WO1997034570A1 - Hair care compositions - Google Patents
Hair care compositions Download PDFInfo
- Publication number
- WO1997034570A1 WO1997034570A1 PCT/EP1997/001177 EP9701177W WO9734570A1 WO 1997034570 A1 WO1997034570 A1 WO 1997034570A1 EP 9701177 W EP9701177 W EP 9701177W WO 9734570 A1 WO9734570 A1 WO 9734570A1
- Authority
- WO
- WIPO (PCT)
- Prior art keywords
- hair
- weight
- hair care
- silicone
- alkyl
- Prior art date
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- 239000000203 mixture Substances 0.000 title claims abstract description 33
- 229920001296 polysiloxane Polymers 0.000 claims abstract description 20
- 230000003750 conditioning effect Effects 0.000 claims abstract description 14
- CGIHFIDULQUVJG-UHFFFAOYSA-N phytantriol Chemical compound CC(C)CCCC(C)CCCC(C)CCCC(C)(O)C(O)CO CGIHFIDULQUVJG-UHFFFAOYSA-N 0.000 claims abstract description 11
- CGIHFIDULQUVJG-VNTMZGSJSA-N phytantriol Natural products CC(C)CCC[C@H](C)CCC[C@H](C)CCC[C@@](C)(O)[C@H](O)CO CGIHFIDULQUVJG-VNTMZGSJSA-N 0.000 claims abstract description 11
- 150000001875 compounds Chemical class 0.000 claims abstract description 8
- 238000000034 method Methods 0.000 claims abstract description 3
- -1 hydroxypropyl Chemical group 0.000 claims description 19
- 244000007835 Cyamopsis tetragonoloba Species 0.000 claims description 9
- 125000002091 cationic group Chemical group 0.000 claims description 8
- 235000013870 dimethyl polysiloxane Nutrition 0.000 claims description 8
- 229920000435 poly(dimethylsiloxane) Polymers 0.000 claims description 8
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 6
- 229920002907 Guar gum Polymers 0.000 claims description 5
- 229940008099 dimethicone Drugs 0.000 claims description 5
- 239000004205 dimethyl polysiloxane Substances 0.000 claims description 5
- 239000000665 guar gum Substances 0.000 claims description 5
- 229960002154 guar gum Drugs 0.000 claims description 5
- 235000010417 guar gum Nutrition 0.000 claims description 5
- 150000001413 amino acids Chemical class 0.000 claims description 4
- XMSXQFUHVRWGNA-UHFFFAOYSA-N Decamethylcyclopentasiloxane Chemical compound C[Si]1(C)O[Si](C)(C)O[Si](C)(C)O[Si](C)(C)O[Si](C)(C)O1 XMSXQFUHVRWGNA-UHFFFAOYSA-N 0.000 claims description 3
- 229940086555 cyclomethicone Drugs 0.000 claims description 3
- 239000000839 emulsion Substances 0.000 claims description 3
- 150000003839 salts Chemical class 0.000 claims description 3
- 239000002245 particle Substances 0.000 claims description 2
- 239000002453 shampoo Substances 0.000 description 17
- 125000000217 alkyl group Chemical group 0.000 description 9
- 241000282372 Panthera onca Species 0.000 description 8
- 239000000463 material Substances 0.000 description 8
- 239000012530 fluid Substances 0.000 description 6
- 230000003766 combability Effects 0.000 description 5
- 150000002191 fatty alcohols Chemical class 0.000 description 5
- OYINQIKIQCNQOX-UHFFFAOYSA-M 2-hydroxybutyl(trimethyl)azanium;chloride Chemical compound [Cl-].CCC(O)C[N+](C)(C)C OYINQIKIQCNQOX-UHFFFAOYSA-M 0.000 description 4
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 4
- 239000003945 anionic surfactant Substances 0.000 description 4
- 125000004432 carbon atom Chemical group C* 0.000 description 4
- 239000003093 cationic surfactant Substances 0.000 description 4
- 238000009472 formulation Methods 0.000 description 4
- 239000011734 sodium Substances 0.000 description 4
- 229910052708 sodium Inorganic materials 0.000 description 4
- IAYPIBMASNFSPL-UHFFFAOYSA-N Ethylene oxide Chemical compound C1CO1 IAYPIBMASNFSPL-UHFFFAOYSA-N 0.000 description 3
- 102220549062 Low molecular weight phosphotyrosine protein phosphatase_C13S_mutation Human genes 0.000 description 3
- 229910019142 PO4 Inorganic materials 0.000 description 3
- 125000002252 acyl group Chemical group 0.000 description 3
- 239000003795 chemical substances by application Substances 0.000 description 3
- 125000004122 cyclic group Chemical group 0.000 description 3
- 239000000499 gel Substances 0.000 description 3
- 239000004615 ingredient Substances 0.000 description 3
- 239000002736 nonionic surfactant Substances 0.000 description 3
- 239000003921 oil Substances 0.000 description 3
- 235000021317 phosphate Nutrition 0.000 description 3
- 229920001083 polybutene Polymers 0.000 description 3
- 229920002545 silicone oil Polymers 0.000 description 3
- 238000006467 substitution reaction Methods 0.000 description 3
- QTDIEDOANJISNP-UHFFFAOYSA-N 2-dodecoxyethyl hydrogen sulfate Chemical compound CCCCCCCCCCCCOCCOS(O)(=O)=O QTDIEDOANJISNP-UHFFFAOYSA-N 0.000 description 2
- QGZKDVFQNNGYKY-UHFFFAOYSA-O Ammonium Chemical compound [NH4+] QGZKDVFQNNGYKY-UHFFFAOYSA-O 0.000 description 2
- 241000195940 Bryophyta Species 0.000 description 2
- 239000004215 Carbon black (E152) Substances 0.000 description 2
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 2
- 102000011782 Keratins Human genes 0.000 description 2
- 108010076876 Keratins Proteins 0.000 description 2
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 description 2
- 239000000443 aerosol Substances 0.000 description 2
- 150000001298 alcohols Chemical class 0.000 description 2
- BTBJBAZGXNKLQC-UHFFFAOYSA-N ammonium lauryl sulfate Chemical compound [NH4+].CCCCCCCCCCCCOS([O-])(=O)=O BTBJBAZGXNKLQC-UHFFFAOYSA-N 0.000 description 2
- 239000002280 amphoteric surfactant Substances 0.000 description 2
- 235000014113 dietary fatty acids Nutrition 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 239000000194 fatty acid Substances 0.000 description 2
- 229930195729 fatty acid Natural products 0.000 description 2
- 150000004665 fatty acids Chemical class 0.000 description 2
- BXWNKGSJHAJOGX-UHFFFAOYSA-N hexadecan-1-ol Chemical compound CCCCCCCCCCCCCCCCO BXWNKGSJHAJOGX-UHFFFAOYSA-N 0.000 description 2
- 229930195733 hydrocarbon Natural products 0.000 description 2
- 150000002430 hydrocarbons Chemical class 0.000 description 2
- 230000002209 hydrophobic effect Effects 0.000 description 2
- 235000011929 mousse Nutrition 0.000 description 2
- GLDOVTGHNKAZLK-UHFFFAOYSA-N octadecan-1-ol Chemical compound CCCCCCCCCCCCCCCCCCO GLDOVTGHNKAZLK-UHFFFAOYSA-N 0.000 description 2
- 239000000047 product Substances 0.000 description 2
- 210000002374 sebum Anatomy 0.000 description 2
- 239000002689 soil Substances 0.000 description 2
- 239000004094 surface-active agent Substances 0.000 description 2
- QLAJNZSPVITUCQ-UHFFFAOYSA-N 1,3,2-dioxathietane 2,2-dioxide Chemical compound O=S1(=O)OCO1 QLAJNZSPVITUCQ-UHFFFAOYSA-N 0.000 description 1
- DUMAFWZFOOOEPH-UHFFFAOYSA-N 2-[bis(2-hydroxyethyl)amino]ethanol;dodecyl benzenesulfonate Chemical compound OCCN(CCO)CCO.CCCCCCCCCCCCOS(=O)(=O)C1=CC=CC=C1 DUMAFWZFOOOEPH-UHFFFAOYSA-N 0.000 description 1
- BIHQJMSIEXRWPS-UHFFFAOYSA-N 2-[bis(2-hydroxyethyl)amino]ethanol;dodecyl dihydrogen phosphate Chemical compound OCCN(CCO)CCO.CCCCCCCCCCCCOP(O)(O)=O BIHQJMSIEXRWPS-UHFFFAOYSA-N 0.000 description 1
- RFVNOJDQRGSOEL-UHFFFAOYSA-N 2-hydroxyethyl octadecanoate Chemical class CCCCCCCCCCCCCCCCCC(=O)OCCO RFVNOJDQRGSOEL-UHFFFAOYSA-N 0.000 description 1
- VHUUQVKOLVNVRT-UHFFFAOYSA-N Ammonium hydroxide Chemical class [NH4+].[OH-] VHUUQVKOLVNVRT-UHFFFAOYSA-N 0.000 description 1
- KWIUHFFTVRNATP-UHFFFAOYSA-N Betaine Natural products C[N+](C)(C)CC([O-])=O KWIUHFFTVRNATP-UHFFFAOYSA-N 0.000 description 1
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical class OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 1
- FPVVYTCTZKCSOJ-UHFFFAOYSA-N Ethylene glycol distearate Chemical compound CCCCCCCCCCCCCCCCCC(=O)OCCOC(=O)CCCCCCCCCCCCCCCCC FPVVYTCTZKCSOJ-UHFFFAOYSA-N 0.000 description 1
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 description 1
- 241000772415 Neovison vison Species 0.000 description 1
- 239000004721 Polyphenylene oxide Substances 0.000 description 1
- GOOHAUXETOMSMM-UHFFFAOYSA-N Propylene oxide Chemical group CC1CO1 GOOHAUXETOMSMM-UHFFFAOYSA-N 0.000 description 1
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical group [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 description 1
- DBMJMQXJHONAFJ-UHFFFAOYSA-M Sodium laurylsulphate Chemical compound [Na+].CCCCCCCCCCCCOS([O-])(=O)=O DBMJMQXJHONAFJ-UHFFFAOYSA-M 0.000 description 1
- 239000004141 Sodium laurylsulphate Substances 0.000 description 1
- XSTXAVWGXDQKEL-UHFFFAOYSA-N Trichloroethylene Chemical compound ClC=C(Cl)Cl XSTXAVWGXDQKEL-UHFFFAOYSA-N 0.000 description 1
- GSEJCLTVZPLZKY-UHFFFAOYSA-N Triethanolamine Chemical class OCCN(CCO)CCO GSEJCLTVZPLZKY-UHFFFAOYSA-N 0.000 description 1
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 description 1
- 125000001931 aliphatic group Chemical group 0.000 description 1
- 150000003973 alkyl amines Chemical class 0.000 description 1
- 125000002947 alkylene group Chemical group 0.000 description 1
- 235000011114 ammonium hydroxide Nutrition 0.000 description 1
- 125000000129 anionic group Chemical group 0.000 description 1
- 239000003242 anti bacterial agent Substances 0.000 description 1
- 229940027983 antiseptic and disinfectant quaternary ammonium compound Drugs 0.000 description 1
- 239000008346 aqueous phase Substances 0.000 description 1
- ZWXYEWJNBYQXLK-UHFFFAOYSA-N azanium;4-dodecoxy-4-oxo-3-sulfobutanoate Chemical compound [NH4+].CCCCCCCCCCCCOC(=O)C(S(O)(=O)=O)CC([O-])=O ZWXYEWJNBYQXLK-UHFFFAOYSA-N 0.000 description 1
- 229960003237 betaine Drugs 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 239000006172 buffering agent Substances 0.000 description 1
- 229960000541 cetyl alcohol Drugs 0.000 description 1
- 229960001927 cetylpyridinium chloride Drugs 0.000 description 1
- YMKDRGPMQRFJGP-UHFFFAOYSA-M cetylpyridinium chloride Chemical compound [Cl-].CCCCCCCCCCCCCCCC[N+]1=CC=CC=C1 YMKDRGPMQRFJGP-UHFFFAOYSA-M 0.000 description 1
- WOWHHFRSBJGXCM-UHFFFAOYSA-M cetyltrimethylammonium chloride Chemical compound [Cl-].CCCCCCCCCCCCCCCC[N+](C)(C)C WOWHHFRSBJGXCM-UHFFFAOYSA-M 0.000 description 1
- MRUAUOIMASANKQ-UHFFFAOYSA-N cocamidopropyl betaine Chemical compound CCCCCCCCCCCC(=O)NCCC[N+](C)(C)CC([O-])=O MRUAUOIMASANKQ-UHFFFAOYSA-N 0.000 description 1
- 229940073507 cocamidopropyl betaine Drugs 0.000 description 1
- 229940018562 coco monoisopropanolamide Drugs 0.000 description 1
- 239000003086 colorant Substances 0.000 description 1
- 239000007859 condensation product Substances 0.000 description 1
- 229920001577 copolymer Polymers 0.000 description 1
- 239000002537 cosmetic Substances 0.000 description 1
- 230000003247 decreasing effect Effects 0.000 description 1
- REZZEXDLIUJMMS-UHFFFAOYSA-M dimethyldioctadecylammonium chloride Chemical compound [Cl-].CCCCCCCCCCCCCCCCCC[N+](C)(C)CCCCCCCCCCCCCCCCCC REZZEXDLIUJMMS-UHFFFAOYSA-M 0.000 description 1
- KPUWHANPEXNPJT-UHFFFAOYSA-N disiloxane Chemical class [SiH3]O[SiH3] KPUWHANPEXNPJT-UHFFFAOYSA-N 0.000 description 1
- JZKFHQMONDVVNF-UHFFFAOYSA-N dodecyl sulfate;tris(2-hydroxyethyl)azanium Chemical compound OCCN(CCO)CCO.CCCCCCCCCCCCOS(O)(=O)=O JZKFHQMONDVVNF-UHFFFAOYSA-N 0.000 description 1
- SYELZBGXAIXKHU-UHFFFAOYSA-N dodecyldimethylamine N-oxide Chemical compound CCCCCCCCCCCC[N+](C)(C)[O-] SYELZBGXAIXKHU-UHFFFAOYSA-N 0.000 description 1
- 230000009977 dual effect Effects 0.000 description 1
- 239000000975 dye Substances 0.000 description 1
- 230000002708 enhancing effect Effects 0.000 description 1
- 150000002148 esters Chemical class 0.000 description 1
- 239000000284 extract Substances 0.000 description 1
- 239000006260 foam Substances 0.000 description 1
- 150000002306 glutamic acid derivatives Chemical class 0.000 description 1
- 235000012907 honey Nutrition 0.000 description 1
- 230000001771 impaired effect Effects 0.000 description 1
- 230000006872 improvement Effects 0.000 description 1
- 238000010348 incorporation Methods 0.000 description 1
- 229940094506 lauryl betaine Drugs 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 150000004668 long chain fatty acids Chemical class 0.000 description 1
- 239000011777 magnesium Substances 0.000 description 1
- 229910052749 magnesium Inorganic materials 0.000 description 1
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 1
- 239000010445 mica Substances 0.000 description 1
- 229910052618 mica group Inorganic materials 0.000 description 1
- 239000004530 micro-emulsion Substances 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 230000003020 moisturizing effect Effects 0.000 description 1
- DVEKCXOJTLDBFE-UHFFFAOYSA-N n-dodecyl-n,n-dimethylglycinate Chemical compound CCCCCCCCCCCC[N+](C)(C)CC([O-])=O DVEKCXOJTLDBFE-UHFFFAOYSA-N 0.000 description 1
- GOQYKNQRPGWPLP-UHFFFAOYSA-N n-heptadecyl alcohol Natural products CCCCCCCCCCCCCCCCCO GOQYKNQRPGWPLP-UHFFFAOYSA-N 0.000 description 1
- 125000001117 oleyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])/C([H])=C([H])\C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 239000003605 opacifier Substances 0.000 description 1
- 239000002304 perfume Substances 0.000 description 1
- 239000012071 phase Substances 0.000 description 1
- 150000002989 phenols Chemical class 0.000 description 1
- 229950001046 piroctone Drugs 0.000 description 1
- BTSZTGGZJQFALU-UHFFFAOYSA-N piroctone olamine Chemical compound NCCO.CC(C)(C)CC(C)CC1=CC(C)=CC(=O)N1O BTSZTGGZJQFALU-UHFFFAOYSA-N 0.000 description 1
- 229920001921 poly-methyl-phenyl-siloxane Polymers 0.000 description 1
- 229920000570 polyether Polymers 0.000 description 1
- 229920000642 polymer Polymers 0.000 description 1
- 229920005862 polyol Polymers 0.000 description 1
- 150000003077 polyols Chemical class 0.000 description 1
- 239000003755 preservative agent Substances 0.000 description 1
- 230000008569 process Effects 0.000 description 1
- 239000003380 propellant Substances 0.000 description 1
- WHMDPDGBKYUEMW-UHFFFAOYSA-N pyridine-2-thiol Chemical compound SC1=CC=CC=N1 WHMDPDGBKYUEMW-UHFFFAOYSA-N 0.000 description 1
- 150000003856 quaternary ammonium compounds Chemical class 0.000 description 1
- 125000001453 quaternary ammonium group Chemical group 0.000 description 1
- 230000000717 retained effect Effects 0.000 description 1
- 108700004121 sarkosyl Proteins 0.000 description 1
- 229940083542 sodium Drugs 0.000 description 1
- 235000019333 sodium laurylsulphate Nutrition 0.000 description 1
- ADWNFGORSPBALY-UHFFFAOYSA-M sodium;2-[dodecyl(methyl)amino]acetate Chemical compound [Na+].CCCCCCCCCCCCN(C)CC([O-])=O ADWNFGORSPBALY-UHFFFAOYSA-M 0.000 description 1
- HFQQZARZPUDIFP-UHFFFAOYSA-M sodium;2-dodecylbenzenesulfonate Chemical compound [Na+].CCCCCCCCCCCCC1=CC=CC=C1S([O-])(=O)=O HFQQZARZPUDIFP-UHFFFAOYSA-M 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
- 239000007921 spray Substances 0.000 description 1
- SFVFIFLLYFPGHH-UHFFFAOYSA-M stearalkonium chloride Chemical compound [Cl-].CCCCCCCCCCCCCCCCCC[N+](C)(C)CC1=CC=CC=C1 SFVFIFLLYFPGHH-UHFFFAOYSA-M 0.000 description 1
- 125000001424 substituent group Chemical group 0.000 description 1
- KDYFGRWQOYBRFD-UHFFFAOYSA-L succinate(2-) Chemical compound [O-]C(=O)CCC([O-])=O KDYFGRWQOYBRFD-UHFFFAOYSA-L 0.000 description 1
- 125000001273 sulfonato group Chemical group [O-]S(*)(=O)=O 0.000 description 1
- 239000004408 titanium dioxide Substances 0.000 description 1
- 125000003944 tolyl group Chemical group 0.000 description 1
- 239000004034 viscosity adjusting agent Substances 0.000 description 1
- 239000011701 zinc Substances 0.000 description 1
- 229910052725 zinc Inorganic materials 0.000 description 1
- 239000002888 zwitterionic surfactant Substances 0.000 description 1
- 239000004711 α-olefin Substances 0.000 description 1
Classifications
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/33—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing oxygen
- A61K8/34—Alcohols
- A61K8/342—Alcohols having more than seven atoms in an unbroken chain
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
- A61K8/73—Polysaccharides
- A61K8/737—Galactomannans, e.g. guar; Derivatives thereof
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
- A61K8/84—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions otherwise than those involving only carbon-carbon unsaturated bonds
- A61K8/89—Polysiloxanes
- A61K8/891—Polysiloxanes saturated, e.g. dimethicone, phenyl trimethicone, C24-C28 methicone or stearyl dimethicone
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q5/00—Preparations for care of the hair
- A61Q5/02—Preparations for cleaning the hair
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q5/00—Preparations for care of the hair
- A61Q5/06—Preparations for styling the hair, e.g. by temporary shaping or colouring
Definitions
- the invention relates to conditioning and styling hair compositions such as shampoos, styling gels and mousses.
- Rave Plus® shampoo obtains conditioning effects through a combination of a silicone microemulsion with guar
- Stylability is another desirable attribute for a hair product.
- U.S. Patent 5,256,407 achieves this attribute through incorporation of per-alk (en)yl hydrocarbon material, particularly polybutene.
- the highly hydrophobic nature of polybutene unfortunately presents compatibility difficulties and therefore limits its concentration level within a formulation.
- Another object of the present invention is to provide a conditioning hair care composition with stylability features that can be applied to the hair in a single application.
- a hair care composition includes:
- shampoos wherein the silicone is dimethicone and/or cyclomethicone .
- Cationic guar gums such as guar hydroxypropyltrimonium salt promote conditioning effectiveness. Enhanced performance is further achieved with the inclusion of keratin amino acids. DETAILED DESCRIPTION OF THE INVENTION
- Phytantriol as known by its CTFA name is a hydrophobic branched triol chemically identified as 3,7,11,15-tetramethyl-1,2,3- hexadecanetriol. Commercially it is available from Hoffmann- La Roche, Inc., Nutley, New Jersey.
- the amount of phytantriol will range from 0.001 to 1%, preferably from 0.01 to 0.5%, optimally from 0.05 to 0.2% by weight.
- Silicone compounds may be chosen from volatile and non- volatile silicone fluids.
- Volatile silicone fluids are preferably oils chosen from cyclic or linear polydimethyl siloxanes containing from 3 to 9, preferably from 4 to 5 silicon atoms. Cyclomethicone is the most preferred cyclic volatile
- Nonvolatile silicone oils useful for the present invention include polyalkyl siloxanes, polyalkylaryl siloxanes and polyether siloxane copolymers.
- Non-volatile polyalkyl siloxanes useful herein include, for example, polydimethyl siloxanes with viscosities of from 5 to 100,000 centistokes at 25°C.
- the preferred non-volatile silicones are the polydimethyl siloxanes having viscosities from 10 to 400 centistokes at 25°C. These siloxanes are available, for example, from the General Electric Company as SF 1075 methyl phenyl fluid or from Dow Corning as 556 Cosmetic Grade Fluid.
- non-volatile polyalkylaryl siloxane fluids that may be used include, for example, polymethylphenylsiloxanes having viscosities of about 15 to 30,000 centistokes at 25°C.
- dimethicone especially an emulsion of dimethicone dispersed as particles within an aqueous phase.
- the preferred silicone emulsion of this variety is available from the Dow Corning Corporation under the trademark DC 1784.
- oils may range from 0.1 to 10%, preferably from 0.5 to 5%, optimally from 0.8 to 2.5% by weight.
- Cationic guar gum may also be utilized as an adjunct
- CTFA name for a preferred guar gum is guar hydroxypropyltrimonium chloride. This material is available from Rhone-Poulenc under the trademark Jaguar®.
- Illustrative is Jaguar® C13S, having a low degree of
- Suitable varieties are Jaguar® C15, having a moderate degree of substitution and a low viscosity; Jaguar® C17 having a high degree of substitution and a high viscosity; and Jaguar® C16 which is a hydroxypropylated cationic guar derivative containing a low level of substituent groups as well as cationic quaternary ammonium groups. Also suitable is
- Jaguar® 162 which is a high transparency, medium viscosity guar having a low degree of substitution. Especially preferred is Jaguar® C13S.
- Amounts of the cationic guar gum may range from 0.001 to 1%, preferably from 0.05 to 0.5%, optimally from 0.08 to 0.2% by weight.
- Compositions of the present invention will necessarily include a cosmetically acceptable carrier. Generally this carrier will be water. Sometimes the carrier may be a propellant such as a hydrocarbon. Volatile solvents such as lower alcohols (e.g. ethanol) may be used instead of or in addition to water. Amounts of the carrier may range from 1 to 99.9% by weight, preferably from 20 to 99.5%, optimally from 40 to 80% by weight.
- Hair care compositions of this invention are preferably in the form of shampoos but may also be in the form of
- compositions are therefore amenable to liquid, gel and spray (aerosol and non-aerosol) formulations.
- Amino acids may also be included in compositions of the present invention. Keratin type amino acids are available from Croda Inc. under the trademark Crotein HKP. Levels of this material may range from 0.01 to 2%, preferably from 0.1 to 1.5%, optimally from 0.3 to 0.8% by weight.
- compositions in accordance with the present invention when intended as shampoos will comprise one or more surfactants selected from anionic, nonionic, amphoteric, zwitterionic and cationic surfactants and mixtures thereof.
- Suitable anionic surfactants are the alkyl sulphates, alkyl ether sulphates, alkaryl sulphonates, alkyl succinates, alkyl sulphosuccinates, N-alkoyl sarcosinates, alkyl phosphates, alkyl ether phosphates, alkyl ether carboxylates, and ⁇ - olefin sulphonates, especially their sodium, magnesium, ammonium and mono-, di- and tri-ethanolamine salts.
- the alkyl groups generally contain from 8 to 18 carbon atoms and may be unsaturated.
- the alkyl ether sulphates, alkyl ether phosphates and alkyl ether carboxylates may contain from 1 to 10 ethylene oxide or propylene oxide units per molecule, and preferably contain 2 to 3 ethylene oxide units per molecule.
- anionic surfactants examples include sodium oleyl succinate, ammonium lauryl sulphosuccinate, ammonium lauryl sulphate, sodium dodecylbenzene sulphonate, triethanolamine dodecylbenzene sulphonate and sodium N-lauryl sarcosinate.
- the most preferred anionic surfactants are sodium lauryl sulphate, triethanolamine lauryl sulphate, triethanolamine monolauryl phosphate, sodium lauryl ether sulphate 1EO, 2EO and 3EO, ammonium lauryl sulphate and ammonium lauryl ether sulphate 1EO, 2EO and 3EO.
- the nonionic surfactants suitable for use in shampoos of the invention may include condensation products of aliphatic (C ⁇ - C 18 ) primary or secondary linear or branched-chain alcohols or phenols with alkylene oxides, usually ethylene oxide and generally 6-30 EO groups.
- Other suitable nonionic surfactants include mono- or di-alkyl alkanolamides, alkyl polyglucosides and polyhydroxy fatty acid amides (e.g. methyl glucamides). Examples are coco mono- or di-ethanolamide, coco mono-iso-propanolamide, and coco polyglucoside.
- the amphoteric surfactants suitable for use in the invention may include alkyl amine oxides, alkyl betaines, alkyl
- amidopr ⁇ pyl betaines alkyl sulphobetaines, alkyl glycinates, alkyl carboxyglycinates, alkyl amphopropionates, alkyl amidopropyl hydroxysultaines, acyl taurates and acyl
- cationic surfactants include: quaternary ammonium salts, quaternary ammonium salts, and quaternary ammonium salts.
- ammonium hydroxides and salts thereof for example cetyl trimethylammonium chloride, stearyl dimethylbenzylammonium chloride, cetylpyridinium chloride, quaternium-5,-31,-18 and mixtures thereof.
- the level of surfactant materials may range from 1 to 40%, preferably from 2 to 35%, optimally from 5 to 30% by weight of the composition.
- fatty alcohol material Another ingredient that may advantageously be incorporated into the hair care compositions of the invention is a fatty alcohol material.
- fatty alcohol material contains from 8 to 22 carbon atoms, more preferably 16 to 20.
- fatty alcohols examples include cetyl alcohol and stearyl alcohol.
- the level of fatty alcohol material may range from 0.1 to 10%, preferably from 0.5 to 5% by weight of the composition. Also includable are minor amounts of other ingredients commonly found in hair care compositions, such as
- foam boosters perfumes, dyes, coloring agents, preservatives, viscosity modifiers,
- polymers buffering agents, polyols and other moisturizing agents, herb extracts, mink oil or honey.
- Opacifiers or pearlescers may also be formulated into
- compositions of the invention Suitable are ethylene glycol esters of fatty acids having from about 16 to 22 carbon atoms. Preferred are the ethylene glycol stearates, both mono and distearate, but particularly the distearate. Most preferred, however, is titanium dioxide coated mica,
- compositions of the invention in shampoo form are generally applied in an amount of from 1 to 50 mis, preferably from 3 to 5 mis to wet hair. After applying the shampoo the wet hair is worked to create a lather.
- the lather may be
- rinsing e.g. from 1 to 4 minutes
- the treatment may be repeated, if required.
- Formulations illustrative of the present invention are listed under Table I. These Examples represent respectively Normal, Fine, Dry and Permed variations of shampoo.
- conditioner formulations are provided under Table II.
- the Examples respectively represent Normal, Fine, Dry, Permed and Intensive conditioners.
- This Example demonstrates the benefits of phytantriol and silicone oil combinations for improving the conditioning property of wet combing.
- Chemically untreated European brown hair was formed into 6- inch long, 5-gram hair swatches. Each was bleached twice within 48 hours to represent chemically damaged hair. A sample size of 12 swatches was used for each shampoo
- a shampoo base identical to the formula of Example 1 (absent DC 1784, Crotein HKP®, Timiron® MP1001 and Jaguar® C13S) was applied to the hair swatches in a treatment consisting of:
- the instrument is a computer-controlled electromechanical device designed to measure force as a function of applied strain. A hair swatch was suspended from the
- a lower value for "work” indicates an improvement in wet combing, i.e., less effort to comb the hair.
- the standard deviation for all the samples was generally 10%. The results indicate that phytantriol assisted in reducing wet combing work and that increasing its level decreased the work.
- Silicone as shown in Sample 5, also had an effect.
- the combinations of phytantriol and silicone have an
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Abstract
Description
Claims
Priority Applications (6)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
BR9708056A BR9708056A (en) | 1996-03-18 | 1997-03-07 | Composition for hair care and process for conditioning and styling hair |
EP97915356A EP0889712B1 (en) | 1996-03-18 | 1997-03-07 | Hair care compositions |
JP9533099A JP2000507238A (en) | 1996-03-18 | 1997-03-07 | Hair care composition |
AU22872/97A AU2287297A (en) | 1996-03-18 | 1997-03-07 | Hair care compositions |
CA 2246621 CA2246621A1 (en) | 1996-03-18 | 1997-03-07 | Hair care compositions |
DE69715390T DE69715390T2 (en) | 1996-03-18 | 1997-03-07 | HAIR CARE PRODUCTS |
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US08/616,949 US5776443A (en) | 1996-03-18 | 1996-03-18 | Hair care compositions |
US08/616,949 | 1996-03-18 |
Publications (1)
Publication Number | Publication Date |
---|---|
WO1997034570A1 true WO1997034570A1 (en) | 1997-09-25 |
Family
ID=24471660
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
PCT/EP1997/001177 WO1997034570A1 (en) | 1996-03-18 | 1997-03-07 | Hair care compositions |
Country Status (9)
Country | Link |
---|---|
US (1) | US5776443A (en) |
EP (1) | EP0889712B1 (en) |
JP (1) | JP2000507238A (en) |
AR (1) | AR006265A1 (en) |
AU (1) | AU2287297A (en) |
BR (1) | BR9708056A (en) |
DE (1) | DE69715390T2 (en) |
ES (1) | ES2183157T3 (en) |
WO (1) | WO1997034570A1 (en) |
Cited By (1)
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WO2000015181A1 (en) * | 1998-09-15 | 2000-03-23 | Unilever Plc | Hair care compositions comprising ceramide and phytantriol |
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- 1997-03-07 BR BR9708056A patent/BR9708056A/en not_active IP Right Cessation
- 1997-03-07 DE DE69715390T patent/DE69715390T2/en not_active Revoked
- 1997-03-07 EP EP97915356A patent/EP0889712B1/en not_active Revoked
- 1997-03-07 JP JP9533099A patent/JP2000507238A/en not_active Ceased
- 1997-03-07 AU AU22872/97A patent/AU2287297A/en not_active Abandoned
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Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO2000015181A1 (en) * | 1998-09-15 | 2000-03-23 | Unilever Plc | Hair care compositions comprising ceramide and phytantriol |
US6110450A (en) * | 1998-09-15 | 2000-08-29 | Helene Curtis, Inc. | Hair care compositions comprising ceramide |
Also Published As
Publication number | Publication date |
---|---|
US5776443A (en) | 1998-07-07 |
AU2287297A (en) | 1997-10-10 |
ES2183157T3 (en) | 2003-03-16 |
DE69715390T2 (en) | 2003-01-02 |
EP0889712A1 (en) | 1999-01-13 |
EP0889712B1 (en) | 2002-09-11 |
AR006265A1 (en) | 1999-08-11 |
DE69715390D1 (en) | 2002-10-17 |
BR9708056A (en) | 1999-07-27 |
JP2000507238A (en) | 2000-06-13 |
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