WO1997002376A1 - Composites fibreux non tisses 'coform' hydrodispersables - Google Patents

Composites fibreux non tisses 'coform' hydrodispersables Download PDF

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Publication number
WO1997002376A1
WO1997002376A1 PCT/US1996/010832 US9610832W WO9702376A1 WO 1997002376 A1 WO1997002376 A1 WO 1997002376A1 US 9610832 W US9610832 W US 9610832W WO 9702376 A1 WO9702376 A1 WO 9702376A1
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WO
WIPO (PCT)
Prior art keywords
water
fibers
fibrous nonwoven
composite structure
nonwoven composite
Prior art date
Application number
PCT/US1996/010832
Other languages
English (en)
Inventor
William Seal Pomplun
David Martin Jackson
Original Assignee
Kimberly-Clark Worldwide, Inc.
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Kimberly-Clark Worldwide, Inc. filed Critical Kimberly-Clark Worldwide, Inc.
Priority to MX9800069A priority Critical patent/MX9800069A/es
Priority to BR9609656-0A priority patent/BR9609656A/pt
Priority to AU62899/96A priority patent/AU6289996A/en
Priority to EP96921776A priority patent/EP0835337B1/fr
Priority to DE69616550T priority patent/DE69616550T2/de
Publication of WO1997002376A1 publication Critical patent/WO1997002376A1/fr

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Classifications

    • D—TEXTILES; PAPER
    • D04—BRAIDING; LACE-MAKING; KNITTING; TRIMMINGS; NON-WOVEN FABRICS
    • D04H—MAKING TEXTILE FABRICS, e.g. FROM FIBRES OR FILAMENTARY MATERIAL; FABRICS MADE BY SUCH PROCESSES OR APPARATUS, e.g. FELTS, NON-WOVEN FABRICS; COTTON-WOOL; WADDING ; NON-WOVEN FABRICS FROM STAPLE FIBRES, FILAMENTS OR YARNS, BONDED WITH AT LEAST ONE WEB-LIKE MATERIAL DURING THEIR CONSOLIDATION
    • D04H5/00—Non woven fabrics formed of mixtures of relatively short fibres and yarns or like filamentary material of substantial length
    • D04H5/08—Non woven fabrics formed of mixtures of relatively short fibres and yarns or like filamentary material of substantial length characterised by the method of forming fleeces or layers, e.g. reorientation of fibres or yarns
    • D—TEXTILES; PAPER
    • D04—BRAIDING; LACE-MAKING; KNITTING; TRIMMINGS; NON-WOVEN FABRICS
    • D04H—MAKING TEXTILE FABRICS, e.g. FROM FIBRES OR FILAMENTARY MATERIAL; FABRICS MADE BY SUCH PROCESSES OR APPARATUS, e.g. FELTS, NON-WOVEN FABRICS; COTTON-WOOL; WADDING ; NON-WOVEN FABRICS FROM STAPLE FIBRES, FILAMENTS OR YARNS, BONDED WITH AT LEAST ONE WEB-LIKE MATERIAL DURING THEIR CONSOLIDATION
    • D04H1/00—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres
    • D04H1/04—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres having existing or potential cohesive properties, e.g. natural fibres, prestretched or fibrillated artificial fibres
    • D04H1/26—Wood pulp
    • D—TEXTILES; PAPER
    • D04—BRAIDING; LACE-MAKING; KNITTING; TRIMMINGS; NON-WOVEN FABRICS
    • D04H—MAKING TEXTILE FABRICS, e.g. FROM FIBRES OR FILAMENTARY MATERIAL; FABRICS MADE BY SUCH PROCESSES OR APPARATUS, e.g. FELTS, NON-WOVEN FABRICS; COTTON-WOOL; WADDING ; NON-WOVEN FABRICS FROM STAPLE FIBRES, FILAMENTS OR YARNS, BONDED WITH AT LEAST ONE WEB-LIKE MATERIAL DURING THEIR CONSOLIDATION
    • D04H1/00—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres
    • D04H1/40—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties
    • D04H1/407—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties containing absorbing substances, e.g. activated carbon
    • D—TEXTILES; PAPER
    • D04—BRAIDING; LACE-MAKING; KNITTING; TRIMMINGS; NON-WOVEN FABRICS
    • D04H—MAKING TEXTILE FABRICS, e.g. FROM FIBRES OR FILAMENTARY MATERIAL; FABRICS MADE BY SUCH PROCESSES OR APPARATUS, e.g. FELTS, NON-WOVEN FABRICS; COTTON-WOOL; WADDING ; NON-WOVEN FABRICS FROM STAPLE FIBRES, FILAMENTS OR YARNS, BONDED WITH AT LEAST ONE WEB-LIKE MATERIAL DURING THEIR CONSOLIDATION
    • D04H1/00—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres
    • D04H1/40—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties
    • D04H1/42—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties characterised by the use of certain kinds of fibres insofar as this use has no preponderant influence on the consolidation of the fleece
    • D04H1/4282—Addition polymers
    • D04H1/4309—Polyvinyl alcohol
    • D—TEXTILES; PAPER
    • D04—BRAIDING; LACE-MAKING; KNITTING; TRIMMINGS; NON-WOVEN FABRICS
    • D04H—MAKING TEXTILE FABRICS, e.g. FROM FIBRES OR FILAMENTARY MATERIAL; FABRICS MADE BY SUCH PROCESSES OR APPARATUS, e.g. FELTS, NON-WOVEN FABRICS; COTTON-WOOL; WADDING ; NON-WOVEN FABRICS FROM STAPLE FIBRES, FILAMENTS OR YARNS, BONDED WITH AT LEAST ONE WEB-LIKE MATERIAL DURING THEIR CONSOLIDATION
    • D04H1/00—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres
    • D04H1/40—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties
    • D04H1/42—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties characterised by the use of certain kinds of fibres insofar as this use has no preponderant influence on the consolidation of the fleece
    • D04H1/4326—Condensation or reaction polymers
    • D04H1/4334—Polyamides
    • D—TEXTILES; PAPER
    • D04—BRAIDING; LACE-MAKING; KNITTING; TRIMMINGS; NON-WOVEN FABRICS
    • D04H—MAKING TEXTILE FABRICS, e.g. FROM FIBRES OR FILAMENTARY MATERIAL; FABRICS MADE BY SUCH PROCESSES OR APPARATUS, e.g. FELTS, NON-WOVEN FABRICS; COTTON-WOOL; WADDING ; NON-WOVEN FABRICS FROM STAPLE FIBRES, FILAMENTS OR YARNS, BONDED WITH AT LEAST ONE WEB-LIKE MATERIAL DURING THEIR CONSOLIDATION
    • D04H1/00—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres
    • D04H1/40—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties
    • D04H1/54—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties by welding together the fibres, e.g. by partially melting or dissolving
    • D04H1/56—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties by welding together the fibres, e.g. by partially melting or dissolving in association with fibre formation, e.g. immediately following extrusion of staple fibres
    • D—TEXTILES; PAPER
    • D04—BRAIDING; LACE-MAKING; KNITTING; TRIMMINGS; NON-WOVEN FABRICS
    • D04H—MAKING TEXTILE FABRICS, e.g. FROM FIBRES OR FILAMENTARY MATERIAL; FABRICS MADE BY SUCH PROCESSES OR APPARATUS, e.g. FELTS, NON-WOVEN FABRICS; COTTON-WOOL; WADDING ; NON-WOVEN FABRICS FROM STAPLE FIBRES, FILAMENTS OR YARNS, BONDED WITH AT LEAST ONE WEB-LIKE MATERIAL DURING THEIR CONSOLIDATION
    • D04H5/00—Non woven fabrics formed of mixtures of relatively short fibres and yarns or like filamentary material of substantial length
    • D04H5/06—Non woven fabrics formed of mixtures of relatively short fibres and yarns or like filamentary material of substantial length strengthened or consolidated by welding-together thermoplastic fibres, filaments, or yarns

Definitions

  • the present invention relates to water-dispersible fibrous nonwoven composite structures comprising at least two different components wherein the composite is water-dispersible. More particularly, the present invention relates to fibrous nonwoven composite structures referred to as "coform" materials which are water-dispersible.
  • Fibrous nonwoven materials and fibrous nonwoven composite materials are widely used as products or as components of products because they can be manufactured inexpensively and can be made to have specific characteristics.
  • One approach has been to mix thermoplastic polymer fibers with one or more types of fibrous material and/or particulates. The mixtures are collected in the form of fibrous nonwoven web composites which may be bonded or treated to provide coherent nonwoven composite materials that take advantage of at least some of the properties of each component.
  • U.S. Patent Number 4,100,324 issued July 11, 1978 to Anderson et al. discloses a nonwoven fabric which is generally a uniform admixture of wood pulp and meltblown thermoplastic polymer fibers.
  • Patent Number 3,971,373 issued July 7, 1976 to Braun discloses a nonwoven material which contains meltblown thermoplastic polymer fibers and discrete solid particles. According to this patent, the particles are uniformly dispersed and intermixed with the meltblown fibers in the nonwoven material.
  • abrasion-resistant fibrous nonwoven structure composed of a matrix of meltblown fibers having a first exterior surface, a second exterior surface and an interior portion with at least one other fibrous material integrated into the meltblown fiber matrix.
  • concentration of meltblown fibers adjacent to each exterior surface of the nonwoven structure is at least about 60 percent by weight and the concentration of meltblown fibers in the interior portion is less than about 40 percent by weight.
  • Many of the aforementioned admixtures are referred to as "coform" materials because they are formed by combining two or more materials in the forming step into a single structure.
  • Coform engineered composites can be used in a wide variety of applications including absorbent media for agueous and organic fluids, filtration media for wet and dry applications, insulating materials, protective cushioning materials, containment and delivery systems and wiping media for both wet and dry applications.
  • Many of the foregoing applications can be met, to varying degrees, through the use of more simplified structures such as absorbent structures wherein only wood pulp fibers are used. This has commonly been the case with, for example, the absorbent cores of personal care absorbent products such as diapers.
  • Wood pulp fibers when formed by themselves tend to yield nonwoven web structures which have very little mechanical integrity and a high degree of collapse when wetted.
  • landfills One possible alternative means of disposal for many products, especially in the area of personal care absorbent products and wipers, is by flushing them into sewage disposal systems.
  • meltblown thermoplastic fiber matrix The very reason why many coform materials provide increased benefits over conventional materials, i.e., the meltblown thermoplastic fiber matrix, is the same reason why such materials are more difficult to recycle or flush. Many wood pulp fiber-based products can be recycled by hydrating and repulping the reclaimed wood pulp fibers. However, in coform structures the thermoplastic meltblown fibers do not readily break-up. The meltblown fibers are hard to separate from the wood pulp fibers, and they remain substantially continuous thereby giving rise to the possibility of clogging or otherwise damaging recycling equipment such as repulpers.
  • the present invention is directed to a water-dispersible fibrous nonwoven composite structure which utilizes at least two different components and wherein the composite is water- dispersible. Such structures are more commonly referred to as "coform" materials.
  • the water-dispersible fibrous nonwoven composite structure comprises a matrix of meltspun water- degradable reinforcing fibers and a multiplicity of discrete absorbent fibers which are disposed within the matrix of meltspun water-degradable reinforcing fibers.
  • the absorbent fibers may include, for example, staple fibers having average fiber lengths of approximately 18 millimeters or less as well as wood pulp fibers.
  • the water-dispersible fibrous nonwoven composite structure may further include a particulate material within the matrix as such as a superabsorbent and/or an odor reducing agent such as, for example, activated charcoal.
  • a particulate material within the matrix such as a superabsorbent and/or an odor reducing agent such as, for example, activated charcoal.
  • meltspun water- degradable reinforcing fibers include, but are not limited to, water-degradable polyamides and poly(vinyl alcohol) .
  • the water-dispersible fibrous nonwoven composite structure may comprise a plurality of particles disposed within and held by the matrix of meltspun water-degradable reinforcing fibers.
  • the materials of the present invention may be used in a wide variety of applications including, for example, personal care absorbent articles such as wipers, diapers, training pants, pantiliners, sanitary napkins, incontinence devices, wound dressings, bandages and the like.
  • Figure 1 is a schematic side elevation, partially in section, of a possible method and apparatus for producing water-dispersible fibrous nonwoven composite structures according to the present invention.
  • Figure 2 is a perspective view of a fragment of a fibrous nonwoven composite structure produced by the method and apparatus of Figure 1.
  • Figure 3 is a partial schematic side elevation of another possible method and apparatus for producing water-dispersible fibrous nonwoven composite structures according to the present invention.
  • the present invention is directed to a fibrous nonwoven composite structure, which has at least two different components which are water-dispersible.
  • fibrous nonwoven composite structure refers to a structure of individual fibers or filaments with or without particulates which are interlaid, but not in an identifiable repeating manner.
  • Nonwoven structures such as, for example, fibrous nonwoven webs have been formed in the past, by a variety of processes known to those skilled in the art including, for example; meltblowing and meltspinning processes, spunbonding processes and bonded carded web processes.
  • water-dispersible refers to a fibrous nonwoven composite structure which when placed in an aqueous environment will, with sufficient time, break apart into smaller pieces.
  • the structure once dispersed may be more advantageously processable in recycling processes or flushable in, for example, septic and municipal sewage treatment systems.
  • fibrous nonwoven structures may be made more water-dispersible or the dispersion may be hastened by the use of agitation and/or certain triggering means as are further described below.
  • the actual amount of time will depend at least in part upon the particular end-use design criteria. For example, in the sanitary napkin embodiments described below, the fibers break apart in less than a minute. In other applications, longer times may be desirable.
  • the fibrous nonwoven structure according to the present invention includes a meltspun reinforcing fiber made from a water-degradable polymer and one or more other components which are intermixed with the reinforcing fiber to form a fibrous nonwoven composite structure according to the present invention.
  • meltspun it is meant a fiber which is formed by a fiber-forming process which yields longer, more continuous fibers (generally in excess of 7.5 centimeters) such as are made by the meltblown and spunbond processes.
  • water- degradable it is meant a polymer which when formed into a fiber and placed in sufficient quantities of water for a sufficient period of time will break apart into smaller pieces. In some cases, agitation may be necessary to break the fibers apart.
  • the most common form of the fibrous nonwoven composite structure according to the present invention is commonly referred to as a "coform" material which includes longer more continuous melt-spun reinforcing fibers intermixed with shorter absorbent fibers such as staple length fibers and wood pulp fibers or particulates such as superabsorbents. Staple length fibers generally have lengths which extend up to approximately 7.5 centimeters.
  • thermoplastic short cut staple fibers which generally have lengths of less than about 18 millimeters and which can be made from a variety of thermoplastic extrudable polymers including, but not limited to, polyolefins and polyesters as well as homopolymers, copolymers and blends of such polymers.
  • polyolefins and polyesters as well as homopolymers, copolymers and blends of such polymers.
  • several different types and/or sizes of such fibers may be used in the coform structure.
  • absorbent fibers is pulp fibers. Pulp fibers are generally obtained from natural sources such as woody and non-woody plants. Woody plants include, for example, deciduous and coniferous trees. Non-woody plants include, for example, cotton, flax, esparto grass, milkweed, straw, jute, and bagasse.
  • Wood pulp fibers are also available and may be used with the present invention.
  • Wood pulp fibers typically have lengths of about 0.5 to 10 millimeters and a length-to-maximum width ratio of about 10/1 to 400/1.
  • a typical cross-section has an irregular width of about 30 micrometers and a thickness of about 5 micrometers.
  • One wood pulp suitable for use with the present invention is Kimberly-Clark CR-54 wood pulp from the Kimberly-Clark
  • the water-degradable reinforcing fibers will typically have lengths in excess of the absorbent fibers including staple and wood pulp fibers. Examples of two such water-degradable reinforcing fibers are meltblown fibers and spunbond fibers.
  • Meltblown fibers are formed by extruding molten thermoplastic material through a plurality of fine, usually circular, die capillaries as molten threads or filaments into a heated high velocity gas stream such as air, which attenuates the filaments of molten thermoplastic material to reduce their diameters.
  • meltblown fibers are carried by the high velocity gas stream and are deposited on a collecting surface to form a web of randomly dispersed meltblown fibers.
  • the meltblown process is well-known and is described in various patents and publications, including NRL Report 4364,
  • meltblown fibers can be made in a wide variety of diameters. Typically, such fibers will have an average diameter of not greater than about 100 micrometers and usually not more than 15 micrometers.
  • Spunbond fibers are formed by extruding a molten thermoplastic material as filaments from a plurality of fine, usually circular, capillaries in a spinneret with the diameter of the extruded filaments then being rapidly reduced, for example, by non-eductive or eductive fluid-drawing or other well-known spunbonding mechanisms. The production of spunbond nonwoven webs is illustrated in patents such as Appel et al., U.S.
  • Patent Number 4,340,563 Matsuki et al., U.S. Patent Number 3,802,817; Dorschner et al., U.S. Patent Number ⁇ 3,692,618; Kinney, U.S. Patent Numbers 3,338,992 and 3,341,394; Levy, U.S. Patent Number 3,276,944; Peterson, U.S. Patent Number 3,502,538; Hartman, U.S. Patent Number 3,502,763; Dobo et al., U.S. Patent Number 3,542,615; and Harmon, Canadian Patent Number 803,714. All of the foregoing references are incorporated herein by reference in their entirety.
  • the fibrous nonwoven structure according to the present invention may employ superabsorbent materials.
  • superabsorbent materials are absorbent materials capable of absorbing at least 10 grams of aqueous liquid (e.g. distilled water) per gram of absorbent material while immersed in a liquid for four hours and which will hold substantially all of the absorbed liquid while under a compression force of up to about 10 kilopascals (kPa) .
  • Superabsorbent materials are produced in a wide variety of forms including, but not limited to, particles, fibers and flakes.
  • Such superabsorbent materials may be used in the present invention in combination with the water-degradable reinforcing fibers and shorter absorbent fibers or in lieu of the staple fibers. Due to the longer, more continuous nature of the fibers formed by the foregoing meltblown and spunbonding processes, such fibers and resultant nonwoven webs including coform webs do not readily break apart due to the inherent tenacity of the meltblown and/or spunbond fibers. As a result, coform materials which are predominantly wood pulp fibers but which still contain longer fibers such as polyolefin meltblown fibers are difficult to reclaim in such apparatus as repulpers.
  • the fibrous nonwoven composite structures according to the present invention use a water- degradable reinforcing fiber which may be made, for example, by the aforementioned and described meltblowing and spunbonding processes.
  • Water-degradable polymers are polymers which can be used to form fibers such as by the meltblowing and spunbonding processes. These water-degradable polymers, when formed into fibers and mixed with absorbent materials such as staple length and/or wood pulp fibers and/or particulates such as superabsorbents, can form fibrous nonwoven structures referred to as coform materials. These coform materials can have subsequent end uses which involve exposure of the structures to aqueous liquids including, but not limited to, normal tap water, waste water and body fluids such as blood and urine.
  • Conventional coform fibrous nonwoven structures are used as absorbent products either alone, as in the form of wipers, or as components of other absorptive devices such as personal care absorbent articles including, but not limited to, diapers, training pants, incontinence garments, sanitary napkins, tampons, wound dressings, bandages and the like. It is desirable therefore, that the fibrous nonwoven composite structures of the present invention be able to withstand the rigors of their intended uses, and then, upon completion of the particular uses, the fibrous nonwoven web composite structures must become water-dispersible. To accomplish this, water- degradable polymers employing a number of triggering mechanisms can be used as the polymers to form the water-degradable reinforcing fibers of the fibrous nonwoven composite structure of the present invention.
  • Certain polymers are only water-degradable when exposed to sufficient guantities of an aqueous liquid within a certain pH range. Outside this range, they will not degrade.
  • a pH-sensitive water-degradable polymer which will not degrade in an aqueous liquid or liquids in one pH range, for example a pH of 3 to 5, but which will become degradable in excess tap water. See for example, U.S. Patent Number 5,102,668 to Eichel et al. which is incorporated herein by reference in its entirety.
  • body fluids such as urine
  • the water- degradable reinforcing fibers will not degrade.
  • such a fibrous nonwoven composite structure can be placed in excess quantities of higher pH liquids such as tap water which will cause the degradation of the water-degradable polymer making up the reinforcing fibers.
  • higher pH liquids such as tap water which will cause the degradation of the water-degradable polymer making up the reinforcing fibers.
  • the longer, more continuous reinforcing fibers will begin to break apart either by themselves or with sufficient agitation so that the discrete fibrous components, such as wood pulp fibers, can be reclaimed, recycled or disposed of by flushing.
  • polymers which could be used to form this type of fiber could include acrylate ester/acrylic or methylacrylic acid copolymers and blends such as those designated as N-10, H-10 or X-10 as supplied by Findley Adhesives, Incorporated of Milwaukee, Wisconsin.
  • It has a nominal molecular weight of 14,000 Daltons, an acid number less than 2, a hydroxyl number less than 10 and a glass transition temperature of 38°C.
  • Other examples could be blends of copolymers of poly(vinyl alcohol) blended with polyacrylic or methylacrylic acid or polyvinylmethyl ether blended with polyacrylic or methylacrylic acid.
  • the Eastman polymers are stable in solutions with high cation concentrations, but will break-up rapidly if placed in sufficient excess water such as tap water to dilute the cation concentration.
  • polyvinylmethylether which has a cloud point of 34°C.
  • this polymer When this polymer is exposed to body fluids such as urine at 37°C, it will not degrade as this temperature is above its cloud point (34°C) . However, if the polymer is placed in water at room temperature (23°C), the polymer will, with time, go back into solution as it is now exposed to water at a temperature below its cloud point. Consequently, the polymer will begin to degrade.
  • Blends of polyvinylmethylether and copolymers may be considered as well.
  • Other cold water soluble polymers include poly(vinyl alcohol) graft copolymers supplied by the Nippon Synthetic Chemical Company, Ltd. of Osaka, Japan which are coded Ecomaty AX2000, AX10000 and AX300G.
  • a water-degradable polymer is extruded through a die head 10 into a primary ga ⁇ stream 11 of high velocity, heated gas (usually air) supplied from nozzles 12 and 13 to attenuate the molten polymer into long, somewhat continuous fibers.
  • the primary gas stream 11 is merged with a secondary gas stream 14 containing individualized wood pulp fibers or other materials including particulates so as to integrate the two different fibrous materials into a single fibrous nonwoven composite structure.
  • the apparatus for forming and delivering the secondary gas stream 14 including the wood pulp fibers can be an apparatus of the type described and claimed in U.S. Patent
  • This apparatus comprises a conventional picker roll 20 having picking teeth for divellicating pulp sheets 21 into individual fibers.
  • the pulp sheets 21 are fed radially, i.e. along a picker roll radius, to the picker roll 20 by means of rolls 22.
  • the teeth on the picker roll 20 divellicate the pulp sheets 21 into individual fibers, the resulting separate fibers are conveyed downwardly toward the primary air stream through a forming nozzle or duct 23.
  • a housing 24 encloses the picker roll 20 and provides a passage 25 between the housing 24 and the picker roll surface.
  • Process air is supplied to the picker roll in the passage 25 via duct 26 in sufficient quantity to serve as a medium for
  • the air may be supplied by a conventional means a ⁇ , for example, a blower.
  • the primary and secondary gas streams 11 and 14 are preferably moving perpendicularly to each other at the point of merger, although other merging angles may be employed if desired to vary the degree of mixing and/or to form concentration gradients through the structure.
  • the velocity of the secondary stream 14 is substantially lower than that of the primary stream 11 so that the integrated stream 15 resulting from the merger continues to flow in the same direction as the primary stream 11.
  • the merger of the two streams is somewhat like an aspirating effect whereby the fibers in the secondary stream 14 are drawn into the primary stream 11 as it passes the outlet of the duct 23.
  • the velocity difference between the two gas streams be such that the secondary stream is integrated with the primary stream in a turbulent manner so that the fibers in the secondary stream become thoroughly mixed with the meltblown fibers in the primary stream.
  • increasing velocity differences between the primary and secondary streams produce more homogenous integration of the two materials while lower velocities and smaller velocity differences will produce concentration gradients of components in the fibrous nonwoven composite structure.
  • the primary air stream have an initial sonic velocity within the nozzles 12 and 13 and that the secondary air stream have a subsonic velocity. As the primary air stream exits the nozzles 12 and 13, it immediately expands with a resulting decrease in velocity.
  • Deceleration of the high velocity ga ⁇ stream carrying the meltblown water-degradable meltblown fibers frees the fibers from the drawing forces which initially form them from the water-degradable polymer mass.
  • a ⁇ the water-degradable reinforcing fiber ⁇ relax, they are better able to follow the minute eddies and to entangle and capture the relatively short wood pulp or other absorbent fibers while both fibers are dispersed and suspended in the gaseous medium.
  • the resultant combination is an intimate mixture of wood pulp fibers and water-degradable reinforcing fibers integrated by physical entrapment and mechanical entanglement.
  • Attenuation of the water-degradable reinforcing fibers occurs both before and after the entanglement of these fibers with the pulp fiber ⁇ .
  • the stream 15 is passed into the nip of a pair of vacuum rolls 30 and 31 having foraminous surfaces that rotate continuously over a pair of fixed vacuum nozzles 32 and 33.
  • the carrying gas is sucked into the two vacuum nozzles 32 and 33 while the fiber blend is supported and slightly compres ⁇ ed by the opposed surfaces of the two rolls 30 and 31.
  • the containment of the wood pulp fibers in the integrated reinforcing fiber matrix is obtained without any further processing or treatment of the air laid composite structure.
  • the composite web or structure 34 may be embossed or bonded using heat and/or pressure.
  • the embossing may be accomplished using, for example, ultrasonic bonding and/or mechanical bonding as through the use of smooth and/or patterned bonding rolls which may or may not be heated.
  • Such bonding techniques are well-known to those skilled in the art.
  • the composite structure 34 is passed through an ultrasonic bonding station comprising an ultrasonic calendering head 40 vibrating against a patterned anvil roll 41.
  • the bonding conditions e.g. pressure, speed, power input
  • the bonding pattern may be appropriately selected to provide the desired characteristics in the final product. See Figure 2.
  • the relative weight percentages of the water-degradable reinforcing fibers and absorbent fibers may be varied according to the particular end use. Generally speaking, increasing the weight percent of the water-degradable reinforcing fibers will increase the overall tensile strength and integrity of the resultant fibrous composite nonwoven structure.
  • Figure 3 of the drawings Another formation process which might be used for forming water-dispersible fibrous nonwoven composites according to the present invention is shown in Figure 3 of the drawings.
  • Figure 3 there is shown an exemplary apparatus for forming an abrasion-resistant fibrous nonwoven composite structure which is generally represented by reference numeral 110.
  • pellets or chip ⁇ etc.
  • thermoplastic polymer (not ⁇ hown) of a thermoplastic polymer are introduced into a pellet hoppers 112 of one or more extruder ⁇ 114.
  • the extruder ⁇ 114 have extru ⁇ ion ⁇ crew ⁇ (not shown) which are driven by a conventional drive motor (not shown) .
  • the polymer advances through the extruders 114, due to rotation of the extrusion screw by the drive motor, the polymer is progressively heated to a molten state. Heating the thermoplastic polymer to the molten state may be accomplished in a plurality of discrete steps with its temperature being gradually elevated as it advances through discrete heating zones of the extruder 114 toward two meltblowing dies 116 and 118, respectively.
  • the meltblowing dies 116 and 118 may be yet another heating zone wherein the temperature of the thermoplastic resin is maintained at an elevated level for extrusion.
  • Each meltblowing die is configured so that two streams of usually heated attenuating ga ⁇ per die converge to form a single stream of gas which entrains and attenuates the molten threads of water-degradable polymer, as the threads exit small holes or orifices 124 in the meltblowing die.
  • the molten threads are attenuated into fibers 120, or depending upon the degree of attenuation, microfibers, of a small diameter which is usually less than the diameter of the orifices 124.
  • each meltblowing die 116 and 118 has a corresponding single stream of gas 126 and 128 containing entrained and attenuated polymer fibers.
  • the gas streams 126 and 128 containing polymer fibers are aligned to converge at an impingement zone 130.
  • One or more types of secondary fibers 132 and/or particulates are added to the two streams 126 and 128 of water- degradable thermoplastic polymer fibers or microfibers 120 at the impingement zone 130.
  • Introduction of the secondary fibers 132 into the two streams 126 and 128 of the water-degradable thermoplastic polymer fibers 120 is designed to produce a graduated distribution of secondary fiber ⁇ 132 within the combined ⁇ treams 126 and 128 of thermoplastic polymer fibers. This may be accomplished by merging a secondary gas stream 134 containing the secondary fibers 132 between the two streams 126 and 128 of water-degradable thermoplastic polymer fibers 120 so that all three gas streams converge in a controlled manner.
  • Apparatus for accomplishing this merger may include a conventional picker roll 136 arrangement which has a plurality of teeth 138 that are adapted to separate a mat or batt 140 of secondary fibers into the individual secondary fiber ⁇ 132.
  • the mat or batt of secondary fibers 140 which is fed to the picker roll 136 may be a sheet of pulp fibers (if a two-component mixture of water-degradable thermopla ⁇ tic polymer fiber ⁇ and secondary pulp fibers is desired) , a mat of staple fibers (if a two-component mixture of water-degradable thermoplastic polymer fibers and a secondary staple fibers is desired) or both a sheet of pulp fibers and a mat of staple fibers (if a three-component mixture of water-degradable thermoplastic polymer fiber ⁇ , secondary staple fibers and secondary pulp fibers is desired) .
  • the secondary fibers 132 are absorbent fibers.
  • the secondary fibers 132 may generally be selected from the group including one or more polyester fibers, polyamide fibers, cellulosic derived fibers such as, for example, rayon fibers, wood pulp fibers and superabsorbent fibers, multi-component fibers such as, for example, ⁇ heath- core multi-component fibers, natural fiber ⁇ such as silk fibers, wool fibers or cotton fibers or electrically conductive fibers or blends of two or more of such secondary fibers.
  • secondary fibers 132 such as, for example, polyethylene fibers and polypropylene fibers, as well as blends of two or more of other types of secondary fibers 132 may be utilized.
  • the secondary fibers 132 may be microfibers or the secondary fibers 132 may be macrofibers having an average diameter of from about 300 micrometers to about 1,000 micrometers.
  • the sheets or mats 140 of secondary fibers 132 are fed to the picker roll 136 by a roller arrangement 142. After the teeth 136 of the picker roll 136 have separated the mat of secondary fiber ⁇ 140 into separate secondary fiber ⁇ 132 the individual secondary fibers 132 are conveyed toward the stream of thermoplastic polymer fibers or microfibers 120 through a nozzle 144.
  • a housing 146 enclose ⁇ the picker roll 136 and provides a passageway or gap 148 between the housing 146 and the ⁇ urface of the teeth 138 of the picker roll 136.
  • a gas such as air is supplied to the pas ⁇ ageway or gap 148 between the surface of the picker roll 136 and the housing 146 by way of a gas duct 150.
  • the gas duct 150 may enter the passageway or gap 148 generally at the junction 152 of the nozzle 144 and the gap 148.
  • the gas is ⁇ upplied in ⁇ ufficient quantity to serve as a medium for conveying the ⁇ econdary fibers 132 through the nozzle 144.
  • the gas supplied from the duct 150 also serves as an aid in removing the secondary fibers 132 from the teeth 138 of the picker roll 136.
  • the gas may be supplied by any conventional arrangement such as, for example, an air blower (not shown) . It is contemplated that additives and/or other materials may be added to or entrained in the gas stream to treat the secondary fiber ⁇ 132 or to provide desired properties in the resultant web.
  • the individual secondary fibers 132 are conveyed through the nozzle 144 at about the velocity at which the secondary fibers 132 leave the teeth 138 of the picker roll
  • the width of the nozzle 144 should be aligned in a direction generally parallel to the width of the meltblowing dies 116 and 118. Desirably, the width of the nozzle 144 should be about the same as the width of the meltblowing dies 116 and 118. Usually, the width of the nozzle 144 should not exceed the width of the sheets or mats 140 that are being fed to the picker roll 136. Generally speaking, it is desirable for the length of the nozzle 144 separating the picker from the impingement zone 130 to be as short as equipment design will allow.
  • the picker roll 136 may be replaced by a conventional particulate injection system to form a fibrous nonwoven composite structure 154 containing various secondary particulates.
  • a combination of both secondary particulates and secondary fibers could be added to the water-degradable thermoplastic polymer fiber ⁇ 120 prior to formation of the fibrous nonwoven composite ⁇ tructure 154 if a conventional particulate injection ⁇ y ⁇ tem was added to the system illustrated in Figure 3.
  • the particulates may be, for example, charcoal, clay, starches, and/or hydrocolloid (hydrogel) particulates commonly referred to as super ⁇ absorbents.
  • the secondary fibers 132 are usually not only mechanically entangled within the matrix formed by the water-degradable fibers 120 but are also thermally bonded or joined to the water-degradable fibers.
  • a collecting device is located in the path of the composite stream 156.
  • the collecting device may be an endless belt 158 conventionally driven by rollers 160 and which is rotating as indicated by the arrow 162 in Figure 3.
  • Other collecting devices are well known to those of skill in the art and may be utilized in place of the endless belt 158. For example, a porous rotating drum arrangement could be utilized.
  • the merged streams of water-degradable fibers and secondary fiber ⁇ are collected a ⁇ a coherent matrix of fibers on the ⁇ urface of the endle ⁇ s belt 158 to form the fibrous nonwoven composite structure or web 154.
  • Vacuum boxes 164 assist in retention of the matrix on the surface of the belt 158.
  • the vacuum may be set at about 2.5 to about 10 centimeters of water column.
  • the fibrous nonwoven composite structure 154 is coherent and may be removed from the belt 158 as a self-supporting nonwoven material.
  • the fibrous nonwoven composite structure 154 has adequate strength and integrity to be used without any post-treatments such as pattern bonding and the like.
  • a pair of pinch rollers or pattern bonding rollers may be used to bond portions of the material. Although such treatment may improve the integrity of the fibrous nonwoven composite structure 154 it also tends to compress and densify the structure.
  • McFarland et al. U.S. Patent Number 4,604,313 issued August 5, 1986 is directed to a process for forming a multi-layered coform material including meltblown fibers and wood pulp fibers in one layer and a second layer which contains meltblown fibers, wood pulp fibers and superabsorbent particles.
  • Another process is disclosed in Eschwey et al., U.S. Patent 4,902,559 issued February 20, 1990. This patent discloses a process wherein endless filaments are spun through a long spinneret into a passage to form what are more commonly referred to as spunbond fibers.
  • Example I water-dispersible fibrous nonwoven composite structures were made using a water soluble poly(vinyl alcohol) copolymer meltblown and fluff wood pulp in 20/80, 30/70, and 40/60 weight percent ratios (meltblown/pulp) based upon the total weight of the fibrous nonwoven composite structure.
  • the polyvinyl alcohol copolymer had code name Ecomaty AXIOOOO and was manufactured by Nippon-Gohsei of Osaka, Japan.
  • the meltflow rate of this AXIOOOO copolymer was 100 grams per 10 minutes at a temperature of 190°C under 2.16 kilograms load using ASTM Test Method D-1238.
  • the softening temperature of the AXIOOOO copolymer was 180°C but it processed better at 210°C to make meltblown microfibers.
  • the fluff wood pulp had code number NF405 as received from Weyerhauser Corporation of Federal Way, Washington.
  • the absorbent structure was produced utilizing a twin extruder and a pulp fiberizer system such as shown in Figure 3.
  • the coformed composite ⁇ were formed on either a porous tissue carrier sheet or a spunbonded polypropylene nonwoven web carrier sheet.
  • the coform composites can be formed directly onto a forming wire.
  • Basis weight ⁇ of the coformed absorbent structures were 190 grams per square meter (gsm) .
  • the absorbent structures were then pattern bonded in a separate process using a heated calender nip with a total bond area of approximately 20 percent.
  • the meltblown fibers dissolved and the web broke apart in les ⁇ than one minute and typically in le ⁇ than 30 seconds.
  • the 20/80 web was placed in a consumer study with adult women in a pantiliner intermenstrual test and the coformed absorbent was found to be capable of sustaining small fluid loads from urine and menses for periods up to six hours.
  • Example II a water-dispersible fibrous nonwoven structure was made using a water soluble polyamide polymer meltblown and wood pulp fluff in a 30/70 meltblown/fluff weight ratio.
  • the polyamide polymer had code number NP 2068 as received from H.B. Fuller Company of St. Paul, Minnesota.
  • the viscosity of the NP 2068 polymer was 95 Pascal-seconds at a temperature of 204°C.
  • the softening temperature range of the NP 2068 polymer was 128°-145°C but it processed best at 210°C to make meltblown microfibers.
  • the fluff wood pulp had code number NF405 as received from the Weyerhauser Corporation of Federal Way, Washington.
  • the absorbent structure was produced in the same fashion as Example I.
  • the coformed composite was formed on a porous tissue carrier sheet.
  • the basis weight of the coformed absorbent structure was 190 grams per square meter.
  • the meltblown fibers dissolved and the web broke apart in less than one minute and typically less than 30 ⁇ econd ⁇ .
  • Example III a water-dispersible fibrous nonwoven composite structure was made using a water soluble polyamide polymer meltblown and wood pulp fluff in a 30/70 meltblown/fluff weight ratio.
  • the polyamide polymer had code number NP 2074 as received from H.B. Fuller Company of St.
  • the viscosity of the NP 2074 polymer was 290
  • the softening temperature range of the NP 2074 polymer was 133°-145°C but it processed best at 210°C to make meltblown microfibers.
  • the fluff wood pulp had code number NF405 as received from the
  • the absorbent structure was produced in the same fashion as Example I.
  • the coformed composite was formed on a porous tissue carrier sheet and the basis weight of the coformed absorbent structure was 190 grams per square meter.
  • the meltblown fibers dissolved and broke apart in less than one minute and typically les ⁇ than 30 ⁇ econd ⁇ .
  • experimental pantiliners were made using the water-degradable coform materials outlined above in Examples I through III and were compared to a conventional coform containing pantiliner.
  • the conventional pantiliner construction included a polyethylene baffle film, a 13 gram per square meter thermally embossed polypropylene spunbond liner and a 190 gram per square meter coform material as the absorbent core.
  • the coform material comprised 30% by weight polypropylene meltblown fibers having an average fiber diameter of approximately 5 micrometers and 70% by weight based upon the weight of the absorbent core wood pulp fiber ⁇ . The polypropylene meltblown and wood pulp fibers were intimately mixed with one another to form the absorbent core.
  • a water-based adhesive was used to laminate the polyethylene film to one side of the coform material and the polypropylene spunbond liner was thermally embossed to the other ⁇ ide of the coform material.
  • a garment adhesive strip for attachment of the product to the undergarment of the wearer.
  • This laminate formed the control as it did not contain any water-degradable reinforcing fibers but, instead, utilized the polypropylene meltblown fibers as the reinforcing means.
  • U.S. Patent No. 3,881,490 to Whitehead et al. and U.S. Patent No. Des. 247,368 to Whitehead both of which are incorporated herein by reference in their entirety.
  • the materials of the present invention from Examples I through III were also formed into pantiliners of the same general description as given above.
  • 190 gsm polypropylene coform material in the control 190 gsm 30% water-degradable reinforcing fiber/70% by weight wood pulp fiber coform composites according to Examples I, II and III were used.
  • the polyethylene baffle was replaced with a water-degradable film and the baffle film was attached to the coform absorbent core by way of a hot melt adhesive instead of a water-based adhesive.
  • control pantiliners which contained polypropylene fibers (which have a density less than 1 gram per cubic centimeter and a polyethylene baffle film with a density less than 1 gram per cubic centimeter) floated on the surface of the water in the toilet bowl. Consequently, the hydraulic driving force acting on the control product was much less than that acting on the experimental product ⁇ . This demonstrated the lack of flushability of the control product because it could not realize the driving force of the priming jet in the toilet.

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  • Engineering & Computer Science (AREA)
  • Textile Engineering (AREA)
  • Chemical & Material Sciences (AREA)
  • Materials Engineering (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Wood Science & Technology (AREA)
  • Nonwoven Fabrics (AREA)
  • Reinforced Plastic Materials (AREA)
  • Biological Depolymerization Polymers (AREA)
  • Laminated Bodies (AREA)
  • Absorbent Articles And Supports Therefor (AREA)

Abstract

L'invention porte sur la structure d'un composite fibreux non tissé dite 'coform' qui diffère des structures coform actuelles en ce qu'elle offre une meilleure hydrodispersabilité raison de l'utilisation d'une matrice fibreuse de renforcement hydrodégradable.
PCT/US1996/010832 1995-06-30 1996-06-26 Composites fibreux non tisses 'coform' hydrodispersables WO1997002376A1 (fr)

Priority Applications (5)

Application Number Priority Date Filing Date Title
MX9800069A MX9800069A (es) 1995-06-30 1996-06-26 Compuestos coform no tejidos fibrosos dispersables en agua.
BR9609656-0A BR9609656A (pt) 1995-06-30 1996-06-26 Compósitos coformados não tecidos fibrosos dispersivos em água.
AU62899/96A AU6289996A (en) 1995-06-30 1996-06-26 Water-dispersible fibrous nonwoven coform composites
EP96921776A EP0835337B1 (fr) 1995-06-30 1996-06-26 Composites fibreux non tisses "coform" hydrodispersables
DE69616550T DE69616550T2 (de) 1995-06-30 1996-06-26 Wasserdispergierbare, faserige, in der form gleiche verbundvliesstoffe

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US49762995A 1995-06-30 1995-06-30
US08/497,629 1995-06-30

Publications (1)

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WO1997002376A1 true WO1997002376A1 (fr) 1997-01-23

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EP (1) EP0835337B1 (fr)
KR (1) KR19990028530A (fr)
AU (1) AU6289996A (fr)
BR (1) BR9609656A (fr)
CA (1) CA2222461A1 (fr)
DE (1) DE69616550T2 (fr)
ES (1) ES2166454T3 (fr)
MX (1) MX9800069A (fr)
WO (1) WO1997002376A1 (fr)

Cited By (12)

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WO1998029590A3 (fr) * 1996-12-31 1998-08-13 Kimberly Clark Co Non-tisse dispersible coforme lie a un systeme hybride, et procede de fabrication associe
WO1998036117A1 (fr) * 1997-02-13 1998-08-20 Kimberly-Clark Worldwide, Inc. Composites coform non tisses fibreux hydro-dispersables
WO1999004831A1 (fr) * 1997-07-22 1999-02-04 Kimberly-Clark Worldwide, Inc. Matiere de conformation presentant des capacites ameliorees d'absorption des fluides et procede de production
EP1010783A1 (fr) * 1998-12-16 2000-06-21 Kuraray Co., Ltd. Fibres d'alcool polyvinylique thermoplastiques et leur procédé de préparation
WO2000039378A2 (fr) * 1998-12-31 2000-07-06 Kimberly-Clark Worldwide, Inc. Non-tisses pouvant se disperser dans l'eau et contenant des materiaux liants polymeres sensibles a la temperature ou aux ions, et procede de fabrication associe
EP1118314A2 (fr) * 2000-01-06 2001-07-25 Uni-Charm Corporation Article absorbant décomposable dans l'eau
WO2002017982A2 (fr) * 2000-09-01 2002-03-07 Kimberly-Clark Worldwide, Inc. Articles d'hygiène personnelle épousant bien les formes du corps
WO2004001127A2 (fr) * 2002-06-19 2003-12-31 Lanxess Corporation Produits de papier resistants et dispersables
US6814974B2 (en) 2000-05-04 2004-11-09 Kimberly-Clark Worldwide, Inc. Ion-sensitive, water-dispersible polymers, a method of making same and items using same
US6828014B2 (en) 2001-03-22 2004-12-07 Kimberly-Clark Worldwide, Inc. Water-dispersible, cationic polymers, a method of making same and items using same
US6835678B2 (en) 2000-05-04 2004-12-28 Kimberly-Clark Worldwide, Inc. Ion sensitive, water-dispersible fabrics, a method of making same and items using same
EP2458081A1 (fr) 2010-11-24 2012-05-30 Ascodero Productique Installation pour la découpe d'un textile notamment pour l'écaillage de la dentelle

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US8226622B2 (en) 2002-12-20 2012-07-24 Kimberly-Clark Worldwide, Inc. Interlabial absorbent article with soluble adhesive and time-delayed dispersion
US7138560B2 (en) 2003-12-10 2006-11-21 Kimberly-Clark Worldwide, Inc. Absorbent article with time-delayed absorbent binder composition
US7514591B2 (en) 2003-12-10 2009-04-07 Kimberly-Clark Worldwide, Inc. Interlabial absorbent article with improved flushability characteristics
DE102009049802A1 (de) * 2009-10-16 2011-04-21 Carl Freudenberg Kg Wasserlösliche Haftmassenbeschichtung für wasserlösliche Einlagestoffe
IT202200010061A1 (it) * 2022-05-16 2023-11-16 Gdm Spa Metodo per realizzare un nastro composito

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EP0564784A1 (fr) * 1992-04-07 1993-10-13 Kimberly-Clark Corporation Tissu non-tissé fibreux anisotropique
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Cited By (21)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5948710A (en) * 1995-06-30 1999-09-07 Kimberly-Clark Worldwide, Inc. Water-dispersible fibrous nonwoven coform composites
US5952251A (en) * 1995-06-30 1999-09-14 Kimberly-Clark Corporation Coformed dispersible nonwoven fabric bonded with a hybrid system
AU730627B2 (en) * 1996-12-31 2001-03-08 Kimberly-Clark Worldwide, Inc. Coformed dispersible nonwoven fabric bonded with a hybrid system and method of making same
WO1998029590A3 (fr) * 1996-12-31 1998-08-13 Kimberly Clark Co Non-tisse dispersible coforme lie a un systeme hybride, et procede de fabrication associe
WO1998036117A1 (fr) * 1997-02-13 1998-08-20 Kimberly-Clark Worldwide, Inc. Composites coform non tisses fibreux hydro-dispersables
AU719186B2 (en) * 1997-02-13 2000-05-04 Kimberly-Clark Worldwide, Inc. Water-dispersible fibrous nonwoven coform composites
WO1999004831A1 (fr) * 1997-07-22 1999-02-04 Kimberly-Clark Worldwide, Inc. Matiere de conformation presentant des capacites ameliorees d'absorption des fluides et procede de production
EP1010783A1 (fr) * 1998-12-16 2000-06-21 Kuraray Co., Ltd. Fibres d'alcool polyvinylique thermoplastiques et leur procédé de préparation
GB2363387A (en) * 1998-12-31 2001-12-19 Kimberly Clark Co Water-dispersible nonwoven fabrics containing temperature-sensitive or ion-sensitive polymeric binder materials and process for making such fabrics
WO2000039378A2 (fr) * 1998-12-31 2000-07-06 Kimberly-Clark Worldwide, Inc. Non-tisses pouvant se disperser dans l'eau et contenant des materiaux liants polymeres sensibles a la temperature ou aux ions, et procede de fabrication associe
WO2000039378A3 (fr) * 1998-12-31 2000-09-21 Kimberly Clark Co Non-tisses pouvant se disperser dans l'eau et contenant des materiaux liants polymeres sensibles a la temperature ou aux ions, et procede de fabrication associe
EP1118314A2 (fr) * 2000-01-06 2001-07-25 Uni-Charm Corporation Article absorbant décomposable dans l'eau
EP1118314A3 (fr) * 2000-01-06 2004-05-12 Uni-Charm Corporation Article absorbant décomposable dans l'eau
US6814974B2 (en) 2000-05-04 2004-11-09 Kimberly-Clark Worldwide, Inc. Ion-sensitive, water-dispersible polymers, a method of making same and items using same
US6835678B2 (en) 2000-05-04 2004-12-28 Kimberly-Clark Worldwide, Inc. Ion sensitive, water-dispersible fabrics, a method of making same and items using same
WO2002017982A2 (fr) * 2000-09-01 2002-03-07 Kimberly-Clark Worldwide, Inc. Articles d'hygiène personnelle épousant bien les formes du corps
WO2002017982A3 (fr) * 2000-09-01 2002-06-13 Kimberly Clark Co Articles d'hygiène personnelle épousant bien les formes du corps
US6828014B2 (en) 2001-03-22 2004-12-07 Kimberly-Clark Worldwide, Inc. Water-dispersible, cationic polymers, a method of making same and items using same
WO2004001127A2 (fr) * 2002-06-19 2003-12-31 Lanxess Corporation Produits de papier resistants et dispersables
WO2004001127A3 (fr) * 2002-06-19 2004-04-22 Bayer Chemicals Corp Produits de papier resistants et dispersables
EP2458081A1 (fr) 2010-11-24 2012-05-30 Ascodero Productique Installation pour la découpe d'un textile notamment pour l'écaillage de la dentelle

Also Published As

Publication number Publication date
DE69616550T2 (de) 2002-04-11
AU6289996A (en) 1997-02-05
KR19990028530A (ko) 1999-04-15
MX9800069A (es) 1998-03-31
BR9609656A (pt) 2000-10-24
CA2222461A1 (fr) 1997-01-23
EP0835337A1 (fr) 1998-04-15
EP0835337B1 (fr) 2001-10-31
DE69616550D1 (de) 2001-12-06
ES2166454T3 (es) 2002-04-16

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