WO1998029472A1 - Polymeres a base de silicone organique comportant des agglomerats metalliques et procede de production de ces polymeres - Google Patents

Polymeres a base de silicone organique comportant des agglomerats metalliques et procede de production de ces polymeres Download PDF

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Publication number
WO1998029472A1
WO1998029472A1 PCT/RU1997/000425 RU9700425W WO9829472A1 WO 1998029472 A1 WO1998029472 A1 WO 1998029472A1 RU 9700425 W RU9700425 W RU 9700425W WO 9829472 A1 WO9829472 A1 WO 9829472A1
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WO
WIPO (PCT)
Prior art keywords
equal
superior
polymers
metal
organosilicon
Prior art date
Application number
PCT/RU1997/000425
Other languages
English (en)
Russian (ru)
Inventor
Alexandr Mikhailovich Tsirlin
Evgeny Andreevich Chernyshev
Kirilovna Elena Florina
Nina Alexandrovna Popova
Lyudmila Leonidovna Borisenko
Sergei Pavlovich Gubin
Vadim Grigorievich Gerlivanov
Elena Alexeevna Izmailova
Original Assignee
Gosudarstvenny Nauchny Tsentr Rossyskoi Federatsii, Gosudarstvenny Nauchno-Issledovatelsky Institut Khimmii I Tekhnologii Elementoorganicheskikh Soedineny (Gnts Rf Gniikhteos)
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority claimed from RU96124720A external-priority patent/RU2125579C1/ru
Priority claimed from RU97121877A external-priority patent/RU2130467C1/ru
Application filed by Gosudarstvenny Nauchny Tsentr Rossyskoi Federatsii, Gosudarstvenny Nauchno-Issledovatelsky Institut Khimmii I Tekhnologii Elementoorganicheskikh Soedineny (Gnts Rf Gniikhteos) filed Critical Gosudarstvenny Nauchny Tsentr Rossyskoi Federatsii, Gosudarstvenny Nauchno-Issledovatelsky Institut Khimmii I Tekhnologii Elementoorganicheskikh Soedineny (Gnts Rf Gniikhteos)
Priority to DE19782222T priority Critical patent/DE19782222T1/de
Publication of WO1998029472A1 publication Critical patent/WO1998029472A1/fr

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Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G79/00—Macromolecular compounds obtained by reactions forming a linkage containing atoms other than silicon, sulfur, nitrogen, oxygen, and carbon with or without the latter elements in the main chain of the macromolecule
    • C08G79/10—Macromolecular compounds obtained by reactions forming a linkage containing atoms other than silicon, sulfur, nitrogen, oxygen, and carbon with or without the latter elements in the main chain of the macromolecule a linkage containing aluminium
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G77/00—Macromolecular compounds obtained by reactions forming a linkage containing silicon with or without sulfur, nitrogen, oxygen or carbon in the main chain of the macromolecule
    • C08G77/60—Macromolecular compounds obtained by reactions forming a linkage containing silicon with or without sulfur, nitrogen, oxygen or carbon in the main chain of the macromolecule in which all the silicon atoms are connected by linkages other than oxygen atoms
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G77/00—Macromolecular compounds obtained by reactions forming a linkage containing silicon with or without sulfur, nitrogen, oxygen or carbon in the main chain of the macromolecule
    • C08G77/60—Macromolecular compounds obtained by reactions forming a linkage containing silicon with or without sulfur, nitrogen, oxygen or carbon in the main chain of the macromolecule in which all the silicon atoms are connected by linkages other than oxygen atoms
    • C08G77/62—Nitrogen atoms
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G79/00—Macromolecular compounds obtained by reactions forming a linkage containing atoms other than silicon, sulfur, nitrogen, oxygen, and carbon with or without the latter elements in the main chain of the macromolecule
    • C08G79/08—Macromolecular compounds obtained by reactions forming a linkage containing atoms other than silicon, sulfur, nitrogen, oxygen, and carbon with or without the latter elements in the main chain of the macromolecule a linkage containing boron

Definitions

  • the stabilized products provided above are typically used for the manufacture of delicate, ceramic products and parts of sophisticated condition, which are used under conditions of convenience. However, when the temperature rises to 1200 ° C and more, the ceramic is recovered, which is in contact with it. Between this, the modern technology will run for a long time at temperatures of 1600 ° C and higher.
  • ⁇ ⁇ ezul ⁇ a ⁇ e ⁇ e ⁇ e ⁇ iches ⁇ i ⁇ and e ⁇ s ⁇ e ⁇ imen ⁇ alny ⁇ issled ⁇ vany ⁇ s ⁇ avlennaya task was ⁇ eshena ⁇ em that we sin ⁇ ezi ⁇ van n ⁇ vy: Class ⁇ e ⁇ ami ⁇ b ⁇ azuyuschi ⁇ ⁇ emniy ⁇ ganiches ⁇ i ⁇ ⁇ lime ⁇ v ⁇ bschey ⁇ muly (1), s ⁇ de ⁇ zhaschi ⁇ me ⁇ ally as ⁇ las ⁇ e ⁇ v ( ⁇ l ⁇ P). ⁇
  • metal-containing compounds in the amount of less than 0.1 wt.%, The effect is very insignificant, with the addition of
  • the reactive mass is maintained for 0.5–5 hours at a temperature of 100–450 ° ⁇ . If the temperature is less than 100 ° ⁇ or less, the reaction does not ideally go above 450 ° ⁇ or with an increase in heating time for more than 5 hours, the product is inaccessible.
  • metal-based compounds For interactions with extreme urban sources, metal-based compounds are used, metal complexes, such as ⁇ , ⁇ Economics, VER ⁇ , POWER carboxylic, carboxylyl, dialkyl (aryl) -amide, ⁇ ialkyl- (aryl) -silyl, bis [hexaalkyl (aryl) disilyl] amide and others.
  • the quality of the metal-containing compounds can be named: [ ⁇ 5 ( ⁇ 3 ) 5 ] 2 ⁇ 1 ⁇ 1 2 , ( ⁇ 5 ⁇ 5 ) 2 ⁇ 1 2 , ( ⁇ 3 ⁇ 5 ⁇ 4 ) 2 ⁇ _ ⁇ 2 , ⁇ réelle ( ⁇ ) 5 , ⁇ 3 ( ⁇ ) 12 , ⁇ réelle 2 ( ⁇ ) 9 , ⁇ - ⁇ 3 ⁇ 5 ⁇ réelle ( ⁇ ) 3 ⁇ 1, [( ⁇ 5 ⁇ 5 ) ⁇ réelle ( ⁇ ) 2 ] 2 , ⁇ - ⁇ 3 ⁇ 5 ⁇ ( ⁇ ) 3 , ⁇ ( ⁇ 5 ⁇ 5 ) 2 , ⁇ 5 ⁇ 5 ⁇ ( ⁇ ) 2 , ⁇ ⁇ ( ⁇ ) 8 , ⁇ 1 ( ⁇ ) 4 , [ ⁇ 5 ⁇ 5 ⁇ ( ⁇ )] 2 , ( ⁇ 3 ⁇ 5 ) 2 ⁇ , (C 5 ⁇ 5 ) 2 ⁇ , ⁇ ⁇ ⁇ , ⁇ ( ⁇ ) 6 ,
  • the proposed method for synthesizing a device is used and is universal for making different types of payments.
  • the practical implementation of the process in all cases results in favorable results in order to satisfy the requirements of the company.
  • a skeleton of the main skeleton ⁇ L ⁇ P consists of ⁇ 1 - C ⁇ 2 - (1050 and 1350 cm -1 ), ⁇ - ⁇ - ⁇ - (950, 1150 cm _1 ), ⁇ - ⁇ - (1550,
  • the reactive mixture is heated to 250 ° C and within 0.5 hour, add 1 g of Ge (C ⁇ ) in the form of a 3% solution in hexane, then the reactive mass is cooled in an inert gas.

Landscapes

  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Silicates, Zeolites, And Molecular Sieves (AREA)

Abstract

Cette invention concerne des polymères à base de silicone organique qui permettent de produire des céramiques et qui comprennent des agglomérats métalliques (Cl), lesquels polymères correspondent à la formule générale (1) où E représente SiR2, NR, (II), (III), (IV), (V), cyclo-(SiR2NR)x, (CB10H10C), (CB10H10C-O-SiR2), p-C6H4 ou (CH2)y; n est supérieur ou égal à 5, tandis que m est égal à 0,001 1, que x est égal à 3, 4 ou 5, et que y varie de 1 à 4. Les éléments R peuvent être identiques ou différents et représentent H, CH3, C2H5, C6H5, CH=CH2, CH2CH=CH2. Cl représente quant à lui des agglomérats de métaux de transition qui appartiennent au groupe Ib ou aux groupes III à VIII de la table de classification périodique. Le procédé de production de ces polymères à base de silicone organique, qui permettent de produire des céramiques et qui comprennent des Cl, consiste à mettre des composés de métaux de transition choisis dans les groupes susmentionnés en interaction avec des composés de silicone organique correspondant aux formules générales (2) et (3), ou avec des mélanges de ces derniers. Ces composés de silicone organique sont préalablement chauffés à une température allant de 50 à 450 °C dans une atmosphère inerte. Dans les formules (2) et (3), E, R, x et y sont tels que définis précédemment, tandis que p est supérieur ou égal à 3, que q est supérieur ou égal à 1, et que r est supérieur ou égal à 4. Après addition des composants contenant des métaux, la masse de réaction peut le cas échéant être maintenue à une température de 100 à 450 °C pendant une durée de 0,5 à 5 heures. Les polymères à base de silicone organique qui permettent de produire des céramiques, qui comprennent des agglomérats métalliques (Cl) et qui correspondent à la formule générale (1), peuvent être utilisés dans la production de céramiques composites d'une grande solidité et résistant à la chaleur.
PCT/RU1997/000425 1996-12-30 1997-12-30 Polymeres a base de silicone organique comportant des agglomerats metalliques et procede de production de ces polymeres WO1998029472A1 (fr)

Priority Applications (1)

Application Number Priority Date Filing Date Title
DE19782222T DE19782222T1 (de) 1996-12-30 1997-12-30 Organopolysiloxanpolymere, enthaltend Metallcluster, und Verfahren zur Herstellung derselben

Applications Claiming Priority (4)

Application Number Priority Date Filing Date Title
RU96124720 1996-12-30
RU96124720A RU2125579C1 (ru) 1996-12-30 1996-12-30 Поликарбосиланы, содержащие металлические кластеры, и способ их получения
RU97121877A RU2130467C1 (ru) 1997-12-26 1997-12-26 Кремнийорганические полимеры, содержащие металлические кластеры, и способ их получения
RU97121877 1997-12-26

Publications (1)

Publication Number Publication Date
WO1998029472A1 true WO1998029472A1 (fr) 1998-07-09

Family

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Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/RU1997/000425 WO1998029472A1 (fr) 1996-12-30 1997-12-30 Polymeres a base de silicone organique comportant des agglomerats metalliques et procede de production de ces polymeres

Country Status (2)

Country Link
DE (1) DE19782222T1 (fr)
WO (1) WO1998029472A1 (fr)

Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4851491A (en) * 1986-07-30 1989-07-25 The United States Of America As Represented By The Administrator Of The National Aeronautics And Space Administration Boron-containing organosilane polymers and ceramic materials thereof
US4871826A (en) * 1987-06-22 1989-10-03 Massachusetts Institute Of Technology Lewis base adducts of decaborane for forming new preceramic polymers, using as binders, forming shaped bodies and forming fibers
EP0453350A1 (fr) * 1990-04-20 1991-10-23 Rhone-Poulenc Chimie Procédé de réticulation de polymères à base de bore et d'azote, notamment pour l'obtention de fibres céramiques
US5118774A (en) * 1987-09-11 1992-06-02 Rhone-Poulenc Chimie Boron/nitrogen preceramic polymers and boron nitride ceramic materials produced therefrom
EP0562248A1 (fr) * 1992-02-13 1993-09-29 Lanxide Technology Company, Lp Polymère précurseur pour des céramiques carbure de silicium/nitrure d'aluminium

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4851491A (en) * 1986-07-30 1989-07-25 The United States Of America As Represented By The Administrator Of The National Aeronautics And Space Administration Boron-containing organosilane polymers and ceramic materials thereof
US4871826A (en) * 1987-06-22 1989-10-03 Massachusetts Institute Of Technology Lewis base adducts of decaborane for forming new preceramic polymers, using as binders, forming shaped bodies and forming fibers
US5118774A (en) * 1987-09-11 1992-06-02 Rhone-Poulenc Chimie Boron/nitrogen preceramic polymers and boron nitride ceramic materials produced therefrom
EP0453350A1 (fr) * 1990-04-20 1991-10-23 Rhone-Poulenc Chimie Procédé de réticulation de polymères à base de bore et d'azote, notamment pour l'obtention de fibres céramiques
EP0562248A1 (fr) * 1992-02-13 1993-09-29 Lanxide Technology Company, Lp Polymère précurseur pour des céramiques carbure de silicium/nitrure d'aluminium

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
Ru Uspekhi V Oblasti Sinteza Elementoorganicheskikh Polimerov Pod Red. V.V. KORSHAKA, M., NAUKA, 1988, pages 267-275, 280. *

Also Published As

Publication number Publication date
DE19782222T1 (de) 1999-12-23

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