WO1998018850A1 - Stable solutions of a silsesquioxane or siloxane resin and a silicone solvent - Google Patents
Stable solutions of a silsesquioxane or siloxane resin and a silicone solvent Download PDFInfo
- Publication number
- WO1998018850A1 WO1998018850A1 PCT/US1997/019299 US9719299W WO9818850A1 WO 1998018850 A1 WO1998018850 A1 WO 1998018850A1 US 9719299 W US9719299 W US 9719299W WO 9818850 A1 WO9818850 A1 WO 9818850A1
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J3/00—Processes of treating or compounding macromolecular substances
- C08J3/02—Making solutions, dispersions, lattices or gels by other methods than by solution, emulsion or suspension polymerisation techniques
- C08J3/09—Making solutions, dispersions, lattices or gels by other methods than by solution, emulsion or suspension polymerisation techniques in organic liquids
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J3/00—Processes of treating or compounding macromolecular substances
- C08J3/02—Making solutions, dispersions, lattices or gels by other methods than by solution, emulsion or suspension polymerisation techniques
- C08J3/09—Making solutions, dispersions, lattices or gels by other methods than by solution, emulsion or suspension polymerisation techniques in organic liquids
- C08J3/091—Making solutions, dispersions, lattices or gels by other methods than by solution, emulsion or suspension polymerisation techniques in organic liquids characterised by the chemical constitution of the organic liquid
- C08J3/098—Other compounds
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J3/00—Processes of treating or compounding macromolecular substances
- C08J3/02—Making solutions, dispersions, lattices or gels by other methods than by solution, emulsion or suspension polymerisation techniques
- C08J3/09—Making solutions, dispersions, lattices or gels by other methods than by solution, emulsion or suspension polymerisation techniques in organic liquids
- C08J3/091—Making solutions, dispersions, lattices or gels by other methods than by solution, emulsion or suspension polymerisation techniques in organic liquids characterised by the chemical constitution of the organic liquid
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2383/00—Characterised by the use of macromolecular compounds obtained by reactions forming in the main chain of the macromolecule a linkage containing silicon with or without sulfur, nitrogen, oxygen, or carbon only; Derivatives of such polymers
- C08J2383/04—Polysiloxanes
Definitions
- the present invention pertains to solutions of silsesquioxane and siloxane resins. More particularly, the invention pertains to a solvent composition for forming improved stability coating compositions containing such resins.
- silsesquioxane and siloxane resins are useful in the electronic and semiconductor fields to coat silicon chips and other similar components. Such coatings protect the surface of substrates and form dielectric layers between electric conductors on integrated circuits. Such coatings can be used as protective coatings, interlevel dielectric layers, doped dielectric layers to produce transistor like devices, pigment loaded binder systems containing silicon to produce capacitor and capacitor like devices, multilayer devices, 3-D devices, silicon on insulator devices, coatings for superconductors, superlattice devices and the like. These resins include hydrogen silsesquioxane resins as well as silsesquioxane resins containing a significant portion of organic moieties.
- U.S. Patent 5,010, 159 teaches a method comprising hydrolyzing hydridosilanes in an arylsulfonic acid hydrate hydrolysis medium to form a resin which is then contacted with a neutralizing agent.
- Other hydridosiloxane resins such as those disclosed in U.S. Patent 4,999,397 are produced by hydrolyzing an alkoxy or acyloxy silane in an acidic, alcoholic hydrolysis medium.
- the use of hydrogen silsesquioxane resin in forming coatings on electronic devices is also well known in the art.
- patent 5,320,868 teaches solvents which can be used for coating hydrogen silsesquioxane resin including alcohols such as ethyl or isopropyl, aromatic hydrocarbons such as benzene or toluene, alkanes such as n-heptane or dodecane, ketones, cyclic dimethylpolysiloxanes, esters or glycol ethers.
- solvents including MLBK and certain silicones which can be used for coating hydrogen silsesquioxane resin, however, there is no appreciation of the improvement in stability when silicone solvents are used as opposed to non-silicone solvents.
- the solvent composition of this invention for coating silsesquioxane and siloxane resins provides shelf life properties that are equal to or better than MLBK and which is safer and more environmentally acceptable than MLBK It has now been found that when silsesquioxane and siloxane resins are dissolved in solvents containing certain siloxane functional groups, the compositions exhibit good coating properties, have very good shelf life, and present fewer handling and environmental concerns than when MLBK is used in the solvent.
- the invention also provides a method of impeding an increase in molecular weight of a one polymer having a formula selected from the group consisting of
- each R is independently H, C, to C 8 alkyl or C 6 to C, aryl which comprises forming a solution of the polymer and at least one solvent selected from the group consisting of (CH 3 ) 3 Si-O-[Si(CH 3 ) 2 ] a - Si(CH 3 ) 3 ,
- the invention further provides a method of forming a layer on a substrate which comprises forming a solution of at least one polymer having a formula selected
- a composition is prepared which is broadly composed of a solution of at least one of the above polymers and at least one of the above solvents.
- the weight average molecular weight may range from about 1,000 to about 220,000.
- n ranges from about 100 to about 800 yielding a molecular weight of from about 5,000 to about 45,000 More preferably, n ranges from about 250 to about 650 yielding a molecular weight of from about 14,000 to about 36,000
- Useful polymers within the context of this invention nonexclusively include hydrogensiloxane, hydrogensilsesquioxane, hydrogenmethylsiloxane, hydrogenethylsiloxane, hydrogenpropylsiloxane, hydrogenbutylsiloxane, hydrogen ert-butylsiloxane, hydrogenphenylsiloxane, hydrogenmethylsilsesquioxane, hydrogenethylsilsesquioxane, hydrogenpropylsilsesquioxane, hydrogenbutylsilsesquioxane, hydrogen er/- butylsilsesquioxane and hydrogenphenylsilsesquioxane.
- the hydroorganosiloxanes are preferred.
- the polymer component is preferably present in an amount of from about 10 % to about 30 % by weight of the composition. A more preferred range is from about 15 % to about 30 % and most preferably from about 17 % to about 25 % by weight of the composition.
- composition then contains a solvent component comprising at least one solvent.
- Useful linear solvents have the formulae (CH 3 ) 3 Si-O-[Si(CH 3 ) 2 j l _-Si(CH 3 ) 3 , (CH 3 CH2)Si-O-[Si(CH 3 CH 2 )2] 1 -SiCH3CH2)3, and R 3 Si-O-[SiR' 2 ].-SiR 3 .
- linear solvents nonexclusively include decamethyltetrasiloxane, 1,3- dioctyltetramethyldisiloxane, octamethyltrisiloxane, pentamethyldisiloxane, hexamethyldisiloxane, 1,1,3,3,5,5-hexamethyltrisiloxane, 1,1,3,3- tetramethyldisiloxane, 1 ,3 -bis-(trimethylsiloxy)- 1 , 3 -dimethylsiloxane, bis(trimethylsiloxy)ethylsilane, bis(trimethylsiloxy)methylsilane, decamethyltetrasiloxane, dodecamethylpentasiloxane, 1,1,1,3,3,5,5- heptamethyhrisiloxane, hexaethyldisiloxane, heptamethyltrisiloxane and 1, 1,3,3- tetrais
- cyclic solvents nonexclusively include decamethylcyclopentasiloxane, hexaethylcyclotrisiloxane, hexamethylcyclotrisiloxane, 1,3,5,7- tetramethylcyclotetrasiloxane, pentamethylcyclopentasiloxane, octamethylcyclotetrasiloxane, methylhydrocyclosiloxanes of the formula (CH 3 HSiO) 3 .5, l,3,5,7,tetraethylcyclotetrasiloxane and l,3,5,7,tetramethylcyclotetrasiloxane.
- Preferred linear solvents are octamethyhrisiloxane and hexamethyldisiloxane and preferred cyclic solvents are decamethylcyclopentasiloxane and
- the solvent component is preferably present in the overall composition in an amount of from about 70 % to about 90 % by weight of the composition, more preferably
- blends of the solvents of this invention are particularly preferred since by forming such blends one is able to fine tune the evaporation rate of the composition on a substrate.
- Low boiling point solvents tend to produce thicker films o and are not as uniform as desired.
- High boiling point solvents tend to produce thinner films and a greater than desired amount of coating is removed during spin coating operations.
- those skilled in the art seek to produce a very smooth film at a desired target film thickness, for example about 4,000 angstroms.
- One particularly useful solvent blend comprises from about 5 % to about 15 % by weight of 5 hexamethyldisiloxane (b.p.
- the overall composition may be used by coating it onto a substrate, such as a o semiconductor substrate, particularly silicon wafers with subsequent drying and/or curing.
- the coating may be used as a planarizing layer or as an insulation between metal lines on the substrate. Drying may be conducted by heating at temperatures of from about 150 °C to about 350 °C for example, for at least one minute. Drying may be conducted at a sequentially increasing temperature, for example 1 minute at 150 °C, followed by one minute at 250 °C and one minute at 350 °C. Suitable drying temperatures and heating times may be easily determined by those skilled in the art. Thereafter the coating may optionally be cured, such as by heating at temperatures of from about 250 °C to about 800 °C until cured to convert the composition to a ceramic. Suitable curing temperatures and heating times may be easily determined by those skilled in the art.
- Examples 1 -4 demonstrate spin-coating, baking and curing using the siloxane solvents of this invention.
- Examples 5-7 show molecular weight growth in the siloxane solvents of this invention.
- Examples 8-10 show molecular weight growth in other solvents for comparison.
- a solvent blend (10 % hexamethyldisiloxane, 15 % octamethyhrisiloxane and 75 % octamethylcyclotetrasiloxane was combined with 32.10g of a tert-butylhydrido siloxane polymer. 2 ml of the solution was coated on a bare silicon wafer using an SVG spin coater. The spin cycle consisted of a 3 sec. delay, 3000 RPM spin for 20 sec. with an acceleration of 50,000 RPM/sec, then a deceleration of 50,000 RPM/sec. Wafer was then baked on three successive hotplates for one min.
- Film thickness measured 2652A on a Nanospec AFT. Refractive index could not be measured on a Rudolph elipsometer. Thickness varied by 0.23% over 5 measurements. Wafer was then cured at 380 °C for lhr in a horizontal furnace under a nitrogen atmosphere at a flow rate of 4IJmin. Thickness measured 2344A on a Nanospec AFT, corrected for the refractive index of 1.375 as measured on a Rudolph elipsometer. Thickness varied by 0.54% over 5 measurements and is
- EXAMPLE S 1368.8g of a solvent blend (10 % hexamethyldisiloxane, 15 % octamethyhrisiloxane and 75 % octamethylcyclotetrasiloxane) was combined with 300. lg of hydridosiloaxne polymer. The solution was filtered to 0.1 micron. The molecular weight of the solution was tested on a Waters 410 GPC using toluene as the flow medium, and calibrated with polystyrene standards. The original molecular weight was measured as 22709 atomic mass units (AMU), and after 15 days at room temperature the molecular weight measured 25060 AMU indicating an average growth rate of 157 AMU per day.
- AMU atomic mass units
- EXAMPLE 7 251.6g of a solvent blend (10 % hexamethyldisiloxane, 15 % octamethyltrisiloxane and 75 % octamethylcyclotetrasiloxane was combined with 55.3 g of a hydridomethyl siloxane polymer.
- the molecular weight of the solution was tested on a Waters 410 GPC using toluene as the flow medium, and caUbrated with polystyrene standards. The original molecular weight was measured as 30492 AMU, and after 105 days at room temperature the molecular weight measured 31466 AMU, indicating a low average growth rate of 9.3 AMU per day.
- the foUowing examples 11-14 demonstrate the improved shelf life of solvents made pursuant to the present invention, as compared to MLBK containing solvents.
- EXAMPLE 11 A solution of 18% by weight of hydrogen silsesquioxane is prepared in the foUowing solvents and stored in Teflon bottles. The molecular weight of the polymer is measured after 1 day and after 5 days. The molecular weight of the polymer has increased much less in decamethylcyclopentasUoxane and octamethylcyclotetrasUoxane than in MLBK.
- a solution of 18% by weight of hydrogen sUsesquioxane is prepared in the foUowing solvents and stored in Teflon bottles.
- the molecular weight of the polymer is measured after 1 day and after 19 days.
- the molecular weight of the polymer has increased much less in the indicated siloxane solvents than in MLBK.
- a solution of 18% by weight of hydrogen silsesquioxane is prepared in the following solvents and stored in high density polyethylene bottles.
- the molecular weight of the polymer is measured after 1 day and after 19 days.
- the molecular weight of the polymer has increased much less in the indicated sUoxane solvents than in MLBK.
- cyclopentasUoxane (1:1) hexamethyldisUoxane/decamethyl- 28551 34033 19.2 cyclopentasUoxane (4:1) hexamethyldisUoxane/octamethyl- 26952 34395 27.6 cyclotetrasUoxane (1:1) hexamethyldisUoxane 26448 35116 32.8
- a solution of 18% by weight of hydrogen sUsesquioxane is prepared in the following solvents and stored in Teflon bottles.
- the molecular weight of the polymer is measured after 1 day and after 16 days.
- the molecular weight of the polymer has increased much less in the indicated sUoxane solvents than in MLBK.
- This example Ulustrates some of the relevant coating properties of sUoxane containing solvents.
- a solution of 18% by weight of hydrogen sUsesquioxane is prepared in the foUowing solvents, coated, baked and cured under the indicated conditions.
- the coating properties of hydrogen sUsesquioxane in these solvents is exceUent, with variation in film thickness only between 0.2 - 1.9%.
- Thicknesses are in angstroms.
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- Chemical & Material Sciences (AREA)
- Dispersion Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- General Chemical & Material Sciences (AREA)
- Paints Or Removers (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Silicon Polymers (AREA)
Abstract
Description
Claims
Priority Applications (5)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
EP97913759A EP0935632B1 (en) | 1996-10-29 | 1997-10-27 | Stable solutions of a silsesquioxane or siloxane resin and a silicone solvent |
DE69709156T DE69709156T2 (en) | 1996-10-29 | 1997-10-27 | STABLE SOLUTIONS CONSISTING OF SILSESQUIOXANES OR SILICONE RESINS AND A SOLVENT BASED ON SILICONE |
JP52063098A JP2002514238A (en) | 1996-10-29 | 1997-10-27 | Stable solution of silsesquioxane resin or siloxane resin and silicone solvent |
AU50872/98A AU5087298A (en) | 1996-10-29 | 1997-10-27 | Stable solutions of a silsesquioxane or siloxane resin and silicone solvent |
CA002269952A CA2269952A1 (en) | 1996-10-29 | 1997-10-27 | Stable solutions of a silsesquioxane or siloxane resin and a silicone solvent |
Applications Claiming Priority (4)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US2923596P | 1996-10-29 | 1996-10-29 | |
US60/029,235 | 1996-10-29 | ||
US08/955,802 | 1997-10-22 | ||
US08/955,802 US6020410A (en) | 1996-10-29 | 1997-10-22 | Stable solution of a silsesquioxane or siloxane resin and a silicone solvent |
Publications (1)
Publication Number | Publication Date |
---|---|
WO1998018850A1 true WO1998018850A1 (en) | 1998-05-07 |
Family
ID=26704717
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
PCT/US1997/019299 WO1998018850A1 (en) | 1996-10-29 | 1997-10-27 | Stable solutions of a silsesquioxane or siloxane resin and a silicone solvent |
Country Status (8)
Country | Link |
---|---|
US (1) | US6020410A (en) |
EP (1) | EP0935632B1 (en) |
JP (1) | JP2002514238A (en) |
KR (1) | KR100512293B1 (en) |
AU (1) | AU5087298A (en) |
CA (1) | CA2269952A1 (en) |
DE (1) | DE69709156T2 (en) |
WO (1) | WO1998018850A1 (en) |
Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO2001029887A1 (en) * | 1999-10-18 | 2001-04-26 | Alliedsignal Inc. | Solvents for processing silsesquioxane and siloxane resins |
US6384119B1 (en) | 2000-06-22 | 2002-05-07 | Basf Corporation | Coating compositions comprising volatile linear siloxane fluids |
Families Citing this family (12)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US6509138B2 (en) | 2000-01-12 | 2003-01-21 | Semiconductor Research Corporation | Solventless, resistless direct dielectric patterning |
US20030096090A1 (en) * | 2001-10-22 | 2003-05-22 | Boisvert Ronald Paul | Etch-stop resins |
US6852367B2 (en) * | 2001-11-20 | 2005-02-08 | Shipley Company, L.L.C. | Stable composition |
US20040033371A1 (en) * | 2002-05-16 | 2004-02-19 | Hacker Nigel P. | Deposition of organosilsesquioxane films |
US8901268B2 (en) * | 2004-08-03 | 2014-12-02 | Ahila Krishnamoorthy | Compositions, layers and films for optoelectronic devices, methods of production and uses thereof |
JP2008547194A (en) * | 2005-06-15 | 2008-12-25 | ダウ・コーニング・コーポレイション | Method to harden hydrogen silsesquioxane and make it dense in nanoscale trench |
US8557877B2 (en) | 2009-06-10 | 2013-10-15 | Honeywell International Inc. | Anti-reflective coatings for optically transparent substrates |
US8648125B2 (en) * | 2009-12-04 | 2014-02-11 | Dow Corning Corporation | Stabilization of silsesquioxane resins |
US8864898B2 (en) | 2011-05-31 | 2014-10-21 | Honeywell International Inc. | Coating formulations for optical elements |
US10651382B2 (en) * | 2015-03-30 | 2020-05-12 | Merck Patent Gmbh | Formulation of an organic functional material comprising a siloxane solvent |
US10544329B2 (en) | 2015-04-13 | 2020-01-28 | Honeywell International Inc. | Polysiloxane formulations and coatings for optoelectronic applications |
DE102017211727A1 (en) * | 2017-07-10 | 2019-01-10 | Tridonic Jennersdorf Gmbh | Bonded LED chips in a polymer matrix |
Citations (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP0479452A2 (en) * | 1990-10-01 | 1992-04-08 | Dow Corning Corporation | Perhydrosiloxane copolymers and their use as coating materials |
EP0503825A1 (en) * | 1991-03-14 | 1992-09-16 | Dow Corning S.A. | Method of making siloxane compositions |
EP0606588A1 (en) * | 1992-12-14 | 1994-07-20 | Dow Corning Toray Silicone Co., Ltd. | Method for the formation of a silicon oxide film |
EP0616001A1 (en) * | 1993-03-19 | 1994-09-21 | Dow Corning Corporation | Stabilization of hydrogen silsesquioxane resin solutions |
JPH07300560A (en) * | 1994-05-02 | 1995-11-14 | Shin Etsu Chem Co Ltd | Silicon composition |
EP0791567A1 (en) * | 1996-02-22 | 1997-08-27 | Dow Corning Corporation | Electronic coating composition |
Family Cites Families (8)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3615272A (en) * | 1968-11-04 | 1971-10-26 | Dow Corning | Condensed soluble hydrogensilsesquioxane resin |
US4756977A (en) * | 1986-12-03 | 1988-07-12 | Dow Corning Corporation | Multilayer ceramics from hydrogen silsesquioxane |
US4999397A (en) * | 1989-07-28 | 1991-03-12 | Dow Corning Corporation | Metastable silane hydrolyzates and process for their preparation |
US5010159A (en) * | 1989-09-01 | 1991-04-23 | Dow Corning Corporation | Process for the synthesis of soluble, condensed hydridosilicon resins containing low levels of silanol |
CA2027031A1 (en) * | 1989-10-18 | 1991-04-19 | Loren A. Haluska | Hermetic substrate coatings in an inert gas atmosphere |
US5145723A (en) * | 1991-06-05 | 1992-09-08 | Dow Corning Corporation | Process for coating a substrate with silica |
JP3174416B2 (en) * | 1992-12-10 | 2001-06-11 | ダウ・コ−ニング・コ−ポレ−ション | Method for forming silicon oxide film |
US5320868A (en) * | 1993-09-13 | 1994-06-14 | Dow Corning Corporation | Method of forming SI-O containing coatings |
-
1997
- 1997-10-22 US US08/955,802 patent/US6020410A/en not_active Expired - Fee Related
- 1997-10-27 AU AU50872/98A patent/AU5087298A/en not_active Abandoned
- 1997-10-27 KR KR10-1999-7003809A patent/KR100512293B1/en not_active IP Right Cessation
- 1997-10-27 CA CA002269952A patent/CA2269952A1/en not_active Abandoned
- 1997-10-27 DE DE69709156T patent/DE69709156T2/en not_active Expired - Fee Related
- 1997-10-27 EP EP97913759A patent/EP0935632B1/en not_active Expired - Lifetime
- 1997-10-27 JP JP52063098A patent/JP2002514238A/en not_active Ceased
- 1997-10-27 WO PCT/US1997/019299 patent/WO1998018850A1/en active IP Right Grant
Patent Citations (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP0479452A2 (en) * | 1990-10-01 | 1992-04-08 | Dow Corning Corporation | Perhydrosiloxane copolymers and their use as coating materials |
EP0503825A1 (en) * | 1991-03-14 | 1992-09-16 | Dow Corning S.A. | Method of making siloxane compositions |
EP0606588A1 (en) * | 1992-12-14 | 1994-07-20 | Dow Corning Toray Silicone Co., Ltd. | Method for the formation of a silicon oxide film |
EP0616001A1 (en) * | 1993-03-19 | 1994-09-21 | Dow Corning Corporation | Stabilization of hydrogen silsesquioxane resin solutions |
JPH07300560A (en) * | 1994-05-02 | 1995-11-14 | Shin Etsu Chem Co Ltd | Silicon composition |
EP0791567A1 (en) * | 1996-02-22 | 1997-08-27 | Dow Corning Corporation | Electronic coating composition |
Non-Patent Citations (1)
Title |
---|
PATENT ABSTRACTS OF JAPAN vol. 096, no. 003 29 March 1996 (1996-03-29) * |
Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO2001029887A1 (en) * | 1999-10-18 | 2001-04-26 | Alliedsignal Inc. | Solvents for processing silsesquioxane and siloxane resins |
US6384119B1 (en) | 2000-06-22 | 2002-05-07 | Basf Corporation | Coating compositions comprising volatile linear siloxane fluids |
Also Published As
Publication number | Publication date |
---|---|
US6020410A (en) | 2000-02-01 |
CA2269952A1 (en) | 1998-05-07 |
EP0935632B1 (en) | 2001-12-12 |
DE69709156D1 (en) | 2002-01-24 |
KR20000052937A (en) | 2000-08-25 |
AU5087298A (en) | 1998-05-22 |
EP0935632A1 (en) | 1999-08-18 |
JP2002514238A (en) | 2002-05-14 |
DE69709156T2 (en) | 2002-08-22 |
KR100512293B1 (en) | 2005-09-05 |
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