200°F.
  • Film inlet speed was 100 fpm, and the stretched film was wound up at about 400 fpm.
  • the film was completely whitened, and the measured WVTR was 4590 g/m 2 /day. This film was also tested perpendicular to the direction of orientation. The values obtained are listed in Table IV below.
  • this film is made with a metallocene-type of copolymer, it is essentially inelastic because of the higher density of the copolymer.
  • the 20-inch wide 1.5 mils thick film was then stretch-oriented in the machine direction (MD) on equipment commonly known in the art as MDO, at a stretch ratio of 5.
  • MD machine direction
  • MDO machine direction
  • OX fast niproll speed divided by the slow niproll speed
  • All rolls being at room temperature (about 70°F) , except the last roll which was set at 120°F to anneal the film.
  • Film inlet speed was 60 fpm
  • outlet speed from the MDO was 300 fpm
  • the film was then directed to a winder whose speed was adjusted to allow the film to relax but without any slack or sag before the winder.
  • a sheet of necked spunbond (previously stretched to neck to 40% of its original width, ending basis weight of 0.9 ounce per square yard) was then unwound, directed under a spray-head, which was positioned between the MDO and the winder, where the spunbond was sprayed with a molten hotmelt (RextacTM RT-2330, available from Rexene Corp. of Odessa, TX) at adhesive add-on level of 3 grams/m 2 , the so-sprayed spunbond was then directed to niprolls just before the winder where the film and the spunbond were contacted to consummate the lamination, and the laminate was wound up at a speed of 155 fpm.
  • the laminate so made had a smooth, cloth-like appearance on one side, it was soft and elastic (extensible with snap- back) in the CD-direction withstanding repeated stretching without delamination.
  • the laminate was breathable with WVTR measured at 1374 g/m 2 /day.
  • the laminate so made was tested for its elastic behavior using tests described above Testing the sample in the cross direction (CD) , that is, in the direction of its extensibility and perpendicular to the direction of film orientation, average of four specimens tested, the values obtained are listed in Table V below:
  • the films of the present invention have high water vapor transmission rate and elasticity that impart a wide variety of functionalities including vapor permeability, liquid impermeability, and comfort fit and stretch. Furthermore, such films can be attached to support layers to form laminates .

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Abstract

On décrit un film imper-respirant comprenant un matériau élastomère au polyéthylène dérivé de métallocène et une charge qui contribue à la formation de pores; ainsi qu'un procédé de production du film imper-respirant qui consiste à étirer le film pour y former des micropores.
PCT/US1997/023262 1996-12-27 1997-12-15 Film elastomere comprenant un elastomere en polyethylene catalyse par metallocene et son procede de production WO1998029479A1 (fr)

Priority Applications (1)

Application Number Priority Date Filing Date Title
AU53844/98A AU5384498A (en) 1996-12-27 1997-12-15 Elastomeric film including metallocene catalyzed polyethylene elastomer and method for making the same

Applications Claiming Priority (4)

Application Number Priority Date Filing Date Title
US77421396A 1996-12-27 1996-12-27
US08/774,213 1996-12-27
US84314797A 1997-04-25 1997-04-25
US08/843,147 1997-04-25

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WO1998029479A1 true WO1998029479A1 (fr) 1998-07-09

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PCT/US1997/023262 WO1998029479A1 (fr) 1996-12-27 1997-12-15 Film elastomere comprenant un elastomere en polyethylene catalyse par metallocene et son procede de production

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WO1999000449A1 (fr) * 1997-06-26 1999-01-07 The Dow Chemical Company Compositions polymeres a materiau de remplissage
US6277479B1 (en) 1997-12-19 2001-08-21 Kimberly-Clark Worldwide, Inc. Microporous films having zoned breathability
US6383431B1 (en) 1997-04-04 2002-05-07 The Procter & Gamble Company Method of modifying a nonwoven fibrous web for use as component of a disposable absorbent article
WO2002060690A2 (fr) * 2000-12-22 2002-08-08 Kimberly-Clark Worldwide, Inc. Procede en une etape de fabrication d'une structure de feuille mince elastique respirante
US7737215B2 (en) 2005-03-17 2010-06-15 Dow Global Technologies Inc. Compositions of ethylene/α-olefin multi-block interpolymer for elastic films and laminates
US7910658B2 (en) 2005-03-17 2011-03-22 Dow Global Technologies Llc Compositions of ethylene/α-olefin multi-block interpolymer for elastic films and laminates
US7968479B2 (en) 2008-06-30 2011-06-28 Kimberly-Clark Worldwide, Inc. Elastic multilayer composite including pattern unbonded elastic materials, articles containing same, and methods of making same

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EP0605831A1 (fr) * 1992-12-28 1994-07-13 Mitsubishi Chemical Corporation Composition résineuse contenant une charge et films tendres utilisant la même
JPH07118431A (ja) * 1993-10-19 1995-05-09 Mitsubishi Chem Corp 通気性樹脂フィルム
EP0659808A1 (fr) * 1993-12-24 1995-06-28 Tokuyama Corporation Film poreux et procédé de sa fabrication
WO1997004955A1 (fr) * 1995-08-01 1997-02-13 Blessings Corporation Tissu multicouche respirant et son procede de fabrication
JPH0977893A (ja) * 1995-09-12 1997-03-25 Mitsui Petrochem Ind Ltd 通気性フィルム
EP0779325A2 (fr) * 1995-12-13 1997-06-18 Mitsui Toatsu Chemicals, Incorporated Film poreux et procédé de sa fabrication

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EP0605831A1 (fr) * 1992-12-28 1994-07-13 Mitsubishi Chemical Corporation Composition résineuse contenant une charge et films tendres utilisant la même
JPH07118431A (ja) * 1993-10-19 1995-05-09 Mitsubishi Chem Corp 通気性樹脂フィルム
EP0659808A1 (fr) * 1993-12-24 1995-06-28 Tokuyama Corporation Film poreux et procédé de sa fabrication
WO1997004955A1 (fr) * 1995-08-01 1997-02-13 Blessings Corporation Tissu multicouche respirant et son procede de fabrication
JPH0977893A (ja) * 1995-09-12 1997-03-25 Mitsui Petrochem Ind Ltd 通気性フィルム
EP0779325A2 (fr) * 1995-12-13 1997-06-18 Mitsui Toatsu Chemicals, Incorporated Film poreux et procédé de sa fabrication

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Cited By (13)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US6383431B1 (en) 1997-04-04 2002-05-07 The Procter & Gamble Company Method of modifying a nonwoven fibrous web for use as component of a disposable absorbent article
WO1999000449A1 (fr) * 1997-06-26 1999-01-07 The Dow Chemical Company Compositions polymeres a materiau de remplissage
US5973049A (en) * 1997-06-26 1999-10-26 The Dow Chemical Company Filled polymer compositions
US6103803A (en) * 1997-06-26 2000-08-15 The Dow Chemical Company Filled polymer compositions
US6277479B1 (en) 1997-12-19 2001-08-21 Kimberly-Clark Worldwide, Inc. Microporous films having zoned breathability
WO2002060690A3 (fr) * 2000-12-22 2003-01-30 Kimberly Clark Co Procede en une etape de fabrication d'une structure de feuille mince elastique respirante
WO2002060690A2 (fr) * 2000-12-22 2002-08-08 Kimberly-Clark Worldwide, Inc. Procede en une etape de fabrication d'une structure de feuille mince elastique respirante
US6582810B2 (en) 2000-12-22 2003-06-24 Kimberly-Clark Worldwide, Inc. One-step method of producing an elastic, breathable film structure
US7737215B2 (en) 2005-03-17 2010-06-15 Dow Global Technologies Inc. Compositions of ethylene/α-olefin multi-block interpolymer for elastic films and laminates
US7910658B2 (en) 2005-03-17 2011-03-22 Dow Global Technologies Llc Compositions of ethylene/α-olefin multi-block interpolymer for elastic films and laminates
US8273068B2 (en) 2005-03-17 2012-09-25 Dow Global Technologies Llc Compositions of ethylene/alpha-olefin multi-block interpolymer for elastic films and laminates
US8721827B2 (en) 2005-03-17 2014-05-13 Dow Global Technologies Llc Elastic films and laminates
US7968479B2 (en) 2008-06-30 2011-06-28 Kimberly-Clark Worldwide, Inc. Elastic multilayer composite including pattern unbonded elastic materials, articles containing same, and methods of making same

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PE4599A1 (es) 1999-02-09

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