WO1997005323A1 - Device to promote reuse of office laser-print paper - Google Patents

Device to promote reuse of office laser-print paper Download PDF

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Publication number
WO1997005323A1
WO1997005323A1 PCT/US1995/009747 US9509747W WO9705323A1 WO 1997005323 A1 WO1997005323 A1 WO 1997005323A1 US 9509747 W US9509747 W US 9509747W WO 9705323 A1 WO9705323 A1 WO 9705323A1
Authority
WO
WIPO (PCT)
Prior art keywords
paper
adhesion
ink
specified
roll
Prior art date
Application number
PCT/US1995/009747
Other languages
French (fr)
Inventor
Richard B. Buie
Original Assignee
Buie Richard B
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Buie Richard B filed Critical Buie Richard B
Priority to PCT/US1995/009747 priority Critical patent/WO1997005323A1/en
Priority to AU32087/95A priority patent/AU3208795A/en
Publication of WO1997005323A1 publication Critical patent/WO1997005323A1/en

Links

Classifications

    • GPHYSICS
    • G03PHOTOGRAPHY; CINEMATOGRAPHY; ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ELECTROGRAPHY; HOLOGRAPHY
    • G03GELECTROGRAPHY; ELECTROPHOTOGRAPHY; MAGNETOGRAPHY
    • G03G21/00Arrangements not provided for by groups G03G13/00 - G03G19/00, e.g. cleaning, elimination of residual charge
    • DTEXTILES; PAPER
    • D21PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21BFIBROUS RAW MATERIALS OR THEIR MECHANICAL TREATMENT
    • D21B1/00Fibrous raw materials or their mechanical treatment
    • D21B1/04Fibrous raw materials or their mechanical treatment by dividing raw materials into small particles, e.g. fibres
    • D21B1/12Fibrous raw materials or their mechanical treatment by dividing raw materials into small particles, e.g. fibres by wet methods, by the use of steam
    • D21B1/30Defibrating by other means
    • D21B1/32Defibrating by other means of waste paper
    • D21B1/325Defibrating by other means of waste paper de-inking devices
    • DTEXTILES; PAPER
    • D21PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21CPRODUCTION OF CELLULOSE BY REMOVING NON-CELLULOSE SUBSTANCES FROM CELLULOSE-CONTAINING MATERIALS; REGENERATION OF PULPING LIQUORS; APPARATUS THEREFOR
    • D21C5/00Other processes for obtaining cellulose, e.g. cooking cotton linters ; Processes characterised by the choice of cellulose-containing starting materials
    • D21C5/02Working-up waste paper
    • D21C5/025De-inking
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02WCLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO WASTEWATER TREATMENT OR WASTE MANAGEMENT
    • Y02W30/00Technologies for solid waste management
    • Y02W30/50Reuse, recycling or recovery technologies
    • Y02W30/64Paper recycling

Definitions

  • the various types of toners are thermosetting plastic resins with carbon black and other minor constituents to control flow properties, electrical and magnetic properties or other characteristics. This toner is "set” onto the paper by using heat to melt the plastic powder into a solid film adhering to the paper surface.
  • the current invention provides a method of loosening this toner- paper adhesion and lifting the toner back off of the paper so that the paper can be reused.
  • This stream of laser-print wastepaper contains very high quality, bleached cellulose fibers derived from chemically pulping wood chips. To produce such high quality papers it typically requires four tons of green wood to produce one ton of paper. Unfortunately the toner has been found to be very tenacious in its adhesion to the fiber in conventional recycling and deinking processes, and even when detached during conventional recycling the ink particles are large and difficult to separate from the pulp slurry. These deinking processes function in the wet state after the paper has been broken down into individual fibers by mechanical action in large repulper devices. This type of process is only performed at large paper manufacturing sites, and is not suitable for office environments.
  • the current invention allows reprocessing of quantities of office papers in a dry state, such that offices could reuse the paper and reduce the quantity of paper purchased. This would have several advantages. First, it avoids shipping of quantities of new or recycled paper to the office and of wastepaper or municipal solid waste away from the office. Reuse of one pound of such office paper would eliminate purchase and shipping of one pound of paper to the office and simultaneously eliminate one pound of wastepaper or office waste emanating from the office.
  • the process uses a softening and lifting off technique which reduces the adhesion of the ink film to the paper sheet.
  • This liftoff process is not sensitive to the ink particle size, and thus the two problems encountered with conventional deinking, namely strong adhesion and large, tough ink particles, are avoided with the dry process proposed here.
  • the process does not require a solvent or solvent recovery process such as other printing removal processes (Mitsubishi Electric Corp., JP04327299).
  • the laser-print paper would be collected in a segregated bin or reprocessed immediately in the case of errors or overruns.
  • staples must first be removed and the paper should be jogged to align the edges. This can be done as separate operations or by add-ons of stages of conventional office equipment to the basic configuration.
  • the first step in the ink removal process is to feed the sheet of paper into the machine and press it into contact with an adhesion roll. Heat and pressure are applied to smooth out creases, flatten the paper, soften the thermosetting ink film, reduce adhesion to the paper, and improve adhesion to the adhesion roll. After adhesion of ink to the roll, the paper sheet is peeled away leaving the toner fused to the adhesion roll. This roll is then cleaned of fused ink and made ready for the next sheet.
  • the paper sheet After peeling the paper sheet from the adhesion roll, the paper sheet is then reconditioned by rehumidification and calendering to reduce curl and roughness, followed by optical inspection and ejection to an accept or reject output bin.
  • the optical inspection can be performed by photo detectors such that an excessive amount of holes or residual ink will result in rejection of the individual sheet. These reject sheets can be used for lower quality purposes or sent to a conventional paper recycling process.

Landscapes

  • Engineering & Computer Science (AREA)
  • Physics & Mathematics (AREA)
  • General Physics & Mathematics (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Wood Science & Technology (AREA)
  • Mechanical Engineering (AREA)
  • Cleaning In Electrography (AREA)
  • Paper (AREA)

Abstract

A device for removing ink from laser print paper comprising an adhesion roller or belt for heating and applying pressure on the sheet of paper, softening the thermosetting ink film surface, reducing the adhesion of the ink to the sheet of paper, and improving the adhesion of the ink to the adhesion roll. After adhesion of ink to the roll, the paper sheet is peeled away leaving the ink toner fused to the adhesion roll. The roll is then cleaned of fused ink and is ready for the next paper sheet.

Description

Device to Promote Reuse of Office Laser-print Paper
INTRODUCTION:
Two principal uses of office paper in the U.S. are in photocopiers and in printers which use a laser printing technology. Both of these processes use a toner material to create the image. The various types of toners are thermosetting plastic resins with carbon black and other minor constituents to control flow properties, electrical and magnetic properties or other characteristics. This toner is "set" onto the paper by using heat to melt the plastic powder into a solid film adhering to the paper surface. The current invention provides a method of loosening this toner- paper adhesion and lifting the toner back off of the paper so that the paper can be reused.
DESCRIPTION OF THE INVENTION:
Approximately 10 million tons of office paper are used annually in the U.S., and the percentage of this paper used in laser-print (this term includes photocopies papers) can be as high as 70%. In addition, approximately 25,000 tons of toner is used annually in the U.S., with a total world use of 50,000 tons annually. Much of the laser printed paper is used for short term purposes and then discarded, creating a large and rapidly growing stream of office wastepaper. It is estimated that this stream of office waste will reach 12 million tons per year by 1995 in the U.S. Similar trends are occurring in developed countries around the world.
This stream of laser-print wastepaper contains very high quality, bleached cellulose fibers derived from chemically pulping wood chips. To produce such high quality papers it typically requires four tons of green wood to produce one ton of paper. Unfortunately the toner has been found to be very tenacious in its adhesion to the fiber in conventional recycling and deinking processes, and even when detached during conventional recycling the ink particles are large and difficult to separate from the pulp slurry. These deinking processes function in the wet state after the paper has been broken down into individual fibers by mechanical action in large repulper devices. This type of process is only performed at large paper manufacturing sites, and is not suitable for office environments.
The current invention allows reprocessing of quantities of office papers in a dry state, such that offices could reuse the paper and reduce the quantity of paper purchased. This would have several advantages. First, it avoids shipping of quantities of new or recycled paper to the office and of wastepaper or municipal solid waste away from the office. Reuse of one pound of such office paper would eliminate purchase and shipping of one pound of paper to the office and simultaneously eliminate one pound of wastepaper or office waste emanating from the office.
The process uses a softening and lifting off technique which reduces the adhesion of the ink film to the paper sheet. This liftoff process is not sensitive to the ink particle size, and thus the two problems encountered with conventional deinking, namely strong adhesion and large, tough ink particles, are avoided with the dry process proposed here. In addition the process does not require a solvent or solvent recovery process such as other printing removal processes (Mitsubishi Electric Corp., JP04327299). In the current invention the laser-print paper would be collected in a segregated bin or reprocessed immediately in the case of errors or overruns. To process the paper, staples must first be removed and the paper should be jogged to align the edges. This can be done as separate operations or by add-ons of stages of conventional office equipment to the basic configuration.
The first step in the ink removal process is to feed the sheet of paper into the machine and press it into contact with an adhesion roll. Heat and pressure are applied to smooth out creases, flatten the paper, soften the thermosetting ink film, reduce adhesion to the paper, and improve adhesion to the adhesion roll. After adhesion of ink to the roll, the paper sheet is peeled away leaving the toner fused to the adhesion roll. This roll is then cleaned of fused ink and made ready for the next sheet.
After peeling the paper sheet from the adhesion roll, the paper sheet is then reconditioned by rehumidification and calendering to reduce curl and roughness, followed by optical inspection and ejection to an accept or reject output bin. The optical inspection can be performed by photo detectors such that an excessive amount of holes or residual ink will result in rejection of the individual sheet. These reject sheets can be used for lower quality purposes or sent to a conventional paper recycling process.
The success of this process will be somewhat dependent on the toner and type of paper used, and on the final quality demanded by the customer. To achieve best performance it may be necessary to adjust process conditions, such as adhesion roll temperature and pressure, for the particular toner-paper combination used in a given office. In addition to the stripping of the ink with an adhesion roll, if necessary, a "white toner" treatment can be applied to the paper to further improve the paper surface quality using a dry electrostatic coating process and clay-starch- polymer blends.

Claims

CLAIMS:What is claimed is:
1. A device which uses a lift off technique to remove laser-print from a cellulosic paper web and deposit it onto an adhesion roller or belt or suitable surface. Such affinity is caused by the surface compatibility between the plastic ink film surface and the surface of the adhesion roll. Such adhesion is further enhanced and aided by the application of suitable heat and pressure dependent on paper and toner characteristics. Other liquids or gaseous adjuvents may also be used to aid toner removal.
2. A device as specified in claim (1) above in which the sheet is further treated by rehumidification to reduce curl and handling problems.
3. A device as specified in claim (1) above in which the paper is calendered to improve final surface smoothness.
4. A device as specified in claim (1) above in which the paper is then treated with a "white toner" using a dry electrostatic process.
5. A device as specified in claim (1) above in which the paper is optically inspected and sorted into reject and accept bins.
6. A device as specified in claim (1) above in which the paper is treated on both sides in a single pass of the process.
PCT/US1995/009747 1995-07-31 1995-07-31 Device to promote reuse of office laser-print paper WO1997005323A1 (en)

Priority Applications (2)

Application Number Priority Date Filing Date Title
PCT/US1995/009747 WO1997005323A1 (en) 1995-07-31 1995-07-31 Device to promote reuse of office laser-print paper
AU32087/95A AU3208795A (en) 1995-07-31 1995-07-31 Device to promote reuse of office laser-print paper

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
PCT/US1995/009747 WO1997005323A1 (en) 1995-07-31 1995-07-31 Device to promote reuse of office laser-print paper

Publications (1)

Publication Number Publication Date
WO1997005323A1 true WO1997005323A1 (en) 1997-02-13

Family

ID=22249575

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/US1995/009747 WO1997005323A1 (en) 1995-07-31 1995-07-31 Device to promote reuse of office laser-print paper

Country Status (2)

Country Link
AU (1) AU3208795A (en)
WO (1) WO1997005323A1 (en)

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101899801A (en) * 2010-04-27 2010-12-01 浙江海洋学院 Apparatus for recycling paper by directly deinking
WO2012093395A2 (en) 2011-01-06 2012-07-12 Freeink Ltd. A method and composition for deinking a printed substrate
JP2016150454A (en) * 2015-02-16 2016-08-22 セイコーエプソン株式会社 Sheet manufacturing apparatus, sheet manufacturing method and used paper processor

Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4818342A (en) * 1985-08-23 1989-04-04 International Paper Company Heat treatment of paper products
US5019249A (en) * 1987-09-18 1991-05-28 Hitachi, Ltd. Apparatus for handling sheets of paper
US5113221A (en) * 1987-10-23 1992-05-12 Minolta Camera Kabushiki Kaisha Image forming apparatus having a plurality of toner developers including white toner
US5405726A (en) * 1991-11-11 1995-04-11 Bando Chemical Industries. Ltd. Method and apparatus for decolorization, and image forming apparatus

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4818342A (en) * 1985-08-23 1989-04-04 International Paper Company Heat treatment of paper products
US5019249A (en) * 1987-09-18 1991-05-28 Hitachi, Ltd. Apparatus for handling sheets of paper
US5113221A (en) * 1987-10-23 1992-05-12 Minolta Camera Kabushiki Kaisha Image forming apparatus having a plurality of toner developers including white toner
US5405726A (en) * 1991-11-11 1995-04-11 Bando Chemical Industries. Ltd. Method and apparatus for decolorization, and image forming apparatus

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101899801A (en) * 2010-04-27 2010-12-01 浙江海洋学院 Apparatus for recycling paper by directly deinking
CN101899801B (en) * 2010-04-27 2013-04-24 舟山市定海区巨洋技术开发有限公司 Apparatus for recycling paper by directly deinking
WO2012093395A2 (en) 2011-01-06 2012-07-12 Freeink Ltd. A method and composition for deinking a printed substrate
JP2016150454A (en) * 2015-02-16 2016-08-22 セイコーエプソン株式会社 Sheet manufacturing apparatus, sheet manufacturing method and used paper processor

Also Published As

Publication number Publication date
AU3208795A (en) 1997-02-26

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