WO1997011802A1 - Procede et dispositif pour projeter sur une paroi une boue aqueuse pour former un revetement - Google Patents
Procede et dispositif pour projeter sur une paroi une boue aqueuse pour former un revetement Download PDFInfo
- Publication number
- WO1997011802A1 WO1997011802A1 PCT/FR1996/001520 FR9601520W WO9711802A1 WO 1997011802 A1 WO1997011802 A1 WO 1997011802A1 FR 9601520 W FR9601520 W FR 9601520W WO 9711802 A1 WO9711802 A1 WO 9711802A1
- Authority
- WO
- WIPO (PCT)
- Prior art keywords
- coating
- surfactant
- aqueous mud
- aqueous
- mud
- Prior art date
Links
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B22—CASTING; POWDER METALLURGY
- B22D—CASTING OF METALS; CASTING OF OTHER SUBSTANCES BY THE SAME PROCESSES OR DEVICES
- B22D41/00—Casting melt-holding vessels, e.g. ladles, tundishes, cups or the like
- B22D41/02—Linings
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F27—FURNACES; KILNS; OVENS; RETORTS
- F27D—DETAILS OR ACCESSORIES OF FURNACES, KILNS, OVENS, OR RETORTS, IN SO FAR AS THEY ARE OF KINDS OCCURRING IN MORE THAN ONE KIND OF FURNACE
- F27D1/00—Casings; Linings; Walls; Roofs
- F27D1/16—Making or repairing linings increasing the durability of linings or breaking away linings
- F27D1/1636—Repairing linings by projecting or spraying refractory materials on the lining
- F27D1/1642—Repairing linings by projecting or spraying refractory materials on the lining using a gunning apparatus
Definitions
- the present invention relates to a method for spraying an aqueous slurry onto a wall to form a coating, this aqueous slurry being prepared from a dry composition comprising inorganic particles, optionally a compound acting as a surfactant and a binder.
- the invention also relates to a device for implementing the above method.
- the invention further relates to a protective coating deposited on a wall by the implementation of the above method and / or device.
- a composition for producing a coating to protect the interior of a metallurgical container such as a tundish can be applied by spraying in the form of aqueous mud, using a suitable device.
- Such a coating has a substantially constant porosity. Its properties can therefore only be modified by modifying the composition of the corresponding aqueous mud.
- EP-A-0 180 491 a method for repairing the coating of a metallurgical container by gunning through a flame: this method consists in spraying two successive layers having respectively, the first a porosity of 15 to 25 %, the second a minimum bulk density of 3.1 kg / dm, using a unique composition and varying the specific power of gunning. This process is extremely expensive to use.
- the object of the present invention is to remedy the drawbacks of known methods and devices, and to propose a method and a device of the aforementioned type providing a satisfactory solution to the above problem.
- said predetermined dry composition is kneaded with water, if necessary added with surfactant, to prepare the aqueous slurry, then said aqueous slurry is pumped through a pipe to a nozzle in which is injected with pressurized air to project said aqueous mud.
- this process is characterized in that said aqueous slurry is mechanically stirred to foam and / or swell the surfactant, and in that the power and / or the speed and / or the time d stirring to foam and / or swell more or less strongly the surfactant in order to vary the porosity of the sprayed coating.
- the coating By giving the coating a variable porosity, it is possible to modify the properties of this coating starting from a single composition.
- the porosity of the coating can vary in the direction of its thickness.
- the insulating power and the sinterability of the coating vary according to its thickness.
- the coating can also have one or more zones where its porosity is below average, ie where the coating is denser and therefore has a higher sinterability and resistance to stresses than elsewhere.
- composition and the particle size of the inorganic particles may be the same throughout the coating.
- the porosity is greater in the part of the coating close to the wall of the metallurgical container, which in particular makes it possible to avoid sintering and the adhesion of the coating to this wall.
- the thermal insulation characteristic and the mechanical resistance characteristic can be varied in opposite directions by varying the porosity of this coating.
- water is added with surfactant to increase the porosity of the sprayed coating.
- air is injected under pressure to facilitate the foaming of the surfactant during the stirring step.
- the aqueous mud is mechanically agitated before pumping it.
- the pressure of the air injected into the nozzle is varied to project the aqueous mud.
- the device for implementing the aforementioned method according to the invention comprises a hopper for loading a dry composition containing inorganic particles, where appropriate a compound acting as a surfactant and a binder, the lower part of this hopper communicating with metering means opening into an elongated chamber comprising a rotary mixer, a water injection pipe opening into said elongated chamber, preferably before the mixer, the end of this chamber opposite the hopper comprising an outlet opening opening into a pump connected to a tube, the end of which comprises a spray nozzle into which opens a compressed air pipe,
- this device is characterized in that it includes stirring means for mechanically stirring said aqueous mud in order to foam and / or swell the surfactant, and means for adjusting the power and / or the speed and / or the stirring time.
- the predetermined dry composition of particles contained in the hopper can be added with dry surfactant, which will foam later under the effect of mechanical agitation.
- the device may also include a reservoir containing water with added surfactant connected to a tube opening into the chamber, preferably before the mixer.
- said aqueous mud is mechanically stirred to foam and / or swell the surfactant contained in the mixture.
- the reservoir containing water with added surfactant is placed in communication with said chamber and the aqueous mud is mechanically agitated to make foam and / or swell the surfactant introduced into the mixture.
- the power and / or the speed and / or the stirring time are adjusted to foam and / or swell the surfactant more or less.
- the protective coating of the aforementioned type is characterized in that it was obtained by the implementation of the method and / or the device according to the invention, and in that it has porosity varying from place to place other of this coating and / or in the direction of the thickness thereof.
- Figure 1 is a partial longitudinal sectional view of a flow distributor having an inner coating according to one invention
- Figures 2 and 3 are views similar to Figure 1 relating to other coatings obtainable according to the invention.
- FIG. 4 is a schematic sectional view of a structure coated with a protective coating according to another embodiment of the present invention.
- FIG. 5 is a schematic sectional view of an embodiment of the device for applying a coating according to one invention.
- Figure 6 is a schematic view similar to Figure 5, concerning a variant of the device
- FIG. 7 is a partial schematic view similar to Figure 5 of the downstream part of a device according to another embodiment of the invention
- - Figure 8 is a schematic view similar to Figure 5 of a device according to another embodiment of the invention.
- the distributor used for the continuous casting for example of liquid steel, comprises an external metal mantle 1 internally lined with a permanent coating 2 made of refractory bricks or cement.
- a consumable coating 3 based on inorganic particles such as for example silica, and / or alumina and / or magnesia, optionally coated in a binder, with if necessary a surfactant.
- the coating 3 can for example have the following weight composition:
- Plasticizer 0 to 5%
- Fibers 0 to 5%
- Binder 0 to 18%
- Carbonaceous matter 0 to 8%
- a coating 3 which usually exhibits, after drying , a natural porosity such that its density is between 1.5 and 1.8 Kg / dm ' approximately.
- a coating obtained from a composition comprising approximately 75% of MgO has, after drying, a density of approximately 1.65
- the composition and the particle size of the inorganic particles are chosen so that this coating, sprayed normally, can sinter on contact with the liquid metal in a manner sufficient to resist the erosion of the liquid metal.
- the aqueous slurry is mechanically stirred to lather and / or swell the surfactant and the power and / or the speed and / or the stirring time are adjusted to lather and / or swell the surfactant more or less strongly in order to vary the porosity of the sprayed coating.
- the surfactant can be made to foam by mechanical agitation of the aqueous mud so as to obtain a more porous coating having, after spraying and drying, a density of between 1 and 1.5 , for example equal to 1.2 or 1.3.
- a coating having a porosity and a density variable from one place to another of this coating and / or in the direction of the thickness thereof.
- this coating is sprayed in such a way that in the region of the coating close to the wall of the container, the porosity is high enough so that the inorganic particles cannot sinter or only partially sinter under the action of the heat of the liquid metal, while in the coating area adjacent to the interior of the container, the porosity is low enough that the inorganic particles can sinter under the action of the heat of the liquid metal, sufficient to resist erosion of the liquid metal.
- the porosity of the coating 3 varies in the direction of its thickness: it gradually decreases from the permanent refractory coating 2 towards the inside of the tundish. In other words, the coating 3 becomes increasingly dense towards its interior surface which is intended to come into contact with the liquid metal.
- the coating 3 Due to the fact that the coating 3 is denser, that is to say less porous, near its surface intended to come into contact with the liquid metal, the coating has in this zone a greater aptitude for sintering, which is important. to form an impermeable barrier to the passage of liquid metal through the coating.
- the coating near the surface of the permanent coating 2, because of its greater porosity, the ability of the coating to sinter is lower or even zero, so that any risk of adhesion of the coating 3 to the permanent coating 2 is avoided. .
- the greater porosity makes it possible to obtain good thermal insulation avoiding too rapid cooling of the liquid metal.
- the coating has in certain places zones 4,
- zones 4, 5 and 6 the density of the coating is higher than elsewhere. Zones 4, 5 and 6 correspond to places where the coating is subjected to particular constraints.
- Zone 4 corresponds to the impact zone and the vicinity of the jet of liquid metal which is poured into the tundish from the tundish.
- the higher density 1.6 to 1.8, instead of 1.3 to 1.5 in the rest of the coating, in this zone 4 allows it to better resist the impact above.
- Zone 5 is adjacent to the upper level of the liquid metal.
- the higher density of the coating in this area allows it to better resist the slag that forms on the surface of the liquid metal.
- the zone 6 of higher density surrounds the pouring orifice 6a, at the bottom of the casting distributor. This higher density gives the coating greater resistance to turbulence generated in the liquid metal near the pouring orifice.
- Such a coating can be at will a protective coating against heat and / or fire, a thermal insulation coating, a sound insulation coating and / or acoustic correction.
- a sound insulation and / or acoustic correction coating it is likewise possible, from a single dry composition, to form a coating comprising a more porous and lighter layer, adapted to attenuate the high sounds , and a less porous and denser layer, better suited than the previous one to attenuate the bass sounds. All these compositions are known in themselves and need not be explained here.
- compositions for forming these coatings are mainly based on inorganic particles, where appropriate refractory particles. However, most often nothing prevents the incorporation into these compositions of organic particles usually used in such coatings.
- FIG. 5 shows a device according to the invention for spraying an aqueous mud on a wall to form a coating.
- This device is particularly suitable for applying the coating 3 inside the tundish. It includes a loading hopper 26 containing a dry composition of inorganic particles, binder and dry surfactants.
- the lower part of this hopper 26 opens at one end of an elongated chamber 7 comprising a rotary Archimedes screw 8, for dosing the dry composition, followed by a rotary mixer 9.
- the end of the chamber 7 opposed to the hopper 26 opens out above a funnel 10 feeding a pump 11 of the sparrow type.
- the latter is connected to a tube 12, the end of which comprises a projection nozzle 13 into which a pipe 14 of compressed air opens.
- the pressure of the compressed air in the pipe 14 can be adjusted by means of a valve 14a.
- a water injection pipe 15 opens into the elongated chamber 7 substantially between the Archimedes screw 8 and the mixer 9, to bring the water necessary for wetting the composition and for the preparation of the aqueous mud.
- the tubing 12 comprises between the funnel 10 and the pump 11 a member 25 adapted to mechanically stir the aqueous sludge leaving the funnel 10 to foam and / or swell the surfactant.
- the member 25 is shown by way of example in the form of a shaft 40 carrying blades 41 and rotating inside a casing 42 under the action of a motor shown diagrammatically at 43.
- the motor 43 is associated with means, shown diagrammatically at 44, for regulating the power and / or the speed and / or the mechanical agitation time of the aqueous mud.
- the means 44 are constituted, for example, by means for varying the power and / or the speed and / or the rotation time of an electric motor 43, or by a mechanical variator, interposed between the member 25 and the motor 43, of any type. Such means are known in themselves.
- the member 25 shown diagrammatically in the form of a rotary shaft 40 with blades 41 can be replaced by any known mechanical agitation device suitable for foaming and / or swelling a surfactant, the mechanical agitation movement being for example a translation and / or vibration movement.
- the funnel 10 is mounted so as to directly feed the pump 11.
- a stirring member 35 constituted for example by a tank 36 inside which a cylindrical cage 37 with peripheral bars 38 rotates around the axis 39 under the action of 'an engine not shown.
- the member 35 is adapted to operate discontinuously, so as to stir for a predetermined period of time, for example several minutes, a predetermined load of aqueous mud.
- the latter After foaming of the surfactant and swelling of the mud, the latter is poured into the funnel 10 for pumping.
- the funnel 45 receives the aqueous mud from the mixer 9 and directly feeds the pump 11.
- the funnel 45 has a capacity at least equal to the flow rate of the pump 11 during this period.
- the funnel 45 comprises one or more of the following types of known stirring means, adapted to be actuated independently of each other:
- external stirring means 49 shown diagrammatically by a propeller driven by a shaft, plunging into the aqueous mud to stir it, and actuated on demand by a motor not shown.
- a scraper 33 (half-view from the left) adapted to scrape the inner wall of said funnel 10 or with a stirrer 34 with blades 34a (half right view).
- the scraper 33 and the agitator 34 can be mounted as desired on the shaft of the rotor of the pump 11 or be actuated by a particular motor means, at constant or variable speed, not re-represented.
- the mixing and stirring of the aqueous mud can thus be carried out between the preparation of the mud and the pumping thereof, either continuously or discontinuously, the transit of the mud being able to be interrupted to allow mixing to be obtained and stirring the desired swelling of the mud before pumping it.
- the agitation member 24, 45 is dimensioned and driven so as to communicate for a predetermined duration a predetermined amount of agitation energy so as to obtain the foaming of the surfactant and the swelling of the aqueous mud sought.
- the device represented in FIG. 8 comprises, like that of FIG. 5, a hopper 26, a screw 8, a mixer 9. It comprises a reservoir 18 containing water with the addition of a surfactant (of any known type , for example of the genus Teepol® or based on proteins) and connected to a tube 19 and to a pump 19a opening into the chamber 7 substantially between the Archimedes screw 8 and the mixer 9, the pipe 15 being a supply from the fountain water.
- a surfactant of any known type , for example of the genus Teepol® or based on proteins
- the dry composition present in the hopper 26 may not contain a surfactant or may contain only a weak amount of surfactant insufficient to obtain the desired foaming and swelling effect.
- the mixer 9 which can also be an agitator of any known type (not shown), is driven by means shown schematically in 9a adapted to communicate to it a variable mixing and stirring energy.
- the means 9a can be a variable speed motor or a speed variator or a time delay which makes it possible to adjust the agitation time.
- the stirring member 25 described above is placed between the pump 11 and the spray nozzle 13.
- a pipe 16 makes it possible to introduce inside the stirring member 25 of the air at an appropriate pressure to facilitate foaming of the surfactant.
- the device shown in Figure 5 operates as follows.
- the Archimedes screw 8 propels the dry composition towards the mixer 9.
- the composition is moistened by the water injected through the tube 15 and is transformed into mud which is kneaded by the mixer 9.
- the rotation blades 41 of the mechanical stirring member 25 lather the surfactant: this has the effect of swelling the aqueous mud.
- the aqueous slurry is then poured into the pump 11 which sends it into the tube 12, at the end of which it is projected by the nozzle 13.
- the devices of FIGS. 6 and 7 work in substantially the same way. In the case of the device according to FIG. 8, the water and surfactant mixture is introduced into chamber 7. Therefore, thanks to the mechanical stirring by the device 25, the surfactant is made to foam and a sparse and porous composition is produced.
- the coating 3 shown in FIG. 1 can be obtained in which the porosity gradually decreases from the outside towards the inside of the casting container to reach its minimum value in the inner layer suitable for coming into contact with the liquid metal.
- the projection of the coating is advantageously carried out by means of a robot carrying the projection lance 13.
- a coating whose porosity varies in the direction of its thickness or depending on the location can be obtained automatically, by controlling the robot using a preprogrammed computer capable of acting on the porosity of the coating as indicated above.
- the porosity of the coating can not only vary in the direction of the thickness of the coating but also anywhere in the coating.
- the inorganic particles can be present in any form.
- the silica can be present, for example, in the form of diatoms or of fossil silica, or in the light form of microporous silica, or in the form of analogous products, for example rice ash, or in the form of silicates of metals such as sodium, aluminum or magnesium: aluminum silicate can be, for example ">->->
- sodium silicate can be expanded glass.
- Calcium silicate is also an effective lightening product.
- the organic particles can be, for example, cellulose, pulp, sawdust or particles of synthetic materials.
- the dry composition used in the invention almost always comprises, in addition to inorganic particles, a minimum content of surfactant to ensure good wetting of the constituents with water to form the aqueous mud, and a minimum content of binder to allow good adhesion of the coating projected on the wall.
- the surfactant and the binder could of course be removed if the inorganic particles constituting the composition exhibited by themselves excellent wettability with water and an excellent ability to cling to the wall to be protected.
- certain compounds acting as surfactant for example based on proteins, can have a binding effect in addition to their action on surface tension
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- Engineering & Computer Science (AREA)
- Mechanical Engineering (AREA)
- General Engineering & Computer Science (AREA)
- Application Of Or Painting With Fluid Materials (AREA)
- Paints Or Removers (AREA)
- On-Site Construction Work That Accompanies The Preparation And Application Of Concrete (AREA)
Abstract
Description
Claims
Priority Applications (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
DE69602541T DE69602541D1 (de) | 1995-09-27 | 1996-09-27 | Verfahren und vorrichtung zum spritzen einer wässrigen masse auf eine wand zu deren beschichtung |
EP96932672A EP0852524B1 (fr) | 1995-09-27 | 1996-09-27 | Procede et dispositif pour projeter sur une paroi une boue aqueuse pour former un revetement |
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
FR95/11334 | 1995-09-27 | ||
FR9511334A FR2739039B1 (fr) | 1995-09-27 | 1995-09-27 | Procede et dispositif pour projeter sur une paroi une boue aqueuse pour former un revetement, et revetement ainsi obtenu |
Publications (1)
Publication Number | Publication Date |
---|---|
WO1997011802A1 true WO1997011802A1 (fr) | 1997-04-03 |
Family
ID=9482970
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
PCT/FR1996/001520 WO1997011802A1 (fr) | 1995-09-27 | 1996-09-27 | Procede et dispositif pour projeter sur une paroi une boue aqueuse pour former un revetement |
Country Status (7)
Country | Link |
---|---|
EP (1) | EP0852524B1 (fr) |
CN (1) | CN1200686A (fr) |
AT (1) | ATE180192T1 (fr) |
CA (1) | CA2232984A1 (fr) |
DE (1) | DE69602541D1 (fr) |
FR (1) | FR2739039B1 (fr) |
WO (1) | WO1997011802A1 (fr) |
Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP2011025245A (ja) * | 2002-10-16 | 2011-02-10 | Solvay (Sa) | スラッジの処理方法 |
WO2021110967A1 (fr) | 2019-12-06 | 2021-06-10 | Vesuvius U S A Corporation | Procédé et appareil pour la production par lots et l'application continue d'une composition réfractaire sur une surface |
Families Citing this family (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN102322741A (zh) * | 2011-08-08 | 2012-01-18 | 北京联合荣大工程材料有限责任公司 | 一种遥控转炉湿法喷补工艺方法及装置 |
Citations (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO1995025610A1 (fr) * | 1994-03-23 | 1995-09-28 | Daussan Et Compagnie | Procede et dispositif pour projeter sur une paroi une boue aqueuse pour former un revetement, et revetement ainsi obtenu |
-
1995
- 1995-09-27 FR FR9511334A patent/FR2739039B1/fr not_active Expired - Fee Related
-
1996
- 1996-09-27 DE DE69602541T patent/DE69602541D1/de not_active Expired - Lifetime
- 1996-09-27 CN CN96197907.0A patent/CN1200686A/zh active Pending
- 1996-09-27 AT AT96932672T patent/ATE180192T1/de active
- 1996-09-27 CA CA002232984A patent/CA2232984A1/fr not_active Abandoned
- 1996-09-27 WO PCT/FR1996/001520 patent/WO1997011802A1/fr active IP Right Grant
- 1996-09-27 EP EP96932672A patent/EP0852524B1/fr not_active Expired - Lifetime
Patent Citations (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO1995025610A1 (fr) * | 1994-03-23 | 1995-09-28 | Daussan Et Compagnie | Procede et dispositif pour projeter sur une paroi une boue aqueuse pour former un revetement, et revetement ainsi obtenu |
Cited By (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP2011025245A (ja) * | 2002-10-16 | 2011-02-10 | Solvay (Sa) | スラッジの処理方法 |
WO2021110967A1 (fr) | 2019-12-06 | 2021-06-10 | Vesuvius U S A Corporation | Procédé et appareil pour la production par lots et l'application continue d'une composition réfractaire sur une surface |
US11759855B2 (en) | 2019-12-06 | 2023-09-19 | Vesuvius Usa Corporation | Method and apparatus for batch production of, and continuous application of, a refractory composition to a surface |
Also Published As
Publication number | Publication date |
---|---|
CA2232984A1 (fr) | 1997-04-03 |
DE69602541D1 (de) | 1999-06-24 |
FR2739039B1 (fr) | 1998-04-17 |
EP0852524A1 (fr) | 1998-07-15 |
EP0852524B1 (fr) | 1999-05-19 |
FR2739039A1 (fr) | 1997-03-28 |
CN1200686A (zh) | 1998-12-02 |
ATE180192T1 (de) | 1999-06-15 |
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