WO1997000006A1 - Greenhouse film having variable light diffusion properties - Google Patents
Greenhouse film having variable light diffusion properties Download PDFInfo
- Publication number
- WO1997000006A1 WO1997000006A1 PCT/CA1996/000395 CA9600395W WO9700006A1 WO 1997000006 A1 WO1997000006 A1 WO 1997000006A1 CA 9600395 W CA9600395 W CA 9600395W WO 9700006 A1 WO9700006 A1 WO 9700006A1
- Authority
- WO
- WIPO (PCT)
- Prior art keywords
- greenhouse
- film
- assembly
- layer
- clear
- Prior art date
Links
Classifications
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01G—HORTICULTURE; CULTIVATION OF VEGETABLES, FLOWERS, RICE, FRUIT, VINES, HOPS OR SEAWEED; FORESTRY; WATERING
- A01G9/00—Cultivation in receptacles, forcing-frames or greenhouses; Edging for beds, lawn or the like
- A01G9/14—Greenhouses
- A01G9/1438—Covering materials therefor; Materials for protective coverings used for soil and plants, e.g. films, canopies, tunnels or cloches
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01G—HORTICULTURE; CULTIVATION OF VEGETABLES, FLOWERS, RICE, FRUIT, VINES, HOPS OR SEAWEED; FORESTRY; WATERING
- A01G9/00—Cultivation in receptacles, forcing-frames or greenhouses; Edging for beds, lawn or the like
- A01G9/14—Greenhouses
- A01G9/1407—Greenhouses of flexible synthetic material
- A01G9/1415—Greenhouses of flexible synthetic material with double or multiple walls
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02A—TECHNOLOGIES FOR ADAPTATION TO CLIMATE CHANGE
- Y02A40/00—Adaptation technologies in agriculture, forestry, livestock or agroalimentary production
- Y02A40/10—Adaptation technologies in agriculture, forestry, livestock or agroalimentary production in agriculture
- Y02A40/25—Greenhouse technology, e.g. cooling systems therefor
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/31504—Composite [nonstructural laminate]
- Y10T428/31855—Of addition polymer from unsaturated monomers
- Y10T428/31909—Next to second addition polymer from unsaturated monomers
- Y10T428/31913—Monoolefin polymer
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/31504—Composite [nonstructural laminate]
- Y10T428/31855—Of addition polymer from unsaturated monomers
- Y10T428/31909—Next to second addition polymer from unsaturated monomers
- Y10T428/31928—Ester, halide or nitrile of addition polymer
Definitions
- thermoplastic greenhouse film having an outer layer with a variable light-diffuse surface and a greenhouse assembly comprising said greenhouse film.
- a greenhouse by its very nature is required to be closed during cold periods to contain the heat to create its growing environment. At high humidity inside the greenhouse, water condenses on the inside of the greenhouse roof or cover when the temperature of the roof or cover is reduced to the dew point or lower.
- a greenhouse film made from an olefinic polymer has a surface characteristic of low surface tension and thereby is hydrophobic.
- thermoplastic greenhouse film in a humid greenhouse environment is that the water condensate forms on the surface of the film as fine droplets. This condition is known as "fogging" and creates two basis problems for the grower. First, the transmission of sunlight, an essential requirement for plant growth, is reduced. Second, the fine droplets coalesce to form larger droplets which fall onto and may damage the crop below. The damage to the crop may be to the extent that the market value based on crop quality is reduced, and in the case of a speciality crop such as flowers, the damage can render the crop unmarketable.
- One way to overcome the above problem of fogging is to spray the surface of the film exposed in the greenhouse environment with a substance which when dry forms a coating which increases the surface tension of the film surface so as to reduce the interfacial tension between the surface and water condensate.
- a commercial product which gives the above described effect is that material sold under the trademark "Sunclear” , manufactured by Solar Sunstill Company, San Antonio, New
- a second way to overcome the above problem of fogging is to incorporate a surfactant additive into the polymer prior to the polymer being converted into a film.
- the additive functions in this utility by migrating to the surface of the film.
- the surfactant dissolves in the droplet water and reduces the surface tension of the water to cause the droplet to spread and coalesce with other droplets until the film is covered with a sheet of water.
- the sheeted water thus allow drainage of condensate continually down the curvature of the film.
- Examples of commercial surfactants are Atmer 184TM and Atmer 103TM sorbitan stearate (ICI Specialty Chemicals).
- Growers in the horticultural field have often expressed the need for a greenhouse film which can change its light diffusion properties according to the weather, i.e. the amount and nature of sunlight falling on the greenhouse film covering the greenhouse crops.
- a grower would like a greenhouse film which is clear to impinging sunlight on temperate days but which darkens under the effect of high, direct sunshine in order to prevent excess heat build-up within the greenhouse. To- date, such a film is not available.
- a shade paint commercially available under the trademark "VariShade” (Solar Sunstill Company, San Antonio, New Mexico, U.S.A.) is often applied to the outer surface of a clear greenhouse film.
- the paint on the film is transparent to direct sunlight when wet, for example, from rain, but which is cloudy or hazy when the film surface is dry under direct sunlight conditions.
- "Varishade II" shade paint is recommended for use on film surfaces facing outside and inside of the greenhouse and is, in addition, removable.
- applying such a shade paint coating to an erected greenhouse film is not satisfactory because of the economic cost, time and labour involved in its application, which, to be effective must be uniformly and properly applied.
- a commercially available film having high haze and light diffusion properties made from a polyethylene resin sold under the trademark MARLEX D252
- a polyethylene greenhouse film covering a greenhouse is the difference between the degree of its light diffusion and its clarity. While a diffusion cover may transmit essentially the same amount of light, diffusion results in the light at any location within the greenhouse to be less intense generally than those areas exposed to direct sunlight. Diffusion of the light spreads more of it to effect better exposed leaf area without also providing plants under dark shadows ' .
- Clear film allows direct light to be transmitted which, in strong sunlight conditions can be harsh to growing crops.
- low light intensity conditions such as under cloudy skies, or in low sunlight conditions of winter, late fall and early spring clarity of the film allows the maximum possible intensity of light passage through to the plants.
- thermoplastic film having a variable light diffuse surface which surface is substantially clear when wetted but has an enhanced degree of surface haze when dry.
- the present invention provides for enhanced growing crop conditions in the present context of variable clarity greenhouse film due to appropriate wetting of the film to provide a variable diffuse and clarity surface property quality depending on the weather conditions.
- the invention provides an improved greenhouse assembly wherein the film having the innermost diffuse surface as hereinabove defined is used in conjunction with an outer second film comprising a polyolefin film.
- the invention also provides an improved greenhouse assembly wherein the film having the diffuse surface outermost as herein described is used in conjunction with an inner second film comprising a polyolefin film and an anti-fogging agent innermost of the assembly.
- polyolefin film containing anti-fogging agents are known and include, for example, polyethylene polymers, EVA (ethylene-vinyl acetate) co-polymers, 1,2- polybutadienes, and blends thereof.
- the polyethylene is selected from the group consisting of LDPE (low density polyethylene) and LLDPE (linear low density polyethylene).
- variable light diffusion surface thermoplastic layer provides the surface of the roof covering a greenhouse with satisfactory light transmission characteristics.
- the nature of the second and, optionally, other layers of the multilayer film of use in the practice of the invention may be suitably selected by the skilled artisan based on the usual desired properties such as weight, ease of manufacture, durability, resistance to sunlight, and the like. It will be, thus, clear that the choice of polyolefin material of such subordinate layers is not crucial to this invention and resides within the skill in the art.
- the subordinate layer is formed of at least one polyolefin.
- polyolefin as used in this specification and claims is meant the polyethylene, polypropylene and polybutadiene family of olefine polymers and copolymers.
- high density, low density and linear low density polyethylenes and 1,2 - polybutadienes may be mentioned.
- polyethylene includes ethylene homopolymers, and copolymers of, such as vinyl acetate, acrylic acid, methyl methacrylate, butene, n-hexene, 4-methyl- 1 -pentene and octene polymers with ethylene and blends thereof.
- the multilayered film of use in the practice of the invention may comprise (a) a plurality of distinct layers constituted as a plurality of distinct plies, (b) a laminate comprising at least two distinct films or plies adhered to each other, directiy, or by means of an adhesive, (c) a co-extruded film produced by the self-adhesion of two or more films to each other under hot process conditions or (d) a co-oriented film, laminate or ply made by the cold drawing of a plurality of thermoplastic films, simultaneously in such close contact together that under the drawing step at the drawing temperature the films become intimately associated and unified into a single resultant film or ply while each undivided film is being uni-axially oriented.
- the coextmded film of use in the invention may comprise two or more layers provided that a variable light diffusion thermoplastic layer comprises one outer layer.
- Preferred multilayer films of use in the practice ofthe invention comprise an outer surface layer of Marlex D252 resin into which an antifog surfactant had been added so as to develop the antifog nature of the surface.
- this surface will be hazy when dry and clear when wetted.
- the invention provides that one surface film is clarified permanently with coextrusion.
- the coextmded film of use in the invention may comprise two or more layers having clear minimal body and surface diffusion (haze).
- the layers of variable light diffusion thermoplastics and clear polyolefin may be, preferably, further stabilized for multiyear service life in a greenhouse environment.
- Stabilization additives include, for example, antioxidants, UV stabilizers,
- UV absorbers and chelating agents in the quantities required for their specific application as would be readily recognized and determined by those skilled in the art.
- coextmded film may contain additives to give further light diffusion, alteration of sunlight spectmm, infra-red energy conservation and barrier properties.
- the film comprises a low density linear polyethylene.
- a typical multilayered film of use in the invention is a coextmsion of polyethylene polymers having anti-fog agents, such as: Low density linear polyethylene MARI-EX* D252 1 mil
- the multilayered films as described aforesaid may be readily made by processes known in the art, preferably by blown film extmsion. Film widths range, typically, from Im to 15m. Most preferred are 2- and 3-layered coextmded films of a LDLPE outer layer with layers of LDPE, LLDPE, EVA copolymer or blends thereof.
- the multilayered film is installed and laid to cover the covering supports of a greenhouse stmcture as is conventional in the art but with the variable light diffusion film surface exposed to the inside atmosphere of the greenhouse and the clear coextmded layer remote from the greenhouse atmosphere.
- the clear second skin is placed outermost and the variable haze film innermost.
- the inside layer will be wetted in situations where condensation in the greenhouse is permitted. This would be when the greenhouse is closed, sealed or the like to prevent heat loss and thereby also prevent the ventilation of moisture therefrom. This would be the situation on cool days.
- the resulting sheeting of condensate water on the anti-fog film surface will cause this layer to be clear to direct light transmission.
- the greenhouse cover may not be formed to provide total enclosure to conserve heat as in temperate areas but rather as a cover against damage from pelting rains.
- the multilayered film would be installed in this situation with the diffuse surface exposed to the outside. During hot sunny days or warm overcast days the outer surface will provide diffusion. On cold rainy days, the rain will clear the haze of the outer surface. This situation is akin to the use of "Varishade" shade paint which relies on rain wetting to improve clarity and transmission through the coating.
- Fig. 1 represents a perspective view of an unrolled, unfolded film positioned on a greenhouse according to the invention
- Fig. 2 is a diagrammatic representation in-part of a single skin greenhouse cover
- Fig. 3 is a diagrammatic representation in-part of a greenhouse double- skin cover; and Figs. 4 and 5 represent similar embodiments as Figs. 2 and 3, but wherein layer 1 is disposed outermost of the assembly and subjected to the outside atmosphere.
- Tinuvin* 328 (Ciba-Geigy) UV absorber. 0.25
- a greenhouse assembly shown generally as 10 has a plurality of roof support members 12 and side support members 14 to which is held a covering film 16.
- Film 16 is selected from multilayered films of the following constmction: Low density linear polyethylene MARLEX* D252 1 mil
- Fig. 2 is a diagrammatic representation in-part of a single skin greenhouse cover shown generally as 20 formed of a coextrude two-layer film having a composition as described in Examples A or B and a three-layer coextmded film of Example C.
- Layer 1 of Examples A, B and C shown as 22 in Fig. 2 faces innermost of the greenhouse atmosphere; whereas layer 2 of Examples A and B or layer 3 of Example C are shown in Fig. 2 as outermost layer 24 of assembly 10.
- Fig. 3 is a diagrammatic representation in-part of a greenhouse double- skin cover shown generally as 30 of an outer skin 32 and an inner skin 34 to define an inflatable air envelope enclosing air 36.
- Inner skin 34 is as described selected from
- FIG. 4 shows generally as 40 a co-extmded two-layer single skin having layer 1 as 24 outermost and an inner layer of layer 2 or 3 of Examples A/B and
- Fig. 5 shows generally as 50 a greenhouse double skin having an outer film 52 of Examples A, B or C wherein layer 1 is outermost to the atmosphere and inner film 54 of a commercial clear low density polyethylene which define an inflated air envelope 56.
- Luminous Transmittance is the ratio of the luminous flux transmitted by a body to the flux incident upon it.
- the haze measurements were made by a hazemeter.
- the luminous transmittance was obtained by placing a clear specimen at a distance from the entrance port of the integrating sphere. However, when the specimen was hazy, the total hemispherical luminous transmittance was measured by placing the specimen at the entrance port of the sphere. The measured total hemispherical luminous transmittance will be greater than the regular luminous transmittance, depending on the optical properties of the sample. With this test method, the specimen is necessarily placed at the entrance port of the sphere in order to measure haze and total hemispherical luminous transmittance.
- Marlex* D252 low density, linear polyethylene film medium molecular weight resin has the following physical properties. Nominal Physical Properties of Marlex*
Landscapes
- Life Sciences & Earth Sciences (AREA)
- Environmental Sciences (AREA)
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Soil Sciences (AREA)
- Greenhouses (AREA)
- Protection Of Plants (AREA)
- Laminated Bodies (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Abstract
Description
Claims
Priority Applications (3)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
AU61174/96A AU694050B2 (en) | 1995-06-15 | 1996-06-10 | Greenhouse film having variable light diffusion properties |
EP19960918539 EP0831687A1 (en) | 1995-06-15 | 1996-06-10 | Greenhouse film having variable light diffusion properties |
NZ310386A NZ310386A (en) | 1995-06-15 | 1996-06-10 | Greenhouse comprising cover support and thermoplastic film having variable light diffuse surface |
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US08/490,670 | 1995-06-15 | ||
US08/490,670 US5585418A (en) | 1995-06-15 | 1995-06-15 | Greenhouse film having variable light diffusion properties |
Publications (1)
Publication Number | Publication Date |
---|---|
WO1997000006A1 true WO1997000006A1 (en) | 1997-01-03 |
Family
ID=23949004
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
PCT/CA1996/000395 WO1997000006A1 (en) | 1995-06-15 | 1996-06-10 | Greenhouse film having variable light diffusion properties |
Country Status (6)
Country | Link |
---|---|
US (1) | US5585418A (en) |
EP (1) | EP0831687A1 (en) |
AU (1) | AU694050B2 (en) |
CA (1) | CA2220082A1 (en) |
NZ (1) | NZ310386A (en) |
WO (1) | WO1997000006A1 (en) |
Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO2012143289A1 (en) | 2011-04-20 | 2012-10-26 | Plastika Kritis S.A. | Multilayer plastic film with separable layers for covering of inflated greenhouse |
US11930750B2 (en) | 2020-07-08 | 2024-03-19 | Qatar Foundation For Education, Science And Community Development | Greenhouse and cooling system of the same |
Families Citing this family (9)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US6131363A (en) * | 1998-03-20 | 2000-10-17 | Innovative Greenhousing Systems, Inc. | Greenhouse roof glazing system |
US20080281063A9 (en) * | 1999-12-30 | 2008-11-13 | Sukhadia Ashish M | Ethylene polymers and copolymers with high optical opacity and methods of making the same |
US6623866B2 (en) | 2001-04-04 | 2003-09-23 | Exxonmobil Oil Corporation | Multilayer films including anti-block |
US20050016438A1 (en) * | 2003-06-17 | 2005-01-27 | Sunstream Corporation | Watercraft canopy |
US7119153B2 (en) | 2004-01-21 | 2006-10-10 | Jensen Michael D | Dual metallocene catalyst for producing film resins with good machine direction (MD) elmendorf tear strength |
US7094857B2 (en) * | 2004-03-10 | 2006-08-22 | Chevron Phillips Chemical Company, L.P. | Ethylene polymers and copolymers with high optical opacity |
US20080148630A1 (en) * | 2006-12-20 | 2008-06-26 | Institute For Technology Development | Methods and systems for growing plants using diffuse scattering illumination |
US10021838B1 (en) | 2014-09-22 | 2018-07-17 | Closed S, LLC | Cannabis growth methods and systems |
CN110651643A (en) * | 2019-10-15 | 2020-01-07 | 沈阳农业大学 | Greenhouse seedling growing greenhouse with seedling growing lighting and ventilation control system |
Citations (8)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
FR2090036A1 (en) * | 1970-05-20 | 1972-01-14 | Boulard Remy | Variably light diffusing material - for windows contg a non ionic surfactant soln |
JPS51100452A (en) * | 1975-02-24 | 1976-09-04 | Musashino Kikai Setsukei Jimus | |
GB1550488A (en) * | 1977-11-10 | 1979-08-15 | Marfani Agricultural Ltd | Inflatable roof for greenhouses |
US4268413A (en) * | 1977-08-25 | 1981-05-19 | Wolfgang Dabisch | Bodies with reversibly variable temperature-dependent light absorbence |
US4816518A (en) * | 1985-03-21 | 1989-03-28 | The Dow Chemical Company | Solid state thermosensitive polymer compositions |
US4877675A (en) * | 1988-09-29 | 1989-10-31 | Waqidi Falicoff | Light transmitting or reflective sheet responsive to temperature variations |
EP0421748A1 (en) * | 1989-10-06 | 1991-04-10 | Sumitomo Chemical Company, Limited | Agricultural film |
EP0654213A1 (en) * | 1993-11-18 | 1995-05-24 | Kabushiki Kaisha Sekuto Kagaku | Composite plastic film and greenhouse built therewith |
Family Cites Families (9)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
FR2063595A5 (en) * | 1969-10-23 | 1971-07-09 | Pechiney Saint Gobain | |
IL62066A (en) * | 1981-02-04 | 1984-10-31 | Rami Bar | Polymeric films for agricultural use |
JPS5890960A (en) * | 1981-11-27 | 1983-05-30 | 三菱化学株式会社 | Agricultural laminated film |
FR2528275A1 (en) * | 1982-06-09 | 1983-12-16 | Monfray Benoit | Deployment of plastic film pref. polyethylene over framework - used for horticultural protection, has film dispensing carriage which rides on the frame |
US4486552A (en) * | 1983-02-28 | 1984-12-04 | The Dow Chemical Company | Fog-resistant olefin polymer films |
IL72879A (en) * | 1984-09-06 | 1988-12-30 | Ginegar Kibbutz | Plastic sheeting |
US5262223A (en) * | 1988-11-25 | 1993-11-16 | Faricerca S.P.A. | Absorbent element and an absorbent article including the element |
US5212903A (en) * | 1989-05-19 | 1993-05-25 | Talbott Gene B | Greenhouse construction and liquid distribution system |
US5038517A (en) * | 1989-05-19 | 1991-08-13 | Talbott Gene B | Greenhouse construction |
-
1995
- 1995-06-15 US US08/490,670 patent/US5585418A/en not_active Expired - Fee Related
-
1996
- 1996-06-10 WO PCT/CA1996/000395 patent/WO1997000006A1/en not_active Application Discontinuation
- 1996-06-10 EP EP19960918539 patent/EP0831687A1/en not_active Ceased
- 1996-06-10 NZ NZ310386A patent/NZ310386A/en unknown
- 1996-06-10 AU AU61174/96A patent/AU694050B2/en not_active Ceased
- 1996-06-10 CA CA 2220082 patent/CA2220082A1/en not_active Abandoned
Patent Citations (8)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
FR2090036A1 (en) * | 1970-05-20 | 1972-01-14 | Boulard Remy | Variably light diffusing material - for windows contg a non ionic surfactant soln |
JPS51100452A (en) * | 1975-02-24 | 1976-09-04 | Musashino Kikai Setsukei Jimus | |
US4268413A (en) * | 1977-08-25 | 1981-05-19 | Wolfgang Dabisch | Bodies with reversibly variable temperature-dependent light absorbence |
GB1550488A (en) * | 1977-11-10 | 1979-08-15 | Marfani Agricultural Ltd | Inflatable roof for greenhouses |
US4816518A (en) * | 1985-03-21 | 1989-03-28 | The Dow Chemical Company | Solid state thermosensitive polymer compositions |
US4877675A (en) * | 1988-09-29 | 1989-10-31 | Waqidi Falicoff | Light transmitting or reflective sheet responsive to temperature variations |
EP0421748A1 (en) * | 1989-10-06 | 1991-04-10 | Sumitomo Chemical Company, Limited | Agricultural film |
EP0654213A1 (en) * | 1993-11-18 | 1995-05-24 | Kabushiki Kaisha Sekuto Kagaku | Composite plastic film and greenhouse built therewith |
Non-Patent Citations (1)
Title |
---|
DATABASE WPI Section Ch Week 7642, Derwent World Patents Index; Class A97, AN 76-78610X [42], XP002013652 * |
Cited By (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO2012143289A1 (en) | 2011-04-20 | 2012-10-26 | Plastika Kritis S.A. | Multilayer plastic film with separable layers for covering of inflated greenhouse |
US9820448B2 (en) | 2011-04-20 | 2017-11-21 | Plastika Kritis S.A. | Multilayer plastic film with separable layers for covering of inflated greenhouse |
US11058069B2 (en) | 2011-04-20 | 2021-07-13 | Plastika Kritis S.A. | Multilayer plastic film with separable layers for covering of inflated greenhouse |
US11930750B2 (en) | 2020-07-08 | 2024-03-19 | Qatar Foundation For Education, Science And Community Development | Greenhouse and cooling system of the same |
Also Published As
Publication number | Publication date |
---|---|
US5585418A (en) | 1996-12-17 |
AU6117496A (en) | 1997-01-15 |
EP0831687A1 (en) | 1998-04-01 |
CA2220082A1 (en) | 1997-01-03 |
NZ310386A (en) | 1998-07-28 |
AU694050B2 (en) | 1998-07-09 |
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