WO1997039054B1 - Compositions and methods for manufacturing ettringite coated fibers and aggregates - Google Patents
Compositions and methods for manufacturing ettringite coated fibers and aggregatesInfo
- Publication number
- WO1997039054B1 WO1997039054B1 PCT/US1997/006095 US9706095W WO9739054B1 WO 1997039054 B1 WO1997039054 B1 WO 1997039054B1 US 9706095 W US9706095 W US 9706095W WO 9739054 B1 WO9739054 B1 WO 9739054B1
- Authority
- WO
- WIPO (PCT)
- Prior art keywords
- composite material
- fibers
- mineralized
- ettringite
- mineralized composite
- Prior art date
Links
- 239000000835 fiber Substances 0.000 title claims abstract 32
- 229910001653 ettringite Inorganic materials 0.000 title claims abstract 25
- 239000000203 mixture Substances 0.000 title claims abstract 5
- 238000004519 manufacturing process Methods 0.000 title claims 18
- 239000002131 composite material Substances 0.000 claims abstract 43
- 239000000463 material Substances 0.000 claims abstract 32
- 239000000758 substrate Substances 0.000 claims abstract 24
- 239000000126 substance Substances 0.000 claims abstract 14
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract 14
- 239000000376 reactant Substances 0.000 claims abstract 13
- 239000007900 aqueous suspension Substances 0.000 claims abstract 8
- ODINCKMPIJJUCX-UHFFFAOYSA-N calcium monoxide Chemical compound [Ca]=O ODINCKMPIJJUCX-UHFFFAOYSA-N 0.000 claims abstract 6
- 239000000292 calcium oxide Substances 0.000 claims abstract 3
- PNEYBMLMFCGWSK-UHFFFAOYSA-N AI2O3 Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 claims 3
- 239000000920 calcium hydroxide Substances 0.000 claims 3
- 229910001861 calcium hydroxide Inorganic materials 0.000 claims 3
- 238000002156 mixing Methods 0.000 claims 3
- 239000000725 suspension Substances 0.000 claims 3
- AXCZMVOFGPJBDE-UHFFFAOYSA-L Calcium hydroxide Chemical compound [OH-].[OH-].[Ca+2] AXCZMVOFGPJBDE-UHFFFAOYSA-L 0.000 claims 2
- 229920000049 Carbon (fiber) Polymers 0.000 claims 2
- 229920002522 Wood fibre Polymers 0.000 claims 2
- 229910052925 anhydrite Inorganic materials 0.000 claims 2
- 239000004917 carbon fiber Substances 0.000 claims 2
- 239000000919 ceramic Substances 0.000 claims 2
- 229910052593 corundum Inorganic materials 0.000 claims 2
- 239000002657 fibrous material Substances 0.000 claims 2
- 229910052500 inorganic mineral Inorganic materials 0.000 claims 2
- 239000002184 metal Substances 0.000 claims 2
- 239000011707 mineral Substances 0.000 claims 2
- 229920000620 organic polymer Polymers 0.000 claims 2
- 102000004169 proteins and genes Human genes 0.000 claims 2
- 108090000623 proteins and genes Proteins 0.000 claims 2
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims 2
- 239000002002 slurry Substances 0.000 claims 2
- 229920002994 synthetic fiber Polymers 0.000 claims 2
- 239000002025 wood fiber Substances 0.000 claims 2
- 229910001845 yogo sapphire Inorganic materials 0.000 claims 2
- 235000019738 Limestone Nutrition 0.000 claims 1
- 239000004372 Polyvinyl alcohol Substances 0.000 claims 1
- 229910000831 Steel Inorganic materials 0.000 claims 1
- 239000008346 aqueous phase Substances 0.000 claims 1
- 239000004927 clay Substances 0.000 claims 1
- 229910052570 clay Inorganic materials 0.000 claims 1
- -1 gravel Substances 0.000 claims 1
- 239000006028 limestone Substances 0.000 claims 1
- 229920000747 poly(lactic acid) polymer Polymers 0.000 claims 1
- 239000004626 polylactic acid Substances 0.000 claims 1
- 229920002451 polyvinyl alcohol Polymers 0.000 claims 1
- 239000011435 rock Substances 0.000 claims 1
- 239000004576 sand Substances 0.000 claims 1
- 239000000377 silicon dioxide Substances 0.000 claims 1
- 239000002893 slag Substances 0.000 claims 1
- 239000010959 steel Substances 0.000 claims 1
- 239000000454 talc Substances 0.000 claims 1
- 229910052623 talc Inorganic materials 0.000 claims 1
- 238000005406 washing Methods 0.000 claims 1
- 239000000945 filler Substances 0.000 abstract 5
- DIZPMCHEQGEION-UHFFFAOYSA-H Aluminium sulfate Chemical compound [Al+3].[Al+3].[O-]S([O-])(=O)=O.[O-]S([O-])(=O)=O.[O-]S([O-])(=O)=O DIZPMCHEQGEION-UHFFFAOYSA-H 0.000 abstract 1
- 238000011065 in-situ storage Methods 0.000 abstract 1
- 239000002244 precipitate Substances 0.000 abstract 1
Abstract
Compositions and methods for the deposition of ettringite (3CaO.A12O3.3Ca(SO4).30-32H2O) onto the surfaces of fibers, aggregates, and other fillers. The ettringite is produced in situ within an aqueous suspension while in proximity to the fibers, aggregates, or other fillers to form a mineralized composite material comprising ettringite coated fibers, aggregates or other fillers. Ettringite treated fibers, aggregates, or other fillers are formed by adding chemical reactants such as calcium oxide and aluminum sulfate, which react together in the presence of water to form ettringite, which then precipitates onto the surface of the fibers or other substrates being treated. The ettringite treated fibers, aggregates or other fillers can be added to hydraulically settable materials to improve the chemical and mechanical bond between the fibers or other substrates within the resulting hardened hydraulically settable composite material, particularly a cementitious or concrete material.
Claims
1. A mineralized composite material comprising: a substantially nonreactive substrate material selected from the group consisting of fibers and aggregates; and ettringite formed on at least a portion of a surface of the substrate material.
2. A mineralized composite material as defined in claim 1, wherein the ettringite covers at least about 25% of the surface of the substrate material.
3. A mineralized composite material as defined in claim 1, wherein the ettringite covers at least about 50% of the surface of the substrate material.
4. A mineralized composite material as defined in claim 1, wherein the ettringite covers at least about 75% of the surface of the substrate material.
5. A mineralized composite material as defined in claim 1, wherein the ettringite covers about 100% of the surface of the substrate material.
6. A mineralized composite material as defined in claim 1, wherein the substantially nonreactive substrate material comprises organic fibers.
7. A mineralized composite material as defined in claim 1, wherein the fibers are selected from the group consisting of cellulosic fibers, wood fibers, plant fibers, protein fibers, organic polymer fibers, ceramic fibers, carbon fibers, metal fibers, and mixtures of the foregoing.
8. A mineralized composite material as defined in claim 6, wherein the fibers comprise polyvinyl alcohol fibers.
9. A mineralized composite material as defined in claim 6, wherein the fibers comprise polylactic acid fibers.
10. A mineralized composite material as defined in claim 1, wherein the fibers comprise steel fibers.
11. A mineralized composite material as defined in claim 1, wherein the substantially nonreactive substrate material comprises an aggregate material.
12. A mineralized composite material as defined in claim 11, wherein the aggregate material comprises a naturally occurring mineral material.
13. A mineralized composite material as defined in claim 1 1, wherein the aggregate material comprises a synthetic material.
14. A mineralized composite material as defined in claim 11, wherein the aggregate material is selected from the group consisting of sand, gravel, rocks, limestone, silica, alumina, slags, expanded clay, talc, chalk and shale.
15. A mineralized fibrous composite comprising a fibrous substrate material A mineralized aggregate composite comprising an aggregate substrate material and ettringite formed on at least a portion of a surface of the aggregate substrate material.
16. A method for manufacturing a mineralized composite material comprising the steps of: providing a substantially nonreactive substrate material selected from the group consisting of fibers and aggregates; mixing together the substantially nonreactive substrate material, water, and at least two chemical reactants which form ettringite when combined in the presence of water to form an aqueous suspension, wherein ettringite formed within the aqueous suspension is deposited onto at least a portion of a surface of the substrate material to form the mineralized composite material; and isolating the mineralized composite material from the aqueous suspension.
17. A method for manufacturing a mineralized composite material as defined in claim 17, wherein the at least two chemical reactants which form ettringite when combined in the presence of water include are Ca(OH)2 and A12(S04)3-18H20.
18. A method for manufacturing a mineralized composite material as defined in claim 17, wherein the at least two chemical reactants which form ettringite when combined in the presence of water include 4CaO-3 Al2O3-S03 and 2CaS04-2H20.
19. A method for manufacturing a mineralized composite material as defined in claim 17, wherein the at least two chemical reactants which form ettringite when combined in the presence of water include CaO and 2AINH4(S04)2 12H20.
20. A method for manufacturing a mineralized composite material as defined in claim 17, wherein the at least two chemical reactants which form ettringite when combined in the presence of water include 3CaO Al203 and CaS04.
21. A method for manufacturing a mineralized composite material as defined in claim 17, wherein the substantially nonreactive substrate material comprises a fibrous material.
22. A method for manufacturing a mineralized composite material as defined in claim 22, wherein the fibrous material is selected from the group consisting of cellulosic fibers, wood fibers, plant fibers, protein fibers, organic polymer fibers, ceramic fibers, carbon fibers, and metal fibers.
23. A method for manufacturing a mineralized composite material as defined in claim 17, wherein the substantially nonreactive substrate material comprises an aggregate material. 22
24. A method for manufacturing a mineralized composite material as defined in claim 24, wherein the aggregate material comprises a naturally occurring mineral.
25. A method for manufacturing a mineralized composite material as defined in claim 24, wherein the aggregate material comprises a synthetic material.
26. A method for manufacturing a mineralized composite material as defined in claim 17, wherein the mineralized composite material is isolated from the suspension by draining the aqueous phase from the aqueous suspension.
27. A method for manufacturing a mineralized composite material as defined in claim 17, further comprising the step of washing the mineralized composite material with water.
28. A method for manufacturing a mineralized composite material comprising the steps of: providing a substantially nonreactive substrate material selected from the group consisting of fibers and aggregates; mixing together water, the substantially nonreactive substrate material, and
Ca(OH)2to form an aqueous suspension; combining Al2(SO4)3- 18H20 with the aqueous suspension such that it reacts with the Ca(OH)2 to form ettringite, which is thereby precipitated onto at least a portion of a surface of the substrate material in order to form the mineralized composite material; and isolating the mineralized composite material from the suspension.
29. A method for manufacturing a mineralized composite material comprising the steps of: providing a substantially nonreactive substrate material selected from the group consisting of fibers and aggregates; forming an aqueous slurry by combining water and the nonreactive substrate material; separately blending at least two chemical reactants in a substantially dry form which will form ettringite when combined with water to form a substantially dry blended mixture of the at least two chemical reactants; combining the substantially dry blended mixture of the at least two chemical reactants with the aqueous slurry to form an aqueous suspension, thereby causing the at least two chemical reactants to form ettringite, which is deposited onto at least a portion of a surface of the substrate material to form the mineralized composite material; and 23 isolating the mineralized composite material from the suspension.
30. A method for manufacturing a composite material as defined in claim 30, wherein the at least two chemical reactants which form ettringite when combined in the presence of water are 4CaO-3Al203-S03 and 2CaS04-2H20.
31. A method for manufacturing a composite material as defined in claim 30, wherein the at least two chemical reactants which form ettringite when combined in the presence of water are CaO and 2A1NH4(S04)2 12H20.
32. A method for manufacturing a composite material as defined in claim 30, wherein the at least two chemical reactants which form ettringite when combined in the presence of water are 3CaO Al203 and CaS04.
Priority Applications (5)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| EP97921161A EP0944450A2 (en) | 1996-04-03 | 1997-04-03 | Compositions and methods for manufacturing ettringite coated fibers and aggregates |
| JP53725497A JP2000503732A (en) | 1996-04-03 | 1997-04-03 | Compositions and processes for the production of ettringite-coated fibers and aggregates |
| CA 2248671 CA2248671A1 (en) | 1996-04-03 | 1997-04-03 | Compositions and methods for manufacturing ettringite coated fibers and aggregates |
| BR9708497A BR9708497A (en) | 1996-04-03 | 1997-04-03 | Compositions and processes for the manufacture of fibers and aggregates coated with etringite |
| AU27279/97A AU711512B2 (en) | 1996-04-03 | 1997-04-03 | Compositions and methods for manufacturing ettringite coated fibers and aggregates |
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US08/627,487 US5786080A (en) | 1996-04-03 | 1996-04-03 | Compositions and methods for manufacturing ettringite coated fibers and aggregates |
| US08/627,487 | 1996-04-03 |
Publications (3)
| Publication Number | Publication Date |
|---|---|
| WO1997039054A2 WO1997039054A2 (en) | 1997-10-23 |
| WO1997039054A3 WO1997039054A3 (en) | 1997-11-27 |
| WO1997039054B1 true WO1997039054B1 (en) | 1997-12-24 |
Family
ID=24514845
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| PCT/US1997/006095 WO1997039054A2 (en) | 1996-04-03 | 1997-04-03 | Compositions and methods for manufacturing ettringite coated fibers and aggregates |
Country Status (7)
| Country | Link |
|---|---|
| US (1) | US5786080A (en) |
| EP (1) | EP0944450A2 (en) |
| JP (1) | JP2000503732A (en) |
| KR (1) | KR20000004907A (en) |
| AU (1) | AU711512B2 (en) |
| BR (1) | BR9708497A (en) |
| WO (1) | WO1997039054A2 (en) |
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| US6176915B1 (en) | 1995-04-14 | 2001-01-23 | Standard Starch, L.L.C. | Sorghum meal-based biodegradable formulations, shaped products made therefrom, and methods of making said shaped products |
| US20010048176A1 (en) | 1995-04-14 | 2001-12-06 | Hans G. Franke | Resilient biodegradable packaging materials |
| US6030572A (en) * | 1997-11-26 | 2000-02-29 | Environmentally Engineered Concrete Products, Inc. | Method for making a plastic aggregate |
| US8087921B2 (en) * | 2003-06-27 | 2012-01-03 | Biosphere Holdings Corporation | Extrusion mold and method of use |
| US7481645B2 (en) | 2003-06-27 | 2009-01-27 | Biosphere Industries, Llc | Method for use in baking articles of manufacture and mold for use in said method |
| US8382888B2 (en) * | 2003-08-27 | 2013-02-26 | Biosphere Industries, Llc | Composition for use in edible biodegradable articles and method of use |
| JP2007517919A (en) * | 2003-08-27 | 2007-07-05 | バイオスフィア・インダストリーズ・コーポレイション | Composition for use in biodegradable articles and method of use |
| US7235288B2 (en) * | 2004-03-10 | 2007-06-26 | Johns Manville | Polymeric bonding of glass fiber reinforcements with silane based coatings in gypsum board |
| US20050202227A1 (en) * | 2004-03-10 | 2005-09-15 | Kajander Richard E. | Silane based coatings on glass fiber reinforcements in gypsum board |
| TW200904365A (en) | 2007-07-03 | 2009-02-01 | Biosphere Ind Llc | Biodegradable and compostable composition having improved physical and chemical properties |
| TWI439401B (en) * | 2008-02-19 | 2014-06-01 | Biosphere Ind Llc | Novel packaging article |
| TWI496725B (en) | 2009-01-20 | 2015-08-21 | Chamness Biodegradables Llc | Multi-layer container |
| TWI449742B (en) * | 2009-04-06 | 2014-08-21 | Biosphere Ind Llc | Ecologically friendly composition containing beneficial additives |
| BR112013007418A2 (en) * | 2010-11-30 | 2016-07-12 | Constr Res & Tech Gmbh | hydrated cement products for pulverized concrete |
| US8604123B1 (en) | 2011-07-13 | 2013-12-10 | C-Stone Llc | Biodegradable polymer composition with calcium carbonate and methods and products using same |
| US8881494B2 (en) | 2011-10-11 | 2014-11-11 | Polymer-Wood Technologies, Inc. | Fire rated door core |
| US9867996B2 (en) | 2011-11-16 | 2018-01-16 | Btl Holdings Limited | Methods and systems for skin treatment |
| US9115024B2 (en) * | 2012-02-29 | 2015-08-25 | Macael, Inc. | Radial coal ash based micro-architectures and method of synthesis |
| US9243444B2 (en) | 2012-06-29 | 2016-01-26 | The Intellectual Gorilla Gmbh | Fire rated door |
| US9375899B2 (en) | 2012-06-29 | 2016-06-28 | The Intellectual Gorilla Gmbh | Gypsum composites used in fire resistant building components |
| US8915033B2 (en) | 2012-06-29 | 2014-12-23 | Intellectual Gorilla B.V. | Gypsum composites used in fire resistant building components |
| US9890083B2 (en) | 2013-03-05 | 2018-02-13 | The Intellectual Gorilla Gmbh | Extruded gypsum-based materials |
| US9475732B2 (en) | 2013-04-24 | 2016-10-25 | The Intellectual Gorilla Gmbh | Expanded lightweight aggregate made from glass or pumice |
| CA2909983C (en) | 2013-04-24 | 2019-11-12 | The Intellectual Gorilla Gmbh | Extruded lightweight thermal insulating cement-based materials |
| JPWO2015029096A1 (en) * | 2013-08-26 | 2017-03-02 | 株式会社日立製作所 | Fiber-reinforced composite material and structure using the same |
| EP2842921A1 (en) * | 2013-08-27 | 2015-03-04 | Construction Research & Technology GmbH | Novel fibers, methods for their preparation and use in the manufacture of reinforced elements |
| CN105873878B (en) | 2013-10-17 | 2021-11-02 | 知识产权古里亚有限责任公司 | High temperature lightweight thermal insulating cement and silica based materials |
| WO2015119987A1 (en) | 2014-02-04 | 2015-08-13 | Intellectual Gorilla B.V. | Lightweight thermal insulating cement based materials |
| US11072562B2 (en) | 2014-06-05 | 2021-07-27 | The Intellectual Gorilla Gmbh | Cement-based tile |
| US10538459B2 (en) | 2014-06-05 | 2020-01-21 | The Intellectual Gorilla Gmbh | Extruded cement based materials |
| FR3027898B1 (en) * | 2014-11-04 | 2016-11-04 | Italcementi Spa | HYDRAULIC MIXTURE COMPRISING VEGETABLE GRANULATES AND PROCESS FOR PREPARING CONCRETE OR MORTAR THEREFROM |
| EP3262009A1 (en) | 2015-02-27 | 2018-01-03 | Basf Se | Use of csh-seed modified fibers in oil field applications |
| US9962553B2 (en) | 2015-03-04 | 2018-05-08 | Btl Holdings Limited | Device and method for contactless skin treatment |
| KR102119999B1 (en) * | 2019-01-17 | 2020-06-08 | 건국대학교 산학협력단 | Cement group synthetic fiber with coating layer for material reinforcement, manufacturing method and concrete including thereof |
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|---|---|---|---|---|
| DE1471355A1 (en) * | 1961-07-14 | 1968-12-05 | Ottenholm Tor Axel Ingvar | Process for the production of construction elements from essentially bark and cement, as well as construction element produced according to this process |
| US4255398A (en) * | 1977-03-15 | 1981-03-10 | Hyogo Prefectural Government Of Japan | Novel ettringite whiskers, production and uses |
| JPS54114582A (en) * | 1978-02-28 | 1979-09-06 | Matsushita Electric Works Ltd | Preparation of cemented excelsior board |
| JPS6014685B2 (en) * | 1980-02-05 | 1985-04-15 | 日新工業株式会社 | Method for producing nonflammable coated paper |
| JPS6016851A (en) * | 1983-07-08 | 1985-01-28 | 花王株式会社 | Cement admixing agent |
| DE3403866A1 (en) * | 1984-02-04 | 1985-08-08 | Sicowa Verfahrenstechnik für Baustoffe GmbH & Co KG, 5100 Aachen | METHOD FOR FASTENING A POURABLE PIPE MIX |
| US5223090A (en) * | 1991-03-06 | 1993-06-29 | The United States Of America As Represented By The Secretary Of Agriculture | Method for fiber loading a chemical compound |
| FR2689530B1 (en) * | 1992-04-07 | 1996-12-13 | Aussedat Rey | NEW COMPLEX PRODUCT BASED ON FIBERS AND FILLERS, AND METHOD FOR MANUFACTURING SUCH A NEW PRODUCT. |
| US5545297A (en) * | 1992-08-11 | 1996-08-13 | E. Khashoggi Industries | Methods for continuously placing filaments within hydraulically settable compositions being extruded into articles of manufacture |
-
1996
- 1996-04-03 US US08/627,487 patent/US5786080A/en not_active Expired - Fee Related
-
1997
- 1997-04-03 WO PCT/US1997/006095 patent/WO1997039054A2/en active IP Right Grant
- 1997-04-03 AU AU27279/97A patent/AU711512B2/en not_active Ceased
- 1997-04-03 BR BR9708497A patent/BR9708497A/en not_active Application Discontinuation
- 1997-04-03 KR KR1019980707449A patent/KR20000004907A/en active IP Right Grant
- 1997-04-03 EP EP97921161A patent/EP0944450A2/en not_active Withdrawn
- 1997-04-03 JP JP53725497A patent/JP2000503732A/en active Pending
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