WO1996028609A1 - Coated paperboard for formed articles - Google Patents
Coated paperboard for formed articles Download PDFInfo
- Publication number
- WO1996028609A1 WO1996028609A1 PCT/SE1996/000079 SE9600079W WO9628609A1 WO 1996028609 A1 WO1996028609 A1 WO 1996028609A1 SE 9600079 W SE9600079 W SE 9600079W WO 9628609 A1 WO9628609 A1 WO 9628609A1
- Authority
- WO
- WIPO (PCT)
- Prior art keywords
- coating
- paperboard
- coated paperboard
- formed articles
- calender
- Prior art date
Links
Classifications
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21G—CALENDERS; ACCESSORIES FOR PAPER-MAKING MACHINES
- D21G1/00—Calenders; Smoothing apparatus
- D21G1/006—Calenders; Smoothing apparatus with extended nips
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H25/00—After-treatment of paper not provided for in groups D21H17/00 - D21H23/00
- D21H25/08—Rearranging applied substances, e.g. metering, smoothing; Removing excess material
- D21H25/12—Rearranging applied substances, e.g. metering, smoothing; Removing excess material with an essentially cylindrical body, e.g. roll or rod
- D21H25/14—Rearranging applied substances, e.g. metering, smoothing; Removing excess material with an essentially cylindrical body, e.g. roll or rod the body being a casting drum, a heated roll or a calender
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H11/00—Pulp or paper, comprising cellulose or lignocellulose fibres of natural origin only
- D21H11/02—Chemical or chemomechanical or chemothermomechanical pulp
- D21H11/04—Kraft or sulfate pulp
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H19/00—Coated paper; Coating material
- D21H19/36—Coatings with pigments
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H27/00—Special paper not otherwise provided for, e.g. made by multi-step processes
- D21H27/30—Multi-ply
- D21H27/38—Multi-ply at least one of the sheets having a fibrous composition differing from that of other sheets
Definitions
- the present invention relates to coated paperboard for formed articles, e.g. liquid packaging board or white top liner, a process for the production thereof, a production line, and a method of reducing the susceptibility to crack formation at folding of a coated paperboard.
- coated paperboard for formed articles are sufficient stiffness measured as bending force, good forming properties including low susceptibility to crack formation at folding, adequate surface for printing and adequate surface gloss. All of these required properties vary with the specific type of formed article which is to be produced from the coated paperboard.
- a conventional way of producing board with high stiffness is to use a fibermatrix with three or more layers where the middle layer gives bulk and the two outer layers have a high elasticity modulus or high tensile stiffness.
- the middle layer gives bulk and the two outer layers have a high elasticity modulus or high tensile stiffness.
- coated board with high stiffness made from only two fiber layers.
- nip calenders which have steel rolls
- soft nip calenders which have steel rolls where the counter rolls have a softer cover.
- the nip lengths in these soft nip calenders are typically approximately 1 cm.
- a new type of calender is disclosed in Pulp & Paper International (PPI), May 1994, page 36. Surface properties of an uncoated board grade were reported to be improved with only minor loss of stiffness (bulk).
- the new calender is constructed to have a relatively soft elastic moving belt supported by a glide body or roll instead of the covered roll in a conventional soft calender.
- the elongated nip contour in combination with the soft elastic belt is reported to yield uniform specific pressures and nip lengths which typically would be four to six centimeter.
- This new type of calender has been named supersoft calender in said article, and said calender could be used in the present invention where a heatable calender with soft extended nip is required.
- Savings in raw material can be made in the amount of fibermatrix used and/or the amount of coating used.
- the present invention provides in one aspect a coated paperboard for formed articles, including liquid packaging board and white top liner, which paperboard consists of a fibermatrix in one, two or more layers and a coating and has adequate surface for printing and adequate surface gloss for each specific type of formed articles.
- the characteristic features of said paperboard are that it has been calendered after coating with a heatable calender having a soft extended nip, and has reduced density and reduced grammage at a given value for bending force compared to corresponding coated paperboard which has been calendered before or before and after coating with a heatable or non-heatable calender having a hard or soft nip.
- extended nip is considered to comprise nip lengths of 3 to 10 cm, such as 4 to 8 cm, e.g. 6 to 7 cm.
- the fibermatrix used in the present invention is preferably composed of sulphate pulp and/or mechanical pulp and/or recycled pulp, and is either unbleached or bleached.
- the coating of the board is composed of binders and usually also pigments to enhance the printability. Examples of common binders in this context are latex and starch, and examples of common pigments are clay and calcium carbonate.
- SUBSfrTTUT ⁇ SHEET (RULE 26)
- the given value for bending force depends on the specific type of formed articles which are to be produced. Small formed articles or packages do not need as high values for bending force as larger ones. For example, for a coated liquid board from which smaller, such as 250 ml, packages are to be produced, values for bending force may be in the range of 50 to 100 mN, and for a coated liquid board from which larger, such as 1 liter, packages are to be produced values for bending force may be in the range of 200 to 300 mN.
- coated paperboard for formed articles wherein said given value for bending force is in the range of 20 to 300 mN, said reduction of density is in the range of 1 - 50 % and said reduction of grammage is in the range of 1 - 20%.
- coated paperboard for formed articles wherein said given value for bending force is in the range of 60 - 270 mN, said reduction of density is in the range of 1 to 35 % and said reduction in grammage is in the range of 1 - 15 %.
- the percent reduction of the density and the percent reduction of the grammage of the coated paperboard at a given value for bending force are calculated on a corresponding coated paperboard for the same specific type of formed articles which has been calendered before or before and after coating with a heatable or non- heatable calender having a hard or soft nip.
- the fibermatrix of the coated paperboard of the invention is composed of two layers.
- the fibermatrix is composed of unbleached sulphate pulp in the bottom layer and bleached sulphate pulp in the top layer and the coating comprises binders and pigments.
- SHEET (RULE 26)
- a production line for the production of coated paperboard which paperboard consists of a fibermatrix in one, two or more layers and a coating and has adequate surface for printing and adequate surface gloss for each specific type of formed articles.
- the characteristic feature of this new production line is that there is arranged, only after a coating device, a heatable calender with a soft extended nip.
- the present invention also comprises production lines where there is additionally arranged a calender before the coating device.
- a precalendering may be performed then the savings of raw material will be less.
- the precalendering before the coating operation may be performed with any type of calender.
- a process for the production of coated paperboard for formed articles with adequate surface for printing and adequate surface gloss for each specific type of formed articles wherein the fibermatrix of the paperboard is composed of one, two or more layers.
- the characteristic feature of the process is that a calendering operation is performed only after a coating operation with a calender which is run at high temperature and has a soft extended nip.
- the calender temperatures is in the range of 140 to 250 °C, but even higher temperatures are possible.
- the present invention also comprises a process for the production of coated paperboard for formed articles wherein there is additionally performed a calendering operation before said coating operation.
- SUBST ⁇ UTE SHEET (RULE 26)
- the characteristic feature of the method is that said coated paperboard is produced in a production line wherein a calendering operation is performed only after a coating operation with a calender which is run at high temperature and has a soft extended nip.
- the present invention also comprises such a method, wherein there is additionally performed a calendering operation before said coating operation.
- the Print-surf roughness at 1000 kPa was measured according to
- the Gloss was measured according to Tappi, T 480.
- the Density was measured according to SCAN P 7:75.
- the Bending force was measured according to SCAN P 29:84.
- the Uniformity variance was evaluated with the aid of an image analyzer "Kontron IBAS" system.
- the grammage was measured in accordance with SCAN P6:75.
- EXAMPLE 1 In a pilot trial it was shown that the uniformity of the coated surface was better when the calendering after coating was done with an extended soft nip in comparison with a conventional soft nip. The board was in this case calendered also before coating. It was also shown that the density was lower when using an soft extended nip in comparison with a conventional soft calender.
- the uniformity of the coating was measured in an image analyzer in the wave length area 2.0-8.0 mm.
- the soft extended nip calender was used to produce the same surface as the reference quality which was calendered only before coating.
- the calendering was done only after coating.
- the stiffness increase measured as bending force was greater than in the pilot trials.
- This increase in stiffness means that the grammage can be reduced from 255 g/m 2 to 245 g/m 2 keeping the other specifications at the same or even improved levels. This improvement makes it possible to further decrease the grammage.
- the board from the mill trial was also printed and the print result was evaluated.
- the overall print result and the uniformity of the print was better for the test quality.
Landscapes
- Paper (AREA)
- Machines For Manufacturing Corrugated Board In Mechanical Paper-Making Processes (AREA)
- Cartons (AREA)
- Making Paper Articles (AREA)
- Laminated Bodies (AREA)
Abstract
Description
Claims
Priority Applications (7)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CA002214977A CA2214977C (en) | 1995-03-16 | 1996-01-25 | Coated paperboard for formed articles |
AT96906118T ATE210760T1 (en) | 1995-03-16 | 1996-01-25 | COATED CARDBOARD MATERIAL FOR MOLDED BODY |
DE69617925T DE69617925T2 (en) | 1995-03-16 | 1996-01-25 | COATED PAPER MATERIAL FOR MOLDED BODIES |
EP96906118A EP0815319B1 (en) | 1995-03-16 | 1996-01-25 | Coated paperboard for formed articles |
AU49595/96A AU4959596A (en) | 1995-03-16 | 1996-01-25 | Coated paperboard for formed articles |
JP52750196A JP3860836B2 (en) | 1995-03-16 | 1996-01-25 | Coated paperboard for processed products |
US08/913,110 US6022448A (en) | 1995-03-16 | 1996-01-25 | Coated paperboard for formed articles |
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
SE9500949A SE503580C2 (en) | 1995-03-16 | 1995-03-16 | Coated cardboard for shaped articles, production line for production of coated cardboard, method for making coated cardboard and ways to reduce the cracking propensity when folding a coated cardboard |
SE9500949-4 | 1995-03-16 |
Publications (1)
Publication Number | Publication Date |
---|---|
WO1996028609A1 true WO1996028609A1 (en) | 1996-09-19 |
Family
ID=20397578
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
PCT/SE1996/000079 WO1996028609A1 (en) | 1995-03-16 | 1996-01-25 | Coated paperboard for formed articles |
Country Status (11)
Country | Link |
---|---|
US (1) | US6022448A (en) |
EP (1) | EP0815319B1 (en) |
JP (1) | JP3860836B2 (en) |
AT (1) | ATE210760T1 (en) |
AU (1) | AU4959596A (en) |
DE (1) | DE69617925T2 (en) |
ES (1) | ES2166880T3 (en) |
FI (1) | FI105493B (en) |
PT (1) | PT815319E (en) |
SE (1) | SE503580C2 (en) |
WO (1) | WO1996028609A1 (en) |
Cited By (14)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO1998044201A1 (en) * | 1997-03-27 | 1998-10-08 | Voith Sulzer Papiermaschinen Gmbh | Method and device for coating a continuous strip of material, specially paper or cardboard, with a liquid or paste-like application medium, method for the production of a coated strip |
WO1999067462A1 (en) * | 1998-06-25 | 1999-12-29 | Valmet Corporation | Method and arrangement for calendering paper and board before and after coating |
US6190500B1 (en) | 1998-10-02 | 2001-02-20 | International Paper Company | Multilayer linerboard having improved printing properties and related method of manufacture |
WO2001029316A1 (en) * | 1999-10-19 | 2001-04-26 | Korsnäs Ab | Uncoated paper and board products |
WO2001051709A1 (en) * | 2000-01-07 | 2001-07-19 | International Paper Company | Paper product having enhanced printing properties and related method of manufacture |
EP1123439A1 (en) * | 1998-09-22 | 2001-08-16 | International Paper Company | Method and apparatus for finishing paperboard to achieve improved smoothness and bulk |
US6299728B1 (en) * | 1997-01-31 | 2001-10-09 | Voith Sulzer Papiermaschinen Gmbh | Multi-ply paper |
WO2001083883A1 (en) * | 2000-04-18 | 2001-11-08 | Metso Paper, Inc. | Method for calendering a board web |
EP1433899A2 (en) * | 2002-11-28 | 2004-06-30 | Voith Paper Patent GmbH | Process and apparatus for treating a paper or cardboard |
US6946186B2 (en) | 2002-08-24 | 2005-09-20 | International Paper Co. | Uncoated facestock for adhesive-backed labels |
WO2006039118A1 (en) * | 2004-09-29 | 2006-04-13 | Meadwestvaco Corporation | White top paperboard |
EP1876294A2 (en) * | 2006-07-05 | 2008-01-09 | Voith Patent GmbH | Method for processing a sheet of raw paper or raw cardboard |
WO2012130908A1 (en) * | 2011-03-29 | 2012-10-04 | Hamburger Rieger Gmbh & Co. Kg | Device and method for producing a multi-layer packaging paper |
EP1755901B2 (en) † | 2004-06-17 | 2016-11-09 | Papierfabrik August Koehler AG | Method for producing thermosensitive recording material and recording material produced according to said method |
Families Citing this family (21)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
FI115649B (en) * | 1998-06-10 | 2005-06-15 | Metso Paper Inc | Method of making paper and paper machine |
ES2141062B1 (en) * | 1998-06-25 | 2000-11-01 | Erplip S A | PROCEDURE FOR THE MANUFACTURE OF COATED CARDBOARD FOR LIQUID PACKAGING. |
FI111476B (en) * | 1999-03-12 | 2003-07-31 | Metso Paper Inc | Method and apparatus for making coated paper and coated paper |
FI991108A (en) * | 1999-05-14 | 2000-11-15 | Valmet Corp | Method and apparatus for the manufacture of calendered paper or calendered paperboard |
US6352022B1 (en) * | 1999-08-12 | 2002-03-05 | Stora Enso North America | Web calendering method and apparatus |
US6440269B1 (en) * | 1999-12-06 | 2002-08-27 | Domtar, Inc. | Base sheet for wallcoverings |
FI112048B (en) * | 2000-04-10 | 2003-10-31 | Stora Enso Oyj | Laminated heat sealable packaging material, food packaging formed therefrom and packaging method |
EP1160379B2 (en) * | 2000-05-31 | 2011-03-16 | Oji Paper Co., Ltd. | Paper for use in molding |
FI108241B (en) * | 2000-08-10 | 2001-12-14 | Metso Paper Inc | Process for the manufacture of coated fiber web, improved paper or paperboard machine and coated paper or paperboard |
FI109550B (en) * | 2001-05-23 | 2002-08-30 | Upm Kymmene Corp | Coated printing paper such as machine finished coated printing paper, comprises specific amount of mechanical pulp, and has specific opacity, brightness and surface roughness |
FI110800B (en) * | 2001-06-25 | 2003-03-31 | M Real Oyj | A process for producing a coated fibrous web |
SE0102941D0 (en) * | 2001-09-05 | 2001-09-05 | Korsnaes Ab Publ | Uncoated paperboard for packages |
FI111281B (en) * | 2001-12-12 | 2003-06-30 | Metso Paper Inc | Cardboard finishing procedure |
DE10204285C1 (en) * | 2002-02-02 | 2003-06-18 | Voith Paper Patent Gmbh | For increased paper web strength, web surface is sprayed with glue, and web passes directly through wide nip between hard roller and rotating mantle |
DE10206333C1 (en) * | 2002-02-14 | 2003-07-31 | Voith Paper Patent Gmbh | Wide nip calender arrangement and method for satinizing a paper or Karrton web |
US20040099391A1 (en) * | 2002-11-26 | 2004-05-27 | Bob Ching | Process for producing super high bulk, light weight coated papers |
FI114163B (en) * | 2002-11-27 | 2004-08-31 | Metso Paper Inc | Cardboard product and process for its manufacture |
FI116080B (en) * | 2002-11-27 | 2005-09-15 | Metso Paper Inc | Cardboard product and process for its manufacture |
FI116079B (en) * | 2002-11-27 | 2005-09-15 | Metso Paper Inc | Cardboard product and process for its manufacture |
DE102004010894A1 (en) * | 2004-03-06 | 2005-09-22 | Voith Paper Patent Gmbh | Method and device for treating a web of paper or cardboard |
US20070137815A1 (en) * | 2005-12-20 | 2007-06-21 | Shearer Dwayne M | Smooth low density paperboard |
Family Cites Families (6)
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US4391833A (en) * | 1975-09-04 | 1983-07-05 | International Paper Company | Method of making and using heat resistant resin coated paperboard product and product thereof |
US4289808A (en) * | 1978-07-19 | 1981-09-15 | Westvaco Corporation | Process for producing dry finished paperboard |
US4828650A (en) * | 1985-08-23 | 1989-05-09 | International Paper Company | Heat treatment of paper products having milk and other additives |
US5064692A (en) * | 1990-02-15 | 1991-11-12 | International Paper Company | Method for producing paper products having increased gloss in which surface characteristics of a release film are imparted to coated substrates |
DE4011394C1 (en) * | 1990-04-09 | 1991-11-28 | Sulzer-Escher Wyss Gmbh, 7980 Ravensburg, De | |
US5378497A (en) * | 1993-02-10 | 1995-01-03 | Westvaco Corporation | Method for providing irreversible smoothness in a paper rawstock |
-
1995
- 1995-03-16 SE SE9500949A patent/SE503580C2/en not_active IP Right Cessation
-
1996
- 1996-01-25 DE DE69617925T patent/DE69617925T2/en not_active Expired - Lifetime
- 1996-01-25 PT PT96906118T patent/PT815319E/en unknown
- 1996-01-25 AT AT96906118T patent/ATE210760T1/en active
- 1996-01-25 US US08/913,110 patent/US6022448A/en not_active Expired - Lifetime
- 1996-01-25 EP EP96906118A patent/EP0815319B1/en not_active Revoked
- 1996-01-25 ES ES96906118T patent/ES2166880T3/en not_active Expired - Lifetime
- 1996-01-25 WO PCT/SE1996/000079 patent/WO1996028609A1/en active IP Right Grant
- 1996-01-25 JP JP52750196A patent/JP3860836B2/en not_active Expired - Lifetime
- 1996-01-25 AU AU49595/96A patent/AU4959596A/en not_active Abandoned
- 1996-01-31 FI FI960453A patent/FI105493B/en not_active IP Right Cessation
Non-Patent Citations (1)
Title |
---|
DIALOG INFORMATION SERVICES, File 148, TRADE & INDUSTRY DATABASE(TM), Dialog Accession No. 08147347, Supplier Number 17379701, FERGUSON KELLY H., "High-end Coated Board Market Guides T-I's Technology Selection"; & PULP & PAPER, Vol. 69, No. 9, p. 63(5), Sep. 1995. * |
Cited By (24)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US6299728B1 (en) * | 1997-01-31 | 2001-10-09 | Voith Sulzer Papiermaschinen Gmbh | Multi-ply paper |
WO1998044201A1 (en) * | 1997-03-27 | 1998-10-08 | Voith Sulzer Papiermaschinen Gmbh | Method and device for coating a continuous strip of material, specially paper or cardboard, with a liquid or paste-like application medium, method for the production of a coated strip |
WO1999067462A1 (en) * | 1998-06-25 | 1999-12-29 | Valmet Corporation | Method and arrangement for calendering paper and board before and after coating |
US6811654B1 (en) | 1998-06-25 | 2004-11-02 | Valmet Corporation | Method and arrangement for calendering paper and board before and after coating |
JP2002519525A (en) * | 1998-06-25 | 2002-07-02 | ヴァルメット コーポレイション | Method and apparatus for calendering paper and cardboard before and after coating |
US6497790B2 (en) | 1998-09-22 | 2002-12-24 | International Paper Company | Paperboard of improved smoothness and bulk |
EP1123439A1 (en) * | 1998-09-22 | 2001-08-16 | International Paper Company | Method and apparatus for finishing paperboard to achieve improved smoothness and bulk |
US6287424B1 (en) | 1998-09-22 | 2001-09-11 | International Paper Company | Method for finishing paperboard to achieve improved smoothness |
US6190500B1 (en) | 1998-10-02 | 2001-02-20 | International Paper Company | Multilayer linerboard having improved printing properties and related method of manufacture |
US6332953B1 (en) | 1998-10-02 | 2001-12-25 | International Paper Company | Paper product having enhanced printing properties and related method of manufacture |
WO2001029316A1 (en) * | 1999-10-19 | 2001-04-26 | Korsnäs Ab | Uncoated paper and board products |
WO2001051709A1 (en) * | 2000-01-07 | 2001-07-19 | International Paper Company | Paper product having enhanced printing properties and related method of manufacture |
WO2001083883A1 (en) * | 2000-04-18 | 2001-11-08 | Metso Paper, Inc. | Method for calendering a board web |
US6869505B2 (en) | 2000-04-18 | 2005-03-22 | Metso Paper, Inc. | Method for calendering a board web |
US7666495B2 (en) | 2002-08-24 | 2010-02-23 | International Paper Company | Uncoated facestock for adhesive-backed labels |
US6946186B2 (en) | 2002-08-24 | 2005-09-20 | International Paper Co. | Uncoated facestock for adhesive-backed labels |
US7794567B2 (en) | 2002-08-24 | 2010-09-14 | International Paper Co. | Uncoated facestock for adhesive-backed labels |
EP1433899A2 (en) * | 2002-11-28 | 2004-06-30 | Voith Paper Patent GmbH | Process and apparatus for treating a paper or cardboard |
EP1433899A3 (en) * | 2002-11-28 | 2007-07-04 | Voith Patent GmbH | Process and apparatus for treating a paper or cardboard |
EP1755901B2 (en) † | 2004-06-17 | 2016-11-09 | Papierfabrik August Koehler AG | Method for producing thermosensitive recording material and recording material produced according to said method |
WO2006039118A1 (en) * | 2004-09-29 | 2006-04-13 | Meadwestvaco Corporation | White top paperboard |
EP1876294A2 (en) * | 2006-07-05 | 2008-01-09 | Voith Patent GmbH | Method for processing a sheet of raw paper or raw cardboard |
EP1876294A3 (en) * | 2006-07-05 | 2010-01-27 | Voith Patent GmbH | Method for processing a sheet of raw paper or raw cardboard |
WO2012130908A1 (en) * | 2011-03-29 | 2012-10-04 | Hamburger Rieger Gmbh & Co. Kg | Device and method for producing a multi-layer packaging paper |
Also Published As
Publication number | Publication date |
---|---|
JP3860836B2 (en) | 2006-12-20 |
DE69617925D1 (en) | 2002-01-24 |
AU4959596A (en) | 1996-10-02 |
PT815319E (en) | 2002-06-28 |
SE9500949L (en) | 1996-07-08 |
FI960453A0 (en) | 1996-01-31 |
FI105493B (en) | 2000-08-31 |
ES2166880T3 (en) | 2002-05-01 |
SE9500949D0 (en) | 1995-03-16 |
EP0815319A1 (en) | 1998-01-07 |
ATE210760T1 (en) | 2001-12-15 |
US6022448A (en) | 2000-02-08 |
EP0815319B1 (en) | 2001-12-12 |
JPH11501994A (en) | 1999-02-16 |
SE503580C2 (en) | 1996-07-08 |
DE69617925T2 (en) | 2002-06-13 |
FI960453A (en) | 1996-09-17 |
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