WO1996040803A1 - Ion exchange polymers for anion separations - Google Patents
Ion exchange polymers for anion separations Download PDFInfo
- Publication number
- WO1996040803A1 WO1996040803A1 PCT/US1996/008800 US9608800W WO9640803A1 WO 1996040803 A1 WO1996040803 A1 WO 1996040803A1 US 9608800 W US9608800 W US 9608800W WO 9640803 A1 WO9640803 A1 WO 9640803A1
- Authority
- WO
- WIPO (PCT)
- Prior art keywords
- integer
- resin
- counterion
- anion exchange
- nitrogen
- Prior art date
Links
- FKNQCJSGGFJEIZ-UHFFFAOYSA-N Cc1ccncc1 Chemical compound Cc1ccncc1 FKNQCJSGGFJEIZ-UHFFFAOYSA-N 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F226/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a single or double bond to nitrogen or by a heterocyclic ring containing nitrogen
- C08F226/06—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a single or double bond to nitrogen or by a heterocyclic ring containing nitrogen by a heterocyclic ring containing nitrogen
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J41/00—Anion exchange; Use of material as anion exchangers; Treatment of material for improving the anion exchange properties
- B01J41/04—Processes using organic exchangers
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J41/00—Anion exchange; Use of material as anion exchangers; Treatment of material for improving the anion exchange properties
- B01J41/08—Use of material as anion exchangers; Treatment of material for improving the anion exchange properties
- B01J41/12—Macromolecular compounds
- B01J41/14—Macromolecular compounds obtained by reactions only involving unsaturated carbon-to-carbon bonds
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F1/00—Treatment of water, waste water, or sewage
- C02F1/42—Treatment of water, waste water, or sewage by ion-exchange
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F8/00—Chemical modification by after-treatment
- C08F8/44—Preparation of metal salts or ammonium salts
Definitions
- the present invention relates to ion exchange resins and to a process of separating anions, including anionic metal complexes, using such ion exchange resins.
- This invention is the result of a contract with the United States Department of Energy (Contract No. W-7405-ENG-36).
- Polymer resins containing charged functional groups have been used for many years to recover anions and cations from solution.
- the fixed charged functional groups on the resin require counterions of opposite charge to maintain overall electroneutrality.
- anions or cations present in the solution may exchange with groups of the same charge bound electrostatically to the charged polymer sites, hence the term "ion exchange" for this process.
- ion exchange One useful feature of this ion exchange process is the ease of separating solid resin from the treated solution.
- the ion exchange equilibria for a particular resin structure and solution composition are driven by a variety of thermodynamic and kinetic factors that are still only partially predictable.
- One resin property of great importance for industrial applications is the selectivity for binding particular metal ions from solution.
- Useful ion exchange resins preferentially bind a target metal ion over other metal ions.
- the desire to remove the target metal ion may result for a variety of reasons including greater value of the target metal (e.g., gold versus iron), greater toxicity of the target metal (e.g., mercury versus sodium), or deleterious effects of the target metal ion on subsequent operations (e.g., lead poisoning of catalytic converters).
- Another object of the present invention is to provide a process for removal of target anions or anionic metal complexes from solution using the anion exchange resins.
- A, B and D are nitrogen
- n is an integer from 2 to 6
- X " is a counterion
- A, B and D is nitrogen and one of A', B' and D' is nitrogen
- each R and R' is an alkyl having from 1 to about 6 carbon atoms
- R' is attached to said A, B or D which is nitrogen
- n is an integer from l to ⁇
- a + b + c + d l and a + b is from about 0.2 to about 1.0
- X " is a counterion.
- each R is the same and is an alkyl having from 1 to about 6 carbon atoms
- n is an integer from 1 to 6
- m is an integer from 1 to 4
- p is an integer from 1 to 6
- x + y 1 and x is from about 0.2 to about 1.0
- X " is a counterion
- A, B and D is nitrogen and one of A', B' and D' is nitrogen
- each R and R' is an alkyl having from 1 to about 6 carbon atoms
- R' is attached to said A, B or D which is nitrogen
- n is an integer from l to ⁇
- X " is a counterion, under conditions suitable for sorption of said target anions or anionic metal complexes by the anion exchange resin, and, contacting said anion exchange resin including sorbed target anions or anionic metal complexes with an aqueous solution having properties suitable for separation of said target anions or anionic metal complexes from the anion exchange resin.
- the present invention is concerned with anion exchange resins and the use of such anion exchange resins in the separation of anions or anionic metal complexes.
- the present anion exchange resins demonstrate higher selectivity and faster sorption kinetics for removing plutonium from nitric acid/nitrate salt solutions, thereby resulting in increased efficiency and decreased costs in such separations.
- the present invention includes polymer resins with repeating units containing two positively charged functional groups with a well-defined and reproducible spacing fixed by the chemical structure or one positively charged functional group and one neutral functional group capable of protonation in acidic media to form a second positively charged functional group, also with a well-defined and reproducible spacing between the charged groups.
- the anion exchange resins of the present invention generally contain at least two positively charged sites with a defined spacing therebetween or contain at least one positively charged site and at least one neutral site capable of protonation in acidic media to yield at least one additional positively charged site also with a defined spacing therebetween.
- the defined spacing can be selectively controlled in the preparation of the anion exchange resin, e.g., by selection of spacer groups such as alkylene groups, oxy alkylene groups and the like. By control of the positive sites and the spacing therebetween, selectivity and kinetics of the anion exchange resin in a separation process can be controlled and enhanced.
- the chloride form of the resin was placed in a column and a solution containing a known concentration of a different anion (such as sulfate, phosphate, nitrate and the like) was passed through the column until all the chloride anions were displaced (as measured by ion chromatography).
- a solution containing a known concentration of a different anion such as sulfate, phosphate, nitrate and the like
- One property of the present anion exchange resins is especially low binding to plutonium at dilute nitric acid (HNO 3 ) concentrations of about 0.1 Molar (M) to about 1 M, i.e., at a pH of about 0 to 1, but high binding of plutonium at strong nitric acid concentrations, i.e., about 5 M to 7 M HNO 3 .
- dilute nitric acid can be used to elute or recover sorbed plutonium from the anion exchange resin with particular ease and completeness and thus regenerate the resin for further use.
- This weaker sorption from dilute nitric acid allows plutonium to be recovered more quickly at higher concentrations and in a smaller volume of eluate.
- the anion exchange resins of the present invention include polymer resins with repeating units containing two positively charged functional groups with a well- defined spacing fixed by the chemical structure or include polymer resins with repeating units containing one positively charged functional group and a neutral group capable of protonation within acidic media to yield a positively charged functional group with a well defined spacing fixed by the chemical structure.
- the two positively charged functional groups can each be, e.g., quaternary nitrogens, or a quaternary nitrogen and a quaternary phosphorus.
- the anion exchange resins of the present invention consist of a poly(vinyl pyridine) polymer structure with appropriate substitution.
- other polymer structures such as polystyrene can also be functionalized to produce resins with repeating units containing two positively charged functional groups having reproducible spacing.
- poly(vinylpyridine) as the basic polymer structure generally from about 30 to about 80 percent of the pyridine groups are functionalized, preferably from about 60 to about 75 percent, thereby yielding a first positively charged functional group.
- the substitution includes the selected defined spacing connecting to either a second positively charged functional group or a neutral tunctional group capable ot protonation in acidic media to yield a second positively charged functional group.
- Excessive functionalization of the pyridine group typically leads to a material which is too hydrophobic to allow for effective anion or anionic metal complex separations in aqueous media. Insufficient functionalization of the pyridine group typically results in inadequate anion exchange capacity by the resin thus increasing the size of the ion exchange column needed for a particular separation.
- degree of functionalization will vary. Examples of poly(vinyl pyridine) that can be substituted include ReillexTM HP poly( vinyl pyridine) resin and ReillexTM 402 poly(vinyl pyridine) resin.
- ReillexTM HP poly(vinyl pyridine) resin is typically about 25 to 30 percent crosslinked with divinyl benzene and ReillexTM 402 poly(vinyl pyridine) resin is typically about 2 percent crosslinked with divinyl benzene. Both resins are available from Reilly Industries, Inc.
- the anion exchange resin generally includes substantial repeating units of the type: (a)
- each R is the same and is an alkyl having from 1 to about 6 carbon atoms
- n is an integer from 2 to 6 when Q is nitrogen and an integer fron 1 to 6 when Q is phosphorus
- X * is a counterion
- each R is the same and is an alkyl having from 1 to about 6 carbon atoms
- n is an integer from 1 to 6 carbon atoms
- m is an integer from 1 to 4
- p is an integer from 1 to 6
- x + y - 1 and x is from about 0.2 to about 1.0
- X " is a counterion
- n is an integer from 1 to 6
- X " is a counterion
- n is an integer from 1 to 6
- X " is a counterion
- each R and R' is an alkyl having from 1 to about 6 carbon atoms
- R' is attached to said A, B or D which is nitrogen
- n is an integer from l to ⁇
- a + b + c + d l and a + b is from about 0.2 to about 1.0
- X " is a counterion.
- the alkyl groups in the above structures have from 1 to 4 carbon atoms because greater than about 4 carbon atoms can result in the resin being too hydrophobic for effective anion or anionic metal complex separations from aqueous solutions.
- x and a + b are more preferably from about 0.2 to about 0.8 and most preferably from about 0.60 to 0.75 as greater values can result in the resin being too hydrophobic for effective anion or anionic metal complex separations from aqueous solutions.
- -(CH 2 CH 2 ) y - unit and the -(CH 2 CH 2 ) d - unit can be either in the free base or the acid form.
- the anion exchange resins can generally be prepared by functionalization of, e.g., poly(vinyl pyridine) resins such as ReillexTM HP poly( vinyl pyridine) resin and ReillexTM 402 poly( vinyl pyridine) resin, with several different types of alkylating agents.
- alkylating agent can be ⁇ -bromoalkyl-trimethylammonium bromides.
- Another related type of alkylating agent can be a ⁇ -bromoalkyl- trimethylammonium bromide with the alkyl containing an oxygen atom in the alkyl group unit, e.g., a CH 2 CH 2 OCH 2 CH 2 group instead of a (CH 2 ) 5 group.
- alkylating agent can be ⁇ -bromoalkylpyridinium bromides which are not commercially available but which can be prepared from reactions of pyridine with l, ⁇ -dibromoalkanes as described, e.g., by Duling et al., J. Am. Chem. Soc, v. 84, p.578 (1962).
- the monosubstitution product often may be found to be heavily contaminated with the product of disubstitution, the present synthetic procedure involved reaction of pyridine with a considerable excess of the appropriate l, ⁇ - dibromoalkane in acetone (for (CH 2 ) 2 ) or benzene (for (CH 2 ) 3 ⁇ ).
- the alkylating agents with (CH 2 ) 2 to (CH 2 ) 4 could be obtained as the monoalkylated products alone whereas for (CH 2 ) 5 and for (CH 2 ) 6 the resultant alkylating agents were contaminated with about 12 percent of the disubstitution product.
- Reaction of the ⁇ -bromoalkylpyridinium bromides with poly(4-vinylpyridine) in ethanol at reflux for 10 days generally yielded alkylation of from about 64 to about 85 percent of the pyridine nitrogens in the resin.
- Still other alkylating agents used to prepare the anion exchange resins were the 3- and 4-picolyl chlorides which were generated in situ from commercially available hydrochloride salts.
- the 3-picolyl-substituted poly(4-vinylpyridine) resin was prepared by reaction of 3-picolyl chloride hydrochloride, potassium carbonate and poly(4-vinylpyridine) in ethanol at reflux for 10 days. The substitution level was about 60 percent. Methylation of the product by reaction with excess iodomethane in ethanol at reflux for three days gave a methylated product with about 83 percent substitution.
- a similar process with the 4-picolyl chloride gave a substitution level of about 45 percent and subsequent methylation gave 97 percent methylation.
- the resins including substantial repeating units with the structure:
- Polystyrene may be functionalized in the same manner as poly( vinyl pyridine) to provide suitable anion exchange resins in accordance with the present invention.
- poly( vinyl pyridine) may be functionalized in the same manner as poly( vinyl pyridine) to provide suitable anion exchange resins in accordance with the present invention.
- the initial starting material can include instead a single methyl group and a hydrogen on the nitrogen such that the one nitrogen would become positively charged upon protonation in acid.
- Ortho and meta isomers of the dimethylaminopyridine can also be used.
- materials such as chloromethyl-substituted polystyrene can be reacted with various hydroxyalkyl-substituted pyridines such as hydroxymethylpyridine, hydroxyethylpyridine, or hydroxypropylpyridine, which may then be further reacted similar to the poly(vinyl pyridine)s to yield a suitable resin.
- a material such as that shown above including an oxygen in the spacer between the charged groups may also be used to separate the polystyrene and the second charged group.
- ⁇ -Bromoalkyltrimethylammonium bromides were as follows. In a fume hood, 10.00 grams (g) of the 1 , ⁇ -dibromoalkane, 150 milliliters (mL) of dry benzene and a magnetic stirring bar were placed in a 250-mL, three-necked flask. Into one side neck of the flask was inserted a glass tube with a drawn tip which extended below the surface of the benzene solution. The other end of the glass tube was connected to a cylinder of trimethylamine gas with rubber tubing. A glass stopper was placed in the middle neck of the flask. To the second side neck of the flask was attached a calcium chloride drying tube.
- 5-Bromopentyltrimethylammonium bromide was obtained in an 82 % yield as a 95:5 mixture of the monosubstitution and disubstitution products.
- 6-Bromohexyltrimethylammonium bromide was obtained in 81-85 % yields uncontaminated with the disubstitution product.
- Preparation of ⁇ -trimethylammoniumalkyl-substituted poly(4-vinylpyridine)s was as follows. A mixture of 5.00 g of the respective ⁇ -bromoalkyltrimethylammonium bromide from Example 1 and an equimolar amount of ReillexTM 402 poly(4- vinylpyridine) in 380 mL of absolute ethanol (alternatively 7.00 g of the ⁇ - bromoalkyltrimethylammonium bromide and an equimolar amount of poly(4- vinylpyridine) in 530 mL of ethanol) was refluxed for 10 days. At room temperature the mixture was filtered with a sintered glass funnel.
- the solid was washed on the funnel with ethanol (3 X 20 mL) and water (2 X 20 mL). The resulting solid was added to 200 mL of benzene and water was removed from the mixture at reflux with a Dean-Stark trap. The benzene was removed from the mixture in vacuo and the residue was dried in vacuo overnight to give the white product resin. The level of substitution was calculated from the percentage of bromine in the resin.
- 6-Bromohexyl-l -pyridinium bromide was obtained in 91% yield as a mixture of 88% monosubstitution product and 12% disubstitution product.
- EXAMPLE 6 Preparation of 3-picolyl-substituted poly(4-vinylpyridine) was as follows. A mixture of 10.00 g (95.11 mmol) of ReillexTM 402 poly(4-vinylpyridine), 16.60 g (95.11 mmol) of 3-picolyl chloride hydrochloride, and 6.92 g (50.06 mmol) of anhydrous potassium carbonate in 650 mL of absolute ethanol was refluxed for 10 days. At room temperature the mixture was filtered with a sintered glass funnel. The solid was washed on the funnel with ethanol (3 X 20 mL) and water (2 X 20 mL).
- the level of methylation of the resin was calculated from the percentage of iodine in the product resin. Elemental analysis: Calculated: I, 51.21 for 83% methylation. Found: I, 51.27.
- each air-dried resin was contacted with a measured 6 milliliter (mL) volume of each solution in a specially modified 20 mL disposable hypodermic syringe.
- the syringes were modified by inserting cylindrical plugs cut from quarter-inch-thick porous Kynar, obtained from Porex Technologies, Fairburn, GA, into the tapered tips as filters, which permitted only liquid to pass therethrough.
- Each portion of postcontact solution was assayed by gamma spectrometry for specific gamma energies of the added radionuclides, such as the 129keV of 239 P.
- the fraction of each element sorbed was determined indirectly from the difference in the measured gamma activity of the selected radionuclude before and after contact with each specified absorber.
- the Kd value of each element was calculated as follows:
- Pr measured precontact activity per mL
- Po measured postcontact activity per mL
- S milliliters of solution contacted
- A grams of dry absorber contacted.
- Example 13 Resin 3 was tested with acid-dissolved sludge solution and acidified supernate (simulant solutions for a Hanford Washington waste tank) to measure the Kd values for a series of 14 elements.
- the measured values shown below in Table 5 provide information about the different elements absorption by the resins and in the case where plutonium is the target metal these data show which elements are likely to interfere or compete with the absorber sites (the selectivity of these resins for the various elements).
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- Engineering & Computer Science (AREA)
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Abstract
Description
Claims
Priority Applications (5)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
AU59809/96A AU720136B2 (en) | 1995-06-07 | 1996-06-04 | Ion exchange polymers for anion separations |
EP96917141A EP0830388A4 (en) | 1995-06-07 | 1996-06-04 | Ion exchange polymers for anion separations |
UA97125866A UA42838C2 (en) | 1995-06-07 | 1996-06-04 | Ion exchange polymer and process of removing anions or anionic metal complexes by means thereof |
BR9609419A BR9609419A (en) | 1995-06-07 | 1996-06-04 | Ion exchange polymers for anion separation |
JP50128997A JP2001525720A (en) | 1995-06-07 | 1996-06-04 | Ion exchange polymer for anion separation |
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US08/476,964 | 1995-06-07 | ||
US08/476,964 US5670550A (en) | 1995-06-07 | 1995-06-07 | Ion exchange polymers for anion separations |
Publications (1)
Publication Number | Publication Date |
---|---|
WO1996040803A1 true WO1996040803A1 (en) | 1996-12-19 |
Family
ID=23893949
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
PCT/US1996/008800 WO1996040803A1 (en) | 1995-06-07 | 1996-06-04 | Ion exchange polymers for anion separations |
Country Status (11)
Country | Link |
---|---|
US (1) | US5670550A (en) |
EP (1) | EP0830388A4 (en) |
JP (1) | JP2001525720A (en) |
KR (1) | KR19990022653A (en) |
CN (1) | CN1214701A (en) |
AU (1) | AU720136B2 (en) |
BR (1) | BR9609419A (en) |
CA (1) | CA2223945A1 (en) |
RU (1) | RU2152957C2 (en) |
UA (1) | UA42838C2 (en) |
WO (1) | WO1996040803A1 (en) |
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN101735371B (en) * | 2009-12-10 | 2012-05-23 | 中国科学院长春应用化学研究所 | Hydroxyl type anion resin containing imidazole structure, method for preparing same and application thereof in preparation of biodiesel |
Families Citing this family (9)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP0883574B1 (en) * | 1996-03-01 | 2004-01-02 | Dionex Corporation | Anion-exchange resins with at least two different nitrogen containing ion-exchange groups |
US6204337B1 (en) | 1996-11-19 | 2001-03-20 | The Board Of Regents Of The University And Community College System Of Neveda | Solid-phase synthesis of codeine from morphine |
JP2003527950A (en) * | 2000-01-03 | 2003-09-24 | ジャングバーワラ、ジュザー | Method and apparatus for removing metal by ion exchange |
JP4717253B2 (en) * | 2000-12-19 | 2011-07-06 | 昭和電工株式会社 | Porous polymer particles, alkali-resistant anion exchanger, production method thereof, ion chromatography column, and anion measurement method |
AT411463B (en) * | 2002-09-03 | 2004-01-26 | Dsm Fine Chem Austria Gmbh | High yield production of alkylated nitrogen containing crosslinked polymer gels, e.g. epichlorohydrin crosslinked poly allylamine hydrochloride, comprises washing with methanol, sodium chloride and water |
DE102007034733A1 (en) * | 2007-07-23 | 2009-01-29 | Lanxess Deutschland Gmbh | Process for the preparation of monodisperse chelating resins |
US7968663B2 (en) * | 2007-12-18 | 2011-06-28 | General Electric Company | Anion exchange polymers, methods for making and materials prepared therefrom |
US11014050B2 (en) | 2013-11-12 | 2021-05-25 | Amogreentech Co., Ltd. | Ion exchange membrane and filter module using same |
KR101715811B1 (en) * | 2013-11-12 | 2017-03-13 | 주식회사 아모그린텍 | Ion exchange membrane |
Citations (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US2683124A (en) * | 1949-09-24 | 1954-07-06 | Koppers Co Inc | Ion-exchange resins from a vinyl heterocyclic amino compound and a vinyl-cyclohexene |
US2801224A (en) * | 1953-03-30 | 1957-07-30 | Permutit Co | Quaternary ammonium anion exchange resins and method for preparing the same |
US4154615A (en) * | 1976-06-24 | 1979-05-15 | Konishiroku Photo Industry Co., Ltd. | Color diffusion transfer unit with polymeric quaternary nitrogen mordant |
Family Cites Families (9)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US2860096A (en) * | 1955-06-15 | 1958-11-11 | Ionics | Polyelectrolytes and the method of making the same |
US3919126A (en) * | 1973-08-23 | 1975-11-11 | Dow Chemical Co | Insoluble polyalkyl phosphonium salt resins having crosslinked backbone |
US4469873A (en) * | 1982-11-04 | 1984-09-04 | Texaco Inc. | Vinyl pyridinium monomers |
CH660370A5 (en) * | 1984-03-23 | 1987-04-15 | Ciba Geigy Ag | RADIATION-SENSITIVE POLYMERS AND THEIR METAL COMPLEXES. |
US4725420A (en) * | 1985-09-25 | 1988-02-16 | Toa Nenryo Kogyo Kabushiki Kaisha | Process for the production of silanes |
US4883608A (en) * | 1987-11-18 | 1989-11-28 | Southwest Research Institute | Polymeric decontamination composition |
GB8912903D0 (en) * | 1989-06-05 | 1989-07-26 | Smith Kline French Lab | Compounds |
JP2832904B2 (en) * | 1990-07-07 | 1998-12-09 | 三菱レイヨン株式会社 | Biodegradable polymer |
US5371160A (en) * | 1993-04-06 | 1994-12-06 | Reilly Industries, Inc. | Linear polyvinylpyridine polymers and processes |
-
1995
- 1995-06-07 US US08/476,964 patent/US5670550A/en not_active Expired - Fee Related
-
1996
- 1996-06-04 JP JP50128997A patent/JP2001525720A/en active Pending
- 1996-06-04 CN CN96195919A patent/CN1214701A/en active Pending
- 1996-06-04 BR BR9609419A patent/BR9609419A/en not_active Application Discontinuation
- 1996-06-04 UA UA97125866A patent/UA42838C2/en unknown
- 1996-06-04 AU AU59809/96A patent/AU720136B2/en not_active Ceased
- 1996-06-04 EP EP96917141A patent/EP0830388A4/en not_active Withdrawn
- 1996-06-04 CA CA002223945A patent/CA2223945A1/en not_active Abandoned
- 1996-06-04 WO PCT/US1996/008800 patent/WO1996040803A1/en not_active Application Discontinuation
- 1996-06-04 RU RU98100087/04A patent/RU2152957C2/en not_active IP Right Cessation
- 1996-06-04 KR KR1019970709228A patent/KR19990022653A/en not_active Application Discontinuation
Patent Citations (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US2683124A (en) * | 1949-09-24 | 1954-07-06 | Koppers Co Inc | Ion-exchange resins from a vinyl heterocyclic amino compound and a vinyl-cyclohexene |
US2801224A (en) * | 1953-03-30 | 1957-07-30 | Permutit Co | Quaternary ammonium anion exchange resins and method for preparing the same |
US4154615A (en) * | 1976-06-24 | 1979-05-15 | Konishiroku Photo Industry Co., Ltd. | Color diffusion transfer unit with polymeric quaternary nitrogen mordant |
Non-Patent Citations (1)
Title |
---|
See also references of EP0830388A4 * |
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN101735371B (en) * | 2009-12-10 | 2012-05-23 | 中国科学院长春应用化学研究所 | Hydroxyl type anion resin containing imidazole structure, method for preparing same and application thereof in preparation of biodiesel |
Also Published As
Publication number | Publication date |
---|---|
JP2001525720A (en) | 2001-12-11 |
RU2152957C2 (en) | 2000-07-20 |
AU5980996A (en) | 1996-12-30 |
BR9609419A (en) | 1999-07-27 |
EP0830388A4 (en) | 2001-03-21 |
KR19990022653A (en) | 1999-03-25 |
CA2223945A1 (en) | 1996-12-19 |
AU720136B2 (en) | 2000-05-25 |
UA42838C2 (en) | 2001-11-15 |
US5670550A (en) | 1997-09-23 |
CN1214701A (en) | 1999-04-21 |
EP0830388A1 (en) | 1998-03-25 |
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