WO1997037835A1 - Materiau de renfort - Google Patents

Materiau de renfort Download PDF

Info

Publication number
WO1997037835A1
WO1997037835A1 PCT/BE1997/000043 BE9700043W WO9737835A1 WO 1997037835 A1 WO1997037835 A1 WO 1997037835A1 BE 9700043 W BE9700043 W BE 9700043W WO 9737835 A1 WO9737835 A1 WO 9737835A1
Authority
WO
WIPO (PCT)
Prior art keywords
reinforcement material
layers
layer
bundles
reinforcement
Prior art date
Application number
PCT/BE1997/000043
Other languages
English (en)
Inventor
Etienne Claeijs
Original Assignee
N.V. Syncoglas S.A.
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by N.V. Syncoglas S.A. filed Critical N.V. Syncoglas S.A.
Priority to EP97916277A priority Critical patent/EP1007336A1/fr
Priority to AU24999/97A priority patent/AU2499997A/en
Publication of WO1997037835A1 publication Critical patent/WO1997037835A1/fr

Links

Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C70/00—Shaping composites, i.e. plastics material comprising reinforcements, fillers or preformed parts, e.g. inserts
    • B29C70/04—Shaping composites, i.e. plastics material comprising reinforcements, fillers or preformed parts, e.g. inserts comprising reinforcements only, e.g. self-reinforcing plastics
    • B29C70/28—Shaping operations therefor
    • B29C70/54—Component parts, details or accessories; Auxiliary operations, e.g. feeding or storage of prepregs or SMC after impregnation or during ageing
    • B29C70/543—Fixing the position or configuration of fibrous reinforcements before or during moulding
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C70/00—Shaping composites, i.e. plastics material comprising reinforcements, fillers or preformed parts, e.g. inserts
    • B29C70/04—Shaping composites, i.e. plastics material comprising reinforcements, fillers or preformed parts, e.g. inserts comprising reinforcements only, e.g. self-reinforcing plastics
    • B29C70/06—Fibrous reinforcements only
    • B29C70/10—Fibrous reinforcements only characterised by the structure of fibrous reinforcements, e.g. hollow fibres
    • B29C70/16—Fibrous reinforcements only characterised by the structure of fibrous reinforcements, e.g. hollow fibres using fibres of substantial or continuous length
    • B29C70/22—Fibrous reinforcements only characterised by the structure of fibrous reinforcements, e.g. hollow fibres using fibres of substantial or continuous length oriented in at least two directions forming a two dimensional structure
    • B29C70/228—Fibrous reinforcements only characterised by the structure of fibrous reinforcements, e.g. hollow fibres using fibres of substantial or continuous length oriented in at least two directions forming a two dimensional structure the structure being stacked in parallel layers with fibres of adjacent layers crossing at substantial angles

Definitions

  • the present invention relates to a reinforcement material, for instance for use as textile reinforcement in composites.
  • Composites can be strengthened using single or multi-layer structures, which structures can be manufac ⁇ tured from different materials.
  • a much used type of reinforcement material is a woven fabric consisting of warp threads and weft threads. These form a right angle to each other. The warp threads therein lie in the 0° direction and the weft threads in the 90° direction.
  • the composites made herewith are however an average of 70% less strong in the +45° and -45° direction. In order to solve this problem different techniques have already been proposed for making products which do strengthen in the +45° and -45° direction.
  • the European patent 0 193 497 describes for instance a woven fabric wherein the warp is a thermoplastic thread or a reinforcement thread coated with thermoplasts. After weaving the weft thread is displaced relative to the warp thread by means of a technique already per se known in the textile industry. The original right angle (90°) between warp and weft is hereby changed, usually into an angle of 45°. Two of these layers, one at an angle of +45° to the warp thread and one at an angle of -45° to the warp thread are subsequently laid on top of one another and then stitched together.
  • Another method is to manufacture webs from a number of parallel running threads or filament bundles, whereafter two such webs wherein the threads run in different directions are fixed to each other by means of knitting or stitching.
  • This method is also per se known and can be performed using the multiaxial machines of the firms Liba and K. Mayer. These known techniques have a number of drawbacks. Reinforcement layers which are stitched together have the drawback that the threads or filament bundles used are damaged by the stitching. At the points where the stitching thread passes through a filament bundle an opening is created (so-called "resin pockets”) . This also occurs when the bundles are knitted to each other. This phenomenon reduces the strength of the end product .
  • Figure 1 shows a reinforcement material manufactured using the above mentioned multiaxial knitting machine, in which the openings in the bundles are clearly visible.
  • Figure 2 Shown in Figure 2 is a reinforcement material manufac- tured according to EP 0 193 497. Herein the resulting openings are even larger.
  • thermoplastic stitching and knitting threads materials are often used for the fixing which are not compatible with the synthetic resin eventually to be used, such as thermoplastic stitching and knitting threads. This also has an adverse effect on the strength and durability of the material. The reinforcement threads are moreover not stretched.
  • a reinforcement material for instance for use in composites, comprising a first layer which at least consists of a plurality of substantially parallel filament bundles and at least one second layer which likewise consists of a plurality of substantially parallel filament bundles, which second layer lies at an angle relative to the first layer of between substantially 60° and 120°, preferably between 70° and 110°, more preferably between 80° and 100°, most preferably of 90°, wherein the first layer and the second layer are mutually adhered by means of an adhesive.
  • the layers which are mutually fixed according to the invention by means of an adhesive can be webs or woven fabrics .
  • the threads are preferably already placed beforehand in a direction differing from the length direction or warp direction at an angle of 30° to 60°, preferably at an angle of substantially 45°.
  • the weft thread will preferably be displaced relative to the warp direction after weaving.
  • thermoplastic or ther osetting powder or a glue e.g. a powder
  • a powder e.g. a powder
  • Adhesion on the basis of a plastic is effected by heating and pressing together the entirety of the layers with the adhesive therebetween so that the plastic melts and both layers mutually adhere.
  • the plastic used can be one on the basis of polyester, epoxy, acrylate and the like.
  • the present invention only a small quantity of powder is used. This is just sufficient to connect the layers in poin -like manner to each other. In preference a maximum of 5% of the surface is thus mutual ⁇ ly adhered. More than 95% of the contact surface of the two layers then remains free of powder.
  • the reinforcement material is malleable and defor able.
  • the biaxial reinfo- rce ent material is supplied to the user on rolls and can afterwards be impregnated with any thermosetting resin such as polyester, epoxy and phenol.
  • one or more of the layers can be sprayed or spread with a glue, for instance a water- dilutable dispersion, two-component glue etc., whereafter the two or more layers are pressed onto each other where ⁇ by they adhere.
  • a glue for instance a water- dilutable dispersion, two-component glue etc.
  • the filament bundles and optional warp threads of which the layers according to the invention consist can be manufactured from any type of material known in the art, but glass fibre, carbon fibre, aramid fibre and the like are recommended. Additional reinforcement materials can optionally be added together with the adhesive, such as for instance chopped threads of the above mentioned materials.
  • the present invention also relates to a method for manufacturing a reinforcement material, wherein the method comprises of : a) manufacturing two or more layers, each at least consisting of a plurality of parallel filament bundles; b) applying an adhesive to the first of the layers; c) laying a second layer on the first layer; d) optionally repeating the steps b) and c) ; and e) causing the layers to adhere to each other.
  • the filament bundles are preferably stretched during adhering.
  • the reinforcement material obtained in this manner has a number of advantages.
  • the reinforcement threads are preferably stretched completely flat and then chemically bonded to each other.
  • the reinforcement material hereby has a high tensile strength, bending strength and elasticity modulus and flat composites with a high content of reinforcement material can be made.
  • the width, angle and weight of the material can be varied as desired. In addition, heavier threads can be used whereby the material can be less expensive.
  • the reinforcement thread is now not damaged by the stitching needle. Because the different layers are mutually adhered the reinforcement material can be punched, cut or otherwise processed without it fraying. The reinforcement material can thus be chopped into small strips.
  • the adhesive powder has the same composition as the synthetic resin with which the composite is manufactured.
  • the adhesive hereby forms an integral part of the end product .
  • the advantage hereof is that no alien materials occur in the laminate, which alien materials can often be the cause of the deterioration in mechanical properties due to capillary penetration of moisture or chemical products.
  • Resin pockets are locations where there is no reinforcement. Such resin pockets can for instance occur when a prior art reinforcement material is used, whereby openings caused by the knitting or stitching needle are created in the filament bundle.
  • a woven fabric was made with 3.5 glass fibres of 68 tex in the warp and 2.4 glass rovings (filament bundles) of 600 tex in the weft. By means of techniques per se known in this field, while stretching the weft threads these are then displaced relative to the warp threads such that an angle of 45° is formed between the two.
  • a second woven fabric with the same composition is laid in reversed position onto the first woven fabric which has been sprayed beforehand with a thermoplastic powder. After heating and pressing together of the two layers there results a multiaxial, chemically bonded reinforcement material in 100% glass.
  • Figure 3 shows a reinforcement material according to the invention to actual size.
  • Figure 4 shows a detail. It is clearly visible that the used filament bundles and warp threads are not damaged. The material is well closed.
  • a web is first made which is bound to a second web according to the same technique. In this manner a biaxial chemically bonded reinforcement material is likewise manufactured.
  • the strength of a biaxial and triaxial reinforcement material according to the invention was determined in comparison to a known material.
  • 0 ° direction contains 50 g/m 2 glass thread 68 Tex +45° direction contains 200 g/m 2 "roving" of parallel threads of 600 Tex -45° direction contains 200 g/m 2 "roving" of parallel threads of 600 Tex 90° direction contains no material
  • the materials were applied as reinforcement material of a polyester laminate. Of this laminate the average bending strength in the 0°, +45°, -45° and 90° direction was determined in accordance with DIN 53452 with 50% by weight of glass. The average values of the four direc ⁇ tions are shown in the following table:
  • Material 1 (according to the invention) Composition:
  • 0° direction contains 400 g/m 2 "roving" of parallel threads of 600 Tex +45° direction contains 200 g/m 2 "roving” of parallel threads of 600 Tex -45° direction contains 200 g/m 2 "roving” of parallel threads of 600 Tex 90° direction contains no material
  • 0° direction contains 400 g/m 2 glass thread 600 Tex +45° direction contains 200 g/m 2 glass thread 320 Tex -45° direction contains 200 g/m 2 glass thread 320 Tex 90° direction contains no material
  • the average bending modulus was determined in 0°, +45°, 45° and 90° direction in accordance with DIN 53457 with 50% by weight of glass. The results are shown in the following table:
  • Tex signifies: a thread of 1 km weighs 1 gram.
  • the rovings were always of the same type and from the same manufacturer.

Landscapes

  • Engineering & Computer Science (AREA)
  • Textile Engineering (AREA)
  • Chemical & Material Sciences (AREA)
  • Composite Materials (AREA)
  • Mechanical Engineering (AREA)
  • Manufacturing Of Multi-Layer Textile Fabrics (AREA)
  • Laminated Bodies (AREA)
  • Woven Fabrics (AREA)

Abstract

L'invention a trait à un matériau de renfort, à utiliser, notamment, dans des composites, constitué d'une première couche elle même constituée d'au moins plusieurs faisceaux de filaments sensiblement parallèles et d'au moins une seconde couche constituée des mêmes faisceaux. Cette seconde couche forme avec la première un angle compris, sensiblement, entre 60 et 120°, de préférence entre 70 et 110°, mieux, entre 80 et 100° et mieux encore, un angle de 90°. La première et la seconde couche adhèrent l'une à l'autre par le moyen d'un adhésif. Les faisceaux de filaments constituent les fils de trame d'un tissu chaîné et tramé ou d'un voile. Cette invention a trait, de surcroît, à un procédé de fabrication du matériau de renfort.
PCT/BE1997/000043 1996-04-09 1997-04-09 Materiau de renfort WO1997037835A1 (fr)

Priority Applications (2)

Application Number Priority Date Filing Date Title
EP97916277A EP1007336A1 (fr) 1996-04-09 1997-04-09 Materiau de renfort
AU24999/97A AU2499997A (en) 1996-04-09 1997-04-09 Reinforcement material

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
NL1002828 1996-04-09
NL1002828A NL1002828C2 (nl) 1996-04-09 1996-04-09 Versterkingsmateriaal.

Publications (1)

Publication Number Publication Date
WO1997037835A1 true WO1997037835A1 (fr) 1997-10-16

Family

ID=19762650

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/BE1997/000043 WO1997037835A1 (fr) 1996-04-09 1997-04-09 Materiau de renfort

Country Status (4)

Country Link
EP (1) EP1007336A1 (fr)
AU (1) AU2499997A (fr)
NL (1) NL1002828C2 (fr)
WO (1) WO1997037835A1 (fr)

Cited By (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP1348791A1 (fr) * 2002-03-07 2003-10-01 Chomarat Composites Complexe de renforcement
EP1350615A1 (fr) * 2002-04-02 2003-10-08 Chomarat Composites Produit de renfort
US6861119B2 (en) 1997-09-18 2005-03-01 Ahlstrom Glassfibre Oy Pressure-loaded panel and use for boat and container construction
FR2864112A1 (fr) * 2003-12-18 2005-06-24 Chomarat Composites Textile tisse, a base de fils de verre, destine a former des renforts pour pieces moulees
US7121161B2 (en) 2003-08-07 2006-10-17 Honda Motor Co. Ltd. Parallel shaft transmission
US7964052B2 (en) 2002-03-08 2011-06-21 Gurit (Uk) Limited Moulding material
US8778479B2 (en) 2003-03-06 2014-07-15 Vestas Wind Systems A/S Pre-form and method of preparing a pre-form

Citations (11)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR359764A (fr) * 1904-11-11 1906-04-04 Francisque Voland Francisque V Machine à biaiser les tissus Machine à biaiser les tissus
US2477407A (en) * 1943-04-22 1949-07-26 Owens Corning Fiberglass Corp Reinforced plastics of increased strength
US3183142A (en) * 1962-04-09 1965-05-11 Minnesota Mining & Mfg Reinforced resinous structural material
US4055697A (en) * 1975-05-19 1977-10-25 Fiberite Corporation Woven material with filling threads at angles other than right angles
EP0033244A2 (fr) * 1980-01-23 1981-08-05 Henry Roy Smith Matières renforcées par des fibres et procédés pour leur fabrication et leur utilisation
EP0193479A1 (fr) * 1985-02-22 1986-09-03 ETABLISSEMENTS LES FILS D'AUGUSTE CHOMARAT & CIE. Société Anonyme Armature textile utilisable pour la réalisation de complexes stratifiés et procédé pour son obtention
EP0330980A2 (fr) * 1988-03-03 1989-09-06 BASF Aktiengesellschaft Fabrication de matériau fibreux préimprégné pour former un objet composite exempt d'espaces vides
US4906506A (en) * 1986-12-16 1990-03-06 Toray Industries, Inc. Preformed material for fiber reinforced plastics
US4992228A (en) * 1989-09-28 1991-02-12 The Dow Chemical Company Method for preparing preforms for molding processes
US5217656A (en) * 1990-07-12 1993-06-08 The C. A. Lawton Company Method for making structural reinforcement preforms including energetic basting of reinforcement members
EP0672776A1 (fr) * 1994-02-24 1995-09-20 ETABLISSEMENT LES FILS D'AUGUSTE CHOMARAT & CIE Armature textile utilisable pour la réalisation de complexes stratifiés

Patent Citations (11)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR359764A (fr) * 1904-11-11 1906-04-04 Francisque Voland Francisque V Machine à biaiser les tissus Machine à biaiser les tissus
US2477407A (en) * 1943-04-22 1949-07-26 Owens Corning Fiberglass Corp Reinforced plastics of increased strength
US3183142A (en) * 1962-04-09 1965-05-11 Minnesota Mining & Mfg Reinforced resinous structural material
US4055697A (en) * 1975-05-19 1977-10-25 Fiberite Corporation Woven material with filling threads at angles other than right angles
EP0033244A2 (fr) * 1980-01-23 1981-08-05 Henry Roy Smith Matières renforcées par des fibres et procédés pour leur fabrication et leur utilisation
EP0193479A1 (fr) * 1985-02-22 1986-09-03 ETABLISSEMENTS LES FILS D'AUGUSTE CHOMARAT & CIE. Société Anonyme Armature textile utilisable pour la réalisation de complexes stratifiés et procédé pour son obtention
US4906506A (en) * 1986-12-16 1990-03-06 Toray Industries, Inc. Preformed material for fiber reinforced plastics
EP0330980A2 (fr) * 1988-03-03 1989-09-06 BASF Aktiengesellschaft Fabrication de matériau fibreux préimprégné pour former un objet composite exempt d'espaces vides
US4992228A (en) * 1989-09-28 1991-02-12 The Dow Chemical Company Method for preparing preforms for molding processes
US5217656A (en) * 1990-07-12 1993-06-08 The C. A. Lawton Company Method for making structural reinforcement preforms including energetic basting of reinforcement members
EP0672776A1 (fr) * 1994-02-24 1995-09-20 ETABLISSEMENT LES FILS D'AUGUSTE CHOMARAT & CIE Armature textile utilisable pour la réalisation de complexes stratifiés

Cited By (12)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US6861119B2 (en) 1997-09-18 2005-03-01 Ahlstrom Glassfibre Oy Pressure-loaded panel and use for boat and container construction
EP1348791A1 (fr) * 2002-03-07 2003-10-01 Chomarat Composites Complexe de renforcement
US7964052B2 (en) 2002-03-08 2011-06-21 Gurit (Uk) Limited Moulding material
US8088470B2 (en) 2002-03-08 2012-01-03 Gurit (Uk) Limited Moulding material
EP1350615A1 (fr) * 2002-04-02 2003-10-08 Chomarat Composites Produit de renfort
US8778479B2 (en) 2003-03-06 2014-07-15 Vestas Wind Systems A/S Pre-form and method of preparing a pre-form
US9180606B2 (en) 2003-03-06 2015-11-10 Vestas Wind Systems A/S Method for preparing pre-form materials
EP1603723B2 (fr) † 2003-03-06 2018-06-27 Vestas Wind Systems A/S Preforme et procede de preparation d'une preforme
US7121161B2 (en) 2003-08-07 2006-10-17 Honda Motor Co. Ltd. Parallel shaft transmission
FR2864112A1 (fr) * 2003-12-18 2005-06-24 Chomarat Composites Textile tisse, a base de fils de verre, destine a former des renforts pour pieces moulees
WO2005061769A1 (fr) * 2003-12-18 2005-07-07 Chomarat Composites Textile tisse, a base de fils de verre, destine a former des renforts pour pieces moulees.
JP2007514876A (ja) * 2003-12-18 2007-06-07 ショマラ・コンポジテ 成形された部材を補強するための繊維ガラスヤーンをベースとする織布

Also Published As

Publication number Publication date
AU2499997A (en) 1997-10-29
NL1002828C2 (nl) 1997-10-14
EP1007336A1 (fr) 2000-06-14

Similar Documents

Publication Publication Date Title
US6355584B1 (en) Complex fabric having layers made from glass fibers and tissue paper
EP0361796B1 (fr) Procédé pour la fabrication d'une matière composite moulable
CA1175332A (fr) Article composite, et methode de fabrication connexe
EP1145841B1 (fr) Méthode de fabrication d'un substrat non-tissé multidirectionnel de fibres de renfort
CA1210683A (fr) Armature non tissee pour articles composites
EP0259612B2 (fr) Matière composite renforçant des membranes de toiture et procédé pour la fabrication de cette matière composite
US4410385A (en) Method of making a composite article
EP0144939A2 (fr) Tissu de base pour renforcement
US20080061464A1 (en) Multi-Layered, Variable-angled, Non-Crimped Fabric for Reinforcement of Composite Materials
US6524980B1 (en) Roofing membranes using composite reinforcement constructions
RU2616667C2 (ru) Сшитый однонаправленный или многоосный армирующий наполнитель и способ его получения
JP5810549B2 (ja) 二方向性強化繊維織物の製造方法
JP3530956B2 (ja) 複合強化原糸を用いた複合材料及びその製造法並びに構造体
WO1997037835A1 (fr) Materiau de renfort
US20030180514A1 (en) Novel strengthening composite
US20110293881A1 (en) Method for producing laid fibre fabrics, and laid fibre fabrics and their use
US20060065352A1 (en) Stabilized fibrous structures and methods for their production
US20070010154A1 (en) Reinforcement material
JPH0129263Y2 (fr)
GB2173828A (en) Stable fabrics
JPH0994900A (ja) 一方向性強化繊維複合基材シート
EP1361949B1 (fr) Composites
JPH043461B2 (fr)
JP4692870B2 (ja) 複合強化原糸を用いた板状の複合材料
CA1185775A (fr) Materiau multicouche de revetement

Legal Events

Date Code Title Description
AK Designated states

Kind code of ref document: A1

Designated state(s): AL AM AT AU AZ BA BB BG BR BY CA CH CN CU CZ DE DK EE ES FI GB GE HU IL IS JP KE KG KP KR KZ LC LK LR LS LT LU LV MD MG MK MN MW MX NO NZ PL PT RO RU SD SE SG SI SK TJ TM TR TT UA UG US UZ VN AM AZ BY KG KZ MD RU TJ TM

AL Designated countries for regional patents

Kind code of ref document: A1

Designated state(s): GH KE LS MW SD SZ UG AT BE CH DE DK ES FI FR GB GR IE IT LU MC NL PT SE BF BJ CF

DFPE Request for preliminary examination filed prior to expiration of 19th month from priority date (pct application filed before 20040101)
121 Ep: the epo has been informed by wipo that ep was designated in this application
WWE Wipo information: entry into national phase

Ref document number: 1997916277

Country of ref document: EP

REG Reference to national code

Ref country code: DE

Ref legal event code: 8642

NENP Non-entry into the national phase

Ref country code: JP

Ref document number: 97520763

Format of ref document f/p: F

NENP Non-entry into the national phase

Ref country code: CA

WWP Wipo information: published in national office

Ref document number: 1997916277

Country of ref document: EP

WWR Wipo information: refused in national office

Ref document number: 1997916277

Country of ref document: EP

WWW Wipo information: withdrawn in national office

Ref document number: 1997916277

Country of ref document: EP