WO1997001191A3 - Nonaqueous battery with cathode active material mixture - Google Patents

Nonaqueous battery with cathode active material mixture Download PDF

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Publication number
WO1997001191A3
WO1997001191A3 PCT/US1996/010760 US9610760W WO9701191A3 WO 1997001191 A3 WO1997001191 A3 WO 1997001191A3 US 9610760 W US9610760 W US 9610760W WO 9701191 A3 WO9701191 A3 WO 9701191A3
Authority
WO
WIPO (PCT)
Prior art keywords
lithium
oxides
homogeneous
disclosed
mixture
Prior art date
Application number
PCT/US1996/010760
Other languages
French (fr)
Other versions
WO1997001191A2 (en
Inventor
Steven T Mayer
Original Assignee
Polystor Corp
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Polystor Corp filed Critical Polystor Corp
Publication of WO1997001191A2 publication Critical patent/WO1997001191A2/en
Publication of WO1997001191A3 publication Critical patent/WO1997001191A3/en

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Classifications

    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/02—Electrodes composed of, or comprising, active material
    • H01M4/13—Electrodes for accumulators with non-aqueous electrolyte, e.g. for lithium-accumulators; Processes of manufacture thereof
    • H01M4/131—Electrodes based on mixed oxides or hydroxides, or on mixtures of oxides or hydroxides, e.g. LiCoOx
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M10/00—Secondary cells; Manufacture thereof
    • H01M10/05—Accumulators with non-aqueous electrolyte
    • H01M10/052—Li-accumulators
    • H01M10/0525—Rocking-chair batteries, i.e. batteries with lithium insertion or intercalation in both electrodes; Lithium-ion batteries
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M10/00—Secondary cells; Manufacture thereof
    • H01M10/05—Accumulators with non-aqueous electrolyte
    • H01M10/056—Accumulators with non-aqueous electrolyte characterised by the materials used as electrolytes, e.g. mixed inorganic/organic electrolytes
    • H01M10/0564—Accumulators with non-aqueous electrolyte characterised by the materials used as electrolytes, e.g. mixed inorganic/organic electrolytes the electrolyte being constituted of organic materials only
    • H01M10/0566—Liquid materials
    • H01M10/0568—Liquid materials characterised by the solutes
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/02—Electrodes composed of, or comprising, active material
    • H01M4/13—Electrodes for accumulators with non-aqueous electrolyte, e.g. for lithium-accumulators; Processes of manufacture thereof
    • H01M4/139—Processes of manufacture
    • H01M4/1391—Processes of manufacture of electrodes based on mixed oxides or hydroxides, or on mixtures of oxides or hydroxides, e.g. LiCoOx
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/02—Electrodes composed of, or comprising, active material
    • H01M4/36—Selection of substances as active materials, active masses, active liquids
    • H01M4/362—Composites
    • H01M4/364—Composites as mixtures
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/02—Electrodes composed of, or comprising, active material
    • H01M4/36—Selection of substances as active materials, active masses, active liquids
    • H01M4/48—Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides
    • H01M4/50—Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides of manganese
    • H01M4/505—Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides of manganese of mixed oxides or hydroxides containing manganese for inserting or intercalating light metals, e.g. LiMn2O4 or LiMn2OxFy
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/02—Electrodes composed of, or comprising, active material
    • H01M4/36—Selection of substances as active materials, active masses, active liquids
    • H01M4/48—Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides
    • H01M4/52—Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides of nickel, cobalt or iron
    • H01M4/525—Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides of nickel, cobalt or iron of mixed oxides or hydroxides containing iron, cobalt or nickel for inserting or intercalating light metals, e.g. LiNiO2, LiCoO2 or LiCoOxFy
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/02—Electrodes composed of, or comprising, active material
    • H01M4/36—Selection of substances as active materials, active masses, active liquids
    • H01M4/58—Selection of substances as active materials, active masses, active liquids of inorganic compounds other than oxides or hydroxides, e.g. sulfides, selenides, tellurides, halogenides or LiCoFy; of polyanionic structures, e.g. phosphates, silicates or borates
    • H01M4/581—Chalcogenides or intercalation compounds thereof
    • H01M4/5815—Sulfides
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M10/00—Secondary cells; Manufacture thereof
    • H01M10/42—Methods or arrangements for servicing or maintenance of secondary cells or secondary half-cells
    • H01M2010/4292—Aspects relating to capacity ratio of electrodes/electrolyte or anode/cathode
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/02—Electrodes composed of, or comprising, active material
    • H01M4/13—Electrodes for accumulators with non-aqueous electrolyte, e.g. for lithium-accumulators; Processes of manufacture thereof
    • H01M4/133—Electrodes based on carbonaceous material, e.g. graphite-intercalation compounds or CFx
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/02—Electrodes composed of, or comprising, active material
    • H01M4/36—Selection of substances as active materials, active masses, active liquids
    • H01M4/48—Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides
    • H01M4/485—Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides of mixed oxides or hydroxides for inserting or intercalating light metals, e.g. LiTi2O4 or LiTi2OxFy
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/02—Electrodes composed of, or comprising, active material
    • H01M4/62—Selection of inactive substances as ingredients for active masses, e.g. binders, fillers
    • H01M4/621—Binders
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/02—Electrodes composed of, or comprising, active material
    • H01M4/62—Selection of inactive substances as ingredients for active masses, e.g. binders, fillers
    • H01M4/624—Electric conductive fillers
    • H01M4/625—Carbon or graphite
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
    • Y02E60/10—Energy storage using batteries

Abstract

Composite cathodes (24) are disclosed which include a mixture of a first homogeneous cathode material and a second homegeneous cathode material, and binders as necessary. By choosing particular types and relative amounts of the first and second homogeneous cathode materials, the resulting composite cathodes can have matched formation and reversible cycling capacities (for a given anode material) and sloping discharge profiles. The first and second homogeneous cathode materials used in the composite cathodes disclosed herein may each be one of lithium molybdenum sulfides, lithium molybdenum oxides, lithium vanadium oxides, lithium chromium oxides, lithium titanium oxides, lithium tungsten oxides, lithium cobalt oxides, lithium nickel oxides, and lithium manganese oxides. Lithium ion cells having such composite electrodes are also disclosed herein. Such cells include a cell container (14), a non-aqueous electrolyte (34) and an anode (22) including a mixture of homogeneous graphitic carbon particles and homogeneous non-graphitic carbon particles.
PCT/US1996/010760 1995-06-22 1996-06-21 Nonaqueous battery with cathode active material mixture WO1997001191A2 (en)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US49371595A 1995-06-22 1995-06-22
US08/493,715 1995-06-22

Publications (2)

Publication Number Publication Date
WO1997001191A2 WO1997001191A2 (en) 1997-01-09
WO1997001191A3 true WO1997001191A3 (en) 1997-02-27

Family

ID=23961403

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/US1996/010760 WO1997001191A2 (en) 1995-06-22 1996-06-21 Nonaqueous battery with cathode active material mixture

Country Status (1)

Country Link
WO (1) WO1997001191A2 (en)

Families Citing this family (14)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5744265A (en) * 1996-06-13 1998-04-28 Valence Technology, Inc. Lithium cell having mixed lithium--metal--chalcogenide cathode
EP0949702B1 (en) * 1998-03-17 2003-08-20 Asahi Glass Company Ltd. Secondary battery power source
GB9807774D0 (en) * 1998-04-09 1998-06-10 Danionics As Electrochemical cell
JP2000200605A (en) 1998-10-30 2000-07-18 Sanyo Electric Co Ltd Nonaqueous electrolyte battery and its manufacture
AU5601299A (en) * 1998-11-04 2000-05-11 Wilson Greatbatch Ltd. Mixed cathode material for high energy density electrochemical cells
JP3754218B2 (en) * 1999-01-25 2006-03-08 三洋電機株式会社 Non-aqueous electrolyte battery positive electrode and manufacturing method thereof, and non-aqueous electrolyte battery using the positive electrode and manufacturing method thereof
JP3670875B2 (en) * 1999-02-09 2005-07-13 三洋電機株式会社 Lithium secondary battery
JP4159212B2 (en) * 1999-11-12 2008-10-01 三洋電機株式会社 Nonaqueous electrolyte secondary battery
JP4878687B2 (en) * 2001-02-23 2012-02-15 三洋電機株式会社 Lithium secondary battery
US9666862B2 (en) * 2005-02-23 2017-05-30 Lg Chem, Ltd. Secondary battery of improved lithium ion mobility and cell capacity
US8501352B2 (en) * 2006-02-03 2013-08-06 The United States Of America, As Represented By The Secretary Of The Navy Lithium-metal-oxide composite electrodes
KR101093705B1 (en) * 2009-04-29 2011-12-19 삼성에스디아이 주식회사 Rechargeable lithium battery
US8426052B2 (en) 2009-05-08 2013-04-23 Robert Bosch Gmbh Li-ion battery with porous anode support
US8313864B2 (en) 2009-05-08 2012-11-20 Robert Bosch Gmbh Li-ion battery with blended electrode

Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5278000A (en) * 1992-09-02 1994-01-11 The United States Of America As Represented By The Administrator Of The National Aeronautics And Space Administration Overcharge and overdischarge protection of ambient temperature secondary lithium cells
US5339024A (en) * 1991-09-24 1994-08-16 Duracell Inc. Battery with electrochemical tester
US5429890A (en) * 1994-02-09 1995-07-04 Valence Technology, Inc. Cathode-active material blends of Lix Mn2 O4
US5451477A (en) * 1993-06-03 1995-09-19 Sony Corporation Non-aqueous liquid electrolyte secondary battery

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5339024A (en) * 1991-09-24 1994-08-16 Duracell Inc. Battery with electrochemical tester
US5278000A (en) * 1992-09-02 1994-01-11 The United States Of America As Represented By The Administrator Of The National Aeronautics And Space Administration Overcharge and overdischarge protection of ambient temperature secondary lithium cells
US5451477A (en) * 1993-06-03 1995-09-19 Sony Corporation Non-aqueous liquid electrolyte secondary battery
US5429890A (en) * 1994-02-09 1995-07-04 Valence Technology, Inc. Cathode-active material blends of Lix Mn2 O4

Non-Patent Citations (5)

* Cited by examiner, † Cited by third party
Title
FULLER ET AL.: "Simulation and optimization of dual lithium ion insertion cell", J. ELECTROCHEM. SOC., vol. 141, January 1994 (1994-01-01), pages 1 - 10 *
GUMMOW ET AL.: "Lithium-cobalt-nickel oxide cathode materials prepared at 400degreesC rechargable lithium bateries", SOLID STATE IONICS, vol. 53-56, 1992, pages 681 - 687 *
OHZUKU ET AL.: "Comparative study of LiCoO2, LiNi1/2Co1/2O2 and LiNiO2 for 4 volt secondary lithium cells", ELECTROCHEMICAL ACTA, vol. 38, no. 9, 1993, pages 1159 - 1167 *
REIMERS ET AL.: "Effects of impurities on the electrochemical properties of LiCoO2", J. ELECTROCHEM. SOC., vol. 140, October 1993 (1993-10-01), pages 2753 - 2754 *
UEDA ET AL.: "Solid state redox reaction of LiNi1/2Co1/2o2 for 4 volt secondary lithium cells", J. ELECTROCHEM. SOC., vol. 141, August 1994 (1994-08-01), pages 2010 - 2014 *

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Publication number Publication date
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